| Common Name: | WINDOW, DOOR & SIDING 100% SILICONE RUBBER SEALANT - BLACK |
| Manufacturer: | DAP GLOBAL |
| SDS Revision Date: | 4/12/2022 |
| SDS Format: | No Format Specified |
| Item Number(s): | 4MY67 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DAP(R*)
SDS NUMBER: 9864201
SAP NUMBER:
REVISION DATE: 4/12/2022
SAFETY DATA SHEET
24 HOUR EMERGENCY PHONE NUMBERS MEDICAL/POISON CONTROL:
IN U.S.: CALL 1-800-222-1222
OUTSIDE U.S.: CALL YOUR LOCAL POISON CONTROL CENTER
TRANSPORTATION/NATIONAL RESPONSE CENTER:
1-800-535-5053
1-352-323-3500
NOTE:
THE NATIONAL RESPONSECENTER EMERGENCY NUMBERS TO BE USED ONLY IN THE EVENT
OF CHEMICAL EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT
INVOLVING CHEMICALS.
IMPORTANT:
PROVIDE THIS INFORMATION TO EMPLOYEES, CUSTOMERS, AND USERS OF THIS
PRODUCT. READ THIS SDS BEFORE HANDLING OR DISPOSING OF THIS PRODUCT. THIS
PRODUCT IS COVERED BY THE OSHA HAZARD COMMUNICATION STANDARD AND THIS
DOCUMENT HAS BEEN PREPARED IN ACCORDANCE WITH REQUIREMENTS OF THIS
STANDARD. ALL ABBREVIATED TERMS USED IN THIS SDS ARE FURTHER DESCRIBED IN
SECTION 16.
| 1. IDENTIFICATION |  |
PRODUCT NAME:
DAP WINDOW, DOOR & SIDING 100% SILICONE RUBBER SEALANT - BLACK
PRODUCT UPC NUMBER: 070798086425
MANUFACTURER:
DAP GLOBAL INC.
2400 BOSTON STREET SUITE 200
BALTIMORE, MD 21224-4723
888-327-8477 (NON - EMERGENCY MATTERS)
SDS COORDINATOR: MSDS@DAP.COM
EMERGENCY TELEPHONE:
TRANSPORTATION:
1-800-535 -5053
1-352-323-3500
POISON CONTROL: 1-800-222-1222
REVISION DATE: 4/12/2022
SUPERCEDES DATE: 12/30/2021
PRODUCT USE/CLASS: CAULKING COMPOUND
SDS NO: 9864201
PREPARER: REGULATORY AND ENVIRONMENTAL AFFAIRS
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. HIGH CONCENTRATION OF VAPORS MAY CAUSE IRRITATION TO EYES
AND RESPIRATORY SYSTEM.
GHS CLASSIFICATION: NOT A HAZARDOUS SUBSTANCE OR MIXTURE.
SYMBOL(S) OF PRODUCT: NONE
SIGNAL WORD: NOT A HAZARDOUS SUBSTANCE OR MIXTURE.
POSSIBLE HAZARDS:
7% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE TOXICITY
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO. WT. % GHS SYMBOLS GHS STATEMENTS
HYDROTREATED MIDDLE 64742-46-7 10-30 GHS07 H332
DISTILLATE
SILICA, AMORPHOUS 7631-86-9 3-7 GHS07 H332
SILANETRIOL, METHYL-, 4253-34-3 1-5 GHS07 H302-312-315-
TRIACETA 319-332
ETHYLTRIACETOXYSILANE 17689-77-9 1-5 GHS07 H302-312-315-
319-332
THE TEXT FOR GHS HAZARD STATEMENTS SHOWN ABOVE (IF ANY) IS GIVEN IN THE
"OTHER INFORMATION" SECTION.
| 4. FIRST-AID MEASURES | |
FIRST AID - INHALATION:
MATERIAL IS NOT LIKELY TO PRESENT AN INHALATION HAZARD AT AMBIENT
CONDITIONS. IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO
OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, GET MEDICAL
ATTENTION IMMEDIATELY.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER FOR 15 MINUTES. GET MEDICAL AID IF SYMPTOMS
PERSIST.
FIRST AID - EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH LARGE QUANTITIES OF WATER
FOR AT LEAST 15 MINUTES UNTIL IRRITATION SUBSIDES. GET MEDICAL ATTENTION
IMMEDIATELY.
FIRST AID - INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
UNUSUAL FIRE AND EXPLOSION HAZARDS: NO INFORMATION
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND (NIOSH APPROVED OR
EQUIVALENT) AND FULL PROTECTIVE GEAR. USE WATER SPRAY TO COOL EXPOSED
SURFACES.
EXTINGUISHING MEDIA:
ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER SPRAY OR FOG
| 6. ACCIDENTAL RELEASE MEASURES | |
ENVIRONMENTAL MEASURES: NO INFORMATION
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
IN CASE OF SPILLAGE, ABSORB WITH INERT MATERIAL AND DISPOSE OF IN
ACCORDANCE WITH APPLICABLE REGULATIONS. SCRAPE UP DRIED MATERIAL AND
PLACE INTO CONTAINERS.
| 7. HANDLING AND STORAGE | |
HANDLING:
KEEP OUT OF REACH OF CHILDREN!
DO NOT TAKE INTERNALLY. AVOID BREATHING VAPOR AND CONTACT WITH EYES,
SKIN AND CLOTHING. USE ONLY WITH ADEQUATE VENTILATION. ENSURE FRESH
AIR ENTRY DURING APPLICATION AND DRYING. WASH THOROUGHLY AFTER
HANDLING. REMOVE CONTACT LENSES BEFORE USING. DO NOT HANDLE CONTACT
LENSES UNTIL ALL SEALANT HAS BEEN CLEANED FROM FINGERTIPS, NAILS
AND CUTICLES. RESIDUAL SEALANT MAY TRANSFER TO CONTACT LENSES AND
CAUSE SEVERE EYE IRRITATION.
STORAGE:
AVOID EXCESSIVE HEAT AND FREEZING. DO NOT STORE AT TEMPERATURES ABOVE
120 DEG. F (49 DEG. C). STORE AWAY FROM CAUSTICS AND OXIDIZERS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENTS WITH OCCUPATIONAL EXPOSURE LIMITS:
CHEMICAL NAME ACGIH ACGIH-TLV OSHA OSHA
TLV-TWA STEL PEL-TWA PEL-CEILING
HYDROTREATED MIDDLE DISTILLATE N.E. N.E. N.E. N.E.
SILICA, AMORPHOUS N.E. N.E. N.E. N.E.
SILANETRIOL, METHYL-, TRIACETA N.E. N.E. N.E. N.E.
ETHYLTRIACETOXYSILANE N.E. N.E. N.E. N.E.
FURTHER ADVICE:
MEL = MAXIMUM EXPOSURE LIMIT
OES = OCCUPATIONAL EXPOSURE STANDARD
SUP = SUPPLIER'S RECOMMENDATION
SK = SKIN SENSITIZER
N.E. = NOT ESTABLISHED
PERSONAL PROTECTION:
RESPIRATORY PROTECTION:
NO PERSONAL RESPIRATORY PROTECTIVE EQUIPMENT NORMALLY REQUIRED.
SKIN PROTECTION: WEAR NITRILE OR NEOPRENE GLOVES.
EYE PROTECTION: GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
OTHER PROTECTIVE EQUIPMENT: NOT REQUIRED UNDER NORMAL USE.
HYGIENIC PRACTICES:
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY. REMOVE AND WASH
CONTAMINATED CLOTHING BEFORE RE-USE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: BLACK
PHYSICAL STATE: PASTE
ODOR: ACETIC ACID
ODOR THRESHOLD: NOT ESTABLISHED
DENSITY, G/CM3: 0.96 - 0.96
PH: NOT APPLICABLE
FREEZE POINT, DEG. C: NOT ESTABLISHED
VISCOSITY (MPA.S): NOT ESTABLISHED
SOLUBILITY IN WATER: NOT ESTABLISHED
PARTITION COEFF., N-OCTANOL/WATER: NOT ESTABLISHED
DECOMPOSITION TEMPERATURE, DEG. C: NOT ESTABLISHED
EXPLOSIVE LIMITS, %: N.E. - N.E.
BOILING RANGE, DEG. C: 100 - 100
AUTO-IGNITION TEMPERATURE, DEG. C: NOT ESTABLISHED
MINIMUM FLASH POINT, DEG. C: 100
VAPOR PRESSURE, MMHg: NOT ESTABLISHED
EVAPORATION RATE: SLOWER THAN N-BUTYL ACETATE
FLASH METHOD: SETA CLOSED CUP
VAPOR DENSITY: HEAVIER THAN AIR
FLAMMABILITY, NFPA: NON-FLAMMABLE
COMBUSTIBLE DUST: DOES NOT SUPPORT COMBUSTION
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
(IF PRODUCT IS AN AEROSOL, THE FLASH POINT STATED ABOVE IS THAT OF THE
PROPELLANT.)
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
CONDITIONS TO AVOID: OXIDIZING AGENTS. EXCESSIVE HEAT AND FREEZING.
INCOMPATIBILITY: INCOMPATIBLE WITH STRONG BASES AND OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NORMAL DECOMPOSITION PRODUCTS, I.E., COX, NOX.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECT OF OVEREXPOSURE - INHALATION:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. DURING APPLICATION AND CURE, THIS PRODUCT RELEASES
METHANOL. DURING APPLICATION AND CURE, THIS PRODUCT RELEASES ACETIC ACID.
INHALATION OF VAPORS IN HIGH CONCENTRATION MAY CAUSE MILD IRRITATION OF
RESPIRATORY SYSTEM (NOSE, MOUTH, MUCOUS MEMBRANES).
EFFECT OF OVEREXPOSURE - SKIN CONTACT:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. PROLONGED OR REPEATED CONTACT WITH SKIN MAY CAUSE MILD
IRRITATION.
EFFECT OF OVEREXPOSURE - EYE CONTACT:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. DIRECT EYE CONTACT MAY CAUSE IRRITATION.
EFFECT OF OVEREXPOSURE - INGESTION:
UNDER NORMAL USE CONDITIONS, THIS PRODUCT IS NOT EXPECTED TO CAUSE ADVERSE
HEALTH EFFECTS. SINGLE DOSE ORAL TOXICITY IS VERY LOW. AMOUNTS INGESTED
INCIDENTAL TO INDUSTRIAL HANDLING ARE NOT LIKELY TO CAUSE INJURY; HOWEVER,
INGESTION OF LARGE AMOUNTS MAY CAUSE INJURY. INGESTION MAY RESULT IN
OBSTRUCTION WHEN MATERIAL HARDENS.
CARCINOGENICITY: NO INFORMATION
EFFECT OF OVEREXPOSURE - CHRONIC HAZARDS:
REPEATED OR PROLONGED EXPOSURE MAY CAUSE MILD IRRITATION OF EYES AND SKIN.
CONSTITUENTS OF THIS PRODUCT INCLUDE CRYSTALLINE SILICA WHICH, IF
INHALABLE, MAY CAUSE SILICOSIS, A FORM OF PROGRESSIVE PULMONARY FIBROSIS.
INHALABLE CRYSTALLINE SILICA IS LISTED BY IARC AS A GROUP I CARCINOGEN
(LUNG) BASED ON SUFFICIENT EVIDENCE IN OCCUPATIONALLY EXPOSED HUMANS AND
SUFFICIENT EVIDENCE IN ANIMALS. CRYSTALLINE SILICA IS ALSO LISTED BY THE
NTP AS A KNOWN HUMAN CARCINOGEN. CONSTITUENTS MAY ALSO CONTAIN ASBESTIFORM
OR NON-ASBESTIFORM TREMOLITE OR OTHER SILICATES AS IMPURITIES, AND ABOVE
DE MINIMUS EXPOSURE TO THESE IMPURITIES IN INHALABLE FORM MAY BE
CARCINOGENIC OR CAUSE OTHER SERIOUS LUNG PROBLEMS.
PRIMARY ROUTE(S) OF ENTRY: EYE CONTACT, INHALATION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
64742-46-7 HYDROTREATED MIDDLE 7400 MG/KG >2000 MG/KG >20 MG/L
DISTILLATE RAT RABBIT
7631-86-9 SILICA, AMORPHOUS 7900 MG/KG >5000 MG/KG N.I.
RAT RABBIT
4253-34-3 SILANETRIOL, 1602 MG/KG 1060 MG/KG 11.6 MG/L
METHYL-, TRIACETA RAT RABBIT
17689-77-9 ETHYLTRIACETOXYSILANE 1460 MG/KG 1060 MG/KG 11.6 MG/KG
RAT RABBIT RAT
N.I. = NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
ECOLOGICAL INJURIES ARE NOT KNOWN OR EXPECTED UNDER NORMAL USE.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
THIS PRODUCT DOES NOT MEET THE DEFINITION OF A HAZARDOUS WASTE ACCORDING
TO U.S. EPA HAZARDOUS WASTE MANAGEMENT REGULATION, 40 CFR SECTION 261.
DISPOSE AS HAZARDOUS WASTE ACCORDING TO ALL LOCAL, STATE, FEDERAL AND
PROVINCIAL REGULATIONS. STATE AND LOCAL REGULATIONS/RESTRICTIONS ARE
COMPLEX AND MAY DIFFER FROM FEDERAL REGULATIONS. RESPONSIBILITY FOR PROPER
WASTE DISPOSAL IS WITH THE OWNER OF THE WASTE.
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
IN CASE OF SPILLAGE, ABSORB WITH INERT MATERIAL AND DISPOSE OF IN
ACCORDANCE WITH APPLICABLE REGULATIONS. SCRAPE UP DRIED MATERIAL AND
PLACE INTO CONTAINERS.
| 14. TRANSPORT INFORMATION | |
DOT UN/NA NUMBER: N.A.
DOT PROPER SHIPPING NAME: NOT REGULATED
DOT TECHNICAL NAME: N.A.
DOT HAZARD CLASS: N.A.
HAZARD SUBCLASS: N.A.
PACKING GROUP: N.A.
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
NONE KNOWN
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
NO SARA 313 COMPONENTS EXIST IN THIS PRODUCT.
TOXIC SUBSTANCES CONTROL ACT:
ALL INGREDIENTS IN THIS PRODUCT ARE EITHER ON TSCA INVENTORY LIST, OR
OTHERWISE EXEMPT.
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
| 16. OTHER INFORMATION | |
REVISION DATE: 4/11/2022
SUPERSEDES DATE: 12/30/2021
REASON FOR REVISION:
SUBSTANCE AND/OR PRODUCT PROPERTIES CHANGED IN SECTION(S):
01 - PRODUCT INFORMATION
08 - EXPOSURE CONTROLS/PERSONAL PROTECTION
DATASHEET PRODUCED BY: REGULATORY DEPARTMENT
HMIS RATINGS:
HEALTH 1
FLAMMABILITY 0
REACTIVITY 0
PERSONAL PROTECTION X
VOC LESS WATER LESS EXEMPT SOLVENT, G/L: 28.9
VOC MATERIAL, G/L: 29
VOC AS DEFINED BY CALIFORNIA CONSUMER PRODUCT REGULATION, WT/WT%: 3.05
VOC ACTUAL, WT/WT%: 3.0
TEXT FOR GHS HAZARD STATEMENTS SHOWN IN SECTION 3 DESCRIBING EACH
INGREDIENT:
H302: HARMFUL IF SWALLOWED.
H312: HARMFUL IN CONTACT WITH SKIN.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
ICONS FOR GHS PICTOGRAMS SHOWN IN SECTION 3 DESCRIBING EACH INGREDIENT:
GHS07: EXCLAMATION MARK
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
DAP BELIEVES THE DATA AND STATEMENTS CONTAINED HEREIN ARE ACCURATE AS OF
THE DATE HEREOF. THEY ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT
AS A PRODUCT SPECIFICATION. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR
IMPLIED, IS MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE
PRODUCT TO WHICH THE INFORMATION REFERS. SINCE THIS DOCUMENT IS INTENDED
ONLY AS A GUIDE TO THE APPROPRIATE USE AND PRECAUTIONARY HANDLING OF THE
REFERENCED PRODUCT BY A PROPERLY TRAINED PERSON, IT IS THEREFORE THE
RESPONSIBILITY OF THE USER TO (I) REVIEW THE RECOMMENDATIONS WITH DUE
CONSIDERATION FOR THE SPECIFIC CONTEXT OF THE INTENDED USE AND (II)
DETERMINE IF THEY ARE APPROPRIATE.