| Common Name: | ST27 TOTAL AIR CONDITIONING LEAK STOP AEROSOL |
| Manufacturer: | TIRE SEAL |
| SDS Revision Date: | 5/5/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 4LTV4 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SUPERCOOL(TM)
TRUSTED BY PROFESSIONALS
ST27 TOTAL AIR CONDITIONING LEAK STOP AEROSOL
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26,
2012 / RULES AND REGULATIONS
DATE OF ISSUE: 05/05/2016
REVISION DATE: 05/05/2016
SUPERSEDES: 04/06/2015
VERSION: 2.8
| SECTION 1: IDENTIFICATION |  |
1.1. IDENTIFICATION:
PRODUCT FORM: MIXTURE
TRADE NAME: ST27 TOTAL AIR CONDITIONING LEAK STOP AEROSOL
PRODUCT CODE: ST27
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE:
TOTAL AIR CONDITIONING LEAK STOP WITH UV DYE AEROSOL IS USED TO SEAL
SMALL LEAKS IN REFRIGERATION SYSTEM METAL AND RUBBER COMPONENTS.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
TIRE SEAL, INC.
3574 CORONA STREET
LAKE WORTH, FLORIDA 33461
USA
T: 561-582-2245
F: 561-582-1499
WWW.SUPERCOOL.AC
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
USA PHONE: 1-800-373-7542
INT'L: 1-484-951-2432
DGA/AAG ENVIRONMENTAL CONTRACT: DGA4000-048
| SECTION 2: HAZARD(S) IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION: NOT CLASSIFIED
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS04: GAS CYLINDER
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): WARNING
HAZARD STATEMENTS (GHS-US):
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
H281: CONTAINS REFRIGERATED GAS; MAY CAUSE CRYOGENIC BURNS OR INJURY
H302: HARMFUL IF SWALLOWED
H312: HARMFUL IN CONTACT WITH SKIN
PRECAUTIONARY STATEMENTS (GHS-US):
P412: DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C / 122 DEG. F
2.3. OTHER HAZARDS:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
CONTAINS GAS UNDER PRESSURE; MAY BURST IF HEATED.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
1,1,1,2- (CAS NO): 811-97-2 48 - 53 NOT CLASSIFIED
TETRAFLUOROETHANE
1,2-BENZENE- (CAS NO): 68515-49-1 13.5 ACUTE TOX. 4 (ORAL),
DICARBOXYLIC ACID H302
DIC9-11 BRANCHED
ALKYLESTERS, C10 ACUTE TOX. 4 (DERMAL),
RICH H312
FULL TEXT OF HAZARD CLASSES AND H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
ALLOW VICTIM TO BREATHE FRESH AIR. ALLOW THE VICTIM TO REST.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE AFFECTED CLOTHING AND WASH ALL EXPOSED SKIN AREA WITH MILD SOAP AND
WATER, FOLLOWED BY WARM WATER RINSE.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER. OBTAIN MEDICAL ATTENTION IF PAIN,
BLINKING OR REDNESS PERSIST.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES:
NOT EXPECTED TO PRESENT A SIGNIFICANT HAZARD UNDER ANTICIPATED CONDITIONS
OF NORMAL USE.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NO ADDITIONAL INFORMATION AVAILABLE
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
6.1.1. FOR NON-EMERGENCY PERSONNEL:
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS. AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
CAUTION:
COMPRESSED GAS. DO NOT PUNCTURE, INCINERATE OR STORE ABOVE 120 DEG. F. DO
NOT STORE IN PASSENGER COMPARTMENT OF AUTOMOBILE. AVOID BREATHING VAPORS,
IF EXPOSED TO HIGH VAPOR CONCENTRATION, LEAVE AREA AT ONCE. AVOID CONTACT
WITH SKIN AND EYES.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C / 122 DEG. F.
INCOMPATIBLE PRODUCTS: STRONG BASES. STRONG ACIDS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT.
STORAGE TEMPERATURE:
<50 DEG. C DO NOT STORE IN PASSENGER COMPARTMENT OF AUTOMOBILES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH
(68515-49-1): NOT APPLICABLE
1,1,1,2-TETRAFLUOROETHANE (811-97-2): NOT APPLICABLE
8.2. EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT: AVOID ALL UNNECESSARY EXPOSURE.
HAND PROTECTION:
THE USE OF GLOVES IMPERVIOUS TO THE SPECIFIC MATERIAL HANDLED IS ADVISED
TO PREVENT SKIN CONTACT.
SUGGESTED PROTECTIVE MATERIAL:
NITRILE, 4.5 MIL THICKNESS, TESTED AT 3.5 ML AND ABOVE WITH NO BREAKTHROUGH
TIME AFTER 240 MINUTES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES.
RESPIRATORY PROTECTION:
WHERE THERE IS POTENTIAL FOR AIRBORNE EXPOSURE ABOVE THE EXPOSURE LIMIT AN
APPROVED AIR PURIFYING RESPIRATOR EQUIPPED WITH TYPE P2 - MEDIUM EFFICIENCY
PARTICLE FILTERS MAY BE USED.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: OPAQUE.
COLOR: GREEN-YELLOW TINT
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NON FLAMMABLE.
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SOLUBILITY: NO DATA AVAILABLE
LOG POW: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY: NOT ESTABLISHED.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES.
10.5. INCOMPATIBLE MATERIALS: STRONG ACIDS. STRONG BASES.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE. CARBON DIOXIDE. THIS MATERIAL CAN BE DECOMPOSED BY HIGH
TEMPERATURES FORMING HYDROFLUORIC ACID AND POSSIBLY CARBONYL FLUORIDE.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH
(68515-49-1):
LD50 ORAL RAT: 2000 MG/KG (RAT)
LD50 DERMAL RABBIT: 2000 MG/KG (RABBIT)
ATE US (ORAL): 2000.000 MG/KG BODY WEIGHT
ATE US (DERMAL): 2000.000 MG/KG BODY WEIGHT
ADDITIONAL INFORMATION:
DI-ISODECYL PHTHALATE (DIDP) HAS BEEN TESTED IN REPRODUCTIVE TOXICOLOGY
STUDIES IN LABORATORY RATS (TWO-GENERATION STUDIES). THERE WERE NO EFFECTS
ON FERTILITY, REPRODUCTIVE PERFORMANCE, OR EVIDENCE OF ALTERATION OF
ENDOCRINE PROCESSES. A SMALL, STATISTICALLY SIGNIFICANT DECREASE IN
OFFSPRING SURVIVAL WAS OBSERVED. IN EVALUATING THESE AND RELATED STUDIES,
THE EU RISK ASSESSMENT FOR DIDP HAS CONCLUDED THAT CLASSIFICATION AND
LABELING IS NOT REQUIRED FOR ANY EFFECT INCLUDING REPRODUCTIVE AND
DEVELOPMENTAL EFFECTS. IN ADDITION THE NTP CENTER FOR EVALUATION OF RISKS
TO HUMAN REPRODUCTION HAS CONCLUDED THAT THERE IS NEGLIGIBLE CONCERN FOR
REPRODUCTIVE EFFECTS IN ADULTS AND MINIMAL CONCERN FOR DEVELOPMENTAL
EFFECTS IN FETUSES AND CHILDREN DUE TO DIDP EXPOSURE
1,1,1,2-TETRAFLUOROETHANE (811-97-2):
LC50 INHALATION RAT (MG/L): >2000 MG/L/4H (RAT; LITERATURE STUDY)
LC50 INHALATION RAT (PPM): >359300 PPM/4H (RAT; LITERATURE STUDY)
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY:
NOT CLASSIFIED
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY:
NOT CLASSIFIED
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - WATER: TOXIC TO AQUATIC LIFE.
1,1,1,2-TETRAFLUOROETHANE (811-97-2):
LC50 FISH 1: 450 MG/L (LC50; 96 H)
EC50 DAPHNIA 1: 980 MG/L (EC50; 48 H)
12.2. PERSISTENCE AND DEGRADABILITY:
ST27 TOTAL AIR CONDITIONING LEAK STOP AEROSOL:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH
(68515-49-1):
PERSISTENCE AND DEGRADABILITY: EXPECTED TO BE READILY BIODEGRADABLE.
1,1,1,2-TETRAFLUOROETHANE (811-97-2):
PERSISTENCE AND DEGRADABILITY: NOT READILY BIODEGRADABLE IN WATER.
12.3. BIOACCUMULATIVE POTENTIAL:
ST27 TOTAL AIR CONDITIONING LEAK STOP AEROSOL:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH
(68515-49-1):
BIOACCUMULATIVE POTENTIAL: NO BIOACCUMULATION DATA AVAILABLE.
1,1,1,2-TETRAFLUOROETHANE (811-97-2):
BCF OTHER AQUATIC ORGANISMS 1: 5 - 58 (BCF)
LOG POW:
1.06 (OECD 107: PARTITION COEFFICIENT (N-OCTANOL/WATER): SHAKE FLASK
METHOD)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
12.4. MOBILITY IN SOIL:
1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH
(68515-49-1):
SURFACE TENSION: 0.033 N/M
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON THE GLOBAL WARMING: NO KNOWN EFFECTS FROM THIS PRODUCT.
GWPMIX COMMENT: NO KNOWN EFFECTS FROM THIS PRODUCT.
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
DEPARTMENT OF TRANSPORTATION (DOT):
IN ACCORDANCE WITH DOT:
PROPER SHIPPING NAME (DOT):
AEROSOLS
LTD QTY
CLASS (DOT): 2.2 - CLASS 2.2 - NON-FLAMMABLE COMPRESSED GAS 49 CFR 173.115
HAZARD LABELS (DOT): LIMITED QUANTITY
LIMITED QUANTITY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
TDG:
TRANSPORT DOCUMENT DESCRIPTION: 1950 AEROSOLS, NON-FLAMMABLE, 2.2
UN-NO. (TDG): 1950
PROPER SHIPPING NAME (TDG): AEROSOLS, NON-FLAMMABLE
TDG PRIMARY HAZARD CLASSES: 2.2 - CLASS 2.2 - NON-FLAMMABLE, NON-TOXIC GAS.
TRANSPORT BY SEA:
AIR TRANSPORT:
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
15.2. INTERNATIONAL REGULATIONS:
CANADA:
ST27 TOTAL AIR CONDITIONING LEAK STOP AEROSOL:
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
NATIONAL REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
15.3. US STATE REGULATIONS:
ST27 TOTAL AIR CONDITIONING LEAK STOP AEROSOL:
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
1,2-BENZENEDICARBOXYLIC ACID DIC9-11 BRANCHED ALKYLESTERS, C10 RICH
(68515-49-1):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NON-SIGNIFICANT RISK LEVEL (NSRL):
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 05/05/2016
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES:
SEE SECTION 16:
H302: HARMFUL IF SWALLOWED
H312: HARMFUL IN CONTACT WITH SKIN
NFPA HEALTH HAZARD 1 - EXPOSURE COULD CAUSE IRRITATION BUT ONLY MINOR
RESIDUAL INJURY EVEN IF NO TREATMENT IS GIVEN.
NFPA FIRE HAZARD 1 - MUST BE PREHEATED BEFORE IGNITION CAN OCCUR.
NFPA REACTIVITY 0 - NORMALLY STABLE, EVEN UNDER FIRE EXPOSURE
CONDITIONS, AND ARE NOT REACTIVE WITH WATER.
SDS US (GHS HAZCOM 2012)
THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED,
EXCEPT THAT IS ACCURATE TO THE BEST KNOWLEDGE OF TIRE SEAL, INC. THE DATA
ON THIS SHEET RELATED ONLY TO THE SPECIFIC MATERIAL DESIGNED HEREIN. TIRE
SEAL, INC. ASSUMES NO LEGAL RESPONSIBILITY FOR THE USE OR RELIANCE UPON
THESE DATA.
EN (ENGLISH US)