| Common Name: | MARINE ADHESIVE SEALANT 5200 MAHOGANY PN 06502 |
| Manufacturer: | 3M |
| SDS Revision Date: | 1/19/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 4YDL3 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
3M(TM) MARINE ADHESIVE SEALANT 5200 MAHOGANY PN 06502
01/19/18
3M
SAFETY DATA SHEET
COPYRIGHT, 2018, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 19-4648-2
VERSION NUMBER: 9.01
ISSUE DATE: 01/19/18
SUPERCEDES DATE: 10/29/14
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) MARINE ADHESIVE SEALANT 5200 MAHOGANY PN 06502
PRODUCT IDENTIFICATION NUMBERS:
60-4400-9507-7, 60-9801-0934-6, 62-5237-5236-8
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: MARINE ADHESIVE SEALANT, SEALANT
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION:
INDUSTRIAL ADHESIVES AND TAPES DIVISION
MARINE & SPECIALTY VEHICLE
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
RESPIRATORY SENSITIZER: CATEGORY 1A.
SKIN SENSITIZER: CATEGORY 1A.
CARCINOGENICITY: CATEGORY 1B.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS: HEALTH HAZARD
PICTOGRAMS: HEALTH HAZARD
HAZARD STATEMENTS:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE CANCER.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
WEAR PROTECTIVE GLOVES.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
1% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
1% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL TOXICITY.
3% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
URETHANE PREPOLYMER 68611-34-7 40 - 70 TRADE SECRET *
TALC 14807-96-6 10 - 30 TRADE SECRET *
CARBITOL ACETATE 112-15-2 1 - 5 TRADE SECRET *
FUMED SILICA 112945-52-5 1 - 5 TRADE SECRET *
TITANIUM DIOXIDE 13463-67-7 1 - 5 TRADE SECRET *
ZINC OXIDE 1314-13-2 1 - 5 TRADE SECRET *
IRON OXIDES MIXTURE 0.5 - 5 TRADE SECRET *
ALKYL ISOCYANATE SILANE 85702-90-5 0.5 - 1.5 TRADE SECRET *
TOLUENE DIISOCYANATE 26471-62-5 <0.5 TRADE SECRET *
HEPTANE 142-82-5 <0.3 TRADE SECRET *
(GAMMA-MERCAPTOPROPYL) 4420-74-0 <0.2 TRADE SECRET *
TRIMETHOXYSILANE
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER MATERIAL WILL NOT BURN. USE A FIRE FIGHTING AGENT SUITABLE
FOR THE SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
ISOCYANATES DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
HYDROGEN CYANIDE DURING COMBUSTION
IRRITANT VAPORS OR GASES DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH BENTONITE,
VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN
SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT
MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD.
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A CONTAINER
APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES, BUT DO NOT SEAL THE
CONTAINER FOR 48 HOURS TO AVOID PRESSURE BUILD-UP. CLEAN UP RESIDUE WITH AN
APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED PERSON.
VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY PRECAUTIONS ON
THE SOLVENT LABEL AND SDS. DISPOSE OF COLLECTED MATERIAL AS SOON AS
POSSIBLE IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS
HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/
SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR
SMOKE WHEN USING THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED
WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. AVOID RELEASE TO
THE ENVIRONMENT. WASH CONTAMINATED CLOTHING BEFORE REUSE. USE PERSONAL
PROTECTIVE EQUIPMENT (GLOVES, RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED TO PREVENT CONTAMINATION WITH WATER OR AIR.
IF CONTAMINATION IS SUSPECTED, DO NOT RESEAL CONTAINER. STORE AWAY FROM
HEAT. STORE AWAY FROM AMINES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
SILICA, AMORPHOUS 112945-52-5 OSHA TWA CONCENTRATION:
0.8 MG/M3;
TWA:
20 MILLIONS OF
PARTICLES/CU. FT.
ZINC OXIDE 1314-13-2 ACGIH TWA(RESPIRABLE
FRACTION):
2 MG/M3;
STEL(RESPIRABLE
FRACTION):
10 MG/M3
ZINC OXIDE 1314-13-2 OSHA TWA(AS FUME):
5 MG/M3;
TWA(AS TOTAL
DUST):
15 MG/M3;
TWA(RESPIRABLE
FRACTION):
5 MG/M3
TITANIUM DIOXIDE 13463-67-7 ACGIH TWA: 10 MG/M3 A4:
NOT CLASS. AS
HUMAN CARCIN
TITANIUM DIOXIDE 13463-67-7 OSHA TWA(AS TOTAL
DUST): 15 MG/M3
HEPTANE 142-82-5 ACGIH TWA: 400 PPM;
STEL: 500 PPM
HEPTANE 142-82-5 OSHA TWA:
2000 MG/M3(500
PPM)
TALC 14807-96-6 ACGIH TWA(RESPIRABLE A4:
FRACTION): 2 MG/M3 NOT CLASS. AS
HUMAN CARCIN
TALC 14807-96-6 OSHA TWA: 2 MG/M3
TOLUENE 26471-62-5 ACGIH TWA(INHALABLE SKIN;
DIISOCYANATE FRACTION AND RESP+DERMAL
VAPOR): SENSITIZER,
0.001 PPM; A4:
STEL(INHALABLE NOT CLASS. AS
FRACTION HUMAN CARCIN
AND VAPOR):
0.005 PPM
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: SAFETY GLASSES WITH SIDE SHIELDS
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING. NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
BUTYL RUBBER
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - BUTYL RUBBER
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: RED/BROWN
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: NOT APPLICABLE
FLASH POINT: NO FLASH POINT
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 11.03 LB/GAL
SPECIFIC GRAVITY: 1.3 [REF STD: WATER=1]
SOLUBILITY IN WATER: NIL
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 100,000 - 500,000 CENTIPOISE
HAZARDOUS AIR POLLUTANTS: <=0.2% WEIGHT [TEST METHOD: CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS:
40 G/L [TEST METHOD: TESTED PER EPA METHOD 24]
VOC LESS H2O & EXEMPT SOLVENTS:
2.9% [TEST METHOD: TESTED PER EPA METHOD 24]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT
10.5. INCOMPATIBLE MATERIALS:
REACTION WITH WATER, ALCOHOLS, AND AMINES IS NOT HAZARDOUS IF CONTAINER CAN
VENT TO THE ATMOSPHERE TO PREVENT PRESSURE BUILDUP.
AMINES
ALCOHOLS
WATER
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION: MAY BE HARMFUL IF INHALED.
ALLERGIC RESPIRATORY REACTION:
SIGNS/SYMPTOMS MAY INCLUDE DIFFICULTY BREATHING, WHEEZING, COUGH, AND
TIGHTNESS OF CHEST.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
CONTACT WITH THE SKIN DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
CONTACT WITH THE EYES DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
ADDITIONAL HEALTH EFFECTS:
CARCINOGENICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
TITANIUM 13463-67-7 GRP. 2B: INTERNATIONAL AGENCY FOR
DIOXIDE POSSIBLE RESEARCH ON CANCER
HUMAN CARC.
TOLUENE 26471-62-5 GRP. 2B: INTERNATIONAL AGENCY FOR
DIISOCYANATE POSSIBLE RESEARCH ON CANCER
HUMAN CARC.
TOLUENE 26471-62-5 ANTICIPATED NATIONAL TOXICOLOGY PROGRAM
DIISOCYANATE HUMAN CARCINOGENS
CARCINOGEN
ADDITIONAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A
CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE; CALCULATED
ATE: >5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE; CALCULATED
VAPOR(4 HR) ATE: 20 - 50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE; CALCULATED
ATE: >5,000 MG/KG
TALC DERMAL LD50 ESTIMATED TO BE:
>5,000 MG/KG
TALC INGESTION LD50 ESTIMATED TO BE:
>5,000 MG/KG
FUMED SILICA DERMAL RABBIT LD50: >5,000 MG/KG
FUMED SILICA INHALATION- RAT LC50: >0.691 MG/L
DUST/MIST
(4 HOURS)
FUMED SILICA INGESTION RAT LD50: >5,110 MG/KG
ZINC OXIDE DERMAL LD50 ESTIMATED TO BE:
>5,000 MG/KG
ZINC OXIDE INHALATION- RAT LC50: >5.7 MG/L
DUST/MIST
(4 HOURS)
ZINC OXIDE INGESTION RAT LD50: >5,000 MG/KG
CARBITOL ACETATE DERMAL RABBIT LD50: 15,000 MG/KG
CARBITOL ACETATE INGESTION RAT LD50: 11,000 MG/KG
TITANIUM DIOXIDE DERMAL RABBIT LD50: >10,000 MG/KG
TITANIUM DIOXIDE INHALATION- RAT LC50: >6.82 MG/L
DUST/MIST
(4 HOURS)
TITANIUM DIOXIDE INGESTION RAT LD50: >10,000 MG/KG
IRON OXIDES DERMAL NOT LD50: 3,100 MG/KG
AVAILABLE
IRON OXIDES INGESTION NOT LD50: 3,700 MG/KG
AVAILABLE
TOLUENE DIISOCYANATE INHALATION- MOUSE LC50: 0.12 MG/L
VAPOR (4
HOURS)
TOLUENE DIISOCYANATE DERMAL RABBIT LD50: >9,400 MG/KG
TOLUENE DIISOCYANATE INHALATION- RAT LC50: 0.35 MG/L
DUST/MIST
(4 HOURS)
TOLUENE DIISOCYANATE INGESTION RAT LD50: >5,000 MG/KG
HEPTANE DERMAL RABBIT LD50: 3,000 MG/KG
HEPTANE INHALATION- RAT LC50: 103 MG/L
VAPOR (4
HOURS)
HEPTANE INGESTION RAT LD50: >15,000 MG/KG
(GAMMA- DERMAL RABBIT LD50: 2,270 MG/KG
MERCAPTOPROPYL)
TRIMETHOXYSILANE
(GAMMA- INGESTION RAT LD50: 770 MG/KG
MERCAPTOPROPYL)
TRIMETHOXYSILANE
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
TALC RABBIT NO SIGNIFICANT IRRITATION
FUMED SILICA RABBIT NO SIGNIFICANT IRRITATION
ZINC OXIDE HUMAN AND ANIMAL NO SIGNIFICANT IRRITATION
CARBITOL ACETATE HUMAN AND ANIMAL MINIMAL IRRITATION
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
IRON OXIDES RABBIT NO SIGNIFICANT IRRITATION
TOLUENE DIISOCYANATE RABBIT IRRITANT
HEPTANE HUMAN MILD IRRITANT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
TALC RABBIT NO SIGNIFICANT IRRITATION
FUMED SILICA RABBIT NO SIGNIFICANT IRRITATION
ZINC OXIDE RABBIT MILD IRRITANT
CARBITOL ACETATE RABBIT SEVERE IRRITANT
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
IRON OXIDES RABBIT NO SIGNIFICANT IRRITATION
TOLUENE DIISOCYANATE RABBIT CORROSIVE
HEPTANE PROFESSIONAL MODERATE IRRITANT
JUDGMENT
SKIN SENSITIZATION:
NAME SPECIES VALUE
FUMED SILICA HUMAN AND ANIMAL NOT CLASSIFIED
ZINC OXIDE GUINEA PIG NOT CLASSIFIED
CARBITOL ACETATE HUMAN AND ANIMAL NOT CLASSIFIED
TITANIUM DIOXIDE HUMAN AND ANIMAL NOT CLASSIFIED
IRON OXIDES HUMAN NOT CLASSIFIED
TOLUENE DIISOCYANATE HUMAN AND ANIMAL SENSITIZING
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
TALC HUMAN NOT CLASSIFIED
TOLUENE DIISOCYANATE HUMAN SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
TALC IN VITRO NOT MUTAGENIC
TALC IN VIVO NOT MUTAGENIC
FUMED SILICA IN VITRO NOT MUTAGENIC
ZINC OXIDE IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
ZINC OXIDE IN VIVO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
CARBITOL ACETATE IN VITRO NOT MUTAGENIC
TITANIUM DIOXIDE IN VITRO NOT MUTAGENIC
TITANIUM DIOXIDE IN VIVO NOT MUTAGENIC
IRON OXIDES IN VITRO NOT MUTAGENIC
TOLUENE DIISOCYANATE IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
HEPTANE IN VITRO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
TALC INHALATION RAT SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
FUMED SILICA NOT MOUSE SOME POSITIVE DATA EXIST, BUT
SPECIFIED THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
TITANIUM DIOXIDE INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
TITANIUM DIOXIDE INHALATION RAT CARCINOGENIC
IRON OXIDES INHALATION HUMAN SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
TOLUENE DIISOCYANATE INHALATION HUMAN NOT CARCINOGENIC
AND
ANIMAL
TOLUENE DIISOCYANATE INGESTION MULTIPLE CARCINOGENIC
ANIMAL
SPECIES
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES TEST RESULT EXPOSURE
DURATION
TALC INGESTION NOT RAT NOAEL: DURING
CLASSIFIED 1,600 ORGANOGENE-
FOR MG/KG SIS
DEVELOPMENT
FUMED SILICA INGESTION NOT RAT NOAEL: 1 GENERATION
CLASSIFIED 509
FOR FEMALE MG/KG/DAY
REPRODUCTION
FUMED SILICA INGESTION NOT RAT NOAEL: 1 GENERATION
CLASSIFIED 497
FOR MALE MG/KG/DAY
REPRODUCTION
FUMED SILICA INGESTION NOT RAT NOAEL: DURING
CLASSIFIED 1,350 ORGANOGENE-
FOR MG/KG/DAY SIS
DEVELOPMENT
ZINC OXIDE INGESTION NOT MULTIPLE NOAEL: PREMATING &
CLASSIFIED ANIMAL 125 DURING
FOR SPECIES MG/KG/DAY GESTATION
REPRODUCTION
AND/OR
DEVELOPMENT
TOLUENE INHALATION NOT RAT NOAEL: 2 GENERATION
DIISOCYANATE CLASSIFIED 0.002 5
FOR FEMALE MG/L
REPRODUCTION
TOLUENE INHALATION NOT RAT NOAEL: 2 GENERATION
DIISOCYANATE CLASSIFIED 0.002 MG/L
FOR MALE
REPRODUCTION
TOLUENE INHALATION NOT RAT NOAEL: DURING
DIISOCYANATE CLASSIFIED 0.004 MG/L ORGANOGENE-
FOR SIS
DEVELOPMENT
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
CARBITOL ACETATE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
CARBITOL ACETATE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
TOLUENE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
DIISOCYANATE IRRITATION IRRITATION
HEPTANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
HEPTANE INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
HEPTANE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
NAME SPECIES TEST RESULT EXPOSURE DURATION
CARBITOL ACETATE HUMAN AND ANIMAL NOAEL: NOT AVAILABLE NOT APPLICABLE
CARBITOL ACETATE MULTIPLE ANIMAL NOAEL: NOT AVAILABLE NOT APPLICABLE
SPECIES
TOLUENE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL
DIISOCYANATE EXPOSURE
HEPTANE HUMAN NOAEL: NOT AVAILABLE
HEPTANE HUMAN NOAEL: NOT AVAILABLE
HEPTANE HUMAN NOAEL: NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
TALC INHALATION PNEUMOCONIOSIS CAUSES DAMAGE TO
ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
TALC INHALATION PULMONARY FIBROSIS | NOT CLASSIFIED
RESPIRATORY SYSTEM
FUMED SILICA INHALATION RESPIRATORY SYSTEM | NOT CLASSIFIED
SILICOSIS
ZINC OXIDE INGESTION NERVOUS SYSTEM NOT CLASSIFIED
ZINC OXIDE INGESTION ENDOCRINE SYSTEM | NOT CLASSIFIED
HEMATOPOIETIC
SYSTEM | KIDNEY
AND/OR BLADDER
CARBITOL ACETATE INHALATION RESPIRATORY SYSTEM | NOT CLASSIFIED
LIVER | IMMUNE
SYSTEM | KIDNEY
AND/OR BLADDER
TITANIUM DIOXIDE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TITANIUM DIOXIDE INHALATION PULMONARY FIBROSIS NOT CLASSIFIED
IRON OXIDES INHALATION PULMONARY FIBROSIS | NOT CLASSIFIED
PNEUMOCONIOSIS
TOLUENE INHALATION RESPIRATORY SYSTEM CAUSES DAMAGE TO
DIISOCYANATE ORGANS THROUGH
PROLONGED OR
REPEATED EXPOSURE
HEPTANE INHALATION LIVER | NERVOUS NOT CLASSIFIED
SYSTEM | KIDNEY
AND/OR BLADDER
NAME SPECIES TEST RESULT EXPOSURE DURATION
TALC HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
TALC RAT NOAEL: 18 MG/M3 113 WEEKS
FUMED SILICA HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
ZINC OXIDE RAT NOAEL: 600 MG/KG/DAY 10 DAYS
ZINC OXIDE OTHER NOAEL: 500 MG/KG/DAY 6 MONTHS
CARBITOL ACETATE RAT NOAEL: 0.48 MG/L 2 WEEKS
TITANIUM DIOXIDE RAT LOAEL: 0.01 MG/L 2 YEARS
TITANIUM DIOXIDE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
IRON OXIDES HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
TOLUENE HUMAN NOAEL: 0 MG/L OCCUPATIONAL EXPOSURE
DIISOCYANATE
HEPTANE RAT NOAEL: 12 MG/L 26 WEEKS
ASPIRATION HAZARD:
NAME VALUE
HEPTANE ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY
REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. IF NO
OTHER DISPOSAL OPTIONS ARE AVAILABLE, WASTE PRODUCT THAT HAS BEEN
COMPLETELY CURED OR POLYMERIZED MAY BE PLACED IN A LANDFILL PROPERLY
DESIGNED FOR INDUSTRIAL WASTE. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
NOT REGULATED PER U.S. DOT, IATA OR IMO.
THESE TRANSPORTATION CLASSIFICATIONS ARE PROVIDED AS A CUSTOMER SERVICE. AS
THE SHIPPER YOU REMAIN RESPONSIBLE FOR COMPLYING WITH ALL APPLICABLE LAWS
AND REGULATIONS, INCLUDING PROPER TRANSPORTATION CLASSIFICATION AND
PACKAGING. 3M TRANSPORTATION CLASSIFICATIONS ARE BASED ON PRODUCT
FORMULATION, PACKAGING, 3M POLICIES AND 3M UNDERSTANDING OF APPLICABLE
CURRENT REGULATIONS. 3M DOES NOT GUARANTEE THE ACCURACY OF THIS
CLASSIFICATION INFORMATION. THIS INFORMATION APPLIES ONLY TO TRANSPORTATION
CLASSIFICATION AND NOT THE PACKAGING, LABELING, OR MARKING REQUIREMENTS.
THE ORIGINAL 3M PACKAGE IS CERTIFIED FOR U.S. GROUND SHIPMENT ONLY. IF YOU
ARE SHIPPING BY AIR OR OCEAN, THE PACKAGE MAY NOT MEET APPLICABLE
REGULATORY REQUIREMENTS.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
CARCINOGENICITY
RESPIRATORY OR SKIN SENSITIZATION
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
ZINC OXIDE (ZINC COMPOUNDS) 1314-13-2 1 - 5
CARBITOL ACETATE (GLYCOL ETHERS) 112-15-2 1 - 5
TOLUENE DIISOCYANATE 26471-62-5 TRADE SECRET <0.5
TOLUENE DIISOCYANATE (BENZENE, 26471-62-5 <0.5
1,3-DIISOCYANATOMETHYL-)
THIS MATERIAL CONTAINS A CHEMICAL WHICH REQUIRES EXPORT NOTIFICATION UNDER
TSCA SECTION 12[B]:
INGREDIENT (CATEGORY IF C.A.S. NO REGULATION STATUS
APPLICABLE)
TOLUENE DIISOCYANATE (BENZENE, 26471-62-5 TOXIC SUBSTANCES PROPOSED
1,3-DIISOCYANATOMETHYL-) CONTROL ACT
(TSCA) 5 SNUR
OR CONSENT ORDER
CHEMICALS
TOLUENE DIISOCYANATE 26471-62-5 TOXIC SUBSTANCES PROPOSED
CONTROL ACT
(TSCA) 5 SNUR
OR CONSENT
ORDER CHEMICALS
THIS MATERIAL CONTAINS A CHEMICAL SUBJECT TO A PROPOSED EPA SIGNIFICANT NEW
USE RULE (TSCA SECTION 5)
INGREDIENT (CATEGORY IF APPLICABLE) C.A.S. NO REFERENCE
TOLUENE DIISOCYANATE 26471-62-5 80 FR 2068
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. LISTING
TOLUENE DIISOCYANATE 26471-62-5 CARCINOGEN
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 19-4648-2
VERSION NUMBER: 9.01
ISSUE DATE: 01/19/18
SUPERCEDES DATE: 10/29/14
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM