| Common Name: | AUTORF +SSPR 6PK VINYL&FABRC BLACK GLOSS, 248918 |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 5/18/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 4YLD5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DATE PRINTED: 5/18/2015
SAFETY DATA SHEET
RUST-OLEUM CORPORATION
TRUSTED QUALITY SINCE 1921
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: AUTORF +SSPR 6PK VINYL&FABRC BLACK GLOSS
PRODUCT IDENTIFIER: 248918
PRODUCT USE/CLASS: TOPCOAT/AEROSOLS
REVISION DATE: 5/18/2015
SUPERCEDES DATE: 5/15/2015
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
| 2. HAZARD IDENTIFICATION | |
EMERGENCY OVERVIEW:
HARMFUL IF SWALLOWED. EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPORS MAY
CAUSE FLASH FIRE OR EXPLOSION. CONTENTS UNDER PRESSURE. HARMFUL IF INHALED.
MAY AFFECT THE BRAIN OR NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE OR
NAUSEA. MAY CAUSE EYE, SKIN, OR RESPIRATORY TRACT IRRITATION. KEEP OUT OF
REACH OF CHILDREN. HARMFUL IF INHALED. CAUSES EYE IRRITATION. USE
VENTILATION NECESSARY TO KEEP EXPOSURES BELOW RECOMMENDED EXPOSURE LIMITS,
IF ANY. VAPOR HARMFUL. CAUSES EYE, SKIN, NOSE, AND THROAT IRRITATION.
CLASSIFICATION:
SYMBOL(S) OF PRODUCT:
EXCLAMATION MARK
FLAME
HEALTH HAZARD
SIGNAL WORD: DANGER
POSSIBLE HAZARDS:
70% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE TOXICITY
GHS ADDITIONAL INFORMATION:
H362:
CONTAINS ONE OR MORE CATEGORY 1 OR CATEGORY 2 REPRODUCTIVE TOXICANTS AT
GREATER THAN 0.1%. A SAFETY DATA SHEET SHALL BE AVAILABLE FOR THE MIXTURE
UPON REQUEST.
GHS HAZARD STATEMENTS:
FLAMMABLE AEROSOL, CATEGORY 1:
H222: EXTREMELY FLAMMABLE AEROSOL.
FLAMMABLE LIQUID, CATEGORY 1:
H224: EXTREMELY FLAMMABLE LIQUID AND VAPOUR.
ACUTE TOXICITY, ORAL, CATEGORY 5:
H303: MAY BE HARMFUL IF SWALLOWED.
ACUTE TOXICITY, DERMAL, CATEGORY 5:
H313: MAY BE HARMFUL IN CONTACT WITH SKIN.
SKIN IRRITATION, CATEGORY 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRITATION, CATEGORY 2:
H319: CAUSES SERIOUS EYE IRRITATION.
ACUTE TOXICITY, INHALATION, CATEGORY 4:
H332: HARMFUL IF INHALED.
STOT, SINGLE EXPOSURE, CATEGORY 3, RTI:
H335: MAY CAUSE RESPIRATORY IRRITATION.
STOT, SINGLE EXPOSURE, CATEGORY 3, NE:
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
ASPIRATION HAZARD, CATEGORY 2:
H305: MAY BE HARMFUL IF SWALLOWED AND ENTERS AIRWAYS
EYE IRRITATION, CATEGORY 2B:
H320: CAUSES EYE IRRITATION
FLAMMABLE AEROSOL, CATEGORY 1:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
GHS LABEL PRECAUTIONARY STATEMENTS:
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P251: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P375: FIGHT FIRE REMOTELY DUE TO THE RISK OF EXPLOSION.
P102: KEEP OUT OF REACH OF CHILDREN.
P103: READ LABEL BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P234: KEEP ONLY IN ORIGINAL CONTAINER.
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P262: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
P264: WASH ... THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P285: IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P350: GENTLY WASH WITH PLENTY OF SOAP AND WATER.
P374: FIGHT FIRE WITH NORMAL PRECAUTIONS FROM A REASONABLE DISTANCE.
P402: STORE IN A DRY PLACE.
P410+P412:
PROTECT FROM SUNLIGHT. DO NO EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C / 122 DEG. F.
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P362: TAKE OFF CONTAMINATED CLOTHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% GHS SYMBOLS GHS STATEMENTS
RANGE
ACETONE 67-64-1 25-50 GHS02-GHS07 H225-336-319
METHYL ISOBUTYL KETONE 108-10-1 10-25 GHS02-GHS06 H225-331-335-319
PROPANE 74-98-6 10-25
METHYL ETHYL KETONE 78-93-3 10-25 GHS02-GHS07 H225-336-319
N-BUTANE 106-97-8 2.5-10
PROPYLENE GLYCOL 5131-66-8 1.0-2.5 GHS02-GHS07 H226-302-315-319
MONOBUTYL ETHER
XYLENE (MIXED ISOMERS) 1330-20-7 1.0-2.5 GHS02-GHS07 H226-312-332-315
1-METHOXY-2-PROPYL 108-65-6 1.0-2.5 GHS02-GHS06 H226-310
ACETATE
TOLUENE 108-88-3 1.0-2.5 GHS02-GHS07- H225-302-332-
GHS08 361-336-373-315
CARBON BLACK 1333-86-4 0.1-1.0 GHS02 H251
ETHYLBENZENE 100-41-4 0.1-1.0 GHS02-GHS07 H225-332
THE TEXT FOR GHS HAZARD STATEMENTS SHOWN ABOVE (IF ANY) IS GIVEN IN THE
"16. OTHER INFORMATION" SECTION.
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES OR
KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO OBTAIN FRESH
AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, GET MEDICAL ASSISTANCE
IMMEDIATELY. REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL
ATTENTION. DO NOT USE MOUTH-TO-MOUTH RESUSCITATION.
FIRST AID - INGESTION:
ASPIRATION HAZARD:
DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL CAN
ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. GET IMMEDIATE MEDICAL
ATTENTION. IF SWALLOWED, GET MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
FLASH POINT IS LESS THAN 20 DEG. F. EXTREMELY FLAMMABLE LIQUID AND VAPOR!
WATER SPRAY MAY BE INEFFECTIVE. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED
TO EXTREME HEAT. VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR. VAPORS CAN
TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. KEEP CONTAINERS TIGHTLY
CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAME.
PERFORATION OF THE PRESSURIZED CONTAINER MAY CAUSE BURSTING OF THE CAN.
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT DUE TO BUILDUP
OF STEAM. NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
SPECIAL FIREFIGHTING PROCEDURES:
EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE. FULL PROTECTIVE
EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED.
WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILDUP AND
POSSIBLE AUTOIGNITION OR EXPLOSION. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL. CONTAINERS MAY EXPLODE WHEN HEATED.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS
SUCH AS SAWDUST. REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA AND REMOVE
WITH INERT ABSORBENT AND NON-SPARKING TOOLS. DISPOSE OF ACCORDING TO LOCAL,
STATE (PROVINCIAL) AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED
CONTAINERS. ISOLATE THE HAZARD AREA AND DENY ENTRY TO UNNECESSARY AND
UNPROTECTED PERSONNEL. VENTILATE AREA, ISOLATE SPILLED MATERIAL, AND REMOVE
WITH INERT ABSORBENT. DISPOSE OF CONTAMINATED ABSORBENT, CONTAINER, AND
UNUSED CONTENTS IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. USE ONLY IN A
WELL-VENTILATED AREA. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER
CONTAINER IS EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID
BREATHING FUMES, VAPORS, OR MIST. REMOVE CONTAMINATED CLOTHING AND LAUNDER
BEFORE REUSE. USE ONLY WITH ADEQUATE VENTILATION. AVOID CONTACT WITH EYES,
SKIN AND CLOTHING.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. CONTENTS UNDER PRESSURE. DO NOT STORE ABOVE
120 DEG. F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR
STORAGE OF NFPA CLASS I FLAMMABLE LIQUIDS. CONTENTS UNDER PRESSURE. DO NOT
EXPOSE TO HEAT OR STORE ABOVE 120 DEG. F. PRODUCT SHOULD BE STORED IN
TIGHTLY SEALED CONTAINERS AND PROTECTED FROM HEAT, MOISTURE, AND FOREIGN
MATERIALS. STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY
CLOSED WHEN NOT IN USE. KEEP AWAY FROM HEAT, SPARKS, FLAME AND SOURCES OF
IGNITION. AVOID EXCESS HEAT.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
ACETONE 67-64-1 35.0
METHYL ISOBUTYL KETONE 108-10-1 20.0
PROPANE 74-98-6 15.0
METHYL ETHYL KETONE 78-93-3 15.0
N-BUTANE 106-97-8 10.0
PROPYLENE GLYCOL MONOBUTYL ETHER 5131-66-8 5.0
XYLENE (MIXED ISOMERS) 1330-20-7 5.0
1-METHOXY-2-PROPYL ACETATE 108-65-6 5.0
TOLUENE 108-88-3 5.0
CARBON BLACK 1333-86-4 1.0
ETHYLBENZENE 100-41-4 1.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA
TLV-TWA TLV-STEL PEL-TWA PEL-CEILING
ACETONE 500 PPM 750 PPM 1000 PPM N.E.
METHYL ISOBUTYL 20 PPM 75 PPM 100 PPM N.E.
KETONE
PROPANE 1000 PPM N.E. 1000 PPM N.E.
METHYL ETHYL 200 PPM 300 PPM 200 PPM N.E.
KETONE
N-BUTANE 1000 PPM 1000 PPM N.E. N.E.
PROPYLENE GLYCOL N.E. N.E. N.E. N.E.
MONOBUTYL ETHER
XYLENE 100 PPM 150 PPM 100 PPM N.E.
(MIXED ISOMERS)
1-METHOXY-2-PROPYL 50 PPM N.E. N.E. N.E.
ACETATE (AIHA WEEL)
TOLUENE 20 PPM N.E. 200 PPM 300 PPM
CARBON BLACK 3 MG/M3 N.E. 3.5 MG/M3 N.E.
(INHALABLE
DUST)
ETHYLBENZENE 20 PPM 125 PPM 100 PPM N.E.
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. USE
EXPLOSION-PROOF VENTILATION EQUIPMENT. PREVENT BUILD-UP OF VAPORS BY
OPENING ALL DOORS AND WINDOWS TO ACHIEVE CROSS-VENTILATION. PROVIDE GENERAL
DILUTION OF LOCAL EXHAUST VENTILATION IN VOLUME AND PATTERN TO KEEP TLV OF
HAZARDOUS INGREDIENTS BELOW ACCEPTABLE LIMITS.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH
ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED
EXPOSURE LIMITS.
SKIN PROTECTION:
USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT AND ABSORPTION OF THIS
MATERIAL THROUGH THE SKIN. NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE
SKIN PROTECTION. USE GLOVES TO PREVENT PROLONGED SKIN CONTACT.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION. REFER TO
SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE REGARDING
TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: AEROSOLIZED MIST
PHYSICAL STATE: LIQUID
ODOR: SOLVENT LIKE
ODOR THRESHOLD: N.E.
RELATIVE DENSITY: 0.752
PH: N.A.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: N.D.
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT, N-OCTANOL/WATER: NO INFORMATION
DECOMPOSITION TEMP., DEG. C: NO INFORMATION
BOILING RANGE, DEG. C: -11 - 752
EXPLOSIVE LIMITS, VOL%: 1.0 - 13.0
FLAMMABILITY: DOES NOT SUPPORT COMBUSTION
FLASH POINT, DEG. C: -105
EVAPORATION RATE: FASTER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: NO INFORMATION
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
AVOID TEMPERATURES ABOVE 120 DEG. F. AVOID ALL POSSIBLE SOURCES OF
IGNITION. AVOID CONTACT WITH STRONG ACID AND STRONG BASES.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
CONTAINS SOLVENTS WHICH MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, AND
FORMALDEHYDE. BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE. WHEN
HEATED TO DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY:
MAY FORM PEROXIDES OF UNKOWN STABILITY. THIS PRODUCT IS STABLE UNDER
NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT: CAUSES SERIOUS EYE IRRITATION
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
MAY BE ABSORBED THROUGH THE SKIN IN HARMFUL AMOUNTS. SUBSTANCE MAY CAUSE
SLIGHT SKIN IRRITATION. PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN
IRRITATION. MAY CAUSE SKIN IRRITATION. ALLERGIC REACTIONS ARE POSSIBLE.
EFFECTS OF OVEREXPOSURE - INHALATION:
HARMFUL IF INHALED. HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS MAY BE
HARMFUL IF INHALED. AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST. HIGH
VAPOR CONCENTRATIONS ARE IRRITATING TO THE EYES, NOSE, THROAT AND LUNGS.
PROLONGED OR EXCESSIVE INHALATION MAY CAUSE RESPIRATORY TRACT IRRITATION.
EFFECTS OF OVEREXPOSURE - INGESTION:
ASPIRATION HAZARD IF SWALLOWED; CAN ENTER LUNGS AND CAUSE DAMAGE. HARMFUL
IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
IARC LISTS ETHYLBENZENE AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B).
OVEREXPOSURE TO METHYL ETHYL KETONE IN LABORATORY ANIMALS HAS BEEN
ASSOCIATED WITH LIVER ABNORMALITIES, KIDNEY AND LUNG DAMAGE.
FETOTOXIC/EMBRYOTOXIC EFFECTS FROM INHALATION HAVE BEEN SEEN IN RATS
EXPOSED TO >1000PPM DURING GESTATION. OVEREXPOSURE TO XYLENE IN LABORATORY
ANIMALS HAS BEEN ASSOCIATED WITH LIVER ABNORMALITIES, KIDNEY, LUNG, SPLEEN,
EYE AND BLOOD DAMAGE AS WELL AS REPRODUCTIVE DISORDERS. EFFECTS IN HUMANS,
DUE TO CHRONIC OVEREXPOSURE, HAVE INCLUDED LIVER, CARDIAC ABNORMALITIES AND
NERVOUS SYSTEM DAMAGE. CONTAINS CARBON BLACK. CHRONIC INFLAMMATION, LUNG
FIBROSIS, AND LUNG TUMORS HAVE BEEN OBSERVED IN SOME RATS EXPERIMENTALLY
EXPOSED FOR LONG PERIODS OF TIME TO EXCESSIVE CONCENTRATIONS OF CARBON
BLACK AND SEVERAL INSOLUBLE FINE DUST PARTICLES. TUMORS HAVE NOT BEEN
OBSERVED IN OTHER ANIMAL SPECIES (I.E., MOUSE AND HAMSTER) UNDER SIMILAR
CIRCUMSTANCES AND STUDY CONDITIONS. EPIDEMIOLOGICAL STUDIES OF NORTH
AMERICAN WORKERS SHOW NO EVIDENCE OF CLINICALLY SIGNIFICANT ADVERSE HEALTH
EFFECTS DUE TO OCCUPATIONAL EXPOSURE TO CARBON BLACK.
CARBON BLACK IS LISTED AS A GROUP 2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY
IARC AND IS PROPOSED TO BE LISTED AS A4- "NOT CLASSIFIED AS A HUMAN
CARCINOGEN" BY THE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL
HYGIENISTS. SIGNIFICANT EXPOSURE IS NOT ANTICIPATED DURING BRUSH
APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL
OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST AND
THE ACTUAL CONCENTRATION OF CARBON BLACK IN THE FORMULA. MAY CAUSE CENTRAL
NERVOUS SYSTEM DISORDER (E.G., NARCOSIS INVOLVING A LOSS OF COORDINATION,
WEAKNESS, FATIGUE, MENTAL CONFUSION, AND BLURRED VISION) AND/OR DAMAGE.
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE
TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. HIGH
CONCENTRATIONS MAY LEAD TO CENTRAL NERVOUS SYSTEM EFFECTS (DROWSINESS,
DIZZINESS, NAUSEA, HEADACHES, PARALYSIS, AND BLURRED VISION) AND/OR DAMAGE.
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
108-10-1 METHYL ISOBUTYL 2080 MG/KG >16000 MG/KG 8.2 MG/L RAT
KETONE RAT RABBIT
74-98-6 PROPANE N.I. N.I. 658 MG/L RAT
5131-66-8 PROPYLENE GLYCOL 1900 MG/KG N.I. N.I.
MONOBUTYL ETHER RAT
1330-20-7 XYLENE 4300 MG/KG N.I. 47635 MG/L RAT
(MIXED ISOMERS) RAT
108-65-6 1-METHOXY-2-PROPYL 8532 MG/KG >5 G/KG N.I.
ACETATE RAT RABBIT
108-88-3 TOLUENE 636 MG/KG 8390 MG/KG 12.5 MG/L RAT
RAT RABBIT
100-41-4 ETHYLBENZENE 3500 MG/KG 15354 MG/KG 17.2 MG/L RAT
RAT RABBIT
N.I. - NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
PRODUCT IS A MIXTURE OF LISTED COMPONENTS. PRODUCT IS A MIXTURE OF LISTED
COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(USDOT) (IMDG)
UN NUMBER N.A. 1950 1950 N.A.
PROPER SHIPPING PAINT AEROSOLS AEROSOLS PAINT
NAME PRODUCTS IN PRODUCTS IN
LIMITED LIMITED
QUANTITIES QUANTITIES
HAZARD CLASS N.A. 2.1 2.1 N.A.
PACKING GROUP N.A. N.A. N.A. N.A.
LIMITED QUANTITY YES YES YES YES
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
FIRE HAZARD, PRESSURE HAZARD, ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
METHYL ISOBUTYL KETONE 108-10-1
METHYL ETHYL KETONE 78-93-3
XYLENE (MIXED ISOMERS) 1330-20-7
TOLUENE 108-88-3
ETHYLBENZENE 100-41-4
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A SUBSTANCE KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER.
CHEMICAL NAME CAS-NO.
METHYL ISOBUTYL KETONE 108-10-1
CARBON BLACK 1333-86-4
ETHYLBENZENE 100-41-4
VINYL CHLORIDE 75-01-4
BENZENE 71-43-2
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS:
WARNING:
THIS PRODUCT CONTAINS A SUBSTANCE KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CHEMICAL NAME CAS-NO.
TOLUENE 108-88-3
BENZENE 71-43-2
INTERNATIONAL REGULATIONS:
CANADIAN WHMIS:
THIS SDS HAS BEEN PREPARED IN COMPLIANCE WITH CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR THE USE OF THE 16 HEADINGS.
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 4
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
CANADIAN WHMIS CLASS:
AB5
D2A
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 4
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS, G/L: 609
MSDS REVISION DATE: 5/18/2015
REASON FOR REVISION: NO INFORMATION
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
TEXT FOR GHS HAZARD STATEMENTS SHOWN IN SECTION 3 DESCRIBING EACH
INGREDIENT:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
H226: FLAMMABLE LIQUID AND VAPOUR.
H251:
SELF-HEATING: MAY CATCH FIRE.
H302: HARMFUL IF SWALLOWED.
H310: FATAL IN CONTACT WITH SKIN.
H312: HARMFUL IN CONTACT WITH SKIN.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H331: TOXIC IF INHALED.
H332: HARMFUL IF INHALED.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H361:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD. CLASSIFED CATEGORY 2
SUSPECTED HUMAN REPRODUCTIVE TOXICANT IRREVERSIBLE EFFECTS SUCH AS
STRUCTURAL MALFUNCTIONS, EMBRYO/FOETAL LETHALITY, POST NATAL FUNCTIONAL
DEFICIENCIES.
H373:
MAY CAUSE DAMAGE TO ORGANS <OR STATE ALL ORGANS AFFECTED, IF KNOWN>
THROUGH PROLONGED OR REPEATED EXPOSURE <STATE ROUTE OF EXPOSURE IF IT IS
CONCLUSIVELY PROVEN THAT NO OTHER ROUTES OF EXPOSURE CAUSE THE HAZARD>.
ICONS FOR GHS PICTOGRAMS SHOWN IN SECTION 3 DESCRIBING EACH INGREDIENT:
GHS02: FLAME
GHS06: SKULLS AND CROSSBONES
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
RUST-OLEUM CORPORATION BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION
AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS
OF THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS OF
HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL, WE
ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. RUST-OLEUM CORPORATION MAKES
NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR RELIABILITY
OF THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION AND
RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE USER
TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO COMPLY WITH
ALL APPLICABLE INTERNATIONAL, FEDERAL, STATE, AND LOCAL LAWS AND
REGULATIONS.