| Common Name: | OXYGEN (0.0015-23.5), METHANE (0.0005-2.5%), CARBON MONOXIDE (0.001-1., 50018MSA |
| Manufacturer: | CALGAZ |
| SDS Revision Date: | 4/1/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 2TEY2, 4LP28, 6BU74 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
MSA
THE SAFETY COMPANY
OXYGEN (0.0015-23.5), METHANE (0.0005-2.5%), CARBON MONOXIDE (0.001-1.0%),
HYDROGEN SULFIDE (0.001-0.025%) IN NITROGEN BALANCE
SAFETY DATA SHEET
50018MSA
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY,
MARCH 26, 2012 / RULES AND REGULATIONS
DATE OF ISSUE: 07/09/2014
REVISION DATE: 04/01/2016
VERSION: 1.2
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
PRODUCT NAME:
OXYGEN (0.0015-23.5), METHANE (0.0005-2.5%), CARBON MONOXIDE (0.001-1.0%),
HYDROGEN SULFIDE (0.001-0.025%) IN NITROGEN BALANCE
MSA P/N:
711058, 711076, 804770, 813720, 814349, 814559, 10045035, 10048280,
10048788, 10048790,10048890, 10050744, 10125695, 10150595, 10150620
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: TEST GAS/CALIBRATION GAS.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER:
CALGAZ, DIVISON OF AIR LIQUIDE
821 CHESAPEAKE DRIVE
CAMBRIDGE, MD 21613
U.S. SUPPLIER:
MINE SAFETY APPLIANCES COMPANY
CRANBERRY TOWNSHIP
PENNSYLVANIA U.S.A. 16066
1-800-MSA-2222
WWW.MSANET.COM/PRISM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300
INTERNATIONALLY: 1-703-527-3887
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
COMPRESSED GAS: H280
REPR. 1A: H360
STOT RE 1: H372
2.2. LABEL ELEMENTS:
GHS-US LABELLING:
HAZARD PICTOGRAMS (GHS-US):
GHS04: GAS CYLINDER
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H360: (INHALATION)
H372:
CAUSES DAMAGE TO ORGANS (CNS) THROUGH PROLONGED OR REPEATED EXPOSURE
(INHALATION)
CGA-HG10: ASPHYXIATING EVEN WITH ADEQUATE OXYGEN
PRECAUTIONARY STATEMENTS (GHS-US):
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P260: DO NOT BREATHE GAS
P264: WASH THOROUGHLY AFTER HANDLING
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
P280: WEAR EYE PROTECTION, PROTECTIVE CLOTHING
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION
P314: GET MEDICAL ADVICE AND ATTENTION IF YOU FEEL UNWELL
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS
CGA-PG02:
PROTECT FROM SUNLIGHT WHEN AMBIENT TEMPERATURE EXCEEDS 52 DEG. C
(125 DEG. F)
CGA-PG05: USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING
CGA-PG06: CLOSE VALVE AFTER EACH USE AND WHEN EMPTY
CGA-PG10: USE ONLY WITH EQUIPMENT RATED FOR CYLINDER PRESSURE
CGA-PG14: APPROACH SUSPECTED LEAK AREA WITH CAUTION
CGA-PG21: OPEN VALVE SLOWLY
P403: STORE IN A WELL-VENTILATED PLACE
2.3. OTHER HAZARDS:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION: NONE.
2.4. UNKNOWN ACUTE TOXICITY (GHS-US): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
FULL TEXT OF H-PHRASES: SEE SECTION 16
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % GHS-US
CLASSIFICATION
NITROGEN (CAS NO): 7727-37-9 72.975 - 99.9965 COMPRESSED GAS,
H280
OXYGEN (CAS NO): 7782-44-7 0.0015 - 23.5 OX. GAS 1, H270
COMPRESSED GAS,
H280
METHANE (CAS NO): 74-82-8 0.0005 - 2.5 FLAM. GAS 1, H220
COMPRESSED GAS,
H280
CARBON MONOXIDE (CAS NO): 630-08-0 0.0005 - 1 FLAM. GAS 1, H220
COMPRESSED GAS,
H280
ACUTE TOX. 3
(INHALATION: GAS),
H331
REPR. 1A, H360
STOT RE 1, H372
HYDROGEN (CAS NO): 7783-06-4 0.001 - 0.025 FLAM. GAS 1, H220
SULFIDE
LIQUEFIED GAS,
H280
ACUTE TOX. 2
(INHALATION: GAS),
H330
STOT SE 3, H335
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES AFTER INHALATION:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT. IF YOU FEEL UNWELL, SEEK
MEDICAL ADVICE.
FIRST-AID MEASURES AFTER SKIN CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
FIRST-AID MEASURES AFTER EYE CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
FIRST-AID MEASURES AFTER INGESTION:
INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES AFTER INHALATION:
NOT EXPECTED TO PRESENT A SIGNIFICANT INHALATION HAZARD UNDER ANTICIPATED
CONDITIONS OF NORMAL USE.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
SYMPTOMS/INJURIES AFTER INGESTION:
INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
SYMPTOMS/INJURIES UPON INTRAVENOUS ADMINISTRATION: NOT KNOWN.
CHRONIC SYMPTOMS: ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE. IF BREATHING IS DIFFICULT, GIVE
OXYGEN. OBTAIN MEDICAL ATTENTION IF BREATHING DIFFICULTY PERSISTS.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
NON-FLAMMABLE GAS. USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER JET TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
EXPLOSION HAZARD:
HEAT MAY BUILD PRESSURE, RUPTURING CLOSED CONTAINERS, SPREADING FIRE AND
INCREASING RISK OF BURNS AND INJURIES.
REACTIVITY:
NO REACTIVITY HAZARD OTHER THAN THE EFFECTS DESCRIBED IN SUB-SECTIONS
BELOW.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL FIRE.
IN CASE OF FIRE:
EVACUATE AREA. FIGHT FIRE REMOTELY DUE TO THE RISK OF EXPLOSION. USE WATER
SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION. STANDARD PROTECTIVE CLOTHING AND EQUIPMENT
(E.G., SELF CONTAINED BREATHING APPARATUS) FOR FIRE FIGHTERS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
TRY TO STOP RELEASE. ENSURE ADEQUATE VENTILATION. PREVENT FROM ENTERING
SEWERS, BASEMENTS AND WORKPITS, OR ANY PLACE WHERE ITS ACCUMULATION CAN
BE DANGEROUS.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
WEAR PROTECTIVE EQUIPMENT CONSISTENT WITH THE SITE EMERGENCY PLAN.
EMERGENCY PROCEDURES:
ESCAPE THE DANGER AREA BY THE CLOSEST SAFE ROUTE. CLOSE DOORS AND WINDOWS
OF ADJACENT PREMISES. KEEP CONTAINERS CLOSED. MARK THE DANGER AREA. SEAL
OFF LOW-LYING AREAS. KEEP UPWIND.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
STANDARD PROTECTIVE CLOTHING AND EQUIPMENT (E.G., SELF CONTAINED BREATHING
APPARATUS) FOR FIRE FIGHTERS. EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: EVACUATE AND LIMIT ACCESS. VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS: STOP LEAK IF SAFE TO DO SO.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT: STOP LEAK IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
DISPOSE OF THIS MATERIAL AND ITS CONTAINER IN ACCORDANCE WITH LOCAL
REGULATIONS.
6.4. REFERENCE TO OTHER SECTIONS: SEE ALSO SECTIONS 8 AND 13.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. USE EQUIPMENT RATED FOR CYLINDER
PRESSURE.
PRECAUTIONS FOR SAFE HANDLING:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
HYGIENE MEASURES: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES: NONE KNOWN.
STORAGE CONDITIONS:
DO NOT EXPOSE TO TEMPERATURES EXCEEDING 52 DEG. C (125 DEG. F). KEEP
CONTAINER CLOSED WHEN NOT IN USE. PROTECT CYLINDER FROM PHYSICAL DAMAGE.
STORE IN WELL VENTILATED AREA. STORE LOCKED UP.
INCOMPATIBLE PRODUCTS: NONE KNOWN.
INCOMPATIBLE MATERIALS: FLAMMABLE MATERIALS.
7.3. SPECIFIC END USE(S): NONE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
NITROGEN (7727-37-9):
METHANE (74-82-8):
USA ACGIH:
ACGIH TWA (PPM): 1000 PPM
HYDROGEN SULFIDE (7783-06-4):
USA ACGIH:
ACGIH TWA (PPM): 1 PPM
USA ACGIH:
ACGIH STEL (PPM): 5 PPM
USA OSHA:
OSHA PEL (CEILING) (PPM): 20 PPM
CARBON MONOXIDE (630-08-0):
USA ACGIH:
ACGIH TWA (PPM): 25 PPM
USA OSHA:
OSHA PEL (TWA) (MG/M3): 55 MG/M3
USA OSHA:
OSHA PEL (TWA) (PPM): 50 PPM
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION. SYSTEMS UNDER
PRESSURE SHOULD BE REGULARLY CHECKED FOR LEAKAGES. OXYGEN DETECTORS SHOULD
BE USED WHEN ASPHYXIATING GASES MAY BE RELEASED. CONSIDER WORK PERMIT
SYSTEM E.G. FOR MAINTENANCE ACTIVITIES.
HAND PROTECTION:
WEAR WORKING GLOVES WHEN HANDLING GAS CONTAINERS. 29 CFR 1910.138:
HAND PROTECTION.
EYE PROTECTION:
WEAR SAFETY GLASSES WITH SIDE SHIELDS. 29 CFR 1910.133:
EYE AND FACE PROTECTION.
SKIN AND BODY PROTECTION:
WEAR SUITABLE PROTECTIVE CLOTHING, E.G. - LAB COATS, COVERALLS OR FLAME
RESISTANT CLOTHING.
RESPIRATORY PROTECTION: SEE SECTIONS 5 & 6.
THERMAL HAZARD PROTECTION: NONE NECESSARY.
ENVIRONMENTAL EXPOSURE CONTROLS:
REFER TO LOCAL REGULATIONS FOR RESTRICTION OF EMISSIONS TO THE ATMOSPHERE.
SEE SECTION 13 FOR SPECIFIC METHODS FOR WASTE GAS TREATMENT. NONE
NECESSARY.
OTHER INFORMATION:
WEAR SAFETY SHOES WHILE HANDLING CONTAINERS. 29 CFR 1910.136:
FOOT PROTECTION.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: GAS
APPEARANCE: CLEAR, COLORLESS GAS.
MOLECULAR MASS: NOT APPLICABLE FOR GAS-MIXTURES.
COLOUR: NO DATA AVAILABLE
ODOUR: NO DATA AVAILABLE
ODOUR THRESHOLD:
ODOUR THRESHOLD IS SUBJECTIVE AND INADEQUATE TO WARN FOR OVEREXPOSURE.
PH: NOT APPLICABLE FOR GAS-MIXTURES.
RELATIVE EVAPORATION RATE (BUTYLACETATE=1): NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (ETHER=1): NOT APPLICABLE FOR GAS-MIXTURES.
MELTING POINT: NOT APPLICABLE FOR GAS-MIXTURES.
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NOT APPLICABLE FOR GAS-MIXTURES.
FLASH POINT: NOT APPLICABLE FOR GAS-MIXTURES.
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOUR PRESSURE: NOT APPLICABLE.
RELATIVE VAPOUR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
RELATIVE GAS DENSITY: HEAVIER THAN AIR.
SOLUBILITY: NO DATA AVAILABLE
LOG POW: NOT APPLICABLE FOR GAS-MIXTURES.
LOG KOW: NOT APPLICABLE FOR GAS-MIXTURES.
VISCOSITY, KINEMATIC: NOT APPLICABLE.
VISCOSITY, DYNAMIC: NOT APPLICABLE.
EXPLOSIVE PROPERTIES: NOT APPLICABLE.
OXIDISING PROPERTIES:
NOT COMBUSTIBLE BUT ENHANCES COMBUSTION OF OTHER SUBSTANCES. SUPPORTS
COMBUSTION.
EXPLOSIVE LIMITS: NOT APPLICABLE FOR GAS-MIXTURES.
9.2. OTHER INFORMATION:
GAS GROUP: COMPRESSED GAS
ADDITIONAL INFORMATION:
GAS/VAPOUR HEAVIER THAN AIR. MAY ACCUMULATE IN CONFINED SPACES,
PARTICULARLY AT OR BELOW GROUND LEVEL.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
NO REACTIVITY HAZARD OTHER THAN THE EFFECTS DESCRIBED IN SUB-SECTIONS
BELOW.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
CAN FORM EXPLOSIVE MIXTURES WITH FLAMMABLE MATERIALS. NONE.
10.4. CONDITIONS TO AVOID:
NONE UNDER RECOMMENDED STORAGE AND HANDLING CONDITIONS (SEE SECTION 7).
NONE.
10.5. INCOMPATIBLE MATERIALS: NONE. FLAMMABLE MATERIALS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
NONE. UNDER NORMAL CONDITIONS OF STORAGE AND USE HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
NITROGEN (7727-37-9):
LC50 INHALATION RAT (PPM): 410000 PPM/4H
METHANE (74-82-8):
LC50 INHALATION RAT (PPM): 410000 PPM/4H
ATE CLP (GASES): 410000.000 PPMV/4H
HYDROGEN SULFIDE (7783-06-4):
LC50 INHALATION RAT (MG/L): 0.99 MG/L (EXPOSURE TIME: 1 H)
LC50 INHALATION RAT (PPM): 356 PPM/4H
ATE CLP (GASES): 356.000 PPMV/4H
ATE CLP (VAPOURS): 0.990 MG/L/4H
ATE CLP (DUST, MIST): 0.990 MG/L/4H
OXYGEN (7782-44-7):
LC50 INHALATION RAT (PPM): 400000 PPM/4H
CARBON MONOXIDE (630-08-0):
LC50 INHALATION RAT (PPM): 1880 PPM/4H
ATE CLP (GASES): 1880.000 PPMV/4H
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: NOT APPLICABLE FOR GAS-MIXTURES.
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH: NOT APPLICABLE FOR GAS-MIXTURES.
RESPIRATORY OR SKIN SENSITISATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: (INHALATION).
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
CAUSES DAMAGE TO ORGANS (CNS) THROUGH PROLONGED OR REPEATED EXPOSURE
(INHALATION).
NO KNOWN EFFECTS FROM THIS PRODUCT.
ASPIRATION HAZARD:
NOT CLASSIFIED
NOT APPLICABLE FOR GASES AND GAS-MIXTURES.
SYMPTOMS/INJURIES AFTER INHALATION:
NOT EXPECTED TO PRESENT A SIGNIFICANT INHALATION HAZARD UNDER ANTICIPATED
CONDITIONS OF NORMAL USE.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
SYMPTOMS/INJURIES AFTER INGESTION:
INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
SYMPTOMS/INJURIES UPON INTRAVENOUS ADMINISTRATION: NOT KNOWN.
CHRONIC SYMPTOMS: ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
HYDROGEN SULFIDE (7783-06-4):
LC50 FISHES 1:
0.0448 MG/L (EXPOSURE TIME: 96 H - SPECIES: LEPOMIS MACROCHIRUS
[FLOW-THROUGH])
EC50 DAPHNIA 1:
0.022 MG/L (EXPOSURE TIME: 96 H - SPECIES: GAMMARUS PSEUDOLIMNAEUS)
LC50 FISH 2:
0.016 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[FLOW-THROUGH])
12.2. PERSISTENCE AND DEGRADABILITY:
OXYGEN (0.0015-23.5), METHANE (0.0005-2.5%), CARBON MONOXIDE (0.001-1.0%),
HYDROGEN SULFIDE (0.001-0.025%) IN NITROGEN BALANCE:
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE.
NITROGEN (7727-37-9):
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
METHANE (74-82-8):
PERSISTENCE AND DEGRADABILITY:
THE SUBSTANCE IS BIODEGRADABLE. UNLIKELY TO PERSIST. NO DATA AVAILABLE.
HYDROGEN SULFIDE (7783-06-4):
PERSISTENCE AND DEGRADABILITY: NOT APPLICABLE FOR INORGANIC GASES.
OXYGEN (7782-44-7):
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
CARBON MONOXIDE (630-08-0):
PERSISTENCE AND DEGRADABILITY:
WILL NOT UNDERGO HYDROLYSIS. NOT READILY BIODEGRADABLE. NOT APPLICABLE
FOR INORGANIC GASES.
12.3. BIOACCUMULATIVE POTENTIAL:
OXYGEN (0.0015-23.5), METHANE (0.0005-2.5%), CARBON MONOXIDE (0.001-1.0%),
HYDROGEN SULFIDE (0.001-0.025%) IN NITROGEN BALANCE:
LOG POW: NOT APPLICABLE FOR GAS-MIXTURES.
LOG KOW: NOT APPLICABLE FOR GAS-MIXTURES.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
NITROGEN (7727-37-9):
LOG POW: NOT APPLICABLE FOR INORGANIC GASES.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
METHANE (74-82-8):
LOG POW: 1.09
LOG KOW: NOT APPLICABLE FOR GAS-MIXTURES.
BIOACCUMULATIVE POTENTIAL:
NOT EXPECTED TO BIOACCUMULATE DUE TO THE LOW LOG KOW (LOG KOW <4). REFER
TO SECTION 9.
HYDROGEN SULFIDE (7783-06-4):
BCF FISH 1: (NO BIOACCUMULATION EXPECTED)
LOG POW: NOT APPLICABLE FOR INORGANIC GASES.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
OXYGEN (7782-44-7):
LOG POW: NOT APPLICABLE FOR INORGANIC GASES.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
CARBON MONOXIDE (630-08-0):
LOG POW: 1.78
BIOACCUMULATIVE POTENTIAL:
NOT EXPECTED TO BIOACCUMULATE DUE TO THE LOW LOG KOW (LOG KOW <4). REFER
TO SECTION 9.
12.4. MOBILITY IN SOIL:
OXYGEN (0.0015-23.5), METHANE (0.0005-2.5%), CARBON MONOXIDE (0.001-1.0%),
HYDROGEN SULFIDE (0.001-0.025%) IN NITROGEN BALANCE:
MOBILITY IN SOIL: NO DATA AVAILABLE.
NITROGEN (7727-37-9):
ECOLOGY - SOIL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
METHANE (74-82-8):
MOBILITY IN SOIL: NO DATA AVAILABLE.
ECOLOGY - SOIL:
BECAUSE OF ITS HIGH VOLATILITY, THE PRODUCT IS UNLIKELY TO CAUSE GROUND
OR WATER POLLUTION.
HYDROGEN SULFIDE (7783-06-4):
ECOLOGY - SOIL:
BECAUSE OF ITS HIGH VOLATILITY, THE PRODUCT IS UNLIKELY TO CAUSE GROUND
OR WATER POLLUTION.
OXYGEN (7782-44-7):
ECOLOGY - SOIL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
CARBON MONOXIDE (630-08-0):
ECOLOGY - SOIL:
BECAUSE OF ITS HIGH VOLATILITY, THE PRODUCT IS UNLIKELY TO CAUSE GROUND
OR WATER POLLUTION.
12.5. OTHER ADVERSE EFFECTS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE TREATMENT METHODS:
CONTACT SUPPLIER IF GUIDANCE IS REQUIRED. MAY BE VENTED TO ATMOSPHERE. DO
NOT DISCHARGE INTO ANY PLACE WHERE ITS ACCUMULATION COULD BE DANGEROUS.
REFER TO THE EIGA CODE OF PRACTICE DOC.30 "DISPOSAL OF GASES", DOWNLOADABLE
AT HTTP://WWW.EIGA.ORG FOR MORE GUIDANCE ON SUITABLE DISPOSAL METHODS.
ADDITIONAL INFORMATION: NONE.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION:
UN1956 COMPRESSED GAS, N.O.S. (OXYGEN, NITROGEN), 2.2
UN-NO.(DOT): 1956
DOT NA NO.: UN1956
DOT PROPER SHIPPING NAME: COMPRESSED GAS, N.O.S. (OXYGEN, NITROGEN)
DEPARTMENT OF TRANSPORTATION (DOT) HAZARD CLASSES:
2.2 - CLASS 2.2 - NON-FLAMMABLE COMPRESSED GAS 49 CFR 173.115
HAZARD LABELS (DOT): 2.2 - NON-FLAMMABLE GAS
DOT SYMBOLS: G - IDENTIFIES PSN REQUIRING A TECHNICAL NAME
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 306; 307
DOT PACKAGING NON BULK (49 CFR 173.XXX): 302; 305
DOT PACKAGING BULK (49 CFR 173.XXX): 314; 315
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 75 KG
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 150 KG
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
ADDITIONAL INFORMATION:
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
SPECIAL TRANSPORT PRECAUTIONS:
AVOID TRANSPORT ON VEHICLES WHERE THE LOAD SPACE IS NOT SEPARATED FROM THE
DRIVER'S COMPARTMENT. ENSURE VEHICLE DRIVER IS AWARE OF THE POTENTIAL
HAZARDS OF THE LOAD AND KNOWS WHAT TO DO IN THE EVENT OF AN ACCIDENT OR
AN EMERGENCY.
BEFORE TRANSPORTING PRODUCT CONTAINERS:
ENSURE THERE IS ADEQUATE VENTILATION.
ENSURE THAT CONTAINERS ARE FIRMLY SECURED.
ENSURE CYLINDER VALVE IS CLOSED AND NOT LEAKING.
ENSURE VALVE OUTLET CAP NUT OR PLUG (WHERE PROVIDED) IS CORRECTLY FITTED.
ENSURE VALVE PROTECTION DEVICE (WHERE PROVIDED) IS CORRECTLY FITTED.
ADR:
TRANSPORT DOCUMENT DESCRIPTION:
TRANSPORT BY SEA:
UN-NO. (IMDG): 1956
PROPER SHIPPING NAME (IMDG): COMPRESSED GAS, N.O.S.
CLASS (IMDG): 2.2 - NON-FLAMMABLE, NON-TOXIC GASES
AIR TRANSPORT:
UN-NO.(IATA): 1956
PROPER SHIPPING NAME (IATA): COMPRESSED GAS, N.O.S.
CLASS (IATA): 2
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
NITROGEN (7727-37-9):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
METHANE (74-82-8):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
HYDROGEN SULFIDE (7783-06-4):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
LISTED ON THE UNITED STATES SARA SECTION 302
LISTED ON UNITED STATES SARA SECTION 313
SARA SECTION 302 THRESHOLD PLANNING QUANTITY (TPQ): 500
SARA SECTION 313 - EMISSION REPORTING: 1.0%
OXYGEN (7782-44-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
CARBON MONOXIDE (630-08-0):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
NITROGEN (7727-37-9): LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
WHMIS CLASSIFICATION: CLASS A - COMPRESSED GAS
METHANE (74-82-8): LISTED ON THE CANADIAN DSL (DOMESTIC SUSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS B DIVISION 1 - FLAMMABLE GAS
HYDROGEN SULFIDE (7783-06-4):
LISTED ON THE CANADIAN DSL (DOMESTIC SUSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS B DIVISION 1 - FLAMMABLE GAS
CLASS D DIVISION 1 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING IMMEDIATE
AND SERIOUS TOXIC EFFECTS
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
OXYGEN (7782-44-7): LISTED ON THE CANADIAN DSL (DOMESTIC SUSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS C - OXIDIZING MATERIAL
CARBON MONOXIDE (630-08-0):
LISTED ON THE CANADIAN DSL (DOMESTIC SUSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS B DIVISION 1 - FLAMMABLE GAS
CLASS D DIVISION 1 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING IMMEDIATE
AND SERIOUS TOXIC EFFECTS
CLASS D DIVISION 2 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
EU-REGULATIONS:
NITROGEN (7727-37-9):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
METHANE (74-82-8):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
HYDROGEN SULFIDE (7783-06-4):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
OXYGEN (7782-44-7):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
CARBON MONOXIDE (630-08-0):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]:
NOT CLASSIFIED
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR 1999/45/EC:
15.2.2. NATIONAL REGULATIONS:
NITROGEN (7727-37-9):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
METHANE (74-82-8):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICAL SUBSTANCES) INVENTORY
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
HYDROGEN SULFIDE (7783-06-4):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICAL SUBSTANCES) INVENTORY
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
OXYGEN (7782-44-7):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
CARBON MONOXIDE (630-08-0):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICAL SUBSTANCES) INVENTORY
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
15.3. US STATE REGULATIONS:
CARBON MONOXIDE (630-08-0):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST:
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE:
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE:
NO SIGNIFICANCE RISK LEVEL (NSRL):
NITROGEN (7727-37-9):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
METHANE (74-82-8):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
HYDROGEN SULFIDE (7783-06-4):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
OXYGEN (7782-44-7):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
CARBON MONOXIDE (630-08-0):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
| SECTION 16: OTHER INFORMATION | |
INDICATION OF CHANGES:
REVISED SAFETY DATA SHEET IN ACCORDANCE WITH OSHA FINAL RULE ON GHS
IMPLEMENTATION PROMULGATED MARCH 26, 2012.
TRAINING ADVICE: RECEPTACLE UNDER PRESSURE.
OTHER INFORMATION:
THIS SAFETY DATA SHEET HAS BEEN ESTABLISHED IN ACCORDANCE WITH THE
APPLICABLE EUROPEAN UNION LEGISLATION. CLASSIFICATION IN ACCORDANCE WITH
CALCULATION METHODS OF REGULATION (EC) 1272/2008 CLP / (EC) 1999/45 DPD.
FULL TEXT OF H-PHRASES:
SEE SECTION 16:
ACUTE TOX. 2 (INHALATION: GAS): ACUTE TOXICITY (INHALATION:GAS) CATEGORY 2
ACUTE TOX. 3 (INHALATION: GAS): ACUTE TOXICITY (INHALATION:GAS) CATEGORY 3
COMPRESSED GAS: GASES UNDER PRESSURE: COMPRESSED GAS
FLAM. GAS 1: FLAMMABLE GASES, CATEGORY 1
LIQUEFIED GAS: GASES UNDER PRESSURE: LIQUEFIED GAS
OX. GAS 1: OXIDISING GASES, CATEGORY 1
REPR. 1A: REPRODUCTIVE TOXICITY, CATEGORY 1A
STOT RE 1: SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, CATEGORY 1
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, CATEGORY 3, RESPIRATORY
TRACT IRRITATION
H220: EXTREMELY FLAMMABLE GAS
H270: MAY CAUSE OR INTENSIFY FIRE; OXIDIZER
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H330: FATAL IF INHALED
H331: TOXIC IF INHALED
O
H335: MAY CAUSE RESPIRATORY IRRITATION
H360: MAY DAMAGE FERTILITY OR THE UNBORN CHILD
H372: CAUSES DAMAGE TO ORGANS (CNS) THROUGH PROLONGED OR REPEATED EXPOSURE
SDS US (GHS HAZCOM 2012)
THIS SAFETY DATA SHEET IS OFFERED PURSUANT TO OSHA'S HAZARD COMMUNICATION
STANDARD, 29 CFR, 1910.1200. OTHER GOVERNMENT REGULATIONS MUST BE REVIEWED
FOR APPLICABILITY TO THIS GAS MIXTURE. TO THE BEST OF CALGAZ'S KNOWLEDGE,
THE INFORMATION CONTAINED HEREIN IS RELIABLE AND ACCURATE AS OF THIS DATE;
HOWEVER, ACCRUACY, SUITABILITY OR COMPLETENESS ARE NOT GUARANTEED AND NO
WARRANTIES OF ANY TYPE, EITHER EXPRESS OR IMPLIED, ARE PROVIDED. THE
INFORMATION CONTAINED HEREIN RELATES ONLY TO THIS SPECIFIC PRODUCT. IF THIS
GAS MIXTURE IS COMBINED WITH OTHER MATERIALS, ALL COMPONENT PROPERTIES MUST
BE CONSIDERED. DATA MAY BE CHANGED FROM TIME TO TIME. BE SURE TO CONSULT
THE LATEST EDITION.
EN (ENGLISH)
SDS ID: 50018MSA