| Common Name: | LOCTITE PC 7227 GY KNOWN AS NORDBAK BRUSHABLE CERAMIC GREY, 98732_10362000, LOCT |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 8/5/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 52HA73 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 007.0
ISSUE DATE: 08/05/2014
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE PC 7227 GY KNOWN AS NORDBAK BRUSHABLE CERAMIC GREY
IDH NUMBER: 702262
ITEM NUMBER: 98732_10362000
PRODUCT TYPE: EPOXY RESIN
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING DUST OR FUMES. WASH THOROUGHLY AFTER HANDLING. USE ONLY
OUTDOORS OR IN A WELL-VENTILATED AREA. CONTAMINATED WORK CLOTHING SHOULD
NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR EYE AND FACE PROTECTION. WEAR
PROTECTIVE GLOVES.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING. CALL A POISON CONTROL CENTER
OR PHYSICIAN IF YOU FEEL UNWELL.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
SILICON CARBIDE 409-21-2 30 - 60
EPOXY RESIN PROPRIETARY 30 - 60
ALUMINUM OXIDE, FIBROUS 1344-28-1 1 - 5
SUBSTITUTED SILANE PROPRIETARY 0.1 - 1
SILICON 7440-21-3 0.1 - 1
CRISTOBALITE 14464-46-1 0.1 - 1
ALUMINUM 7429-90-5 0.1 - 1
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. GET MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO
EXTREME HEAT. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. ALDEHYDES. ACIDS. PHENOLICS. CARBONYL FLUORIDE.
HEXAFLUOROPROPENE. PERFLUOROISOBUTYLENE. TETRAFLUOROETHYLENE. IRRITATING
ORGANIC FRAGMENTS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. IMMEDIATELY CONTACT EMERGENCY PERSONNEL.
EVACUATE AND VENTILATE SPILL AREA; DIKE SPILL TO PREVENT ENTRY INTO WATER
SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT DURING CLEAN-UP. SOAK UP WITH INERT
ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER, UNIVERSAL BINDER,
SAWDUST). SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. STORE IN A CLOSED
CONTAINER UNTIL READY FOR DISPOSAL. REFER TO SECTION 8 "EXPOSURE CONTROLS /
PERSONAL PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
DO NOT TASTE OR SWALLOW. KEEP CONTAINER CLOSED. USE ONLY WITH ADEQUATE
VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE
VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING. REFER TO SECTION 8.
STORAGE:
STORE IN ORIGINAL CONTAINER UNTIL READY TO USE. KEEP IN A COOL, WELL
VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME. KEEP CONTAINER
TIGHTLY CLOSED UNTIL READY FOR USE.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE AT:
(800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
SILICON CARBIDE 10 MG/M3 TWA 5 MG/M3 PEL NONE NONE
INHALABLE RESPIRABLE
FRACTION. FRACTION.
3 MG/M3 TWA 15 MG/M3 PEL
RESPIRABLE TOTAL DUST.
FRACTION.
0.1 FIBERS/CM3
TWA FIBER.
EPOXY RESIN NONE NONE NONE NONE
ALUMINUM OXIDE, 1 MG/M3 TWA 5 MG/M3 PEL NONE NONE
FIBROUS RESPIRABLE RESPIRABLE
FRACTION. FRACTION.
15 MG/M3 PEL
TOTAL DUST.
SUBSTITUTED SILANE NONE NONE NONE NONE
SILICON NONE 5 MG/M3 PEL NONE NONE
RESPIRABLE
FRACTION.
15 MG/M3 PEL
TOTAL DUST.
CRISTOBALITE 0.025 MG/M3 TWA 0.05 MG/M3 NONE NONE
RESPIRABLE TWA
FRACTION. RESPIRABLE.
0.15 MG/M3
TWA TOTAL
DUST.
1.2 MPPCF
TWA
RESPIRABLE.
ALUMINUM 1 MG/M3 TWA 5 MG/M3 PEL NONE NONE
RESPIRABLE (AS Al)
FRACTION. RESPIRABLE
DUST.
15 MG/M3 PEL
(AS Al) TOTAL
DUST.
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN
APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE
COLOR: WHITE
ODOR: EPOXY, MILD, PETROLEUM
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.743
VAPOR DENSITY: >1
FLASH POINT: >93 DEG. C (>199.4 DEG. F) TAGLIABUE CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: SLOWER THAN BUTYL ACETATE.
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: <0.1%; <1 G/L (VALUE FOR RESIN AND HARDENER TOGETHER)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS: OXIDES OF CARBON. IRRITATING VAPORS.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. STRONG BASES. STRONG LEWIS ACIDS. STRONG MINERAL
ACIDS. STRONG ACIDS. AMINES. MERCAPTANS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION. EXCESSIVE HEAT. STORE
AWAY FROM INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE RESPIRATORY TRACT IRRITATION. INHALATION OF VAPORS OR MISTS OF
THE PRODUCT MAY BE IRRITATING TO THE RESPIRATORY SYSTEM. VAPORS AND MISTS
WILL IRRITATE NOSE AND THROAT AND POSSIBLY EYES.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
SILICON CARBIDE NONE NUISANCE DUST
EPOXY RESIN NONE ALLERGEN, IRRITANT
ALUMINUM OXIDE, FIBROUS NONE IRRITANT, NUISANCE DUST,
CORROSIVE
SUBSTITUTED SILANE NONE ALLERGEN, IRRITANT
SILICON NONE IRRITANT, NUISANCE DUST
CRISTOBALITE NONE CARCINOGEN, IMMUNE SYSTEM,
KIDNEY, LUNG
ALUMINUM NONE CENTRAL NERVOUS SYSTEM, IRRITANT,
LUNG
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY REGULATED)
SILICON CARBIDE NO NO NO
EPOXY RESIN NO NO NO
ALUMINUM OXIDE, FIBROUS NO NO NO
SUBSTITUTED SILANE NO NO NO
SILICON NO NO NO
CRISTOBALITE KNOWN TO BE GROUP 1 NO
HUMAN
CARCINOGEN.
ALUMINUM NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BISPHENOL-A
EPICHLORHYDRIN RESIN)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BISPHENOL-A
EPICHLORHYDRIN RESIN)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
MARINE POLLUTANT: BISPHENOL-A EPICHLORHYDRIN RESIN
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). ALUMINUM OXIDE, FIBROUS
(CAS# 1344-28-1).
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: SHEILA GINES, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 08/05/2014
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 005.0
ISSUE DATE: 08/04/2014
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: LOCTITE PC 7227 GY KNOWN AS NORDBAK BRUSH CERAMIC - GREY
IDH NUMBER: 702263
ITEM NUMBER: 98732_301000
PRODUCT TYPE: EPOXY HARDENER
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
COMBUSTIBLE LIQUID.
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING
DIFFICULTIES IF INHALED.
MAY CAUSE DROWSINESS OR DIZZINESS.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE LIQUID 4
SKIN CORROSION 1C
SERIOUS EYE DAMAGE 1
RESPIRATORY SENSITIZATION 1
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S):
HEALTH HAZARD
CORROSION
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES - NO SMOKING. DO NOT
BREATHE VAPORS, MIST, OR SPRAY. WASH THOROUGHLY AFTER HANDLING. USE ONLY
OUTDOORS OR IN A WELL-VENTILATED AREA. CONTAMINATED WORK CLOTHING SHOULD
NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE GLOVES, EYE
PROTECTION, AND FACE PROTECTION. IN CASE OF INADEQUATE VENTILATION WEAR
RESPIRATORY PROTECTION.
RESPONSE:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR): TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CONTROL CENTER OR PHYSICIAN.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE REUSE.
IN CASE OF FIRE: USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A
WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
4% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE TOXICITY.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
BENZYL ALCOHOL 100-51-6 30 - 60
FORMALDEHYDE AMINE POLYMER PROPRIETARY 30 - 60
PHENOLIC ACID PROPRIETARY 5 - 10
DIETHYLENETRIAMINE 111-40-0 1 - 5
SUBSTITUTED AMINE PROPRIETARY 1 - 5
4,4'-ISOPROPYLIDENEDIPHENOL 80-05-7 1 - 5
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH CLOTHING BEFORE REUSE.
THOROUGHLY CLEAN SHOES BEFORE REUSE. GET MEDICAL ATTENTION.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY. CLOSED CONTAINERS
MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. AMMONIA. PHENOLICS. NITRIC ACID.
ALDEHYDES. NITROSAMINES. IRRITATING ORGANIC FRAGMENTS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. IMMEDIATELY CONTACT EMERGENCY PERSONNEL.
EVACUATE AND VENTILATE SPILL AREA; DIKE SPILL TO PREVENT ENTRY INTO WATER
SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT DURING CLEAN-UP. SOAK UP WITH INERT
ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER, UNIVERSAL BINDER,
SAWDUST). SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. STORE IN A CLOSED
CONTAINER UNTIL READY FOR DISPOSAL. REFER TO SECTION 8 "EXPOSURE CONTROLS /
PERSONAL PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
DO NOT TASTE OR SWALLOW. USE ONLY WITH ADEQUATE VENTILATION. KEEP CONTAINER
CLOSED. PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR
AND MIST. WASH THOROUGHLY AFTER HANDLING. REFER TO SECTION 8.
STORAGE:
STORE AWAY FROM HEAT, SPARKS, FLAMES, OR OTHER SOURCES OF IGNITION. KEEP
CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY FROM
INCOMPATIBLE MATERIALS.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE AT:
(800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
BENZYL ALCOHOL NONE NONE 10 PPM (44.20 NONE
MG/M3) TWA
FORMALDEHYDE AMINE POLYMER NONE NONE NONE NONE
PHENOLIC ACID NONE NONE NONE NONE
DIETHYLENETRIAMINE 1 PPM TWA NONE NONE NONE
(SKIN)
SUBSTITUTED AMINE NONE NONE NONE NONE
4,4'-ISOPROPYLIDENE- NONE NONE NONE NONE
DIPHENOL
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN
APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: LIGHT YELLOW
ODOR: AMMONIACAL
ODOR THRESHOLD: NOT AVAILABLE.
PH: ALKALINE
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: 400 DEG. C (752 DEG. F)
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.0616
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: 93 DEG. C (199.4 DEG. F) SETAFLASH CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: PARTIALLY SOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: <0.1%; <1 G/L (VALUE FOR RESIN AND HARDENER TOGETHER)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON AND NITROGEN, ALDEHYDES, ACIDS AND UNDETERMINED ORGANICS.
AMMONIA. PHENOLICS. NITROSAMINES.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. STRONG REDUCING AGENTS. METALS. ACIDS. STRONG
MINERAL ACIDS. STRONG BASES. PEROXIDES.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
STORE AWAY FROM INCOMPATIBLE MATERIALS. EXCESSIVE HEAT. HEAT, FLAMES,
SPARKS AND OTHER SOURCES OF IGNITION.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE ALLERGIC RESPIRATORY REACTION. THESE SYMPTOMS, WHICH CAN INCLUDE
CHEST TIGHTNESS, WHEEZING, COUGH, SHORTNESS OF BREATH OR ASTHMA ATTACK,
COULD BE IMMEDIATE OR DELAYED (UP TO SEVERAL HOURS AFTER EXPOSURE). MAY
CAUSE DIZZINESS, INCOORDINATION, HEADACHE, NAUSEA, AND VOMITING.
SKIN CONTACT:
CORROSIVE TO SKIN. CAUSES SKIN BURNS. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION:
MAY CAUSE BURNS OF MOUTH AND THROAT IF SWALLOWED. IRRITATION AND CORROSIVE
ACTION CAN OCCUR IN THE MOUTH, STOMACH TISSUE AND DIGESTIVE TRACT IF
SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
BENZYL ALCOHOL ORAL LD50 (RABBIT): ALLERGEN, CENTRAL NERVOUS
1,940 MG/KG SYSTEM, CORROSIVE,
ORAL LD50 (RAT): IRRITANT
1,230 - 3,100 MG/KG
ORAL LD50 (RAT):
3,100 MG/KG
DERMAL LD50 (RABBIT):
2,000 MG/KG
INHALATION LC50
(RAT, 8 H): 1,000 MG/L
FORMALDEHYDE AMINE NONE NO RECORDS
POLYMER
PHENOLIC ACID ORAL LD50 (RAT): IRRITANT
891 MG/KG
DERMAL LD50 (RAT):
>2 G/KG
DIETHYLENETRIAMINE ORAL LD50 (RAT): ALLERGEN, IRRITANT, EYES
1,080 MG/KG
ORAL LD50 (RAT):
2.33 G/KG
ORAL LD50 (RAT)
APPROXIMATE:
1,140 MG/KG
SUBSTITUTED AMINE NONE IRRITANT, ALLERGEN
4,4'-ISOPROPYLIDENE- ORAL LD50 (RAT): ALLERGEN, BLOOD, IRRITANT,
DIPHENOL 4,100 MG/KG KIDNEY, REPRODUCTIVE,
ORAL LD50 (RAT): SPLEEN
3,300 MG/KG
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC OSHA CARCINOGEN
CARCINOGEN (SPECIFICALLY
REGULATED)
BENZYL ALCOHOL NO NO NO
FORMALDEHYDE AMINE POLYMER NO NO NO
PHENOLIC ACID NO NO NO
DIETHYLENETRIAMINE NO NO NO
SUBSTITUTED AMINE NO NO NO
4,4'-ISOPROPYLIDENEDIPHENOL NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER:
IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE IF AN ITEM IS HAZARDOUS
AS DEFINED IN THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) AT THE TIME
OF DISPOSAL. PRODUCT USES, TRANSFORMATIONS, MIXTURES, PROCESSES, ETC., MAY
RENDER THE RESULTING MATERIAL HAZARDOUS, UNDER THE CRITERIA OF
IGNITABILITY, CORROSIVITY, REACTIVITY AND TOXICITY CHARACTERISTICS OF THE
TOXICITY CHARACTERISTICS LEACHING PROCEDURE (TCLP) 40 CFR 261.20-24.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME:
AMINES, LIQUID, CORROSIVE, N.O.S. (DIETHYLENETRIAMINE,
4,4-METHYLENEBISCYCLOHEXYLAMINE)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 2735
PACKING GROUP: III
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
AMINES, LIQUID, CORROSIVE, N.O.S. (DIETHYLENETRIAMINE,
4,4-METHYLENEBISCYCLOHEXYLAMINE)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 2735
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
AMINES, LIQUID, CORROSIVE, N.O.S. (DIETHYLENETRIAMINE,
4,4-METHYLENEBISCYCLOHEXYLAMINE)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 2735
PACKING GROUP: III
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372).
4,4'-ISOPROPYLIDENEDIPHENOL (CAS# 80-05-7).
CALIFORNIA PROPOSITION 65:
NO CALIFORNIA PROPOSITION 65 LISTED CHEMICALS ARE KNOWN TO BE PRESENT.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: SHEILA GINES, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 08/04/2014
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.