| Common Name: | FIRE D ONE SHOT FOGGER |
| Manufacturer: | BIG D INDUSTRIES |
| SDS Revision Date: | 7/10/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 4KN49, 659G61 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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BIG D(R*)
SAFETY DATA SHEET
BIG D FIRE D ONE SHOT FOGGER
| SECTION 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: BIG D FIRE D ONE SHOT FOGGER
OTHER MEANS OF IDENTIFICATION: 202
OTHER IDENTIFICATION: FIRE D ONE SHOT FOGGER
PRODUCT FAMILY: AEROSOL
RECOMMENDED USE: AIR FRESHENER.
RESTRICTIONS ON USE: NONE KNOWN.
MANUFACTURER:
BIG D INDUSTRIES, INC.
5620 SW 29TH ST
OKLAHOMA CITY, OK, 73179
405 682 2541
BIGDIND.COM
SUPPLIER:
BIG D INDUSTRIES, INC.
5620 SW 29TH ST
OKLAHOMA CITY, OK, 73179
405 682 2541
BIGDIND.COM
EMERGENCY PHONE NO.: BIG D INDUSTRIES, 800 535 5053, 24HR (INFOTRAC)
SDS NO.: 0226
DATE OF PREPARATION: JULY 10, 2014
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
FLAMMABLE AEROSOL - CATEGORY 1; SERIOUS EYE DAMAGE/EYE IRRITATION -
CATEGORY 2A; SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - CATEGORY 3;
AQUATIC HAZARD (ACUTE) - CATEGORY 2; AQUATIC HAZARD (CHRONIC) - CATEGORY 2
GHS LABEL ELEMENTS:
FLAME
EXCLAMATION MARK
ENVIRONMENT
SIGNAL WORD: DANGER
H222: EXTREMELY FLAMMABLE AEROSOL.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H402: HARMFUL TO AQUATIC LIFE.
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
P210: KEEP AWAY FROM SPARKS AND OPEN FLAMES.
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P251:
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P261: AVOID BREATHING GAS.
P264: WASH HANDS AND SKIN THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280: WEAR EYE PROTECTION/FACE PROTECTION.
P273: AVOID RELEASE TO THE ENVIRONMENT.
OTHER HAZARDS: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURE:
CHEMICAL NAME CAS NO. % OTHER IDENTIFIERS
ACETONE 67-64-1 60-80
N-BUTANE 106-97-8 10-20
PROPANE 74-98-6 10-20
OTHER COMPONENTS BELOW NO CAS 2.5-10
REPORTABLE LEVELS
| SECTION 4. FIRST-AID MEASURES | |
FIRST-AID MEASURES:
INHALATION:
MOVE TO FRESH AIR. CALL A POISON CENTRE OR DOCTOR IF YOU FEEL UNWELL OR ARE
CONCERNED.
SKIN CONTACT:
WASH GENTLY AND THOROUGHLY WITH LUKEWARM, GENTLY FLOWING WATER AND MILD
SOAP FOR 5 MINUTES. IF SKIN IRRITATION OCCURS GET MEDICAL ADVICE/ATTENTION.
EYE CONTACT:
IMMEDIATELY RINSE THE CONTAMINATED EYE(S) WITH LUKEWARM, GENTLY FLOWING
WATER FOR 15-20 MINUTES, WHILE HOLDING THE EYELID(S) OPEN. REMOVE CONTACT
LENSES, IF PRESENT AND EASY TO DO. IF EYE IRRITATION PERSISTS, GET MEDICAL
ADVICE/ATTENTION.
INGESTION:
CALL A POISON CENTRE OR DOCTOR IF YOU FEEL UNWELL OR ARE CONCERNED.
FIRST-AID COMMENTS:
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL OR ARE CONCERNED.
MOST IMPORTANT SYMPTOMS AND EFFECTS, ACUTE AND DELAYED:
MAY CAUSE MODERATE TO SEVERE IRRITATION.
IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT:
SPECIAL INSTRUCTIONS: NOT APPLICABLE.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NONE KNOWN.
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CLOSED CONTAINERS MAY RUPTURE VIOLENTLY WHEN HEATED RELEASING CONTENTS.
IN A FIRE, THE FOLLOWING HAZARDOUS MATERIALS MAY BE GENERATED:
FLAMMABLE CHEMICALS; IRRITATING CHEMICALS; TOXIC CHEMICALS; VERY TOXIC
CARBON MONOXIDE, CARBON DIOXIDE.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FOR A MASSIVE FIRE, IMMEDIATELY EVACUATE THE AREA AND USE UNMANNED HOSE
HOLDER OR MONITOR NOZZLES.
FIRE-FIGHTERS MAY ENTER THE AREA IF POSITIVE PRESSURE SCBA AND FULL BUNKER
GEAR IS WORN.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES:
EVACUATE THE AREA IMMEDIATELY. ISOLATE THE HAZARD AREA. KEEP OUT
UNNECESSARY AND UNPROTECTED PERSONNEL. USE THE PERSONAL PROTECTIVE
EQUIPMENT RECOMMENDED IN SECTION 8 OF THIS SAFETY DATA SHEET. DO NOT TOUCH
DAMAGED CONTAINERS OR SPILLED PRODUCT UNLESS WEARING APPROPRIATE PROTECTIVE
EQUIPMENT.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW INTO ANY SEWER, ON THE GROUND OR INTO ANY WATERWAY. IT IS GOOD
PRACTICE TO PREVENT RELEASES INTO THE ENVIRONMENT.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
REVIEW SECTION 7 (HANDLING) OF THIS SAFETY DATA SHEET BEFORE PROCEEDING
WITH CLEAN-UP. VENTILATE THE AREA TO PREVENT THE GAS FROM ACCUMULATING,
ESPECIALLY IN CONFINED SPACES.
OTHER INFORMATION:
REPORT SPILLS TO LOCAL HEALTH, SAFETY AND ENVIRONMENTAL AUTHORITIES, AS
REQUIRED.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
DO NOT PUNCTURE OR INCINERATE CONTAINER EVEN WHEN EMPTY. DO NOT SPRAY ON AN
OPEN FLAME OR OTHER IGNITION SOURCE. DO NOT PIERCE OR BURN CONTAINER, EVEN
AFTER USE. PREVENT HEATING. DO NOT USE NEAR WELDING OPERATIONS OR OTHER
HIGH ENERGY SOURCES. ONLY USE WHERE THERE IS ADEQUATE VENTILATION. AVOID
BREATHING IN THIS PRODUCT. PREVENT SKIN CONTACT. DO NOT GET IN EYES. WASH
HANDS THOROUGHLY AFTER HANDLING THIS MATERIAL.
CONDITIONS FOR SAFE STORAGE:
RESTRICT ACCESS TO AUTHORIZED PERSONNEL ONLY. STORE IN AN AREA THAT IS:
TEMPERATURE-CONTROLLED, WELL-VENTILATED, OUT OF DIRECT SUNLIGHT AND AWAY
FROM HEAT AND IGNITION SOURCES.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
CHEMICAL NAME ACGIH TLV(R*) OSHA PEL AIHA WEEL
TWA STEL TWA CEILING 8-HR TWA TWA
ACETONE 500 PPM 750 PPM 1000
N-BUTANE 1000 PPM 800 PPM
PROPANE 1000 PPM 1000 PPM
APPROPRIATE ENGINEERING CONTROLS: GENERAL VENTILATION IS USUALLY ADEQUATE.
INDIVIDUAL PROTECTION MEASURES:
EYE/FACE PROTECTION:
WEAR CHEMICAL SAFETY GOGGLES AND FACE SHIELD WHEN CONTACT IS POSSIBLE.
SKIN PROTECTION:
WEAR CHEMICAL PROTECTIVE CLOTHING E.G. GLOVES, APRONS, BOOTS.
RESPIRATORY PROTECTION:
NOT NORMALLY REQUIRED IF PRODUCT IS USED AS DIRECTED.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: CLEAR GAS.
ODOUR: NOT AVAILABLE
ODOUR THRESHOLD: NOT AVAILABLE
PH: NOT AVAILABLE
MELTING POINT/FREEZING POINT: NOT AVAILABLE (MELTING)
INITIAL BOILING POINT/RANGE: NOT AVAILABLE
FLASH POINT: <-156.00 DEG. F (-104.44 DEG. C) (ESTIMATED) (ACETONE)
EVAPORATION RATE: NOT AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMIT:
NOT AVAILABLE (UPPER)
NOT AVAILABLE (LOWER)
VAPOUR PRESSURE:
APPROX. 18009.40 MMHg (2401.25 KPA) AT 68 DEG. F (ESTIMATED)
VAPOUR DENSITY (AIR = 1): NOT AVAILABLE
RELATIVE DENSITY (WATER = 1):
APPROX. 0.701 (ESTIMATED) AT 20 DEG. C (68 DEG. F)
SOLUBILITY:
NOT AVAILABLE IN WATER
NOT AVAILABLE (IN OTHER LIQUIDS)
PARTITION COEFFICIENT, N-OCTANOL/WATER (LOG KOW):
2.36 AT 20 DEG. C (68 DEG. F) (ESTIMATED) (PROPANE)
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE
DECOMPOSITION TEMPERATURE: NOT AVAILABLE
VISCOSITY:
NOT AVAILABLE (KINEMATIC)
NOT AVAILABLE (DYNAMIC)
OTHER INFORMATION:
PHYSICAL STATE: GAS
OTHER PHYSICAL PROPERTY 3:
COLOR: NOT AVAILABLE
FORM: AEROSOL
PHYSICAL STATE: GAS
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NOT REACTIVE UNDER NORMAL CONDITIONS OF USE.
CHEMICAL STABILITY: NORMALLY STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
NONE EXPECTED UNDER NORMAL CONDITIONS OF STORAGE AND USE.
CONDITIONS TO AVOID:
HIGH TEMPERATURES. TEMPERATURES ABOVE 122.0 DEG. F (50.0 DEG. C)
INCOMPATIBLE MATERIALS:
NONE KNOWN.
NOT CORROSIVE TO METALS.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION PRESENTED BELOW IS FOR THE ENTIRE PRODUCT, UNLESS OTHERWISE
SPECIFIED.
LIKELY ROUTES OF EXPOSURE:
INGESTION; INHALATION; SKIN CONTACT; EYE CONTACT.
ACUTE TOXICITY:
CHEMICAL NAME LC50 LD50 (ORAL) LD50 (DERMAL)
ACETONE 76 MG/KG (MOUSE) 5800 MG/KG (RAT) 20000 MG/KG
(4-HOUR EXPOSURE) (RABBIT)
(GAS)
N-BUTANE 680 MG/L (MOUSE)
(2-HOUR EXPOSURE)
PROPANE 658 MG/L (RAT)
(4-HOUR EXPOSURE)
SKIN CORROSION/IRRITATION:
HUMAN EXPERIENCE AND ANIMAL TESTS SHOW NO OR VERY MILD IRRITATION.
SERIOUS EYE DAMAGE/IRRITATION:
HUMAN EXPERIENCE SHOWS SERIOUS EYE IRRITATION.
STOT (SPECIFIC TARGET ORGAN TOXICITY) - SINGLE EXPOSURE:
INHALATION:
MAY BE HARMFUL BASED ON INFORMATION FOR CLOSELY RELATED MATERIALS.
SKIN ABSORPTION: NO INFORMATION WAS LOCATED.
INGESTION: NOT A RELEVANT ROUTE OF EXPOSURE (GAS).
ASPIRATION HAZARD: NOT KNOWN TO BE AN ASPIRATION HAZARD.
STOT (SPECIFIC TARGET ORGAN TOXICITY) - REPEATED EXPOSURE:
NOT HARMFUL BASED ON INFORMATION FOR CLOSELY RELATED CHEMICALS.
RESPIRATORY AND/OR SKIN SENSITIZATION:
NOT KNOWN TO BE A RESPIRATORY SENSITIZER. NOT KNOWN TO BE A SKIN
SENSITIZER.
CARCINOGENICITY:
CHEMICAL NAME IARC ACGIH(R*) NTP OSHA
ACETONE A4
NOT KNOWN TO CAUSE CANCER.
REPRODUCTIVE TOXICITY:
DEVELOPMENT OF OFFSPRING: NOT KNOWN TO HARM THE UNBORN CHILD.
SEXUAL FUNCTION AND FERTILITY:
NOT KNOWN TO CAUSE EFFECTS ON SEXUAL FUNCTION OR FERTILITY.
EFFECTS ON OR VIA LACTATION:
NOT KNOWN TO CAUSE EFFECTS ON OR VIA LACTATION.
GERM CELL MUTAGENICITY: NOT MUTAGENIC.
INTERACTIVE EFFECTS: NO INFORMATION WAS LOCATED.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY: HARMFUL, WITH LONG LASTING EFFECTS TO AQUATIC LIFE.
ACUTE AQUATIC TOXICITY:
CHEMICAL NAME LC50 FISH EC50 CRUSTACEA ERC50 AQUATIC ERC50
PLANTS ALGAE
ACETONE 4740-6330 MG/L 21.6-23.9 MG/L
(ONCORHYNCHUS (DAPHNIA MAGNA
MYKISS (RAINBOW (WATER FLEA);
TROUT); 96-HOUR; 48-HOUR;
FRESH WATER) FRESH WATER)
PERSISTENCE AND DEGRADABILITY: NO INFORMATION WAS LOCATED.
BIOACCUMULATIVE POTENTIAL:
THIS PRODUCT OR ITS DEGRADATION PRODUCTS ARE EXPECTED TO BIOACCUMULATE.
MOBILITY IN SOIL: STUDIES ARE NOT AVAILABLE.
OTHER ADVERSE EFFECTS: THERE IS NO INFORMATION AVAILABLE.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THIS PRODUCT AND ITS CONTAINER MUST BE DISPOSED OF AS HAZARDOUS WASTE.
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND OR INTO ANY BODY OF WATER. THE
REQUIRED HAZARD EVALUATION OF THE WASTE AND COMPLIANCE WITH THE APPLICABLE
HAZARDOUS WASTE LAWS ARE THE RESPONSIBILITY OF THE USER.
| SECTION 14. TRANSPORT INFORMATION | |
REGULATION UN NO. PROPER SHIPPING TRANSPORT HAZARD PACKING
NAME CLASS(ES) GROUP
US DOT 1950 AEROSOLS, FLAMMABLE 2.1
IATA (AIR) 1950 AEROSOLS, FLAMMABLE 2.1
IMO (MARINE) 1950 AEROSOLS, MARINE 2
POLLUTANT
SPECIAL PRECAUTIONS FOR USER:
PLEASE NOTE: THIS MATERIAL IS CLASSIFIED AS A MARINE POLLUTANT PER IMDG
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE
EMERGENCY RESPONSE GUIDE NO.: 10L
OTHER INFORMATION:
DOT:
THIS PRODUCT MEETS THE EXCEPTION REQUIREMENTS OF SECTION 173.306 AS A
LIMITED QUANTITY AND MAY BE SHIPPED AS A LIMITED QUANTITY.
| SECTION 15. REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS:
CANADA:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CONTROLLED PRODUCTS REGULATIONS AND THE SDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
DOMESTIC SUBSTANCES LIST (DSL) / NON-DOMESTIC SUBSTANCES LIST (NDSL):
ALL INGREDIENTS ARE LISTED ON THE DSL OR ARE NOT REQUIRED TO BE LISTED.
USA:
ADDITIONAL USA REGULATORY LISTS:
CERCLA. (ACETONE)
US FEDERAL. (ACETONE)
NEW JERSEY RIGHT TO KNOW. (PROPANE). (N-BUTANE)
PENNSYLVANIA RIGHT TO KNOW. (ACETONE). (N-BUTANE). (PROPANE)
| SECTION 16. OTHER INFORMATION | |
NFPA RATING:
HEALTH 1
FLAMMABILITY 3
INSTABILITY 0
SDS PREPARED BY: WAYNE HEGSTROM
PHONE NO.: 405 682 2541
CREATED USING: CANWRITE(TM)