| Common Name: | POLYGUARD 2-CYCLE OIL |
| Manufacturer: | ZECOL PRODUCTS |
| SDS Revision Date: | 5/10/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 52HG09 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ZECOL(TM)
EFFECTIVE DATE: MAY 10, 2016
PRODUCT #(S): 75224
SAFETY DATA SHEET
FOR EMERGENCY CALL:
CHEM-TEL: (800) 255-3924 24 HOUR ASSISTANCE
| 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: POLYGUARD 2-CYCLE OIL
CAS NUMBER: 64742-47-6 / 64742-65-0
RECOMMENDED USES: AUTOMOTIVE LUBRICANT
COMPANY IDENTIFICATION:
MANUFACTURER'S NAME: ZECOL PRODUCTS COMPANY
ADDRESS:
4635 WILLOW DRIVE
MEDINA, MN 55340
TELEPHONE:
GENERAL INFORMATION: (763) 478-3438
| 2. HAZARDS IDENTIFICATION | |
HAZARD CLASSES:
FLAMMABLE LIQUID CATEGORY 4
SKIN CORROSION/IRRITATION CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY SINGLE EXPOSURE CATEGORY 3
AQUATIC TOXICITY-LONG TERM CATEGORY 2
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
H227: COMBUSTIBLE LIQUID.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H315: CAUSES SKIN IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H411: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
P101:
IF MEDICAL ADVICE IS NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
P102: KEEP OUT OF REACH OF CHILDREN,
P103: READ LABEL BEFORE USE.
P210: KEEP AWAY FROM FLAMES/HOT SURFACES - NO SMOKING.
P261: AVOID BREATHING VAPORS.
P264: WASH THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280: WEAR PROTECTIVE GLOVES / PROTECTIVE CLOTHING / EYE PROTECTION..
P303 + P361 + P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P332 + P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P304 + P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P308 + P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P312: CALL POISON CENTER OR DOCTOR IF YOU FEEL UNWELL.
P370 + P378:
IN CASE OF FIRE:
USE DRY CHEMICAL, CO2, ALCOHOL-RESISTANT FOAM, AND WATER SPRAY FOR
EXTINCTION. .
P391: COLLECT SPILLAGE.
P403 + P233:
STORE IN WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P501:
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO A SPECIALIZED WASTE DISPOSAL PLANT IN
ACCORDANCE WITH LOCAL/REGIONAL REGULATIONS
HAZARD PICTOGRAMS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
ENVIRONMENT
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS TYPICAL WEIGHT CAS NUMBER
PERCENTAGE
HYDROTREATED DISTILLATE, LIGHT ...C9-C16 15% 64742-47-6
LUBRICANT BASE OIL 80% 64742-65-0
ADDITIVES 5% PROPRIETARY
| 4. FIRST AID | |
EYES:
IF IRRITATION OR REDNESS DEVELOPS, MOVE VICTIM AWAY FROM EXPOSURE AND INTO
FRESH AIR. FLUSH EYES WITH CLEAN WATER. IF SYMPTOMS PERSIST, SEEK MEDICAL
ATTENTION.
SKIN:
REMOVE CONTAMINATED SHOES AND CLOTHING AND FLUSH AFFECTED AREA(S) WITH
LARGE AMOUNTS OF WATER. IF SKIN SURFACE IS DAMAGED, APPLY A CLEAN
DRESSING AND SEEK MEDICAL ATTENTION. IF SKIN SURFACE IS NOT DAMAGED,
CLEANSE AFFECTED AREA(S) THOROUGHLY BY WASHING WITH MILD SOAP AND WATER
OR A WATERLESS HAND CLEANER. IF IRRITATION OR REDNESS DEVELOPS, SEEK
MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
INHALATION:
IF RESPIRATORY SYMPTOMS DEVELOP, MOVE VICTIM AWAY FROM SOURCE OF EXPOSURE
AND INTO FRESH AIR IN A POSITION COMFORTABLE FOR BREATHING. IF BREATHING
DIFFICULTIES DEVELOP, OXYGEN SHOULD BE ADMINISTERED BY QUALIFIED
PERSONNEL. SEEK IMMEDIATE MEDICAL ATTENTION.
INGESTION:
FIRST AID IS NOT NORMALLY REQUIRED, HOWEVER, IF SWALLOWED AND SYMPTOMS
DEVELOP, SEEK MEDICAL ATTENTION.
NOTES TO PHYSICIANS:
ACUTE ASPIRATIONS OF LARGE AMOUNTS OF OIL-LADEN MATERIAL MAY PRODUCE A
SERIOUS ASPIRATION PNEUMONIA. PATIENTS WHO ASPIRATE THESE OILS SHOULD BE
FOLLOWED FOR THE DEVELOPMENT OF LONG-TERM SEQUELAE. INHALATION EXPOSURE
TO OIL MISTS BELOW CURRENT WORKPLACE EXPOSURE LIMITS IS UNLIKELY TO
CAUSE PULMONARY ABNORMALITIES.
MEDICAL CONDITIONS:
CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE INCLUDE SKIN DISORDERS.
| 5. FIRE FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL, CO2, WATER SPRAY OR ALCOHOL-RESISTANT FOAM. . WATER SPRAY IS
RECOMMENDED TO COOL OR PROTECT EXPOSED MATERIALS OR STRUCTURES. WATER MAY
BE INEFFECTIVE FOR EXTINGUISHMENT, UNLESS USED UNDER FAVORABLE CONDITIONS
BY EXPERIENCED FIRE FIGHTERS. CARBON DIOXIDE CAN DISPLACE OXYGEN. USE
CAUTION WHEN APPLYING CARBON DIOXIDE IN CONFINED SPACES.
SPECIFIC HAZARDS:
THIS MATERIAL IS COMBUSTIBLE AND CAN BE IGNITED BY HEAT, SPARKS, FLAMES OR
OTHER SOURCES OF IGNITION (E.G., STATIC ELECTRICITY, PILOT LIGHTS OR
MECHANICAL/ELECTRICAL EQUIPMENT). FLAME IS INVISIBLE IN DAYLIGHT. MAY
CREATE VAPOR/AIR EXPLOSION HAZARD INDOORS, IN CONFINED SPACES, OUTDOORS OR
IN SEWERS. IF CONTAINER IS NOT PROPERLY COOLED, IT CAN RUPTURE IN THE HEAT
OF A FIRE. VAPORS ARE HEAVIER THAN AREA AND CAN ACCUMULATE IN LOW AREAS.
HAZARDOUS COMBUSTION PRODUCTS:
COMBUSTION MAY YIELD SMOKE, CARBON MONOXIDE AND OTHER PRODUCTS OF
INCOMPLETE COMBUSTION.
SPECIAL FIREFIGHTING PROCEDURES:
FOR FIRES BEYOND THE INITIAL STAGE, EMERGENCY RESPONDERS IN THE IMMEDIATE
HAZARD AREA SHOULD WEAR BUNKER GEAR. WHEN THE POTENTIAL CHEMICAL HAZARD IS
UNKNOWN, IN ENCLOSED OR CONFINED SPACES, OR WHEN EXPLICITLY REQUIRED BY
DOT, A SELF-CONTAINED BREATHING APPARATUS SHOULD BE WORN. IN ADDITION,
WEAR OTHER APPROPRIATE PROTECTIVE EQUIPMENT AS CONDITIONS WARRANT (SEE
SECTION 8). ISOLATE IMMEDIATE HAZARD AREA AND KEEP UNAUTHORIZED PERSONNEL
OUT. STOP SPILL/RELEASE IF IT CAN BE DONE WITH MINIMAL RISK. MOVE
UNDAMAGED CONTAINERS FROM IMMEDIATE HAZARD AREA IF IT CAN BE DONE WITH
MINIMAL RISK. WATER SPRAY MAY BE USEFUL IN MINIMIZING OR DISPERSING
VAPORS AND TO PROTECT PERSONNEL. COOL EQUIPMENT EXPOSED TO FIRE WITH
WATER, IF IT CAN BE DONE WITH MINIMAL RISK. AVOID SPREADING BURNING
LIQUID WITH WATER USED FOR COOLING PURPOSES.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
COMBUSTIBLE. SPILLING OF LIQUID PRODUCT MAY CREATE A FIRE HAZARD AND MAY
FORM AN EXPLOSIVE ATMOSPHERE. KEEP ALL SOURCES OF IGNITION AWAY FROM
SPILL/RELEASE IF SAFE TO DO SO. STAY UPWIND AND AWAY FROM SPILL/RELEASE.
FOR LARGE SPILLS, NOTIFY PEOPLE DOWN-WIND OF SPILL/RELEASE, ISOLATE
IMMEDIATE HAZARD AREA AND KEEP UNAUTHORIZED PERSONNEL OUT. WEAR
APPROPRIATE PROTECTIVE EQUIPMENT INCLUDING RESPIRATORY PROTECTION AS
CONDITIONS WARRANT (SEE SECTION 8). SEE SECTIONS 2 AND 7 FOR ADDITIONAL
INFORMATION ON HAZARDS AND PRECAUTIONARY MEASURES.
ENVIRONMENTAL PRECAUTIONS:
STOP SPILL/RELEASE IF IT CAN BE DONE WITH MINIMAL RISK. PREVENT SPILLED
MATERIAL FROM ENTERING SEWERS, STORM DRAINS, OTHER UNAUTHORIZED TREATMENT
DRAINAGE SYSTEMS, AND NATURAL WATERWAYS. USE FOAM ON SPILLS TO MINIMIZE
VAPORS. USE WATER SPARINGLY TO MINIMIZE ENVIRONMENTAL CONTAMINATION AND
REDUCE DISPOSAL REQUIREMENTS. IF SPILL OCCURS ON WATER, NOTIFY APPROPRIATE
AUTHORITIES. SPILLS INTO OR UPON NAVIGABLE WATERS, THE CONTIGUOUS ZONE, OR
ADJOINING SHORELINES THAT CAUSE A SHEEN OR DISCOLORATION ON THE SURFACE
WATER, MAY REQUIRE NOTIFICATION OF THE NATIONAL RESPONSE CENTER (PHONE
NUMBER 800-424-8802).
METHODS FOR CONTAINMENT AND CLEAN-UP:
NOTIFY RELEVANT AUTHORITIES IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
IMMEDIATE CLEANUP OF ANY SPILL IS RECOMMENDED. DIKE FAR AHEAD OF SPILL FOR
LATER RECOVERY OR DISPOSAL. ABSORB SPILL WITH INERT MATERIAL SUCH AS SAND,
EARTH OR OTHER NONCOMBUSTIBLE MATERIAL, AND PLACE IN SUITABLE CONTAINER
FOR DISPOSAL. IF SPILLED ON WATER REMOVE WITH APPROPRIATE METHODS (E.G.,
SKIMMING, BOOMS OR ABSORBENTS). IN CASE OF SOIL CONTAMINATION, REMOVE
CONTAMINATED SOIL FOR REMEDIATION OR DISPOSAL, IN ACCORDANCE WITH LOCAL
REGULATIONS.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
KEEP AWAY FROM IGNITION SOURCES SUCH AS HEAT/SPARKS/OPEN FLAMES - NO
SMOKING. TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
NON-SPARKING TOOLS SHOULD BE USED. WEAR PROTECTIVE GLOVES/CLOTHING AND
EYE/FACE PROTECTION. WASH THOROUGHLY AFTER HANDLING. USE GOOD PERSONAL
HYGIENE PRACTICES AND WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT
(SEE SECTION 8).
COMBUSTIBLE. OPEN CONTAINER SLOWLY TO RELIEVE ANY PRESSURE. DO NOT ENTER
CONFINED SPACES SUCH AS TANKS OR PITS WITHOUT FOLLOWING PROPER ENTRY
PROCEDURES SUCH AS ASTM D-4276 AND 29CFR 1910.146. DO NOT WEAR
CONTAMINATED CLOTHING OR SHOES. KEEP CONTAMINATED CLOTHING AWAY FROM
SOURCES OF IGNITION SUCH AS SPARKS OR OPEN FLAMES. USE GOOD PERSONAL
HYGIENE PRACTICE.
CONDITIONS FOR SAFE STORAGE:
KEEP CONTAINER(S) TIGHTLY CLOSED. USE AND STORE THIS MATERIAL IN COOL,
DRY, WELL-VENTILATED AREAS AWAY FROM HEAT AND ALL SOURCES OF IGNITION.
POST AREA "NO SMOKING OR OPEN FLAME." KEEP AWAY FROM ANY INCOMPATIBLE
MATERIAL (SEE SECTION 10). PROTECT CONTAINER(S) AGAINST PHYSICAL DAMAGE.
OUTDOOR OR DETACHED STORAGE IS PREFERRED. INDOOR STORAGE SHOULD MEET
OSHA STANDARDS AND APPROPRIATE FIRE CODES.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE GUIDELINES:
COMPONENT ACGIH TLV ACGIH STEL OSHA PEL OSHA STEL
HYDROTREATED 200 PPM NONE NONE NONE
DISTILLATE,
LIGHT
LUBRICANT BASE 5MG/M3 10 MG/M3 5MG/M3
OIL (AS OIL
MIST, IF
GENERATED)
ENGINEERING CONTROLS:
IF CURRENT VENTILATION PRACTICES ARE NOT ADEQUATE TO MAINTAIN AIRBORNE
CONCENTRATIONS BELOW THE ESTABLISHED EXPOSURE LIMITS, ADDITIONAL
VENTILATION OR EXHAUST SYSTEMS MAY BE REQUIRED.
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
THE USE OF EYE PROTECTION THAT MEETS OR EXCEEDS ANSI Z.87.1 IS RECOMMENDED
TO PROTECT AGAINST POTENTIAL EYE CONTACT, IRRITATION OR INJURY. DEPENDING
ON CONDITIONS OF USE, A FACE SHIELD MAY BE NECESSARY.
SKIN:
THE USE OF GLOVES IMPERVIOUS TO THE SPECIFIC MATERIAL HANDLED IS ADVISED
TO PREVENT SKIN CONTACT. USERS SHOULD CHECK WITH MANUFACTURERS TO CONFIRM
THE BREAKTHROUGH PERFORMANCE OF THEIR PRODUCTS. DEPENDING ON EXPOSURE AND
USE CONDITIONS, ADDITIONAL PROTECTION MAY BE NECESSARY TO PREVENT SKIN
CONTACT INCLUDING USE OF ITEMS SUCH AS CHEMICAL RESISTANT BOOTS, APRONS,
ARM COVERS, HOODS, COVERALLS, OR ENCAPSULATED SUITS.
SUGGESTED PROTECTIVE MATERIALS: VITON(R*) AND NITRILE RUBBERS.
RESPIRATORY PROTECTION:
WHERE THERE IS POTENTIAL FOR AIRBORNE EXPOSURE ABOVE THE EXPOSURE LIMITS,
A NIOSH APPROVED AIR PURIFYING RESPIRATOR WITH AN ORGANIC VAPOR CARTRIDGE
MAY BE USED.
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND
ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS
WARRANT A RESPIRATOR'S USE. AIRPURIFYING RESPIRATORS PROVIDE LIMITED
PROTECTION AND CANNOT BE USED IN ATMOSPHERES THAT EXCEED THE MAXIMUM USE
CONCENTRATION AS DIRECTED BY REGULATION OR THE MANUFACTURER'S
INSTRUCTIONS, IN OXYGEN DEFICIENT (LESS THAN 19.5% OXYGEN) SITUATIONS OR
UNDER CONDITIONS THAT ARE IMMEDIATELY DANGEROUS TO LIFE AND HEALTH (IDLH).
USE A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS POTENTIAL FOR
UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE UNKNOWN, OR ANY OTHER
CIRCUMSTANCES WHERE AIR-PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
OTHER PROTECTIVE EQUIPMENT:
EYE WASH AND QUICK-DRENCH SHOWER FACILITIES SHOULD BE AVAILABLE IN THE
WORK AREA. THOROUGHLY CLEAN SHOES AND WASH CONTAMINATED CLOTHING BEFORE
REUSE.
SUGGESTIONS PROVIDED IN THIS SECTION FOR EXPOSURE CONTROL AND SPECIFIC
TYPES OF PROTECTIVE EQUIPMENT ARE BASED ON READILY AVAILABLE INFORMATION.
USERS SHOULD CONSULT WITH THE SPECIFIC MANUFACTURER TO CONFIRM THE
PERFORMANCE OF THEIR PROTECTIVE EQUIPMENT. SPECIFIC SITUATIONS MAY
REQUIRE CONSULTATION WITH INDUSTRIAL HYGIENE, SAFETY, OR ENGINEERING
PROFESSIONALS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
ODOR: PETROLEUM ODOR
ODOR THRESHOLD: NO DATA
PH: NOT APPLICABLE
MELTING/FREEZING POINT: NOT AVAILABLE
BOILING RANGE: >315.6 DEG. C / 600 DEG. F
FLASH POINT: >70 DEG. C / 158 DEG. F
AUTO-IGNITION TEMPERATURE: NO DATA
EVAPORATION RATE (BUTYL ACETATE = 1): >1
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
EXPLOSIVE LIMITS (APPROX..):
LOWER: NO DATA
UPPER: NO DATA
VAPOR PRESSURE: <0.01 MMHg @ 37.8 DEG. C / 100 DEG. F
VAPOR DENSITY (AIR = 1): >1
SPECIFIC GRAVITY (H20 = 1): 0.88-0.90 @ 15.6DEG. C / 60 DEG. F
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT: NO DATA
DECOMPOSITION TEMPERATURE: NO DATA
VISCOSITY: 8.0-10.2 CST @ 100 DEG. C / 212 DEG. F
| 10. STABILITY AND REACTIVITY | |
STABILITY (THERMAL, LIGHT, ETC.):
STABLE UNDER NORMAL CONDITIONS OF STORAGE AND HANDLING.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SEE SECTIONS 5 AND 7).
INCOMPATIBILITY (MATERIALS TO AVOID):
AVOID CONTACT WITH STRONG OXIDIZERS SUCH AS LIQUID CHLORINE AND OXYGEN.
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION MAY RELEASE CARBON MONOXIDE AND CARBON DIOXIDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT(ESTIMATED SPECIES DOSE
BASED ON SIMILAR
MATERIAL)
HYDROTREATED DISTILLATE, LD50 ORAL RAT >/=5 G/KG
LIGHT AND LUBRICANT BASE
OIL LD50 DERMAL RABBIT >2 G/KG
LC50 INHALATION RAT >5.2 MG/L
(VAPOR)
SKIN CORROSION/IRRITATION:
CAUSES SKIN IRRITATION. REPEATED EXPOSURE MAY CAUSE DRYNESS OR CRACKING.
SERIOUS EYE DAMAGE/IRRITATION: CAUSES MILD IRRITATION.
SIGNS AND SYMPTOMS:
HIGH CONCENTRATIONS CAN CAUSE MINOR RESPIRATORY IRRITATION, HEADACHE,
DROWSINESS, DIZZINESS, LOSS OF COORDINATION, DISORIENTATION AND FATIGUE.
INGESTION CAN CAUSE IRRITATION OF THE DIGESTIVE TRACT, NAUSEA, VOMITING
AND DIARRHEA.
SKIN SENSITIZATION: NONE REPORTED
RESPIRATORY SENSITIZATION: NO DATA FOUND.
GERM CELL MUTAGENICITY:
THERE IS INSUFFICIENT INFORMATION AVAILABLE TO CONCLUDE THAT THIS MATERIAL
IS MUTAGENIC.
CARCINOGENICITY:
REPEATED SKIN APPLICATION OF VARIOUS PETROLEUM NAPHTHAS IN MICE FOR TWO
YEARS RESULTED IN AN INCREASED INCIDENCE OF SKIN TUMORS BUT ONLY IN THE
PRESENCE OF SEVERE SKIN IRRITATION. FOLLOW-UP MECHANISTIC STUDIES SUGGEST
THAT THE OCCURRENCE OF THESE TUMORS MAY BE THE CONSEQUENCE OF PROMOTIONAL
PROCESSES AND NOT RELEVANT TO HUMAN RISK ASSESSMENT.
THIS MATERIAL IS NOT IDENTIFIED AS A CARCINOGEN BY NTP, IAR OR OSHA.
REPRODUCTIVE TOXICITY:
THERE IS INSUFFICIENT INFORMATION AVAILABLE TO CONCLUDE THAT THIS MATERIAL
IS A REPRODUCTIVE TOXICANT.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
MAY CAUSE DROWSINESS AND DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NINETY DAYS STUDY OF VARIOUS PETROLEUM NAPHTHAS DID NOT PRODUCE
SIGNIFICANT TARGET ORGAN TOXICITY IN LABORATORY ANIMALS. NEPHROPATHY IN
MALE RATS, CHARACTERIZED BY THE ACCUMULATION OF ALPHA-2-U-GLOBULIN IN
EPITHELIAL CELLS OF THE PROXIMAL TUBULES WAS OBSERVED, HOWEVER FOLLOW-UP
STUDIES SUGGEST THAT THESE CHANGES ARE UNIQUE TO THE MALE RAT.
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
| 12. ECOLOGICAL INFORMATION | |
TOXICITY:
ACUTE AQUATIC TOXICITY STUDIES ON SAMPLES OF NAPHTHA STREAMS/KEROSENES
SHOW ACUTE TOXICITY VALUES GREATER THAN 1 MG/L. THESE TESTS WERE CARRIED
OUT ON WATER ACCOMMODATED FRACTIONS, IN CLOSED SYSTEMS TO PREVENT
EVAPORATIVE LOSS. RESULTS ARE CONSISTENT WITH THE PREDICTED AQUATIC
TOXICITY OF THESE SUBSTANCES BASED ON THEIR HYDROCARBON COMPOSITION.
THESE SUBSTANCES SHOULD BE REGARDED AS TOXIC TO AQUATIC ORGANISMS, WITH
THE POTENTIAL TO CAUSE LONG TERM ADVERSE EFFECTS IN THE AQUATIC
ENVIRONMENT. CLASSIFICATION: H411; CHRONIC CATEGORY 2
PERSISTENCE AND DEGRADABILITY:
THE HYDROCARBONS IN THIS MATERIAL ARE NOT READILY BIODEGRADABLE BUT ARE
REGARDED AS INHERENTLY BIODEGRADABLE SINCE THEIR HYDROCARBON COMPONENTS
CAN BE DEGRADED BY MICROORGANISM.
BIOACCUMULATIVE POTENTIAL:
LOG KOW VALUES MEASURED RANGE FROM 2 TO 6 AND THEREFORE ARE REGARDED AS
HAVING THE POTENTIAL TO BIOCCUMULATE. IN PRACTICE, METABOLIC PROCESSES OR
PHYSICAL PROPERTIES MAY PREVENT THIS EFFECT OR LIMIT BIOAVAILABILITY.
MOBILITY IN SOIL:
ON RELEASE TO WATER, HYDROCARBONS WILL FLOAT ON THE SURFACE AND SINCE THEY
ARE SPARINGLY SOLUBLE, THE ONLY SIGNIFICANT LOSS IS VOLATILIZATION TO AIR.
IN AIR, THESE HYDROCABONS ARE PHOTODEGRADED BY REACTION WITH HYDROXYL
RADICALS WITH HALF-LIVES VARYING FROM 6.5 DAYS FOR BENZENE TO 0.5 DAYS
FOR N-DODECANE.
OTHER ADVERSE EFFECTS: NONE KNOWN
| 13. DISPOSAL CONSIDERATIONS | |
THE GENERATOR OF A WASTE IS ALWAYS RESPONSIBLE FOR MAKING PROPER HAZARDOUS
WASTE DETERMINATIONS AND NEEDS TO CONSIDER STATE AND LOCAL REQUIREMENTS IN
ADDITION TO FEDERAL REGULATIONS.
THIS MATERIAL, IF DISCARDED AS PRODUCED, WOULD NOT BE A FEDERALLY
REGULATED RCRA "LISTED" HAZARDOUS WASTE. HOWEVER, IT WOULD LIKELY BE
IDENTIFIED AS A FEDERALLY REGULATED RCRA HAZARDOUS WASTE FOR THE FOLLOWING
CHARACTERISTIC OF IGNITABILITY (D001). SEE SECTIONS 7 AND 8 FOR
INFORMATION ON HANDLING, STORAGE AND PERSONAL PROTECTION AND SECTION 9 FOR
PHYSICAL/CHEMICAL PROPERTIES. IT IS POSSIBLE THAT THE MATERIAL AS PRODUCED
CONTAINS CONSTITUENTS WHICH ARE NOT REQUIRED TO BE LISTED IN THE MSDS BUT
COULD AFFECT THE HAZARDOUS WASTE DETERMINATION. ADDITIONALLY, USE WHICH
RESULTS IN CHEMICAL OR PHYSICAL CHANGE OF THIS MATERIAL COULD SUBJECT IT
TO REGULATION AS A HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
DOT/TDG PROPER SHIPPING NAME: NOT REGULATED
DOT/TDG IDENTIFICATION NUMBER: NOT REGULATED
DOT/TDG HAZARD CLASS: NOT REGULATED
DOT/TDG PACKING GROUP: NOT REGULATED
ERG GUIDE NUMBER: NOT REGULATED
MARINE POLLUTANT: NO
| 15. REGULATORY INFORMATION | |
TSCA:
THIS MATERIAL AND/OR ITS COMPONENTS ARE LISTED ON THE TSCA INVENTORY OR
NOT REGULATED BY TSCA.
DSL:
THIS MATERIAL AND/OR ITS COMPONENTS ARE LISTED ON THE DSL INVENTORY OR
ARE EXEMPT FROM DSL LISTING REQUIREMENTS.
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION):
THIS MATERIAL IS CONSIDERED TO BE HAZARDOUS AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD.
THIS MATERIAL HAS NOT BEEN IDENTIFIED AS A CARCINOGEN BY NTP, IARC OR OSHA
HOWEVER, COMPONENTS ARE LISTED BY IARC (SEE SECTION 11).
CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES AND TPQ (IN
POUNDS):
THIS MATERIAL DOES NOT CONTAIN CHEMICALS SUBJECT TO THE REPORTING
REQUIREMENTS OF SARA 302 AND 40 CFR 355 APPENDIX A AND B.
EPA (CERCLA) REPORTABLE QUANTITY (IN POUNDS):
EPAS PETROLEUM EXCLUSION APPLIES TO THIS MATERIAL (CERCLA 101(14)).
CERCLA/SARA - SECTIONS 311/312 (TITLE III HAZARD CATEGORIES):
ACUTE: YES
CHRONIC: NO
FIRE: YES
REACTIVITY: NO
CERCLA/SARA - SECTION 313 AND 40 CFR 372:
THIS MATERIAL DOES NOT CONTAIN CHEMICALS SUBJECT TO THE REPORTING
REQUIREMENTS OF SARA 313 AND SARA TITLE III AND 40 CFR.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986
(PROPOSITION 65):
THIS MATERIAL DOES NOT CONTAIN DETECTABLE CHEMICALS KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE CANCER AND/OR REPRODUCTIVE TOXICITY.
CANADA:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA
OF THE CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE SDS CONTAINS ALL
THE INFORMATION REQUIRED BY THE REGULATIONS.
WHMIS HAZARD CLASS: B2, D2B
| 16. OTHER INFORMATION | |
ISSUE DATE: MAY 10, 2016
PREVIOUS ISSUE DATE: JUNE 1, 2015
CHANGE: MINOR WORDING CHANGES
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES:
THE INFORMATION IN THIS DOCUMENT IS BELIEVED TO BE CORRECT AS OF THE DATE
ISSUED. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY
PARTICULAR PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED
REGARDING THE ACCURACY OR COMPLETENESS OF THIS INFORMATION, THE RESULTS TO
BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF
THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. THIS INFORMATION AND
PRODUCT ARE FURNISHED ON THE CONDITION THAT THE PERSON RECEIVING THEM
SHALL MAKE HIS OWN DETERMINATION AS TO THE SUITABILITY OF THE PRODUCT FOR
THIS PARTICULAR PURPOSE AND ON THE CONDITION THAT HE ASSUMES THE RISK OF
HIS USE THEREOF.