| Common Name: | UNDERCOATING, PN 08881 |
| Manufacturer: | 3M |
| SDS Revision Date: | 5/21/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 527Y15 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) UNDERCOATING, PN 08881
05/21/18
3M
SAFETY DATA SHEET
COPYRIGHT,2018,3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 19-8684-3
ISSUE DATE: 05/21/18
VERSION NUMBER: 5.00
SUPERCEDES DATE: 04/04/18
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: 3M(TM) UNDERCOATING, PN 08881
PRODUCT IDENTIFICATION NUMBERS: 60-4400-9649-7
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: COATING, UNDERCOATING FOR AUTOMOBILES.
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: AUTOMOTIVE AFTERMARKET
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
THE LABEL ELEMENTS BELOW WERE PREPARED IN ACCORDANCE WITH OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
THIS INFORMATION MAY BE DIFFERENT FROM THE ACTUAL PRODUCT LABEL INFORMATION
FOR LABELS REGULATED BY OTHER AGENCIES.
2.1. HAZARD CLASSIFICATION:
FLAMMABLE AEROSOL: CATEGORY 1.
GAS UNDER PRESSURE: LIQUEFIED GAS.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2B.
SKIN CORROSION/IRRITATION: CATEGORY 2.
REPRODUCTIVE TOXICITY: CATEGORY 1B.
CARCINOGENICITY: CATEGORY 1A.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
FLAME
GAS CYLINDER
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
FLAME
GAS CYLINDER
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
MAY CAUSE CANCER.
CAUSES DAMAGE TO ORGANS: CARDIOVASCULAR SYSTEM
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
NERVOUS SYSTEM
SENSORY ORGANS
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
SPECIFIC TREATMENT (SEE NOTES TO PHYSICIAN ON THIS LABEL).
STORAGE:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50C/122F.
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
NOTES TO PHYSICIAN:
EXPOSURE MAY INCREASE MYOCARDIAL IRRITABILITY. DO NOT ADMINISTER
SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY.
15% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE DERMAL
TOXICITY.
60% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE
INHALATION TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
ASPHALT 8052-42-4 15 - 40 TRADE SECRET *
CALCIUM CARBONATE 471-34-1 15 - 40 TRADE SECRET *
TOLUENE 108-88-3 10 - 20 TRADE SECRET *
PROPANE 74-98-6 5 - 15 TRADE SECRET *
MEDIUM ALIPHATIC SOLVENT 64742-88-7 5 - 10 TRADE SECRET *
NAPHTHA
BUTANE 106-97-8 3 - 7 TRADE SECRET *
ALUMINATESILICATE 1327-36-2 1 - 5 TRADE SECRET *
QUARTZ SILICA 14808-60-7 0.1 - 1 TRADE SECRET *
METHYL ALCOHOL 67-56-1 <1 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION: REMOVE PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU ARE CONCERNED, GET MEDICAL ADVICE.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED:
EXPOSURE MAY INCREASE MYOCARDIAL IRRITABILITY. DO NOT ADMINISTER
SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
USE A FIRE FIGHTING AGENT SUITABLE FOR THE SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
HYDROCARBONS DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
HYDROGEN SULFIDE DURING COMBUSTION
OXIDES OF SULFUR DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED
TO KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO
SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
FOR LARGE SPILL, OR SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL
VENTILATION TO DISPERSE OR EXHAUST VAPORS, IN ACCORDANCE WITH GOOD
INDUSTRIAL HYGIENE PRACTICE.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY
PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
IF POSSIBLE, SEAL LEAKING CONTAINER. PLACE LEAKING CONTAINERS IN A
WELL-VENTILATED AREA, PREFERABLY AN OPERATING EXHAUST HOOD, OR IF NECESSARY
OUTDOORS ON AN IMPERMEABLE SURFACE UNTIL APPROPRIATE PACKAGING FOR THE
LEAKING CONTAINER OR ITS CONTENTS IS AVAILABLE. CONTAIN SPILL. COVER SPILL
AREA WITH A FIRE-EXTINGUISHING FOAM DESIGNED FOR USE ON SOLVENTS, SUCH AS
ALCOHOLS AND ACETONE, THAT CAN DISSOLVE IN WATER. AN AR - AFFF TYPE FOAM IS
RECOMMENDED. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH
BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE
USING NON-SPARKING TOOLS. PLACE IN A METAL CONTAINER APPROVED FOR
TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP RESIDUE WITH AN
APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED PERSON.
VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY PRECAUTIONS ON
THE SOLVENT LABEL AND SDS. SEAL THE CONTAINER. DISPOSE OF COLLECTED
MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE WITH APPLICABLE LOCAL/REGIONAL/
NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT USE IN A CONFINED AREA WITH MINIMAL AIR EXCHANGE. KEEP AWAY FROM
HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT SPRAY ON AN
OPEN FLAME OR OTHER IGNITION SOURCE. DO NOT PIERCE OR BURN, EVEN AFTER
USE. DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES,
ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. WASH THOROUGHLY AFTER HANDLING. AVOID CONTACT WITH OXIDIZING
AGENTS (EG. CHLORINE, CHROMIC ACID ETC.) USE PERSONAL PROTECTIVE EQUIPMENT
(GLOVES, RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. PROTECT
FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50C/122F. STORE
AWAY FROM ACIDS. STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL COMMENTS
BUTANE 106-97-8 ACGIH STEL: 1000 PPM
NATURAL GAS 106-97-8 ACGIH LIMIT VALUE NOT SIMPLE ASPHYXIANT
ESTABLISHED:
TOLUENE 108-88-3 ACGIH TWA: 20 PPM A4:
NOT CLASS. AS HUMAN
CARCIN
TOLUENE 108-88-3 OSHA TWA: 200 PPM
CEIL: 300 PPM
ALUMINUM, 1327-36-2 ACGIH TWA(RESPIRABLE A4:
INSOLUBLE FRACTION): NOT CLASS. AS HUMAN
COMPOUNDS 1 MG/M3 CARCIN
QUARTZ SILICA 14808-60-7 ACGIH TWA(RESPIRABLE A2:
FRACTION): SUSPECTED HUMAN
0.025 MG/M3 CARCIN.
QUARTZ SILICA 14808-60-7 OSHA TWA TABLE Z-
1(RESPIRABLE):
0.05
MG/M3; TWA
TABLE Z-
3(RESPIRABLE):
0.1 MG/M3
LIMESTONE 471-34-1 OSHA TWA(AS TOTAL
DUST):
15 MG/M3
TWA(RESPIRABLE
FRACTION):
5 MG/M3
METHYL 67-56-1 ACGIH TWA: 200 PPM SKIN
ALCOHOL STEL: 250 PPM
METHYL 67-56-1 OSHA TWA:
ALCOHOL 260 MG/M3
(200 PPM)
PROPANE 74-98-6 ACGIH LIMIT VALUE
NOT ESTABLISHED: SIMPLE ASPHYXIANT
PROPANE 74-98-6 OSHA TWA:
1800 MG/M3
(1000 PPM)
ASPHALT 8052-42-4 ACGIH TWA(AS BENZENE A4:
SOLUBLES, NOT CLASS. AS HUMAN
INHALABLE CARCIN
FRACTION):
0.5 MG/M3
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
PROVIDE VENTILATED ENCLOSURE FOR HEAT CURING. CURING ENCLOSURES MUST BE
EXHAUSTED TO OUTDOORS OR TO A SUITABLE EMISSION CONTROL DEVICE. USE GENERAL
DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO CONTROL AIRBORNE
EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
FLUOROELASTOMER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE SUPPLIED-AIR RESPIRATOR
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: AEROSOL
ODOR, COLOR, GRADE: THICK BLACK SOLUTION WITH A SOLVENT ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: -20 DEG. F
EVAPORATION RATE: >= 1 [REF STD: ETHER=1]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): 1.0%
FLAMMABLE LIMITS(UEL): 9.5%
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: >= 1 [REF STD: AIR=1]
DENSITY: 1.1 G/ML
SPECIFIC GRAVITY: 1.1 [REF STD: WATER=1]
SOLUBILITY IN WATER: NOT APPLICABLE
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/ WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
AVERAGE PARTICLE SIZE: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS: 0.29 LB HAPS/LB SOLIDS [TESTMETHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
39.1% WEIGHT [TEST METHOD: CALCULATED PER CARB TITLE 2]
VOLATILE ORGANIC COMPOUNDS:
430 G/L [TEST METHOD: CALCULATED SCAQMD RULE 443.1]
PERCENT VOLATILE: 61.0%
VOC LESS H2O & EXEMPT SOLVENTS:
430 G/L [TESTMETHOD: CALCULATED SCAQMD RULE 443.1]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL IS CONSIDERED TO BE NON REACTIVE UNDER NORMAL USE CONDITIONS.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: NONE KNOWN.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION: MAY BE HARMFUL IF INHALED.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
EYE CONTACT:
MODERATE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED OR
HAZY VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
SINGLE EXPOSURE, ABOVE RECOMMENDED GUIDELINES, MAY CAUSE:
CARDIAC SENSITIZATION:
SIGNS/SYMPTOMS MAY INCLUDE IRREGULAR HEARTBEAT (ARRHYTHMIA), FAINTNESS,
CHEST PAIN, AND MAY BE FATAL.
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
OCULAR EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE BLURRED OR SIGNIFICANTLY IMPAIRED VISION.
AUDITORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE HEARING IMPAIRMENT, BALANCE DYSFUNCTION AND
RINGING IN THE EARS.
OLFACTORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE DECREASED ABILITY TO DETECT ODORS AND/OR
COMPLETE LOSS OF SMELL.
NEUROLOGICAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE PERSONALITY CHANGES, LACK OF COORDINATION,
SENSORY LOSS, TINGLING OR NUMBNESS OF THE EXTREMITIES, WEAKNESS, TREMORS,
AND/OR CHANGES IN BLOOD PRESSURE AND HEART RATE.
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
CARCINOGENICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE CANCER.
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
SILICA, CRYS 14808-60-7 KNOWN HUMAN NATIONAL TOXICOLOGY
AIRRESP CARCINOGEN PROGRAM CARCINOGENS
ASPHALT 8052-42-4 GRP. 2B: INTERNATIONAL AGENCY FOR
POSSIBLE HUMAN RESEARCH ON CANCER
CARC.
QUARTZ SILICA 14808-60-7 GRP. 1: INTERNATIONAL AGENCY FOR
CARCINOGENIC TO RESEARCH ON CANCER
HUMANS
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE >5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR(4 HR) CALCULATED ATE 20 - 50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE >5,000 MG/KG
ASPHALT DERMAL RABBIT LD50: >2,000 MG/KG
ASPHALT INGESTION RAT LD50: >5,000 MG/KG
CALCIUM CARBONATE DERMAL RAT LD50: >2,000 MG/KG
CALCIUM CARBONATE INHALATION- RAT LC50: 3 MG/L
DUST/MIST
(4 HOURS)
CALCIUM CARBONATE INGESTION RAT LD50: 6,450 MG/KG
TOLUENE DERMAL RAT LD50: 12,000 MG/KG
TOLUENE INHALATION- RAT LC50: 30 MG/L
VAPOR
(4 HOURS)
TOLUENE INGESTION RAT LD50: 5,550 MG/KG
PROPANE INHALATION- RAT LC50: >200,000 PPM
GAS (4
HOURS)
MEDIUM ALIPHATIC INHALATION- LC50 ESTIMATED TO
SOLVENT NAPHTHA VAPOR BE 20 - 50 MG/L
MEDIUM ALIPHATIC DERMAL RABBIT LD50: >3,000 MG/KG
SOLVENT NAPHTHA
MEDIUM ALIPHATIC INGESTION RAT LD50: >5,000 MG/KG
SOLVENT NAPHTHA
BUTANE INHALATION- RAT LC50: 277,000 PPM
GAS (4
HOURS)
ALUMINATESILICATE DERMAL LD50 ESTIMATED TO BE
>5,000 MG/KG
ALUMINATESILICATE INGESTION LD50 ESTIMATED TO BE
>5,000 MG/KG
METHYL ALCOHOL DERMAL LD50 ESTIMATED TO BE
1,000 - 2,000 MG/KG
METHYL ALCOHOL INHALATION- LC50 ESTIMATED TO BE
VAPOR 10 - 20 MG/L
METHYL ALCOHOL INGESTION LD50 ESTIMATED TO BE
50 - 300 MG/KG
QUARTZ SILICA DERMAL LD50 ESTIMATED TO BE
>5,000 MG/KG
QUARTZ SILICA INGESTION LD50 ESTIMATED TO BE
>5,000 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
ASPHALT HUMAN MINIMAL IRRITATION
CALCIUM CARBONATE RABBIT NO SIGNIFICANT IRRITATION
TOLUENE RABBIT IRRITANT
PROPANE RABBIT MINIMAL IRRITATION
MEDIUM ALIPHATIC SOLVENT RABBIT IRRITANT
NAPHTHA
BUTANE PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
METHYL ALCOHOL RABBIT MILD IRRITANT
QUARTZ SILICA PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
ASPHALT HUMAN MILD IRRITANT
CALCIUM CARBONATE RABBIT NO SIGNIFICANT IRRITATION
TOLUENE RABBIT MODERATE IRRITANT
PROPANE RABBIT MILD IRRITANT
MEDIUM ALIPHATIC SOLVENT RABBIT NO SIGNIFICANT IRRITATION
NAPHTHA
BUTANE RABBIT NO SIGNIFICANT IRRITATION
METHYL ALCOHOL RABBIT MODERATE IRRITANT
SKIN SENSITIZATION:
NAME SPECIES VALUE
TOLUENE GUINEA NOT SENSITIZING
PIG
MEDIUM ALIPHATIC SOLVENT GUINEA NOT SENSITIZING
NAPHTHA PIG
METHYL ALCOHOL GUINEA NOT SENSITIZING
PIG
PHOTOSENSITIZATION:
NAME SPECIES VALUE
ASPHALT HUMAN NOT SENSITIZING
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
ASPHALT IN VIVO NOT MUTAGENIC
ASPHALT IN VITRO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE IN VITRO NOT MUTAGENIC
TOLUENE IN VIVO NOT MUTAGENIC
PROPANE IN VITRO NOT MUTAGENIC
MEDIUM ALIPHATIC SOLVENT IN VIVO NOT MUTAGENIC
NAPHTHA
MEDIUM ALIPHATIC SOLVENT IN VITRO SOME POSITIVE DATA EXIST, BUT THE
NAPHTHA DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
BUTANE IN VITRO NOT MUTAGENIC
METHYL ALCOHOL IN VITRO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
METHYL ALCOHOL IN VIVO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
QUARTZ SILICA IN VITRO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
QUARTZ SILICA IN VIVO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
ASPHALT NOT HUMAN SOME POSITIVE DATA EXIST, BUT THE
SPECIFIED AND DATA ARE NOT SUFFICIENT FOR
ANIMAL CLASSIFICATION
TOLUENE DERMAL MOUSE SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION RAT SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION MOUSE SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
MEDIUM ALIPHATIC DERMAL MOUSE SOME POSITIVE DATA EXIST, BUT THE
SOLVENT NAPHTHA DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
MEDIUM ALIPHATIC INHALATION HUMAN SOME POSITIVE DATA EXIST, BUT THE
SOLVENT NAPHTHA AND DATA ARE NOT SUFFICIENT FOR
ANIMAL CLASSIFICATION
METHYL ALCOHOL INHALATION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
QUARTZ SILICA INHALATION HUMAN CARCINOGENIC
AND
ANIMAL
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
CALCIUM CARBONATE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
TOLUENE INHALATION NOT CLASSIFIED FOR FEMALE
REPRODUCTION
TOLUENE INHALATION NOT CLASSIFIED FOR MALE REPRODUCTION
TOLUENE INGESTION TOXIC TO DEVELOPMENT
TOLUENE INHALATION TOXIC TO DEVELOPMENT
MEDIUM ALIPHATIC INHALATION NOT CLASSIFIED FOR DEVELOPMENT
SOLVENT NAPHTHA
METHYL ALCOHOL INGESTION NOT CLASSIFIED FOR MALE REPRODUCTION
METHYL ALCOHOL INGESTION TOXIC TO DEVELOPMENT
METHYL ALCOHOL INHALATION TOXIC TO DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
CALCIUM CARBONATE RAT NOAEL: PREMATING &
625 MG/KG/DAY DURING GESTATION
TOLUENE HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
TOLUENE RAT NOAEL: 2.3 MG/L 1 GENERATION
TOLUENE RAT LOAEL: DURING GESTATION
520 MG/KG/DAY
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
MEDIUM ALIPHATIC RAT NOAEL: 2.4 MG/L DURING ORGANOGENESIS
SOLVENT NAPHTHA
METHYL ALCOHOL RAT NOAEL: 21 DAYS
1,600 MG/KG/DAY
METHYL ALCOHOL MOUSE LOAEL: DURING ORGANOGENESIS
4,000 MG/KG/DAY
METHYL ALCOHOL MOUSE NOAEL: 1.3 MG/L DURING ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
CALCIUM CARBONATE INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
TOLUENE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
TOLUENE INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
TOLUENE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
PROPANE INHALATION CARDIAC CAUSES DAMAGE TO
SENSITIZATION ORGANS
PROPANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
PROPANE INHALATION RESPIRATORY NOT CLASSIFIED
IRRITATION
MEDIUM ALIPHATIC INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SOLVENT NAPHTHA SYSTEM DEPRESSION OR DIZZINESS
MEDIUM ALIPHATIC INHALATION RESPIRATORY SOME POSITIVE DATA
SOLVENT NAPHTHA IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR
CLASSIFICATION
MEDIUM ALIPHATIC INHALATION NERVOUS SYSTEM NOT CLASSIFIED
SOLVENT NAPHTHA
MEDIUM ALIPHATIC INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SOLVENT NAPHTHA SYSTEM DEPRESSION OR DIZZINESS
BUTANE INHALATION CARDIAC CAUSES DAMAGE TO
SENSITIZATION ORGANS
BUTANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
BUTANE INHALATION HEART NOT CLASSIFIED
BUTANE INHALATION RESPIRATORY NOT CLASSIFIED
IRRITATION
METHYL ALCOHOL INHALATION BLINDNESS CAUSES DAMAGE TO
ORGANS
METHYL ALCOHOL INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
METHYL ALCOHOL INHALATION RESPIRATORY SOME POSITIVE DATA
IRRITATION EXIST, BUT THE DATA
ARE NOT SUFFICIENT FOR
CLASSIFICATION
METHYL ALCOHOL INGESTION BLINDNESS CAUSES DAMAGE TO
ORGANS
METHYL ALCOHOL INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS
SYSTEM DEPRESSION OR DIZZINESS
NAME SPECIES TEST RESULT EXPOSURE DURATION
CALCIUM CARBONATE RAT NOAEL: 0.812 MG/L 90 MINUTES
TOLUENE HUMAN NOAEL:
NOT AVAILABLE
TOLUENE HUMAN NOAEL:
NOT AVAILABLE
TOLUENE MOUSE NOAEL: 0.004 MG/L 3 HOURS
TOLUENE HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
PROPANE HUMAN NOAEL:
NOT AVAILABLE
PROPANE HUMAN NOAEL:
NOT AVAILABLE
PROPANE HUMAN NOAEL:
NOT AVAILABLE
MEDIUM ALIPHATIC HUMAN NOAEL:
SOLVENT NAPHTHA AND NOT AVAILABLE
ANIMAL
MEDIUM ALIPHATIC NOAEL:
SOLVENT NAPHTHA NOT AVAILABLE
MEDIUM ALIPHATIC DOG NOAEL: 6.5 MG/L 4 HOURS
SOLVENT NAPHTHA
MEDIUM ALIPHATIC PROFESSIONAL NOAEL:
SOLVENT NAPHTHA JUDGEMENT NOT AVAILABLE
BUTANE HUMAN NOAEL:
NOT AVAILABLE
BUTANE HUMAN NOAEL:
AND NOT AVAILABLE
ANIMAL
BUTANE DOG NOAEL: 5,000 PPM 25 MINUTES
BUTANE RABBIT NOAEL:
NOT AVAILABLE
METHYL ALCOHOL HUMAN NOAEL: OCCUPATIONAL
NOT AVAILABLE EXPOSURE
METHYL ALCOHOL HUMAN NOAEL: NOT AVAILABLE
NOT AVAILABLE
METHYL ALCOHOL RAT NOAEL: 6 HOURS
NOT AVAILABLE
METHYL ALCOHOL HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
METHYL ALCOHOL HUMAN NOAEL: POISONING
NOT AVAILABLE AND/OR ABUSE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
ASPHALT INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
CALCIUM CARBONATE INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
TOLUENE INHALATION AUDITORY SYSTEM CAUSES DAMAGE TO ORGANS
NERVOUS SYSTEM THROUGH PROLONGED OR
EYES REPEATED EXPOSURE
OLFACTORY SYSTEM
TOLUENE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INHALATION HEART NOT CLASSIFIED
LIVER
KIDNEY AND/OR
BLADDER
TOLUENE INHALATION ENDOCRINE SYSTEM NOT CLASSIFIED
TOLUENE INHALATION IMMUNE SYSTEM NOT CLASSIFIED
TOLUENE INHALATION BONE, TEETH, NOT CLASSIFIED
NAILS, AND/OR HAIR
TOLUENE INHALATION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
VASCULAR SYSTEM
TOLUENE INHALATION GASTROINTESTINAL NOT CLASSIFIED
TRACT
TOLUENE INGESTION NERVOUS SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
TOLUENE INGESTION HEART NOT CLASSIFIED
TOLUENE INGESTION LIVER NOT CLASSIFIED
KIDNEY AND/OR
BLADDER
TOLUENE INGESTION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
TOLUENE INGESTION ENDOCRINE SYSTEM NOT CLASSIFIED
TOLUENE INGESTION IMMUNE SYSTEM NOT CLASSIFIED
MEDIUM ALIPHATIC INHALATION NERVOUS SYSTEM NOT CLASSIFIED
SOLVENT NAPHTHA
MEDIUM ALIPHATIC INHALATION KIDNEY AND/OR NOT CLASSIFIED
SOLVENT NAPHTHA BLADDER
MEDIUM ALIPHATIC INHALATION RESPIRATORY NOT CLASSIFIED
SOLVENT NAPHTHA SYSTEM
MEDIUM ALIPHATIC INHALATION BONE, TEETH, NOT CLASSIFIED
SOLVENT NAPHTHA NAILS, AND/OR
HAIR
BLOOD
LIVER
MUSCLES
MEDIUM ALIPHATIC INHALATION HEART NOT CLASSIFIED
SOLVENT NAPHTHA
BUTANE INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
METHYL ALCOHOL INHALATION LIVER NOT CLASSIFIED
METHYL ALCOHOL INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
METHYL ALCOHOL INGESTION LIVER NOT CLASSIFIED
NERVOUS SYSTEM
QUARTZ SILICA INHALATION SILICOSIS CAUSES DAMAGE TO ORGANS
THROUGH PROLONGED OR
REPEATED EXPOSURE
NAME SPECIES TEST RESULT EXPOSURE DURATION
ASPHALT HUMAN NOAEL: OCCUPATIONAL EXPOSURE
NOT AVAILABLE
CALCIUM CARBONATE HUMAN NOAEL: OCCUPATIONAL EXPOSURE
NOT AVAILABLE
TOLUENE HUMAN NOAEL: POISONING AND/OR ABUSE
NOT AVAILABLE
TOLUENE RAT LOAEL: 2.3 MG/L 15 MONTHS
TOLUENE RAT NOAEL: 11.3 MG/L 15 WEEKS
TOLUENE RAT NOAEL: 1.1 MG/L 4 WEEKS
TOLUENE MOUSE NOAEL: 20 DAYS
NOT AVAILABLE
TOLUENE MOUSE NOAEL: 1.1 MG/L 8 WEEKS
TOLUENE HUMAN NOAEL: OCCUPATIONAL EXPOSURE
NOT AVAILABLE
TOLUENE MULTIPLE NOAEL: 11.3 MG/L 15 WEEKS
ANIMAL NOT AVAILABLE
SPECIES
TOLUENE RAT NOAEL: 13 WEEKS
625 MG/KG/DAY
TOLUENE RAT NOAEL: 13 WEEKS
2,500 MG/KG/DAY
TOLUENE MULTIPLE NOAEL: 13 WEEKS
ANIMAL 2,500 MG/KG/DAY
SPECIES
TOLUENE MOUSE NOAEL: 14 DAYS
600 MG/KG/DAY
TOLUENE MOUSE NOAEL: 28 DAYS
105 MG/KG/DAY
TOLUENE MOUSE NOAEL: 4 WEEKS
105 MG/KG/DAY
MEDIUM ALIPHATIC RAT LOAEL: 4.6 MG/L 6 MONTHS
SOLVENT NAPHTHA
MEDIUM ALIPHATIC RAT LOAEL: 1.9 MG/L 13 WEEKS
SOLVENT NAPHTHA
MEDIUM ALIPHATIC MULTIPLE NOAEL: 0.6 MG/L 90 DAYS
SOLVENT NAPHTHA ANIMAL
SPECIES
MEDIUM ALIPHATIC RAT NOAEL: 5.6 MG/L 12 WEEKS
SOLVENT NAPHTHA
MEDIUM ALIPHATIC MULTIPLE NOAEL: 1.3 MG/L 90 DAYS
SOLVENT NAPHTHA ANIMAL
SPECIES
BUTANE RAT NOAEL: 4,489 PPM 90 DAYS
METHYL ALCOHOL RAT NOAEL: 6.55 MG/L 4 WEEKS
METHYL ALCOHOL RAT NOAEL: 13.1 MG/L 6 WEEKS
METHYL ALCOHOL RAT NOAEL: 90 DAYS
2,500 MG/KG/DAY
QUARTZ SILICA HUMAN NOAEL: OCCUPATIONAL EXPOSURE
NOT AVAILABLE
ASPIRATION HAZARD:
NAME VALUE
TOLUENE ASPIRATION HAZARD
MEDIUM ALIPHATIC SOLVENT NAPHTHA ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATERIAL IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE UNCURED
PRODUCT IN A PERMITTED WASTE INCINERATION FACILITY. FACILITY MUST BE
CAPABLE OF HANDLING AEROSOL CANS. IF NO OTHER DISPOSAL OPTIONS ARE
AVAILABLE, WASTE PRODUCT THAT HAS BEEN COMPLETELY CURED OR POLYMERIZED MAY
BE PLACED IN A LANDFILL PROPERLY DESIGNED FOR INDUSTRIAL WASTE. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS:
FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
GAS UNDER PRESSURE
HEALTH HAZARDS:
CARCINOGENICITY
REPRODUCTIVE TOXICITY
SERIOUS EYE DAMAGE OR EYE IRRITATION
SKIN CORROSION OR IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
TOLUENE 108-88-3 TRADE SECRET 10 - 20
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. CLASSIFICATION
BITUMENS, EXTRACTS OF STEAM- NONE CARCINOGEN
REFINED AND AIR-REFINED
SILICA, CRYSTALLINE (AIRBORNE NONE CARCINOGEN
PARTICLES OF RESPIRABLE SIZE)
TOLUENE 108-88-3 DEVELOPMENTAL TOXIN
METHYL ALCOHOL 67-56-1 DEVELOPMENTAL TOXIN
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS
PRODUCT ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 4
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED
ON THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO
INCLUDE THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT
ARE KNOWN TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 19-8684-3
VERSION NUMBER: 5.00
ISSUE DATE: 05/21/18
SUPERCEDES DATE: 04/04/18
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
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GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND APPLICATION OF
A 3MPRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S KNOWLEDGE AND
CONTROL,IT IS ESSENTIAL THAT THE USER EVALUATE THE3MPRODUCT TO DETERMINE
WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD
OF USE OR APPLICATION.
3MPROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
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