| Common Name: | LOCTITE EA E-20HP A RESIN KNOWN AS DB EPOXY ADH E-20HP 50 ML RESIN, 29314_209532 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 8/21/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 4UK09 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 002.0
ISSUE DATE: 08/21/2014
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE EA E-20HP A RESIN KNOWN AS DB EPOXY ADH E-20HP 50 ML RESIN
IDH NUMBER: 701979
PRODUCT TYPE: EPOXY RESIN
ITEM NUMBER: 29314_209532
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
WEAR EYE AND FACE PROTECTION. WEAR PROTECTIVE GLOVES.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: NOT PRESCRIBED
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED
NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF
CHEMICALS (GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
EPOXY RESIN PROPRIETARY 60 - 100
SUBSTITUTED SILANE PROPRIETARY 0.1 - 1
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES
BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
PERSONNEL IN VICINITY AND DOWNWIND SHOULD BE EVACUATED. BURNING PRODUCES
OBNOXIOUS AND TOXIC FUMES. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER
SPRAY. CLOSED CONTAINERS MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN
EXPOSED TO EXTREME HEAT.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. ALDEHYDES. FORMALDEHYDE. ACIDS.
ACRYLIC MONOMERS. TOXIC FUMES. IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
ENSURE ADEQUATE VENTILATION. WEAR APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION"
PRIOR TO CLEAN UP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND,
SILICA GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP SPILLED
MATERIAL AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. USE ONLY WITH ADEQUATE VENTILATION.
KEEP CONTAINER CLOSED.
STORAGE:
KEEP CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY
FROM INCOMPATIBLE MATERIALS. KEEP AWAY FROM HEAT, SPARK AND FLAME. PROTECT
FROM DIRECT SUNLIGHT.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE
AT (800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
EPOXY RESIN NONE NONE NONE NONE
SUBSTITUTED SILANE NONE NONE NONE NONE
ENGINEERING CONTROLS:
USE LOCAL EXHAUST VENTILATION IF THE POTENTIAL FOR AIRBORNE EXPOSURE
EXISTS.
RESPIRATORY PROTECTION:
USE A NIOSH APPROVED RESPIRATOR IF VENTILATION IS INADEQUATE.
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN
APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: PALE YELLOW, TO, OFF WHITE
ODOR: FAINT, EPOXY
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.10
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: 96.11 DEG. C (205 DEG. F) SETAFLASH CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0.0% CALIFORNIA SCAQMD METHOD 316B
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS:
REACTION WITH SOME CURING AGENTS MAY PRODUCE AN EXOTHERMIC REACTION WHICH
IN LARGE MASSES COULD CAUSE RUNAWAY POLYMERIZATION.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. ALDEHYDES. FORMALDEHYDE. ACIDS.
ACRYLIC MONOMERS. TOXIC FUMES. IRRITATING VAPORS.
INCOMPATIBLE MATERIALS: ACIDS. BASES. OXIDIZING AGENTS. AMINES.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
INHALATION OF VAPORS OR MISTS OF THE PRODUCT MAY BE IRRITATING TO THE
RESPIRATORY SYSTEM.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: NOT EXPECTED UNDER NORMAL CONDITIONS OF USE.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
EPOXY RESIN NONE ALLERGEN, IRRITANT
SUBSTITUTED SILANE NONE ALLERGEN, IRRITANT
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
EPOXY RESIN NO NO NO
SUBSTITUTED SILANE NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
MARINE POLLUTANT: EPOXY RESIN
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: RENA PETRIDES, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 08/21/2014
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 005.0
ISSUE DATE: 08/27/2014
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME:
LOCTITE EA E-20HP B HARDENER KNOWN AS DB EPOXY ADH E-20HP 50 ML HARD
IDH NUMBER: 701980
PRODUCT TYPE: EPOXY HARDENER
ITEM NUMBER: 29314_209533
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE AN ALLERGIC SKIN REACTION.
HAZARD CLASS HAZARD CATEGORY
SKIN CORROSION 1B
SERIOUS EYE DAMAGE 1
SKIN SENSITIZATION 1
PICTOGRAM(S):
CORROSION
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE VAPORS, MIST, OR SPRAY. WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR
PROTECTIVE GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR): TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CONTROL CENTER OR PHYSICIAN.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED
NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF
CHEMICALS (GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
POLYGLYCOL DIAMINE PROPRIETARY 10 - 30
ACID SALT PROPRIETARY 5 - 10
GLYCEROL 56-81-5 1 - 5
SUBSTITUTED AMINOPHENOL PROPRIETARY 1 - 5
DIETHYLENEGLYCOL MONOETHYL ETHER 111-90-0 1 - 5
ALCOHOL DERIVATIVE PROPRIETARY 0.1 - 1
SUBSTITUTED AMINOPHENOL PROPRIETARY 0.1 - 1
ETHYLENE GLYCOL 107-21-1 0.1 - 1
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED
TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. GET MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. GIVE
A CONSCIOUS PERSON SEVERAL GLASSES OF WATER. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
PERSONNEL IN VICINITY AND DOWNWIND SHOULD BE EVACUATED. BURNING PRODUCES
OBNOXIOUS AND TOXIC FUMES.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. OXIDES OF SULFUR. ACROLEIN. AMMONIA.
HYDROGEN FLUORIDE. NITRIC ACID. TOXIC FUMES. IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
ENSURE ADEQUATE VENTILATION. WEAR APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION"
PRIOR TO CLEAN UP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA
GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP SPILLED MATERIAL
AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. USE ONLY WITH ADEQUATE VENTILATION.
KEEP CONTAINER CLOSED.
STORAGE:
KEEP CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY
FROM INCOMPATIBLE MATERIALS. KEEP AWAY FROM HEAT, SPARK AND FLAME. DO NOT
STORE IN REACTIVE METAL CONTAINERS.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE
AT (800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
POLYGLYCOL DIAMINE NONE NONE NONE NONE
ACID SALT NONE NONE NONE NONE
GLYCEROL NONE 5 MG/M3 PEL NONE NONE
RESPIRABLE
FRACTION.
15 MG/M3 PEL
TOTAL DUST.
SUBSTITUTED AMINOPHENOL NONE NONE NONE NONE
DIETHYLENEGLYCOL NONE NONE 25 PPM NONE
MONOETHYL ETHER (140 MG/M3)
TWA
ALCOHOL DERIVATIVE NONE NONE 10 PPM NONE
(44.20 MG/M3)
TWA
SUBSTITUTED AMINOPHENOL NONE NONE NONE NONE
ETHYLENE GLYCOL 100 MG/M3 NONE NONE NONE
CEILING
AEROSOL.
ENGINEERING CONTROLS:
USE LOCAL VENTILATION IF GENERAL VENTILATION IS INSUFFICIENT TO MAINTAIN
VAPOR CONCENTRATION BELOW ESTABLISHED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: LIGHT YELLOW
ODOR: MILD
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.15
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: >93.4 DEG. C (>200.12 DEG. F) SETAFLASH CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: PARTIALLY SOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: <1.0%; <10 G/L ESTIMATED
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. OXIDES OF SULFUR. ACROLEIN. AMMONIA.
NITRIC ACID. HYDROGEN FLUORIDE. TOXIC FUMES. IRRITATING VAPORS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS. ORGANIC ACIDS. MINERAL ACIDS. PEROXIDES. SODIUM
HYPOCHLORITE. THIS PRODUCT SLOWLY CORRODES COPPER, ALUMINUM, ZINC AND
GALVANIZED SURFACES.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION: MISTS, VAPORS OR LIQUID MAY CAUSE SEVERE IRRITATION OR BURNS.
SKIN CONTACT: CAUSES SKIN BURNS. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION:
IF INGESTED, SEVERE BURNS OF THE MOUTH AND THROAT MAY OCCUR, AS WELL AS
PERFORATION OF THE ESOPHAGUS AND THE STOMACH.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
POLYGLYCOL DIAMINE NONE CORROSIVE
ACID SALT NONE NO RECORDS
GLYCEROL NONE BLOOD, IRRITANT,
KIDNEY, NUISANCE DUST
SUBSTITUTED AMINOPHENOL NONE IRRITANT, ALLERGEN
DIETHYLENEGLYCOL ORAL LD50 (RAT): BLOOD, CENTRAL NERVOUS
MONOETHYL ETHER 1,920 MG/KG SYSTEM, IRRITANT,
KIDNEY
ORAL LD50 (RAT):
5.54 G/KG
ORAL LD50 (RAT):
5,900 MG/KG
ORAL LD50 (RABBIT):
3,620 MG/KG
ORAL LD50 (RAT):
6,500 MG/KG
ORAL LD50 (RABBIT):
4,450 MG/KG
ORAL LD50 (RAT):
7,500 MG/KG
DERMAL LD50 (RABBIT):
10,300 MG/KG
DERMAL LD50 (RAT):
6,000 MG/KG
DERMAL LD50 (RABBIT):
11,176 MG/KG
DERMAL LD50 (RABBIT):
8,500 MG/KG
DERMAL LD50 (RABBIT):
8,476 MG/KG
ALCOHOL DERIVATIVE ORAL LD50 (RABBIT): ALLERGEN, CENTRAL
1,940 MG/KG NERVOUS SYSTEM,
CORROSIVE, IRRITANT
ORAL LD50 (RAT):
1,230 - 3,100 MG/KG
ORAL LD50 (RAT):
3,100 MG/KG
DERMAL LD50 (RABBIT):
2,000 MG/KG
INHALATION LC50
(RAT, 8 H):
1,000 MG/L
SUBSTITUTED AMINOPHENOL NONE NO RECORDS
ETHYLENE GLYCOL ORAL LD50 (RAT): BLOOD, BONE MARROW,
5.89 G/KG CENTRAL NERVOUS
SYSTEM, DEVELOPMENTAL,
DERMAL LD50 (RABBIT): EYES, IRRITANT,
9,530 MG/KG KIDNEY, LIVER,
METABOLIC
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
POLYGLYCOL DIAMINE NO NO NO
ACID SALT NO NO NO
GLYCEROL NO NO NO
SUBSTITUTED AMINOPHENOL NO NO NO
DIETHYLENEGLYCOL NO NO NO
MONOETHYL ETHER
ALCOHOL DERIVATIVE NO NO NO
SUBSTITUTED AMINOPHENOL NO NO NO
ETHYLENE GLYCOL NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL GOVERNMENTAL REGULATIONS.
HAZARDOUS WASTE NUMBER:
IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE IF AN ITEM IS HAZARDOUS
AS DEFINED IN THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) AT THE
TIME OF DISPOSAL. PRODUCT USES, TRANSFORMATIONS, MIXTURES, PROCESSES, ETC.,
MAY RENDER THE RESULTING MATERIAL HAZARDOUS, UNDER THE CRITERIA OF
IGNITABILITY, CORROSIVITY, REACTIVITY AND TOXICITY CHARACTERISTICS OF THE
TOXICITY CHARACTERISTICS LEACHING PROCEDURE (TCLP) 40 CFR 261.20-24.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME:
AMINES, LIQUID, CORROSIVE, N.O.S. (POLYGLYCOL DIAMINE)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 2735
PACKING GROUP: II
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
AMINES, LIQUID, CORROSIVE, N.O.S. (POLYGLYCOL DIAMINE)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 2735
PACKING GROUP: II
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
AMINES, LIQUID, CORROSIVE, N.O.S. (POLYGLYCOL DIAMINE)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 2735
PACKING GROUP: II
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). DIETHYLENEGLYCOL
MONOETHYL ETHER (CAS# 111-90-0).
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
CONTAINS ONE OR MORE COMPONENTS LISTED ON THE NON-DOMESTIC SUBSTANCES
LIST. ALL OTHER COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE
DOMESTIC SUBSTANCES LIST. COMPONENTS LISTED ON THE NDSL MUST BE TRACKED BY
ALL CANADIAN IMPORTERS OF RECORD AS REQUIRED BY ENVIRONMENT CANADA. THEY
MAY BE IMPORTED INTO CANADA IN LIMITED QUANTITIES. PLEASE CONTACT
REGULATORY AFFAIRS FOR ADDITIONAL DETAILS.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: RENA PETRIDES, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 08/27/2014
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.