| Common Name: | MS-242L, QUIK-FREEZE |
| Manufacturer: | MILLER-STEPHENSON CHEMICAL |
| SDS Revision Date: | 2/1/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 52HN13 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MS(TM)
MILLER-STEPHENSON
SDS
SAFETY DATA SHEET
| 1. CHEMICAL PRODUCT/COMPANY IDENTIFICATION |  |
NAME: MS-242L QUIK-FREEZE
PRODUCT USE: FREEZE SPRAY
MANUFACTURER/DISTRIBUTOR:
MILLER-STEPHENSON CHEMICAL
55 BACKUS AVE.
DANBURY, CONN. 06810
USA
(203) 743-4447
EMERGENCY PHONE NUMBER: (800) 424-9300
| 2. HAZARDS IDENTIFICATION | |
PHYSICAL HAZARD: GASES UNDER PRESSURE - LIQUEFIED GAS
LABEL ELEMENTS: GAS CYLINDER
SINGLE WORD: WARNING
HAZARD STATEMENTS:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
PRECAUTIONARY STATEMENTS:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
PROTECT FROM SUNLIGHT.
STORE IN A WELL-VENTILATED PLACE.
| 3. INGREDIENTS | |
MATERIAL (S) CAS NO. APPROXIMATE %
TRANS-1,3,3,3-TETRAFLUOROPROP-1-ENE 29118-24-9 100
| 4. FIRST AID MEASURES | |
INHALATION:
IMMEDIATELY REMOVE PATIENT TO FRESH AIR. KEEP PERSON CALM. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT GIVE
OXYGEN, PROVIDED OPERATOR IS PRESENT. GET MEDICAL ATTENTION IMMEDIATELY.
EYE:
REMOVE CONTACT LENSES FROM EYES. IMMEDIATELY FLUSH WITH LARGE AMOUNTS
OF WATER, LIFTING EYELIDS UNTIL NO EVIDENCE OF THE CHEMICAL REMAINS.
GET MEDICAL ATTENTION.
SKIN:
REMOVE CONTAMINATED CLOTHING AND SHOES. FLUSH PROMPTLY WITH PLENTY
OF WATER. GET MEDICAL ATTENTION IF NECESSARY. TREAT FOR FROSTBITE
IF NECESSARY BY GENTLY WARMING AFFECTED AREA.
ORAL:
IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE. DO NOT INDUCE VOMITING
WITHOUT MEDICAL ADVICE. IMMEDIATELY RINSE MOUTH AND DRINK PLENTY OF WATER.
CALL A PHYSICIAN IMMEDIATELY.
NOTES TO PHYSICIAN:
TREATMENT OF EXPOSURE SHOULD BE DIRECTED AT THE CONTROL OF SYMPTOMS AND THE
CLINICAL CONDITION OF THE PATIENT.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: USE THE MEDIA APPROPRIATE FOR SURROUNDING MATERIALS.
FIRE AND EXPLOSION: AEROSOL CANS MAY RUPTURE UNDER FIRE CONDITIONS.
HAZARDOUS DECOMPOSITION PRODUCTS:
IN CASE OF FIRE, FORMING TOXIC GASES ALONG WITH HYDROGEN FLUORIDE.
SPECIFIC HAZARDS:
AVOID CONTACT WITH FLAME AND HOT SURFACES BECAUSE BURST AND TOXIC
DECOMPOSITION PRODUCTS MAY FORM. VAPORS ARE HEAVIER THAN AIR AND CAN CAUSE
SUFFOCATION BY REDUCING OXYGEN AVAILABLE FOR BREATHING.
PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
REMOVE ALL IGNITION SOURCES. AEROSOLS CAN EXPLODE WHEN HEATED. WARN
PERSONNEL OF THIS HAZARD AND UNPROTECTED PERSONNEL SHOULD NOT RETURN UNTIL
SAFE TO DO SO. VENTILATE AREA. AVOID INHALATION OF VAPORS. USE AN APPROVED
RESPIRATOR IF NEEDED TO KEEP EXPOSURE LEVELS BELOW THE ACCEPTED LEVEL.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE, IF SAFE TO DO SO. THIS PRODUCT
EVAPORATES READILY.
METHODS FOR CLEAN UP:
EXTINGUISH ALL IGNITION SOURCES. AVOID SPARKS, FLAMES, AND HEAT. VENTILATE.
| 7. HANDLING AND STORAGE | |
HANDLING:
AVOID INHALATION OF VAPORS. USE IN A WELL-VENTILATED AREA TO KEEP EMPLOYEE
EXPOSURE BELOW RECOMMENDED LIMITS. USE AN APPROVED RESPIRATOR IF NECESSARY.
VAPORS ARE HEAVIER THAN AIR AND ACCUMULATE IN LOW AREAS. AVOID CONTACT WITH
NAKED FLAMES AND HOT SURFACES AS TOXIC DECOMPOSITION PRODUCTS CAN BE
FORMED. DO NOT GET IN EYES OR ON SKIN. DO NOT PUNCTURE OR BURN.
STORAGE CONDITIONS:
STORE IN A CLEAN, DRY PLACE, NOT NEAR SOURCES OF HEAT, IN DIRECT SUNLIGHT
OR WHERE TEMPERATURES EXCEED 122 DEG. F/50 DEG. C.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE LIMITS WEEL (AIHA) HONEYWELL
TRANS-1,3,3,3-TETRAFLUOROPROP-1-ENE 800 PPM (TWA) 800 PPM (TWA)
* LIMIT ESTABLISHED BY HONEYWELL INTERNATIONAL INC.
ENGINEERING MEASURES:
USE ADEQUATE VENTILATION. VAPORS ARE HEAVIER THAN AIR AND IF WORKING IN
CONFINED OR POORLY VENTILATED AREAS, PROPER RESPIRATORY PROTECTION MUST
BE USED TO PREVENT EXCEEDING THE EXPOSURE LIMIT.
RESPIRATORY PROTECTION:
MECHANICAL VENTILATION, OR RESPIRATORY PROTECTION WITH AIR SUPPLY SHOULD BE
USED IN LOW OR ENCLOSED AREAS. IN POORLY VENTILATED AREAS, OR IF A LARGE
RELEASE OCCURS, USE AN APPROVED SELF-CONTAINED BREATHING APPARATUS (SCBA).
EYE PROTECTION: WEAR APPROVED SAFETY GOGGLES.
SKIN PROTECTION:
AVOID CONTACT WITH SKIN (DANGER OF FROSTBITE). WEAR COLD INSULTING
GLOVES/FACE SHIELD/EYE PROTECTION, IF NECESSARY. USE PROTECTIVE GLOVES
WHEN PROLONGED OR FREQUENTLY REPEATED CONTACT OCCURS.
HYGIENE MEASURES:
GOOD PERSONAL HYGIENE PRACTICES ARE ALWAYS ADVISABLE. DO NOT EAT, DRINK,
OR SMOKE WHEN USING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING POINT: -2 DEG. F/-19 DEG. C
PERCENT VOLATILE BY VOLUME: 100%
DENSITY: 1.17 G/CC AT 70 DEG. F/21.1 DEG. C
VAPOR PRESSURE:
60.8 PSI AT 68 DEG. F/20 DEG. C
159.5 PSI AT 129.9 DEG. F/54.4 DEG. C
VAPOR DENSITY (AIR=1): 4
SOLUBILITY IN H2O: 0.373 G/L
PH INFORMATION: NEUTRAL
APPEARANCE: CLEAR
FORM: LIQUEFIED GAS
ODOR: FAINT ETHEREAL
COLOR: COLORLESS
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS.
MATERIAL AND CONDITIONS TO AVOID:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG.
C. AVOID OPEN FLAMES AND HOT SURFACES AS CORROSIVE AND TOXIC DECOMPOSITION
PRODUCTS CAN BE FORMED. ALKALI METALS, POWDERED METALS.
DECOMPOSITION:
THIS MATERIAL CAN BE DECOMPOSED BY HIGH TEMPERATURES (OPEN FLAMES, GLOWING
METAL SURFACES, ETC.) FORMING CORROSIVE AND TOXIC PRODUCTS, INCLUDING
FLUORIDE, FLUOROCARBONS, AND HYDROGEN FLUORIDE.
POLYMERIZATION: WILL NOT OCCUR.
| 11. TOXICOLOGICAL INFORMATION | |
INHALATION:
4 HOUR, LC50 RAT: >207000 PPM
SKIN IRRITATION: NO SKIN IRRITATION IN RABBITS.
METHOD: OECD TEST GUIDELINE 404
METHOD: OECD TEST GUIDELINE 404
SENSITIZATION: CARDIAC SENSITIZATION
SPECIES: DOGS
RESULT: DID NOT CAUSE SENSITIZATION ON LABORATORY ANIMALS.
REPEATED DOSE TOXICITY:
13 WEEKS, INHALATION, RAT: CAUSES MILD EFFECTS ON THE HEART. NOEL 5,000 PPM
GENOTOXICITY IN VITRO: IN VITRO TESTS DID NOT SHOW MUTAGENIC EFFECTS.
TERATOGENICITY: DID NOT SHOW TERATOGENIC EFFECTS IN ANIMAL EXPERIMENTS.
OTHER HEALTH EFFECTS:
THIS SUBSTANCE HAS NO EVIDENCE OF CARCINOGENIC PROPERTIES.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY EFFECTS:
96 HOUR NOEC - CYPRINUS CARPIO (CARP): >117 MG/L
48 HOUR EC50 - DAPHNIA MAGNA (WATER FLEA): >160 MG/L
TOXICITY TO ALGAE:
GROWTH INHIBITION:
NOEC: >170 MG/L
EXPOSURE TIME: 72 H
BIODEGRADABILITY:
AEROBIC: NOT READILY BIODEGRADABLE
| 13. DISPOSAL CONSIDERATIONS | |
COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS. DO NOT PUNCTURE OR
INCINERATE CANS.
| 14. TRANSPORT INFORMATION | |
U.S. DOT:
PROPER SHIPPING NAME: CONSUMER COMMODITY
HAZARD CLASS: ORM-D
IDENTIFICATION NO. NONE
PACKING GROUP: NONE
IATA:
PROPER SHIPPING NAME:
LIQUEFIED GAS, N.O.S. (TRANS-1,3,3,3-TETRAFLUOROPROP-1-ENE)
HAZARD CLASS: 2.2
IDENTIFICATION NO.: UN 3163
LABEL: 2.2
PACKING INSTRUCTION (CARGO AIRCRAFT): 200
PACKING INSTRUCTION (PASSENGER AIRCRAFT): 200
IMDG:
PROPER SHIPPING NAME:
LIQUEFIED GAS, N.O.S. (TRANS-1,3,3,3-TETRAFLUOROPROP-1-ENE)
HAZARD CLASS: 2.2
IDENTIFICATION NO.: UN 3163
LABEL: 2.2
EMS NUMBER: F-C, S-V
MARINE POLLUTANT: NO
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
TSCA: ALL INGREDIENTS ARE LISTED IN TSCA INVENTORY.
SARA 302:
NO INGREDIENTS IN THIS MATERIAL ARE SUBJECT TO THE REPORTING REQUIREMENTS
OF SARA TITLE III, SECTION 302.
SARA 313 EMISSION REPORTING:
NONE OF THE INGREDIENTS EXCEED THE THRESHOLD REPORTING LEVELS ESTABLISHED
BY SARA TITLE III, SECTION 313.
SARA 311/312 HAZARDS:
ACUTE HEALTH HAZARD & SUDDEN RELEASE OF PRESSURE HAZARD
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65 CARCINOGENS AND REPRODUCTIVE TOXINS:
NONE OF THE INGREDIENTS ARE LISTED.
INTERNATIONAL INVENTORIES:
CANADA: DSL
ALL INGREDIENTS ARE LISTED
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 1
FLAMMABILITY 0
REACTIVITY 0
PERSONAL PROTECTIVE RATING TO BE SUPPLIED BY USER DEPENDING ON THE
CONDITIONS.
FOR INDUSTRIAL USE ONLY
REVISION DATE: FEBRUARY 2016
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT. FINAL DETERMINATION OF SUITABILITY
OF ANY MATERIAL IS THE SOLE RESPONSIBILITY OF THE USER.