| Common Name: | WYE RESIN SPLICE KIT 90-B1, WITH SCOTCHCAST RESIN 4 |
| Manufacturer: | 3M |
| SDS Revision Date: | 2/3/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 4NU57 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) WYE RESIN SPLICE KIT 90-B1, WITH 3M(TM) SCOTCHCAST(TM) RESIN 4
02/03/16
3M
SAFETY DATA SHEET
COPYRIGHT, 2016, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 08-4956-2
VERSION NUMBER: 5.01
ISSUE DATE: 02/03/16
SUPERCEDES DATE: 07/09/14
PRODUCT IDENTIFIER:
3M(TM) WYE RESIN SPLICE KIT 90-B1, WITH 3M(TM) SCOTCHCAST(TM) RESIN 4
ID NUMBER(S): 80-6109-8161-7
RECOMMENDED USE:
ELECTRICAL, REINSULATING SPLICES ON POWER DISTRIBUTION CABLE
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: ELECTRICAL MARKETS DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH OF
THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET.
THE DOCUMENT NUMBERS FOR COMPONENTS OF THIS PRODUCT ARE:
24-9848-3, 24-9869-9
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
SCOTCHCAST RESIN 4 PART A
02/19/14
3M
SAFETY DATA SHEET
COPYRIGHT, 2014, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 24-9848-3
VERSION NUMBER: 2.00
ISSUE DATE: 02/19/14
SUPERCEDES DATE: 04/07/11
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: SCOTCHCAST RESIN 4 PART A
PRODUCT IDENTIFICATION NUMBERS:
LH-A100-0560-7, LH-A100-0560-8, LH-A100-0560-9, LH-A100-0561-0,
LH-A100-0561-1, LH-A100-0561-2
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ELECTRICAL, PART A OF RESIN 4
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: ELECTRICAL MARKETS DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2B.
SKIN SENSITIZER: CATEGORY 1A
2.2. LABEL ELEMENTS:
SIGNAL WORD: WARNING
SYMBOLS: EXCLAMATION MARK
PICTOGRAMS: EXCLAMATION MARK
HAZARD STATEMENTS:
CAUSES EYE IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
2,2-BIS(P-HYDROXYPHENYL)PROPANE 25085-99-8 80 - 100 TRADE SECRET *
DIGLYCIDYL ETHER POLYMER
OXIRANE, MONO[(C12-14- 68609-97-2 0 - 20 TRADE SECRET *
ALKYLOXY)METHYL]DERIVATIVES
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
TOXIC VAPOR, GAS, PARTICULATE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO UNUSUAL FIRE OR EXPLOSION HAZARDS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR SPILLS IN CONFINED
SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR EXHAUST VAPORS, IN
ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON
SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE
ALLOWED OUT OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
NO SPECIAL STORAGE REQUIREMENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
NO OCCUPATIONAL EXPOSURE LIMIT VALUES EXIST FOR ANY OF THE COMPONENTS
LISTED IN SECTION 3 OF THIS SDS.
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT. THE FOLLOWING
PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED: APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: RESIN
ODOR, COLOR, GRADE: CLEAR, AMBER RESIN WITH EPOXY ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: >=201 DEG. F
FLASH POINT: >=201 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS (LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS (UEL): NO DATA AVAILABLE
VAPOR PRESSURE: <=27 PSIA [@ 131 DEG. F]
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.16 G/ML
SPECIFIC GRAVITY: 1.16 [REF STD: WATER=1]
SOLUBILITY IN WATER: NEGLIGIBLE
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/ WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 3,000 CENTIPOISE - 5,000 CENTIPOISE
AVERAGE PARTICLE SIZE: NO DATA AVAILABLE
BULK DENSITY: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS: NO DATA AVAILABLE
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS: NO DATA AVAILABLE
PERCENT VOLATILE: NEGLIGIBLE
SOFTENING POINT: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS: NO DATA AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL IS CONSIDERED TO BE NON REACTIVE UNDER NORMAL USE CONDITIONS.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS:
NONE KNOWN.
NO DATA AVAILABLE
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION: NO HEALTH EFFECTS ARE EXPECTED.
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
MODERATE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED OR
HAZY VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
2,2-BIS(P-HYDROXYPHENYL)PROPANE DERMAL RAT LD50: >1,600 MG/KG
DIGLYCIDYL ETHER POLYMER
2,2-BIS(P-HYDROXYPHENYL)PROPANE INGESTION RAT LD50: >1,000 MG/KG
DIGLYCIDYL ETHER POLYMER
OXIRANE, MONO[(C12-14- DERMAL RABBIT LD50: >4,000 MG/KG
ALKYLOXY)METHYL]DERIVATIVES
OXIRANE, MONO[(C12-14- INGESTION RAT LD50: 17,100 MG/KG
ALKYLOXY)METHYL]DERIVATIVES
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
2,2-BIS(P-HYDROXYPHENYL)PROPANE RABBIT MILD IRRITANT
DIGLYCIDYL ETHER POLYMER
OXIRANE, MONO[(C12-14-ALKYLOXY) RABBIT MILD IRRITANT
METHYL]DERIVATIVES
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
2,2-BIS(P-HYDROXYPHENYL)PROPANE RABBIT MODERATE IRRITANT
DIGLYCIDYL ETHER POLYMER
OXIRANE, MONO[(C12-14-ALKYLOXY) RABBIT MILD IRRITANT
METHYL]DERIVATIVES
SKIN SENSITIZATION:
NAME SPECIES VALUE
2,2-BIS(P-HYDROXYPHENYL)PROPANE HUMAN SENSITIZING
DIGLYCIDYL ETHER POLYMER AND
ANIMAL
OXIRANE, MONO[(C12-14-ALKYLOXY) GUINEA SENSITIZING
METHYL]DERIVATIVES PIG
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
2,2-BIS(P-HYDROXYPHENYL)PROPANE HUMAN SOME POSITIVE DATA
DIGLYCIDYL ETHER POLYMER EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
2,2-BIS(P-HYDROXYPHENYL)PROPANE IN VIVO NOT MUTAGENIC
DIGLYCIDYL ETHER POLYMER
2,2-BIS(P-HYDROXYPHENYL)PROPANE IN VITRO SOME POSITIVE DATA
DIGLYCIDYL ETHER POLYMER EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
OXIRANE, MONO[(C12-14-ALKYLOXY) IN VIVO NOT MUTAGENIC
METHYL]DERIVATIVES
OXIRANE, MONO[(C12-14-ALKYLOXY) IN VITRO SOME POSITIVE DATA
METHYL]DERIVATIVES EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
2,2-BIS(P-HYDROXYPHENYL) DERMAL MOUSE SOME POSITIVE DATA
PROPANE DIGLYCIDYL EXIST, BUT THE DATA ARE
ETHER POLYMER NOT SUFFICIENT FOR
CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
2,2-BIS(P-HYDROXYPHENYL)PROPANE INGESTION NOT TOXIC TO FEMALE
DIGLYCIDYL ETHER POLYMER REPRODUCTION
2,2-BIS(P-HYDROXYPHENYL)PROPANE INGESTION NOT TOXIC TO MALE
DIGLYCIDYL ETHER POLYMER REPRODUCTION
2,2-BIS(P-HYDROXYPHENYL)PROPANE DERMAL NOT TOXIC TO DEVELOPMENT
DIGLYCIDYL ETHER POLYMER
2,2-BIS(P-HYDROXYPHENYL)PROPANE INGESTION NOT TOXIC TO DEVELOPMENT
DIGLYCIDYL ETHER POLYMER
OXIRANE, MONO[(C12-14- DERMAL NOT TOXIC TO MALE
ALKYLOXY)METHYL]DERIVATIVES REPRODUCTION
OXIRANE, MONO[(C12-14- DERMAL NOT TOXIC TO DEVELOPMENT
ALKYLOXY)METHYL]DERIVATIVES
NAME SPECIES TEST RESULT EXPOSURE DURATION
2,2-BIS(P-HYDROXYPHENYL) RAT NOAEL: 2 GENERATION
PROPANE DIGLYCIDYL ETHER 750 MG/KG/DAY
POLYMER
2,2-BIS(P-HYDROXYPHENYL) RAT NOAEL: 2 GENERATION
PROPANE DIGLYCIDYL ETHER 750 MG/KG/DAY
POLYMER
2,2-BIS(P-HYDROXYPHENYL) RABBIT NOAEL: DURING
PROPANE DIGLYCIDYL ETHER 300 MG/KG/DAY ORGANOGENESIS
POLYMER
2,2-BIS(P-HYDROXYPHENYL) RAT NOAEL: 2 GENERATION
PROPANE DIGLYCIDYL ETHER 750 MG/KG/DAY
POLYMER
OXIRANE, MONO[(C12-14- RABBIT NOAEL: 24 HOURS
ALKYLOXY)METHYL] 4,000 MG/KG
DERIVATIVES
OXIRANE, MONO[(C12-14- RAT NOAEL: DURING
ALKYLOXY)METHYL] 200 MG/KG/DAY ORGANOGENESIS
DERIVATIVES
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
OXIRANE, MONO[(C12- DERMAL HEART ALL DATA ARE
14-ALKYLOXY)METHYL] BLOOD NEGATIVE
DERIVATIVES LIVER
NERVOUS SYSTEM
KIDNEY AND/OR
BLADDER
NAME SPECIES TEST RESULT EXPOSURE DURATION
OXIRANE, MONO[(C12- RABBIT NOAEL: 4,000 MG/KG 24 HOURS
14-ALKYLOXY)METHYL]
DERIVATIVES
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
2,2-BIS(P- DERMAL LIVER SOME POSITIVE DATA
HYDROXYPHENYL)PROPANE EXIST, BUT THE DATA
DIGLYCIDYL ETHER POLYMER ARE NOT SUFFICIENT
FOR CLASSIFICATION
2,2-BIS(P- DERMAL NERVOUS SYSTEM ALL DATA ARE
HYDROXYPHENYL)PROPANE NEGATIVE
DIGLYCIDYL ETHER POLYMER
2,2-BIS(P- INGESTION AUDITORY SYSTEM ALL DATA ARE
HYDROXYPHENYL)PROPANE HEART NEGATIVE
DIGLYCIDYL ETHER POLYMER ENDOCRINE SYSTEM
HEMATOPOIETIC
SYSTEM
LIVER
EYES
KIDNEY AND/OR
BLADDER
OXIRANE, MONO[(C12- DERMAL NERVOUS SYSTEM SOME POSITIVE DATA
14-ALKYLOXY)METHYL] EXIST, BUT THE DATA
DERIVATIVES ARE NOT SUFFICIENT
FOR CLASSIFICATION
OXIRANE, MONO[(C12- DERMAL RESPIRATORY ALL DATA ARE
14-ALKYLOXY)METHYL] SYSTEM NEGATIVE
DERIVATIVES
OXIRANE, MONO[(C12- DERMAL BLOOD ALL DATA ARE
14-ALKYLOXY)METHYL] LIVER NEGATIVE
DERIVATIVES EYES
KIDNEY AND/OR
BLADDER
NAME SPECIES TEST RESULT EXPOSURE DURATION
2,2-BIS(P- RAT NOAEL: 2 YEARS
HYDROXYPHENYL)PROPANE 1,000 MG/KG/DAY
DIGLYCIDYL ETHER POLYMER
2,2-BIS(P- RAT NOAEL: 13 WEEKS
HYDROXYPHENYL)PROPANE 1,000 MG/KG/DAY
DIGLYCIDYL ETHER POLYMER
2,2-BIS(P- RAT NOAEL: 28 DAYS
HYDROXYPHENYL)PROPANE 1,000 MG/KG/DAY
DIGLYCIDYL ETHER POLYMER
OXIRANE, MONO[(C12- RAT NOAEL: 14 WEEKS
14-ALKYLOXY)METHYL] 100 MG/KG/DAY
DERIVATIVES
OXIRANE, MONO[(C12- RAT NOAEL: 14 WEEKS
14-ALKYLOXY)METHYL] 100 MG/KG/DAY
DERIVATIVES
OXIRANE, MONO[(C12- RAT NOAEL: 13 WEEKS
14-ALKYLOXY)METHYL] 100 MG/KG/DAY
DERIVATIVES
ASPIRATION HAZARD:
NAME VALUE
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION
MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
AUSTRALIA NATIONAL INDUSTRIAL CHEMICAL NOTIFICATION AND ASSESSMENT SCHEME
(NICNAS). CERTAIN RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR
ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE NEW SUBSTANCE
NOTIFICATION REQUIREMENTS OF CEPA.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE CHINA "MEASURES
ON ENVIRONMENTAL MANAGEMENT OF NEW CHEMICAL SUBSTANCE". CERTAIN
RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR ADDITIONAL
INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
THE KOREAN TOXIC CHEMICAL CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
PHILIPPINES RA 6969 REQUIREMENTS. CERTAIN RESTRICTIONS MAY APPLY. CONTACT
THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
HMIS HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) III) HAZARD RATINGS ARE
DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE. THESE
RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL UNDER EXPECTED
CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE IN EMERGENCY
SITUATIONS. HMIS(R*) III RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED
HMIS(R*) III PROGRAM. HMIS(R*) IS A REGISTERED MARK OF THE AMERICAN
COATINGS ASSOCIATION (ACA).
DOCUMENT GROUP: 24-9848-3
VERSION NUMBER: 2.00
ISSUE DATE: 02/19/14
SUPERCEDES DATE: 04/07/11
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
SCOTCHCAST RESIN 4 PART B
10/31/14
3M
SAFETY DATA SHEET
COPYRIGHT, 2014, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 24-9869-9
VERSION NUMBER: 5.00
ISSUE DATE: 10/31/14
SUPERCEDES DATE: 02/14/14
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER: SCOTCHCAST RESIN 4 PART B
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ELECTRICAL, PART B OF RESIN 4
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: ELECTRICAL MARKETS DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
ACUTE TOXICITY (ORAL): CATEGORY 4.
ACUTE TOXICITY (DERMAL): CATEGORY 4.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 1B.
RESPIRATORY SENSITIZER: CATEGORY 1.
SKIN SENSITIZER: CATEGORY 1B.
REPRODUCTIVE TOXICITY: CATEGORY 2.
CARCINOGENICITY: CATEGORY 2.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
HARMFUL IF SWALLOWED.
HARMFUL IN CONTACT WITH SKIN.
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE AN ALLERGIC SKIN REACTION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SUSPECTED OF CAUSING CANCER.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
MAY CAUSE CHEMICAL GASTROINTESTINAL BURNS.
44% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
44% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
PHENOL, 4-NONYL-, BRANCHED 84852-15-3 15 - 40 TRADE SECRET *
N-AMINOETHYLPIPERAZINE 140-31-8 5 - 20 TRADE SECRET *
REACTION PRODUCTS WITH TRADE SECRET* 5 - 20 TRADE SECRET *
TRIETHYLENETETRAMINE
HEAVY NAPHTHENIC DISTILLATE 64742-11-6 5 - 20 TRADE SECRET *
SOLVENT PETROLEUM EXTRACTS
REACTION PRODUCTS WITH TETA TRADE SECRET* 4 - 10 TRADE SECRET *
AND DGEBA
REACTION PRODUCTS WITH ETHER TRADE SECRET* 1 - 6 TRADE SECRET *
PETROLEUM DISTILLATES TRADE SECRET* 1 - 6 TRADE SECRET *
TRIS(2,4,6-DIMETHYLAMINOMONO- 90-72-2 1 - 5 TRADE SECRET *
METHYL)PHENOL
TRIETHYLENETETRAMINE 112-24-3 1 - 3 TRADE SECRET *
CARBON BLACK 1333-86-4 <1 TRADE SECRET *
DIETHYLENETRIAMINE 111-40-0 0 - 0.2 TRADE SECRET *
(2-AMINOETHYL)ETHANOLAMINE 111-41-1 0 - 0.12 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTAMINATED CLOTHING. GET IMMEDIATE MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
AMINE COMPOUNDS DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. REFER TO OTHER SECTIONS
OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT USE IN A CONFINED AREA WITH MINIMAL AIR EXCHANGE. DO NOT HANDLE
UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE. USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES,
RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE AWAY
FROM ACIDS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
DIETHYLENETRIAMINE 111-40-0 ACGIH TWA: 1 PPM SKIN NOTATION
TRIETHYLENETETRAMINE 112-24-3 AIHA TWA: SKIN NOTATION
6 MG/M3 (1 PPM)
CARBON BLACK 1333-86-4 ACGIH TWA (INHALABLE A3:
FRACTION): CONFIRMED
3 MG/M3 ANIMAL
CARCIN.
CARBON BLACK 1333-86-4 CMRG TWA: 0.5 MG/M3
CARBON BLACK 1333-86-4 OSHA TWA: 3.5 MG/M3
TRIS(2,4,6- 90-72-2 CMRG TWA: 5 PPM
DIMETHYLAMINOMONO-
METHYL)PHENOL
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: FULL FACE SHIELD INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT. THE FOLLOWING
PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED: APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE SUPPLIED-AIR RESPIRATOR
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: RESIN
ODOR, COLOR, GRADE: SMOOTH, BLACK LIQUID WITH AMINE ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
BOILING POINT: >=200 DEG. F
FLASH POINT: >=200 DEG. F [TEST METHOD: CLOSED CUP]
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS (LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS (UEL): NO DATA AVAILABLE
VAPOR PRESSURE: <=27 PSIA [@ 131 DEG. F]
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.04 G/ML
SPECIFIC GRAVITY: 1.04 [REF STD: WATER=1]
SOLUBILITY IN WATER: NEGLIGIBLE
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/ WATER: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 2,200 CENTIPOISE - 3,500 CENTIPOISE
AVERAGE PARTICLE SIZE: NO DATA AVAILABLE
BULK DENSITY: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS: NO DATA AVAILABLE
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS: NO DATA AVAILABLE
PERCENT VOLATILE: 3% - 5%
SOFTENING POINT: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS: NO DATA AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL IS CONSIDERED TO BE NON REACTIVE UNDER NORMAL USE CONDITIONS.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS:
NONE KNOWN.
NO DATA AVAILABLE
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
ALLERGIC RESPIRATORY REACTION:
SIGNS/SYMPTOMS MAY INCLUDE DIFFICULTY BREATHING, WHEEZING, COUGH, AND
TIGHTNESS OF CHEST.
SKIN CONTACT:
HARMFUL IN CONTACT WITH SKIN. CORROSIVE (SKIN BURNS):
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, INTENSE
PAIN, BLISTERING, ULCERATION, AND TISSUE DESTRUCTION.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION:
HARMFUL IF SWALLOWED. GASTROINTESTINAL CORROSION:
SIGNS/SYMPTOMS MAY INCLUDE SEVERE MOUTH, THROAT AND ABDOMINAL PAIN; NAUSEA;
VOMITING; AND DIARRHEA; BLOOD IN THE FECES AND/OR VOMITUS MAY ALSO BE SEEN.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
CARCINOGENICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT C.A.S. NO. CLASS DESCRIPTION REGULATION
CARBON BLACK 1333-86-4 GRP. 2B: INTERNATIONAL AGENCY
POSSIBLE HUMAN CARC. FOR RESEARCH ON CANCER
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
1,000 - 2,000 MG/KG
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
300 - 2,000 MG/KG
PHENOL, 4-NONYL-, BRANCHED DERMAL RABBIT LD50: >2,000 MG/KG
PHENOL, 4-NONYL-, BRANCHED INGESTION RAT LD50: 1,531 MG/KG
N-AMINOETHYLPIPERAZINE DERMAL RABBIT LD50: 865 MG/KG
N-AMINOETHYLPIPERAZINE INGESTION RAT LD50: 1,470 MG/KG
TRIS(2,4,6-DIMETHYLAMINO- DERMAL RAT LD50: 1,280 MG/KG
MONOMETHYL)PHENOL
TRIS(2,4,6-DIMETHYLAMINO- INGESTION RAT LD50: 1,000 MG/KG
MONOMETHYL)PHENOL
TRIETHYLENETETRAMINE DERMAL RABBIT LD50: 550 MG/KG
TRIETHYLENETETRAMINE INGESTION RAT LD50: 2,500 MG/KG
DIETHYLENETRIAMINE DERMAL RABBIT LD50: 1,045 MG/KG
DIETHYLENETRIAMINE INGESTION RAT LD50: 819 MG/KG
CARBON BLACK DERMAL RABBIT LD50: >3,000 MG/KG
CARBON BLACK INGESTION RAT LD50: >8,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
PHENOL, 4-NONYL-, BRANCHED RABBIT CORROSIVE
N-AMINOETHYLPIPERAZINE RABBIT CORROSIVE
TRIS(2,4,6-DIMETHYLAMINOMONOMETHYL)PHENOL RABBIT CORROSIVE
TRIETHYLENETETRAMINE RABBIT CORROSIVE
DIETHYLENETRIAMINE RABBIT CORROSIVE
CARBON BLACK RABBIT NO SIGNIFICANT
IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
PHENOL, 4-NONYL-, BRANCHED RABBIT CORROSIVE
N-AMINOETHYLPIPERAZINE RABBIT CORROSIVE
TRIS(2,4,6-DIMETHYLAMINOMONOMETHYL)PHENOL RABBIT CORROSIVE
TRIETHYLENETETRAMINE RABBIT CORROSIVE
DIETHYLENETRIAMINE RABBIT CORROSIVE
CARBON BLACK RABBIT NO SIGNIFICANT
IRRITATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
PHENOL, 4-NONYL-, BRANCHED GUINEA NOT SENSITIZING
PIG
N-AMINOETHYLPIPERAZINE GUINEA SENSITIZING
PIG
TRIS(2,4,6-DIMETHYLAMINOMONOMETHYL)PHENOL GUINEA SOME POSITIVE DATA
PIG EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TRIETHYLENETETRAMINE GUINEA SENSITIZING
PIG
DIETHYLENETRIAMINE GUINEA SENSITIZING
PIG
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
DIETHYLENETRIAMINE HUMAN SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
PHENOL, 4-NONYL-, BRANCHED IN VITRO NOT MUTAGENIC
PHENOL, 4-NONYL-, BRANCHED IN VIVO NOT MUTAGENIC
N-AMINOETHYLPIPERAZINE IN VIVO NOT MUTAGENIC
N-AMINOETHYLPIPERAZINE IN VITRO SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TRIS(2,4,6-DIMETHYLAMINOMONOMETHYL)PHENOL IN VITRO NOT MUTAGENIC
DIETHYLENETRIAMINE IN VITRO NOT MUTAGENIC
CARBON BLACK IN VITRO NOT MUTAGENIC
CARBON BLACK IN VIVO SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
DIETHYLENETRIAMINE DERMAL MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
CARBON BLACK DERMAL MOUSE NOT CARCINOGENIC
CARBON BLACK INGESTION MOUSE NOT CARCINOGENIC
CARBON BLACK INHALATION RAT CARCINOGENIC
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
PHENOL, 4-NONYL-, BRANCHED INGESTION SOME POSITIVE MALE
REPRODUCTIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
PHENOL, 4-NONYL-, BRANCHED INGESTION TOXIC TO FEMALE REPRODUCTION
PHENOL, 4-NONYL-, BRANCHED INGESTION TOXIC TO DEVELOPMENT
N-AMINOETHYLPIPERAZINE INGESTION NOT TOXIC TO FEMALE
REPRODUCTION
N-AMINOETHYLPIPERAZINE INGESTION NOT TOXIC TO MALE
REPRODUCTION
N-AMINOETHYLPIPERAZINE INGESTION NOT TOXIC TO DEVELOPMENT
DIETHYLENETRIAMINE INGESTION NOT TOXIC TO MALE
REPRODUCTION
DIETHYLENETRIAMINE INGESTION NOT TOXIC TO DEVELOPMENT
DIETHYLENETRIAMINE INGESTION SOME POSITIVE FEMALE
REPRODUCTIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE
DURATION
PHENOL, 4-NONYL-, BRANCHED RAT NOAEL: 28 DAYS
400 MG/KG/DAY
PHENOL, 4-NONYL-, BRANCHED OFFICIAL NOAEL:
CLASSIFICATION NOT AVAILABLE
PHENOL, 4-NONYL-, BRANCHED OFFICIAL NOAEL:
CLASSIFICATION NOT AVAILABLE
N-AMINOETHYLPIPERAZINE RAT NOAEL: PREMATING &
598 MG/KG/DAY DURING GESTATION
N-AMINOETHYLPIPERAZINE RAT NOAEL: 32 DAYS
409 MG/KG/DAY
N-AMINOETHYLPIPERAZINE RAT NOAEL: PREMATING &
899 MG/KG/DAY DURING GESTATION
DIETHYLENETRIAMINE RAT NOAEL: 28 DAYS
300 MG/KG/DAY
DIETHYLENETRIAMINE RAT NOAEL: PREMATING &
300 MG/KG/DAY DURING GESTATION
DIETHYLENETRIAMINE RAT NOAEL: PREMATING &
30 MG/KG/DAY DURING GESTATION
LACTATION:
NAME ROUTE SPECIES VALUE
PHENOL, 4-NONYL-, BRANCHED INGESTION RAT DOES NOT CAUSE EFFECTS
ON OR VIA LACTATION
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
N-AMINOETHYLPIPERAZINE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TRIS(2,4,6- INHALATION RESPIRATORY SOME POSITIVE DATA
DIMETHYLAMINOMON- IRRITATION EXIST, BUT THE DATA
OMETHYL)PHENOL ARE NOT SUFFICIENT
FOR CLASSIFICATION
DIETHYLENETRIAMINE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
N-AMINOETHYLPIPERAZINE NOAEL:
NOT AVAILABLE
TRIS(2,4,6- NOAEL:
DIMETHYLAMINOMON- NOT AVAILABLE
OMETHYL)PHENOL
DIETHYLENETRIAMINE NOAEL:
NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
PHENOL, 4-NONYL-, INGESTION ENDOCRINE SYSTEM SOME POSITIVE DATA
BRANCHED HEMATOPOIETIC EXIST, BUT THE DATA
SYSTEM ARE NOT SUFFICIENT
LIVER FOR CLASSIFICATION
PHENOL, 4-NONYL-, INGESTION KIDNEY AND/OR SOME POSITIVE DATA
BRANCHED BLADDER EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
PHENOL, 4-NONYL-, INGESTION HEART ALL DATA ARE
BRANCHED BONE, TEETH, NEGATIVE
NAILS, AND/OR HAIR
IMMUNE SYSTEM
MUSCLES
NERVOUS SYSTEM
RESPIRATORY SYSTEM
N-AMINOETHYLPIPERAZINE INGESTION HEART ALL DATA ARE
ENDOCRINE SYSTEM NEGATIVE
HEMATOPOIETIC
SYSTEM
LIVER
NERVOUS SYSTEM
KIDNEY AND/OR
BLADDER
TRIS(2,4,6- DERMAL SKIN SOME POSITIVE DATA
DIMETHYLAMINOMON- LIVER EXIST, BUT THE DATA
OMETHYL)PHENOL NERVOUS SYSTEM ARE NOT SUFFICIENT
FOR CLASSIFICATION
TRIS(2,4,6- DERMAL AUDITORY SYSTEM ALL DATA ARE
DIMETHYLAMINOMON- HEMATOPOIETIC NEGATIVE
OMETHYL)PHENOL SYSTEM
EYES
DIETHYLENETRIAMINE INGESTION ENDOCRINE SYSTEM SOME POSITIVE DATA
LIVER EXIST, BUT THE DATA
KIDNEY AND/OR ARE NOT SUFFICIENT
BLADDER FOR CLASSIFICATION
CARBON BLACK INHALATION PNEUMOCONIOSIS SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
PHENOL, 4-NONYL-, RAT NOAEL: 400 MG/KG/DAY 28 DAYS
BRANCHED
PHENOL, 4-NONYL-, RAT NOAEL: 150 MG/KG/DAY 90 DAYS
BRANCHED
PHENOL, 4-NONYL-, RAT NOAEL: 150 MG/KG/DAY 90 DAYS
BRANCHED
N-AMINOETHYLPIPERAZINE RAT NOAEL: 598 MG/KG/DAY 28 DAYS
TRIS(2,4,6- RAT NOAEL: 125 MG/KG/DAY 28 DAYS
DIMETHYLAMINOMON-
OMETHYL)PHENOL
TRIS(2,4,6- RAT NOAEL: 125 MG/KG/DAY 28 DAYS
DIMETHYLAMINOMON-
OMETHYL)PHENOL
DIETHYLENETRIAMINE RAT NOAEL: 90 DAYS
1,210 MG/KG/DAY
CARBON BLACK HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
EXPOSURE
ASPIRATION HAZARD:
NAME VALUE
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE UNCURED PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY.
PROPER DESTRUCTION MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING
INCINERATION PROCESSES. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL SUBSTANCES/
MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
THIS MATERIAL CONTAINS A CHEMICAL WHICH REQUIRES EXPORT NOTIFICATION UNDER
TSCA SECTION 12[B]:
INGREDIENT (CATEGORY C.A.S. NO REGULATION STATUS
IF APPLICABLE)
PHENOL, 4-NONYL-, BRANCHED 84852-15-3 TOXIC SUBSTANCES PROPOSED
CONTROL ACT (TSCA) 5
SNUR OR CONSENT ORDER
CHEMICALS
THIS MATERIAL CONTAINS A CHEMICAL SUBJECT TO A PROPOSED EPA SIGNIFICANT NEW
USE RULE (TSCA SECTION 5):
INGREDIENT (CATEGORY IF APPLICABLE) C.A.S. NO REFERENCE
PHENOL, 4-NONYL-, BRANCHED 84852-15-3 79 FR 59186
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
HMIS HAZARD CLASSIFICATION:
HEALTH 3*
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) III) HAZARD RATINGS ARE
DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE. THESE
RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL UNDER EXPECTED
CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE IN EMERGENCY
SITUATIONS. HMIS(R*) III RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED
HMIS(R*) III PROGRAM. HMIS(R*) IS A REGISTERED MARK OF THE AMERICAN
COATINGS ASSOCIATION (ACA).
DOCUMENT GROUP: 24-9869-9
VERSION NUMBER: 5.00
ISSUE DATE: 10/31/14
SUPERCEDES DATE: 02/14/14
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AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
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