| Common Name: | LOCTITE EA E-120HP A RESIN KNOWN AS DB EPOXY ADH E-120HP 50 ML RES, 29353_209547 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 6/17/2020 |
| SDS Format: | GHS-US |
| Item Number(s): | 4UK12 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 003.1
ISSUE DATE: 06/17/2020
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE EA E-120HP A RESIN KNOWN AS DB EPOXY ADH E-120HP 50 ML RES
PRODUCT TYPE/USE: ADHESIVE
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 702021
ITEM NUMBER: 29353_209547
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER
HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE
WORKPLACE. WEAR PROTECTIVE GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: NOT PRESCRIBED
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
PHENOL POLYMER WITH FORMALDEHYDE, GLYCIDYL ETHER 28064-14-4 30 - 60
EPICHLOROHYDRIN-4,4'-ISOPROPYLIDENE DIPHENOL RESIN 25068-38-6 30 - 60
AMORPHOUS FUMED SILICA 68611-44-9 1 - 5
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES
BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
PERSONNEL IN VICINITY AND DOWNWIND SHOULD BE EVACUATED. BURNING PRODUCES
OBNOXIOUS AND TOXIC FUMES. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER
SPRAY. CLOSED CONTAINERS MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN
EXPOSED TO EXTREME HEAT.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. ALDEHYDES. FORMALDEHYDE. ACIDS.
ACRYLIC MONOMERS. OXIDES OF SILICON. TOXIC FUMES. IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
ENSURE ADEQUATE VENTILATION. WEAR APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION"
PRIOR TO CLEAN UP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA
GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP SPILLED MATERIAL
AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. USE ONLY WITH ADEQUATE VENTILATION.
KEEP CONTAINER CLOSED.
STORAGE:
KEEP CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY
FROM INCOMPATIBLE MATERIALS. KEEP AWAY FROM HEAT, SPARK AND FLAME.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
PHENOL POLYMER WITH NONE NONE NONE NONE
FORMALDEHYDE,
GLYCIDYL ETHER
EPICHLOROHYDRIN- NONE NONE NONE NONE
4,4'-ISOPROPYLIDENE
DIPHENOL RESIN
AMORPHOUS FUMED SILICA NONE 0.8 MG/M3 TWA NONE NONE
20 MPPCF TWA
ENGINEERING CONTROLS:
USE LOCAL EXHAUST VENTILATION IF THE POTENTIAL FOR AIRBORNE EXPOSURE
EXISTS.
RESPIRATORY PROTECTION:
USE A NIOSH APPROVED RESPIRATOR IF VENTILATION IS INADEQUATE.
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: PALE YELLOW, TO, OFF WHITE
ODOR: FAINT, EPOXY
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.0 - 1.2
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: 96.11 DEG. C (205 DEG. F) SETAFLASH CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT MISCIBLE OR DIFFICULT TO MIX
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0.0% CALIFORNIA SCAQMD METHOD 316B
VISCOSITY: 41,000 - 61,000 CP
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS:
POLYMERIZATION MAY OCCUR AT ELEVATED TEMPERATURE OR IN THE PRESENCE OF
INCOMPATIBLE MATERIALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. ALDEHYDES. FORMALDEHYDE. ACIDS.
ACRYLIC MONOMERS. OXIDES OF SILICON. TOXIC FUMES. IRRITATING VAPORS.
INCOMPATIBLE MATERIALS: ACIDS. BASES. OXIDIZING AGENTS. AMINES.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS.
NOTE:
HEATING THE EPOXY RESIN IN THIS PRODUCT ABOVE 148.9 DEG. C (300 DEG. F)
IN THE PRESENCE OF AIR MAY CAUSE SLOW OXIDATIVE DECOMPOSITION. ABOVE
260 DEG. C (500 DEG. F) POLYMERIZATION OF THE EPOXY RESIN MAY OCCUR.
ALIPHATIC POLYAMINES CAN PRODUCE EXOTHERMIC REACTIONS WITH EPOXY RESINS
WHICH IN LARGE MASSES CAN CAUSE RUNAWAY POLYMERIZATION AND CHARRING OF
THE REACTANTS. FUMES AND VAPORS FROM THESE THERMAL AND CHEMICAL
DECOMPOSITIONS VARY WIDELY IN COMPOSITION AND TOXICITY. DO NOT
BREATHE FUMES.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
INHALATION OF VAPORS OR MISTS OF THE PRODUCT MAY BE IRRITATING TO THE
RESPIRATORY SYSTEM.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: NOT EXPECTED UNDER NORMAL CONDITIONS OF USE.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
PHENOL POLYMER WITH NONE ALLERGEN, IRRITANT
FORMALDEHYDE, GLYCIDYL
ETHER
EPICHLOROHYDRIN-4,4'- NONE ALLERGEN, IRRITANT
ISOPROPYLIDENE DIPHENOL
RESIN
AMORPHOUS FUMED SILICA NONE NO TARGET ORGANS
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY REGULATED)
PHENOL POLYMER WITH NO NO NO
FORMALDEHYDE, GLYCIDYL
ETHER
EPICHLOROHYDRIN-4,4'- NO NO NO
ISOPROPYLIDENE DIPHENOL
RESIN
AMORPHOUS FUMED SILICA NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
MARINE POLLUTANT: EPOXY RESIN
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED AS ACTIVE OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT (TSCA) INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 3,7,8,11,14,15
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 06/17/2020
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION IN
ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION OF ANY
KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF ANY OTHER
JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION PROVIDED
HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY OTHER
JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY AND
REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 004.1
ISSUE DATE: 11/08/2017
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME:
LOCTITE EA E-120HP B HARDENER KNOWN AS DB EPOXY ADH E-120HP 50 ML. HAR
PRODUCT TYPE: ADHESIVE
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 702022
ITEM NUMBER: 29353_209548
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE AN ALLERGIC SKIN REACTION.
HAZARD CLASS HAZARD CATEGORY
SKIN CORROSION 1B
SERIOUS EYE DAMAGE 1
SKIN SENSITIZATION 1
PICTOGRAM(S):
CORROSION
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY
AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE. WEAR PROTECTIVE GLOVES, CLOTHING, EYE AND FACE
PROTECTION.
RESPONSE:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR): TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
C18 FATTY ACID DIMER, TALL OIL 68082-29-1 70 - 80
FATTY ACID, TRIETHYLENETETRAMINE
POLYMER
TETRAETHYLENE PENTAMINE 112-57-2 10 - 20
TRIETHYLENETETRAMINE 112-24-3 5 - 10
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. GET MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
IMMEDIATE MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. RINSE
THE MOUTH. DRINK 1-2 GLASSES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. GET IMMEDIATE MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: DRY CHEMICAL. CARBON DIOXIDE. ALCOHOL FOAM.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
PERSONNEL IN VICINITY AND DOWNWIND SHOULD BE EVACUATED. BURNING PRODUCES
OBNOXIOUS AND TOXIC FUMES. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER
SPRAY. CLOSED CONTAINERS MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN
EXPOSED TO EXTREME HEAT.
HAZARDOUS COMBUSTION PRODUCTS:
AMMONIA. OXIDES OF CARBON. OXIDES OF NITROGEN.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
ENSURE ADEQUATE VENTILATION. WEAR APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION"
PRIOR TO CLEAN UP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA
GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP SPILLED MATERIAL
AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. USE ONLY WITH ADEQUATE VENTILATION.
KEEP CONTAINER CLOSED.
STORAGE:
FOR SAFE STORAGE, STORE BETWEEN 0 DEG. C (32 DEG. F) AND 32 DEG. C (89.6
DEG. F)
KEEP CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY
FROM INCOMPATIBLE MATERIALS. KEEP AWAY FROM HEAT, SPARK AND FLAME. PROTECT
FROM DIRECT SUNLIGHT. AVOID MOISTURE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
C18 FATTY ACID DIMER, NONE NONE NONE NONE
TALL OIL FATTY ACID,
TRIETHYLENETETRAMINE
POLYMER
TETRAETHYLENE PENTAMINE NONE NONE (SKIN) AEROSOL. NONE
1 PPM (5 MG/M3)
TWA AEROSOL.
(SKIN
SENSITIZER)
TRIETHYLENETETRAMINE NONE NONE 1 PPM (6 MG/M3) NONE
TWA (SKIN)
ENGINEERING CONTROLS:
USE LOCAL VENTILATION IF GENERAL VENTILATION IS INSUFFICIENT TO MAINTAIN
VAPOR CONCENTRATION BELOW ESTABLISHED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN
APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: AMBER
ODOR: SLIGHT
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: >93 DEG. C (>199.4 DEG. F)1,013 HPA
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 0.9 - 1.1
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: >93 DEG. C (>199.4 DEG. F); ESTIMATED
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: PARTIALLY MISCIBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: <1.0%; <10 G/L ESTIMATED
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
AMMONIA. OXIDES OF CARBON. OXIDES OF NITROGEN.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS. ACIDS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS. EXPOSURE
TO WATER VAPOUR. EXPOSURE TO SUNLIGHT.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION: MISTS, VAPORS OR LIQUID MAY CAUSE SEVERE IRRITATION OR BURNS.
SKIN CONTACT: CAUSES SKIN BURNS. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION:
IF INGESTED, SEVERE BURNS OF THE MOUTH AND THROAT MAY OCCUR, AS WELL AS
PERFORATION OF THE ESOPHAGUS AND THE STOMACH.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
C18 FATTY ACID DIMER, NONE NO RECORDS
TALL OIL FATTY ACID,
TRIETHYLENETETRAMINE
POLYMER
TETRAETHYLENE PENTAMINE ORAL LD50 (RAT): IRRITANT, MUTAGEN, ALLERGEN
3.99 G/KG
ORAL LD50 (RAT):
2.1 G/KG
DERMAL LD50
(RABBIT):
0.66 G/KG
TRIETHYLENETETRAMINE NONE ALLERGEN, CORROSIVE,
DEVELOPMENTAL, IRRITANT, MUTAGEN
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY REGULATED)
C18 FATTY ACID DIMER, NO NO NO
TALL OIL FATTY ACID,
TRIETHYLENETETRAMINE
POLYMER
TETRAETHYLENE PENTAMINE NO NO NO
TRIETHYLENETETRAMINE NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL GOVERNMENTAL REGULATIONS.
HAZARDOUS WASTE NUMBER:
IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE IF AN ITEM IS HAZARDOUS
AS DEFINED IN THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) AT THE TIME
OF DISPOSAL. PRODUCT USES, TRANSFORMATIONS, MIXTURES, PROCESSES, ETC., MAY
RENDER THE RESULTING MATERIAL HAZARDOUS, UNDER THE CRITERIA OF
IGNITABILITY, CORROSIVITY, REACTIVITY AND TOXICITY CHARACTERISTICS OF THE
TOXICITY CHARACTERISTICS LEACHING PROCEDURE (TCLP) 40 CFR 261.20-24.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME:
AMINES, LIQUID, CORROSIVE, N.O.S. (TETRAETHYLENE PENTAMINE,
TRIETHYLENETETRAMINE)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 2735
PACKING GROUP: III
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
AMINES, LIQUID, CORROSIVE, N.O.S. (TETRAETHYLENE PENTAMINE,
TRIETHYLENETETRAMINE)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 2735
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
AMINES, LIQUID, CORROSIVE, N.O.S. (TETRAETHYLENE PENTAMINE,
TRIETHYLENETETRAMINE, DIMER FATTY ACID(C18)POLY AMIDO AMINE RESIN)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 2735
PACKING GROUP: III
MARINE POLLUTANT: DIMER FATTY ACID(C18)POLY AMIDO AMINE RESIN
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CALIFORNIA PROPOSITION 65:
NO CALIFORNIA PROPOSITION 65 LISTED CHEMICALS ARE KNOWN TO BE PRESENT.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 9
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 11/08/2017
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.