| Common Name: | PEBBLE TAN, 97100.73 |
| Manufacturer: | STERLING COLORS |
| SDS Revision Date: | 4/17/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 4PLT1 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET PER OSHA HCS
DATE SDS PRINTED & REVIEWED: 05/17/17
LAST FORMULA REVISION DATE: 04/13/17
(APF)
| SECTION 1: IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PEBBLE TAN
97100.73
OTHER MEANS OF IDENTIFICATION:
RECOMMENDED USE OF THE CHEMICAL: AEROSOL SPRAY
SUPPLIER DETAILS:
MANUFACTURED BY:
STERLING COLORS, LLC
W6166 GREENVILLE DRIVE
UNIT C
GREENVILLE, WI 54942
(920) 757-6967
MANUFACTURED FOR:
RICHARDS WILCOX
600 SOUTH LAKE STREET
AURORA, IL 60506
630-264-4614
EMERGENCY 24-HOUR TELEPHONE NUMBER(S): 1-920-740-7959
| SECTION 2: HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OF MIXTURE:
FLAMMABLE AEROSOLS, CATEGORY 1
GASSES UNDER PRESSURE, CATEGORY COMPRESSED LIQUID
ACUTE TOXICITY - DERMAL, CATEGORY 4
SKIN CORROSION/IRRITATION, CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION, CATEGORY 2A
ACUTE TOXICITY - INHALATION, CATEGORY 4
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, CATEGORY 3
GERM CELL MUTAGENICITY, CATEGORY 1A,1B
CARCINOGENICITY, CATEGORY 1A, 1B
HAZARD PICTOGRAMS:
GHS02: FLAME
GHS04: GAS CYLINDER
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H222: EXTREMELY FLAMMABLE AEROSOL.
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H312: HARMFUL IN CONTACT WITH SKIN.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H340: MAY CAUSE GENETIC DEFECTS.
H350: MAY CAUSE CANCER.
PRECAUTIONARY STATEMENTS:
GENERAL & PREVENTION:
P102: KEEP OUT OF REACH OF CHILDREN.
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/OTHER IGNITION SOURCES. NO SMOKING.
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P251:
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P261: AVOID BREATHING VAPOR/SPRAY.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280: WEAR EYE PROTECTION.
RESPONSE:
P302+P350:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P304+P340:
IF INHALED: REMOVE VICTIM TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
P312: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
STORAGE:
P403+P233:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN
USE.
P410+P403: PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
P410+P412:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEGREES
C/122 DEGREES F.
DISPOSAL:
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL
REGULATIONS.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
# COMPONENT CAS# % BY WT.
1 ACETONE 67-64-1 30-36
2 PROPANE 74-98-6 15-21
3 XYLENE 1330-20-7 10-16
4 *TITANIUM DIOXIDE 13463-67-7 10-16
5 *TOLUENE 108-88-3 8-10
6 N-BUTANE 106-97-8 5-8
7 *ETHYLBENZENE 100-41-4 3-5
8 PM ACETATE 108-65-6 1-3
9 VM&P NAPTHA 64742-89-8 1-3
| SECTION 4: FIRST AID MEASURES | |
INHALATION:
IF INHALED:
MOVE PERSON TO FRESH AIR AND KEEP IN COMFORTABLE POSITION FOR BREATHING.
IF BREATHING DIFFICULTY PERSISTS: GET MEDICAL ADVICE/ATTENTION.
SKIN CONTACT:
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE.
IF SKIN IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
INGESTION:
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER/DOCTOR. DO NOT INDUCE VOMITING UNLESS
DIRECTED TO DO SO BY MEDICAL PERSONNEL.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11: TOXICOLOGICAL INFORMATION AND EFFECTS.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: TREAT SYMPTOMATICALLY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
CO2 (CARBON DIOXIDE), DRY CHEMICAL, OR WATER FOG.
UNSUITABLE EXTINGUISHING MEDIA:
WATER SPRAY MAY BE UNSUITABLE. HOWEVER IF WATER IS USED FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE
BUILD-UP AND POSSIBLE EXPLOSION WHEN EXPOSED TO EXTREME HEAT.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
PRODUCTS OF COMBUSTION MAY INCLUDE BUT ARE NOT LIMITED TO:
OXIDES OF CARBON.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS
SHOULD BE USED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS: USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8.
ENVIRONMENTAL PRECAUTIONS:
PREVENT CONTAMINATION OF SOIL/GROUND, WATERWAYS, DRAINS, AND SEWERS.
METHODS OF CONTAINMENT: ABSORB SPILLED LIQUID IN SUITABLE MATERIAL.
METHODS FOR CLEAN-UP:
USE SPARK-PROOF TOOLS TO SWEEP OR SCRAPE UP, CONTAINERIZE, AND DISPOSE OF
PROPERLY.
OTHER INFORMATION: ENSURE ADEQUATE VENTILATION.
| SECTION 7: HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
VAPORS MAY IGNITE EXPLOSIVELY. PREVENT BUILDUP OF VAPORS. KEEP FROM SPARKS,
HEAT, FLAME OR OTHER HEAT SOURCES. DO NOT SMOKE. TURN OFF PILOT LIGHTS,
HEATERS, ELECTRIC MOTORS AND OTHER SOURCES OF IGNITION DURING USE AND
UNTIL ALL VAPORS ARE GONE. DO NOT PUNCTURE OR INCINERATE/BURN CONTAINER.
KEEP CONTAINER TIGHTLY CLOSED WHILE NOT IN USE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN DRY, WELL-VENTILATED AREA AND IN ACCORDANCE WITH FEDERAL, STATE,
AND LOCAL REGULATIONS. DO NOT EXPOSE TO HEAT OR STORE AT TEMPERATURES ABOVE
50 DEGREES C / 122 DEGREES F. IF STORING IN COLD TEMPERATURES, ALLOW
PRODUCT TO WARM TO ROOM TEMPERATURE BEFORE USE. KEEP CONTAINER TIGHTLY
CLOSED AND AWAY FROM HEAT AND SUNLIGHT WHEN NOT IN USE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
# COMPONENT ACGIH TLV-STEL ACGIH TLV-TWA OSHA PEL-TWA
1 ACETONE 750 PPM 500 PPM 1000 PPM
2 PROPANE 1800 PPM 2500 PPM 1000 PPM
3 *TITANIUM DIOXIDE N/E 10 MG/M3 PPM 15 MG/M3 PPM
4 XYLENE 150 PPM 100 PPM 100 PPM
5 *TOLUENE N/E 50.0 200.0 PPM
5 N-BUTANE N/E 800 PPM 800 PPM
6 *ETHYLBENZENE 125 PPM 100 PPM 100 PPM
7 VM&P NAPHTHA N/E 100 PPM 500 PPM
8 PM ACETATE N/E N/E N/E
APPROPRIATE ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION TO KEEP AIR CONTAMINATION BELOW OSHA
PERMISSIBLE EXPOSURE LIMITS AND ACGIH TLV EXPOSURE LEVELS.
EYE/FACE PROTECTION:
WEAR SAFETY GLASSES WITH SIDE SHIELDS. HAVE EYE WASH FACILITIES IMMEDIATELY
AVAILABLE.
SKIN PROTECTION: WEAR CHEMICAL RESISTANT GLOVES IF CONTACT IS LIKELY.
RESPIRATORY PROTECTION:
USE NIOSH-APPROVED AIR-PURIFYING RESPIRATOR WITH ORGANIC CARTRIDGE OR
CANISTER IF EXPOSURE CANNOT BE CONTROLLED WITHIN APPLICABLE LIMITS WITH
VENTILATION.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: AEROSOL - PRESSURIZED LIQUID
COLOR: SEE PRODUCT IDENTIFICATION
ODOR: SOLVENT ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
FREEZING POINT: NOT ESTABLISHED (MIXTURE)
BOILING POINT: NOT APPLICABLE (PRESSURIZED MIXTURE)
FLASH POINT: <-18 DEGREES C (<-0.4 DEGREES F), C.C.
EVAPORATION RATE: FASTER THAN ETHER
UPPER FLAMMABILITY LIMIT: NOT ESTABLISHED (MIXTURE)
LOWER FLAMMABILITY LIMIT: NOT ESTABLISHED (MIXTURE)
VAPOR PRESSURE: NOT ESTABLISHED (PRESSURIZED MIXTURE)
SPECIFIC GRAVITY: 0.795
SOLUBILITY (WATER): NEGLIGIBLE
VOC PERCENT BY WEIGHT: 41.4
HAPS PERCENT BY WEIGHT: 11.58
| SECTION 10: STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: WILL NOT OCCUR.
CONDITIONS TO AVOID: KEEP AWAY FROM HEAT, SPARKS, AND FLAMES.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
BY FIRE: CARBON DIOXIDE AND CARBON MONOXIDE
| SECTION 11: TOXICOLOGICAL INFORMATION | |
LIKELY ROUTES OF ENTRY: SKIN CONTACT, INHALATION, EYE CONTACT, INGESTION
SIGNS AND SYMPTOMS OF EXPOSURE:
SKIN CONTACT:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, ITCHING, DRYING AND CRACKING
OF SKIN.
INHALATION:
INTENTIONAL CONCENTRATION AND INHALATION MAY BE HARMFUL OR FATAL.
EYE CONTACT:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
TARGET ORGANS POTENTIALLY AFFECTED BY EXPOSURE:
CENTRAL NERVOUS SYSTEM, KIDNEYS, LUNGS, LIVER, EYES, SKIN, BRAIN,
RESPIRATORY TRACT, URINARY TRACT, REPRODUCTIVE SYSTEM, CARDIOVASCULAR
SYSTEM
TOXICOLOGICAL DATA:
# COMPONENT LD50 ORAL LD50 DERMAL
1. ACETONE 1000 2400
2. PROPANE 1000 1800
3. *TITANIUM DIOXIDE N/E N/E
4. XYLENE 4300 2000
5. *TOLUENE 637 14100
6. N-BUTANE N/E N/E
7. *ETHYLBENZENE 3500 5000
8. VM&P NAPTHA N/E N/E
9. PM ACETATE 8535 5000
| SECTION 12: ECOLOGICAL INFORMATION | |
NO DATA AVAILABLE.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
DISPOSE OF CONTAINER AND ITS CONTENTS IN ACCORDANCE WITH FEDERAL, STATE,
AND LOCAL REGULATIONS.
DO NOT PUNCTURE, INCINERATE, OR PLACE CONTAINER IN TRASH COMPACTOR.
| SECTION 14: TRANSPORTATION INFORMATION | |
GROUND (D.O.T./49 CFR):
UN I.D. NUMBER: UN1950
TRANSPORT HAZARD CLASS: 2.1
PACKING GROUP: (NOT APPLICABLE)
PROPER SHIPPING NAME:
AEROSOLS (",FLAMMABLE" IS OPTIONAL TO ADD AFTER AEROSOLS)
HAZARD LABEL: LIMITED QUANTITY (LTD QTY) LABEL - SEE 49 CFR 172.315
SHIPPING PAPERS FORMAT:
UN1950, AEROSOLS, 2.1, LTD QTY (CAN ADD ",FLAMMABLE" AFTER AEROSOLS)
AIR (IATA):
UN I.D. NUMBER: UN1950
TRANSPORT HAZARD CLASS: 2.1
PACKING GROUP: (NOT APPLICABLE)
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
PACKING INSTRUCTION: Y203
HAZARD LABELS: LTD QTY LABEL WITH "Y" IN IT, AND FLAMMABLE GAS LABEL
SHIPPING PAPERS FORMAT:
UN1950, AEROSOLS, FLAMMABLE, 2.1 (NOTE LTD QTY NOT NEEDED ON PAPERS)
WATER (IMDG):
UN I.D. NUMBER: UN1950
TRANSPORT HAZARD CLASS: 2.1
PACKING GROUP: (NOT APPLICABLE)
PROPER SHIPPING NAME: AEROSOLS
HAZARD LABEL: LTD QTY LABEL (SEE IMDG 3.4.5.1)
PACKING INSTRUCTION: P003, LP02
EMS: F-D, S-U
STOWAGE AND SEGREGATION: CATEGORY A
SHIPPING PAPERS FORMAT: UN1950, AEROSOLS, 2.1, (-18 C C.C.), LTD QTY
NO COMPONENT OF THIS PRODUCT IS A LISTED MARINE POLLUTANT (49 CFR
172, 101, APPENDIX B).
| SECTION 15: REGULATORY INFORMATION | |
INTERNATIONAL CHEMICAL INVENTORY:
ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON OR EXEMPT FROM THE FOLLOWING
INVENTORIES:
TSCA (UNITED STATES), CEPA/DSL (CANADA), AICS (AUSTRALIA), IECSC (CHINA)
SARA SECTION 313 TOXIC CHEMICALS:
XYLENE 1330-20-7, *ETHYLBENZENE 100-41-4
CHEMICALS LISTED ABOVE ARE SUBJECT TO THE SARA REPORTING REQUIREMENTS UNDER
40 CFR 372.45(C)(5).
CALIFORNIA PROP65 CHEMICALS:
*ETHYLBENZENE 100-41-4 *
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986
(PROPOSITION 65):
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| SECTION 16: OTHER INFORMATION | |
REVISION DATE: 04/17/17
HMIS & NFPA HAZARD SCALE:
HMIS (AMERICAN COATINGS ASSOCIATION'S HAZARDOUS MATERIAL IDENTIFICATION
SYSTEM):
HEALTH 2
FLAMMABILITY 4
PHYSICAL HAZARD 1
0=MINIMAL
1=SLIGHT
2=MODERATE
3=SERIOUS
4=SEVERE
NFPA 704 (NATIONAL FIRE PROTECTION ASSOCIATION'S HAZARD IDENTIFICATION
RATINGS SYSTEM):
HEALTH 2
FLAMMABILITY 4
INSTABILITY 1
THIS SDS IS BASED ON INFORMATION BELIEVED TO BE RELIABLE AND ACCURATE.
BECAUSE OF CHANGING REPORTING REQUIREMENTS AND OTHER VARIABLES IT IS
IMPOSSIBLE TO GUARANTEE WITH COMPLETE ACCURACY ALL THE INFORMATION
CONTAINED IN THIS DOCUMENT. IT IS THE RESPONSIBILITY OF THE USER TO
DETERMINE PROPER PERSONAL PROTECTION BASED ON ACTUAL CONDITION