| Common Name: | UNIVERSAL HP ALKYD METAL PRIMER WHITE |
| Manufacturer: | KRYLON PRODUCTS |
| SDS Revision Date: | 6/20/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 52JN54, 52JN55 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
K000S4700
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: KRYLON(R*) UNIVERSAL HP ALKYD METAL PRIMER WHITE
PRODUCT CODE: K000S4700
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
PRODUCT TYPE: LIQUID.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: NOT APPLICABLE.
MANUFACTURER:
KRYLON PRODUCTS GROUP
CLEVELAND, OH 44115
EMERGENCY TELEPHONE NUMBER OF THE COMPANY: (216) 566-2917
PRODUCT INFORMATION TELEPHONE NUMBER: (800) 247-3266
REGULATORY INFORMATION TELEPHONE NUMBER: (216) 566-2902
TRANSPORTATION EMERGENCY TELEPHONE NUMBER: (800) 424-9300
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE LIQUIDS: CATEGORY 3
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
CARCINOGENICITY: CATEGORY 1A
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2
ASPIRATION HAZARD: CATEGORY 1
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN TOXICITY:
12.3%
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
FLAMMABLE LIQUID AND VAPOR.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE CANCER.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE GLOVES. WEAR
EYE OR FACE PROTECTION. WEAR PROTECTIVE CLOTHING. KEEP AWAY FROM HEAT, HOT
SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. NO SMOKING. USE
EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING AND ALL MATERIAL-HANDLING
EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST
STATIC DISCHARGE. KEEP CONTAINER TIGHTLY CLOSED. DO NOT BREATHE VAPOR.
WASH HANDS THOROUGHLY AFTER HANDLING.
RESPONSE: GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER OR
SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE: STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
DANGER:
RAGS, STEEL WOOL, OTHER WASTE SOAKED WITH THIS PRODUCT, AND SANDING
RESIDUE MAY SPONTANEOUSLY CATCH FIRE IF IMPROPERLY DISCARDED. IMMEDIATELY
PLACE RAGS, STEEL WOOL, OTHER WASTE SOAKED WITH THIS PRODUCT, AND SANDING
RESIDUE IN A SEALED, WATER-FILLED, METAL CONTAINER. DISPOSE OF IN
ACCORDANCE WITH LOCAL FIRE REGULATIONS. DELAYED EFFECTS FROM LONG TERM
OVEREXPOSURE. CONTAINS SOLVENTS WHICH CAN CAUSE PERMANENT BRAIN AND
NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING
AND INHALING THE CONTENTS CAN BE HARMFUL OR FATAL.
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. FOR INDUSTRIAL USE
ONLY. ADEQUATE VENTILATION REQUIRED WHEN SANDING OR ABRADING THE DRIED
FILM. IF ADEQUATE VENTILATION CANNOT BE PROVIDED WEAR AN APPROVED
PARTICULATE RESPIRATOR (NIOSH APPROVED). FOLLOW RESPIRATOR MANUFACTURER'S
DIRECTIONS FOR RESPIRATOR USE. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE.
ABRADING OR SANDING OF THE DRY FILM MAY RELEASE CRYSTALLINE SILICA WHICH
HAS BEEN SHOWN TO CAUSE LUNG DAMAGE AND CANCER UNDER LONG TERM EXPOSURE.
PLEASE REFER TO THE SDS FOR ADDITIONAL INFORMATION. KEEP OUT OF REACH OF
CHILDREN. DO NOT TRANSFER CONTENTS TO OTHER CONTAINERS FOR STORAGE.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS NUMBER/OTHER IDENTIFIERS:
INGREDIENT NAME % BY WEIGHT CAS NUMBER
TITANIUM DIOXIDE 9.98 13463-67-7
XYLENE 8.59 1330-20-7
METHYL N-AMYL KETONE 6.53 110-43-0
ETHYLBENZENE 1.56 100-41-4
METHYL N-PROPYL KETONE 1.25 107-87-9
METHYL ISOBUTYL KETONE 0.22 108-10-1
CRYSTALLINE SILICA, RESPIRABLE POWDER 0.17 14808-60-7
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS
DUE TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH AND HENCE REQUIRE REPORTING IN THIS
SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE
UPPER AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE
TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION. IF UNCONSCIOUS, PLACE
IN RECOVERY POSITION AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN
OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR
WAISTBAND.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING
IT, OR WEAR GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL
ATTENTION. WASH CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. WASH
OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH AIR
AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL HAS
BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES
OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS VOMITING MAY
BE DANGEROUS. ASPIRATION HAZARD IF SWALLOWED. CAN ENTER LUNGS AND CAUSE
DAMAGE. DO NOT INDUCE VOMITING. IF VOMITING OCCURS, THE HEAD SHOULD BE
KEPT LOW SO THAT VOMIT DOES NOT ENTER THE LUNGS. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION
AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN
TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT: NO SPECIFIC DATA.
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: NAUSEA OR VOMITING
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY
IF LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT
MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE DRY CHEMICAL, CO2, WATER SPRAY (FOG) OR FOAM.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER JET.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
FLAMMABLE LIQUID AND VAPOR. IN A FIRE OR IF HEATED, A PRESSURE INCREASE
WILL OCCUR AND THE CONTAINER MAY BURST, WITH THE RISK OF A SUBSEQUENT
EXPLOSION. THE VAPOR/GAS IS HEAVIER THAN AIR AND WILL SPREAD ALONG THE
GROUND. VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL A
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. RUNOFF TO
SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
PHOSPHORUS OXIDES
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE AREA
IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
SHUT OFF ALL IGNITION SOURCES. NO FLARES, SMOKING OR FLAMES IN HAZARD AREA.
AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE
ALSO THE INFORMATION IN "FOR NONEMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. DILUTE WITH WATER AND MOP UP IF
WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE, ABSORB WITH AN INERT
DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER. DISPOSE
OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH
SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN
AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND,
EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR
DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF VIA
A LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY
POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). AVOID
EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL
SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT GET IN EYES OR ON
SKIN OR CLOTHING. DO NOT BREATHE VAPOR OR MIST. DO NOT SWALLOW. USE ONLY
WITH ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION
IS INADEQUATE. DO NOT ENTER STORAGE AREAS AND CONFINED SPACES UNLESS
ADEQUATELY VENTILATED. KEEP IN THE ORIGINAL CONTAINER OR AN APPROVED
ALTERNATIVE MADE FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT
IN USE. STORE AND USE AWAY FROM HEAT, SPARKS, OPEN FLAME OR ANY OTHER
IGNITION SOURCE. USE EXPLOSION-PROOF ELECTRICAL (VENTILATING, LIGHTING
AND MATERIAL HANDLING) EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE
PRECAUTIONARY MEASURES AGAINST ELECTROSTATIC DISCHARGES. EMPTY CONTAINERS
RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS. DO NOT REUSE CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN A SEGREGATED AND
APPROVED AREA. STORE IN ORIGINAL CONTAINER PROTECTED FROM DIRECT SUNLIGHT
IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10) AND FOOD AND DRINK. STORE LOCKED UP. ELIMINATE ALL
IGNITION SOURCES. SEPARATE FROM OXIDIZING MATERIALS. KEEP CONTAINER TIGHTLY
CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS THAT HAVE BEEN OPENED
MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT LEAKAGE. DO NOT
STORE IN UNLABELED CONTAINERS. USE APPROPRIATE CONTAINMENT TO AVOID
ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS (OSHA UNITED STATES):
INGREDIENT NAME EXPOSURE LIMITS
TITANIUM DIOXIDE ACGIH TLV (UNITED STATES, 3/2015).
TWA: 10 MG/M3 8 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
XYLENE ACGIH TLV (UNITED STATES, 3/2015).
TWA: 100 PPM 8 HOURS.
TWA: 434 MG/M3 8 HOURS.
STEL: 150 PPM 15 MINUTES.
STEL: 651 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
METHYL N-AMYL KETONE ACGIH TLV (UNITED STATES, 3/2015).
TWA: 50 PPM 8 HOURS.
TWA: 233 MG/M3 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 100 PPM 10 HOURS.
TWA: 465 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 100 PPM 8 HOURS.
TWA: 465 MG/M3 8 HOURS.
ETHYLBENZENE ACGIH TLV (UNITED STATES, 3/2015).
TWA: 20 PPM 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 100 PPM 10 HOURS.
TWA: 435 MG/M3 10 HOURS.
STEL: 125 PPM 15 MINUTES.
STEL: 545 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
METHYL N-PROPYL KETONE NIOSH REL (UNITED STATES, 10/2013).
TWA: 150 PPM 10 HOURS.
TWA: 530 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 200 PPM 8 HOURS.
TWA: 700 MG/M3 8 HOURS.
ACGIH TLV (UNITED STATES, 3/2015).
STEL: 150 PPM 15 MINUTES.
METHYL ISOBUTYL KETONE ACGIH TLV (UNITED STATES, 3/2015).
TWA: 20 PPM 8 HOURS.
STEL: 75 PPM 15 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 50 PPM 10 HOURS.
TWA: 205 MG/M3 10 HOURS.
STEL: 75 PPM 15 MINUTES.
STEL: 300 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 100 PPM 8 HOURS.
TWA: 410 MG/M3 8 HOURS.
CRYSTALLINE SILICA, OSHA PEL Z3 (UNITED STATES, 2/2013).
RESPIRABLE POWDER TWA: 250 MPPCF / (%SiO2+5) 8 HOURS.
FORM: RESPIRABLE
TWA: 10 MG/M3 / (%SiO2+2) 8 HOURS.
FORM: RESPIRABLE
ACGIH TLV (UNITED STATES, 3/2015).
TWA: 0.025 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
NIOSH REL (UNITED STATES, 10/2013).
TWA: 0.05 MG/M3 10 HOURS.
FORM: RESPIRABLE DUST
OCCUPATIONAL EXPOSURE LIMITS (CANADA):
INGREDIENT NAME EXPOSURE LIMITS
XYLENE CA ALBERTA PROVINCIAL (CANADA, 4/2009).
8 HRS OEL: 100 PPM 8 HOURS.
15 MIN OEL: 651 MG/M3 15 MINUTES.
15 MIN OEL: 150 PPM 15 MINUTES.
8 HRS OEL: 434 MG/M3 8 HOURS.
CA BRITISH COLUMBIA PROVINCIAL (CANADA, 5/2015).
TWA: 100 PPM 8 HOURS.
STEL: 150 PPM 15 MINUTES.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 100 PPM 8 HOURS.
TWAEV: 434 MG/M3 8 HOURS.
STEV: 150 PPM 15 MINUTES.
STEV: 651 MG/M3 15 MINUTES.
CA ONTARIO PROVINCIAL (CANADA, 7/2015).
STEL: 150 PPM 15 MINUTES.
TWA: 100 PPM 8 HOURS.
CA SASKATCHEWAN PROVINCIAL (CANADA, 7/2013).
STEL: 150 PPM 15 MINUTES.
TWA: 100 PPM 8 HOURS.
ETHYLBENZENE CA ALBERTA PROVINCIAL (CANADA, 4/2009).
8 HRS OEL: 100 PPM 8 HOURS.
8 HRS OEL: 434 MG/M3 8 HOURS.
15 MIN OEL: 543 MG/M3 15 MINUTES.
15 MIN OEL: 125 PPM 15 MINUTES.
CA BRITISH COLUMBIA PROVINCIAL (CANADA, 5/2015).
TWA: 20 PPM 8 HOURS.
CA ONTARIO PROVINCIAL (CANADA, 7/2015).
TWA: 20 PPM 8 HOURS.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 100 PPM 8 HOURS.
TWAEV: 434 MG/M3 8 HOURS.
STEV: 125 PPM 15 MINUTES.
STEV: 543 MG/M3 15 MINUTES.
CA SASKATCHEWAN PROVINCIAL (CANADA, 7/2013).
STEL: 125 PPM 15 MINUTES.
TWA: 100 PPM 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS. THE
ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS
BELOW ANY LOWER EXPLOSIVE LIMITS. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTISTATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
BASED ON THE HAZARD AND POTENTIAL FOR EXPOSURE, SELECT A RESPIRATOR THAT
MEETS THE APPROPRIATE STANDARD OR CERTIFICATION. RESPIRATORS MUST BE USED
ACCORDING TO A RESPIRATORY PROTECTION PROGRAM TO ENSURE PROPER FITTING,
TRAINING, AND OTHER IMPORTANT ASPECTS OF USE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: WHITE.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT: NOT AVAILABLE.
BOILING POINT: 102 DEG. C (215.6 DEG. F)
FLASH POINT:
CLOSED CUP: 37 DEG. C (98.6 DEG. F) [PENSKY-MARTENS CLOSED CUP]
EVAPORATION RATE: 2.3 (BUTYL ACETATE = 1)
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 1%
UPPER: 8.7%
VAPOR PRESSURE: 0.49 KPA (3.706 MMHg) [AT 20 DEG. C]
VAPOR DENSITY: 3.45 [AIR = 1]
RELATIVE DENSITY: 1.65
SOLUBILITY: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (ROOM TEMPERATURE): <0.205 CM2/S (<20.5 CST)
KINEMATIC (40 DEG. C (104 DEG. F)): <0.205 CM2/S (<20.5 CST)
MOLECULAR WEIGHT: NOT APPLICABLE.
AEROSOL PRODUCT:
HEAT OF COMBUSTION: 6.744 KJ/G
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME). DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT OR
SOURCES OF IGNITION. DO NOT ALLOW VAPOR TO ACCUMULATE IN LOW OR CONFINED
AREAS.
INCOMPATIBLE MATERIALS:
REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS: OXIDIZING MATERIALS
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
XYLENE LC50 INHALATION RAT 5000 PPM 4 HOURS
GAS.
LD50 ORAL RAT 4300 MG/KG
METHYL N-AMYL KETONE LD50 ORAL RAT 1600 MG/KG
ETHYLBENZENE LD50 DERMAL RABBIT >5000 MG/KG
LD50 ORAL RAT 3500 MG/KG
METHYL N-PROPYL KETONE LD50 DERMAL RABBIT 6500 MG/KG
LD50 ORAL RAT 1600 MG/KG
METHYL ISOBUTYL KETONE LD50 ORAL RAT 2080 MG/KG
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVATION
NAME
TITANIUM DIOXIDE SKIN: HUMAN 72 HOURS
MILD 300 MICROGRAMS
IRRITANT INTERMITTENT
XYLENE EYES: RABBIT 87 MILLIGRAMS
MILD
IRRITANT
EYES: RABBIT 24 HOURS
SEVERE 5 MILLIGRAMS
IRRITANT
SKIN: RAT 8 HOURS
MILD 60 MICROLITERS
IRRITANT
SKIN: RABBIT 24 HOURS
MODERATE 500 MILLIGRAMS
IRRITANT
SKIN: RABBIT 100 PERCENT
MODERATE
IRRITANT
METHYL N-AMYL SKIN: RABBIT 24 HOURS
KETONE MILD 14 MILLIGRAMS
IRRITANT
ETHYLBENZENE EYES: RABBIT 500 MILLIGRAMS
SEVERE
IRRITANT
SKIN: RABBIT 24 HOURS
MILD 15 MILLIGRAMS
IRRITANT
METHYL N-PROPYL SKIN: RABBIT 405 MILLIGRAMS
KETONE MILD
IRRITANT
METHYL ISOBUTYL EYES: RABBIT 24 HOURS
KETONE MODERATE 100 MICROLITERS
IRRITANT
EYES: RABBIT 40 MILLIGRAMS
SEVERE
IRRITANT
SKIN: RABBIT 24 HOURS
MILD 500 MILLIGRAMS
IRRITANT
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
TITANIUM DIOXIDE 2B
XYLENE 3
ETHYLBENZENE 2B
METHYL ISOBUTYL KETONE 2B
CRYSTALLINE SILICA, RESPIRABLE 1 KNOWN TO BE A HUMAN
POWDER CARCINOGEN.
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
XYLENE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
METHYL N-AMYL KETONE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
ETHYLBENZENE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
METHYL N-PROPYL CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
KETONE IRRITATION AND
NARCOTIC EFFECTS
METHYL ISOBUTYL CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
KETONE IRRITATION AND
NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
XYLENE CATEGORY 2 NOT DETERMINED NOT DETERMINED
METHYL N-AMYL KETONE CATEGORY 2 NOT DETERMINED NOT DETERMINED
ETHYLBENZENE CATEGORY 2 NOT DETERMINED NOT DETERMINED
METHYL N-PROPYL KETONE CATEGORY 2 NOT DETERMINED NOT DETERMINED
METHYL ISOBUTYL KETONE CATEGORY 2 NOT DETERMINED NOT DETERMINED
CRYSTALLINE SILICA, CATEGORY 1 INHALATION NOT DETERMINED
RESPIRABLE POWDER
ASPIRATION HAZARD:
NAME RESULT
XYLENE ASPIRATION HAZARD - CATEGORY 1
ETHYLBENZENE ASPIRATION HAZARD - CATEGORY 1
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT: NO SPECIFIC DATA.
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: NAUSEA OR VOMITING
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
CARCINOGENICITY:
MAY CAUSE CANCER. RISK OF CANCER DEPENDS ON DURATION AND LEVEL OF EXPOSURE.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 12002.5 MG/KG
INHALATION (GASES) 51073.2 PPM
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
TITANIUM DIOXIDE ACUTE LC50: FISH - FUNDULUS 96 HOURS
>1000000 (MICRO)G/L HETEROCLITUS
MARINE WATER
XYLENE ACUTE LC50: CRUSTACEANS - 48 HOURS
8500 (MICRO)G/L PALAEMONETES PUGIO
MARINE WATER
ACUTE LC50: FISH - PIMEPHALES 96 HOURS
13400 (MICRO)G/L PROMELAS
FRESH WATER
METHYL N-AMYL KETONE ACUTE LC50: FISH - PIMEPHALES 96 HOURS
131000 (MICRO)G/L PROMELAS
FRESH WATER
ETHYLBENZENE ACUTE EC50: ALGAE - 72 HOURS
4600 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: ALGAE - 96 HOURS
3600 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: CRUSTACEANS - 48 HOURS
6530 (MICRO)G/L ARTEMIA
FRESH WATER SP. - NAUPLII
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
2930 (MICRO)G/L MAGNA - NEONATE
FRESH WATER
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
4200 (MICRO)G/L MYKISS
FRESH WATER
METHYL N-PROPYL ACUTE LC50: FISH - PIMEPHALES 96 HOURS
KETONE 1240000 (MICRO)G/L PROMELAS
FRESH WATER
METHYL ISOBUTYL ACUTE LC50: FISH - PIMEPHALES 96 HOURS
KETONE 505000 (MICRO)G/L PROMELAS
FRESH WATER
CHRONIC NOEC: DAPHNIA - DAPHNIA 21 DAYS
78 MG/L MAGNA
FRESH WATER
CHRONIC NOEC: FISH - PIMEPHALES 33 DAYS
168 MG/L PROMELAS - EMBRYO
FRESH WATER
PERSISTENCE AND DEGRADABILITY:
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
XYLENE READILY
METHYL N-AMYL KETONE READILY
ETHYLBENZENE READILY
METHYL ISOBUTYL KETONE READILY
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
XYLENE 8.1 TO 25.9 LOW
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY
BE CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS
CONTAINER MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN
HANDLING EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. VAPOR FROM PRODUCT
RESIDUES MAY CREATE A HIGHLY FLAMMABLE OR EXPLOSIVE ATMOSPHERE INSIDE THE
CONTAINER. DO NOT CUT, WELD OR GRIND USED CONTAINERS UNLESS THEY HAVE BEEN
CLEANED THOROUGHLY INTERNALLY. AVOID DISPERSAL OF SPILLED MATERIAL AND
RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
UN NUMBER UN1263 UN1263 UN1263
UN PROPER SHIPPING PAINT PAINT PAINT
NAME
TRANSPORT HAZARD 3 3 3
CLASS(ES)
FLAMMABLE LIQUID, CLASS 3, CLASS 3,
CLASS/DIVISION FLAMMABLE FLAMMABLE
3.1, 3.2, 3.3 LIQUIDS LIQUIDS
PACKING GROUP III III III
ENVIRONMENTAL NO. NO. NO.
HAZARDS
ADDITIONAL PRODUCT
INFORMATION CLASSIFIED AS
PER THE
FOLLOWING
SECTIONS OF THE
TRANSPORTATION
OF DANGEROUS
GOODS
REGULATIONS:
2.18-2.19
(CLASS 3).
ERG NO.: 128 ERG NO.: 128 ERG NO.: 128
IATA IMDG
UN NUMBER UN1263 UN1263
UN PROPER SHIPPING NAME PAINT PAINT
TRANSPORT HAZARD CLASS(ES) 3 3
CLASS 3, CLASS 3 - FLAMMABLE
FLAMMABLE LIQUIDS LIQUIDS
PACKING GROUP III III
ENVIRONMENTAL HAZARDS NO. NO.
ADDITIONAL INFORMATION EMERGENCY SCHEDULES
(EMS): F-E, S-E
SPECIAL PRECAUTIONS FOR USER:
MULTI-MODAL SHIPPING DESCRIPTIONS ARE PROVIDED FOR INFORMATIONAL PURPOSES
AND DO NOT CONSIDER CONTAINER SIZES. THE PRESENCE OF A SHIPPING DESCRIPTION
FOR A PARTICULAR MODE OF TRANSPORT (SEA, AIR, ETC.), DOES NOT INDICATE THAT
THE PRODUCT IS PACKAGED SUITABLY FOR THAT MODE OF TRANSPORT. ALL PACKAGING
MUST BE REVIEWED FOR SUITABILITY PRIOR TO SHIPMENT, AND COMPLIANCE WITH THE
APPLICABLE REGULATIONS IS THE SOLE RESPONSIBILITY OF THE PERSON OFFERING
THE PRODUCT FOR TRANSPORT. PEOPLE LOADING AND UNLOADING DANGEROUS GOODS
MUST BE TRAINED ON ALL OF THE RISKS DERIVING FROM THE SUBSTANCES AND ON
ALL ACTIONS IN CASE OF EMERGENCY SITUATIONS.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT AVAILABLE.
PROPER SHIPPING NAME: NOT AVAILABLE.
SHIP TYPE: NOT AVAILABLE.
POLLUTION CATEGORY: NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
SARA 313:
SARA 313 (40 CFR 372.45) SUPPLIER NOTIFICATION CAN BE FOUND ON THE
ENVIRONMENTAL DATA SHEET.
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 2*
FLAMMABILITY 3
PHYSICAL HAZARDS 0
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON SDSS UNDER 29 CFR 1910.1200,
THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED MARK
OF THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA). HMIS(R*) MATERIALS
MAY BE PURCHASED EXCLUSIVELY FROM J. J. KELLER (800) 327-6868.
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
FLAMMABLE LIQUIDS - CATEGORY 3 ON BASIS OF TEST DATA
SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2A CALCULATION METHOD
CARCINOGENICITY - CATEGORY 1A CALCULATION METHOD
SPECIFIC TARGET ORGAN TOXICITY CALCULATION METHOD
(REPEATED EXPOSURE) - CATEGORY 2
ASPIRATION HAZARD - CATEGORY 1 CALCULATION METHOD
HISTORY:
DATE OF PRINTING: 6/20/2016
DATE OF ISSUE/DATE OF REVISION: 6/20/2016
DATE OF PREVIOUS ISSUE: 6/4/2016
VERSION: 3.01
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
NOTICE TO READER:
IT IS RECOMMENDED THAT EACH CUSTOMER OR RECIPIENT OF THIS SAFETY DATA
SHEET (SDS) STUDY IT CAREFULLY AND CONSULT RESOURCES, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THIS INFORMATION IS
PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE
DATE HEREIN. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. THE
INFORMATION PRESENTED HERE APPLIES ONLY TO THE PRODUCT AS SHIPPED. THE
ADDITION OF ANY MATERIAL CAN CHANGE THE COMPOSITION, HAZARDS AND RISKS OF
THE PRODUCT. PRODUCTS SHALL NOT BE REPACKAGED, MODIFIED, OR TINTED EXCEPT
AS SPECIFICALLY INSTRUCTED BY SHERWIN-WILLIAMS, INCLUDING BUT NOT LIMITED
TO THE INCORPORATION OF NON SHERWIN-WILLIAMS PRODUCTS OR THE USE OR
ADDITION OF PRODUCTS IN PROPORTIONS NOT SPECIFIED BY SHERWIN-WILLIAMS.
REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN
VARIOUS LOCATIONS AND JURISDICTIONS. THE CUSTOMER/BUYER/USER IS RESPONSIBLE
TO ENSURE THAT HIS ACTIVITIES COMPLY WITH ALL COUNTRY, FEDERAL, STATE,
PROVINCIAL OR LOCAL LAWS. THE CONDITIONS FOR USE OF THE PRODUCT ARE NOT
UNDER THE CONTROL OF THE MANUFACTURER; THE CUSTOMER/BUYER/USER IS
RESPONSIBLE TO DETERMINE THE CONDITIONS NECESSARY FOR THE SAFE USE OF THIS
PRODUCT. THE CUSTOMER/BUYER/USER SHOULD NOT USE THE PRODUCT FOR ANY PURPOSE
OTHER THAN THE PURPOSE SHOWN IN THE APPLICABLE SECTION OF THIS SDS WITHOUT
FIRST REFERRING TO THE SUPPLIER AND OBTAINING WRITTEN HANDLING
INSTRUCTIONS. DUE TO THE PROLIFERATION OF SOURCES FOR INFORMATION SUCH
AS MANUFACTURER-SPECIFIC SDS, THE MANUFACTURER CANNOT BE RESPONSIBLE FOR
SDSS OBTAINED FROM ANY OTHER SOURCE.