| Common Name: | HIGH BUILD MASTIC EPOXY SEMI-GLOSS, WHITE/BASE 1 |
| Manufacturer: | KRYLON PRODUCTS GROUP |
| SDS Revision Date: | 5/22/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 321KY6, 52JN38 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
K000S3731
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: KRYLON(R*) HIGH BUILD MASTIC EPOXY SEMI-GLOSS WHITE/BASE 1
PRODUCT CODE: K000S3731
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
PRODUCT TYPE: LIQUID.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: PAINT OR PAINT RELATED MATERIAL.
MANUFACTURER:
KRYLON PRODUCTS GROUP
101 PROSPECT AVENUE NW
CLEVELAND, OH 44115
EMERGENCY TELEPHONE NUMBER OF THE COMPANY:
US/CANADA: (216) 566-2917
MEXICO:
CHEMTREC MEXICO 01-800-681-9531. AVAILABLE 24 HOURS AND 365 DAYS PER YEAR
PRODUCT INFORMATION TELEPHONE NUMBER:
US/CANADA: (800) 247-3266
MEXICO: NOT AVAILABLE
REGULATORY INFORMATION TELEPHONE NUMBER:
US/CANADA: (216) 566-2902
MEXICO: NOT AVAILABLE
TRANSPORTATION EMERGENCY TELEPHONE NUMBER:
US/CANADA: (800) 424-9300
MEXICO:
SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 HOURS / 365 DAYS A YEAR
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE LIQUIDS: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SKIN SENSITIZATION: CATEGORY 1
CARCINOGENICITY: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(RESPIRATORY TRACT IRRITATION): CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (NARCOTIC EFFECTS):
CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (LUNGS, SKIN):
CATEGORY 1
ASPIRATION HAZARD: CATEGORY 1
| PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN ORAL
| TOXICITY: 29.4%
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN DERMAL
TOXICITY: 29.6%
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN
INHALATION TOXICITY: 50.1%
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
CORROSION
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
COMBUSTIBLE LIQUID.
CAUSES SERIOUS EYE DAMAGE.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
SUSPECTED OF CAUSING CANCER.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
(LUNGS, SKIN)
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE GLOVES. WEAR
EYE OR FACE PROTECTION. WEAR PROTECTIVE CLOTHING. KEEP AWAY FROM FLAMES
AND HOT SURFACES. - NO SMOKING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED
AREA. DO NOT BREATHE VAPOR. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. WASH HANDS THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING
MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE: GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. DO NOT INDUCE VOMITING.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER OR PHYSICIAN.
STORAGE: STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. CONTAINS SOLVENTS WHICH CAN
CAUSE PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL OR
FATAL.
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. FOR INDUSTRIAL USE
ONLY. THIS PRODUCT MUST BE MIXED WITH OTHER COMPONENTS BEFORE USE. BEFORE
OPENING THE PACKAGES, READ AND FOLLOW WARNING LABELS ON ALL COMPONENTS.
PLEASE REFER TO THE SDS FOR ADDITIONAL INFORMATION. KEEP OUT OF REACH
OF CHILDREN. DO NOT TRANSFER CONTENTS TO OTHER CONTAINERS FOR STORAGE.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS NUMBER/OTHER IDENTIFIERS:
INGREDIENT NAME % BY WEIGHT CAS NUMBER
| TITANIUM DIOXIDE >/=25 - </=50 13463-67-7
P-CHLOROBENZOTRIFLUORIDE >/=10 - </=25 98-56-6
PHENOL, ISOBUTYLENATED METHYLSTYRENATED >/=10 - </=25 68457-74-9
POLYAMIDE </=10 68410-23-1
TALC </=10 14807-96-6
XYLENE, MIXED ISOMERS </=3 1330-20-7
TRIETHYLENE TETRAMINE <1 112-24-3
ETHYLBENZENE </=0.3 100-41-4
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS
DUE TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH AND HENCE REQUIRE REPORTING IN THIS
SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN.
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE
UPPER AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE
TO RINSE FOR AT LEAST 10 MINUTES. CHEMICAL BURNS MUST BE TREATED PROMPTLY
BY A PHYSICIAN.
INHALATION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN.
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IF
NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST OCCURS,
PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED PERSONNEL. IT MAY BE
DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION.
IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL ATTENTION
IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A
COLLAR, TIE, BELT OR WAISTBAND. IN CASE OF INHALATION OF DECOMPOSITION
PRODUCTS IN A FIRE, SYMPTOMS MAY BE DELAYED. THE EXPOSED PERSON MAY NEED
TO BE KEPT UNDER MEDICAL SURVEILLANCE FOR 48 HOURS.
SKIN CONTACT:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. WASH
WITH PLENTY OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH
CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING IT, OR WEAR
GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. CHEMICAL BURNS MUST
BE TREATED PROMPTLY BY A PHYSICIAN. IN THE EVENT OF ANY COMPLAINTS OR
SYMPTOMS, AVOID FURTHER EXPOSURE. WASH CLOTHING BEFORE REUSE. CLEAN SHOES
THOROUGHLY BEFORE REUSE.
INGESTION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. WASH
OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH AIR
AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL HAS
BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES
OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS VOMITING MAY
BE DANGEROUS. ASPIRATION HAZARD IF SWALLOWED. CAN ENTER LUNGS AND CAUSE
DAMAGE. DO NOT INDUCE VOMITING. IF VOMITING OCCURS, THE HEAD SHOULD BE
KEPT LOW SO THAT VOMIT DOES NOT ENTER THE LUNGS. CHEMICAL BURNS MUST BE
TREATED PROMPTLY BY A PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET
MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT
CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS
OR DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY BE FATAL IF
SWALLOWED AND ENTERS AIRWAYS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
REDNESS
BLISTERING MAY OCCUR
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
STOMACH PAINS
NAUSEA OR VOMITING
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN:
IN CASE OF INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY BE
DELAYED. THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL SURVEILLANCE
FOR 48 HOURS.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT
MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE DRY CHEMICAL, CO2, WATER SPRAY (FOG) OR FOAM.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER JET.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
COMBUSTIBLE LIQUID. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER
MAY BURST, WITH THE RISK OF A SUBSEQUENT EXPLOSION. THE VAPOR/GAS IS
HEAVIER THAN AIR AND WILL SPREAD ALONG THE GROUND. VAPORS MAY ACCUMULATE
IN LOW OR CONFINED AREAS OR TRAVEL A CONSIDERABLE DISTANCE TO A SOURCE OF
IGNITION AND FLASH BACK.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
HALOGENATED COMPOUNDS
CARBONYL HALIDES
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE AREA
IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
SHUT OFF ALL IGNITION SOURCES. NO FLARES, SMOKING OR FLAMES IN HAZARD
AREA. DO NOT BREATHE VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE
ALSO THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL
OR AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. DILUTE WITH WATER AND MOP UP IF
WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE, ABSORB WITH AN INERT
DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER. DISPOSE
OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH
SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN
AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND,
EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR
DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF VIA
A LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY
POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). PERSONS
WITH A HISTORY OF SKIN SENSITIZATION PROBLEMS SHOULD NOT BE EMPLOYED IN
ANY PROCESS IN WHICH THIS PRODUCT IS USED. AVOID EXPOSURE - OBTAIN SPECIAL
INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE
BEEN READ AND UNDERSTOOD. DO NOT GET IN EYES OR ON SKIN OR CLOTHING. DO
NOT BREATHE VAPOR OR MIST. DO NOT SWALLOW. USE ONLY WITH ADEQUATE
VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE.
DO NOT ENTER STORAGE AREAS AND CONFINED SPACES UNLESS ADEQUATELY
VENTILATED. KEEP IN THE ORIGINAL CONTAINER OR AN APPROVED ALTERNATIVE MADE
FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT IN USE. STORE AND
USE AWAY FROM HEAT, SPARKS, OPEN FLAME OR ANY OTHER IGNITION SOURCE. USE
EXPLOSION-PROOF ELECTRICAL (VENTILATING, LIGHTING AND MATERIAL HANDLING)
EQUIPMENT. USE ONLY NON-SPARKING TOOLS. EMPTY CONTAINERS RETAIN PRODUCT
RESIDUE AND CAN BE HAZARDOUS. DO NOT REUSE CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN A SEGREGATED AND
APPROVED AREA. STORE IN ORIGINAL CONTAINER PROTECTED FROM DIRECT SUNLIGHT
IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10) AND FOOD AND DRINK. STORE LOCKED UP. ELIMINATE ALL
IGNITION SOURCES. SEPARATE FROM OXIDIZING MATERIALS. KEEP CONTAINER TIGHTLY
CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS THAT HAVE BEEN OPENED
MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT LEAKAGE. DO NOT
STORE IN UNLABELED CONTAINERS. USE APPROPRIATE CONTAINMENT TO AVOID
ENVIRONMENTAL CONTAMINATION. SEE SECTION 10 FOR INCOMPATIBLE MATERIALS
BEFORE HANDLING OR USE.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS (OSHA UNITED STATES):
INGREDIENT NAME EXPOSURE LIMITS
| TITANIUM DIOXIDE ACGIH TLV (UNITED STATES, 3/2018).
| TWA: 10 MG/M3 8 HOURS.
OSHA PEL (UNITED STATES, 5/2018).
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
P-CHLOROBENZOTRIFLUORIDE NONE.
PHENOL, ISOBUTYLENATED NONE.
METHYLSTYRENATED
POLYAMIDE NONE.
TALC NIOSH REL (UNITED STATES, 10/2016).
TWA: 2 MG/M3 10 HOURS.
FORM: RESPIRABLE FRACTION
ACGIH TLV (UNITED STATES, 3/2018).
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
XYLENE, MIXED ISOMERS ACGIH TLV (UNITED STATES, 3/2018).
TWA: 100 PPM 8 HOURS.
TWA: 434 MG/M3 8 HOURS.
STEL: 150 PPM 15 MINUTES.
STEL: 651 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 5/2018).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
TRIETHYLENE TETRAMINE AIHA WEEL (UNITED STATES, 7/2018).
ABSORBED THROUGH SKIN.
TWA: 1 PPM 8 HOURS.
ETHYLBENZENE ACGIH TLV (UNITED STATES, 3/2018).
TWA: 20 PPM 8 HOURS.
NIOSH REL (UNITED STATES, 10/2016).
TWA: 100 PPM 10 HOURS.
TWA: 435 MG/M3 10 HOURS.
STEL: 125 PPM 15 MINUTES.
STEL: 545 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 5/2018).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
OCCUPATIONAL EXPOSURE LIMITS (CANADA):
INGREDIENT NAME EXPOSURE LIMITS
| TITANIUM DIOXIDE CA BRITISH COLUMBIA PROVINCIAL (CANADA, 7/2018).
TWA: 3 MG/M3 8 HOURS.
FORM: RESPIRABLE DUST
TWA: 10 MG/M3 8 HOURS.
FORM: TOTAL DUST
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 10 MG/M3 8 HOURS.
FORM: TOTAL DUST.
CA ALBERTA PROVINCIAL (CANADA, 6/2018).
8 HRS OEL: 10 MG/M3 8 HOURS.
CA ONTARIO PROVINCIAL (CANADA, 1/2018).
TWA: 10 MG/M3 8 HOURS.
CA SASKATCHEWAN PROVINCIAL (CANADA, 7/2013).
STEL: 20 MG/M3 15 MINUTES.
TWA: 10 MG/M3 8 HOURS.
TALC (NONE ASBESTIFORM) CA BRITISH COLUMBIA PROVINCIAL (CANADA, 7/2018).
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE
TWA: 0.1 F/CC 8 HOURS.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 3 MG/M3 8 HOURS.
FORM: RESPIRABLE DUST.
CA ONTARIO PROVINCIAL (CANADA, 1/2018).
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION.
TWA: 2 F/CC 8 HOURS.
CA ALBERTA PROVINCIAL (CANADA, 6/2018).
8 HRS OEL: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE PARTICULATE
CA SASKATCHEWAN PROVINCIAL (CANADA, 7/2013).
TWA: 2 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
XYLENE CA ALBERTA PROVINCIAL (CANADA, 6/2018).
8 HRS OEL: 100 PPM 8 HOURS.
15 MIN OEL: 651 MG/M3 15 MINUTES.
15 MIN OEL: 150 PPM 15 MINUTES.
8 HRS OEL: 434 MG/M3 8 HOURS.
CA BRITISH COLUMBIA PROVINCIAL (CANADA, 7/2018).
TWA: 100 PPM 8 HOURS.
STEL: 150 PPM 15 MINUTES.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 100 PPM 8 HOURS.
TWAEV: 434 MG/M3 8 HOURS.
STEV: 150 PPM 15 MINUTES.
STEV: 651 MG/M3 15 MINUTES.
CA ONTARIO PROVINCIAL (CANADA, 1/2018).
STEL: 150 PPM 15 MINUTES.
TWA: 100 PPM 8 HOURS.
CA SASKATCHEWAN PROVINCIAL (CANADA, 7/2013).
STEL: 150 PPM 15 MINUTES.
TWA: 100 PPM 8 HOURS.
TRIETHYLENETETRAMINE CA ONTARIO PROVINCIAL (CANADA, 1/2018).
ABSORBED THROUGH SKIN.
TWA: 3 MG/M3 8 HOURS.
TWA: 0.5 PPM 8 HOURS.
ETHYLBENZENE CA ALBERTA PROVINCIAL (CANADA, 6/2018).
8 HRS OEL: 100 PPM 8 HOURS.
8 HRS OEL: 434 MG/M3 8 HOURS.
15 MIN OEL: 543 MG/M3 15 MINUTES.
15 MIN OEL: 125 PPM 15 MINUTES.
CA BRITISH COLUMBIA PROVINCIAL (CANADA, 7/2018).
TWA: 20 PPM 8 HOURS.
CA ONTARIO PROVINCIAL (CANADA, 1/2018).
TWA: 20 PPM 8 HOURS.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 100 PPM 8 HOURS.
TWAEV: 434 MG/M3 8 HOURS.
STEV: 125 PPM 15 MINUTES.
STEV: 543 MG/M3 15 MINUTES.
CA SASKATCHEWAN PROVINCIAL (CANADA, 7/2013).
STEL: 125 PPM 15 MINUTES.
TWA: 100 PPM 8 HOURS.
OCCUPATIONAL EXPOSURE LIMITS (MEXICO):
INGREDIENT NAME EXPOSURE LIMITS
| XYLENE, MIXED ISOMERS NOM-010-STPS-2014 (MEXICO, 4/2016).
STEL: 150 PPM 15 MINUTES.
TWA: 100 PPM 8 HOURS.
ETHYLBENZENE NOM-010-STPS-2014 (MEXICO, 4/2016).
TWA: 20 PPM 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS. THE
ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS
BELOW ANY LOWER EXPLOSIVE LIMITS. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE
WORKING PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE THAT
EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION:
CHEMICAL SPLASH GOGGLES AND/OR FACE SHIELD. IF INHALATION HAZARDS EXIST,
A FULL-FACE RESPIRATOR MAY BE REQUIRED INSTEAD.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON
THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED
BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
BASED ON THE HAZARD AND POTENTIAL FOR EXPOSURE, SELECT A RESPIRATOR THAT
MEETS THE APPROPRIATE STANDARD OR CERTIFICATION. RESPIRATORS MUST BE USED
ACCORDING TO A RESPIRATORY PROTECTION PROGRAM TO ENSURE PROPER FITTING,
TRAINING, AND OTHER IMPORTANT ASPECTS OF USE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: NOT AVAILABLE.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
BOILING POINT/BOILING RANGE: 138 DEG. C (280.4 DEG. F)
FLASH POINT:
CLOSED CUP: 61 DEG. C (141.8 DEG. F) [TAGLIABUE CLOSED CUP]
EVAPORATION RATE: 0.53 (BUTYL ACETATE = 1)
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 0.9%
UPPER: 10.5%
VAPOR PRESSURE: 0.79 KPA (5.9 MMHg) [AT 20 DEG. C]
VAPOR DENSITY: 3.66 [AIR = 1]
RELATIVE DENSITY: 1.61
SOLUBILITY: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (40 DEG. C (104 DEG. F)): <0.205 CM2/S (<20.5 CST)
MOLECULAR WEIGHT: NOT APPLICABLE.
AEROSOL PRODUCT:
HEAT OF COMBUSTION: 10.18 KJ/G
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME). DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT OR
SOURCES OF IGNITION. DO NOT ALLOW VAPOR TO ACCUMULATE IN LOW OR CONFINED
AREAS.
INCOMPATIBLE MATERIALS:
REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS: OXIDIZING MATERIALS
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
| P-CHLOROBENZO- LD50 ORAL RAT 13 G/KG
| TRIFLUORIDE
PHENOL, LD50 DERMAL RABBIT >20000 MG/KG
ISOBUTYLENATED
METHYLSTYRENATED
XYLENE, MIXED LC50 INHALATION GAS. RAT 5000 PPM 4 HOURS
ISOMERS LD50 ORAL RAT 4300 MG/KG
TRIETHYLENE LD50 DERMAL RABBIT 805 MG/KG
TETRAMINE LD50 ORAL RAT 2500 MG/KG
ETHYLBENZENE LD50 DERMAL RABBIT >5000 MG/KG
LD50 ORAL RAT 3500 MG/KG
IRRITATION/CORROSION:
PRODUCT/ RESULT SPECIES SCORE EXPOSURE OBSERVATION
INGREDIENT
NAME
| TITANIUM SKIN: HUMAN 72 HOURS
| DIOXIDE MILD IRRITANT 300 MICROGRAMS
| INTERMITTENT
TALC SKIN: HUMAN 72 HOURS
MILD IRRITANT 300 MICROGRAMS
INTERMITTENT
XYLENE, EYES: RABBIT 87 MILLIGRAMS
MIXED MILD IRRITANT
ISOMERS
EYES: RABBIT 24 HOURS
SEVERE 5 MILLIGRAMS
IRRITANT
SKIN: RAT 8 HOURS
MILD IRRITANT 60 MICROLITERS
SKIN: RABBIT 24 HOURS
MODERATE 500 MILLIGRAMS
IRRITANT
SKIN: RABBIT 100 PERCENT
MODERATE
IRRITANT
TRIETHYLENE EYES: RABBIT 24 HOURS
TETRAMINE MODERATE 20 MILLIGRAMS
IRRITANT
EYES: RABBIT 49 MILLIGRAMS
SEVERE
IRRITANT
SKIN: RABBIT 24 HOURS
SEVERE 5 MILLIGRAMS
IRRITANT
SKIN: RABBIT 490 MILLIGRAMS
SEVERE
IRRITANT
ETHYLBENZENE EYES: RABBIT 500 MILLIGRAMS
SEVERE
IRRITANT
SKIN: RABBIT 24 HOURS
MILD IRRITANT 15 MILLIGRAMS
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
| TITANIUM DIOXIDE 2B
TALC 3
XYLENE, MIXED ISOMERS 3
ETHYLBENZENE 2B
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
| P-CHLOROBENZO- CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
| TRIFLUORIDE IRRITATION
PHENOL, ISOBUTYLENATED CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
METHYLSTYRENATED IRRITATION AND
NARCOTIC EFFECTS
XYLENE, MIXED ISOMERS CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION
ETHYLBENZENE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
| PHENOL, ISOBUTYLENATED CATEGORY 2 NOT DETERMINED SKIN
| METHYLSTYRENATED
TALC CATEGORY 1 INHALATION LUNGS
XYLENE, MIXED ISOMERS CATEGORY 2 NOT DETERMINED NOT DETERMINED
ETHYLBENZENE CATEGORY 2 NOT DETERMINED NOT DETERMINED
ASPIRATION HAZARD:
NAME RESULT
| PHENOL, ISOBUTYLENATED METHYLSTYRENATED ASPIRATION HAZARD - CATEGORY 1
XYLENE, MIXED ISOMERS ASPIRATION HAZARD - CATEGORY 1
ETHYLBENZENE ASPIRATION HAZARD - CATEGORY 1
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS
OR DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY BE FATAL IF
SWALLOWED AND ENTERS AIRWAYS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
REDNESS
BLISTERING MAY OCCUR
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
STOMACH PAINS
NAUSEA OR VOMITING
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND
LONG TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. ONCE
SENSITIZED, A SEVERE ALLERGIC REACTION MAY OCCUR WHEN SUBSEQUENTLY
EXPOSED TO VERY LOW LEVELS.
CARCINOGENICITY:
SUSPECTED OF CAUSING CANCER. RISK OF CANCER DEPENDS ON DURATION AND LEVEL
OF EXPOSURE.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
| ORAL 215209.5 MG/KG
DERMAL 54956.2 MG/KG
INHALATION (GASES) 177166 PPM
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
| TITANIUM DIOXIDE ACUTE LC50: FISH - FUNDULUS 96 HOURS
| >1000000 (MICRO) HETEROCLITUS
| MARINE WATER
XYLENE, MIXED ACUTE LC50: CRUSTACEANS - 48 HOURS
ISOMERS 8500 (MICRO) PALAEMONETES PUGIO
MARINE WATER
ACUTE LC50: FISH - PIMEPHALES 96 HOURS
13400 (MICRO) PROMELAS
FRESH WATER
TRIETHYLENE ACUTE EC50: ALGAE - 96 HOURS
TETRAMINE 3700 (MICRO) PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE LC50: DAPHNIA - DAPHNIA 48 HOURS
33900 (MICRO) MAGNA
FRESH WATER
ETHYLBENZENE ACUTE EC50: ALGAE - 72 HOURS
4600 (MICRO) PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: ALGAE - 96 HOURS
3600 (MICRO) PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: CRUSTACEANS - ARTEMIA 48 HOURS
6.53 MG/L SP. - NAUPLII
MARINE WATER
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
2.93 MG/L MAGNA - NEONATE
FRESH WATER
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
4200 (MICRO) MYKISS
FRESH WATER
PERSISTENCE AND DEGRADABILITY:
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
| XYLENE, MIXED ISOMERS READILY
ETHYLBENZENE READILY
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
| XYLENE, MIXED ISOMERS 8.1 TO 25.9 LOW
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY
BE CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS
CONTAINER MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN
HANDLING EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. VAPOR FROM PRODUCT
RESIDUES MAY CREATE A HIGHLY FLAMMABLE OR EXPLOSIVE ATMOSPHERE INSIDE THE
CONTAINER. DO NOT CUT, WELD OR GRIND USED CONTAINERS UNLESS THEY HAVE BEEN
CLEANED THOROUGHLY INTERNALLY. AVOID DISPERSAL OF SPILLED MATERIAL AND
RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
| UN NUMBER NOT REGULATED. NOT REGULATED. NOT REGULATED.
| UN PROPER SHIPPING
| NAME
| TRANSPORT HAZARD
| CLASS(ES)
| PACKING GROUP
| ENVIRONMENTAL HAZARDS NO. NO. NO.
| ADDITIONAL
| INFORMATION
IATA IMDG
| UN NUMBER NOT REGULATED. UN3082
| UN PROPER SHIPPING ENVIRONMENTALLY HAZARDOUS
| NAME SUBSTANCE, LIQUID, N.O.S.
| (P-CHLOROBENZOTRIFLUORIDE,
| POLYAMIDE).
| MARINE POLLUTANT
| (P-CHLOROBENZOTRIFLUORIDE,
| POLYAMIDE)
| TRANSPORT HAZARD 9
| CLASS(ES) CLASS 9 - MISCELLANEOUS
|
| ENVIRONMENT
| PACKING GROUP III
| ENVIRONMENTAL HAZARDS NO. YES.
| ADDITIONAL INFORMATION THE ENVIRONMENTALLY THIS PRODUCT IS NOT
| HAZARDOUS REGULATED AS A
| SUBSTANCE MARK DANGEROUS GOOD
| MAY APPEAR IF WHEN TRANSPORTED IN
| REQUIRED BY OTHER SIZES OF </=5 L
| TRANSPORTATION OR </=5 KG, PROVIDED
| REGULATIONS. THE PACKAGINGS MEET
| THE GENERAL PROVISIONS
| OF 4.1.1. 1,4.1.1.2 AND
| 4.1. 1.4 TO 4.1.1.8.
| EMERGENCY SCHEDULES:
| F-A, S-F
SPECIAL PRECAUTIONS FOR USER:
MULTI-MODAL SHIPPING DESCRIPTIONS ARE PROVIDED FOR INFORMATIONAL PURPOSES
AND DO NOT CONSIDER CONTAINER SIZES. THE PRESENCE OF A SHIPPING DESCRIPTION
FOR A PARTICULAR MODE OF TRANSPORT (SEA, AIR, ETC.), DOES NOT INDICATE THAT
THE PRODUCT IS PACKAGED SUITABLY FOR THAT MODE OF TRANSPORT. ALL PACKAGING
MUST BE REVIEWED FOR SUITABILITY PRIOR TO SHIPMENT, AND COMPLIANCE WITH THE
APPLICABLE REGULATIONS IS THE SOLE RESPONSIBILITY OF THE PERSON OFFERING
THE PRODUCT FOR TRANSPORT. PEOPLE LOADING AND UNLOADING DANGEROUS GOODS
MUST BE TRAINED ON ALL OF THE RISKS DERIVING FROM THE SUBSTANCES AND ON
ALL ACTIONS IN CASE OF EMERGENCY SITUATIONS.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT AVAILABLE.
PROPER SHIPPING NAME: NOT AVAILABLE.
SHIP TYPE: NOT AVAILABLE.
POLLUTION CATEGORY: NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
SARA 313:
SARA 313 (40 CFR 372.45) SUPPLIER NOTIFICATION CAN BE FOUND ON THE
ENVIRONMENTAL DATA SHEET.
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
INTERNATIONAL REGULATIONS:
INTERNATIONAL LISTS:
AUSTRALIA INVENTORY (AICS): NOT DETERMINED.
CHINA INVENTORY (IECSC): NOT DETERMINED.
JAPAN INVENTORY (ENCS): NOT DETERMINED.
JAPAN INVENTORY (ISHL): NOT DETERMINED.
KOREA INVENTORY (KECI): NOT DETERMINED.
MALAYSIA INVENTORY (EHS REGISTER): NOT DETERMINED.
NEW ZEALAND INVENTORY OF CHEMICALS (NZIOC): NOT DETERMINED.
PHILIPPINES INVENTORY (PICCS): NOT DETERMINED.
TAIWAN CHEMICAL SUBSTANCES INVENTORY (TCSI): NOT DETERMINED.
THAILAND INVENTORY: NOT DETERMINED.
TURKEY INVENTORY: NOT DETERMINED.
VIETNAM INVENTORY: NOT DETERMINED.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 3*
FLAMMABILITY 2
PHYSICAL HAZARDS 0
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
FOR MORE INFORMATION ON HMIS(R*) PERSONAL PROTECTIVE EQUIPMENT (PPE) CODES,
CONSULT THE HMIS(R*) IMPLEMENTATION MANUAL.
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS.
ALTHOUGH HMIS(R*) RATINGS AND THE ASSOCIATED LABEL ARE NOT REQUIRED ON SDSS
OR PRODUCTS LEAVING A FACILITY UNDER 29 CFR 1910.1200, THE PREPARER MAY
CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED WITH A FULLY
IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED TRADEMARK AND
SERVICE MARK OF THE AMERICAN COATINGS ASSOCIATION, INC.
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
FLAMMABLE LIQUIDS - CATEGORY 4 ON BASIS OF TEST DATA
SKIN CORROSION/IRRITATION - CATEGORY 2 CALCULATION METHOD
SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 1 CALCULATION METHOD
SKIN SENSITIZATION - CATEGORY 1 CALCULATION METHOD
CARCINOGENICITY - CATEGORY 2 CALCULATION METHOD
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CALCULATION METHOD
(RESPIRATORY TRACT IRRITATION) - CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CALCULATION METHOD
(NARCOTIC EFFECTS) - CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) CALCULATION METHOD
(LUNGS, SKIN) - CATEGORY 1
ASPIRATION HAZARD - CATEGORY 1 CALCULATION METHOD
HISTORY:
DATE OF PRINTING: 5/22/2019
DATE OF ISSUE/DATE OF REVISION: 5/22/2019
DATE OF PREVIOUS ISSUE: 10/29/2018
VERSION: 10
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
IT IS RECOMMENDED THAT EACH CUSTOMER OR RECIPIENT OF THIS SAFETY DATA
SHEET (SDS) STUDY IT CAREFULLY AND CONSULT RESOURCES, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THIS INFORMATION IS
PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE
DATE HEREIN. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. THE
INFORMATION PRESENTED HERE APPLIES ONLY TO THE PRODUCT AS SHIPPED. THE
ADDITION OF ANY MATERIAL CAN CHANGE THE COMPOSITION, HAZARDS AND RISKS OF
THE PRODUCT. PRODUCTS SHALL NOT BE REPACKAGED, MODIFIED, OR TINTED EXCEPT
AS SPECIFICALLY INSTRUCTED BY THE MANUFACTURER, INCLUDING BUT NOT LIMITED
TO THE INCORPORATION OF PRODUCTS NOT SPECIFIED BY THE MANUFACTURER, OR
THE USE OR ADDITION OF PRODUCTS IN PROPORTIONS NOT SPECIFIED BY THE
MANUFACTURER. REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER
BETWEEN VARIOUS LOCATIONS AND JURISDICTIONS. THE CUSTOMER/BUYER/USER IS
RESPONSIBLE TO ENSURE THAT HIS ACTIVITIES COMPLY WITH ALL COUNTRY,
FEDERAL, STATE, PROVINCIAL OR LOCAL LAWS. THE CONDITIONS FOR USE OF THE
PRODUCT ARE NOT UNDER THE CONTROL OF THE MANUFACTURER; THE
CUSTOMER/BUYER/USER IS RESPONSIBLE TO DETERMINE THE CONDITIONS NECESSARY
FOR THE SAFE USE OF THIS PRODUCT. THE CUSTOMER/BUYER/USER SHOULD NOT USE
THE PRODUCT FOR ANY PURPOSE OTHER THAN THE PURPOSE SHOWN IN THE APPLICABLE
SECTION OF THIS SDS WITHOUT FIRST REFERRING TO THE SUPPLIER AND OBTAINING
WRITTEN HANDLING INSTRUCTIONS. DUE TO THE PROLIFERATION OF SOURCES FOR
INFORMATION SUCH AS MANUFACTURER-SPECIFIC SDS, THE MANUFACTURER CANNOT
BE RESPONSIBLE FOR SDSS OBTAINED FROM ANY OTHER SOURCE.
SHW-85-NA-GHS-US