| Common Name: | MS-555, DPMS-C0716A, HEAVY DUTY SOLVENT & FLUX REMOVER |
| Manufacturer: | MILLER-STEPHENSON CHEMICAL |
| SDS Revision Date: | 9/1/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 52HN16 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MS(TM)
MILLER-STEPHENSON
SDS
SAFETY DATA SHEET
| 1. CHEMICAL PRODUCT/COMPANY IDENTIFICATION |  |
NAME: MS-555 DPMS-C0716A HEAVY DUTY SOLVENT & FLUX REMOVER
PRODUCT USE: SOLVENT CLEANING & FLUX REMOVAL FOR ELECTRONIC ASSEMBLIES.
MANUFACTURER/DISTRIBUTOR:
MILLER-STEPHENSON CHEMICAL
55 BACKUS AVE.
DANBURY, CONN. 06810
USA
(203) 743-4447
EMERGENCY PHONE NUMBER: (800) 424-9300
| 2. HAZARDS IDENTIFICATION | |
HAZARD CLASSIFICATION:
FLAMMABLE AEROSOL: CATEGORY 2
ACUTE TOXICITY (ORAL): CATEGORY 4
ACUTE TOXICITY (INHALATION: VAPOR): CATEGORY 4
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1
AQUATIC CHRONIC: CATEGORY 3
LABEL ELEMENTS:
SIGNAL WORD: DANGER
PICTOGRAMS:
HEALTH HAZARD
FLAME
EXCLAMATION MARK
HAZARD STATEMENTS:
FLAMMABLE AEROSOL
HARMFUL IF SWALLOWED OR IF INHALED
CAUSES DAMAGE TO ORGANS (OPTIC NERVE)
HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
AVOID BREATHING MIST/VAPORS/SPRAY.
WASH SKIN THOROUGHLY AFTER HANDLING.
DO NOT EAT, DRINK, OR SMOKE WHEN USING THIS PRODUCT.
USE IN A WELL-VENTILATED AREA.
AVOID RELEASE TO THE ENVIRONMENT.
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/ PHYSICIAN IF YOU FEEL UNWELL.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
IF EXPOSED: CALL A POISON CENTER/DOCTOR
CALL A POISON CENTER OR DOCTOR/PHYSICIAN, IF YOU FEEL UNWELL.
IN CASE OF FIRE:
USE DRY SAND, DRY CHEMICAL OR ALCOHOL-RESISTANT FOAM FOR EXTINCTION.
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG.
C/122 DEG. F.
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL,
AND INTERNATIONAL REGULATIONS.
OTHER HAZARDS:
EXPOSURE MAY AGGRAVATE THOSE WITH PRE-EXISTING EYE, SKIN, OR RESPIRATORY
CONDITIONS. IN HIGH CONCENTRATIONS ASPHYXIATION MAY OCCUR. VICTIM MAY NOT
BE AWARE OF ASPHYXIATION. THIS MATERIAL MAY MAKE THE HEART MORE SUSCEPTIBLE
TO ARRHYTHMIAS. CATECHOLAMINES SUCH AS ADRENALINE, AND OTHER COMPOUNDS
HAVING SIMILAR EFFECTS, SHOULD BE RESERVED FOR EMERGENCIES AND THEN USED.
EFFECTS OF BREATHING HIGH CONCENTRATIONS OF VAPOR MAY INCLUDE: TIREDNESS OR
DROWSINESS. CONVULSIONS. MAY CAUSE CARDIAC ARRHYTHMIA. PROLONGED SKIN
CONTACT MAY DEFAT THE SKIN AND PRODUCE DERMATITIS.
| 3. INGREDIENTS | |
MATERIAL (S) CAS NO. APPROXIMATE %
1,1,1,2,2,3,4,5,5,5-DECAFLUOROPENTANE 138495-42-8 22 - 26
(HFC-43-10MEE)
TRANS,1.2-DICHLOROETHYLENE 156-60-5 65 - 70
METHANOL 67-56-1 4 - 6
CARBON DIOXIDE 124-38-9 3 - 4
| 4. FIRST AID MEASURES | |
INHALATION:
REMOVE PATIENT TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION.
GIVE OXYGEN AS NECESSARY, IF QUALIFIED PERSONNEL IS AVAILABLE. GET MEDICAL
ATTENTION IF NECESSARY.
EYE:
FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES, LIFTING EYELIDS
UNTIL NO EVIDENCE OF THE CHEMICAL REMAINS. GET MEDICAL ATTENTION. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE TO RINSE.
SKIN:
WASH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. WASH CONTAMINATED
CLOTHING BEFORE USE. GET MEDICAL ATTENTION IF NECESSARY.
ORAL:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
HARMFUL IF INHALED. MAY CAUSE RESPIRATORY IRRITATION. HARMFUL IS SWALLOWED.
CAUSES DAMAGE TO ORGANS (OPTIC NERVE). SWALLOWING A SMALL QUANTITY OF THIS
MATERIAL WILL RESULT IN A SERIOUS HEALTH HAZARD. THIS MATERIAL CONTAINS
METHANOL, WHICH, WHEN INGESTED, MAY CAUSE ACIDOSIS AND OCULAR TOXICITY
RANGING FROM DIMINISHED VISUAL CAPACITY TO COMPLETE BLINDNESS, AND POSSIBLE
DEATH. MAY CAUSE EYE IRRITATION. PROLONGED EXPOSURE MAY CAUSE SKIN
IRRITATION.
| 5. FIRE FIGHTING MEASURES | |
FLAMMABILITY: THIS PRODUCT IS FLAMMABLE.
TEST METHOD: IGNITION DISTANCE TEST AND ENCLOSED SPACE IGNITION TEST
SUITABLE EXTINGUISHING MEDIA:
ALCOHOL RESISTANT FOAM, DRY CHEMICAL, CARBON DIOXIDE (CO2)
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A HEAVY WATER STREAM. USE OF HEAVY STREAM OF WATER MA SPREAD
THE FIRE.
SPECIAL HAZARDS:
HAZARDOUS REACTION WILL NOT OCCUR UNDER NORMAL CONDITIONS. KEEP CONTAINERS
COOL BY SPRAYING WITH WATER. VAPORS MAY ACCUMULATE IN CONFINED SPACES AND
ARE HEAVIER THAN AIR.
SPECIAL FIRE FIGHTING INSTRUCTION:
DO NOT ENTER AREA WITHOUT PERSONAL PROTECTIVE EQUIPMENT. EXPOSURE TO
DECOMPOSITION PRODUCTS MAY BE A HAZARD TO HEALTH. WEAR SELF-CONTAINED
BREATHING APPARATUS, IF NECESSARY. USE WATER SPRAY TO KEEP EXPOSED
CONTAINERS COOL. DO NOT ALLOW RUN-OFF FROM FIRE-FIGHTING TO ENTER DRAINS
OR WATER SOURCES.
| 6. ACCIDENTAL RELEASE MEASURES | |
SAFEGUARDS (PERSONNEL):
EVACUATE PERSONNEL TO SAFE AREA. USE PERSONAL PROTECTIVE EQUIPMENT. REMOVE
ALL SOURCES OF IGNITION. VENTILATE AREA, ESPECIALLY LOW OR ENCLOSED PLACES
WHERE HEAVY VAPORS MIGHT COLLECT. IN CASE OF INSUFFICIENT VENTILATION, WEAR
SUITABLE RESPIRATORY EQUIPMENT.
ENVIRONMENTAL PRECAUTIONS:
PREVENT MATERIAL FROM ENTERING SEWERS, WATERWAYS, OR LOW AREAS. SHOULD NOT
BE RELEASED INTO THE ENVIRONMENT.
SPILL CLEANUP:
CONTAIN SPILLAGE, AND THEN COLLECT WITH ELECTRICALLY PROTECTED VACUUM
CLEANER OR BY WET-BRUSHING AND PLACE IN CONTAINER FOR DISPOSAL ACCORDING
TO LOCAL / NATIONAL REGULATIONS
| 7. HANDLING AND STORAGE | |
HANDLING:
KEEP AWAY FROM OPEN FLAME OR OTHER IGNITION SOURCES. USE IN A
WELL-VENTILATED AREA TO AVOID BREATHING VAPORS. VAPORS ARE HEAVIER THAN
AIR AND ACCUMULATE IN LOW AREAS. USE ONLY WITH ADEQUATE VENTILATION. USE
APPROPRIATE RESPIRATORY PROTECTION WHEN VENTILATION IS INADEQUATE. WHEN
USING DO NOT EAT, DRINK, OR SMOKE. AVOID CONTACT WITH SKIN, EYES OR
CLOTHING. WASH THOROUGHLY AFTER HANDLING.
STORAGE CONDITIONS:
STORE IN A CLEAN, DRY PLACE THAT IS WELL-VENTILATED. DO NOT STORE NEAR
SOURCES OF HEAT, IN DIRECT SUNLIGHT OR WHERE TEMPERATURES EXCEED
125 DEG. F/52 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER USE.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE LIMITS TLV (ACGIH) PEL (OSHA) AEL* (DUPONT)
1,1,1,2,2,3,4,5,5,5- NOT NOT 200 PPM, 8 & 12 HR. TWA
DECAFLUOROPENTANE ESTABLISHED ESTABLISHED 400 PPM, CEILING
TRANS,1,2- 200 PPM, TWA 200 PPM, 8 HR. 200 PPM, 8 & 12 HR. TWA
DICHLOROETHYLENE TWA
METHANOL 200 PPM, TWA 200 PPM, 8 HR. 200 PPM, 8 & 12 HR.
TWA TWA, SKIN
* AEL IS DUPONT'S ACCEPTABLE EXPOSURE LIMIT. WHERE GOVERNMENTALLY IMPOSED
OCCUPATIONAL EXPOSURE LIMITS WHICH IS LOWER THAN THE AEL ARE IN EFFECT,
SUCH LIMITS SHALL TAKE PRECEDENCE.
RESPIRATORY PROTECTION:
AVOID BREATHING VAPORS, MISTS OR SPRAY. USE WITH SUFFICIENT VENTILATION
ESPECIALLY FOR ENCLOSED OR LOW PLACES. VAPORS ARE HEAVIER THAN AIR AND CAN
CAUSE SUFFOCATION BY REDUCING OXYGEN. IN POORLY VENTILATED AREAS, USE AN
APPROVED SELF-CONTAINED BREATHING APPARATUS.
EYE PROTECTION:
AVOID EYE CONTACT. USE CHEMICAL GOGGLES OR SAFETY GLASSES WITH SIDE
SHIELDS.
SKIN PROTECTION:
AVOID CONTACT WITH SKIN. USE GLOVES/PROTECTIVE CLOTHING THAT IMPERVIOUS
TO THIS MATERIAL WHEN PROLONGED OR FREQUENTLY REPEATED CONTACT OCCURS.
PREVENTION OF SWALLOWING:
DO NOT EAT OR DRINK WHEN USING THIS PRODUCT. WASH EXPOSED AREAS THOROUGHLY
WITH SOAP AND WATER.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING POINT: N.A.
PERCENT VOLATILE BY VOLUME: 100%
DENSITY: 1.28 G/CC AT 77 DEG. F/25 DEG. C
VAPOR PRESSURE: TO BE DETERMINED
VAPOR DENSITY (AIR=1): >1
SOLUBILITY IN H2O: TO BE DETERMINED
PH INFORMATION: NEUTRAL
EVAPORATION RATE (CC14=1): N.A.
FORM: AEROSOL
APPEARANCE: CLEAR
COLOR: COLORLESS
ODOR: ETHEREAL
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: HAZARDOUS REACTIONS WILL NOT OCCUR UNDER NORMAL CONDITIONS.
CHEMICAL STABILITY: STABLE AT NORMAL AMBIENT CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
MATERIAL AND CONDITIONS TO AVOID:
HEAT, SPARKS, FLAMES. DIRECT SUNLIGHT. EXTREMELY HIGH TEMPERATURES. STRONG
ACIDS, STRONG BASES AND STRONG OXIDIZERS.
DECOMPOSITION:
THIS PRODUCT CAN BE DECOMPOSED BY HIGH TEMPERATURES (FLAME, GLOWING METAL
SURFACES, ETC.) FORMING CARBON OXIDES (CO, CO2), HYDROGEN CHLORIDE,
HYDROGEN FLUORIDE, CARBONYL FLUORIDE, FLUOROCARBONS.
| 11. TOXICOLOGICAL INFORMATION | |
ANIMAL DATA:
1,1,1,2,2,3,4,5,5,5-DECAFLUOROPENTANE (HFC-43-10MEE):
INHALATION:
4 HOUR LC50: 114MG/L IN RATS, CENTRAL NERVOUS SYSTEM EFFECTS, CONVULSIONS
ORAL:
LD50: >5,000 MG/KG IN RATS
DERMAL:
LD50: >5,000 MG/KG IN RABBITS
SKIN IRRITATION: NO SKIN IRRITATION, RABBIT
EYE IRRITATION: NO EYE IRRITATION, RABBIT
SKIN SENSITIZATION:
DID NOT CAUSE SENSITIZATION ON LABORATORY ANIMALS., GUINEA PIG
REPEATED DOSE TOXICITY:
INHALATION, RAT
NO TOXICOLOGICALLY SIGNIFICANT EFFECTS WERE FOUND.
REPRODUCTIVE TOXICITY: ANIMAL TESTING SHOWED NO REPRODUCTIVE TOXICITY.
TERATOGENICITY: ANIMAL TESTING SHOWED NO DEVELOPMENTAL TOXICITY.
TRANS-1,2-DICHLOROETHYLENE:
ORAL:
LD50: 7902 MG/KG IN RATS
DERMAL:
LD50: >5,000 MG/KG IN RABBITS
INHALATION:
4 HOUR LC50: 95.4 MG/L IN RATS
TARGET ORGANS: CENTRAL NERVOUS SYSTEM, NARCOSIS
SKIN IRRITATION: MILD SKIN IRRITATION IN RABBITS
EYE IRRITATION: MILD EYE IRRITATION IN RABBITS
REPEATED DOSE TOXICITY:
INHALATION, 90 DAYS IN RATS:
NO TOXICOLOGICALLY SIGNIFICANT EFFECTS WERE FOUND.
ORAL, 90 DAYS IN RATS: NO TOXICOLOGICALLY SIGNIFICANT EFFECTS WERE FOUND.
MUTAGENICITY:
DID NOT CAUSE GENETIC DAMAGE IN ANIMALS.
TEST ON BACTERIAL OR MAMMALIAN CELL CULTURES DID NOT SHOW MUTAGENIC
EFFECTS.
REPRODUCTIVE TOXICITY: ANIMAL TESTING SHOWED NO REPRODUCTIVE TOXICITY.
TERATOGENICITY: ANIMAL TESTING SHOWED NO DEVELOPMENTAL TOXICITY.
METHANOL:
INHALATION ACUTE TOXICITY: 3 MG/L, ANIMALS (UNSPECIFIED SPECIES)
TARGET ORGANS:
CENTRAL NERVOUS SYSTEM, EYE, CENTRAL NERVOUS SYSTEM EFFECTS, NARCOSIS, EYE
EFFECTS.
DERMAL ACUTE TOXICITY: 300 MG/KG IN RABBITS (UNSPECIFIED SPECIES)
TARGET ORGANS:
CENTRAL NERVOUS SYSTEM, EYE, CENTRAL NERVOUS SYSTEM EFFECTS, NARCOSIS, EYE
EFFECTS.
ORAL ACUTE TOXICITY: 100 MG/KG, ANIMALS (UNSPECIFIED SPECIES)
TARGET ORGANS:
CENTRAL NERVOUS SYSTEM, EYE, CENTRAL NERVOUS SYSTEM EFFECTS:
NARCOSIS, EYE EFFECTS
SKIN IRRITATION: SLIGHT OR NO IRRITATION, RABBIT
EYE IRRITATION: SLIGHT IRRITATION, RABBIT
SKIN SENSITIZATION:
DID NOT CAUSE SENSITIZATION ON LABORATORY ANIMALS, GUINEA PIG
CARCINOGENICITY:
NOT CLASSIFIABLE AS A HUMAN CARCINOGEN. OVERALL WEIGHT EVIDENCE INDICATES
THAT THE SUBSTANCE IS NOT CARCINOGENIC.
MUTAGENICITY:
ANIMAL TESTING DID NOT SHOW ANY MUTAGENIC EFFECTS.
TESTS ON BACTERIAL OR MAMMALIAN CELL CULTURES DID NOT SHOW MUTAGENIC
EFFECTS.
OVERALL WEIGHT OF EVIDENCE INDICATES THAT THE SUBSTANCE IS NOT MUTAGENIC.
DID NOT CAUSE GENETIC DAMAGE IN ANIMALS.
GENETIC DAMAGE IN CULTURED MAMMALIAN CELLS WAS OBSERVED IN SOME LABORATORY
TESTS BUT NOT IN OTHERS.
GENETIC DAMAGE IN CULTURED BACTERIAL CELLS WAS OBSERVED IN SOME LABORATORY
TESTS BUT NOT IN OTHERS.
REPRODUCTIVE TOXICITY:
NO TOXICITY OR REPRODUCTION. EVIDENCE SUGGESTS THE SUBSTANCE IS NOT A
REPRODUCTIVE TOXIN IN ANIMALS.
TERATOGENICITY:
EVIDENCE SUGGESTS THE SUBSTANCE IS NOT A DEVELOPMENTAL TOXIN IN ANIMALS.
| 12. ECOLOGICAL INFORMATION | |
AQUATIC TOXICITY:
1,1,1,2,2,3,4,5,5,5-DECAFLUOROPENTANE (HFC-43-10 MEE):
96 HOUR LC50 IN FATHEAD MINNOWS: 27.2 MG/L
96 HOUR LC50 IN RAINBOW TROUT: 13.9 MG/L
48 HOUR LC50 IN DAPHNIA MAGNA: 11.7 MG/L
72 HOUR EC50 IN GREEN ALGAE: >120 MG/L
TRANS-1,2-DICHLOROETHYLENE:
96 HOUR LC50 IN BLUEGILL SUNFISH: 74 MG/L
48 HOUR LC50 IN DAPHNIA MAGNA: 79 MG/L
96 HOUR EC50 IN GREEN ALGAE: 798 MG/L
METHANOL:
96 HOUR LC50 - FLATHEAD MINNOW: 28,100 MG/L
48 HOUR EC50 - DAPHNIA (WATER FLEA): >10,000 MG/L
96 HOUR LC50 - GREEN ALGAE (SELENASTRUM CARPRICORNUTUM): 22,000 MG/L
| 13. DISPOSAL CONSIDERATIONS | |
COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS. REMOVE TO A PERMITTED
WASTE DISPOSAL FACILITY.
| 14. TRANSPORT INFORMATION | |
U.S. DOT:
PROPER SHIPPING NAME: CONSUMER COMMODITY
HAZARD CLASS: ORM-D
IDENTIFICATION NO.: NONE
PACKING GROUP: NONE
IATA:
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS: 2.1
IDENTIFICATION NO.: UN1950
PACKING GROUP: NONE
IMDG:
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS: 2.1
IDENTIFICATION NO.: UN1950
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA: ALL INGREDIENTS ARE LISTED IN TSCA INVENTORY.
1,1,1,2,2,3,4,5,5,5-DECAFLUOROPENTANE (CAS# 138495-42-8) IS CONTROLLED BY
TSCA SECTION 5, SIGNIFICANT NEW USE RULE (SNUR; 40 CFR 721.5645) THE
APPROVED USES ARE: PRECISION AND GENERAL CLEANING, CARRIER FLUID,
DISPLACEMENT DRYING, PRINTED CIRCUIT BOARD CLEANING, PARTICULATE REMOVAL,
FILM CLEANING, PROCESS MEDIUM, HEAT TRANSFER FLUID (DIELECTRIC AND
NON-DIELECTRIC), AND TEST FLUID. PROCESSORS AND USERS OF THIS SUBSTANCE
MUST ALSO COMPLY WITH THE APPLICABLE GENERAL SNUR REQUIREMENTS SET FORTH IN
40 CFR 721 SUBPART A, INCLUDING EXPORT NOTIFICATION REQUIREMENTS IF
APPLICABLE (40 CFR 721.20), AND THE APPLICABLE RECORD KEEPING REQUIREMENTS
SET FORTH AT 40 CFR 721.125.
SARA 313 REGULATED CHEMICALS: TRANS-DICHLOROETHYLENE, METHANOL
STATE REGULATIONS (U.S.):
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND/OR BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| 16. OTHER INFORMATION | |
NPCA-HMIS RATINGS:
HEALTH 2
FLAMMABILITY 2
REACTIVITY 1
PERSONAL PROTECTIVE RATING TO BE SUPPLIED BY USER DEPENDING ON THE
CONDITIONS.
FOR INDUSTRIAL USE ONLY
REVISION DATE: SEPTEMBER 2015
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT. FINAL DETERMINATION OF SUITABILITY
OF ANY MATERIAL IS THE SOLE RESPONSIBILITY OF THE USER.