| Common Name: | VENTILATION SMOKE TUBE |
| Manufacturer: | MINE SAFETY APPLIANCES |
| SDS Revision Date: | 5/29/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 4LP18, 6BU78 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MSA
THE SAFETY COMPANY
SAFETY DATA SHEET
ISSUE DATE: NO DATA AVAILABLE
REVISION DATE: 29-MAY-2015
VERSION: 1
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: VENTILATION SMOKE TUBE
OTHER MEANS OF IDENTIFICATION:
FORMULA: CH3COOH SORBED ON SILICA GEL, NH2CH2 CH2NH2 SORBED ON PUMICE
UN/ID NO.: UN1759
SYNONYMS:
P/N 458480, TUBE, VENTILATION SMOKE, PKG. OF 12
P/N 458481, VENTILATION SMOKE TUBE KIT
SDS011
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: VENTILATION FLOW PATTERNS
USES ADVISED AGAINST: NO INFORMATION AVAILABLE.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER ADDRESS:
MINE SAFETY APPLIANCES COMPANY
1000 CRANBERRY WOODS DRIVE
CRANBERRY TOWNSHIP, PA 16066
PHONE: (724) 776-8900
EMERGENCY TELEPHONE NUMBER:
CUSTOMER SERVICE:
(800) MSA-2222 (8:30 A.M. - 5:00 P.M., USA LOCAL TIME)
(800) 255-3924 (CHEM-TEL, INC.)
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
EMERGENCY OVERVIEW:
EACH FLEXIBLE TUBE CONTAINS TWO SEALED GLASS AMPOULES, ONE WHITE WITH
APPROXIMATELY 0.4 GMS ACETIC ACID SORBED ON SILICA GEL AND ONE GRAY / BLACK
WITH APPROXIMATELY 0.3 GMS ETHYLENEDIAMINE SORBED ON PUMICE. WHEN THE
AMPOULES ARE MANUALLY CRUSHED, ASPIRATED AIR FLOW CAUSES MIXING OF THE
RELEASED VAPORS WHICH REACT FORMING ETHYLENEDIAMINE ACETATE SMOKE. NO TLV
IS LISTED FOR ETHYLENEDIAMINE ACETATE; HOWEVER, AVOID BREATHING THE TUBE
EFFLUENT. TUBE EFFLUENT CONTAINS ETHYLENEDIAMINE ACETATE SMOKE AND MAY
CONTAIN RESIDUAL VAPORS OF ACETIC ACID AND ETHYLENEDIAMINE, EITHER OF
WHICH WILL CAUSE IRRITATION TO EYES, MUCOUS MEMBRANES AND SKIN.
OSHA REGULATORY STATUS:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
SKIN CORROSION/IRRITATION: CATEGORY 1 SUB-CATEGORY B
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
RESPIRATORY SENSITIZATION: CATEGORY 1
SKIN SENSITIZATION: CATEGORY 1
LABEL ELEMENTS:
EMERGENCY OVERVIEW:
DANGER:
HAZARD STATEMENTS:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED
MAY CAUSE AN ALLERGIC SKIN REACTION
HEALTH HAZARD
CORROSION
APPEARANCE:
ACETIC ACID / SILICA GEL
AMPOULE - WHITE GRANULES, VINEGAR ODOR.
ETHYLENEDIAMINE / PUMICE AMPOULE
GRAY TO BLACK GRANULES, AMMONIA ODOR.
PHYSICAL STATE: SOLID
ODOR:
ACETIC ACID: VINEGAR ODOR
ETHYLENEDIAMINE: AMMONIA ODOR
SMOKE:
PRECAUTIONARY STATEMENTS - PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE
PRECAUTIONARY STATEMENTS - RESPONSE:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
SPECIFIC TREATMENT (SEE SECTION 4)
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING IMMEDIATELY CALL A POISON CENTER
OR DOCTOR/PHYSICIAN
WASH CONTAMINATED CLOTHING BEFORE REUSE
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE
FOR BREATHING IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING
PRECAUTIONARY STATEMENTS - STORAGE: STORE LOCKED UP
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC):
OTHER INFORMATION:
UNKNOWN ACUTE TOXICITY:
75% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SYNONYMS:
P/N 458480, TUBE, VENTILATION SMOKE, PKG. OF 12
P/N 458481, VENTILATION SMOKE TUBE KIT.
EACH TUBE CONTAINS TWO (2) AMPOULES:
AMPOULE 1): ACETIC ACID SORBED ON SILICA GEL
CHEMICAL NAME CAS NO. WEIGHT-%
ACETIC ACID 64-19-7 20
SILICA GEL 63231-67-4 80
AMPOULE 2): 1,2 - DIAMINOETHANE (ETHYLENE DIAMINE) SORBED ON PUMICE
CHEMICAL NAME CAS NO. WEIGHT-%
ETHYLINEDIAMINE 107-15-3 40
PUMICE 1332-09-8 60
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
AS SMOKE PUFF GENERATION IS UNDER MANUAL CONTROL OF THE USER BY ACTUATION
OF A SQUEEZE BULB, OVEREXPOSURE IS UNLIKELY UNDER INTENDED CONDITIONS OF
USE. FIRST AID PROCEDURES FOLLOW SHOULD OVEREXPOSURE OCCUR.
EYE CONTACT:
REMOVE VICTIM FROM EXPOSURE. FLUSH EYES WITH WATER FOR 15 MINUTES HOLDING
EYES OPEN AND RAISING EYELIDS TO FLUSH UNDER LID AREAS. SEE A PHYSICIAN
IMMEDIATELY.
SKIN CONTACT: WASH SKIN WITH SOAP AND WATER.
INHALATION:
REMOVE VICTIM FROM EXPOSURE. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN.
IF BREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL
ATTENTION IMMEDIATELY IN BOTH CASES.
INGESTION:
IF TUBE CONTENTS ARE SOMEHOW INGESTED AND IF VICTIM IS CONSCIOUS, GIVE
TWO GLASSES OF WATER TO DILUTE CHEMICAL. GET MEDICAL ATTENTION IMMEDIATELY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
ACETIC ACID:
IRRITATION OF EYES, MUCOUS MEMBRANES, SKIN. FUMES MAY CAUSE EYE AND SKIN
IRRITATION. INGESTION OF 1 CM3 GLACIAL ACID PRODUCED PERFORATION OF THE
ESOPHAGUS.
ETHYLENEDIAMINE: IRRITATION OF EYE, MUCOUS MEMBRANES, SKIN.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED
NOTE TO PHYSICIANS: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
AMPOULES MAY RUPTURE AND EMIT TOXIC FUMES UNDER FIRE CONDITIONS.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NONE.
SENSITIVITY TO STATIC DISCHARGE: NONE.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
IF CONTENTS OF A TUBE ARE RELEASED, AVOID SKIN CONTACT WITH SPILLED
MATERIAL. LEAVE THE IMMEDIATE AREA IF SMOKE IS GENERATED UNTIL SMOKE
SUBSIDES. WEAR RUBBER GLOVES AND SPLASHPROOF GOGGLES.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
SEE SECTION 12 FOR ADDITIONAL ECOLOGICAL INFORMATION.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
FILL A BUCKET 3/4 FULL OF WATER. SWEEP UP SPILLED MATERIAL AND PLACE
SWEEPINGS IN BUCKET. EXAMINE THE TUBE TO BE SURE BOTH AMPOULES WITHIN
THE TUBE ARE CRUSHED. IF BOTH AMPOULES ARE CRUSHED, PLACE THE TUBE WITH
CONTENTS INTO THE BUCKET SO THAT THE TUBE IS IMMERSED. IF THE TUBE CONTAINS
AN UNBROKEN AMPOULE, CRUSH IT (WITHIN THE TUBE) AND IMMERSE THE TUBE AND
ITS CONTENTS IN THE BUCKET. IF AN UNBROKEN AMPOULE HAS BEEN RELEASED FROM
THE TUBE, REPLACE IT IN THE TUBE, CRUSH IT (WITHIN THE TUBE), AND IMMERSE
THE TUBE WITH CONTENTS IN THE BUCKET. IN ALL CASES LET THE TUBE SOAK
OVERNIGHT. DISPOSE THE MATERIAL IN THE BUCKET IN ACCORDANCE WITH LOCAL,
STATE, AND FEDERAL REGULATIONS.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING: WASH HANDS AFTER USING PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
STORE IN A COOL, DRY LOCATION PROTECTED FROM CRUSHING AND IMPACT FORCES.
INCOMPATIBLE MATERIALS:
ACIDS, BASES, OXIDIZERS, CARBON TETRACHLORIDE, AND OTHER CHLORINATED
ORGANIC COMPOUNDS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
ACETIC ACID STEL: 15 PPM TWA: 10 PPM IDLH: 50 PPM
64-19-7 TWA: 10 PPM TWA: 25 MG/M3 TWA: 10 PPM
(VACATED) TWA: 10 PPM TWA: 25 MG/M3
(VACATED) TWA: 25 MG/M3 STEL: 15 PPM
STEL: 37 MG/M3
ETHYLENEDIAMINE TWA: 10 PPM TWA: 10 PPM IDLH: 1000 PPM
107-15-3 S* TWA: 25 MG/M3 TWA: 10 PPM
(VACATED) TWA: 10 PPM TWA: 25 MG/M3
(VACATED) TWA: 25 MG/M3
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS: NOT APPLICABLE.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
PERSONAL PROTECTIVE EQUIPMENT:
DUE TO THE LIMITED AMOUNT OF CHEMICALS IN EACH TUBE AND THE SLOW RELEASE
RATE, USE OF PERSONAL PROTECTIVE EQUIPMENT IS NOT INDICATED UNDER
ANTICIPATED CONDITIONS OF USE. THE USER IS CAUTIONED TO AVOID BREATHING
THE TUBE EMISSIONS AS THEY MAY CAUSE IRRITATION TO EYES, MUCOUS MEMBRANES,
AND SKIN.
EYE/FACE PROTECTION:
NO SPECIAL TECHNICAL PROTECTIVE MEASURES ARE NECESSARY.
SKIN AND BODY PROTECTION:
NO SPECIAL TECHNICAL PROTECTIVE MEASURES ARE NECESSARY.
RESPIRATORY PROTECTION:
IF EXPOSURE LIMITS ARE EXCEEDED OR IRRITATION IS EXPERIENCED, NIOSH/MSHA
APPROVED RESPIRATORY PROTECTION SHOULD BE WORN. POSITIVE-PRESSURE SUPPLIED
AIR RESPIRATORS MAY BE REQUIRED FOR HIGH AIRBORNE CONTAMINANT
CONCENTRATIONS. RESPIRATORY PROTECTION MUST BE PROVIDED IN ACCORDANCE
WITH CURRENT LOCAL REGULATIONS.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
WORK PRACTICES:
THIS PRODUCT IS FOR USE IN DETERMINATION OF DIRECTION AND VELOCITY OF
VENTILATION AIR CURRENTS. AVOID BREATHING EMISSIONS FROM TUBE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: SOLID
APPEARANCE:
ACETIC ACID / SILICA GEL AMPOULE - WHITE GRANULES, VINEGAR ODOR.
ETHYLENEDIAMINE / PUMICE AMPOULE - GRAY TO BLACK GRANULES, AMMONIA ODOR.
ODOR:
ACETIC ACID: VINEGAR ODOR
ETHYLENEDIAMINE: AMMONIA ODOR
COLOR:
SILICA GEL: WHITE
PUMICE: GRAY TO BLACK
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES REMARKS
PH NO INFORMATION AVAILABLE THE FOLLOWING
DATA REPRESENTS
THE NATURE OF
THE COMPONENTS
THAT MAKE UP
THE GRANULES.
MELTING POINT/FREEZING POINT NO INFORMATION AVAILABLE
BOILING POINT / BOILING RANGE ACETIC ACID: 118 DEG. C
ETHYLENEDIAMINE:
117 DEG. C
FLASH POINT ACETIC ACID: 103 DEG. F
ETHYLENEDIAMINE: 93 DEG. F
EVAPORATION RATE NO INFORMATION AVAILABLE
FLAMMABILITY (SOLID, GAS) NO INFORMATION AVAILABLE
FLAMMABILITY LIMIT IN AIR:
UPPER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
LOWER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
VAPOR PRESSURE ACETIC ACID:
14.8 MMHg @ 25 DEG. C
ETHYLENEDIAMINE:
10.0 MMHg @ 20 DEG. C
VAPOR DENSITY NO INFORMATION AVAILABLE
WATER SOLUBILITY SOLUBLE (ACETIC ACID,
ETHYLENEDIAMINE)
SOLUBILITY IN OTHER SOLVENTS NO INFORMATION AVAILABLE
PARTITION COEFFICIENT NO INFORMATION AVAILABLE
AUTOIGNITION TEMPERATURE NO INFORMATION AVAILABLE
DECOMPOSITION TEMPERATURE NO INFORMATION AVAILABLE
KINEMATIC VISCOSITY NO INFORMATION AVAILABLE
DYNAMIC VISCOSITY NO INFORMATION AVAILABLE
EXPLOSIVE PROPERTIES ACETIC ACID:
LEL: 4%
UEL: 19.9%
ETHYLENEDIAMINE:
LEL: 2.6%
UEL: 14.4%
OXIDIZING PROPERTIES NO INFORMATION AVAILABLE
OTHER INFORMATION:
SOFTENING POINT NO INFORMATION AVAILABLE
MOLECULAR WEIGHT NO INFORMATION AVAILABLE
VOC CONTENT (%) NO INFORMATION AVAILABLE
DENSITY NO INFORMATION AVAILABLE
BULK DENSITY NO INFORMATION AVAILABLE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
COMPONENTS ARE SORBED ON INERT SOLIDS. TOTAL AMOUNT OF
COMBUSTIBLE/FLAMMABLE MATERIAL IS LESS THAN 1 GM PER TUBE. AMPOULES ARE
SEALED UNTIL TIME OF ACTUAL USE.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID:
AVOID ACIDS, BASES, OXIDIZERS, CARBON TETRACHLORIDE, AND OTHER CHLORINATED
ORGANIC COMPOUNDS.
INCOMPATIBLE MATERIALS:
ACIDS, BASES, OXIDIZERS, CARBON TETRACHLORIDE, AND OTHER CHLORINATED
ORGANIC COMPOUNDS.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN BASED ON INFORMATION SUPPLIED.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
PRIMARY ROUTES OF ENTRY:
INHALATION, EYES & SKIN CONTACT, SKIN ABSORPTION, INGESTION
INHALATION: NO DATA AVAILABLE.
EYE CONTACT: NO DATA AVAILABLE.
SKIN CONTACT: NO DATA AVAILABLE.
INGESTION: NO DATA AVAILABLE.
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50
ACETIC ACID =3310 MG/KG =1060 MG/KG =11.4 MG/L (RAT) 4 H
64-19-7 (RAT) (RABBIT)
ETHYLENE DIAMINE =637 MG/KG =560 MG/KG
107-15-3 (RAT) (RABBIT)
INFORMATION ON TOXICOLOGICAL EFFECTS:
SYMPTOMS:
ACETIC ACID:
IRRITATION OF EYES, MUCOUS MEMBRANES, SKIN. FUMES MAY CAUSE EYE AND SKIN
IRRITATION. INGESTION OF 1 CM3 GLACIAL ACID PRODUCED PERFORATION OF THE
ESOPHAGUS.
ETHYLENEDIAMINE: IRRITATION OF EYE, MUCOUS MEMBRANES, SKIN.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
SENSITIZATION: NO INFORMATION AVAILABLE.
GERM CELL MUTAGENICITY: SEE RTECS DATA FOR ACETIC ACID.
CARCINOGENICITY:
THIS PRODUCT DOES NOT CONTAIN ANY CARCINOGENS OR POTENTIAL CARCINOGENS
AS LISTED BY OSHA, IARC OR NTP.
REPRODUCTIVE TOXICITY: NO INFORMATION AVAILABLE.
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
TARGET ORGAN EFFECTS: EYES, NOSE, THROAT, SKIN, LIVER, KIDNEY.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
NUMERICAL MEASURES OF TOXICITY - PRODUCT INFORMATION:
UNKNOWN ACUTE TOXICITY:
75% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
75% OF THE MIXTURE CONSISTS OF COMPONENTS(S) OF UNKNOWN HAZARDS TO THE
AQUATIC ENVIRONMENT.
CHEMICAL NAME ALGAE/AQUATIC PLANTS FISH
ACETIC ACID 79:
64-19-7 96 H PIMEPHALES PROMELAS
MG/L LC50 STATIC
75:
96 H LEPOMIS MACROCHIRUS
MG/L LC50 STATIC
ETHYLENEDIAMINE 645: 98.6 - 131.6:
107-15-3 72 H PSEUDOKIRCHNERIELLA 96 H PIMEPHALES PROMELAS
SUBCAPITATA MG/L EC50 MG/L LC50 STATIC
151: 180 - 560:
96 H PSEUDOKIRCHNERIELLA 96 H POECILIA RETICULATA
SUBCAPITATA MG/L EC50 MG/L LC50 SEMI-STATIC
191 - 254:
96 H PIMEPHALES PROMELAS
MG/L LC50 FLOW-THROUGH
115.7:
96 H PIMEPHALES PROMELAS
MG/L LC50 SEMI-STATIC
CHEMICAL NAME TOXICITY TO MICROORGANISMS CRUSTACEA
ACETIC ACID EC50: 8.8 MG/L 15 MIN 65:
EC50: 8.8 MG/L 25 MIN 48 H DAPHNIA MAGNA
EC50: 8.8 MG/L 5 MIN MG/L EC50 STATIC
47:
24 H DAPHNIA MAGNA
MG/L EC50
ETHYLENEDIAMINE EC50: 20 MG/L 15 MIN 17:
EC50: 29 MG/L 17 H 48 H DAPHNIA MAGNA
MG/L EC50
PERSISTENCE AND DEGRADABILITY:
IF RELEASED TO WATER OR SOIL, ACETIC ACID WILL BIODEGRADE READILY.
EVAPORATION FROM DRY SURFACES IS LIKELY TO OCCUR. WHEN SPILLED ON SOIL,
THE LIQUID WILL SPREAD ON THE SURFACE AND PENETRATE INTO THE SOIL AT A
RATE DEPENDENT ON THE SOIL TYPE AND ITS WATER CONTENT. IF RELEASED TO
THE ATMOSPHERE, IT IS DEGRADED IN THE VAPOR-PHASE BY REACTION WITH
PHOTOCHEMICALLY PRODUCED HYDROXYL RADICALS (ESTIMATED TYPICAL HALF-LIFE
OF 26.7 DAYS). IT OCCURS IN ATMOSPHERIC PARTICULATE MATTER AND PHYSICAL
REMOVAL FROM AIR CAN OCCUR VIA WET AND DRY DEPOSITION. NATURAL WATERS WILL
NEUTRALIZE DILUTE SOLUTIONS TO ACETATE SALTS.
ON SOIL, ETHYLENEDIAMINE WILL LEACH AND VOLATILIZE. IN WATER, SUBSTANCE
WILL FORM ALKALINE SOLUTION AND WILL BIODEGRADE. BIOCONCENTRATION IS NOT
PREDICTED. IN AIR, SUBSTANCE WILL REACT WITH HYDROXYL RADICALS AND CARBON
DIOXIDE.
BIOLOGICAL OXYGEN DEMAND (BOD): 75% (THEOR.), 5 DAYS.
BIOACCUMULATION:
ACETIC ACID SHOWS NO POTENTIAL FOR BIOLOGICAL ACCUMULATION OR FOOD CHAIN
CONTAMINATION.
CHEMICAL NAME PARTITION COEFFICIENT
ACETIC ACID -0.31
64-19-7
ETHYLENE DIAMINE -1.221
107-15-3
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
DISPOSAL OF WASTES:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING: DO NOT REUSE CONTAINER.
CHEMICAL NAME CALIFORNIA HAZARDOUS WASTE STATUS
ACETIC ACID TOXIC
64-19-7 CORROSIVE
IGNITABLE
ETHYLENEDIAMINE TOXIC
107-15-3
| 14. TRANSPORT INFORMATION | |
NOTE:
THIS MATERIAL CAN BE SHIPPED UNDER LIMITED QUANTITY RULES IF SHIPPING LESS
THAN THE APPLICABLE LIMITED QUANTITY MAXIMUM. WHEN SHIPPING LIMITED
QUANTITY BY AIR, IATA PACKING INSTRUCTION Y845 APPLIES. HOWEVER, CHECK WITH
THE TRANSPORTER PRIOR TO SHIPPING FOR TRANSPORTER SPECIFIC RESTRICTIONS.
DOT: REGULATED
UN/ID NO.: UN1759
PROPER SHIPPING NAME:
CORROSIVE SOLIDS, N.O.S. (ACETIC ACID, ETHYLENEDIAMINE)
HAZARD CLASS: 8
PACKING GROUP: III
IATA:
MAY BE SHIPPED "LIMITED QUANTITY". WHEN SHIPPING BY AIR AND USING THE
LIMITED QUANTITY EXCEPTION. BOTH THE CORROSIVE LABEL AND THE AIR LIMITED
QUANTITY DIAMOND ARE REQUIRED. PACKING INSTRUCTION Y845. MAX QUANTITY PER
PACKAGE: 1 KG PER INNER PACKAGE, 5 KG NET QUANTITY PER PACKAGE.
CORROSION
IMDG: NOT REGULATED
RID: NOT REGULATED
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA: ALL INGREDIENTS ARE ON THE INVENTORY OR EXEMPT FROM LISTING
DSL/NDSL: ALL INGREDIENTS ARE ON THE INVENTORY OR EXEMPT FROM LISTING
EINECS/ELINCS: NOT EVALUATED
ENCS: NOT EVALUATED
IECSC: ALL INGREDIENTS ARE ON THE INVENTORY OR EXEMPT FROM LISTING
KECL: ALL INGREDIENTS ARE ON THE INVENTORY OR EXEMPT FROM LISTING
PICCS: ALL INGREDIENTS ARE ON THE INVENTORY OR EXEMPT FROM LISTING
AICS: ALL INGREDIENTS ARE ON THE INVENTORY OR EXEMPT FROM LISTING
LEGEND:
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
EINECS/ELINCS:
EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES/EUROPEAN LIST OF
NOTIFIED CHEMICAL SUBSTANCES
ENCS: JAPAN EXISTING AND NEW CHEMICAL SUBSTANCES
IECSC: CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES
KECL: KOREAN EXISTING AND EVALUATED CHEMICAL SUBSTANCES
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
AICS: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES
US FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: NO
FIRE HAZARD: NO
SUDDEN RELEASE OF PRESSURE HAZARD: NO
REACTIVE HAZARD: NO
CWA (CLEAN WATER ACT):
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES WHICH ARE REGULATED
POLLUTANTS PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40
CFR 122.42):
CHEMICAL NAME CWA - CWA - TOXIC CWA - CWA - HAZARDOUS
REPORTABLE POLLUTANTS PRIORITY SUBSTANCES
QUANTITIES POLLUTANTS
ACETIC ACID 5000 LB X
64-19-7
ETHYLENE DIAMINE 5000 LB X
107-15-3
CERCLA:
THIS MATERIAL, AS SUPPLIED, CONTAINS ONE OR MORE SUBSTANCES REGULATED AS
A HAZARDOUS SUBSTANCE UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302)
CHEMICAL NAME HAZARDOUS CERCLA/SARA REPORTABLE QUANTITY
SUBSTANCES RQS RQ (RQ)
ACETIC ACID 5000 LB RQ: 5000 LB FINAL RQ
64-19-7 RQ: 2270 KG FINAL RQ
ETHYLENE DIAMINE 5000 LB 5000 LB RQ: 5000 LB FINAL RQ
107-15-3 RQ: 2270 KG FINAL RQ
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY PROPOSITION 65 CHEMICALS
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
CHEMICAL NAME NEW JERSEY MASSACHUSETTS PENNSYLVANIA
ACETIC ACID X X X
64-19-7
ETHYLENE DIAMINE X X X
107-15-3
SILICA GEL X X
63231-67-4
U.S. EPA LABEL INFORMATION:
EPA PESTICIDE REGISTRATION NUMBER: NOT APPLICABLE
CANADA:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA
OF THE CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE SDS CONTAINS ALL THE
INFORMATION REQUIRED BY THE CPR.
WHMIS HAZARD CLASS: E - CORROSIVE MATERIAL
| 16. OTHER INFORMATION | |
REVISION DATE: 29-MAY-2015
REVISION NOTE: CONVERSION TO SDS
DISCLAIMER:
WARNING:
THIS IS A HAZARDOUS CHEMICAL PRODUCT. BY FOLLOWING THE DIRECTIONS AND
WARNINGS PROVIDED WITH THIS PRODUCT, THE HAZARDS ASSOCIATED WITH THE USE
OF THIS PRODUCT CAN BE GREATLY REDUCED BUT NEVER ENTIRELY ELIMINATED. MINE
SAFETY APPLIANCES COMPANY MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, WITH
RESPECT TO THIS PRODUCT AND EXPRESSLY DISCLAIMS THE WARRANTY OF
MERCHANTABILITY AND ANY WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE.
USERS ASSUME ALL RISKS IN HANDLING, USING OR STORING THIS PRODUCT.
PREPARED BY:
COMPREHENSIVE SAFETY COMPLIANCE, INC. (CSC)
OCCUPATIONAL HEALTH AND SAFETY CONSULTANT
(412) 826-5480
VERSION NO.: 1
APPROVAL DATE: 5/29/15
CONTACT:
MINE SAFETY APPLIANCES COMPANY
1000 CRANBERRY WOODS DRIVE
CRANBERRY TOWNSHIP, PA 16066
(724) 776-8900
SUPERSEDES MSDS DATED: 8/8/2013