| Common Name: | IRON OUT (POWDER) |
| Manufacturer: | IRON OUT DBA SUMMIT BRANDS |
| SDS Revision Date: | 3/16/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 4YJW2, 4YJW3, 4YJW4, 4YJW5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SUMMIT BRANDS
SPECIALTY CLEARERS
SAFETY DATA SHEET
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER: IRON OUT (POWDER)
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE
RECOMMENDED USE: RUST & STAIN REMOVER
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER:
IRON OUT DBA SUMMIT BRANDS
7201 ENGLE ROAD
FORT WAYNE, IN 46804-5875
US
PHONE: 260-483-2519
EMERGENCY PHONE: 1-800-424-9300 (CHEMTREC)
| 2. HAZARDS IDENTIFICATION | |
PHYSICAL HAZARDS: NOT CLASSIFIED.
HEALTH HAZARDS:
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SENSITIZATION, RESPIRATORY: CATEGORY 1
SENSITIZATION, SKIN: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE RESPIRATORY TRACT
IRRITATION: CATEGORY 3
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
CORROSION
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
CAUSES SERIOUS EYE DAMAGE. MAY CAUSE AN ALLERGIC SKIN REACTION. MAY CAUSE
ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED. MAY CAUSE
RESPIRATORY IRRITATION.
PRECAUTIONARY STATEMENT:
PREVENTION:
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. AVOID BREATHING DUST. IN
CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION. WEAR EYE/FACE
PROTECTION. WEAR PROTECTIVE GLOVES. CONTAMINATED WORK CLOTHING MUST NOT BE
ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER/DOCTOR. SPECIFIC TREATMENT (SEE THIS LABEL).
IF EXPERIENCING RESPIRATORY SYMPTOMS: CALL A POISON CENTER/DOCTOR.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NOT APPLICABLE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURE:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
SODIUM HYDROSULFITE 7775-14-6 15 - 40
SODIUM CARBONATE 497-19-8 10 - 30
SODIUM METABISULFITE 7681-57-4 10 - 30
CITRIC ACID 77-92-9 1 - 5
SODIUM SULFITE 7757-83-7 0.5 - 1.5
COMPOSITION COMMENTS:
US GHS:
THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS A
TRADE SECRET IN ACCORDANCE WITH PARAGRAPH (I) OF SUBSECTION 1910.1200.
| 4. FIRST AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. DO NOT USE
MOUTH-TO-MOUTH METHOD IF VICTIM INHALED THE SUBSTANCE. INDUCE ARTIFICIAL
RESPIRATION WITH THE AID OF A POCKET MASK EQUIPPED WITH A ONE-WAY VALVE OR
OTHER PROPER RESPIRATORY MEDICAL DEVICE.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH SKIN WITH SOAP AND WATER.
IN CASE OF ECZEMA OR OTHER SKIN DISORDERS:
SEEK MEDICAL ATTENTION AND TAKE ALONG THESE INSTRUCTIONS. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. GET MEDICAL ATTENTION
IMMEDIATELY. CONTINUE RINSING.
INGESTION:
RINSE MOUTH. IF INGESTION OF A LARGE AMOUNT DOES OCCUR, CALL A POISON
CONTROL CENTER IMMEDIATELY.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED
VISION. PERMANENT EYE DAMAGE INCLUDING BLINDNESS COULD RESULT. MAY CAUSE AN
ALLERGIC SKIN REACTION. DERMATITIS. RASH. MAY CAUSE ALLERGIC RESPIRATORY
REACTION.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. WASH CONTAMINATED CLOTHING BEFORE
REUSE. AVOID CONTACT WITH EYES AND SKIN. KEEP OUT OF REACH OF CHILDREN.
| 5. FIRE FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA: DRY CHEMICAL. CARBON DIOXIDE. FOAM.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN THE EVENT OF FIRE, COOL TANKS WITH WATER SPRAY.
SPECIFIC METHODS:
COOL CONTAINERS EXPOSED TO FLAMES WITH WATER UNTIL WELL AFTER THE FIRE IS
OUT.
GENERAL FIRE HAZARDS: NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
HAZARDOUS COMBUSTION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO:
OXIDES OF CARBON. OXIDES OF SULFUR. HYDROGEN SULFIDE. HYDROGEN CHLORIDE.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NOT AVAILABLE.
SENSITIVITY TO STATIC DISCHARGE: NOT AVAILABLE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING. ENSURE ADEQUATE VENTILATION. LOCAL
AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE CONTAINED.
FOR PERSONAL PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK. PREVENT ENTRY INTO
WATERWAYS, SEWER, BASEMENTS OR CONFINED AREAS. FOLLOWING PRODUCT RECOVERY,
FLUSH AREA WITH WATER. FOR WASTE DISPOSAL, SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
DO NOT GET THIS MATERIAL IN CONTACT WITH EYES. AVOID CONTACT WITH SKIN.
AVOID PROLONGED EXPOSURE. AVOID CONTACT WITH CLOTHING. PROVIDE ADEQUATE
VENTILATION. IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY
EQUIPMENT. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. OBSERVE GOOD
INDUSTRIAL HYGIENE PRACTICES. USE CARE IN HANDLING/STORAGE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A WELL-VENTILATED
PLACE. STORE AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
SODIUM METABISULFITE (CAS 7681-57-4) TWA 5 MG/M3
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
SODIUM METABISULFITE (CAS 7681-57-4) TWA 5 MG/M3
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENT(S).
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL. PROVIDE EYEWASH STATION.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS.
SKIN PROTECTION:
HAND PROTECTION: WEAR APPROPRIATE CHEMICAL RESISTANT GLOVES.
OTHER: WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING.
RESPIRATORY PROTECTION:
USE ONLY UNDER GOOD VENTILATION CONDITIONS OR WITH RESPIRATORY PROTECTION.
THERMAL HAZARDS: NOT APPLICABLE.
GENERAL HYGIENE CONSIDERATIONS:
ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER
HANDLING THE MATERIAL AND BEFORE EATING, DRINKING, AND/OR SMOKING.
ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO REMOVE
CONTAMINANTS. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE
WORKPLACE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: FREE-FLOWING
PHYSICAL STATE: SOLID.
FORM: POWDER
COLOR: WHITE
ODOR: MINT
ODOR THRESHOLD: NOT AVAILABLE.
PH: 5.5 - 6.5
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE.
POUR POINT: NOT AVAILABLE.
SPECIFIC GRAVITY: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
FLASH POINT: NONE
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE.
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: 1.2 - 1.3 G/ML
SOLUBILITY(IES): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THIS PRODUCT MAY REACT WITH STRONG ACIDS. THIS PRODUCT MAY REACT WITH
OXIDIZING AGENTS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
CONDITIONS TO AVOID: CONTACT WITH INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: ACIDS. OXIDIZERS.
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO:
OXIDES OF CARBON. OXIDES OF SULFUR. HYDROGEN SULPHIDE. HYDROGEN CHLORIDE.
| 11. TOXICOLOGICAL INFORMATION | |
ROUTES OF EXPOSURE: EYE, SKIN CONTACT, INHALATION, INGESTION.
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD.
INHALATION:
PROLONGED INHALATION MAY BE HARMFUL. MAY CAUSE IRRITATION TO THE
RESPIRATORY SYSTEM. MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING
DIFFICULTIES IF INHALED.
SKIN CONTACT: MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED
VISION. PERMANENT EYE DAMAGE INCLUDING BLINDNESS COULD RESULT. MAY CAUSE AN
ALLERGIC SKIN REACTION. DERMATITIS. RASH.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
EYE IRRITATION MAY CAUSE AN ALLERGIC SKIN REACTION. MAY CAUSE ALLERGY OR
ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED. MAY CAUSE RESPIRATORY
IRRITATION.
COMPONENTS SPECIES TEST RESULTS
CITRIC ACID (CAS 77-92-9):
ACUTE:
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 MOUSE 5040 MG/KG
RAT 3000 MG/KG
SODIUM CARBONATE (CAS 497-19-8):
ACUTE:
DERMAL:
LD50 RAT >2000 MG/KG
INHALATION:
LC50 GUINEA PIG 400 MG/M3
0.8 MG/L, 2 HOURS
MOUSE 1.2 MG/L, 2 HOURS
RAT 2.3 MG/L, 2 HOURS
ORAL:
LD50 RAT 4090 MG/KG
SODIUM HYDROSULFITE (CAS 7775-14-6):
ACUTE:
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 RAT 2500 MG/KG
SODIUM METABISULFITE (CAS 7681-57-4):
ACUTE:
DERMAL:
LD50 GUINEA PIG 1000 MG/KG
RAT 2000 MG/KG
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 RAT 1131 MG/KG
SHEEP 2515 MG/KG
2.5 G/KG
SODIUM SULFITE (CAS 7757-83-7):
ACUTE:
DERMAL:
LD50 NOT AVAILABLE
INHALATION:
LC50 RAT >5.5 MG/L/4H
ORAL:
LD50 MOUSE 820 MG/KG
RAT 3560 MG/KG
SKIN CORROSION/IRRITATION:
PROLONGED SKIN CONTACT MAY CAUSE TEMPORARY IRRITATION.
EXPOSURE MINUTES: NOT AVAILABLE.
ERYTHEMA VALUE: NOT AVAILABLE.
OEDEMA VALUE: NOT AVAILABLE.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE DAMAGE.
CORNEAL OPACITY VALUE: NOT AVAILABLE.
IRIS LESION VALUE: NOT AVAILABLE.
CONJUNCTIVAL REDDENING VALUE: NOT AVAILABLE.
CONJUNCTIVAL OEDEMA VALUE: NOT AVAILABLE.
RECOVER DAYS: NOT AVAILABLE.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY:
THIS PRODUCT IS NOT CONSIDERED TO BE A CARCINOGEN BY IARC, ACGIH, NTP, OR
OSHA.
ACGIH CARCINOGENS:
SODIUM METABISULFITE (CAS 7681-57-4):
A4 NOT CLASSIFIABLE AS A HUMAN CARCINOGEN.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
SODIUM METABISULFITE (CAS 7681-57-4):
VOLUME 54 - 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
SODIUM SULFITE (CAS 7757-83-7):
VOLUME 54 - 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
TERATOGENICITY: NOT CLASSIFIED.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
RESPIRATORY TRACT IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT CLASSIFIED.
CHRONIC EFFECTS: PROLONGED INHALATION MAY BE HARMFUL.
FURTHER INFORMATION: NOT AVAILABLE.
NAME OF TOXICOLOGICALLY SYNERGISTIC PRODUCTS: NOT AVAILABLE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT CLASSIFIED AS ENVIRONMENTALLY HAZARDOUS. HOWEVER, THIS
DOES NOT EXCLUDE THE POSSIBILITY THAT LARGE OR FREQUENT SPILLS CAN HAVE A
HARMFUL OR DAMAGING EFFECT ON THE ENVIRONMENT. SEE BELOW
COMPONENTS SPECIES TEST RESULTS
CITRIC ACID (CAS 77-92-9):
ACUTE:
CRUSTACEA EC50 DAPHNIA MAGNA 120 MG/L, 72 HR
AQUATIC:
ACUTE:
FISH LC50 BLUEGILL (LEPOMIS 1516 MG/L, 96 HR
MACROCHIRUS)
SODIUM CARBONATE (CAS 497-19-8):
CRUSTACEA EC50 DAPHNIA 265 MG/L, 48 HOURS
AQUATIC:
CRUSTACEA EC50 WATER FLEA 156.6 - 298.9 MG/L, 48 HOURS
(CERIODAPHNIA
DUBIA)
FISH LC50 BLUEGILL (LEPOMIS 300 MG/L, 96 HOURS
MACROCHIRUS)
SODIUM HYDROSULFITE (CAS 7775-14-6):
ALGAE IC50 ALGAE 120 MG/L, 72 HOURS
CRUSTACEA EC50 DAPHNIA 98 MG/L, 48 HOURS
SODIUM METABISULFITE (CAS 7681-57-4):
ALGAE IC50 ALGAE 48 MG/L, 72 HOURS
SODIUM SULFITE (CAS 7757-83-7):
AQUATIC:
FISH LC50 WESTERN MOSQUITOFISH 660 MG/L, 96 HOURS
(GAMBUSIA AFFINIS)
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
MOBILITY IN SOIL: NO DATA AVAILABLE.
MOBILITY IN GENERAL: NOT AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS
HAZARDOUS WASTE. DO NOT ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER
SUPPLIES. DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL
OR USED CONTAINER. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
| 14. TRANSPORT INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION (DOT): NOT REGULATED AS DANGEROUS GOODS.
TRANSPORTATION OF DANGEROUS GOODS (TDG - CANADA):
NOT REGULATED AS DANGEROUS GOODS.
| 15. REGULATORY INFORMATION | |
CANADIAN FEDERAL REGULATIONS:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CONTROLLED PRODUCTS REGULATIONS AND THE SDS CONTAINS ALL THE
INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
CANADA WHMIS INGREDIENT DISCLOSURE THRESHOLD LIMITS
CITRIC ACID (CAS 77-92-9) 1%
SODIUM CARBONATE (CAS 497-19-8) 1%
SODIUM METABISULFITE (CAS 7681-57-4) 1%
WHMIS STATUS: CONTROLLED
WHMIS CLASSIFICATION: CLASS D - DIVISION 2A, 2B
WHMIS LABELING:
D2 - MATERIALS CAUSING OTHER TOXIC EFFECTS
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4): NOT LISTED.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130): NOT REGULATED.
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: YES
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SARA 311/312 HAZARDOUS CHEMICAL: NO
SARA 313 (TRI REPORTING): NOT REGULATED.
OTHER FEDERAL REGULATIONS:
CLEAN WATER ACT (CWA) SECTION 112(R) (40 CFR 68.130): HAZARDOUS SUBSTANCE
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
US STATE REGULATIONS:
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986
(PROPOSITION 65):
THIS MATERIAL IS NOT KNOWN TO CONTAIN ANY CHEMICALS CURRENTLY LISTED AS
CARCINOGENS OR REPRODUCTIVE TOXINS.
US - CALIFORNIA HAZARDOUS SUBSTANCES (DIRECTOR'S) LISTED SUBSTANCE
SODIUM METABISULFITE (CAS 7681-57-4) LISTED.
US - CALIFORNIA PROPOSITION 65 - CARCINOGENS & LISTED SUBSTANCE
REPRODUCTIVE TOXICITY (CRT)
NOT LISTED.
US - MINNESOTA HAZ SUBS LISTED SUBSTANCE
SODIUM METABISULFITE (CAS 7681-57-4) LISTED.
US - NEW JERSEY RTK - SUBSTANCES LISTED SUBSTANCE
SODIUM HYDROSULFITE (CAS 7775-14-6) LISTED.
SODIUM METABISULFITE (CAS 7681-57-4) LISTED.
US - TEXAS EFFECTS SCREENING LEVELS LISTED SUBSTANCE
CITRIC ACID (CAS 77-92-9) LISTED.
SODIUM CARBONATE (CAS 497-19-8) LISTED.
SODIUM HYDROSULFITE (CAS 7775-14-6) LISTED.
SODIUM METABISULFITE (CAS 7681-57-4) LISTED.
SODIUM SULFITE (CAS 7757-83-7) LISTED.
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
SODIUM HYDROSULFITE (CAS 7775-14-6): LISTED.
SODIUM METABISULFITE (CAS 7681-57-4): LISTED.
US. PENNSYLVANIA RTK - HAZARDOUS SUBSTANCES:
SODIUM HYDROSULFITE (CAS 7775-14-6): LISTED.
SODIUM METABISULFITE (CAS 7681-57-4): LISTED.
US. RHODE ISLAND RTK: NOT REGULATED.
INVENTORY STATUS:
COUNTRY(S) INVENTORY NAME ON INVENTORY
OR REGION (YES/NO)*
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
UNITED STATES TOXIC SUBSTANCES CONTROL ACT (TSCA) INVENTORY YES
& PUERTO RICO
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
| 16. OTHER INFORMATION | |
HEALTH 2*
FLAMMABILITY 0
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA:
2
0
1
LEGEND:
SEVERE: 4
SERIOUS: 3
MODERATE: 2
SLIGHT: 1
MINIMAL: 0
DISCLAIMER:
THE DATA CONTAINED IN THIS MATERIAL SAFETY DATA SHEET WAS OBTAINED FROM
SOURCES THAT WERE TECHNICALLY ACCURATE, RELIABLE, AND STATE OF THE ART WHEN
THIS DOCUMENT WAS PREPARED. IF DATA WAS UNAVAILABLE TO COMPLETE CERTAIN
SECTIONS, THE ABSENCE OF THAT DATA IS IDENTIFIED IN THIS DOCUMENT. BECAUSE
THE SUPPLIER CANNOT KNOW THE EXACT CIRCUMSTANCES DURING ACTUAL USE OF THIS
PRODUCT, OTHER HAZARDS, EXPOSURE SCENARIOS, DISPOSAL CONSIDERATIONS, AND
REGULATIONS MAY APPLY AND IT IS THE RESPONSIBILITY OF THE USER TO READ AND
UNDERSTAND THE PRODUCT LABEL AND THIS DOCUMENT BEFORE USE. DO NOT USE THE
PRODUCT FOR PURPOSES OTHER THAN THOSE STATED IN SECTION 1.
ISSUE DATE: 16-MARCH-2015
EFFECTIVE DATE: 01-AUGUST-2014
EXPIRY DATE: 01-AUGUST-2017
FURTHER INFORMATION:
FOR AN UPDATED SDS, PLEASE CONTACT THE SUPPLIER/MANUFACTURER LISTED IN THE
BEGINNING OF THIS DOCUMENT.
PREPARED BY: DELL TECH LABORATORIES, LTD.
PHONE: (519) 858-5021
OTHER INFORMATION:
THIS SAFETY DATA SHEET WAS PREPARED TO COMPLY WITH THE CURRENT OSHA HAZARD
COMMUNICATION STANDARD (HCS) ADOPTION OF THE GLOBALLY HARMONIZED SYSTEM OF
CLASSIFICATION AND LABELING OF CHEMICALS (GHS).
THIS SDS CONFORMS TO THE ANSI Z400.1/Z129.1-2010 STANDARD.
REDBOOK REVISION #: 14, 11/4/13
#7840