| Common Name: | FIRE-D LIQUID AFTER FIRE ODOR CONTROL |
| Manufacturer: | BIG D INDUSTRIES |
| SDS Revision Date: | 4/7/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 4KN48 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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BIG D(R*)
SAFETY DATA SHEET
BIG D FIRE-D LIQUID AFTER FIRE ODOR CONTROL
| SECTION 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: BIG D FIRE-D LIQUID AFTER FIRE ODOR CONTROL
OTHER MEANS OF IDENTIFICATION: 02201, 120200, 420200, 520200, & C0420203
OTHER IDENTIFICATION: FIRE-D LIQUID
PRODUCT FAMILY: LIQUID DEODORANTS
RECOMMENDED USE: DEODORANT.
RESTRICTIONS ON USE: NONE KNOWN.
MANUFACTURER:
BIG D INDUSTRIES, INC.
5620 SW 29TH ST
OKLAHOMA CITY, OK, 73179
405 682 2541
BIGDIND.COM
EMERGENCY PHONE NO.:
BIG D INDUSTRIES, 405 682 2541, 8-4:30 MONDAY-FRIDAY
SDS NO.: 0434
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
FLAMMABLE LIQUID: CATEGORY 4
ACUTE TOXICITY (ORAL): CATEGORY 2
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SKIN SENSITIZATION: CATEGORY 1
GERM CELL MUTAGENICITY: CATEGORY 1B
CARCINOGENICITY: CATEGORY 1A
AQUATIC HAZARD (ACUTE): CATEGORY 2
AQUATIC HAZARD (CHRONIC): CATEGORY 2
GHS LABEL ELEMENTS:
CORROSION
SKULLS AND CROSSBONES
EXCLAMATION MARK
ENVIRONMENT
HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENT(S):
COMBUSTIBLE LIQUID.
FATAL IF SWALLOWED.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE DAMAGE.
MAY CAUSE GENETIC DEFECTS.
MAY CAUSE CANCER.
TOXIC TO AQUATIC LIFE.
TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENT(S):
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM FLAMES AND HOT SURFACES. - NO SMOKING.
AVOID BREATHING DUST, FUME, GAS, MIST, VAPOURS OR SPRAY.
WASH HANDS AND SKIN THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
AVOID RELEASE TO THE ENVIRONMENT.
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTRE/DOCTOR.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IMMEDIATELY CALL A POISON CENTRE/DOCTOR.
RINSE MOUTH.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
SPECIFIC TREATMENT (SEE ON THIS LABEL).
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
IN CASE OF FIRE: USE APPROPRIATE FOAM, CARBON DIOXIDE, DRY CHEMICAL POWDER
TO EXTINGUISH.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL
AND INTERNATIONAL REGULATIONS.
OTHER HAZARDS: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURE:
CHEMICAL NAME CAS NO. % OTHER
IDENTIFIERS
DIPROPYLENE GLYCOL MONOMETHYL ETHER 34590-94-8 50.13
OTHER COMPONENTS BELOW REPORTABLE LEVELS NO CAS
1,2-PROPYLENE GLYCOL 57-55-6 21.98
PINE OIL 8002-09-3 2.05
N-AMYL ACETATE 628-63-7 1.92
TERPENES AND TERPENOIDS, SWEET ORANGE-OIL 68647-72-3 1.87
ALPHA-TERPINEOL 98-55-5 1.56
TERPINEOL, ACETATE 8007-35-0 1.48
2-METHYLBUTYL ACETATE 624-41-9 1.03
P-MENTHA-6,8-DIEN-2-ONE, (R)-(-)- 6485-40-1 0.82
NAPHTHA (PETROLEUM), HEAVY ALKYLATE 64741-65-7 0.68
CITRAL 5392-40-5 0.64
CEDARWOOD OIL 8000-27-9 0.52
CITRONELLA OIL 8000-29-1 0.45
METHYL ANTHRANILATE 134-20-3 0.45
CORNMINT OIL 68917-18-0 0.43
HYDROCARBONS, TERPENE PROCESSING 68956-56-9 0.43
BY-PRODUCTS
METHYL SALICYLATE 119-36-8 0.39
EUCALYPTUS OIL 8000-48-4 0.33
ETHYL ACETATE 141-78-6 0.32
ETHYL BUTYRATE 105-54-4 0.27
BENZYL ACETATE 140-11-4 0.24
CEYLON CINNAMON OIL 8015-91-6 0.23
CINNAMALDEHYDE 104-55-2 0.16
LAVANDIN OIL 8022-15-9 0.16
VANILLIN 121-33-5 0.16
COUMARIN 91-64-5 0.14
ANETHOLE 104-46-1 0.14
| SECTION 4. FIRST-AID MEASURES | |
FIRST-AID MEASURES:
INHALATION:
TAKE PRECAUTIONS TO ENSURE YOUR OWN SAFETY BEFORE ATTEMPTING RESCUE (E.G.
WEAR APPROPRIATE PROTECTIVE EQUIPMENT). MOVE TO FRESH AIR. IF EXPERIENCING
RESPIRATORY SYMPTOMS (E.G. COUGHING, SHORTNESS OF BREATH, WHEEZING), CALL
A POISON CENTRE OR DOCTOR.
SKIN CONTACT:
AVOID DIRECT CONTACT. WEAR CHEMICAL PROTECTIVE CLOTHING IF NECESSARY.
IMMEDIATELY WASH GENTLY AND THOROUGHLY WITH LUKEWARM, GENTLY FLOWING WATER
AND MILD SOAP FOR 15-20 MINUTES.
EYE CONTACT:
AVOID DIRECT CONTACT. WEAR CHEMICAL PROTECTIVE GLOVES IF NECESSARY.
IMMEDIATELY RINSE THE CONTAMINATED EYE(S) WITH LUKEWARM, GENTLY FLOWING
WATER FOR 15-20 MINUTES, WHILE HOLDING THE EYELID(S) OPEN.
INGESTION:
RINSE MOUTH WITH WATER. IF VOMITING OCCURS NATURALLY, LIE ON YOUR SIDE IN
THE RECOVERY POSITION. RINSE MOUTH WITH WATER AGAIN.
FIRST-AID COMMENTS:
IF EXPOSED OR CONCERNED, GET MEDICAL ADVICE/ATTENTION.
MOST IMPORTANT SYMPTOMS AND EFFECTS, ACUTE AND DELAYED:
SYMPTOMS INCLUDE SLIGHT REDNESS AND SWELLING. REPEATED OR PROLONGED
EXPOSURE CAN IRRITATE THE SKIN. CONTACT CAN CAUSE PAIN, REDNESS, BURNS,
AND BLISTERING. PERMANENT SCARRING CAN RESULT.
IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT:
SPECIAL INSTRUCTIONS: NOT APPLICABLE.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NONE KNOWN.
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CAN IGNITE IF STRONGLY HEATED.
VERY TOXIC CARBON MONOXIDE, CARBON DIOXIDE.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
USE EXTREME CAUTION.
CHEMICAL PROTECTIVE CLOTHING (E.G. CHEMICAL SPLASH SUIT) AND POSITIVE
PRESSURE SCBA MAY BE NECESSARY.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES:
DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED PRODUCT UNLESS WEARING
APPROPRIATE PROTECTIVE EQUIPMENT. USE THE PERSONAL PROTECTIVE EQUIPMENT
RECOMMENDED IN SECTION 8 OF THIS SAFETY DATA SHEET.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW INTO ANY SEWER, ON THE GROUND OR INTO ANY WATERWAY. IF THE
SPILL IS INSIDE A BUILDING, PREVENT PRODUCT FROM ENTERING DRAINS,
VENTILATION SYSTEMS AND CONFINED AREAS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
REVIEW SECTION 7 (HANDLING) OF THIS SAFETY DATA SHEET BEFORE PROCEEDING
WITH CLEAN-UP. CONTAIN AND SOAK UP SPILL WITH ABSORBENT THAT DOES NOT REACT
WITH SPILLED PRODUCT. PLACE USED ABSORBENT INTO SUITABLE, COVERED, LABELLED
CONTAINERS FOR DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
AVOID BREATHING IN THIS PRODUCT. PREVENT ALL SKIN CONTACT. DO NOT GET IN
EYES, ON SKIN OR ON CLOTHING. DO NOT SWALLOW. AVOID RELEASE TO THE
ENVIRONMENT. IMMEDIATELY REPORT LEAKS, SPILLS OR FAILURES OF THE SAFETY
EQUIPMENT (E.G. VENTILATION SYSTEM). GET MEDICAL ADVICE/ATTENTION FOR ALL
EXPOSURES. SYMPTOMS CAN BE DELAYED.
CONDITIONS FOR SAFE STORAGE:
STORE IN AN AREA THAT IS:
WELL-VENTILATED, OUT OF DIRECT SUNLIGHT AND AWAY FROM HEAT AND IGNITION
SOURCES.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
CHEMICAL NAME ACGIH TLV(R*) OSHA PEL AIHA WEEL
TWA STEL TWA CEILING 8-HR TWA TWA
BENZYL ACETATE 10 PPM
N-AMYL ACETATE 50 PPM 100 PPM 525
MG/M3
2-METHYLBUTYL ACETATE 50 PPM 100 PPM
CITRAL 5 PPM
ETHYL ACETATE 400 PPM 1400
MG/M3
VANILLIN 10
MG/M3
1,2-PROPYLENE GLYCOL 10
MG/M3
DIPROPYLENE GLYCOL 100 PPM 150 PPM 600
MONOMETHYL ETHER MG/M3
ACGIH(R*) = AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS.
OSHA = US OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION.
TWA = TIME-WEIGHTED AVERAGE.
STEL = SHORT-TERM EXPOSURE LIMIT.
PEL = PERMISSIBLE EXPOSURE LIMITS.
APPROPRIATE ENGINEERING CONTROLS: GENERAL VENTILATION IS USUALLY ADEQUATE.
INDIVIDUAL PROTECTION MEASURES:
EYE/FACE PROTECTION:
WEAR CHEMICAL SAFETY GOGGLES AND FACE SHIELD WHEN CONTACT IS POSSIBLE.
SKIN PROTECTION:
WEAR CHEMICAL PROTECTIVE CLOTHING E.G. GLOVES, APRONS, BOOTS.
RESPIRATORY PROTECTION:
NOT USUALLY REQUIRED WHEN WORKING WITH SMALL QUANTITIES.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: LIQUID.
PARTICLE SIZE: NOT APPLICABLE
ODOUR: FRAGRANT
ODOUR THRESHOLD: NOT AVAILABLE
PH: NOT APPLICABLE
MELTING POINT/FREEZING POINT:
NOT AVAILABLE (MELTING); NOT AVAILABLE (FREEZING)
INITIAL BOILING POINT/RANGE: NOT AVAILABLE
FLASH POINT: 63 DEG. C (145 DEG. F)
EVAPORATION RATE: NOT AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMIT:
NOT AVAILABLE (UPPER)
NOT AVAILABLE (LOWER)
VAPOUR PRESSURE: NOT AVAILABLE
VAPOUR DENSITY (AIR = 1): NOT AVAILABLE
RELATIVE DENSITY (WATER = 1): NOT AVAILABLE
SOLUBILITY:
NOT AVAILABLE IN WATER
NOT AVAILABLE (IN OTHER LIQUIDS)
PARTITION COEFFICIENT, N-OCTANOL/WATER (LOG KOW): NOT AVAILABLE
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE
DECOMPOSITION TEMPERATURE: NOT AVAILABLE
VISCOSITY:
NOT AVAILABLE (KINEMATIC)
NOT AVAILABLE (DYNAMIC)
OTHER INFORMATION:
PHYSICAL STATE: LIQUID
MOLECULAR FORMULA: NOT APPLICABLE
MOLECULAR WEIGHT: NOT APPLICABLE
BULK DENSITY: NOT AVAILABLE
SURFACE TENSION: NOT AVAILABLE
CRITICAL TEMPERATURE: NOT AVAILABLE
ELECTRICAL CONDUCTIVITY: NOT AVAILABLE
VAPOUR PRESSURE AT 50 DEG C: NOT AVAILABLE
SATURATED VAPOUR CONCENTRATION: NOT AVAILABLE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NONE KNOWN.
CHEMICAL STABILITY: NORMALLY STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE KNOWN.
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBLE MATERIALS: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN CONTACT; EYE CONTACT.
ACUTE TOXICITY:
CHEMICAL NAME LC50 LD50 (ORAL) LD50 (DERMAL)
BENZYL ACETATE 830 MG/KG (MOUSE) >5000 MG/KG (RABBIT)
COUMARIN 293 MG/KG (RAT)
CITRAL 4950 MG/KG (RAT) >2000 MG/KG (RAT)
METHYL ANTHRANILATE 2910 MG/KG (RAT) 5000 MG/KG (RABBIT)
ETHYL ACETATE 16000 MG/L 5600 MG/M3 (RAT)
(RAT) (2-HOUR EXPOSURE)
ETHYL BUTYRATE 13050 MG/KG (RAT)
CINNAMALDEHYDE 3400 MG/KG (RAT) >1200 MG/KG (RAT)
VANILLIN 1580 MG/KG (RAT)
1,2-PROPYLENE GLYCOL 22000 MG/KG 20800 MG/KG (RABBIT)
(MOUSE)
DIPROPYLENE GLYCOL 5135 MG/KG 9500 MG/KG
MONOMETHYL ETHER
LC50: NO INFORMATION WAS LOCATED.
LD50 (ORAL): NO INFORMATION WAS LOCATED.
LD50 (DERMAL): NO INFORMATION WAS LOCATED.
SKIN CORROSION/IRRITATION: NO INFORMATION WAS LOCATED.
SERIOUS EYE DAMAGE/IRRITATION: NO INFORMATION WAS LOCATED.
STOT (SPECIFIC TARGET ORGAN TOXICITY) - SINGLE EXPOSURE:
INHALATION: NO INFORMATION WAS LOCATED.
SKIN ABSORPTION: NO INFORMATION WAS LOCATED.
INGESTION: NO INFORMATION WAS LOCATED.
ASPIRATION HAZARD: NO INFORMATION WAS LOCATED.
STOT (SPECIFIC TARGET ORGAN TOXICITY) - REPEATED EXPOSURE:
NO INFORMATION WAS LOCATED.
RESPIRATORY AND/OR SKIN SENSITIZATION:
NO INFORMATION WAS LOCATED FOR RESPIRATORY SENSITIZATION. MAY CAUSE AN
ALLERGIC REACTION (SKIN SENSITIZATION) BASED ON LIMITED EVIDENCE.
CARCINOGENICITY: NO INFORMATION WAS LOCATED.
REPRODUCTIVE TOXICITY:
DEVELOPMENT OF OFFSPRING: NO INFORMATION WAS LOCATED.
SEXUAL FUNCTION AND FERTILITY: NO INFORMATION WAS LOCATED.
EFFECTS ON OR VIA LACTATION: NO INFORMATION WAS LOCATED.
GERM CELL MUTAGENICITY: NO INFORMATION WAS LOCATED.
INTERACTIVE EFFECTS: NO INFORMATION WAS LOCATED.
| SECTION 12. ECOLOGICAL INFORMATION | |
ENVIRONMENTAL INFORMATION WAS NOT LOCATED.
TOXICITY: NO INFORMATION WAS LOCATED.
ACUTE AQUATIC TOXICITY:
CHEMICAL NAME LC50 FISH EC50 ERC50 AQUATIC ERC50
CRUSTACEA PLANTS ALGAE
COUMARIN 32-100 MG/L
(96-HOUR)
N-AMYL ACETATE 65 MG/L
(96-HOUR)
METHYL ANTHRANILATE 7.98-10.51
MG/L (LEPOMIS
MACROCHIRUS
(BLUEGILL);
96-HOUR)
ETHYL ACETATE 200.32-225.42
MG/L (48-HOUR)
VANILLIN 53-61.3 MG/L
(PIMEPHALES
PROMELAS
(FATHEAD
MINNOW);
96-HOUR)
PERSISTENCE AND DEGRADABILITY: NO INFORMATION WAS LOCATED.
BIOACCUMULATIVE POTENTIAL: NO INFORMATION WAS LOCATED.
MOBILITY IN SOIL: NO INFORMATION WAS LOCATED.
OTHER ADVERSE EFFECTS: THERE IS NO INFORMATION AVAILABLE.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
STORE PRODUCT FOR DISPOSAL AS DESCRIBED UNDER STORAGE IN SECTION 7 OF THIS
SAFETY DATA SHEET.
| SECTION 14. TRANSPORT INFORMATION | |
NOT REGULATED UNDER CANADIAN TDG REGULATIONS. NOT REGULATED UNDER US DOT
REGULATIONS.
SPECIAL PRECAUTIONS FOR USER: NOT APPLICABLE
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE
| SECTION 15. REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS: NONE KNOWN.
USA:
ADDITIONAL USA REGULATORY LISTS:
CERCLA. (2-METHYLBUTYL ACETATE). (ETHYL ACETATE). (ETHYL BUTYRATE).
(N-AMYL ACETATE). (PINENE)
MASSACHUSETTS RIGHT TO KNOW. (DIPROPYLENE GLYCOL MONOMETHYL ETHER).
(ETHYL ACETATE). (ETHYL BUTYRATE). (N-AMYL ACETATE). (PINENE)
NEW JERSEY RIGHT TO KNOW. (DIPROPYLENE GLYCOL MONOMETHYL ETHER).
(PINE OIL). (BENZYL ACETATE). (ETHYL ACETATE). (ETHYL BUTYRATE).
(N-AMYL ACETATE). (PINENE)
PENNSYLVANIA RIGHT TO KNOW. (DIPROPYLENE GLYCOL MONOMETHYL ETHER).
(ETHYL ACETATE). (ETHYL BUTYRATE). (METHYL SALICYLATE). (N-AMYL ACETATE).
(PINENE)
RHODE ISLAND RIGHT TO KNOW. (ETHYL ACETATE). (N-AMYL ACETATE)
| SECTION 16. OTHER INFORMATION | |
SDS PREPARED BY: WAYNE HEGSTROM
PHONE NO.: 405 682 2541
DATE OF PREPARATION: APRIL 07, 2015
REVISION INDICATORS: NOT APPLICABLE.
CREATED USING: CANWRITE(TM)