| Common Name: | LOCTITE LB 8009 HEAVY DUTY ANTI-SEIZE KNOWN AS HEAVY DUTY ANTI-SEIZE, 51605 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 9/30/2020 |
| SDS Format: | No Format Specified |
| Item Number(s): | 4KM74 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 007.0
ISSUE DATE: 09/30/2020
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE LB 8009 HEAVY DUTY ANTI-SEIZE KNOWN AS HEAVY DUTY ANTI-SEIZE
PRODUCT TYPE/USE: ANTISEIZE
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 234347
ITEM NUMBER: 51605
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. WEAR PROTECTIVE GLOVES, EYE
PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: NOT PRESCRIBED
DISPOSAL: NOT PRESCRIBED
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED
NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF
CHEMICALS (GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
CALCIUM FLUORIDE 7789-75-5 10 - 30
DISTILLATES (PETROLEUM), SOLVENT-REFINED 64741-88-4 10 - 30
HEAVY PARAFFINIC
DISTILLATES (PETROLEUM), SOLVENT-DEWAXED 64742-65-0 10 - 30
HEAVY PARAFFINIC <3%DMSO
GRAPHITE 7782-42-5 10 - 30
CALCIUM DISTEARATE 1592-23-0 5 - 10
DISTILLATES (PETROLEUM), HYDROTREATED 64742-52-5 5 - 10
HEAVY NAPHTHENIC
PETROLEUM DISTILLATES, HYDROTREATED, 64742-53-6 5 - 10
LIGHT NAPHTHENIC
CALCIUM DODECYLBENZENE SULFONATE 26264-06-2 1 - 5
RESIDUAL OILS (PETROLEUM), 64742-01-4 0.1 - 1
SOLVENT-REFINED, <3% DMSO
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE
IS PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION: MOVE TO FRESH AIR. IF SYMPTOMS PERSIST, SEEK MEDICAL ADVICE.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL
ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED
TO EXTREME HEAT.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. TOXIC AND IRRITATING VAPORS. TRACES OF OXIDES OF SULFUR.
MAY RELEASE TRACE QUANTITIES OF FLUORIDE.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEM.
CLEAN-UP METHODS:
SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. CLEAN RESIDUE WITH SOAP AND WATER.
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
KEEP CONTAINER CLOSED. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. WASH
THOROUGHLY AFTER HANDLING.
STORAGE: KEEP IN A COOL, WELL VENTILATED AREA.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA OTHER
WEEL
CALCIUM FLUORIDE 2.5 MG/M3 2.5 MG/M3 NONE NONE
TWA (AS F) PEL (AS F)
2.5 MG/M3
TWA DUST.
DISTILLATES (PETROLEUM), 5 MG/M3 TWA 500 PPM NONE NONE
SOLVENT-REFINED HEAVY INHALABLE (2,000 MG/M3)
PARAFFINIC FRACTION. PEL
5 MG/M3 TWA 5 MG/M3 PEL
MIST MIST.
10 MG/M3 STEL 5 MG/M3 TWA
MIST MIST
DISTILLATES (PETROLEUM), 5 MG/M3 TWA 500 PPM NONE NONE
SOLVENT-DEWAXED HEAVY INHALABLE (2,000 MG/M3)
PARAFFINIC <3% DMSO FRACTION. PEL
5 MG/M3 PEL
MIST.
GRAPHITE 2 MG/M3 TWA 5 MG/M3 PEL NONE NONE
RESPIRABLE RESPIRABLE
FRACTION. FRACTION.
15 MG/M3 PEL
TOTAL DUST.
CALCIUM DISTEARATE 3 MG/M3 TWA NONE NONE NONE
RESPIRABLE
FRACTION.
3 MG/M3 TWA
RESPIRABLE
FRACTION.
10 MG/M3 TWA
INHALABLE
FRACTION.
DISTILLATES (PETROLEUM), 5 MG/M3 TWA 500 PPM NONE NONE
HYDROTREATED HEAVY INHALABLE (2,000 MG/M3)
NAPHTHENIC FRACTION. PEL
5 MG/M3 PEL
MIST.
PETROLEUM DISTILLATES, 5 MG/M3 TWA 500 PPM NONE NONE
HYDROTREATED, LIGHT INHALABLE (2,000 MG/M3)
NAPHTHENIC FRACTION. PEL
5 MG/M3 PEL
MIST.
CALCIUM DODECYLBENZENE NONE NONE NONE NONE
SULFONATE
RESIDUAL OILS (PETROLEUM), NONE NONE NONE NONE
SOLVENT-REFINED, <3% DMSO
ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. LOCAL EXHAUST VENTILATION IS
RECOMMENDED WHEN GENERAL VENTILATION IS NOT SUFFICIENT TO CONTROL AIRBORNE
CONTAMINATION BELOW OCCUPATIONAL EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT
SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE
COLOR: GRAY
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: 550 DEG. F (287.8 DEG. C)
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.18
VAPOR DENSITY: HEAVIER THAN AIR.
FLASH POINT: >93 DEG. C (>199.4 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT DETERMINED
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT DETERMINED
AUTOIGNITION TEMPERATURE: NOT DETERMINED
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT DETERMINED
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED
VOC CONTENT: <3% ESSENTIALLY ZERO (EXEMPT COMPOUNDS)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE AT NORMAL CONDITIONS.
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. HYDROCARBONS. IRRITATING ORGANIC VAPOURS. TRACES OF
OXIDES OF SULFUR. MAY RELEASE TRACE QUANTITIES OF FLUORIDE.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: STORE AWAY FROM INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
THIS PRODUCT HAS LOW VOLATILITY AND IS NOT EXPECTED TO CAUSE RESPIRATORY
TRACT IRRITATION DURING NORMAL CONDITIONS OF USE.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
CALCIUM FLUORIDE ORAL LD50 (RAT): TEETH, MUSCLE,
4,250 MG/KG RESPIRATORY
DISTILLATES (PETROLEUM), INHALATION LC50 IRRITANT
SOLVENT-REFINED HEAVY (RAT, 4 H): 2.18 MG/L
PARAFFINIC
DISTILLATES (PETROLEUM), INHALATION LC50 IRRITANT
SOLVENT-DEWAXED HEAVY (RAT, 4 H): 218 MG/L
PARAFFINIC <3% DMSO
GRAPHITE INHALATION LC50 LUNG
(RAT, 4 H):
>2,000 MG/M3
CALCIUM DISTEARATE NONE NO TARGET ORGANS
DISTILLATES (PETROLEUM), INHALATION LC50 IRRITANT
HYDROTREATED HEAVY (RAT, 4 H): 2.18 MG/L
NAPHTHENIC
PETROLEUM DISTILLATES, INHALATION LC50 IRRITANT
HYDROTREATED, LIGHT (RAT, 4 H): 2.18 MG/L
NAPHTHENIC
CALCIUM DODECYLBENZENE NONE EYES, IRRITANT
SULFONATE
RESIDUAL OILS (PETROLEUM), INHALATION LC50 IRRITANT
SOLVENT-REFINED, <3% DMSO (RAT, 4 H): <5.7 MG/L
INHALATION LC50
(RAT, 4 H): 5.7 MG/L
INHALATION LC50
(RAT, 4 H): >4.7 MG/L
INHALATION LC50
(RAT, 4 H):
>4.026 MG/L
INHALATION LC50
(RAT, 4 H): >3.9 MG/L
INHALATION LC50
(RAT, 4 H): 9.6 MG/L
INHALATION LC50
(RAT, 4 H): >5 MG/L
INHALATION LC50
(RAT, 4 H): >3.9 MG/L
INHALATION LC50
(RAT, 4 H): >5.2 MG/L
INHALATION LC50
(RAT, 4 H): 9.6 MG/L
INHALATION LC50
(RAT, 4 H): >5.2 MG/L
INHALATION LC50
(RAT, 4 H): 10.5 MG/L
INHALATION LC50
(RAT, 4 H): >5.53 MG/L
INHALATION LC50
(RAT, 4 H): >5 MG/L
INHALATION LC50
(RAT, 4 H): >5 MG/L
INHALATION LC50
(RAT, 4 H): >2.4 MG/L
INHALATION LC50
(RAT, 4 H): >5.3 MG/L
INHALATION LC50
(RAT, 4 H): 2.18 MG/L
INHALATION LC50
(RAT, 4 H): 10.5 MG/L
INHALATION LC50
(RAT, 4 H): >5 MG/L
INHALATION LC50
(RAT, 4 H): >5.3 MG/L
INHALATION LC50
(RAT, 4 H): >2.5 MG/L
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY
REGULATED)
CALCIUM FLUORIDE NO NO NO
DISTILLATES (PETROLEUM), NO NO NO
SOLVENT-REFINED HEAVY
PARAFFINIC
DISTILLATES (PETROLEUM), NO NO NO
SOLVENT-DEWAXED HEAVY
PARAFFINIC <3% DMSO
GRAPHITE NO NO NO
CALCIUM DISTEARATE NO NO NO
DISTILLATES (PETROLEUM), NO NO NO
HYDROTREATED HEAVY NAPHTHENIC
PETROLEUM DISTILLATES, NO NO NO
HYDROTREATED, LIGHT NAPHTHENIC
CALCIUM DODECYLBENZENE NO NO NO
SULFONATE
RESIDUAL OILS (PETROLEUM), NO NO NO
SOLVENT-REFINED, <3% DMSO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED AS ACTIVE OR ARE EXEMPT FROM LISTING ON THE
TOXIC SUBSTANCES CONTROL ACT (TSCA) INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CALIFORNIA PROPOSITION 65:
NO CALIFORNIA PROPOSITION 65 LISTED CHEMICALS ARE KNOWN TO BE PRESENT.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 8
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 09/30/2020
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION IN
ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION OF
ANY KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF ANY
OTHER JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION PROVIDED
HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY OTHER
JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY AND
REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.