| Common Name: | TARN-X TARNISH REMOVER |
| Manufacturer: | JELMAR |
| SDS Revision Date: | 10/27/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 4LEZ5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
JELMAR
MAKERS OF CLR(R*) TARN-X(R*)
SAFETY DATA SHEET
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: TARN-X(R*) TARNISH REMOVER
RESTRICTIONS ON USE:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, ACIDS, BASES, AND BLEACH. DO
NOT USE ON STAINLESS STEEL, CHROME, PEWTER, ALUMINUM, BRASS, ZINC, MARBLE,
STEEL KNIVES, ARTIFICIALLY OXIDIZED SILVER, LACQUERED SURFACES, PEARLS,
OPALS OR POROUS STONES. AVOID SPILLING ON LAMINATES, COUNTERTOPS,
FORMICA(R*), OR SYNTHETIC SURFACES WHICH MAY BE AFFECTED; CLEAN
SPILL IMMEDIATELY.
PRODUCT USE:
AQUEOUS ACIDIC TARNISH REMOVER FOR REMOVAL OF ACCUMULATED TARNISH ON
STERLING SILVER, SILVER PLATE, COPPER AND JEWELRY
RETAIL PACKAGES: [12 FL. OZ. (354.8 ML); 18 FL. OZ. (532.3 ML]
MANUFACTURER: JELMAR, LLC
ADDRESS:
5550 W. TOUHY AVE.
SKOKIE, IL 60077
USA
1(847) 675-8400
EMERGENCY PHONE NUMBER:
1(800) 323-5497 (USA) 8:30 A.M. - 4:30 P.M. CST MONDAY - FRIDAY
EMERGENCY 24-HOUR CONTACT:
CHEMTREC: 1(800) 424-9300
| SECTION 2 - HAZARDS IDENTIFICATION | |
COMPLIES WITH 29 CFR 1900.1200 DATED MAY 2012
HEALTH HAZARD
EXCLAMATION MARK
WARNING
ACUTE ORAL TOXICITY (CATEGORY 4)
ACUTE EYE IRRITATION (CATEGORY 2B)
ACUTE DERMAL IRRITATION (CATEGORY 3)
CARCINOGENITY (CATEGORY 2)
REPRODUCTIVE TOXICITY (CATEGORY 2)
HAZARD NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER INFORMATION: NO INFORMATION AVAILABLE
DO NOT INGEST
DO NOT GET IN EYES, ON SKIN OR CLOTHING.
DO NOT MIX WITH BLEACH OR OTHER HOUSEHOLD CHEMICALS HARMFUL; FUMES
MAY RESULT.
DO NOT BREATHE VAPOR OR MIST. USE IN WELL VENTILATED AREAS.
KEEP CONTAINER CLOSED WHEN NOT IN USE.
KEEP OUT OF REACH OF CHILDREN
HAZARD STATEMENT(S):
HARMFUL IF SWALLOWED
CAUSES EYE IRRITATION
MAY CAUSE MILD SKIN IRRITATION
SUSPECTED OF CAUSING CANCER
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
PRECAUTIONARY STATEMENT (S):
DO NOT USE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
USE IN WELL VENTILATED AREA.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WASH SKIN THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
AVOID RELEASE TO THE ENVIRONMENT.
WEAR PROTECTIVE GLOVES.
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
RINSE MOUTH.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND SHOES; WASH BEFORE REUSE.
STORE LOCKED UP.
DISPOSE OF CONTENTS/ CONTAINER TO AN APPROVED WASTE DISPOSAL FACILITY.
WEAR PROTECTIVE GLOVES.
| SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENT CAS# OSHA HAZARD % BY WEIGHT
1. THIOUREA 62-56-6 YES 4.00-7.00
2. SULFAMIC ACID 5329-14-6 YES 2.00-5.00
THE EXACT PERCENTAGES (CONCENTRATION) OF MIXTURE HAS BEEN WITHHELD AS
A TRADE SECRET IN ACCORDANCE TO PARAGRAPH (I) OF SUBSECTION 1910.1200.
| SECTION 4 - FIRST AID MEASURES | |
EYE CONTACT:
IN CASE OF EYE CONTACT, IMMEDIATELY RINSE EYE THOROUGHLY WITH PLENTY OF
WATER. REMOVE CONTACT LENSES, AND CONTINUE RINSING FOR AT LEAST 15 MINUTES.
IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
SKIN CONTACT:
CAN BE IRRITATING TO SKIN, PROLONGED CONTACT CAN BE MORE SEVERE, NO ADVERSE
EFFECTS DURING NORMAL USAGE. IN CASE OF SKIN CONTACT, RINSE AREA FOR AT
LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOES, WASH THOROUGHLY
BEFORE REUSE. IF IRRITATION PERSISTS GET MEDICAL ATTENTION.
INHALATION:
NOT A SIGNIFICANT ROUTE OF EXPOSURE. REMOVE TO FRESH AIR. IF BREATHING IS
DIFFICULT, GET MEDICAL ATTENTION IMMEDIATELY.
INGESTION:
DO NOT INDUCE VOMITING. IF FULLY CONSCIOUS, DRINK 16 OUNCES OF WATER.
CALL A PHYSCIAN OR POISON CONTROL CENTER IMMEDIATELY. NEVER GIVE AN
UNCONSCIOUS PERSON ANYTHING TO INGEST.
| SECTION 5 - FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
NOT FLAMMABLE. USE APPROPRIATE MEDIA FOR AREA. USE WATER SPRAY, DRY
CHEMICAL, ALCOHOL FOAM OR CARBON DIOXIDE.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON MONOXIDE NITROGEN OXIDES (NOX) AND SULFUR OXIDES. THERMAL
DECOMPOSITION CAN LEAD TO IRRITATING GASES AND VAPORS.
FIRE FIGHTING METHODS:
EVACUATE AREA OF PERSONNEL. WEAR PROTECTIVE NIOSH-APPROVED SELF-CONTAINED
BREATHING APPARATUS. REMAIN UPWIND OF FIRE TO AVOID HAZARDOUS VAPORS AND
DECOMPOSITION PRODUCTS. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
RUN-OFF OF LARGE QUANTITIES OF PRODUCT FROM FIRE CONTROL CAN CAUSE
POLLUTION. CONTACT APPROPRIATE AGENCIES.
FIRE AND EXPLOSION HAZARDS: NONE KNOWN
| SECTION 6 - ACCIDENTAL RELEASES MEASURES | |
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
AVOID CONTACT WITH SKIN AND EYES
SMALL SPILL:
NO SPECIAL CLEAN-UP PROCEDURE IS NECESSARY FOR SMALL (LESS THAN 1 GALLON)
SPILLS. FLUSH SPILL AREA WITH WATER. WEAR RUBBER GLOVES.
LARGE SPILL:
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8. ISOLATE AREA, AND DENY
ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL. DAM SPILL, AND ABSORB WITH
EARTH, SAND OR SIMILAR MATERIAL. PLACE IN NON-LEAKING CONTAINERS. DISPOSE
OF COLLECTED MATERIAL ACCORDING TO LOCAL, STATE, AND FEDERAL REGULATIONS.
FLUSH RESIDUE WITH LARGE AMOUNT OF WATER. DO NOT REUSE MOPS FROM CLEAN UP;
DISPOSE WITH COLLECTED MATERIAL. DO NOT DISCHARGE TO SEWERS AND SURFACE
WATERS. CONTACT LICENSED PROFESSIONAL WASTE DISPOSAL SERVICE.
| SECTION 7 - HANDLING AND STORAGE | |
HANDLING AND STORAGE:
AVOID CONTACT WITH EYES, SKIN OR CLOTHING. MAY BE HARMFUL IF SWALLOWED.
USE WITH ADEQUATE VENTILATION. AVOID BREATHING VAPORS OR MIST. DO NOT EAT,
DRINK, OR SMOKE IN WORK AREA. WASH HANDS THOROUGHLY AFTER USE. CONSUMER
SIZE CONTAINER (12 AND 18 FLUID OUNCES), SHOULD BE RINSED AND RECYCLED.
STORE IN COOL WELL-VENTILATED AREA AWAY FROM HEAT. STORE IN ORIGINAL
CONTAINER IN A SECURE AREA AWAY FROM CHILDREN AND PETS. KEEP CONTAINERS
TIGHTLY CLOSED. AVOID CONTACT WITH COMBUSTIBLE MATERIALS, WOOD, AND ORGANIC
MATERIALS. AVOID CONTACT WITH STRONG OXIDIZING AGENTS, ACIDS, BASES, AND
BLEACH.
DO NOT MIX WITH BLEACH, OR ANY OTHER PRODUCTS AS TOXIC FUMES MAY RESULT.
KEEP OUT OF REACH OF CHILDREN.
| SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
COMPONENT OSHA ACGIH
PEL STEL/C TWA STEL/C
1. THIOUREA N.E N.E. N.E. N.E.
2. SULFAMIC ACID N.E N.E. N.E. N.E.
VENTILATION REQUIREMENT:
AVOID PROLONGED BREATHING MISTS OR DUSTS OF THIS PRODUCT. USE WITH ADEQUATE
VENTILATION. DO NOT USE IN CLOSED OR CONFINED SPACES.
RESPIRATORY PROTECTION:
NONE REQUIRED DURING NORMAL HOUSEHOLD USE. EMERGENCY RESPONDERS SHOULD
WEAR SELF-CONTAINED BREATHING APPARATUS (SCBA) TO AVOID INHALATION OF
PRODUCT.
EYE PROTECTION:
NOT REQUIRED DURING NORMAL HOUSEHOLD USAGE. EMERGENCY RESPONDERS SHOULD
WEAR FULL EYE AND FACE PROTECTION.
SKIN PROTECTION:
RUBBER GLOVES WITH PROTECTIVE CUFF. EMERGENCY RESPONDERS SHOULD WEAR
IMPERMEABLE GLOVES.
OTHER PROTECTION:
EMERGENCY RESPONDERS SHOULD WEAR CHEMICAL TYPE (IMPERMEABLE) PROTECTIVE
CLOTHING AND FOOTWEAR WHERE DIRECT CONTACT WITH CHEMICALS IN THIS PRODUCT
IS POSSIBLE.
WORK/HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER AFTER USE OR HANDLING.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CRYSTAL CLEAR, WATER WHITE LIQUID
FLAMMABILITY: NOT FLAMMABLE
ODOR: SLIGHTLY ACIDIC
UPPER/LOWER FLAMMABILITY: N.A.
ODOR THRESHOLD: N.D.
VAPOR PRESSURE: N.D
PH: @ 20 DEG. C: 0.85-1.05
VAPOR DENSITY (MMHg): N.D.
MELTING POINT: N.D.
RELATIVE DENSITY @ 20 DEG. C: 1.029 - 1.039
FREEZING POINT: N.D
SOLUBILITY IN WATER: 100%
BOILING POINT: 103 DEG. C / 217 DEG. F
PARTITION COEFFICIENT; N-OCTANOL/WATER: N.D.
BOILING POINT RANGE: N.A.
FLASH POINT: NONE
AUTO IGNITION TEMPERATURE: N.A.
EVAPORATION RATE: N.D
DECOMPOSITION TEMPERATURE: N.A.
VISCOSITY: N.D.
| SECTION 10 - STABILITY AND REACTIVITY | |
REACTIVITY: N.A.
CHEMICAL STABILITY: STABLE UNDER NORMAL STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: N.D.
CONDITIONS TO AVOID: AVOID ELEVATED TEMPERATURES.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZERS, NITRIC ACID, CHLORINE, ACROLEIN, ACRYLALDEHYDE, STRONG
BASES, AND HYDROGEN PEROXIDE.
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY EMIT AMMONIA AND OXIDES OF SULFUR, NITROGEN, AND CARBON.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
ROUTES OF EXPOSURE: EYES, SKIN, INHALATION, INGESTION.
EYES:
IRRITANT
AVOID EYE CONTACT
EFFECTS MAY VARY DEPENDING ON LENGTH OF EXPOSURE, SOLUTION CONCENTRATION
SKIN: MILD IRRITANT. PROLONGED CONTACT MAY CAUSE DERMATITIS, AND ITCHING.
INHALATION: NO ADVERSE EFFECTS EXPECTED UNDER TYPICAL USE CONDITIONS.
INGESTION:
HARMFUL IF SWALLOWED. MAY CAUSE GASTROINTESTINAL IRRITATION WITH NAUSEA,
VOMITING AND DIARRHEA. MAY CAUSE BURNS TO THE DIGESTIVE TRACT.
REPRODUCTIVE TOXICITY:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE REPRODUCTIVE AND FETAL EFFECTS.
LABORATORY EXPERIMENTS HAVE RESULTED IN MUTAGENIC EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY: - SINGLE EXPOSURE N.D.
SPECIFIC ORGAN TOXICITY:
REPEATED DOSE - BLOOD, LIVER, BONE MARROW, THYROID, AND REPRODUCTIVE
SYSTEM. PROBABLE CARCINOGEN AND MUTAGEN. WASH HANDS THOROUGHLY AFTER USE.
LD50 ACUTE EYE IRRITATION: GHS TOXICITY CATEGORY 2B
LD50 ACUTE ORAL TOXICITY - RATS: GHS CATEGORY 4
LD50 ACUTE DERMAL IRRITATION - RABBITS: GHS CATEGORY 3
LD50 ACUTE DERMAL TOXICITY - RABBITTS: >5,000 MG/KG
LD50 ACUTE INHALATION TOXICITY - RATS: NOT TOXIC BY INHALATION.
THIS PRODUCT CONTAINS A COMPONENT THAT HAS BEEN REPORTED TO BE PROBABLY
CARCINOGENIC BASED ON ITS IARC, NTP, AND OSHA CLASSIFICATION.
| SECTION 12 - ECOLOGICAL INFORMATION | |
THIOUREA:
ECOTOXICITY:
TOXICITY TO FISH LC50 - DANIO RERIO (ZEBRA FISH): 10.000 MG/L - 96.0 H
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES
EC50 - DAPHNIA MAGNA (WATER FLEA): 5.6 - 18.0 MG/L - 48 H
TOXICITY TO ALGAE EC50 - DESMODESMUS SUBSPICATUS (GREEN ALGAE):
6.8 MG/L - 96 H
PERSISTENCE / DEGRADABILITY:
BIODEGRADABILITY BIOTIC/AEROBIC
RESULT: < 1 % - NOT READILY BIODEGRADABLE.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
MOBILITY IN SOIL: NO DATA AVAILABLE
SULFAMIC ACID:
ECOTOXICITY: NO DATA AVAILABLE
PERSISTENCE / DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
MOBILITY IN SOIL: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS:
AN ENVIRONMENTAL HAZARD CANNOT BE EXCLUDED IN THE EVENT OF UNPROFESSIONAL
HANDLING OR DISPOSAL.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
DISPOSAL METHOD:
RINSE EMPTY CONTAINERS AND RECYCLE. DISPOSE OF UNUSED PRODUCT IN A
PERMITTED HAZARDOUS WASTE MANAGEMENT FACILITY FOLLOWING ALL LOCAL,
STATE, AND FEDERAL REGULATIONS.
FOLLOW LABEL WARNINGS, SINCE CONTAINERS MAY RETAIN SOME RESIDE OF THE
PRODUCT.
PROCESSING, USE OR CONTAMINATION OF THIS PRODUCT MAY CHANGE THE WASTE
MANAGEMENT OPTIONS. IT IS THE RESPONSIBILITY OF THE WASTE GENERATOR TO
DETERMINE THE TOXICITY AND PHYSICAL PROPERTIES OF THE MATERIAL GENERATED
TO DETERMINE THE PROPER WASTE IDENTIFICATION AND DISPOSAL METHODS IN
COMPLIANCE WITH APPLICABLE REGULATIONS. STATE AND LOCAL DISPOSAL
REGULATIONS MAY DIFFER FROM FEDERAL DISPOSAL REGULATIONS.
| SECTION 14 - TRANSPORTATION INFORMATION | |
THE FOLLOWING TRANSPORTATION INFORMATION APPLIES ONLY TO 12 AND 18 FL.
OZ. BOTTLES:
UN NUMBER: UN2922
UN PROPER SHIPPING NAME:
CORROSIVE LIQUID, TOXIC, N.O.S. CONTAINS SULFAMIC ACID, THIOUREA
HAZARD CLASS: 8(6.1)
DOT (DEPARTMENT OF TRANSPORTATION PROPER SHIPPING NAME):
CORROSIVE LIQUID, TOXIC, N.O.S. CONTAINS SULFAMIC ACID, THIOUREA - LIMITED
QUANTITY
PACKING GROUP: III.
ENVIRONMENTAL HAZARD: MARINE - YES
REPORTABLE QUANTITY (RQ): 10# THIOUREA
TDG CLASSIFICATION: LIMITED QUANTITY
IMDG CLASSIFICATION:
LIMITED QUANTITY - TRANSPORT IN ACCORDANCE WITH 3.4.4.1.2 OF THE IMDG CODE
IATA CLASSIFICATION:
PASSENGER - NO; CARGO - YES; PACKAGING INSTRUCTIONS 85 (12, 18 FL. OZ.)
WHIMS (CANADA):
DIA, D1B, AND D2A. THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE
HAZARD CRITERIA OF THE CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE SDS
CONTAINS ALL THE INFORMATION REQUIRED BY CPR.
| SECTION 15 - REGULATORY INFORMATION | |
FEDERAL REGULATIONS:
TSCA INVENTORY STATUS:
ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY OR ARE
EXEMPT FROM TSCA INVENTORY REQUIREMENTS.
SARA TITTLE III SECTION 311/312 CATEGORY:
IMMEDIATE (ACUTE) HEALTH HAZARARD: YES
DELAYED (CHRONIC) HEALTH HAZARD: YES
FIRE HAZARD: NO
SUDDEN RELEASE OF PRESSURE: NO
REACTIVE HAZARD: NO
SARA SECTIONS 302/304/313/HAP: NO
INTERNATIONAL CHEMICAL INVENTORY STATUS:
EUROPEAN UNION (EINECS): YES
JAPAN (METI): YES
AUSTRALIA (ACIS): YES
KOREA (KECL): YES
CANADA (DSL): YES
CANADA (NDSL): NO
PHILIPPINES: YES
STATES RIGHT TO KNOW:
CALIFORNIA, NEW JERSEY, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS, AND
WISCONSIN. COMPLIES WITH LISTED STATES RIGHT TO KNOW ACTS.
THE FOLLOWING STATEMENT IS MADE IN ORDER TO COMPLY WITH THE CALIFORNIA
STATE DRINKING WATER ACT. CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS THIOUREA KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND/OR TO CAUSE BIRTH DEFECTS AND OTHER REPRODUCTIVE HARM.
| SECTION 16 - OTHER INFORMATION | |
HAZARDOUS WASTE NUMBER: D002
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
AVOID EXPOSURE TO EXCESS HEAT, AND PREVENT FROM FREEZING.
NFPA:
2
0
0
NONE
VOC (WT %): <0.06 (CALCULATED)
TARN-X(R*)TARNISH REMOVER CHEMICAL FATE INFORMATION:
28-DAY BIODEGRADATION.
THE MATTER IS BIODEGRADABLE: OECD 301D.
OTHER PRECAUTIONS: NONE REQUIRED.
SDS ABBREVIATIONS:
N. A.: NOT APPLICABLE
N. D.: NOT DETERMINED
N.E.: NOT ESTABLISHED
C: CEILING LIMIT
HAP: HAZARDOUS AIR POLLUTANT
VOC: VOLATILE ORGANIC COMPOUND
REVISION:
GHS FORMAT; ADDITIONAL INFORMATION. NEW LOGO. ADDITIONAL SECTION 14.
ALTHOUGH THE INFORMATION AND RECOMMENDATIONS SET FORTH HEREIN ARE PRESENTED
IN GOOD FAITH AND BELIEVED TO BE CORRECT AS OF THE DATE HEREOF, JELMAR
OFFERS NO REPRESENTATIONS AS TO THE COMPLETENESS OR ACCURACY THEREOF.
INFORMATION IS PROVIDED UPON THE CONDITION THAT THE PERSONS RECEIVING SAME
WILL MAKE THEIR OWN DETERMINATION AS TO ITS SUITABILITY FOR THEIR PURPOSES
PRIOR TO USE. IN NO EVENT WILL JELMAR BE RESPONSIBLE FOR DAMAGES OF ANY
NATURE WHATSOEVER RESULTING FROM USE OF OR RELIANCE UPON SAID INFORMATION.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF
MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE
ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH
INFORMATION HEREIN REFERS.
901017
DATE ISSUED: 27-OCTOBER-2017