| Common Name: | B-12 CHEMTOOL FUEL SYSTEM CLEANER |
| Manufacturer: | BERRYMAN PRODUCTS |
| SDS Revision Date: | 7/8/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 52HF60 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
BERRYMAN(R*)
SINCE 1918
| SECTION 1 - IDENTIFICATION OF THE MIXTURE AND OF THE COMPANY |  |
PRODUCT IDENTIFICATION:
PRIMARY IDENTIFIER(S) USED ON THE LABEL:
BERRYMAN B-12 CHEMTOOL FUEL SYSTEM CLEANER
PRODUCT SYNONYM(S): BLEND "1AA-1"
PRODUCT NUMBER(S): 0101, 0105, 0115, 0116, AND 0155
RELEVANT IDENTIFIED USES AND USES ADVISED AGAINST:
RECOMMENDED USES: GASOLINE FUEL ADDITIVE
USES ADVISED AGAINST: NOT FOR USE IN DIESEL FUELS
MANUFACTURER/SUPPLIER DETAILS:
BERRYMAN PRODUCTS, INC.
3800 E RANDOL MILL RD
ARLINGTON, TX 76011
(800) 433-1704 (USA/CANADA)
(817) 640-2376 (INTERNATIONAL)
WWW.BERRYMANPRODUCTS.COM
EMERGENCY 24 - HOUR TELEPHONE NUMBER(S) - INFOTRAC, INC.:
(800) 535-5053 (USA/CANADA)
(352) 323-3500 (INTERNATIONAL)
| SECTION 2 - HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE (29 CFR 1910.1200):
PHYSICAL HAZARDS:
FLAMMABLE LIQUID: CATEGORY 2
HEALTH HAZARDS:
ACUTE ORAL: CATEGORY 4
ACUTE DERMAL: CATEGORY 4
ACUTE INHALATION: CATEGORY 3
SKIN IRRITANT: CATEGORY 2
EYE IRRITANT: CATEGORY 2A
DEVELOPMENTAL: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
CATEGORY 3 (NARCOTIC EFFECTS)
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
CATEGORY 2 (BLOOD/BLOOD SYSTEM, CENTRAL NERVOUS SYSTEM)
ASPIRATION HAZARD: CATEGORY 1
ENVIRONMENTAL HAZARD - ACUTE: CATEGORY 2
ALLOCATION OF LABEL ELEMENTS:
CHEMICAL IDENTITY: BERRYMAN B-12 CHEMTOOL FUEL SYSTEM CLEANER
PICTOGRAMS:
FLAME
SKULLS AND CROSSBONES
HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H302: HARMFUL IF SWALLOWED.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H312: HARMFUL IN CONTACT WITH SKIN.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H321:
SPECIFIC TREATMENT (SEE SUPPLEMENTAL FIRST AID INSTRUCTIONS THIS
LABEL/DOCUMENT).
H331: TOXIC IF INHALED.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H361D: SUSPECTED OF DAMAGING THE UNBORN CHILD.
H370: CAUSES DAMAGE TO ORGANS.
H373:
MAY CAUSE DAMAGE TO BLOOD/BLOOD SYSTEM AND CENTRAL NERVOUS SYSTEM THROUGH
PROLONGED OR REPEATED EXPOSURE.
H401: TOXIC TO AQUATIC LIFE.
PREVENTION PRECAUTIONARY STATEMENTS:
P101: KEEP OUT OF REACH OF CHILDREN.
P102: READ LABEL BEFORE USE.
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, AND HOT SURFACES. NO SMOKING.
P235: KEEP COOL.
P240:
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. SPECIAL PRECAUTIONS MAY BE
NECESSARY FOR NON-CONDUCTIVE CONTAINERS.
P241: USE EXPLOSION-PROOF ELECTRICAL, VENTILATION, AND LIGHTING EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS, SUCH AS BRASS OR BRONZE.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P260: DO NOT BREATHE FUMES, GAS, MIST, VAPOR, OR SPRAY.
P264: WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280:
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE OR FACE PROTECTION.
RESPONSE PRECAUTIONARY STATEMENTS:
P311: CALL POISON CONTROL CENTER, HOSPITAL EMERGENCY ROOM, OR DOCTOR.
P321:
SPECIFIC TREATMENT AVAILABLE IN THIS DOCUMENT IN "SECTION 4 - FIRST AID
MEASURES. "
P330: RINSE MOUTH.
P331: DO NOT INDUCE VOMITING.
P301/P310:
IF SWALLOWED:
IMMEDIATELY CALL POISON CONTROL CENTER, HOSPITAL EMERGENCY ROOM, OR DOCTOR.
P303/P361/P353:
IF ON SKIN (OR HAIR):
IMMEDIATELY TAKE OFF ALL CONTAMINATED CLOTHING. RINSE SKIN WITH SOAP AND
WATER OR SHOWER.
P304/P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305/P351/P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P308/P313: IF EXPOSED OR CONCERNED, GET MEDICAL ADVICE/ATTENTION.
P332/P313: IF SKIN IRRITATION OCCURS, GET MEDICAL ADVICE/ATTENTION.
P337/P313: IF EYE IRRITATION PERSISTS, GET MEDICAL ADVICE/ATTENTION.
P361/364:
IMMEDIATELY TAKE OFF ALL CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE.
P362/364: TAKE OFF CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE.
P370/P378:
IN CASE OF FIRE, USE WATER FOG, DRY CHEMICAL, ALCOHOL-RESISTANT FOAM, OR
CARBON DIOXIDE TO EXTINGUISH.
STORAGE PRECAUTIONARY STATEMENTS:
P405: STORE LOCKED-UP.
P403/P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
DISPOSAL PRECAUTIONARY STATEMENTS:
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL,
AND INTERNATIONAL REGULATIONS, AS APPLICABLE.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN
INGREDIENTS OF UNKNOWN ACUTE TOXICITY: NONE
| SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENT CAS RN WEIGHT
TOLUENE 108-88-3 40-50%
ACETONE 67-64-1 20-25%
METHANOL 67-56-1 20-25%
METHYL ETHYL KETONE 78-93-3 1-5%
2-BUTOXYETHANOL 111-76-2 1-5%
2-PROPANOL 67-63-0 1-5%
| SECTION 4 - FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
INGESTION:
IMMEDIATELY CALL POISON CONTROL CENTER, HOSPITAL EMERGENCY ROOM, OR DOCTOR.
DO NOT INDUCE VOMITING. RINSE MOUTH. DRINK 1-2 GLASSES OF MILK OR WATER.
EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IF EYE IRRITATION PERSISTS, GET
MEDICAL ADVICE/ATTENTION.
SKIN CONTACT:
IMMEDIATELY TAKE OFF ALL CONTAMINATED CLOTHING. RINSE SKIN WITH SOAP AND
WATER OR SHOWER.
INHALATION:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. IF
EXPERIENCING RESPIRATORY SYMPTOMS, CALL POISON CONTROL CENTER, HOSPITAL
EMERGENCY ROOM, OR DOCTOR.
MOST IMPORTANT SYMPTOMS AND EFFECTS:
ACUTE/IMMEDIATE:
HEADACHE AND LIGHTHEADEDNESS; NARCOTIC EFFECTS, INCLUDING DIZZINESS,
DROWSINESS, AND LOSS OF COORDINATION; NAUSEA AND VOMITING
DELAYED: DRYING, CRACKING, OR DEFATTING OF THE SKIN
INDICATIONS OF NEED FOR IMMEDIATE MEDICAL ATTENTION AND SPECIFIC TREATMENT
REQUIRED:
INDICATIONS OF NEED FOR IMMEDIATE MEDICAL ATTENTION:
IN THE EVENT OF SHORTNESS OF BREATH, DIFFICULTY BREATHING, OR SPONTANEOUS
VOMITING, SEVERE HEADACHE, OR LOSS OF CONSCIOUSNESS, SEEK IMMEDIATE MEDICAL
ATTENTION.
SPECIFIC TREATMENT AND NOTES TO PHYSICIAN:
IF PERFORMING LAVAGE, ENDOTRACHEAL AND/OR ESOPHAGEAL CONTROL IS
RECOMMENDED. IF SPONTANEOUS VOMITING OCCURS, KEEP HEAD BELOW HIPS TO AVOID
ASPIRATION.
| SECTION 5 - FIREFIGHTING MEASURES | |
FIRE EXTINGUISHING MEDIA:
SUPPORT FOR COMBUSTION: PRODUCT SUPPORTS COMBUSTION.
SUITABLE EXTINGUISHING MEDIA:
WATER FOG, DRY CHEMICAL, ALCOHOL-RESISTANT FOAM, OR CARBON DIOXIDE
UNSUITABLE EXTINGUISHING MEDIA:
WATER JET/SPRAY (MAY CAUSE PRODUCT TO FLOAT TO SURFACE AND REIGNITE)
SPECIAL HAZARDS/CONSIDERATIONS:
COMBUSTION PRODUCTS:
COMBUSTION IN THE PRESENCE OF AIR MAY YIELD HYDROCARBONS, CARBON MONOXIDE,
CARBON DIOXIDE, AND ORGANIC OXYGENATES.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SPECIAL PROTECTIVE EQUIPMENT:
FIREFIGHTERS SHOULD EMPLOY SCBA AND FULL PROTECTIVE GEAR, INCLUDING SHIELD,
AS PRODUCT IS COMPRISED OF LOW-BOILING SOLVENTS AND MAY VENT, RUPTURE, OR
EXPLODE VIOLENTLY AT ELEVATED TEMPERATURES.
PRECAUTIONS AND PROCEDURES:
HIGHLY FLAMMABLE LIQUID AND VAPOR. VAPORS HEAVIER THAN AIR. REMOVE PRODUCT
FROM AREA IF SAFE TO DO SO. USE WATER SPRAY TO COOL NEARBY CONTAINERS.
ADDITIONAL INFORMATION:
NATIONAL FIRE PROTECTION ASSOCIATION NFPA):
FLAMMABLE LIQUID CLASSIFICATION IB
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PERSONAL AND ENVIRONMENTAL PRECAUTIONS:
PERSONAL PRECAUTIONS:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, AND HOT SURFACES. NO SMOKING.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. GROUND/BOND CONTAINER
AND RECEIVING EQUIPMENT. SPECIAL PRECAUTIONS MAY BE NECESSARY FOR
NON-CONDUCTIVE CONTAINERS. USE EXPLOSION-PROOF ELECTRICAL, VENTILATION,
AND LIGHTING EQUIPMENT. USE ONLY NON-SPARKING TOOLS, SUCH AS BRASS OR
BRONZE. DO NOT BREATHE FUMES, GAS, MIST, VAPOR, OR SPRAY. WASH THOROUGHLY
WITH SOAP AND WATER AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING
THIS PRODUCT. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. WEAR
PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE OR FACE PROTECTION.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. PREVENT CONTAMINATION OF GROUND WATER.
MATERIALS AND METHODS FOR CONTAINMENT:
SMALL SPILLS:
USE SOCKS/ABSORBENT MINI-BOOMS OR OTHER INERT BARRIER IF NECESSARY TO
CONTAIN SMALL SPILLS.
LARGE SPILLS:
USE LARGE SOCKS/ABSORBENT BOOMS OR OTHER INERT BARRIER TO FORM DAM/DIKE IN
ORDER TO CONTAIN LARGE SPILLS AND PREVENT FURTHER LOSS.
MATERIALS AND METHODS FOR CLEANUP:
SMALL SPILLS:
REMOVE SOURCE FROM AREA IF SAFE TO DO SO. USE GRANULAR SORBENT, GEL
SORBENT, VERMICULITE, CAT LITTER, DIRT/EARTH, PADS/ROLLS, OR PILLOWS TO
ABSORB SPILLED MATERIAL. REMEDIATE AREA AS NECESSARY.
LARGE SPILLS:
KEEP UPWIND FROM SPILL. REMOVE SOURCE FROM AREA IF SAFE TO DO SO. USE
EXPLOSION-PROOF TRANSFER EQUIPMENT TO RECOVER SPILLED MATERIAL. USE
GRANULAR SORBENT, GEL SORBENT, VERMICULITE, CAT LITTER, DIRT/EARTH,
PADS/ROLLS, OR PILLOWS TO ABSORB RESIDUAL MATERIAL. REMEDIATE AREA AS
NECESSARY.
| SECTION 7 - HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PERSONAL PRECAUTIONS:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
DO NOT BREATHE FUMES, GAS, MIST, VAPOR, OR SPRAY. USE ONLY OUTDOORS OR IN A
WELL-VENTILATED AREA. WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE
OR FACE PROTECTION. WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING. DO
NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
ENVIRONMENTAL PRECAUTIONS:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, AND HOT SURFACES. NO SMOKING.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. GROUND/BOND CONTAINER
AND RECEIVING EQUIPMENT. SPECIAL PRECAUTIONS MAY BE NECESSARY FOR
NON-CONDUCTIVE CONTAINERS. USE EXPLOSION-PROOF ELECTRICAL, VENTILATION, AND
LIGHTING EQUIPMENT. USE ONLY NON-SPARKING TOOLS, SUCH AS BRASS OR BRONZE.
AVOID RELEASE TO THE ENVIRONMENT.
CONDITIONS AND CONSIDERATIONS FOR SAFE STORAGE:
HIGHLY FLAMMABLE LIQUID AND VAPOR. STORE IN A WELL-VENTILATED PLACE. KEEP
CONTAINER TIGHTLY CLOSED. KEEP COOL. KEEP OUT OF REACH OF CHILDREN. STORE
LOCKED-UP AND IN ACCORDANCE WITH NFPA FLAMMABLE LIQUID CLASSIFICATION IB
RECOMMENDATIONS.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
COMPONENT CAS RN OSHA PEL ACGIH TLV
TOLUENE 108-88-3 200 PPM 20 PPM
ACETONE 67-64-1 1000 PPM 500 PPM
METHANOL 67-56-1 200 PPM 200 PPM
METHYL ETHYL KETONE 78-93-3 200 PPM 200 PPM
2-BUTOXYETHANOL 111-76-2 50 PPM 20 PPM
2-PROPANOL 67-63-0 500 PPM 400 PPM
EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
IF PRACTICAL, USE OUTSIDE WITH ADEQUATE VENTILATION TO MINIMIZE EXPOSURE.
PPE OVERVIEW:
HAND PROTECTION:
USE OF CHEMICAL-RESISTANT GLOVES (EVAL, NEOPRENE, NITRILE/BUNA-N, PVC, OR
VITON) IS RECOMMENDED.
EYE PROTECTION:
USE OF SAFETY GLASSES WITH WRAP-AROUND LENS OR GOGGLES IS RECOMMENDED.
RESPIRATORY PROTECTION:
IF NECESSARY, USE RESPIRATORY PROTECTION SUFFICIENT TO REDUCE EXPOSURE TO
PERMISSIBLE LIMITS.
ADDITIONAL PROTECTION:
FOR INDUSTRIAL SETTINGS, ACCESS TO A CHEMICAL SAFETY SHOWER WITH EYE WASH
STATION IS STRONGLY RECOMMENDED.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: CLEAR, COLORLESS
ODOR: AROMATIC (TOLUENE)
ODOR THRESHOLD: 0.5 PPM
PH: NOT RELEVANT
FREEZING POINT: < -107 DEG. F
BOILING RANGE: 133 - 343 DEG. F
FLASH POINT AND METHOD: <20 DEG. F BY CLOSED-CUP TESTER
EXPLOSION LIMITS IN AIR: 2.5 - 16.2% BY VOLUME (COMPOSITE)
EVAPORATION RATE: 2.7 (N-BUTYL ACETATE=1.0)
VAPOR PRESSURE, AS SUPPLIED: 81 MM OF Hg AT 68 DEG. F
VAPOR DENSITY: >1.0
SPECIFIC GRAVITY: 0.831 AT 68 DEG. F
DENSITY: 6.92 LB/GAL AT 68 DEG. F
WATER SOLUBILITY: PRACTICALLY INSOLUBLE
N-OCTANOL/WATER PARTITION COEFFICIENT (LOG POW): 1.0 (COMPOSITE)
VISCOSITY: 0.5 CST AT 68 DEG. F
VOLATILITY: 100% BY WEIGHT
AUTO-IGNITION TEMPERATURE: 930 DEG. F (COMPOSITE)
DECOMPOSITION TEMPERATURE: UNKNOWN
| SECTION 10 - STABILITY AND REACTIVITY | |
CHEMICAL STABILITY UNDER NORMAL CONDITIONS OF USE:
CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS OF USE.
CONDITIONS AFFORDING INSTABILITY: NONE KNOWN
REACTIVITY: NOT EXPECTED
POSSIBILITY OF HAZARDOUS REACTIONS: NONE KNOWN
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, AND HOT SURFACES. NO SMOKING. IF
PRACTICAL, AVOID TEMPERATURES EXCEEDING FLASH POINT.
INCOMPATIBLE MATERIALS: STRONG ACIDS; OXIDIZERS; REDUCING AGENTS
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
LIKELY ROUTES OF EXPOSURE:
INGESTION, SKIN CONTACT, EYE CONTACT, INHALATION
SYMPTOMS RELATED TO PHYSICAL, CHEMICAL, AND TOXICOLOGICAL CHARACTERISTICS:
INGESTION:
LARGE QUANTITY:
GASTROINTESTINAL DISTURBANCES, INCLUDING UPSET STOMACH, CRAMPING, NAUSEA,
VOMITING, AND DIARRHEA
SMALL QUANTITY/INCIDENTAL CONTACT:
VIRTUALLY NONTOXIC AFTER SINGLE INGESTION OF SMALL QUANTITY
SKIN CONTACT: MODERATE IRRITATION
EYE CONTACT: BLURRED VISION, MODERATE EYE IRRITATION
INHALATION:
HEADACHE, LIGHTHEADEDNESS; NARCOTIC EFFECTS, INCLUDING DIZZINESS,
DROWSINESS, AND LOSS OF COORDINATION; NAUSEA AND VOMITING
IMMEDIATE, DELAYED, AND CHRONIC EFFECTS:
SHORT-TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
INGESTION:
DRYING, BURNING, OR IRRITATION OF THE MOUTH AND THROAT, GASTROINTESTINAL
DISTURBANCES, NAUSEA AND VOMITING, AND BLINDNESS
SKIN CONTACT: DRYING OF THE SKIN
EYE CONTACT: BLURRED VISION, TEMPORARY CORNEAL DAMAGE
INHALATION:
SHORTNESS OF BREATH OR DIFFICULTY BREATHING, HEADACHE, DIZZINESS, NAUSEA
AND VOMITING, DROWSINESS, FATIGUE, LOSS OF CONSCIOUSNESS, AND DEATH
POTENTIAL DELAYED EFFECTS:
INGESTION: ASPIRATION PNEUMONITIS, CYANOSIS, COMA, AND DEATH
SKIN CONTACT:
DEFATTING OF THE SKIN, DRYING AND CRACKING OF THE SKIN, AGGRAVATION OF
PRE-EXISTING SKIN CONDITIONS
EYE CONTACT: TEMPORARY CORNEAL DAMAGE
INHALATION: FATIGUE
LONG-TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NONE KNOWN
POTENTIAL DELAYED EFFECTS: BRAIN/CENTRAL NERVOUS SYSTEM (CNS) EFFECTS
POTENTIAL CHRONIC HEALTH EFFECTS:
CARCINOGENICITY:
INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) MONOGRAPHS:
ALL COMPONENTS "GROUP 3 - NOT CLASSIFIABLE AS TO HUMAN CARCINOGENICITY" OR
NOT LISTED
NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS: NOT LISTED
OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION (OSHA): NOT LISTED
MUTAGENICITY / GENETIC TOXICITY:
NOT SUSPECTED OF BEING A HUMAN MUTAGEN / GENETIC TOXICANT
TERATOGENICITY: NOT SUSPECTED OF BEING A HUMAN TERATOGEN
DEVELOPMENTAL EFFECTS:
POSSIBLE DEVELOPMENTAL TOXICANT (TOLUENE AND METHANOL)
FERTILITY EFFECTS:
NOT SUSPECTED OF BEING A REPRODUCTIVE/FERTILITY TOXICANT
EFFECTS ON LACTATION: NOT SUSPECTED OF AFFECTING LACTATION
SPECIFIC TARGET ORGAN TOXICITY (STOT):
SINGLE EXPOSURE: CENTRAL NERVOUS SYSTEM (NARCOTIC EFFECTS)
REPEATED EXPOSURE: BRAIN/CENTRAL NERVOUS SYSTEM (CNS) EFFECTS
NUMERICAL MEASURES OF ACUTE TOXICITY:
ORAL (HUMAN):
ATE: 350 MG/KG (ADDITIVITY METHOD)
DERMAL (RABBIT):
LD50: 1100 MG/KG (DERIVED)
INHALATION (RAT):
LC50: 9.2 MG/L (DERIVED)
ADDITIONAL TOXICOLOGICAL INFORMATION:
SKIN IRRITATION/CORROSION (RABBIT): SKIN IRRITANT
SERIOUS EYE DAMAGE/IRRITATION (RABBIT): EYE IRRITANT
RESPIRATORY SENSITIZATION: DOES NOT CAUSE RESPIRATORY SENSITIZATION
SKIN SENSITIZATION: DOES NOT CAUSE SKIN SENSITIZATION
ASPIRATION HAZARD: KNOWN ASPIRATION HAZARD
| SECTION 12 - ECOLOGICAL INFORMATION | |
GENERAL ECOLOGICAL ASSESSMENT/OVERVIEW:
HARMFUL TO ANIMAL LIFE. TOXIC TO AQUATIC LIFE. VERY MOBILE IN SOILS WHICH
MAY LEAD TO CONTAMINATION OF GROUNDWATER.
AQUATIC TOXICITY:
VERTEBRATES (FISH):
ACUTE TOXICITY:
LC50: 73 MG/L (DERIVED)
CHRONIC TOXICITY:
NOEC: 2.9 MG/L (DERIVED)
INVERTEBRATES (WATER FLEA):
ACUTE TOXICITY:
LC50: 7.2 MG/L (DERIVED)
CHRONIC TOXICITY:
NOEC: 1.2 MG/L (DERIVED)
AQUATIC PLANTS (FRESHWATER ALGAE):
ACUTE TOXICITY:
EC50: 4.7 MG/L (DERIVED)
CHRONIC TOXICITY:
NOEC: NOT AVAILABLE
TERRESTRIAL TOXICITY:
INVERTEBRATE (EARTHWORM):
LC50: NOT AVAILABLE
PERSISTENCE AND DEGRADABILITY:
PERSISTENCE: NOT EXPECTED TO BE PERSISTENT
DEGRADABILITY: RAPIDLY DEGRADABLE
BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATION POTENTIAL ASSESSMENT: DOES NOT BIOACCUMULATE
BIOACCUMULATION FACTOR: 90 (TOLUENE)
MOBILITY IN SOILS:
MOBILITY IN SOILS ASSESSMENT:
VERY MOBILE IN SOILS - MAY CONTAMINATE GROUNDWATER
SOIL ORGANIC CARBON/WATER PARTITION COEFFICIENT (LOG KOC):
1.9 (COMPOSITE)
RESULTS OF PBT AND VPVB ASSESSMENT:
NOT A PERSISTENT, BIOACCUMULATIVE, TOXIC CHEMICAL (PBT);
NOT VERY PERSISTENT AND VERY BIOACCUMULATIVE (VPVB)
OTHER ADVERSE EFFECTS: NONE KNOWN
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
GENERAL ASSESSMENT/OVERVIEW:
DISPOSE OF WASTE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS. HARMFUL TO
ANIMAL LIFE-DO NOT POUR ON GROUND. TOXIC TO AQUATIC LIFE-DO NOT POUR INTO
WATERWAYS. HIGHLY FLAMMABLE LIQUID AND VAPOR AND AGGRESSIVE SOLVENTS, WHICH
MAY DISSOLVE PVC PIPES AND FITTINGS-DO NOT POUR DOWN DRAIN.
RCRA HAZARDOUS WASTE CODE(S) (40 CFR 261.20-33):
BASED ON THIS MATERIAL AS-SUPPLIED, USED OR UNWANTED PRODUCT MAY BE SUBJECT
TO RCRA REGULATIONS AND CLASSIFIED AS F003 - SPENT NON-HALOGENATED SOLVENT
MIXTURE CONTAINING ACETONE, METHANOL, AND/OR XYLENE
| SECTION 14 - TRANSPORTATION INFORMATION | |
TRANSPORTATION BY GROUND - US DEPARTMENT OF TRANSPORTATION:
SHIPPING DESCRIPTION:
UN1993, FLAMMABLE LIQUIDS, N.O.S., (CONTAINS TOLUENE, METHANOL, ACETONE),
3, PG II
EXEMPTION ELIGIBILITY:
WHEN SHIPPED BY GROUND, PART #0116 MAY BE ELIGIBLE FOR A "LIMITED QUANTITY"
EXCEPTION PER SUBSECTION 49 CFR 173.150.
TRANSPORTATION BY AIR - ICAO/IATA:
SHIPPING DESCRIPTION:
UN1993, FLAMMABLE LIQUIDS, N.O.S., (CONTAINS TOLUENE, METHANOL, ACETONE),
3, PG II
EXEMPTION ELIGIBILITY:
WHEN SHIPPED BY AIR, PART #0116 MAY BE ELIGIBLE FOR A "LIMITED QUANTITY"
EXCEPTION.
TRANSPORTATION BY WATER - IMO/IMDG:
SHIPPING DESCRIPTION:
UN1993, FLAMMABLE LIQUIDS, N.O.S., (CONTAINS TOLUENE, METHANOL, ACETONE),
3, PG II
EXEMPTION ELIGIBILITY:
WHEN SHIPPED BY WATER, PART #0116 MAY BE ELIGIBLE FOR A "LIMITED QUANTITY"
EXCEPTION.
| SECTION 15 - REGULATORY INFORMATION | |
SAFETY, HEALTH, AND ENVIRONMENTAL REGULATIONS/LEGISLATION:
UNITED STATES - SELECT FEDERAL REGULATIONS:
ENVIRONMENTAL PROTECTION AGENCY (EPA):
TOXIC SUBSTANCES CONTROL ACT (TSCA) (15 USC 2601, ET SEQ.)
ALL CHEMICALS KNOWN TO BE PRESENT IN THIS PRODUCT ARE EITHER LISTED ON THE
TSCA INVENTORY OR ARE NOT REQUIRED TO BE.
SARA TITLE III (42 USC 9601, ET SEQ.):
SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355): NONE
SECTION 304 - EMERGENCY RELEASE NOTIFICATION (40 CFR 302.4):
TOLUENE, ACETONE, METHANOL, AND METHYL ETHYL KETONE
SECTION 311/312 - HAZARD CATEGORIZATION (40 CFR 370.40):
ACUTE TOXICITY, CHRONIC TOXICITY, FIRE HAZARD, SUDDEN RELEASE OF PRESSURE
SECTION 313 - TOXIC CHEMICALS (40 CFR 372.65):
TOLUENE, METHANOL, AND 2-BUTOXYETHANOL ("CERTAIN GLYCOL ETHERS")
CLEAN AIR ACT (42 USC 7401,,, ET SEQ.):
SECTION 112 - HAZARDOUS AIR POLLUTANTS:
TOLUENE, METHANOL, METHYL ETHYL KETONE
REGULATION OF FUELS AND FUEL ADDITIVES:
THIS PRODUCT COMPLIES WITH THE REQUIREMENTS OF SUBSECTION 40 CFR 80 AND
MUST BE USED IN A MANNER CONSISTENT WITH THE DIRECTIONS ON THE PRODUCT
LABEL.
OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION (OSHA):
HAZARD COMMUNICATION STANDARD:
THIS SAFETY DATA SHEET (SDS) IS PROVIDED FOR COMPLIANCE WITH APPLICABLE
REGULATIONS OF THE HAZARD COMMUNICATION STANDARD OF 2012 (HCS/HAZCOM 2012)
FOUND IN SUBSECTION 29 CFR 1910.1200. FEDERAL LAW REQUIRES PERSONS
RECEIVING THIS DOCUMENT TO STUDY IT CAREFULLY, BECOME AWARE OF THE HAZARDS
OF THIS PRODUCT, AND NOTIFY ALL EMPLOYEES, VISITORS, AGENTS, AND
CONTRACTORS OF THE INFORMATION CONTAINED HEREIN.
CONSUMER PRODUCT SAFETY COMMISSION:
FEDERAL HAZARDOUS SUBSTANCES ACT:
THIS PRODUCT IS REGULATED UNDER THE FEDERAL HAZARDOUS SUBSTANCES ACT, IS
SUBJECT TO THE LABELING REQUIREMENTS OF 16 CFR 1500, AND MUST INCLUDE AT
MINIMUM THE FOLLOWING CAUTIONARY STATEMENTS: DANGER
POISON:
EXTREMELY FLAMMABLE. MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED. VAPOR
HARMFUL. EYE AND SKIN IRRITANT. KEEP OUT OF THE REACH OF CHILDREN.
UNITED STATES - SELECT REGIONAL CONSIDERATIONS:
OZONE TRANSPORT COMMISSION (OTC) - MODEL RULE VOC LIMIT AND CATEGORY:
N/A: NOT REGULATED AS A FUEL ADDITIVE
LAKE MICHIGAN AIR DIRECTORS CONSORTIUM (LADCO) - MODEL RULE VOC LIMIT AND
CATEGORY:
N/A: NOT REGULATED AS A FUEL ADDITIVE
UNITED STATES - SELECT STATE REGULATIONS:
CALIFORNIA:
OFFICE OF ENVIRONMENTAL HEALTH HAZARD ASSESSMENT (OEHHA):
PROPOSITION 65 - SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986
("PROP 65"):
THIS PRODUCT IS SUBJECT TO THE LABELING REQUIREMENTS OF PROPOSITION 65 -
SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 AND MUST BEAR THE
CAUTIONARY STATEMENT:
WARNING!
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
AIR RESOURCES BOARD (ARB/CARB):
REGULATION FOR REDUCING EMISSIONS FROM CONSUMER PRODUCTS - VOC LIMIT AND
CATEGORY:
N/A: NOT REGULATED AS A FUEL ADDITIVE
MASSACHUSETTS:
"RIGHT-TO-KNOW" LEGISLATION - SUBSTANCE LIST (105 CMR 670.000):
TOLUENE, ACETONE, METHANOL, METHYL ETHYL KETONE (MEK), 2-BUTOXYETHANOL,
2-PROPANOL
NEW JERSEY:
"RIGHT-TO-KNOW" LEGISLATION - HAZARDOUS SUBSTANCE LIST (34:5A-1, ET SEQ.):
TOLUENE, ACETONE, METHYL ALCOHOL, ISOPROPYL ALCOHOL, METHYL ETHYL KETONE,
2-BUTOXYETHANOL
PENNSYLVANIA:
"RIGHT-TO-KNOW" LEGISLATION - HAZARDOUS SUBSTANCE LIST (CHAPTER 323):
METHYLBENZENE, 2-PROPANONE, METHYL ALCOHOL, 2-BUTANONE, 2-BUTOXYETHANOL,
2-PROPANOL
INTERNATIONAL - SELECT REGULATIONS:
CANADA:
ENVIRONMENT CANADA - DOMESTIC SUBSTANCES LIST (DSL):
ALL CHEMICALS KNOWN TO BE PRESENT IN THIS PRODUCT ARE LISTED ON THE DSL.
CHINA:
MINISTRY OF ENVIRONMENTAL PROTECTION - INVENTORY OF EXISTING CHEMICAL
SUBSTANCES PRODUCED OR IMPORTED IN CHINA (IECSC):
ALL CHEMICALS KNOWN TO BE PRESENT IN THIS PRODUCT ARE LISTED ON THE IECSC.
EUROPEAN UNION:
EUROPEAN CHEMICAL AGENCY - EUROPEAN INVENTORY OF EXISTING CHEMICAL
SUBSTANCES (EINECS):
ALL CHEMICALS KNOWN TO BE PRESENT IN THIS PRODUCT ARE LISTED ON THE EINECS.
CHEMICAL SAFETY ASSESSMENT:
HAS NOT BEEN CONDUCTED ON PRODUCT, AS-SUPPLIED
| SECTION 16 - OTHER INFORMATION | |
HAZARDOUS MATERIALS INFORMATION SYSTEM (HMIS):
HEALTH 3*
FLAMMABILITY 3
REACTIVITY 0
PROTECTIVE EQUIPMENT B
HAZARD INDEX:
LEAST: 0
SLIGHT: 1
MODERATE: 2
HIGH: 3
EXTREME: 4
INDEX OF ABBREVIATIONS:
ACGIH - AMERICAN COUNCIL OF GOVERNMENTAL AND INDUSTRIAL HYGIENISTS
ATE - ACUTE TOXICITY ESTIMATE
CAS RN - CHEMICAL ABSTRACTS SERVICE REGISTRY NUMBER
EC50 - MEDIAN EFFECTIVE CONCENTRATION
IATA - INTERNATIONAL AIR TRANSPORT ASSOCIATION
ICAO - INTERNATIONAL CIVIL AVIATION ORGANIZATION
IMDG - INTERNATIONAL MARITIME DANGEROUS GOODS
IMO - INTERNATIONAL MARITIME ORGANIZATION
LC50 - MEDIAN LETHAL CONCENTRATION
LD50 - MEDIAN LETHAL DOSE
N/A - NOT APPLICABLE
NE - NOT ESTABLISHED
NOEC - NO OBSERVABLE EXPOSURE CONCENTRATION
PEL - PERMISSIBLE EXPOSURE LIMIT (AS REQUIRED BY OSHA)
TLV - THRESHOLD LIMIT VALUE (AS RECOMMENDED BY ACGIH)
VOC - VOLATILE ORGANIC COMPOUND
RELEVANT DATES AND APPLICABILITY:
DATE OF ISSUANCE: JULY 8, 2016
DATE OF PREVIOUS REVISION: JUNE 8, 2015
PRIMARY REVISION CHANGE(S):
"SECTION 11 - TOXICOLOGICAL INFORMATION"; "SECTION 14 - TRANSPORTATION
INFORMATION"
DOCUMENT APPLICABILITY:
THIS SAFETY DATA SHEET APPLIES TO PART NUMBERS 0101, 0105, 0115, 0116, AND
0155 MANUFACTURED ON OR AFTER JANUARY 1, 2015.
DOCUMENT AUTHOR: DAN NOWLAN
LEGAL DISCLAIMER:
THE INFORMATION CONTAINED IN THIS DOCUMENT IS, TO THE BEST OF BERRYMAN
PRODUCTS, INC.'S KNOWLEDGE, COMPLETE AND ACCURATE BUT IS NOT WARRANTED. ALL
MATERIALS MAY PRESENT UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. IT
IS THE RESPONSIBILITY OF THE USER TO EVALUATE THE INFORMATION IN A PRUDENT
MANNER AND TO USE IT IN A MANNER CONSISTENT WITH ITS INTENDED PURPOSE.
RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION
IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES.
BERRYMAN PRODUCTS, INC. - PART #S 000 101, 0105, 0115, 0116, AND 0155