| Common Name: | BIG RIG LIGHT GRAY PRIMER, 0000201631 |
| Manufacturer: | SEYMOUR OF SYCAMORE |
| SDS Revision Date: | 2/8/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 50DK22 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
PRINTING DATE: 02/08/2016
REVISED ON: 02/08/2016
| 1 IDENTIFICATION OF THE SUBSTANCE AND MANUFACTURER |  |
TRADE NAME: BIG RIG LIGHT GRAY PRIMER
PRODUCT CODE: 0000201631
PRODUCT CATEGORY: PC9A PAINTS AND COATINGS.
MANUFACTURER/SUPPLIER:
SEYMOUR OF SYCAMORE
917 CROSBY AVENUE
SYCAMORE, IL 60178
PHONE: 815-895-9101
WWW.SEYMOURPAINT.COM
EMERGENCY TELEPHONE NUMBER:
CHEMTEL: 1-800-255-3924, OR 813-248-0585.
| 2 HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAM. AEROSOL 1:
H222: EXTREMELY FLAMMABLE AEROSOL.
PRESS. GAS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRIT. 2A:
H319: CAUSES SERIOUS EYE IRRITATION.
REPR. 2:
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
STOT SE 3:
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
STOT RE 2:
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
GHS HAZARD PICTOGRAMS:
GHS02: FLAME
GHS04: GAS CYLINDER
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
DO NOT PIERCE OR BURN, EVEN AFTER USE.
WASH HANDS THOROUGHLY AFTER HANDLING.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
WEAR PROTECTIVE GLOVES.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
STORE LOCKED UP.
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL CHARACTERIZATION: MIXTURES
CHEMICAL DESCRIPTION:
THIS PRODUCT IS A MIXTURE OF THE SUBSTANCES LISTED BELOW WITH NONHAZARDOUS
ADDITIONS.
DANGEROUS COMPONENTS:
67-64-1 ACETONE 23.24%
74-98-6 PROPANE 12.6%
13463-67-7 TITANIUM DIOXIDE 7.43%
106-97-8 N-BUTANE 7.4%
108-88-3 TOLUENE 6.08%
64742-89-8 VM&P NAPHTHA 5.5%
14807-96-6 TALC 4.3%
1330-20-7 XYLENE (MIX) 3.97%
64-17-5 ETHYL ALCOHOL 3.81%
64742-47-8 MINERAL SPIRITS 3.1%
123-86-4 N-BUTYL ACETATE 2.67%
110-19-0 ISOBUTYL ACETATE 1.52%
67-63-0 ISOPROPYL ALCOHOL 1.32%
108-65-6 PM ACETATE 1.31%
| 4 FIRST-AID MEASURES | |
AFTER INHALATION: SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
AFTER SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH SOAP AND WATER.
AFTER EYE CONTACT:
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. IF SYMPTOMS
PERSIST, CONSULT A DOCTOR.
AFTER SWALLOWING:
RINSE OUT MOUTH AND THEN DRINK PLENTY OF WATER.
RINSE MOUTH WITH WATER. DO NOT INDUCE VOMITING.
MOST IMPORTANT SYMPTOMS AND EFFECTS: DIZZINESS
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION NEEDED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING AGENTS:
CO2, EXTINGUISHING POWDER OR WATER SPRAY. FIGHT LARGER FIRES WITH WATER
SPRAY.
SPECIAL HAZARDS: CAN FORM EXPLOSIVE GAS-AIR MIXTURES.
PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
A RESPIRATORY PROTECTIVE DEVICE MAY BE NECESSARY.
| 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF
FUMES/DUST/AEROSOL.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ENSURE ADEQUATE VENTILATION.
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO SECTION 13.
| 7 HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING: USE ONLY IN WELL VENTILATED AREAS.
STORAGE REQUIREMENTS:
KEEP AWAY FROM SOURCES OF HEAT AND DIRECT SUNLIGHT. DO NOT WAREHOUSE IN
SUBFREEZING CONDITIONS. STORE LOCKED UP.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
67-64-1 ACETONE:
PEL (USA):
LONG-TERM VALUE: 2400 MG/M3, 1000 PPM
REL (USA):
LONG-TERM VALUE: 590 MG/M3, 250 PPM
TLV (USA):
SHORT-TERM VALUE: 1187 MG/M3, 500 PPM
LONG-TERM VALUE: 594 MG/M3, 250 PPM
BEI
74-98-6 PROPANE:
PEL (USA):
LONG-TERM VALUE: 1800 MG/M3, 1000 PPM
REL (USA):
LONG-TERM VALUE: 1800 MG/M3, 1000 PPM
TLV (USA): REFER TO APPENDIX F IN TLVS AND BEIS BOOK
106-97-8 N-BUTANE:
REL (USA):
LONG-TERM VALUE: 1900 MG/M3, 800 PPM
TLV (USA):
SHORT-TERM VALUE: 2370 MG/M3, 1000 PPM
108-88-3 TOLUENE:
PEL (USA):
LONG-TERM VALUE: 200 PPM
CEILING LIMIT VALUE: 300; 500* PPM
*10-MIN PEAK PER 8-HR SHIFT
REL (USA):
SHORT-TERM VALUE: 560 MG/M3, 150 PPM
LONG-TERM VALUE: 375 MG/M3, 100 PPM
TLV (USA):
LONG-TERM VALUE: 75 MG/M3, 20 PPM
BEI
1330-20-7 XYLENE (MIX):
PEL (USA):
LONG-TERM VALUE: 435 MG/M3, 100 PPM
REL (USA):
SHORT-TERM VALUE: 655 MG/M3, 150 PPM
LONG-TERM VALUE: 435 MG/M3, 100 PPM
TLV (USA):
SHORT-TERM VALUE: 651 MG/M3, 150 PPM
LONG-TERM VALUE: 434 MG/M3, 100 PPM
BEI
64-17-5 ETHYL ALCOHOL:
PEL (USA):
LONG-TERM VALUE: 1900 MG/M3, 1000 PPM
REL (USA):
LONG-TERM VALUE: 1900 MG/M3, 1000 PPM
TLV (USA):
SHORT-TERM VALUE: 1880 MG/M3, 1000 PPM
123-86-4 N-BUTYL ACETATE:
PEL (USA):
LONG-TERM VALUE: 710 MG/M3, 150 PPM
REL (USA):
SHORT-TERM VALUE: 950 MG/M3, 200 PPM
LONG-TERM VALUE: 710 MG/M3, 150 PPM
TLV (USA):
SHORT-TERM VALUE: (950) NIC-712 MG/M3, (200) NIC-150 PPM
LONG-TERM VALUE: (713) NIC-238 MG/M3, (150) NIC-50 PPM
110-19-0 ISOBUTYL ACETATE:
PEL (USA):
LONG-TERM VALUE: 700 MG/M3, 150 PPM
REL (USA):
LONG-TERM VALUE: 700 MG/M3, 150 PPM
TLV (USA):
SHORT-TERM VALUE: NIC-712 MG/M3, NIC-150 PPM
LONG-TERM VALUE: (713) NIC-238 MG/M3, (150) NIC-50 PPM
67-63-0 ISOPROPYL ALCOHOL:
PEL (USA):
LONG-TERM VALUE: 980 MG/M3, 400 PPM
REL (USA):
SHORT-TERM VALUE: 1225 MG/M3, 500 PPM
LONG-TERM VALUE: 980 MG/M3, 400 PPM
TLV (USA):
SHORT-TERM VALUE: 984 MG/M3, 400 PPM
LONG-TERM VALUE: 492 MG/M3, 200 PPM
BEI
108-65-6 PM ACETATE:
WEEL (USA):
LONG-TERM VALUE: 50 PPM
INGREDIENTS WITH BIOLOGICAL LIMIT VALUES:
67-64-1 ACETONE:
BEI (USA): 50 MG/L
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: ACETONE (NONSPECIFIC)
108-88-3 TOLUENE:
BEI (USA): 0.02 MG/L
MEDIUM: BLOOD
TIME: PRIOR TO LAST SHIFT OF WORKWEEK
PARAMETER: TOLUENE
0.03 MG/L
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: TOLUENE
0.3 MG/G CREATININE
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: O-CRESOL WITH HYDROLYSIS (BACKGROUND)
1330-20-7 XYLENE (MIX):
BEI (USA): 1.5 G/G CREATININE
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: METHYLHIPPURIC ACIDS
67-63-0 ISOPROPYL ALCOHOL:
BEI (USA): 40 MG/L
MEDIUM: URINE
TIME: END OF SHIFT AT END OF WORKWEEK
PARAMETER: ACETONE (BACKGROUND, NONSPECIFIC)
HYGIENIC PROTECTION:
KEEP AWAY FROM FOODSTUFFS AND ANIMAL FEED. WASH HANDS AFTER USE.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING.
WASH HANDS AFTER USE.
AVOID CONTACT WITH THE EYES AND SKIN.
DO NOT EAT OR DRINK WHILE WORKING.
BREATHING EQUIPMENT:
A RESPIRATOR IS GENERALLY NOT NECESSARY WHEN USING THIS PRODUCT OUTDOORS
OR IN LARGE OPEN AREAS.
IN CASES WHERE SHORT AND/OR LONG TERM OVEREXPOSURE EXISTS, A CHARCOAL
FILTER RESPIRATOR SHOULD BE WORN. IF YOU SUSPECT OVEREXPOSURE CONDITIONS
EXIST, PLEASE CONSULT AN AUTHORITY ON CHEMICAL HYGEINE.
HAND PROTECTION:
NITRILE GLOVES.
PROTECTIVE GLOVES. THE GLOVE MATERIAL MUST BE IMPERMEABLE AND RESISTANT
TO THE SUBSTANCE.
EYE PROTECTION: TIGHTLY SEALED GOGGLES
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: AEROSOL.
ODOR: AROMATIC
ODOR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
MELTING POINT/MELTING RANGE: UNDETERMINED.
BOILING POINT: -110 DEG. C (-166 DEG. F)
FLASH POINT: -19 DEG. C (-2 DEG. F)
FLAMMABILITY (SOLID, GAS): EXTREMELY FLAMMABLE.
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
AUTO IGNITING: PRODUCT IS NOT SELF-IGNITING.
DANGER OF EXPLOSION:
IN USE, MAY FORM FLAMMABLE/EXPLOSIVE VAPOUR-AIR MIXTURE.
LOWER EXPLOSION LIMIT: 1.7 VOL %
UPPER EXPLOSION LIMIT: 10.9 VOL %
VAPOR PRESSURE: NOT DETERMINED.
RELATIVE DENSITY: BETWEEN 0.77 AND 0.85 (WATER EQUALS 1.00)
VAPOUR DENSITY: NOT DETERMINED.
EVAPORATION RATE: NOT APPLICABLE.
PARTITION COEFFICIENT N-OCTONAL/WATER: NOT DETERMINED.
SOLUBILITY: NOT DETERMINED.
VISCOSITY: NOT DETERMINED.
VOC CONTENT: 535.6 G/L / 4.47 LB/GL
VOC CONTENT (LESS EXEMPT SOLVENTS): 50.8%
MIR VALUE: 1.10
SOLIDS CONTENT: 25.5%
| 10 STABILITY AND REACTIVITY | |
REACTIVITY: STABLE AT NORMAL TEMPERATURES.
CONDITIONS TO AVOID:
DO NOT ALLOW CAN TO EXCEED 120 DEGREES FAHRENHEIT. DO NOT WAREHOUSE IN
SUBFREEZING TEMPERATURES.
CHEMICAL STABILITY: NOT FULLY EVALUATED.
POSSIBILITY OF HAZARDOUS REACTIONS: NO DANGEROUS REACTIONS KNOWN.
INCOMPATIBLE MATERIALS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
HAZARDOUS DECOMPOSITION: NO DANGEROUS DECOMPOSITION PRODUCTS KNOWN.
| 11 TOXICOLOGICAL INFORMATION | |
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
13463-67-7 TITANIUM DIOXIDE:
ORAL:
LD50: >20000 MG/KG (RAT)
DERMAL:
LD50: >10000 MG/KG (RBT)
INHALATIVE:
LC50/4 H: >6.82 MG/L (RAT)
106-97-8 N-BUTANE:
INHALATIVE:
LC50/4 H: 658 MG/L (RAT)
1330-20-7 XYLENE (MIX):
ORAL:
LD50: 8700 MG/KG (RAT)
DERMAL:
LD50: 2000 MG/KG (RBT)
INHALATIVE:
LC50/4 H: 6350 MG/L (RAT)
64-17-5 ETHYL ALCOHOL:
ORAL:
LD50: 7060 MG/KG (RAT)
INHALATIVE:
LC50/4 H: 20000 MG/L (RAT)
123-86-4 N-BUTYL ACETATE:
ORAL:
LD50: 14000 MG/KG (RAT)
INHALATIVE:
LC50/4 H: >21.0 MG/L (RAT)
110-19-0 ISOBUTYL ACETATE:
ORAL:
LD50: 4763 MG/KG (RBT)
67-63-0 ISOPROPYL ALCOHOL:
ORAL:
LD50: 4570 MG/KG (RAT)
DERMAL:
LD50: 13400 MG/KG (RAB)
INHALATIVE:
LC50/4 H: 30 MG/L (RAT)
108-65-6 PM ACETATE:
ORAL:
LD50: 8500 MG/KG (RAT)
INHALATIVE:
LC50/4 H: 35.7 MG/L (RAT)
INFORMATION ON TOXICOLOGICAL EFFECTS: NO DATA AVAILABLE.
SKIN EFFECTS: NO IRRITANT EFFECT.
EYE EFFECTS: IRRITATING EFFECT.
SENSITIZATION: NO SENSITIZING EFFECTS KNOWN.
CARCINOGENIC CATEGORIES:
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
13463-67-7 TITANIUM DIOXIDE 2B
108-88-3 TOLUENE 3
14807-96-6 TALC 2B
1330-20-7 XYLENE (MIX) 3
64-17-5 ETHYL ALCOHOL 1
67-63-0 ISOPROPYL ALCOHOL 3
NTP (NATIONAL TOXICOLOGY PROGRAM): NONE OF THE INGREDIENTS IS LISTED.
| 12 ECOLOGICAL INFORMATION | |
AQUATIC TOXICITY: HAZARDOUS FOR WATER, DO NOT EMPTY INTO DRAINS.
PERSISTENCE AND DEGRADABILITY:
THE PRODUCT IS DEGRADABLE AFTER PROLONGED EXPOSURE TO NATURAL WEATHERING
PROCESSES.
BIOACCUMULATIVE POTENTIAL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DO NOT
PUNCTURE, INCINERATE, OR COMPACT. PARTIALLY EMPTY CANS MUST BE DISPOSED OF
RESPONSIBLY. DO NOT HEAT OR CUT EMPTY CONTAINERS WITH ELECTRIC OR GAS
TORCHES.
RECOMMENDATION: COMPLETELY EMPTY CANS SHOULD BE RECYCLED.
| 14 TRANSPORT INFORMATION | |
UN-NUMBER: UN1950
DOT:
N/A
UN1950
DOT:
CONSUMER COMMODITY ORM-D
AEROSOLS, FLAMMABLE
ADR: 1950 AEROSOLS
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER:
WARNING: GASES
EMS NUMBER: F-D, S-U
PACKAGING GROUP:
UN "MODEL REGULATION": UN1950, AEROSOLS, 2.1
| 15 REGULATORY INFORMATION | |
SARA SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS IN THIS PRODUCT ARE LISTED.
SARA SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
108-88-3 TOLUENE
1330-20-7 XYLENE (MIX)
67-63-0 ISOPROPYL ALCOHOL
CPSC:
THIS PRODUCT COMPLIES WITH 16 CFR 1303 AND DOES NOT CONTAIN MORE THAN
90 PPM OF LEAD.
CALIFORNIA PROPOSITION 65 CHEMICALS KNOWN TO CAUSE CANCER:
13463-67-7 TITANIUM DIOXIDE
100-41-4 ETHYL BENZENE
1333-86-4 CARBON BLACK
108-10-1 METHYL ISOBUTYL KETONE
CALIFORNIA PROPOSITION 65 CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
108-88-3 TOLUENE
67-56-1 METHANOL
CANADIAN ENVIRONMENTAL PROTECTION ACT:
ALL HAZARDOUS INGREDIENTS FOR THIS PRODUCT APPEAR ON THE CANADIAN DOMESTICE
SUBSTANCE LIST.
WHMIS SYMBOLS FOR CANADA:
A - COMPRESSED GAS
D2A -VERY TOXIC MATERIAL CAUSING OTHER TOXIC EFFECTS
B - FLAMMABLE AND COMBUSTIBLE MATERIAL
EPA:
67-64-1 ACETONE I
108-88-3 TOLUENE II
1330-20-7 XYLENE (MIX) I
110-19-0 ISOBUTYL ACETATE D
| 16 OTHER INFORMATION | |
CONTACT: REGULATORY AFFAIRS
DATE OF PREPARATION / LAST REVISION: 02/08/2016 / -