| Common Name: | MARINE ADHESIVE SEALANT 5200, WHITE, PN 05203, PN 05206, PN 06500 |
| Manufacturer: | 3M |
| SDS Revision Date: | 7/25/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 4YDL4 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) MARINE ADHESIVE SEALANT 5200, WHITE, PN 05203, PN 05206, PN 06500
07/25/18
3M
SAFETY DATA SHEET
COPYRIGHT, 2018, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 16-3092-0
VERSION NUMBER: 15.07
ISSUE DATE: 07/25/18
SUPERCEDES DATE: 07/16/18
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) MARINE ADHESIVE SEALANT 5200, WHITE, PN 05203, PN 05206, PN 06500
PRODUCT IDENTIFICATION NUMBERS:
60-4100-0946-2, 60-4100-0947-0, 60-4100-0967-8, 60-9800-4300-8,
60-9801-0556-7, 60-9801-0843-9, 62-5225-5236-3, 62- 5239-5230-7
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
MARINE ADHESIVE SEALANT, ONE-PART POLYURETHANE ADHESIVE FOR MARINE
APPLICATIONS.
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION:
INDUSTRIAL ADHESIVES AND TAPES DIVISION
MARINE & SPECIALTY VEHICLE
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
RESPIRATORY SENSITIZER: CATEGORY 1.
SKIN SENSITIZER: CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS: HEALTH HAZARD
PICTOGRAMS: HEALTH HAZARD
HAZARD STATEMENTS:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE AN ALLERGIC SKIN REACTION.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
WEAR PROTECTIVE GLOVES.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
SUPPLEMENTAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A
CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES.
1% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
1% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
URETHANE PREPOLYMER 68611-34-7 30 - 60 TRADE SECRET *
TALC 14807-96-6 15 - 40 TRADE SECRET *
TITANIUM DIOXIDE 13463-67-7 5 - 10 TRADE SECRET *
FUMED SILICA 112945-52-5 0.5 - 5 TRADE SECRET *
ZINC OXIDE 1314-13-2 1 - 5 TRADE SECRET *
DIETHYLENE GLYCOL MONO- 112-15-2 1 - 5 TRADE SECRET *
ETHYL ETHER ACETATE
ALKYL ISOCYANATE SILANE 85702-90-5 0.5 - 1.5 TRADE SECRET *
(GAMMA-MERCAPTOPROPYL)- 4420-74-0 <0.19 TRADE SECRET *
TRIMETHOXYSILANE
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A CARBON DIOXIDE OR DRY CHEMICAL EXTINGUISHER TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
ISOCYANATES DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
HYDROGEN CYANIDE DURING COMBUSTION
IRRITANT VAPORS OR GASES DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
OXIDES OF SULFUR DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A CLOSED
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP
RESIDUE. SEAL THE CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS
POSSIBLE IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/
SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR
SMOKE WHEN USING THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED
WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. AVOID RELEASE TO
THE ENVIRONMENT. WASH CONTAMINATED CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED TO PREVENT CONTAMINATION WITH WATER OR AIR.
IF CONTAMINATION IS SUSPECTED, DO NOT RESEAL CONTAINER. KEEP COOL. PROTECT
FROM SUNLIGHT. STORE AWAY FROM HEAT. STORE AWAY FROM AMINES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY
SILICA, AMORPHOUS 112945-52-5 OSHA
ZINC OXIDE 1314-13-2 ACGIH
ZINC OXIDE 1314-13-2 OSHA
TITANIUM DIOXIDE 13463-67-7 ACGIH
TITANIUM DIOXIDE 13463-67-7 OSHA
DUST, INERT OR NUISANCE 14807-96-6 OSHA
TALC 14807-96-6 ACGIH
TALC 14807-96-6 OSHA
INGREDIENT LIMIT TYPE ADDITIONAL
COMMENTS
SILICA, AMORPHOUS TWA CONCENTRATION: 0.8 MG/M3;
TWA: 20 MILLIONS OF
PARTICLES/CU. FT.
ZINC OXIDE TWA(RESPIRABLE FRACTION):
2 MG/M3;
STEL(RESPIRABLE FRACTION):
10 MG/M3
ZINC OXIDE TWA(AS FUME): 5 MG/M3;
TWA(AS TOTAL DUST): 15 MG/M3;
TWA(RESPIRABLE FRACTION):
5 MG/M3
TITANIUM DIOXIDE TWA: 10 MG/M3 A4:
NOT CLASS.
AS HUMAN
CARCIN
TITANIUM DIOXIDE TWA(AS TOTAL DUST): 15 MG/M3
DUST, INERT OR NUISANCE TWA(AS TOTAL DUST): 15 MG/M3;
TWA(AS TOTAL DUST):
50 MILLIONS OF PARTICLES/CU.
FT. (15 MG/M3);
TWA(RESPIRABLE FRACTION):
15 MILLIONS OF PARTICLES/CU.
FT. 5 MG/M3);
TWA(RESPIRABLE FRACTION):
5 MG/M3
TALC TWA(RESPIRABLE FRACTION): A4:
2 MG/M3 NOT CLASS.
AS HUMAN
CARCIN
TALC TWA: 2 MG/M3
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS: USE GENERAL DILUTION VENTILATION AND/OR
LOCAL EXHAUST VENTILATION TO CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT
EXPOSURE LIMITS AND/OR CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF
VENTILATION IS NOT ADEQUATE, USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
SAFETY GLASSES WITH SIDE SHIELDS
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING. NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: SOLID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: WHITE
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO FLASH POINT
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT CLASSIFIED
FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE
FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.36 G/ML
SPECIFIC GRAVITY: 1.36 [REF STD: WATER=1]
SOLUBILITY IN WATER: NO DATA AVAILABLE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 100,000 - 500,000 CENTIPOISE
HAZARDOUS AIR POLLUTANTS: <=0.2% WEIGHT [TEST METHOD: CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
PERCENT VOLATILE: 2.9% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
40 G/L [TEST METHOD: TESTED PER EPA METHOD 24]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT
10.5. INCOMPATIBLE MATERIALS:
REACTION WITH WATER, ALCOHOLS, AND AMINES IS NOT HAZARDOUS IF CONTAINER CAN
VENT TO THE ATMOSPHERE TO PREVENT PRESSURE BUILDUP.
AMINES
ALCOHOLS
WATER
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
ALLERGIC RESPIRATORY REACTION:
SIGNS/SYMPTOMS MAY INCLUDE DIFFICULTY BREATHING, WHEEZING, COUGH, AND
TIGHTNESS OF CHEST.
SKIN CONTACT:
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
CONTACT WITH THE EYES DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
CARCINOGENICITY:
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
TITANIUM DIOXIDE 13463-67-7 GRP. 2B: INTERNATIONAL AGENCY
POSSIBLE HUMAN CARC. FOR RESEARCH ON CANCER
ADDITIONAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A
CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
TALC DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
TALC INGESTION LD50:
ESTIMATED TO BE
>5,000 MG/KG
TITANIUM DIOXIDE DERMAL RABBIT LD50: >10,000 MG/KG
TITANIUM DIOXIDE INHALATION- RAT LC50: >6.82 MG/L
DUST/MIST
(4 HOURS)
TITANIUM DIOXIDE INGESTION RAT LD50: >10,000 MG/KG
FUMED SILICA DERMAL RABBIT LD50: >5,000 MG/KG
FUMED SILICA INHALATION- RAT LC50: >0.691 MG/L
DUST/MIST
(4 HOURS)
FUMED SILICA INGESTION RAT LD50: >5,110 MG/KG
ZINC OXIDE DERMAL LD50:
ESTIMATED TO BE
>5,000 MG/KG
ZINC OXIDE INHALATION- RAT LC50: >5.7 MG/L
DUST/MIST
(4 HOURS)
ZINC OXIDE INGESTION RAT LD50: >5,000 MG/KG
DIETHYLENE GLYCOL DERMAL RABBIT LD50: 15,000 MG/KG
MONOETHYL ETHER
ACETATE
DIETHYLENE GLYCOL INGESTION RAT LD50: 11,000 MG/KG
MONOETHYL ETHER
ACETATE
(GAMMA-MERCAPTO- DERMAL RABBIT LD50: 2,270 MG/KG
PROPYL)TRIMETHOXY-
SILANE
(GAMMA-MERCAPTO- INGESTION RAT LD50: 770 MG/KG
PROPYL)TRIMETHOXY-
SILANE
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
TALC RABBIT NO SIGNIFICANT IRRITATION
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
FUMED SILICA RABBIT NO SIGNIFICANT IRRITATION
ZINC OXIDE HUMAN AND ANIMAL NO SIGNIFICANT IRRITATION
DIETHYLENE GLYCOL HUMAN AND ANIMAL MINIMAL IRRITATION
MONOETHYL ETHER ACETATE
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
TALC RABBIT NO SIGNIFICANT IRRITATION
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
FUMED SILICA RABBIT NO SIGNIFICANT IRRITATION
ZINC OXIDE RABBIT MILD IRRITANT
DIETHYLENE GLYCOL RABBIT SEVERE IRRITANT
MONOETHYL ETHER ACETATE
SKIN SENSITIZATION:
NAME SPECIES VALUE
TITANIUM DIOXIDE HUMAN AND ANIMAL NOT CLASSIFIED
FUMED SILICA HUMAN AND ANIMAL NOT CLASSIFIED
ZINC OXIDE GUINEA PIG NOT CLASSIFIED
DIETHYLENE GLYCOL HUMAN AND ANIMAL NOT CLASSIFIED
MONOETHYL ETHER ACETATE
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
TALC HUMAN NOT CLASSIFIED
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
TALC IN VITRO NOT MUTAGENIC
TALC IN VIVO NOT MUTAGENIC
TITANIUM DIOXIDE IN VITRO NOT MUTAGENIC
TITANIUM DIOXIDE IN VIVO NOT MUTAGENIC
FUMED SILICA IN VITRO NOT MUTAGENIC
ZINC OXIDE IN VITRO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
ZINC OXIDE IN VIVO SOME POSITIVE DATA EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR CLASSIFICATION
DIETHYLENE GLYCOL IN VITRO NOT MUTAGENIC
MONOETHYL ETHER ACETATE
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
TALC INHALATION RAT SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
TITANIUM DIOXIDE INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
TITANIUM DIOXIDE INHALATION RAT CARCINOGENIC
FUMED SILICA NOT SPECIFIED MOUSE SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
TALC INGESTION NOT CLASSIFIED FOR DEVELOPMENT
FUMED SILICA INGESTION NOT CLASSIFIED FOR FEMALE REPRODUCTION
FUMED SILICA INGESTION NOT CLASSIFIED FOR MALE REPRODUCTION
FUMED SILICA INGESTION NOT CLASSIFIED FOR DEVELOPMENT
ZINC OXIDE INGESTION NOT CLASSIFIED FOR REPRODUCTION
AND/OR DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
TALC RAT NOAEL: 1,600 MG/KG DURING ORGANOGENESIS
FUMED SILICA RAT NOAEL: 509 MG/KG/DAY 1 GENERATION
FUMED SILICA RAT NOAEL: 497 MG/KG/DAY 1 GENERATION
FUMED SILICA RAT NOAEL: 1,350 MG/KG/DAY DURING ORGANOGENESIS
ZINC OXIDE MULTIPLE NOAEL: 125 MG/KG/DAY PREMATING & DURING
ANIMAL GESTATION
SPECIES
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
DIETHYLENE GLYCOL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
MONOETHYL ETHER SYSTEM DEPRESSION OR DIZZINESS
ACETATE
DIETHYLENE GLYCOL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
MONOETHYL ETHER SYSTEM DEPRESSION OR DIZZINESS
ACETATE
NAME SPECIES TEST RESULT EXPOSURE DURATION
DIETHYLENE GLYCOL HUMAN AND NOAEL: NOT AVAILABLE NOT APPLICABLE
MONOETHYL ETHER ANIMAL
ACETATE
DIETHYLENE GLYCOL MULTIPLE NOAEL: NOT AVAILABLE NOT APPLICABLE
MONOETHYL ETHER ANIMAL
ACETATE SPECIES
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
TALC INHALATION PNEUMOCONIOSIS CAUSES DAMAGE TO
ORGANS THROUGH
PROLONGED OR REPEATED
EXPOSURE
TALC INHALATION PULMONARY FIBROSIS | NOT CLASSIFIED
RESPIRATORY SYSTEM
TITANIUM DIOXIDE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR
CLASSIFICATION
TITANIUM DIOXIDE INHALATION PULMONARY FIBROSIS NOT CLASSIFIED
FUMED SILICA INHALATION RESPIRATORY SYSTEM | NOT CLASSIFIED
SILICOSIS
ZINC OXIDE INGESTION NERVOUS SYSTEM NOT CLASSIFIED
ZINC OXIDE INGESTION ENDOCRINE SYSTEM | NOT CLASSIFIED
HEMATOPOIETIC
SYSTEM | KIDNEY
AND/OR BLADDER
DIETHYLENE GLYCOL INHALATION RESPIRATORY SYSTEM | NOT CLASSIFIED
MONOETHYL ETHER LIVER | IMMUNE
ACETATE SYSTEM | KIDNEY
AND/OR BLADDER
NAME SPECIES TEST RESULT EXPOSURE DURATION
TALC HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
TALC RAT NOAEL: 18 MG/M3 113 WEEKS
TITANIUM DIOXIDE RAT LOAEL: 0.01 MG/L 2 YEARS
TITANIUM DIOXIDE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
FUMED SILICA HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
ZINC OXIDE RAT NOAEL: 600 MG/KG/DAY 10 DAYS
ZINC OXIDE OTHER NOAEL: 500 MG/KG/DAY 6 MONTHS
DIETHYLENE GLYCOL RAT NOAEL: 0.48 MG/L 2 WEEKS
MONOETHYL ETHER
ACETATE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. AS A
DISPOSAL ALTERNATIVE, INCINERATE IN A PERMITTED WASTE INCINERATION
FACILITY. PROPER DESTRUCTION MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING
INCINERATION PROCESSES. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL SUBSTANCES/
MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS: RESPIRATORY OR SKIN SENSITIZATION
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
ZINC OXIDE (ZINC COMPOUNDS) 1314-13-2 1 - 5
DIETHYLENE GLYCOL MONOETHYL ETHER ACETATE 112-15-2 1 - 5
(GLYCOL ETHERS)
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. LISTING
CADMIUM COMPOUNDS NONE MALE REPRODUCTIVE TOXIN
CADMIUM COMPOUNDS NONE CARCINOGEN
CADMIUM COMPOUNDS NONE DEVELOPMENTAL TOXIN
TOLUENE DIISOCYANATE 26471-62-5 CARCINOGEN
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS
PRODUCT ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 16-3092-0
VERSION NUMBER: 15.07
ISSUE DATE: 07/25/18
SUPERCEDES DATE: 07/16/18
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM