| Common Name: | AUTORF QT 4PK BLACK TRUCK BED, 248915 |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 5/18/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 4YLD2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DATE PRINTED: 5/18/2015
SAFETY DATA SHEET
RUST-OLEUM CORPORATION
TRUSTED QUALITY SINCE 1921
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: AUTORF QT 4PK BLACK TRUCK BED
PRODUCT IDENTIFIER: 248915
PRODUCT USE/CLASS: TOPCOAT/ACRYLIC
REVISION DATE: 5/18/2015
SUPERCEDES DATE: 5/15/2015
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
| 2. HAZARD IDENTIFICATION | |
EMERGENCY OVERVIEW:
HARMFUL IF SWALLOWED. CAUSES EYE IRRITATION. FLAMMABLE LIQUID AND VAPOR.
CAUSES NOSE AND THROAT IRRITATION. HARMFUL IF INHALED. MAY AFFECT THE
BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. VAPOR
HARMFUL. CAUSES EYE, SKIN, NOSE, AND THROAT IRRITATION. MAY CAUSE EYE,
SKIN, OR RESPIRATORY TRACT IRRITATION. KEEP OUT OF REACH OF CHILDREN.
HARMFUL IF INHALED. USE VENTILATION NECESSARY TO KEEP EXPOSURES BELOW
RECOMMENDED EXPOSURE LIMITS, IF ANY.
CLASSIFICATION:
SYMBOL(S) OF PRODUCT:
EXCLAMATION MARK
HEALTH HAZARD
FLAME
SIGNAL WORD: DANGER
GHS HAZARD STATEMENTS:
FLAMMABLE LIQUID, CATEGORY 2:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
ACUTE TOXICITY, ORAL, CATEGORY 5:
H303: MAY BE HARMFUL IF SWALLOWED.
ACUTE TOXICITY, DERMAL, CATEGORY 5:
H313: MAY BE HARMFUL IN CONTACT WITH SKIN.
SKIN IRRITATION, CATEGORY 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRITATION, CATEGORY 2:
H319: CAUSES SERIOUS EYE IRRITATION.
ACUTE TOXICITY, INHALATION, CATEGORY 4:
H332: HARMFUL IF INHALED.
STOT, SINGLE EXPOSURE, CATEGORY 3, RTI:
H335: MAY CAUSE RESPIRATORY IRRITATION.
STOT, SINGLE EXPOSURE, CATEGORY 3, NE:
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
ORGANIC PEROXIDE, CATEGORIES C, D:
H242: HEATING MAY CAUSE A FIRE.
ASPIRATION HAZARD, CATEGORY 2:
H305: MAY BE HARMFUL IF SWALLOWED AND ENTERS AIRWAYS
EYE IRRITATION, CATEGORY 2B:
H320: CAUSES EYE IRRITATION
GERM CELL MUTAGENICITY, CATEGORY 1B:
H340:
MAY CAUSE GENETIC DEFECTS. CLASSIFIED AS MUTAGENIC CATEGORY 1 IF ONE
INGREDIENT IS PRESENT AT OR ABOVE 0.1% APPLIES TO LIQUIDS, SOLIDS
(W/W UNITS) AND GASES (V/V). THE SUBSTANCE MAY ALSO HAVE ITS OWN EXPOSURE
LIMIT. ROUTES OF EXPOSURE ARE DEPENDANT ON INGREDIENT FORM.
CARCINOGENICITY, CATEGORY 1B:
H350:
MAY CAUSE CANCER. CLASSIFIED AS CARCINOGENIC CATEGORY 1 ON THE BASIS OF
EPIDEMIOLOGICAL AND/OR ANIMAL DATA. MIXTURES ARE CLASSIFIED AS CARCINOGENIC
WHEN AT LEAST 1 INGREDIENT HAS BEEN CLASSIFIED AS CARCINOGENIC AND IS
PRESENT AT 0.1% OR ABOVE ROUTES OF EXPOSURE ARE DEPENDANT ON INGREDIENT
FORM.
REPRODUCTIVE TOXICITY, CATEGORY 2:
H361:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. CLASSIFED CATEGORY 2
SUSPECTED HUMAN REPRODUCTIVE TOXICANT IRREVERSIBLE EFFECTS SUCH AS
STRUCTURAL MALFUNCTIONS, EMBRYO/FOETAL LETHALITY, POST NATAL FUNCTIONAL
DEFICIENCIES.
ACUTE TOXICITY, DERMAL, CATEGORY 4:
H312: HARMFUL IN CONTACT WITH SKIN.
GHS LABEL PRECAUTIONARY STATEMENTS:
P102: KEEP OUT OF REACH OF CHILDREN.
P103: READ LABEL BEFORE USE.
P234: KEEP ONLY IN ORIGINAL CONTAINER.
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P262: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
P264: WASH ... THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P285: IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P350: GENTLY WASH WITH PLENTY OF SOAP AND WATER.
P374: FIGHT FIRE WITH NORMAL PRECAUTIONS FROM A REASONABLE DISTANCE.
P402: STORE IN A DRY PLACE.
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P362: TAKE OFF CONTAMINATED CLOTHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% GHS SYMBOLS GHS STATEMENTS
RANGE
SOLVENT NAPHTHA, 64742-95-6 10-25 GHS08 H340-350
LIGHT AROMATIC
1,2,4-TRIMETHYLBENZENE 95-63-6 10-25 GHS02-GHS07 H226-335-332-
315-319
ETHYLENE GLYCOL 111-76-2 2.5-10 GHS02-GHS06 H226-302-311-
MONOBUTYL ETHER 332-315-319
TOLUENE 108-88-3 2.5-10 GHS02-GHS07- H225-302-332-
GHS08 361-336-373-315
AROMATIC PETROLEUM 64742-94-5 2.5-10 GHS06 H227-310
DISTILLATES
1,3,5-TRIMETHYLBENZENE 108-67-8 2.5-10 GHS02-GHS07 H226-335
XYLENE (MIXED ISOMERS) 1330-20-7 1.0-2.5 GHS02-GHS07 H226-312-332-315
DIETHYLBENZENE, MIXED 25340-17-4 1.0-2.5 GHS02 H226
ISOMERS
CARBON BLACK 1333-86-4 1.0-2.5 GHS02 H251
ETHYLBENZENE 100-41-4 0.1-1.0 GHS02-GHS07 H225-332
NAPHTHALENE 91-20-3 0.1-1.0 GHS02-GHS07- H228-312-351-302
GHS08
THE TEXT FOR GHS HAZARD STATEMENTS SHOWN ABOVE (IF ANY) IS GIVEN IN THE
"16. OTHER INFORMATION" SECTION.
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES OR
KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION:
ASPIRATION HAZARD:
DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL CAN
ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. GET IMMEDIATE MEDICAL
ATTENTION. IF SWALLOWED, GET MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAME. VAPORS CAN
TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. VAPORS MAY FORM EXPLOSIVE
MIXTURES WITH AIR. NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT DUE TO BUILDUP OF
STEAM. KEEP CONTAINERS TIGHTLY CLOSED.
SPECIAL FIREFIGHTING PROCEDURES:
WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILDUP AND
POSSIBLE AUTOIGNITION OR EXPLOSION. EVACUATE AREA AND FIGHT FIRE FROM A
SAFE DISTANCE. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL.
CONTAINERS MAY EXPLODE WHEN HEATED.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS
SUCH AS SAWDUST. ELIMINATE ALL IGNITION SOURCES; USE EXPLOSION-PROOF
EQUIPMENT. PLACE MATERIAL IN A CONTAINER AND DISPOSE OF ACCORDING TO LOCAL,
PROVINCIAL, STATE AND FEDERAL REGULATIONS. REMOVE ALL SOURCES OF IGNITION,
VENTILATE AREA AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS.
DISPOSE OF ACCORDING TO LOCAL, STATE (PROVINCIAL) AND FEDERAL REGULATIONS.
DO NOT INCINERATE CLOSED CONTAINERS. VENTILATE AREA, ISOLATE SPILLED
MATERIAL, AND REMOVE WITH INERT ABSORBENT. DISPOSE OF CONTAMINATED
ABSORBENT, CONTAINER, AND UNUSED CONTENTS IN ACCORDANCE WITH LOCAL, STATE,
AND FEDERAL REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. USE ONLY WITH
ADEQUATE VENTILATION. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER
CONTAINER IS EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. AVOID BREATHING FUMES,
VAPORS, OR MIST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. KEEP AWAY FROM HEAT, SPARKS, FLAME AND SOURCES OF
IGNITION. KEEP CONTAINER CLOSED WHEN NOT IN USE. PRODUCT SHOULD BE STORED
IN TIGHTLY SEALED CONTAINERS AND PROTECTED FROM HEAT, MOISTURE, AND FOREIGN
MATERIALS. STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY
CLOSED WHEN NOT IN USE. AVOID EXCESS HEAT. DO NOT STORE ABOVE 120 DEG. F.
STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF
NFPA CLASS II COMBUSTIBLE LIQUIDS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
SOLVENT NAPHTHA, LIGHT AROMATIC 64742-95-6 15.0
1,2,4-TRIMETHYLBENZENE 95-63-6 15.0
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 10.0
TOLUENE 108-88-3 10.0
AROMATIC PETROLEUM DISTILLATES 64742-94-5 10.0
1,3,5-TRIMETHYLBENZENE 108-67-8 5.0
XYLENE (MIXED ISOMERS) 1330-20-7 5.0
DIETHYLBENZENE, MIXED ISOMERS 25340-17-4 5.0
CARBON BLACK 1333-86-4 5.0
ETHYLBENZENE 100-41-4 1.0
NAPHTHALENE 91-20-3 1.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA
TLV-TWA TLV-STEL PEL-TWA PEL-CEILING
SOLVENT NAPHTHA, N.E. N.E. N.E. N.E.
LIGHT AROMATIC
1,2,4- 25 PPM N.E. N.E. N.E.
TRIMETHYLBENZENE (NIOSH REL)
ETHYLENE GLYCOL 20 PPM N.E. 50 PPM N.E.
MONOBUTYL ETHER
TOLUENE 20 PPM N.E. 200 PPM 300 PPM
AROMATIC PETROLEUM N.E. N.E. N.E. N.E.
DISTILLATES
1,3,5- 25 PPM N.E. N.E. N.E.
TRIMETHYLBENZENE
XYLENE 100 PPM 150 PPM 100 PPM N.E.
(MIXED ISOMERS)
DIETHYLBENZENE, N.E. N.E. N.E. N.E.
MIXED ISOMERS
CARBON BLACK 3 MG/M3 N.E. 3.5 MG/M3 N.E.
(INHALABLE
DUST)
ETHYLBENZENE 20 PPM 125 PPM 100 PPM N.E.
NAPHTHALENE 10 PPM 15 PPM 10 PPM N.E.
(NIOSH)
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH AN
ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED
EXPOSURE LIMITS.
PROTECTION PROVIDED BY AIR PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE
PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR AN
UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE NOT KNOWN, OR IN ANY OTHER
CIRCUMSTANCES WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
SKIN PROTECTION:
USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT AND ABSORPTION OF THIS
MATERIAL THROUGH THE SKIN. NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE
SKIN PROTECTION. USE GLOVES TO PREVENT PROLONGED SKIN CONTACT.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION. REFER TO
SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE REGARDING
TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
PHYSICAL STATE: LIQUID
ODOR: SOLVENT LIKE
ODOR THRESHOLD: N.E.
RELATIVE DENSITY: 1.019
PH: N.A.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: N.D.
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT, N-OCTANOL/WATER: NO INFORMATION
DECOMPOSITION TEMP., DEG. C: NO INFORMATION
BOILING RANGE, DEG. C: 230 - 390
EXPLOSIVE LIMITS, VOL%: 0.7 - 10.6
FLAMMABILITY: DOES NOT SUPPORT COMBUSTION
FLASH POINT, DEG. C: >93
EVAPORATION RATE: SLOWER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: NO INFORMATION
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION. AVOID TEMPERATURES ABOVE
120 DEG. F. AVOID CONTACT WITH STRONG ACID AND STRONG BASES.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE. WHEN HEATED TO
DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES. CONTAINS
SOLVENTS WHICH MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, AND FORMALDEHYDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT: CAUSES SERIOUS EYE IRRITATION
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
MAY BE ABSORBED THROUGH THE SKIN IN HARMFUL AMOUNTS. PROLONGED OR REPEATED
SKIN CONTACT MAY CAUSE IRRITATION. CAUSES SKIN IRRITATION. ALLERGIC
REACTIONS ARE POSSIBLE.
EFFECTS OF OVEREXPOSURE - INHALATION:
HARMFUL IF INHALED. AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST. MAY
CAUSE HEADACHES AND DIZZINESS. HIGH VAPOR CONCENTRATIONS ARE IRRITATING TO
THE EYES, NOSE, THROAT AND LUNGS. HIGH GAS, VAPOR, MIST OR DUST
CONCENTRATIONS MAY BE HARMFUL IF INHALED. PROLONGED OR EXCESSIVE INHALATION
MAY CAUSE RESPIRATORY TRACT IRRITATION.
EFFECTS OF OVEREXPOSURE - INGESTION:
HARMFUL IF SWALLOWED. ASPIRATION HAZARD IF SWALLOWED; CAN ENTER LUNGS AND
CAUSE DAMAGE.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
IARC LISTS ETHYLBENZENE AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B).
OVEREXPOSURE TO XYLENE IN LABORATORY ANIMALS HAS BEEN ASSOCIATED WITH
LIVER ABNORMALITIES, KIDNEY, LUNG, SPLEEN, EYE AND BLOOD DAMAGE AS WELL AS
REPRODUCTIVE DISORDERS. EFFECTS IN HUMANS, DUE TO CHRONIC OVEREXPOSURE,
HAVE INCLUDED LIVER, CARDIAC ABNORMALITIES AND NERVOUS SYSTEM DAMAGE.
CONTAINS CARBON BLACK. CHRONIC INFLAMMATION, LUNG FIBROSIS, AND LUNG
TUMORS HAVE BEEN OBSERVED IN SOME RATS EXPERIMENTALLY EXPOSED FOR LONG
PERIODS OF TIME TO EXCESSIVE CONCENTRATIONS OF CARBON BLACK AND SEVERAL
INSOLUBLE FINE DUST PARTICLES. TUMORS HAVE NOT BEEN OBSERVED IN OTHER
ANIMAL SPECIES (I.E., MOUSE AND HAMSTER) UNDER SIMILAR CIRCUMSTANCES AND
STUDY CONDITIONS. EPIDEMIOLOGICAL STUDIES OF NORTH AMERICAN WORKERS SHOW NO
EVIDENCE OF CLINICALLY SIGNIFICANT ADVERSE HEALTH EFFECTS DUE TO
OCCUPATIONAL EXPOSURE TO CARBON BLACK.
CARBON BLACK IS LISTED AS A GROUP 2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY
IARC AND IS PROPOSED TO BE LISTED AS A4- "NOT CLASSIFIED AS A HUMAN
CARCINOGEN" BY THE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL
HYGIENISTS. SIGNIFICANT EXPOSURE IS NOT ANTICIPATED DURING BRUSH
APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL
OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST AND
THE ACTUAL CONCENTRATION OF CARBON BLACK IN THE FORMULA. REPORTS HAVE
ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS
WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. HIGH CONCENTRATIONS MAY
LEAD TO CENTRAL NERVOUS SYSTEM EFFECTS (DROWSINESS, DIZZINESS, NAUSEA,
HEADACHES, PARALYSIS, AND BLURRED VISION) AND/OR DAMAGE.
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
64742-95-6 SOLVENT NAPHTHA, N.I. >2000 MG/KG N.I.
LIGHT AROMATIC RABBIT
95-63-6 1,2,4- 3280 MG/KG >3160 MG/KG N.I.
TRIMETHYLBENZENE RAT RABBIT
111-76-2 ETHYLENE GLYCOL 470 MG/KG 220 MG/KG N.I.
MONOBUTYL ETHER RAT RABBIT
108-88-3 TOLUENE 636 MG/KG 8390 MG/KG 12.5 MG/L RAT
RAT RABBIT
64742-94-5 AROMATIC >5000 MG/KG >2 ML/KG N.I.
PETROLEUM RAT RABBIT
DISTILLATES
1330-20-7 XYLENE 4300 MG/KG N.I. 47635 MG/L
(MIXED ISOMERS) RAT RAT
100-41-4 ETHYLBENZENE 3500 MG/KG 15354 MG/KG 17.2 MG/L RAT
RAT RABBIT
91-20-3 NAPHTHALENE N.I. 1120 MG/KG N.I.
RABBIT
N.I. - NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
PRODUCT IS A MIXTURE OF LISTED COMPONENTS. PRODUCT IS A MIXTURE OF LISTED
COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(USDOT) (IMDG)
UN NUMBER N.A. 1263 1263 N.A.
PROPER SHIPPING PAINT PAINT PAINT PAINT
NAME PRODUCTS IN PRODUCTS IN
LIMITED LIMITED
QUANTITIES QUANTITIES
HAZARD CLASS N.A. 3 3 N.A.
PACKING GROUP N.A. III III N.A.
LIMITED YES YES YES YES
QUANTITY
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
FIRE HAZARD, ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
1,2,4-TRIMETHYLBENZENE 95-63-6
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2
TOLUENE 108-88-3
XYLENE (MIXED ISOMERS) 1330-20-7
ETHYLBENZENE 100-41-4
NAPHTHALENE 91-20-3
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A SUBSTANCE KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER.
CHEMICAL NAME CAS-NO.
CARBON BLACK 1333-86-4
ETHYLBENZENE 100-41-4
NAPHTHALENE 91-20-3
BENZENE 71-43-2
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS:
WARNING:
THIS PRODUCT CONTAINS A SUBSTANCE KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CHEMICAL NAME CAS-NO.
TOLUENE 108-88-3
BENZENE 71-43-2
INTERNATIONAL REGULATIONS:
CANADIAN WHMIS:
THIS SDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 3
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
CANADIAN WHMIS CLASS:
B2
D2A
D2B
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS, G/L: 616
MSDS REVISION DATE: 5/18/2015
REASON FOR REVISION: NO INFORMATION
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
TEXT FOR GHS HAZARD STATEMENTS SHOWN IN SECTION 3 DESCRIBING EACH
INGREDIENT:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
H226: FLAMMABLE LIQUID AND VAPOUR.
H227: COMBUSTIBLE LIQUID
H228: FLAMMABLE SOLID.
H251:
SELF-HEATING: MAY CATCH FIRE.
H302: HARMFUL IF SWALLOWED.
H310: FATAL IN CONTACT WITH SKIN.
H311: TOXIC IN CONTACT WITH SKIN.
H312: HARMFUL IN CONTACT WITH SKIN.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H340:
MAY CAUSE GENETIC DEFECTS <STATE ROUTE OF EXPOSURE IF IT IS CONCLUSIVELY
PROVEN THAT NO OTHER ROUTES OF EXPOSURE CAUSE THE HAZARD>.
H350:
MAY CAUSE CANCER <STATE ROUTE OF EXPOSURE IF IT IS CONCLUSIVELY PROVEN
THAT NO OTHER ROUTES OF EXPOSURE CAUSE THE HAZARD>.
H351:
SUSPECTED OF CAUSING CANCER. CLASSIFIED AS CATEGORY 2 BASED ON LIMITED
EVIDENCE ON HUMAN AND/OR ANIMAL STUDIES. MIXTURES WITH CONCENTRATIONS OF
SUSPECTED CARCINOGENS INGREDIENTS AT CONCENTRATION PRESENT BETWEEN 0.1%
AND 1.0% LABELLING THE SDS WILL BE OPTIONAL DEPENDING ON AUTHORITIES.
IF CATEGORY 2 CARCINOGENIC PRESENT AT A CONCENTRATION OF 1% OR ABOVE
LABELLING THE SDS WILL BE EXPECTED. ROUTES OF EXPOSURE ARE DEPENDANT ON
INGREDIENT FORM.
H361:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. CLASSIFED CATEGORY 2
SUSPECTED HUMAN REPRODUCTIVE TOXICANT IRREVERSIBLE EFFECTS SUCH AS
STRUCTURAL MALFUNCTIONS, EMBRYO/FOETAL LETHALITY, POST NATAL FUNCTIONAL
DEFICIENCIES.
H373:
MAY CAUSE DAMAGE TO ORGANS <OR STATE ALL ORGANS AFFECTED, IF KNOWN>
THROUGH PROLONGED OR REPEATED EXPOSURE <STATE ROUTE OF EXPOSURE IF IT IS
CONCLUSIVELY PROVEN THAT NO OTHER ROUTES OF EXPOSURE CAUSE THE HAZARD>.
ICONS FOR GHS PICTOGRAMS SHOWN IN SECTION 3 DESCRIBING EACH INGREDIENT:
GHS02: FLAME
GHS06: SKULLS AND CROSSBONES
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
THE MANUFACTURER BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION AND
BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS OF
THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS OF
HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL, WE
ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. THE MANUFACTURER MAKES NO
WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR RELIABILITY OF
THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION AND
RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE USER
TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO COMPLY WITH
ALL APPLICABLE INTERNATIONAL, FEDERAL, STATE, AND LOCAL LAWS AND
REGULATIONS.