| Common Name: | VALVOLINE HD SYNTHETIC TRANS SAE 50 SYNTHETIC MANUAL TRANSMISSION FLUID |
| Manufacturer: | ASHLAND CHEMICAL |
| SDS Revision Date: | 5/22/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 4NPV2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ASHLAND(R*)
SAFETY DATA SHEET
VALVOLINE(TM) HD SYNTHETIC TRANS SAE 50 SYNTHETIC MANUAL TRANSMISSION FLUID
VV706035M
REVISION DATE: 05/22/2015
PRINT DATE: 8/21/2015
SDS NUMBER: R0284085
VERSION: 1.0
29 CFR 1910.1200 (OSHA HAZCOM 2012)
| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER:
TRADE NAME:
VALVOLINE(TM) HD SYNTHETIC TRANS SAE 50 SYNTHETIC MANUAL TRANSMISSION FLUID
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
USE OF THE SUBSTANCE/MIXTURE: TRANSMISSION FLUID
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
ASHLAND
P.O. BOX 2219
COLUMBUS, OH 43216
UNITED STATES OF AMERICA
EHS CUSTOMER REQUESTS@ASHLAND.COM
EMERGENCY TELEPHONE NUMBER: 1-800-ASHLAND (1-800-274-5263)
REGULATORY INFORMATION NUMBER: 1-800-325-3751
PRODUCT INFORMATION: 614-790-3333
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
SKIN SENSITIZATION: CATEGORY 1
REPRODUCTIVE TOXICITY: CATEGORY 2
GHS LABEL ELEMENT:
HAZARD PICTOGRAMS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
MAY CAUSE AN ALLERGIC SKIN REACTION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
CHEMICAL NATURE: DEFATTER
HAZARDOUS COMPONENTS:
CHEMICAL NAME CAS-NO. CLASSIFICATION CONCENTRATION (%)
C11-C14 BRANCHED 80939-62-4 SKIN IRRIT. 2; H315 4.99
ALKYL AMINE EYE IRRIT. 2A; H319
PHOSPHATE
N-PHENYL-1- 90-30-2 ACUTE TOX. 4; H302 0.99
NAPHTHYLAMINE SKIN SENS. 1; H317
STOT RE 2; H373
P-DODECYLPHENOL 27193-86-8 SKIN IRRIT. 2; H315 0.49
EYE IRRIT. 2A; H319
REPR. 2; H361
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
MOVE OUT OF DANGEROUS AREA.
CALL A POISON CENTRE OR DOCTOR/PHYSICIAN IF EXPOSED OR YOU FEEL UNWELL.
SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
DO NOT LEAVE THE VICTIM UNATTENDED.
IF INHALED:
IF BREATHED IN, MOVE PERSON INTO FRESH AIR.
IF UNCONSCIOUS PLACE IN RECOVERY POSITION AND SEEK MEDICAL ADVICE.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
IN CASE OF SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. IF IRRITATION DEVELOPS, GET MEDICAL
ATTENTION.
IF ON SKIN, RINSE WELL WITH WATER.
WASH CONTAMINATED CLOTHING BEFORE RE-USE.
IN CASE OF EYE CONTACT:
FLUSH EYES WITH WATER AS A PRECAUTION.
REMOVE CONTACT LENSES.
PROTECT UNHARMED EYE.
IF EYE IRRITATION PERSISTS, CONSULT A SPECIALIST.
IF SWALLOWED:
OBTAIN MEDICAL ATTENTION.
DO NOT GIVE MILK OR ALCOHOLIC BEVERAGES.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
MAY CAUSE AN ALLERGIC SKIN REACTION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
NO SYMPTOMS KNOWN OR EXPECTED.
NOTES TO PHYSICIAN: NO HAZARDS WHICH REQUIRE SPECIAL FIRST AID MEASURES.
| SECTION 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES
AND THE SURROUNDING ENVIRONMENT.
WATER SPRAY
FOAM
CARBON DIOXIDE (CO2)
DRY CHEMICAL
UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET
SPECIFIC HAZARDS DURING FIREFIGHTING:
DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON DIOXIDE AND CARBON MONOXIDE
OXIDES OF SULFUR, NITROGEN AND PHOSPHORUS
NITROGEN OXIDES (NOX)
OXIDES OF PHOSPHORUS
SPECIFIC EXTINGUISHING METHODS:
PRODUCT IS COMPATIBLE WITH STANDARD FIRE-FIGHTING AGENTS.
FURTHER INFORMATION:
FIRE RESIDUES AND CONTAMINATED FIRE EXTINGUISHING WATER MUST BE DISPOSED
OF IN ACCORDANCE WITH LOCAL REGULATIONS.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT.
ENSURE ADEQUATE VENTILATION.
PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF
SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED.
ENVIRONMENTAL PRECAUTIONS:
PREVENT PRODUCT FROM ENTERING DRAINS.
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
IF THE PRODUCT CONTAMINATES RIVERS AND LAKES OR DRAINS INFORM RESPECTIVE
AUTHORITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER,
UNIVERSAL BINDER, SAWDUST).
KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
OTHER INFORMATION:
COMPLY WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
| SECTION 7. HANDLING AND STORAGE | |
ADVICE ON SAFE HANDLING:
DO NOT BREATHE VAPOURS/DUST.
DO NOT SMOKE.
PERSONS SUSCEPTIBLE TO SKIN SENSITISATION PROBLEMS OR ASTHMA, ALLERGIES,
CHRONIC OR RECURRENT RESPIRATORY DISEASE SHOULD NOT BE EMPLOYED IN ANY
PROCESS IN WHICH THIS MIXTURE IS BEING USED.
CONTAINER HAZARDOUS WHEN EMPTY.
AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
AVOID CONTACT WITH SKIN AND EYES.
SMOKING, EATING AND DRINKING SHOULD BE PROHIBITED IN THE APPLICATION AREA.
FOR PERSONAL PROTECTION SEE SECTION 8.
DISPOSE OF RINSE WATER IN ACCORDANCE WITH LOCAL AND NATIONAL REGULATIONS.
CONDITIONS FOR SAFE STORAGE:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
CONTAINERS WHICH ARE OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO
PREVENT LEAKAGE.
OBSERVE LABEL PRECAUTIONS.
ELECTRICAL INSTALLATIONS / WORKING MATERIALS MUST COMPLY WITH THE
TECHNOLOGICAL SAFETY STANDARDS.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
ENGINEERING MEASURES:
PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION
TO MAINTAIN EXPOSURE BELOW EXPOSURE GUIDELINES (IF APPLICABLE) OR BELOW
LEVELS THAT CAUSE KNOWN, SUSPECTED OR APPARENT ADVERSE EFFECTS.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
A NIOSH-APPROVED AIR-PURIFYING RESPIRATOR WITH AN APPROPRIATE CARTRIDGE
AND/OR FILTER MAY BE PERMISSIBLE UNDER CERTAIN CIRCUMSTANCES WHERE
AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE LIMITS (IF
APPLICABLE) OR IF OVEREXPOSURE HAS OTHERWISE BEEN DETERMINED. PROTECTION
PROVIDED BY AIR-PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE PRESSURE,
AIR-SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR UNCONTROLLED RELEASE,
EXPOSURE LEVELS ARE NOT KNOWN OR ANY OTHER CIRCUMSTANCES WHERE AN
AIR-PURIFYING RESPIRATOR MAY NOT PROVIDE ADEQUATE PROTECTION.
HAND PROTECTION:
REMARKS:
THE SUITABILITY FOR A SPECIFIC WORKPLACE SHOULD BE DISCUSSED WITH THE
PRODUCERS OF THE PROTECTIVE GLOVES.
EYE PROTECTION:
NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. WEAR SPLASH-PROOF SAFETY
GOGGLES IF MATERIAL COULD BE MISTED OR SPLASHED INTO EYES.
SKIN AND BODY PROTECTION:
WEAR AS APPROPRIATE:
IMPERVIOUS CLOTHING
SAFETY SHOES
CHOOSE BODY PROTECTION ACCORDING TO THE AMOUNT AND CONCENTRATION OF THE
DANGEROUS SUBSTANCE AT THE WORK PLACE. DISCARD GLOVES THAT SHOW TEARS,
PINHOLES, OR SIGNS OF WEAR. WEAR RESISTANT GLOVES (CONSULT YOUR SAFETY
EQUIPMENT SUPPLIER).
HYGIENE MEASURES:
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
WHEN USING DO NOT EAT OR DRINK.
WHEN USING DO NOT SMOKE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOUR: AMBER
ODOUR: MILD
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
BOILING POINT/BOILING RANGE: NO DATA AVAILABLE
FLASH POINT: >376 DEG. F / >191 DEG. C
METHOD: CLOSED CUP
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOUR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
DENSITY: 0.8610 G/CM3 (20 DEG. C)
SOLUBILITY(IES):
WATER SOLUBILITY: NO DATA AVAILABLE
SOLUBILITY IN OTHER SOLVENTS: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
THERMAL DECOMPOSITION: NO DATA AVAILABLE
VISCOSITY:
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
PRODUCT WILL NOT UNDERGO HAZARDOUS POLYMERIZATION.
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBLE MATERIALS:
STRONG ACIDS
STRONG BASES
STRONG OXIDIZING AGENTS
HAZARDOUS DECOMPOSITION PRODUCTS:
NO HAZARDOUS DECOMPOSITION PRODUCTS ARE KNOWN.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION
SKIN CONTACT
EYE CONTACT
INGESTION
ACUTE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
ACUTE ORAL TOXICITY:
LD50 (RAT): >2,000 MG/KG
COMPONENTS:
C11-C14 BRANCHED ALKYL AMINE PHOSPHATE:
ACUTE ORAL TOXICITY:
LD50 (RAT): >5,000 MG/KG
METHOD: OECD TEST GUIDELINE 401
GLP: YES
ACUTE DERMAL TOXICITY:
LD50 (RAT): >2,000 MG/KG
METHOD: OECD TEST GUIDELINE 402
ASSESSMENT:
NO ADVERSE EFFECT HAS BEEN OBSERVED IN ACUTE DERMAL TOXICITY TESTS.
N-PHENYL-1-NAPHTHYLAMINE:
ACUTE ORAL TOXICITY:
LD50 (RAT, MALE): CA. 1,625 MG/KG
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >5,000 MG/KG
P-DODECYLPHENOL:
ACUTE ORAL TOXICITY:
LD50 (RAT): 2,100 MG/KG
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >5,000 MG/KG
SKIN CORROSION/IRRITATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
REMARKS: MAY CAUSE SKIN IRRITATION IN SUSCEPTIBLE PERSONS.
RESULT: REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
COMPONENTS:
C11-C14 BRANCHED ALKYL AMINE PHOSPHATE:
SPECIES: RABBIT
RESULT: IRRITATING TO SKIN
N-PHENYL-1-NAPHTHYLAMINE:
SPECIES: RABBIT
METHOD: OECD TEST GUIDELINE 404
RESULT: MILDLY IRRITATING TO SKIN
P-DODECYLPHENOL:
RESULT: IRRITATING TO SKIN
SERIOUS EYE DAMAGE/EYE IRRITATION:
NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
REMARKS:
VAPOURS MAY CAUSE IRRITATION TO THE EYES, RESPIRATORY SYSTEM AND THE SKIN.
COMPONENTS:
C11-C14 BRANCHED ALKYL AMINE PHOSPHATE:
SPECIES: RABBIT
RESULT: IRRITATING TO EYES
N-PHENYL-1-NAPHTHYLAMINE:
RESULT: MILDLY IRRITATING TO EYES
METHOD: OECD TEST GUIDELINE 405
P-DODECYLPHENOL:
RESULT: IRRITATING TO EYES
RESPIRATORY OR SKIN SENSITISATION:
SKIN SENSITISATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
RESPIRATORY SENSITISATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
C11-C14 BRANCHED ALKYL AMINE PHOSPHATE:
TEST TYPE: MAXIMISATION TEST (GPMT)
SPECIES: GUINEA PIG
METHOD: OECD TEST GUIDELINE 406
RESULT: DOES NOT CAUSE SKIN SENSITISATION.
N-PHENYL-1-NAPHTHYLAMINE:
TEST TYPE: MAXIMISATION TEST (GPMT)
SPECIES: GUINEA PIG
ASSESSMENT: MAY CAUSE SENSITISATION BY SKIN CONTACT.
METHOD: OECD TEST GUIDELINE 406
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
C11-C14 BRANCHED ALKYL AMINE PHOSPHATE:
GENOTOXICITY IN VITRO:
TEST TYPE: AMES TEST
TEST SPECIES: SALMONELLA TYPHIMURIUM
METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION
METHOD: OECD TEST GUIDELINE 471
RESULT: NEGATIVE
TEST SPECIES: CHINESE HAMSTER LUNG CELLS
METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION
METHOD: OECD TEST GUIDELINE 476
RESULT: NEGATIVE
CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
COMPONENTS:
P-DODECYLPHENOL:
REPRODUCTIVE TOXICITY - ASSESSMENT:
SUSPECTED OF DAMAGING FERTILITY., SOME EVIDENCE OF ADVERSE EFFECTS ON
SEXUAL FUNCTION AND FERTILITY, BASED ON ANIMAL EXPERIMENTS.
STOT - SINGLE EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT - REPEATED EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
N-PHENYL-1-NAPHTHYLAMINE:
EXPOSURE ROUTES: INGESTION
TARGET ORGANS: BLOOD
ASSESSMENT:
THE SUBSTANCE OR MIXTURE IS CLASSIFIED AS SPECIFIC TARGET ORGAN TOXICANT,
REPEATED EXPOSURE, CATEGORY 2.
ASPIRATION TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
FURTHER INFORMATION:
PRODUCT:
REMARKS: NO DATA AVAILABLE
CARCINOGENICITY:
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
PRODUCT:
TOXICITY TO FISH:
LC50 (FISH): 10 - 100 MG/L
COMPONENTS:
C11-C14 BRANCHED ALKYL AMINE PHOSPHATE:
TOXICITY TO FISH:
LC50 (ONCORHYNCHUS MYKISS (RAINBOW TROUT)): 5.5 MG/L
EXPOSURE TIME: 96 H
TEST TYPE: STATIC TEST
METHOD: OECD TEST GUIDELINE 203
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (DAPHNIA MAGNA (WATER FLEA)): >1 MG/L
EXPOSURE TIME: 48 H
TEST TYPE: STATIC TEST
METHOD: OECD TEST GUIDELINE 202
REMARKS: NO TOXICITY AT THE LIMIT OF SOLUBILITY
TOXICITY TO ALGAE:
EC50 (PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE)): >10 MG/L
EXPOSURE TIME: 72 H
TEST TYPE: STATIC TEST
METHOD: OECD TEST GUIDELINE 201
GLP: YES
NOEC (PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE)): 3.2 MG/L
EXPOSURE TIME: 72 H
TEST TYPE: STATIC TEST
METHOD: OECD TEST GUIDELINE 201
GLP: YES
N-PHENYL-1-NAPHTHYLAMINE:
TOXICITY TO FISH:
LC50 (ONCORHYNCHUS MYKISS (RAINBOW TROUT)): 0.44 - 0.74 MG/L
EXPOSURE TIME: 96 H
TEST TYPE: FLOW-THROUGH TEST
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (WATER FLEA (DAPHNIA MAGNA)): 0.3 - 0.68 MG/L
EXPOSURE TIME: 48 H
TEST TYPE: STATIC TEST
P-DODECYLPHENOL:
TOXICITY TO FISH:
LL50 (PIMEPHALES PROMELAS (FATHEAD MINNOW)): 40 MG/L
EXPOSURE TIME: 96 H
TEST SUBSTANCE: WAF
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (WATER FLEA (DAPHNIA MAGNA)): 0.037 MG/L
EXPOSURE TIME: 48 H
TOXICITY TO ALGAE:
EC50 (DESMODESMUS SUBSPICATUS (GREEN ALGAE)): 0.36 MG/L
END POINT: GROWTH INHIBITION
EXPOSURE TIME: 72 H
M-FACTOR (ACUTE AQUATIC TOXICITY): 10
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY):
NOEC (WATER FLEA (DAPHNIA MAGNA)): 0.002 MG/L
METHOD: OECD TEST GUIDELINE 211
M-FACTOR (CHRONIC AQUATIC TOXICITY): 10
PERSISTENCE AND DEGRADABILITY:
COMPONENTS:
C11-C14 BRANCHED ALKYL AMINE PHOSPHATE:
BIODEGRADABILITY:
RESULT: NOT READILY BIODEGRADABLE.
BIODEGRADATION: 13%
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301B
N-PHENYL-1-NAPHTHYLAMINE:
BIODEGRADABILITY:
RESULT: NOT READILY BIODEGRADABLE.
BIODEGRADATION: 0 %
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301C
P-DODECYLPHENOL:
BIODEGRADABILITY:
RESULT: NOT READILY BIODEGRADABLE.
BIOACCUMULATIVE POTENTIAL:
COMPONENTS:
C11-C14 BRANCHED ALKYL AMINE PHOSPHATE:
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: 1.5 - 2.3
METHOD: OECD TEST GUIDELINE 117
GLP: YES
N-PHENYL-1-NAPHTHYLAMINE:
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: 4.20
P-DODECYLPHENOL:
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: 6.58
MOBILITY IN SOIL:
COMPONENTS: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
PRODUCT:
ADDITIONAL ECOLOGICAL INFORMATION:
AN ENVIRONMENTAL HAZARD CANNOT BE EXCLUDED IN THE EVENT OF UNPROFESSIONAL
HANDLING OR DISPOSAL., TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
COMPONENTS:
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
GENERAL ADVICE:
THE PRODUCT SHOULD NOT BE ALLOWED TO ENTER DRAINS, WATER COURSES OR THE
SOIL.
DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED
CONTAINER.
SEND TO A LICENSED WASTE MANAGEMENT COMPANY.
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY REMAINING CONTENTS.
DISPOSE OF AS UNUSED PRODUCT.
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
DO NOT RE-USE EMPTY CONTAINERS.
| SECTION 14. TRANSPORT INFORMATION | |
INTERNATIONAL TRANSPORT REGULATIONS:
REGULATION:
ID NUMBER PROPER SHIPPING *HAZARD SUBSIDIARY PACKING MARINE
NAME CLASS HAZARDS GROUP POLLUTANT /
LTD. QTY.
U.S. DOT - ROAD: NOT DANGEROUS GOODS
U.S. DOT - RAIL: NOT DANGEROUS GOODS
U.S. DOT - INLAND WATERWAYS: NOT DANGEROUS GOODS
TRANSPORT CANADA - ROAD: NOT DANGEROUS GOODS
TRANSPORT CANADA - RAIL: NOT DANGEROUS GOODS
TRANSPORT CANADA - INLAND WATERWAYS:
NOT DANGEROUS GOODS
INTERNATIONAL MARITIME DANGEROUS GOODS: MARINE
NOT DANGEROUS GOODS POLLUTANT:
(PARA-
DODECYLPHENOL,
N-PHENYL-1-
NAPHTHYLAMINE)
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO:
NOT DANGEROUS GOODS
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER:
NOT DANGEROUS GOODS
MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS
MATERIALS AND WASTES: NOT DANGEROUS GOODS
*ORM = ORM-D
CBL = COMBUSTIBLE LIQUID
MARINE POLLUTANT: YES
DANGEROUS GOODS DESCRIPTIONS (IF INDICATED ABOVE) MAY NOT REFLECT QUANTITY,
END-USE OR REGION-SPECIFIC EXCEPTIONS THAT CAN BE APPLIED. CONSULT SHIPPING
DOCUMENTS FOR DESCRIPTIONS THAT ARE SPECIFIC TO THE SHIPMENT.
| SECTION 15. REGULATORY INFORMATION | |
SARA 311/312 HAZARDS:
ACUTE HEALTH HAZARD
CHRONIC HEALTH HAZARD
SARA 313 COMPONENT(S)SARA 313:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN
CAS NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS
ESTABLISHED BY SARA TITLE III, SECTION 313.
CALIFORNIA PROP 65:
PROPOSITION 65 WARNINGS ARE NOT REQUIRED FOR THIS PRODUCT BASED ON THE
RESULTS OF A RISK ASSESSMENT.
THE COMPONENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES:
TSCA: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
PICCS: NOT IN COMPLIANCE WITH THE INVENTORY
IECSC: NOT IN COMPLIANCE WITH THE INVENTORY
NZIOC: NOT IN COMPLIANCE WITH THE INVENTORY
KECL: NOT IN COMPLIANCE WITH THE INVENTORY
ENCS: NOT IN COMPLIANCE WITH THE INVENTORY
AUSTR: NOT IN COMPLIANCE WITH THE INVENTORY
DSL: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
INVENTORIES:
AICS (AUSTRALIA), DSL (CANADA), IECSC (CHINA), REACH (EUROPEAN UNION),
ENCS (JAPAN), ISHL (JAPAN), KECI (KOREA), NZIOC (NEW ZEALAND), PICCS
(PHILIPPINES), TSCA (USA)
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
REVISION DATE: 05/22/2015
NFPA:
HEALTH 0
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARD.
HMIS III:
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
0 = NOT SIGNIFICANT
1 = SLIGHT
2 = MODERATE
3 = HIGH
4 = EXTREME
* = CHRONIC
NFPA FLAMMABLE AND COMBUSTIBLE LIQUIDS CLASSIFICATION:
COMBUSTIBLE LIQUID CLASS IIIB
FULL TEXT OF H-STATEMENTS REFERRED TO UNDER SECTIONS 2 AND 3.
H302: HARMFUL IF SWALLOWED.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H319: CAUSES SERIOUS EYE IRRITATION.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
H373:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE IF
SWALLOWED.
SOURCES OF KEY DATA USED TO COMPILE THE SAFETY DATA SHEET
ASHLAND INTERNAL DATA INCLUDING OWN AND SPONSORED TEST REPORTS
THE UNECE ADMINISTERS REGIONAL AGREEMENTS IMPLEMENTING HARMONISED
CLASSIFICATION FOR LABELLING (GHS) AND TRANSPORT.
THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT
WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS
ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT,
APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. THIS SDS HAS BEEN
PREPARED BY ASHLAND'S ENVIRONMENTAL HEALTH AND SAFETY DEPARTMENT
(1-800-325-3751).
LIST OF ABBREVIATIONS AND ACRONYMS THAT COULD BE, BUT NOT NECESSARILY ARE,
USED IN THIS SAFETY DATA SHEET:
ACGIH: AMERICAN CONFERENCE OF INDUSTRIAL HYGIENISTS
BEI: BIOLOGICAL EXPOSURE INDEX
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY).
CMR: CARCINOGENIC, MUTAGENIC OR TOXIC FOR REPRODUCTION
FG: FOOD GRADE
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS.
H-STATEMENT: HAZARD STATEMENT
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION.
IATA-DGR:
DANGEROUS GOODS REGULATION BY THE "INTERNATIONAL AIR TRANSPORT
ASSOCIATION" (IATA).
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
ICAO-TI (ICAO):
TECHNICAL INSTRUCTIONS BY THE "INTERNATIONAL CIVIL AVIATION ORGANIZATION"
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
ISO: INTERNATIONAL ORGANIZATION FOR STANDARDIZATION
LOGPOW: OCTANOL-WATER PARTITION COEFFICIENT
LCXX: LETHAL CONCENTRATION, FOR XX PERCENT OF TEST POPULATION
LDXX: LETHAL DOSE, FOR XX PERCENT OF TEST POPULATION.
ICXX: INHIBITORY CONCENTRATION FOR XX OF A SUBSTANCE
ECXX: EFFECTIVE CONCENTRATION OF XX
N.O.S.: NOT OTHERWISE SPECIFIED
OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
OEL: OCCUPATIONAL EXPOSURE LIMIT
P-STATEMENT: PRECAUTIONARY STATEMENT
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
PPE: PERSONAL PROTECTIVE EQUIPMENT
STEL: SHORT-TERM EXPOSURE LIMIT
STOT: SPECIFIC TARGET ORGAN TOXICITY
TLV: THRESHOLD LIMIT VALUE
TWA: TIME-WEIGHTED AVERAGE
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
WEL: WORKPLACE EXPOSURE LEVEL
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
DOT: DEPARTMENT OF TRANSPORTATION
FIFRA: FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT
HMIRC: HAZARDOUS MATERIALS INFORMATION REVIEW COMMISSION
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PMRA: HEALTH CANADA PEST MANAGEMENT REGULATORY AGENCY
RTK: RIGHT TO KNOW
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM