| Common Name: | PROVON TEARLESS SHAMPOO & BODY WASH |
| Manufacturer: | GOJO INDUSTRIES |
| SDS Revision Date: | 3/31/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 52JT34, 5MZT6, 5MZT7, 5MZT9, 5MZU0 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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GOJO(R*)
SAFETY DATA SHEET
PROVON(R*) TEARLESS SHAMPOO & BODY WASH
VERSION: 1.0
REVISION DATE: 03/31/2015
MSDS NUMBER: 87192-00001
DATE OF LAST ISSUE:
DATE OF FIRST ISSUE: 03/31/2015
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: PROVON(R*) TEARLESS SHAMPOO & BODY WASH
MANUFACTURER OR SUPPLIER'S DETAILS:
COMPANY NAME OF SUPPLIER: GOJO INDUSTRIES, INC.
ADDRESS:
ONE GOJO PLAZA
SUITE 500
AKRON OH 44311
TELEPHONE: 1 (330) 255-6000
EMERGENCY TELEPHONE: 1-800-424-9300 CHEMTREC
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: HAIR CARE, SHAMPOOS
RESTRICTIONS ON USE:
THIS IS A PERSONAL CARE OR COSMETIC PRODUCT THAT IS SAFE FOR CONSUMERS AND
OTHER USERS UNDER NORMAL AND REASONABLY FORESEEABLE USE. COSMETICS AND
CONSUMER PRODUCTS, SPECIFICALLY DEFINED BY REGULATIONS AROUND THE WORLD,
ARE EXEMPT FROM THE REQUIREMENT OF AN SDS FOR THE CONSUMER. WHILE THIS
MATERIAL IS NOT CONSIDERED HAZARDOUS, THIS SDS CONTAINS VALUABLE
INFORMATION CRITICAL TO THE SAFE HANDLING AND PROPER USE OF THE PRODUCT FOR
INDUSTRIAL WORKPLACE CONDITIONS AS WELL AS UNUSUAL AND UNINTENDED EXPOSURES
SUCH AS LARGE SPILLS. THIS SDS SHOULD BE RETAINED AND AVAILABLE FOR
EMPLOYEES AND OTHER USERS OF THIS PRODUCT. FOR SPECIFIC INTENDED-USE
GUIDANCE, PLEASE REFER TO THE INFORMATION PROVIDED ON THE PACKAGE OR
INSTRUCTION SHEET.
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
EYE IRRITATION: CATEGORY 2A
GHS LABEL ELEMENT:
HAZARD PICTOGRAMS: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
H319: CAUSES SERIOUS EYE IRRITATION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P264: WASH SKIN THOROUGHLY AFTER HANDLING.
P280: WEAR EYE PROTECTION/FACE PROTECTION.
RESPONSE:
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P337 + P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
OTHER HAZARDS: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
HAZARDOUS INGREDIENTS:
CHEMICAL NAME CAS-NO. CONCENTRATION (%)
COCOAMIDOPROPYL BETAINE 61789-40-0 >=1 - <5
SODIUM 2-[2-[2-(TRIDECYLOXY) 25446-78-0 >=1 - <5
ETHOXY]ETHOXY]ETHYL SULPHATE
ACETIC ACID, CHLORO-, SODIUM SALT, 68608-66-2 >=1 - <5
REACTION PRODUCTS WITH
4,5-DIHYDRO-2-UNDECYL-
1H-IMIDAZOLE-1-ETHANOL AND
SODIUM HYDROXIDE
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
IN THE CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY.
WHEN SYMPTOMS PERSIST OR IN ALL CASES OF DOUBT SEEK MEDICAL ADVICE.
IF INHALED:
IF INHALED, REMOVE TO FRESH AIR.
GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
IN CASE OF SKIN CONTACT:
WASH WITH WATER AND SOAP AS A PRECAUTION.
GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
IN CASE OF EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES.
IF EASY TO DO, REMOVE CONTACT LENS, IF WORN.
GET MEDICAL ATTENTION.
IF SWALLOWED:
IF SWALLOWED, DO NOT INDUCE VOMITING.
GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
RINSE MOUTH THOROUGHLY WITH WATER.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
CAUSES SERIOUS EYE IRRITATION.
PROTECTION OF FIRST-AIDERS:
FIRST AID RESPONDERS SHOULD PAY ATTENTION TO SELF-PROTECTION, AND USE THE
RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT WHEN THE POTENTIAL FOR EXPOSURE
EXISTS.
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
| SECTION 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY
ALCOHOL-RESISTANT FOAM
DRY CHEMICAL
CARBON DIOXIDE (CO2)
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS DURING FIRE FIGHTING:
EXPOSURE TO COMBUSTION PRODUCTS MAY BE A HAZARD TO HEALTH.
HAZARDOUS COMBUSTION PRODUCTS:
NONE KNOWN.
CARBON OXIDES
NITROGEN OXIDES (NOX)
METAL OXIDES
CHLORINE COMPOUNDS
SPECIFIC EXTINGUISHING METHODS:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
USE WATER SPRAY TO COOL UNOPENED CONTAINERS.
REMOVE UNDAMAGED CONTAINERS FROM FIRE AREA IF IT IS SAFE TO DO SO.
EVACUATE AREA.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
USE PERSONAL PROTECTIVE EQUIPMENT.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT.
FOLLOW SAFE HANDLING ADVICE AND PERSONAL PROTECTIVE EQUIPMENT
RECOMMENDATIONS.
ENVIRONMENTAL PRECAUTIONS:
DISCHARGE INTO THE ENVIRONMENT MUST BE AVOIDED.
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
PREVENT SPREADING OVER A WIDE AREA (E.G. BY CONTAINMENT OR OIL BARRIERS).
RETAIN AND DISPOSE OF CONTAMINATED WASH WATER.
LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE
CONTAINED.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SOAK UP WITH INERT ABSORBENT MATERIAL.
FOR LARGE SPILLS, PROVIDE DIKING OR OTHER APPROPRIATE CONTAINMENT TO KEEP
MATERIAL FROM SPREADING. IF DIKED MATERIAL CAN BE PUMPED, STORE RECOVERED
MATERIAL IN APPROPRIATE CONTAINER.
CLEAN UP REMAINING MATERIALS FROM SPILL WITH SUITABLE ABSORBENT.
LOCAL OR NATIONAL REGULATIONS MAY APPLY TO RELEASES AND DISPOSAL OF THIS
MATERIAL, AS WELL AS THOSE MATERIALS AND ITEMS EMPLOYED IN THE CLEANUP OF
RELEASES. YOU WILL NEED TO DETERMINE WHICH REGULATIONS ARE APPLICABLE.
SECTIONS 13 AND 15 OF THIS SDS PROVIDE INFORMATION REGARDING CERTAIN LOCAL
OR NATIONAL REQUIREMENTS.
| SECTION 7. HANDLING AND STORAGE | |
TECHNICAL MEASURES:
SEE ENGINEERING MEASURES UNDER EXPOSURE
CONTROLS/PERSONAL PROTECTION SECTION.
LOCAL/TOTAL VENTILATION: USE ONLY WITH ADEQUATE VENTILATION.
ADVICE ON SAFE HANDLING:
AVOID INHALATION OF VAPOR OR MIST.
DO NOT SWALLOW. DO NOT GET IN EYES.
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN.
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
TAKE CARE TO PREVENT SPILLS, WASTE AND MINIMIZE RELEASE TO THE ENVIRONMENT.
CONDITIONS FOR SAFE STORAGE:
KEEP IN PROPERLY LABELED CONTAINERS.
STORE IN ACCORDANCE WITH THE PARTICULAR NATIONAL REGULATIONS.
MATERIALS TO AVOID:
DO NOT STORE WITH THE FOLLOWING PRODUCT TYPES:
STRONG OXIDIZING AGENTS
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENTS WITH WORKPLACE CONTROL PARAMETERS:
CONTAINS NO SUBSTANCES WITH OCCUPATIONAL EXPOSURE LIMIT VALUES.
HAZARDOUS COMPONENTS WITHOUT WORKPLACE CONTROL PARAMETERS:
INGREDIENTS CAS-NO.
COCOAMIDOPROPYL BETAINE 61789-40-0
SODIUM 2-[2-[2-(TRIDECYLOXY)ETHOXY]ETHOXY]ETHYL 25446-78-0
SULPHATE
ACETIC ACID, CHLORO-, SODIUM 68608-66-2
SALT, REACTION PRODUCTS WITH 4,5-DIHYDRO-
2-UNDECYL-1H-IMIDAZOLE-1-ETHANOL AND SODIUM
HYDROXIDE
ENGINEERING MEASURES:
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS.
MINIMIZE WORKPLACE EXPOSURE CONCENTRATIONS.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
GENERAL AND LOCAL EXHAUST VENTILATION IS RECOMMENDED TO MAINTAIN VAPOR
EXPOSURES BELOW RECOMMENDED LIMITS. WHERE CONCENTRATIONS ARE ABOVE
RECOMMENDED LIMITS OR ARE UNKNOWN, APPROPRIATE RESPIRATORY PROTECTION
SHOULD BE WORN. FOLLOW OSHA RESPIRATOR REGULATIONS (29 CFR 1910.134) AND
USE NIOSH/MSHA APPROVED RESPIRATORS. PROTECTION PROVIDED BY AIR PURIFYING
RESPIRATORS AGAINST EXPOSURE TO ANY HAZARDOUS CHEMICAL IS LIMITED. USE A
POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR
UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE UNKNOWN, OR ANY OTHER
CIRCUMSTANCE WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
HAND PROTECTION:
MATERIAL: IMPERVIOUS GLOVES
REMARKS:
CHOOSE GLOVES TO PROTECT HANDS AGAINST CHEMICALS DEPENDING ON THE
CONCENTRATION SPECIFIC TO PLACE OF WORK. BREAKTHROUGH TIME IS NOT
DETERMINED FOR THE PRODUCT. CHANGE GLOVES OFTEN! FOR SPECIAL APPLICATIONS,
WE RECOMMEND CLARIFYING THE RESISTANCE TO CHEMICALS OF THE AFOREMENTIONED
PROTECTIVE GLOVES WITH THE GLOVE MANUFACTURER. WASH HANDS BEFORE BREAKS AND
AT THE END OF WORKDAY.
EYE PROTECTION:
WEAR THE FOLLOWING PERSONAL PROTECTIVE EQUIPMENT: SAFETY GOGGLES
SKIN AND BODY PROTECTION:
SELECT APPROPRIATE PROTECTIVE CLOTHING BASED ON CHEMICAL RESISTANCE DATA
AND AN ASSESSMENT OF THE LOCAL EXPOSURE POTENTIAL.
SKIN CONTACT MUST BE AVOIDED BY USING IMPERVIOUS PROTECTIVE CLOTHING
(GLOVES, APRONS, BOOTS, ETC).
HYGIENE MEASURES:
ENSURE THAT EYE FLUSHING SYSTEMS AND SAFETY SHOWERS ARE LOCATED CLOSE TO
THE WORKING PLACE. WHEN USING DO NOT EAT, DRINK OR SMOKE. WASH CONTAMINATED
CLOTHING BEFORE RE-USE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
COLOR: CLEAR, BLUE, GREEN
ODOR: FRUITY
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 5.0 - 7.0
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
INITIAL BOILING POINT AND BOILING RANGE: NO DATA AVAILABLE
FLASH POINT: >100 DEG. C
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.00 G/CM3
SOLUBILITY(IES):
WATER SOLUBILITY: SOLUBLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT APPLICABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED SELF-REACTIVE.
VISCOSITY:
VISCOSITY, KINEMATIC: 1,000 - 20,000 MM2/S (20 DEG. C)
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
OXIDIZING PROPERTIES:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS OXIDIZING.
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NOT CLASSIFIED AS A REACTIVITY HAZARD.
CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: CAN REACT WITH STRONG OXIDIZING AGENTS.
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS
HAZARDOUS DECOMPOSITION PRODUCTS:
NO HAZARDOUS DECOMPOSITION PRODUCTS ARE KNOWN.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION
SKIN CONTACT
INGESTION
EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
ACUTE ORAL TOXICITY:
ACUTE TOXICITY ESTIMATE: >5,000 MG/KG
METHOD: CALCULATION METHOD
INGREDIENTS:
COCOAMIDOPROPYL BETAINE:
ACUTE ORAL TOXICITY:
LD50: >5,000 MG/KG
METHOD: OECD TEST GUIDELINE 401
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
ACUTE DERMAL TOXICITY:
LD50 (RAT): >2,000 MG/KG
METHOD: OECD TEST GUIDELINE 402
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE DERMAL TOXICITY
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
SODIUM 2-[2-[2-(TRIDECYLOXY)ETHOXY]ETHOXY]ETHYL SULPHATE:
ACUTE ORAL TOXICITY:
LD50 (RAT): >5,000 MG/KG
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >2,000 MG/KG
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE DERMAL TOXICITY
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
ACETIC ACID, CHLORO-, SODIUM SALT, REACTION PRODUCTS WITH
4,5-DIHYDRO-2-UNDECYL-1H-IMIDAZOLE-1-ETHANOL AND SODIUM HYDROXIDE:
ACUTE ORAL TOXICITY:
LD50 (RAT): 3,422 MG/KG
ACUTE DERMAL TOXICITY:
LD50 (RAT): >5,000 MG/KG
METHOD: OECD TEST GUIDELINE 402
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
SKIN CORROSION/IRRITATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
RESULT: NO SKIN IRRITATION
INGREDIENTS:
SODIUM 2-[2-[2-(TRIDECYLOXY)ETHOXY]ETHOXY]ETHYL SULPHATE:
SPECIES: RABBIT
RESULT: SKIN IRRITATION
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
ACETIC ACID, CHLORO-, SODIUM SALT, REACTION PRODUCTS WITH
4,5-DIHYDRO-2-UNDECYL-1H-IMIDAZOLE-1-ETHANOL AND SODIUM HYDROXIDE:
SPECIES: RABBIT
METHOD: OECD TEST GUIDELINE 404
RESULT: NO SKIN IRRITATION
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
PRODUCT:
RESULT: IRRITATION TO EYES, REVERSING WITHIN 21 DAYS
INGREDIENTS:
COCOAMIDOPROPYL BETAINE:
SPECIES: RABBIT
RESULT: IRREVERSIBLE EFFECTS ON THE EYE
METHOD: OECD TEST GUIDELINE 405
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
SODIUM 2-[2-[2-(TRIDECYLOXY)ETHOXY]ETHOXY]ETHYL SULPHATE:
SPECIES: RABBIT
RESULT: IRREVERSIBLE EFFECTS ON THE EYE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
ACETIC ACID, CHLORO-, SODIUM SALT, REACTION PRODUCTS WITH
4,5-DIHYDRO-2-UNDECYL-1H-IMIDAZOLE-1-ETHANOL AND SODIUM HYDROXIDE:
SPECIES: RABBIT
RESULT: IRRITATION TO EYES, REVERSING WITHIN 21 DAYS
METHOD: OECD TEST GUIDELINE 405
RESPIRATORY OR SKIN SENSITIZATION:
SKIN SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
RESPIRATORY SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
ASSESSMENT: DOES NOT CAUSE SKIN SENSITIZATION.
INGREDIENTS:
COCOAMIDOPROPYL BETAINE:
TEST TYPE: MAXIMIZATION TEST (GPMT)
ROUTES OF EXPOSURE: SKIN CONTACT
SPECIES: GUINEA PIG
RESULT: NEGATIVE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
SODIUM 2-[2-[2-(TRIDECYLOXY)ETHOXY]ETHOXY]ETHYL SULPHATE:
TEST TYPE: MAXIMIZATION TEST (GPMT)
ROUTES OF EXPOSURE: SKIN CONTACT
SPECIES: GUINEA PIG
METHOD: OECD TEST GUIDELINE 406
RESULT: NEGATIVE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
ACETIC ACID, CHLORO-, SODIUM SALT, REACTION PRODUCTS WITH
4,5-DIHYDRO-2-UNDECYL-1H-IMIDAZOLE-1-ETHANOL AND SODIUM HYDROXIDE:
TEST TYPE: MAXIMIZATION TEST (GPMT)
ROUTES OF EXPOSURE: SKIN CONTACT
SPECIES: GUINEA PIG
RESULT: NEGATIVE
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
COCOAMIDOPROPYL BETAINE:
GENOTOXICITY IN VITRO:
TEST TYPE: BACTERIAL REVERSE MUTATION ASSAY (AMES)
METHOD: OECD TEST GUIDELINE 471
RESULT: NEGATIVE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
GENOTOXICITY IN VIVO:
TEST TYPE:
MAMMALIAN ERYTHROCYTE MICRONUCLEUS TEST (IN VIVO CYTOGENETIC ASSAY)
SPECIES: MOUSE
APPLICATION ROUTE: INGESTION
RESULT: NEGATIVE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
SODIUM 2-[2-[2-(TRIDECYLOXY)ETHOXY]ETHOXY]ETHYL SULPHATE:
GENOTOXICITY IN VITRO:
TEST TYPE: IN VITRO MAMMALIAN CELL GENE MUTATION TEST
METHOD: OECD TEST GUIDELINE 476
RESULT: NEGATIVE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
GENOTOXICITY IN VIVO:
TEST TYPE:
MUTAGENICITY (IN VIVO MAMMALIAN BONE-MARROW CYTOGENETIC TEST, CHROMOSOMAL
ANALYSIS)
SPECIES: MOUSE
APPLICATION ROUTE: INGESTION
METHOD: OECD TEST GUIDELINE 475
RESULT: NEGATIVE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
ACETIC ACID, CHLORO-, SODIUM SALT, REACTION PRODUCTS WITH
4,5-DIHYDRO-2-UNDECYL-1H-IMIDAZOLE-1-ETHANOL AND SODIUM HYDROXIDE:
GENOTOXICITY IN VITRO:
TEST TYPE: CHROMOSOME ABERRATION TEST IN VITRO
METHOD: OECD TEST GUIDELINE 473
RESULT: NEGATIVE
CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
IARC:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
OSHA:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
NTP:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
REPRODUCTIVE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
COCOAMIDOPROPYL BETAINE:
EFFECTS ON FETAL DEVELOPMENT:
TEST TYPE: EMBRYO-FETAL DEVELOPMENT
SPECIES: RAT
APPLICATION ROUTE: INGESTION
METHOD: OECD TEST GUIDELINE 414
RESULT: NEGATIVE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
SODIUM 2-[2-[2-(TRIDECYLOXY)ETHOXY]ETHOXY]ETHYL SULPHATE:
EFFECTS ON FERTILITY:
TEST TYPE: TWO-GENERATION REPRODUCTION TOXICITY STUDY
SPECIES: RAT
APPLICATION ROUTE: INGESTION
RESULT: NEGATIVE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
EFFECTS ON FETAL DEVELOPMENT:
TEST TYPE: EMBRYO-FETAL DEVELOPMENT
SPECIES: RAT
APPLICATION ROUTE: INGESTION
METHOD: OECD TEST GUIDELINE 414
RESULT: NEGATIVE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
STOT-SINGLE EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT-REPEATED EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
REPEATED DOSE TOXICITY:
INGREDIENTS:
COCOAMIDOPROPYL BETAINE:
SPECIES: RAT
NOAEL: 250 MG/KG
APPLICATION ROUTE: INGESTION
EXPOSURE TIME: 90 D
METHOD: OECD TEST GUIDELINE 408
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
SODIUM 2-[2-[2-(TRIDECYLOXY)ETHOXY]ETHOXY]ETHYL SULPHATE:
SPECIES: RAT
NOAEL: 225 MG/KG
APPLICATION ROUTE: INGESTION
EXPOSURE TIME: 90 D
METHOD: OECD TEST GUIDELINE 408
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
ACETIC ACID, CHLORO-, SODIUM SALT, REACTION PRODUCTS WITH
4,5-DIHYDRO-2-UNDECYL-1H-IMIDAZOLE-1-ETHANOL AND SODIUM HYDROXIDE:
SPECIES: RAT
NOAEL: 250 MG/KG
APPLICATION ROUTE: INGESTION
EXPOSURE TIME: 28 D
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
ASPIRATION TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
INGREDIENTS:
COCOAMIDOPROPYL BETAINE:
TOXICITY TO FISH:
LC50: >1 - 10 MG/L
EXPOSURE TIME: 96 H
METHOD: ISO 7346/2
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
TOXICITY TO BACTERIA:
EC50: >100 MG/L
METHOD: OECD TEST GUIDELINE 209
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
SODIUM 2-[2-[2-(TRIDECYLOXY)ETHOXY]ETHOXY]ETHYL SULPHATE:
TOXICITY TO FISH:
LC50 (ONCORHYNCHUS MYKISS (RAINBOW TROUT)): 10.4 MG/L
EXPOSURE TIME: 96 H
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (DAPHNIA MAGNA (WATER FLEA)): 9.1 MG/L
EXPOSURE TIME: 48 H
METHOD: OECD TEST GUIDELINE 202
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
TOXICITY TO ALGAE:
EC50 (DESMODESMUS SUBSPICATUS (GREEN ALGAE)): 27 MG/L
EXPOSURE TIME: 72 H
METHOD: OECD TEST GUIDELINE 201
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
NOEC (DESMODESMUS SUBSPICATUS (GREEN ALGAE)): 0.93 MG/L
EXPOSURE TIME: 72 H
METHOD: OECD TEST GUIDELINE 201
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
TOXICITY TO FISH (CHRONIC TOXICITY):
NOEC (PIMEPHALES PROMELAS (FATHEAD MINNOW)): 1 MG/L
EXPOSURE TIME: 45 D
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY):
NOEC (DAPHNIA MAGNA (WATER FLEA)): 0.27 MG/L
EXPOSURE TIME: 21 D
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
TOXICITY TO BACTERIA:
EC50 (PSEUDOMONAS PUTIDA): > 10 G/L
EXPOSURE TIME: 16 H
METHOD: DIN 38 412 PART 8
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
ACETIC ACID, CHLORO-, SODIUM SALT, REACTION PRODUCTS WITH
4,5-DIHYDRO-2-UNDECYL-1H-IMIDAZOLE-1-ETHANOL AND SODIUM HYDROXIDE:
TOXICITY TO FISH:
LC50 (DANIO RERIO (ZEBRA FISH)): 1.6 MG/L
EXPOSURE TIME: 96 H
METHOD: ISO 7346/1
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (DAPHNIA MAGNA (WATER FLEA)): 89 MG/L
EXPOSURE TIME: 48 H
METHOD: DIN 38412
TOXICITY TO ALGAE:
EC50 (DESMODESMUS SUBSPICATUS (GREEN ALGAE)): 14.8 MG/L
EXPOSURE TIME: 72 H
METHOD: OECD TEST GUIDELINE 201
EC10 (DESMODESMUS SUBSPICATUS (GREEN ALGAE)): 3.8 MG/L
EXPOSURE TIME: 72 H
METHOD: OECD TEST GUIDELINE 201
TOXICITY TO BACTERIA:
NOEC: 560 MG/L
EXPOSURE TIME: 3 H
METHOD: OECD TEST GUIDELINE 209
PERSISTENCE AND DEGRADABILITY:
INGREDIENTS:
COCOAMIDOPROPYL BETAINE:
BIODEGRADABILITY:
RESULT: READILY BIODEGRADABLE.
BIODEGRADATION: >60%
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
SODIUM 2-[2-[2-(TRIDECYLOXY)ETHOXY]ETHOXY]ETHYL SULPHATE:
BIODEGRADABILITY:
RESULT: READILY BIODEGRADABLE.
BIODEGRADATION: 65%
EXPOSURE TIME: 38 D
METHOD: OECD TEST GUIDELINE 301B
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
ACETIC ACID, CHLORO-, SODIUM SALT, REACTION PRODUCTS WITH
4,5-DIHYDRO-2-UNDECYL-1H-IMIDAZOLE-1-ETHANOL AND SODIUM HYDROXIDE:
BIODEGRADABILITY:
RESULT: READILY BIODEGRADABLE.
BIODEGRADATION: 100%
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301B
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
MOBILITY IN SOIL: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES: DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
CONTAMINATED PACKAGING:
DISPOSE OF AS UNUSED PRODUCT.
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
| SECTION 14. TRANSPORT INFORMATION | |
INTERNATIONAL REGULATION:
UNRTDG: NOT REGULATED AS A DANGEROUS GOOD
IATA-DGR: NOT REGULATED AS A DANGEROUS GOOD
IMDG-CODE: NOT REGULATED AS A DANGEROUS GOOD
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE FOR PRODUCT AS SUPPLIED.
DOMESTIC REGULATION:
49 CFR: NOT REGULATED AS A DANGEROUS GOOD
| SECTION 15. REGULATORY INFORMATION | |
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW:
CERCLA REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A CERCLA RQ.
SARA 304 EXTREMELY HAZARDOUS SUBSTANCES REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 304 EHS RQ.
SARA 311/312 HAZARDS: ACUTE HEALTH HAZARD
SARA 302:
NO CHEMICALS IN THIS MATERIAL ARE SUBJECT TO THE REPORTING REQUIREMENTS OF
SARA TITLE III, SECTION 302.
SARA 313:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS ESTABLISHED
BY SARA TITLE III, SECTION 313.
US STATE REGULATIONS:
PENNSYLVANIA RIGHT TO KNOW:
WATER 7732-18-5 70 - 90%
POLYETHYLENE GLYCOL SORBITAN MONOLAURATE 9005-64-5 1 - 5%
NEW JERSEY RIGHT TO KNOW:
WATER 7732-18-5 70 - 90%
POLYETHYLENE GLYCOL SORBITAN MONOLAURATE 9005-64-5 1 - 5%
COCOAMIDOPROPYL BETAINE 61789-40-0 1 - 5%
SODIUM 2-[2-[2-(TRIDECYLOXY)ETHOXY]ETHOXY] 25446-78-0 1 - 5%
ETHYL SULPHATE
POLYETHYLENE GLYCOL DISTEARATE 9005-08-7 1 - 5%
ACETIC ACID, CHLORO-, SODIUM SALT, REACTION 68608-66-2 1 - 5%
PRODUCTS WITH 4,5-DIHYDRO-
2-UNDECYL-1H-IMIDAZOLE-1-ETHANOL AND
SODIUM HYDROXIDE
CALIFORNIA PROP 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH, OR ANY OTHER REPRODUCTIVE DEFECTS.
THE INGREDIENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES:
REACH: ALL INGREDIENTS (PRE-)REGISTERED OR EXEMPT.
TSCA:
ALL CHEMICAL SUBSTANCES IN THIS PRODUCT ARE EITHER LISTED ON THE TSCA
INVENTORY OR ARE IN COMPLIANCE WITH A TSCA INVENTORY EXEMPTION.
DSL:
ALL CHEMICAL SUBSTANCES IN THIS PRODUCT COMPLY WITH THE CEPA 1999 AND NSNR
AND ARE ON OR EXEMPT FROM LISTING ON THE CANADIAN DOMESTIC SUBSTANCES LIST
(DSL).
AICS: ALL INGREDIENTS LISTED OR EXEMPT.
INVENTORIES:
AICS (AUSTRALIA), DSL (CANADA), IECSC (CHINA), REACH (EUROPEAN UNION), ENCS
(JAPAN), ISHL (JAPAN), KECI (KOREA), NZIOC (NEW ZEALAND), PICCS
(PHILIPPINES), TCSI (TAIWAN), TSCA (USA)
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
NFPA:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARD.
HMIS III:
HEALTH 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
0 = NOT SIGNIFICANT
1 = SLIGHT
2 = MODERATE
3 = HIGH
4 = EXTREME
* = CHRONIC
SOURCES OF KEY DATA USED TO COMPILE THE MATERIAL SAFETY DATA SHEET:
INTERNAL TECHNICAL DATA, DATA FROM RAW MATERIAL SDSS, OECD ECHEM PORTAL
SEARCH RESULTS AND EUROPEAN CHEMICALS AGENCY, HTTP://ECHA.EUROPA.EU/
REVISION DATE: 03/31/2015
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING, USE,
PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND SHALL NOT BE
CONSIDERED A WARRANTY OR QUALITY SPECIFICATION OF ANY TYPE. THE INFORMATION
PROVIDED RELATES ONLY TO THE SPECIFIC MATERIAL IDENTIFIED AT THE TOP OF
THIS SDS AND MAY NOT BE VALID WHEN THE SDS MATERIAL IS USED IN COMBINATION
WITH ANY OTHER MATERIALS OR IN ANY PROCESS, UNLESS SPECIFIED IN THE TEXT.
MATERIAL USERS SHOULD REVIEW THE INFORMATION AND RECOMMENDATIONS IN THE
SPECIFIC CONTEXT OF THEIR INTENDED MANNER OF HANDLING, USE, PROCESSING AND
STORAGE, INCLUDING AN ASSESSMENT OF THE APPROPRIATENESS OF THE SDS MATERIAL
IN THE USER'S END PRODUCT, IF APPLICABLE.
US / Z8