| Common Name: | ROTELLA T4 TRIPLE PROTECTION 15W-40 |
| Manufacturer: | SHELL OIL PRODUCTS |
| SDS Revision Date: | 5/22/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 52ND99, 52NE01, 52NE02, 52NE03 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
ACCORDING TO OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200
SHELL ROTELLA T4 TRIPLE PROTECTION 15W-40
VERSION: 2.0
REVISION DATE: 05/22/2019
SDS NUMBER: 800010026636
PRINT DATE: 05/23/2019
DATE OF LAST ISSUE: 05/22/2019
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: SHELL ROTELLA T4 TRIPLE PROTECTION 15W-40
PRODUCT CODE: 001F8880
MANUFACTURER OR SUPPLIER'S DETAILS:
MANUFACTURER/SUPPLIER:
SHELL OIL PRODUCTS US
PO BOX 4427
HOUSTON TX 77210-4427
USA
SDS REQUEST: (+1) 877-276-7285
CUSTOMER SERVICE:
EMERGENCY TELEPHONE NUMBER:
SPILL INFORMATION: 877-504-9351
HEALTH INFORMATION: 877-242-7400
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: ENGINE OIL.
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910.1200:
| LONG-TERM (CHRONIC) AQUATIC HAZARD: CATEGORY 3
GHS LABEL ELEMENTS:
| HAZARD PICTOGRAMS: NO SYMBOL
| SIGNAL WORD: NO SIGNAL WORD
| HAZARD STATEMENTS:
| PHYSICAL HAZARDS: NOT CLASSIFIED AS A PHYSICAL HAZARD UNDER GHS CRITERIA.
| HEALTH HAZARDS: NOT CLASSIFIED AS A HEALTH HAZARD UNDER GHS CRITERIA.
| ENVIRONMENTAL HAZARDS:
| H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
| PRECAUTIONARY STATEMENTS:
| PREVENTION:
| P273: AVOID RELEASE TO THE ENVIRONMENT.
| RESPONSE: NO PRECAUTIONARY PHRASES.
| STORAGE: NO PRECAUTIONARY PHRASES.
| DISPOSAL:
| P501: DISPOSE OF CONTENTS/ CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION:
PROLONGED OR REPEATED SKIN CONTACT WITHOUT PROPER CLEANING CAN CLOG THE
PORES OF THE SKIN RESULTING IN DISORDERS SUCH AS OIL ACNE/FOLLICULITIS.
USED OIL MAY CONTAIN HARMFUL IMPURITIES.
NOT CLASSIFIED AS FLAMMABLE BUT WILL BURN.
THE CLASSIFICATION OF THIS MATERIAL IS BASED ON OSHA HCS 2012 CRITERIA.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NATURE:
HIGHLY REFINED MINERAL OILS AND ADDITIVES.
THE HIGHLY REFINED MINERAL OIL CONTAINS <3% (W/W) DMSO-EXTRACT, ACCORDING
TO IP346.
* CONTAINS ONE OR MORE OF THE FOLLOWING CAS-NUMBERS:
64742-53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-65-0, 68037-01-4,
72623-86-0, 72623-87-1, 8042-47-5, 848301-69-9.
HAZARDOUS COMPONENTS:
CHEMICAL NAME SYNONYMS CAS-NO. CONCENTRATION (% W/W)
ALKARYL AMINE BIS(NONYLPHENYL) 36878-20-3 1 - 3
AMINE
CALCIUM SULPHONATE BENZENESULFONIC 70024-69-0 0.1 - 0.99
ACID, MONO-C16-
24-ALKYL
DERIVS.,
CALCIUM SALTS
ALKYL BORATE NOT ASSIGNED 0.1 - 0.99
DIALKYL ALKARYL NOT ASSIGNED 0.1 - 0.99
AMINOMETHYL
DICARBOXYLATE
ALCOHOL, ALCOHOLS, 68551-12-2 0.1 - 0.5
ETHOXYLATED C12-16,
ETHOXYLATED
INTERCHANGEABLE NOT ASSIGNED 0 - 90
LOW VISCOSITY
BASE OIL
(<20,5 CST
@40 DEG. C) *
| SECTION 4. FIRST-AID MEASURES | |
IF INHALED:
NO TREATMENT NECESSARY UNDER NORMAL CONDITIONS OF USE.
IF SYMPTOMS PERSIST, OBTAIN MEDICAL ADVICE.
IN CASE OF SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. FLUSH EXPOSED AREA WITH WA-TER AND FOLLOW BY
WASHING WITH SOAP IF AVAILABLE.
IF PERSISTENT IRRITATION OCCURS, OBTAIN MEDICAL ATTENTION.
IN CASE OF EYE CONTACT:
FLUSH EYE WITH COPIOUS QUANTITIES OF WATER.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF PERSISTENT IRRITATION OCCURS, OBTAIN MEDICAL ATTENTION.
IF SWALLOWED:
IN GENERAL NO TREATMENT IS NECESSARY UNLESS LARGE QUANTITIES ARE
SWALLOWED, HOWEVER, GET MEDICAL ADVICE.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
OIL ACNE/FOLLICULITIS SIGNS AND SYMPTOMS MAY INCLUDE FORMATION OF BLACK
PUSTULES AND SPOTS ON THE SKIN OF EXPOSED AREAS.
INGESTION MAY RESULT IN NAUSEA, VOMITING AND/OR DIARRHOEA.
PROTECTION OF FIRST-AIDERS:
WHEN ADMINISTERING FIRST AID, ENSURE THAT YOU ARE WEARING THE
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT ACCORDING TO THE INCIDENT,
INJURY AND SURROUNDINGS.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
TREAT SYMPTOMATICALLY.
| SECTION 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
FOAM, WATER SPRAY OR FOG. DRY CHEMICAL POWDER, CARBON DIOXIDE, SAND OR
EARTH MAY BE USED FOR SMALL FIRES ONLY.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER IN A JET.
SPECIFIC HAZARDS DURING FIRE-FIGHTING:
HAZARDOUS COMBUSTION PRODUCTS MAY INCLUDE:
A COMPLEX MIXTURE OF AIRBORNE SOLID AND LIQUID PARTICULATES AND GASES
(SMOKE).
CARBON MONOXIDE MAY BE EVOLVED IF INCOMPLETE COMBUSTION OCCURS.
UNIDENTIFIED ORGANIC AND INORGANIC COMPOUNDS.
SPECIFIC EXTINGUISHING METHODS:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES
AND THE SURROUNDING ENVIRONMENT.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
PROPER PROTECTIVE EQUIPMENT INCLUDING CHEMICAL RESISTANT GLOVES ARE TO BE
WORN; CHEMICAL RESISTANT SUIT IS INDICATED IF LARGE CONTACT WITH SPILLED
PRODUCT IS EXPECTED. SELF-CONTAINED BREATHING APPARATUS MUST BE WORN WHEN
APPROACHING A FIRE IN A CONFINED SPACE. SELECT FIRE FIGHTER'S CLOTHING
APPROVED TO RELEVANT STANDARDS (E.G. EUROPE: EN469).
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
AVOID CONTACT WITH SKIN AND EYES.
ENVIRONMENTAL PRECAUTIONS:
LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE
CONTAINED.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SLIPPERY WHEN SPILT. AVOID ACCIDENTS, CLEAN UP IMMEDIATELY.
PREVENT FROM SPREADING BY MAKING A BARRIER WITH SAND, EARTH OR OTHER
CONTAINMENT MATERIAL.
RECLAIM LIQUID DIRECTLY OR IN AN ABSORBENT.
SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY, SAND OR OTHER SUITABLE
MATERIAL AND DISPOSE OF PROPERLY.
ADDITIONAL ADVICE:
FOR GUIDANCE ON SELECTION OF PERSONAL PROTECTIVE EQUIPMENT SEE CHAPTER 8
OF THIS SAFETY DATA SHEET.
FOR GUIDANCE ON DISPOSAL OF SPILLED MATERIAL SEE CHAPTER 13 OF THIS SAFETY
DATA SHEET.
| SECTION 7. HANDLING AND STORAGE | |
TECHNICAL MEASURES:
USE LOCAL EXHAUST VENTILATION IF THERE IS RISK OF INHALATION OF VAPOURS,
MISTS OR AEROSOLS.
USE THE INFORMATION IN THIS DATA SHEET AS INPUT TO A RISK ASSESSMENT OF
LOCAL CIRCUMSTANCES TO HELP DETERMINE APPROPRIATE CONTROLS FOR SAFE
HANDLING, STORAGE AND DISPOSAL OF THIS MATERIAL.
ADVICE ON SAFE HANDLING:
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN.
AVOID INHALING VAPOUR AND/OR MISTS.
WHEN HANDLING PRODUCT IN DRUMS, SAFETY FOOTWEAR SHOULD BE WORN AND PROPER
HANDLING EQUIPMENT SHOULD BE USED.
PROPERLY DISPOSE OF ANY CONTAMINATED RAGS OR CLEANING MATERIALS
IN ORDER TO PREVENT FIRES.
AVOIDANCE OF CONTACT: STRONG OXIDISING AGENTS.
PRODUCT TRANSFER:
PROPER GROUNDING AND BONDING PROCEDURES SHOULD BE USED DURING ALL BULK
TRANSFER OPERATIONS TO AVOID STATIC ACCUMULATION.
FURTHER INFORMATION ON STORAGE STABILITY:
KEEP CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED PLACE.
USE PROPERLY LABELED AND CLOSABLE CONTAINERS.
STORE AT AMBIENT TEMPERATURE.
PACKAGING MATERIAL:
SUITABLE MATERIAL:
FOR CONTAINERS OR CONTAINER LININGS, USE MILD STEEL OR HIGH DENSITY
POLYETHYLENE.
UNSUITABLE MATERIAL: PVC.
CONTAINER ADVICE:
POLYETHYLENE CONTAINERS SHOULD NOT BE EXPOSED TO HIGH TEMPERATURES
BECAUSE OF POSSIBLE RISK OF DISTORTION.
| SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
COMPONENTS CAS-NO. VALUE TYPE CONTROL PARAMETERS BASIS
(FORM OF EXPOSURE) / PERMISSIBLE
CONCENTRATION
OIL MIST, NOT ASSIGNED TWA (MIST) 5 MG/M3 OSHA Z-1
MINERAL
OIL MIST, TWA (INHALABLE 5 MG/M3 ACGIH
MINERAL FRACTION)
BIOLOGICAL OCCUPATIONAL EXPOSURE LIMITS: NO BIOLOGICAL LIMIT ALLOCATED.
MONITORING METHODS:
MONITORING OF THE CONCENTRATION OF SUBSTANCES IN THE BREATHING ZONE OF
WORKERS OR IN THE GENERAL WORKPLACE MAY BE REQUIRED TO CONFIRM COMPLIANCE
WITH AN OEL AND ADEQUACY OF EXPOSURE CONTROLS. FOR SOME SUBSTANCES
BIOLOGICAL MONITORING MAY ALSO BE APPROPRIATE.
VALIDATED EXPOSURE MEASUREMENT METHODS SHOULD BE APPLIED BY A COMPETENT
PERSON AND SAMPLES ANALYSED BY AN ACCREDITED LABORATORY.
EXAMPLES OF SOURCES OF RECOMMENDED EXPOSURE MEASUREMENT METHODS ARE GIVEN
BELOW OR CONTACT THE SUPPLIER. FURTHER NATIONAL METHODS MAY BE AVAILABLE.
NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH (NIOSH), USA:
MANUAL OF ANALYTICAL METHODS HTTP://WWW.CDC.GOV/NIOSH/
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA), USA:
SAMPLING AND ANALYTICAL METHODS HTTP://WWW.OSHA.GOV/
HEALTH AND SAFETY EXECUTIVE (HSE), UK:
METHODS FOR THE DETERMINATION OF HAZARDOUS SUBSTANCES
HTTP://WWW.HSE.GOV.UK/
INSTITUT FUR ARBEITSSCHUTZ DEUTSCHEN GESETZLICHEN UNFALLVERSICHERUNG
(IFA), GERMANY HTTP://WWW.DGUV.DE/INHALT/INDEX.JSP
L'INSTITUT NATIONAL DE RECHERCHE ET DE SECURITE, (INRS), FRANCE
HTTP://WWW.INRS.FR/ACCUEIL
ENGINEERING MEASURES:
THE LEVEL OF PROTECTION AND TYPES OF CONTROLS NECESSARY WILL VARY
DEPENDING UPON POTENTIAL EXPOSURE CONDITIONS. SELECT CONTROLS BASED
ON A RISK ASSESSMENT OF LOCAL CIRCUMSTANCES.
APPROPRIATE MEASURES INCLUDE:
ADEQUATE VENTILATION TO CONTROL AIRBORNE CONCENTRATIONS.
WHERE MATERIAL IS HEATED, SPRAYED OR MIST FORMED, THERE IS GREATER
POTENTIAL FOR AIRBORNE CONCENTRATIONS TO BE GENERATED.
GENERAL INFORMATION:
DEFINE PROCEDURES FOR SAFE HANDLING AND MAINTENANCE OF CONTROLS.
EDUCATE AND TRAIN WORKERS IN THE HAZARDS AND CONTROL MEASURES RELEVANT
TO NORMAL ACTIVITIES ASSOCIATED WITH THIS PRODUCT.
ENSURE APPROPRIATE SELECTION, TESTING AND MAINTENANCE OF EQUIPMENT USED
TO CONTROL EXPOSURE, E.G. PERSONAL PROTECTIVE EQUIPMENT, LOCAL EXHAUST
VENTILATION.
DRAIN DOWN SYSTEM PRIOR TO EQUIPMENT BREAKIN OR MAINTENANCE.
RETAIN DRAIN DOWNS IN SEALED STORAGE PENDING DISPOSAL OR SUBSEQUENT
RECYCLE.
ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING HANDS
AFTER HANDLING THE MATERIAL AND BEFORE EATING, DRINKING, AND/OR SMOKING.
ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO REMOVE
CONTAMINANTS. DISCARD CONTAMINATED CLOTHING AND FOOTWEAR THAT CANNOT
BE CLEANED. PRACTICE GOOD HOUSE KEEPING.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
NO RESPIRATORY PROTECTION IS ORDINARILY REQUIRED UNDER NORMAL CONDITIONS
OF USE.
IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICES, PRECAUTIONS SHOULD
BE TAKEN TO AVOID BREATHING OF MATERIAL.
IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS TO A LEVEL
WHICH IS ADEQUATE TO PROTECT WORKER HEALTH, SELECT RESPIRATORY PROTECTION
EQUIPMENT SUITABLE FOR THE SPECIFIC CONDITIONS OF USE AND MEETING
RELEVANT LEGISLATION.
CHECK WITH RESPIRATORY PROTECTIVE EQUIPMENT SUPPLIERS.
WHERE AIR-FILTERING RESPIRATORS ARE SUITABLE, SELECT AN APPROPRIATE
COMBINATION OF MASK AND FILTER.
SELECT A FILTER SUITABLE FOR THE COMBINATION OF ORGANIC GASES AND VAPOURS
[TYPE A/TYPE P BOILING POINT >65 DEG. C (149 DEG. F)].
HAND PROTECTION:
REMARKS:
WHERE HAND CONTACT WITH THE PRODUCT MAY OCCUR THE USE OF GLOVES APPROVED
TO RELEVANT STANDARDS (E.G. EUROPE: EN374, US: F739) MADE FROM THE
FOLLOWING MATERIALS MAY PROVIDE SUITABLE CHEMICAL PROTECTION. PVC,
NEOPRENE OR NITRILE RUBBER GLOVES SUITABILITY AND DURABILITY OF A GLOVE
IS DEPENDENT ON USAGE, E.G. FREQUENCY AND DURATION OF CONTACT, CHEMICAL
RESISTANCE OF GLOVE MATERIAL, DEXTERITY. ALWAYS SEEK ADVICE FROM GLOVE
SUPPLIERS. CONTAMINATED GLOVES SHOULD BE REPLACED. PERSONAL HYGIENE IS
A KEY ELEMENT OF EFFECTIVE HAND CARE. GLOVES MUST ONLY BE WORN ON CLEAN
HANDS. AFTER USING GLOVES, HANDS SHOULD BE WASHED AND DRIED THOROUGHLY.
APPLICATION OF A NON-PERFUMED MOISTURIZER IS RECOMMENDED. FOR CONTINUOUS
CONTACT WE RECOMMEND GLOVES WITH BREAK-THROUGH TIME OF MORE THAN 240
MINUTES WITH PREFERENCE FOR >480 MINUTES WHERE SUITABLE GLOVES CAN BE
IDENTIFIED. FOR SHORT-TERM/SPLASH PROTECTION WE RECOMMEND THE SAME BUT
RECOGNIZE THAT SUITABLE GLOVES OFFERING THIS LEVEL OF PROTECTION MAY NOT
BE AVAILABLE AND IN THIS CASE A LOWER BREAK THROUGH TIME MAYBE ACCEPTABLE
SO LONG AS APPROPRIATE MAINTENANCE AND REPLACEMENT REGIMES ARE FOLLOWED.
GLOVE THICKNESS IS NOT A GOOD PREDICTOR OF GLOVE RESISTANCE TO A CHEMICAL
AS IT IS DEPENDENT ON THE EXACT COMPOSITION OF THE GLOVE MATERIAL. GLOVE
THICKNESS SHOULD BE TYPICALLY GREATER THAN 0.35 MM DEPENDING ON THE GLOVE
MAKE AND MODEL.
EYE PROTECTION:
IF MATERIAL IS HANDLED SUCH THAT IT COULD BE SPLASHED INTO EYES,
PROTECTIVE EYEWEAR IS RECOMMENDED.
SKIN AND BODY PROTECTION:
SKIN PROTECTION IS NOT ORDINARILY REQUIRED BEYOND STANDARD WORK CLOTHES.
IT IS GOOD PRACTICE TO WEAR CHEMICAL RESISTANT GLOVES.
PROTECTIVE MEASURES:
PERSONAL PROTECTIVE EQUIPMENT (PPE) SHOULD MEET RECOMMENDED NATIONAL
STANDARDS. CHECK WITH PPE SUPPLIERS.
THERMAL HAZARDS: NOT APPLICABLE
ENVIRONMENTAL EXPOSURE CONTROLS:
GENERAL ADVICE:
TAKE APPROPRIATE MEASURES TO FULFILL THE REQUIREMENTS OF RELEVANT
ENVIRONMENTAL PROTECTION LEGISLATION. AVOID CONTAMINATION OF THE
ENVIRONMENT BY FOLLOWING ADVICE GIVEN IN SECTION 6. IF NECESSARY,
PREVENT UNDISSOLVED MATERIAL FROM BEING DISCHARGED TO WASTE WATER.
WASTE WATER SHOULD BE TREATED IN A MUNICIPAL OR INDUSTRIAL WASTE
WATER TREATMENT PLANT BEFORE DISCHARGE TO SURFACE WATER.
LOCAL GUIDELINES ON EMISSION LIMITS FOR VOLATILE SUBSTANCES MUST BE
OBSERVED FOR THE DISCHARGE OF EXHAUST AIR CONTAINING VAPOUR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
COLOUR: CLEAR AMBER
ODOUR: SLIGHT HYDROCARBON
ODOUR THRESHOLD: DATA NOT AVAILABLE
PH: NOT APPLICABLE
POUR POINT: -36 DEG. C / -33 DEG. F
METHOD: ASTM D97
INITIAL BOILING POINT AND BOILING RANGE:
>280 DEG. C / 536 DEG. F ESTIMATED VALUE(S)
FLASH POINT: 234 DEG. C / 453 DEG. F
METHOD: ASTM D92 (COC)
EVAPORATION RATE: DATA NOT AVAILABLE
FLAMMABILITY (SOLID, GAS): DATA NOT AVAILABLE
UPPER EXPLOSION LIMIT / UPPER FLAMMABILITY LIMIT: TYPICAL 10 %(V)
LOWER EXPLOSION LIMIT / LOWER FLAMMABILITY LIMIT: TYPICAL 1 %(V)
VAPOUR PRESSURE: <0.5 PA (20 DEG. C / 68 DEG. F) ESTIMATED VALUE(S)
RELATIVE VAPOUR DENSITY: >1 ESTIMATED VALUE(S)
RELATIVE DENSITY: 0.878 (15 DEG. C / 59 DEG. F)
DENSITY: 878 KG/M3 (15.0 DEG. C / 59.0 DEG. F)
METHOD: ASTM D4052
SOLUBILITY(IES):
WATER SOLUBILITY: NEGLIGIBLE
SOLUBILITY IN OTHER SOLVENTS: DATA NOT AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: >6
(BASED ON INFORMATION ON SIMILAR PRODUCTS)
AUTOIGNITION TEMPERATURE: >320 DEG. C / 608 DEG. F
DECOMPOSITION TEMPERATURE: DATA NOT AVAILABLE
VISCOSITY:
VISCOSITY, DYNAMIC: DATA NOT AVAILABLE
VISCOSITY, KINEMATIC: 14.9 MM2/S (100 DEG. C / 212 DEG. F)
METHOD: ASTM D445
EXPLOSIVE PROPERTIES: NOT CLASSIFIED
OXIDIZING PROPERTIES: DATA NOT AVAILABLE
CONDUCTIVITY: THIS MATERIAL IS NOT EXPECTED TO BE A STATIC ACCUMULATOR.
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT DOES NOT POSE ANY FURTHER REACTIVITY HAZARDS IN ADDITION TO
THOSE LISTED IN THE FOLLOWING SUB-PARAGRAPH.
CHEMICAL STABILITY: STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS: REACTS WITH STRONG OXIDISING AGENTS.
CONDITIONS TO AVOID: EXTREMES OF TEMPERATURE AND DIRECT SUNLIGHT.
INCOMPATIBLE MATERIALS: STRONG OXIDISING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
BASIS FOR ASSESSMENT:
INFORMATION GIVEN IS BASED ON DATA ON THE COMPONENTS AND THE TOXICOLOGY
OF SIMILAR PRODUCTS. UNLESS INDICATED OTHERWISE, THE DATA PRESENTED IS
REPRESENTATIVE OF THE PRODUCT AS A WHOLE, RATHER THAN FOR INDIVIDUAL
COMPONENT(S).
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
SKIN AND EYE CONTACT ARE THE PRIMARY ROUTES OF EXPOSURE ALTHOUGH EXPOSURE
MAY OCCUR FOLLOWING ACCIDENTAL INGESTION.
ACUTE TOXICITY:
PRODUCT:
ACUTE ORAL TOXICITY:
LD50 (RAT): >5,000 MG/KG
REMARKS:
LOW TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ACUTE INHALATION TOXICITY:
REMARKS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >5,000 MG/KG
REMARKS:
LOW TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SKIN CORROSION/IRRITATION:
PRODUCT:
REMARKS:
SLIGHTLY IRRITATING TO SKIN., PROLONGED OR REPEATED SKIN CONTACT WITHOUT
PROPER CLEANING CAN CLOG THE PORES OF THE SKIN RESULTING IN DISORDERS SUCH
AS OIL ACNE/FOLLICULITIS., BASED ON AVAILABLE DATA, THE CLASSIFICATION
CRITERIA ARE NOT MET.
SERIOUS EYE DAMAGE/EYE IRRITATION:
PRODUCT:
REMARKS:
SLIGHTLY IRRITATING TO THE EYE., BASED ON AVAILABLE DATA, THE
CLASSIFICATION CRITERIA ARE NOT MET.
RESPIRATORY OR SKIN SENSITISATION:
PRODUCT:
REMARKS: NOT A SKIN SENSITISER.
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
COMPONENTS:
CALCIUM SULPHONATE:
REMARKS: MAY CAUSE AN ALLERGIC SKIN REACTION IN SENSITIVE INDIVIDUALS.
REMARKS: CLASSIFIED SKIN SENSITISER CATEGORY 1B.
ALKYL BORATE:
REMARKS: MAY CAUSE AN ALLERGIC SKIN REACTION IN SENSITIVE INDIVIDUALS.
REMARKS: CLASSIFIED SKIN SENSITISER CATEGORY 1B.
DIALKYL ALKARYL AMINOMETHYL DICARBOXYLATE:
REMARKS: MAY CAUSE AN ALLERGIC SKIN REACTION IN SENSITIVE INDIVIDUALS.
REMARKS: CLASSIFIED SKIN SENSITISER CATEGORY 1B.
GERM CELL MUTAGENICITY:
PRODUCT:
REMARKS:
NON MUTAGENIC, BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE
NOT MET.
CARCINOGENICITY:
PRODUCT:
REMARKS:
NOT A CARCINOGEN., BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE
NOT MET.
REMARKS:
PRODUCT CONTAINS MINERAL OILS OF TYPES SHOWN TO BE NON-CARCINOGENIC IN
ANIMAL SKIN-PAINTING STUDIES., HIGHLY REFINED MINERAL OILS ARE NOT
CLASSIFIED AS CARCINOGENIC BY THE INTERNATIONAL AGENCY FOR RESEARCH ON
CANCER (IARC).
IARC:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS ON OSHA'S LIST OF REGULATED CARCINOGENS.
NTP:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
REPRODUCTIVE TOXICITY:
PRODUCT:
REMARKS:
NOT A DEVELOPMENTAL TOXICANT., DOES NOT IMPAIR FERTILITY., BASED ON
AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT - SINGLE EXPOSURE:
PRODUCT:
REMARKS: BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT - REPEATED EXPOSURE:
PRODUCT:
REMARKS: BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ASPIRATION TOXICITY:
PRODUCT: NOT AN ASPIRATION HAZARD.
FURTHER INFORMATION:
PRODUCT:
REMARKS:
USED OILS MAY CONTAIN HARMFUL IMPURITIES THAT HAVE ACCUMULATED DURING USE.
THE CONCENTRATION OF SUCH IMPURITIES WILL DEPEND ON USE AND THEY MAY
PRESENT RISKS TO HEALTH AND THE ENVIRONMENT ON DISPOSAL., ALL USED OIL
SHOULD BE HANDLED WITH CAUTION AND SKIN CONTACT AVOIDED AS FAR AS POSSIBLE.
REMARKS:
CONTINUOUS CONTACT WITH USED ENGINE OILS HAS CAUSED SKIN CANCER IN ANIMAL
TESTS.
REMARKS: SLIGHTLY IRRITATING TO RESPIRATORY SYSTEM.
| SECTION 12. ECOLOGICAL INFORMATION | |
BASIS FOR ASSESSMENT:
ECOTOXICOLOGICAL DATA HAVE NOT BEEN DETERMINED SPECIFICALLY FOR THIS
PRODUCT.
INFORMATION GIVEN IS BASED ON A KNOWLEDGE OF THE COMPONENTS AND THE
ECOTOXICOLOGY OF SIMILAR PRODUCTS.
UNLESS INDICATED OTHERWISE, THE DATA PRESENTED IS REPRESENTATIVE OF THE
PRODUCT AS A WHOLE, RATHER THAN FOR INDIVIDUAL COMPONENT(S).(LL/EL/IL50
EXPRESSED AS THE NOMINAL AMOUNT OF PRODUCT REQUIRED TO PREPARE AQUEOUS
TEST EXTRACT).
ECOTOXICITY:
PRODUCT:
TOXICITY TO FISH (ACUTE TOXICITY):
REMARKS:
LL/EL/IL50 10-100 MG/L
HARMFUL
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (ACUTE TOXICITY):
REMARKS:
LL/EL/IL50 10-100 MG/L
HARMFUL
TOXICITY TO ALGAE (ACUTE TOXICITY):
REMARKS:
LL/EL/IL50 10-100 MG/L
HARMFUL
TOXICITY TO FISH (CHRONIC TOXICITY):
REMARKS: DATA NOT AVAILABLE
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY):
REMARKS: DATA NOT AVAILABLE
TOXICITY TO MICROORGANISMS (ACUTE TOXICITY):
REMARKS: DATA NOT AVAILABLE
PERSISTENCE AND DEGRADABILITY:
PRODUCT:
BIODEGRADABILITY:
REMARKS: NOT READILY BIODEGRADABLE.
MAJOR CONSTITUENTS ARE INHERENTLY BIODEGRADABLE, BUT CONTAINS COMPONENTS
THAT MAY PERSIST IN THE ENVIRONMENT.
BIOACCUMULATIVE POTENTIAL:
PRODUCT:
BIOACCUMULATION:
REMARKS: CONTAINS COMPONENTS WITH THE POTENTIAL TO BIOACCUMULATE.
MOBILITY IN SOIL:
PRODUCT:
MOBILITY:
REMARKS:
LIQUID UNDER MOST ENVIRONMENTAL CONDITIONS.
IF IT ENTERS SOIL, IT WILL ADSORB TO SOIL PARTICLES AND WILL NOT BE MOBILE.
REMARKS: FLOATS ON WATER.
OTHER ADVERSE EFFECTS:
PRODUCT:
DOES NOT HAVE OZONE DEPLETION POTENTIAL, PHOTOCHEMICAL OZONE CREATION
POTENTIAL OR GLOBAL WARMING POTENTIAL.
PRODUCT IS A MIXTURE OF NON-VOLATILE COMPONENTS, WHICH WILL NOT BE RELEASED
TO AIR IN ANY SIGNIFICANT QUANTITIES UNDER NORMAL CONDITIONS OF USE.
POORLY SOLUBLE MIXTURE.
CAUSES PHYSICAL FOULING OF AQUATIC ORGANISMS.
MINERAL OIL DOES NOT CAUSE CHRONIC TOXICITY TO AQUATIC ORGANISMS AT
CONCENTRATIONS LESS THAN 1 MG/L.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES:
RECOVER OR RECYCLE IF POSSIBLE.
IT IS THE RESPONSIBILITY OF THE WASTE GENERATOR TO DETERMINE THE TOXICITY
AND PHYSICAL PROPERTIES OF THE MATERIAL GENERATED TO DETERMINE THE PROPER
WASTE CLASSIFICATION AND DISPOSAL METH-ODS IN COMPLIANCE WITH APPLICABLE
REGULATIONS.
DO NOT DISPOSE INTO THE ENVIRONMENT, IN DRAINS OR IN WATER COURSES
WASTE PRODUCT SHOULD NOT BE ALLOWED TO CONTAMINATE SOIL OR GROUND WATER,
OR BE DISPOSED OF INTO THE ENVIRONMENT.
WASTE, SPILLS OR USED PRODUCT IS DANGEROUS WASTE.
CONTAMINATED PACKAGING:
DISPOSE IN ACCORDANCE WITH PREVAILING REGULATIONS, PREFERABLY TO A
RECOGNIZED COLLECTOR OR CONTRACTOR. THE COMPETENCE OF THE COLLECTOR OR
CONTRACTOR SHOULD BE ESTABLISHED BEFOREHAND.
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL, AND
LOCAL LAWS AND REGULATIONS.
LOCAL LEGISLATION:
REMARKS:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL, AND
LOCAL LAWS AND REGULATIONS.
| SECTION 14. TRANSPORT INFORMATION | |
NATIONAL REGULATIONS:
US DEPARTMENT OF TRANSPORTATION CLASSIFICATION (49 CFR PARTS 171-180):
NOT REGULATED AS A DANGEROUS GOOD
INTERNATIONAL REGULATIONS:
IATA-DGR:
NOT REGULATED AS A DANGEROUS GOOD
IMDG-CODE:
NOT REGULATED AS A DANGEROUS GOOD
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE FOR PRODUCT AS SUPPLIED. MARPOL ANNEX 1 RULES APPLY FOR BULK
SHIPMENTS BY SEA.
SPECIAL PRECAUTIONS FOR USER:
REMARKS:
SPECIAL PRECAUTIONS:
REFER TO SECTION 7, HANDLING & STORAGE, FOR SPECIAL PRECAUTIONS WHICH A
USER NEEDS TO BE AWARE OF OR NEEDS TO COMPLY WITH IN CONNECTION WITH
TRANSPORT.
| SECTION 15. REGULATORY INFORMATION | |
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT:
CERCLA REPORTABLE QUANTITY:
COMPONENTS CAS-NO. COMPONENT CALCULATED PRODUCT
RQ (LBS) RQ (LBS)
BENZENE 71-43-2 10 10 (D018)
2-METHYLPROPAN-1-OL 78-83-1 100 100 (F005)
BENZENE 71-43-2 10 *
*: CALCULATED RQ EXCEEDS REASONABLY ATTAINABLE UPPER LIMIT., SHELL
CLASSIFIES THIS MATERIAL AS AN "OIL" UNDER THE CERCLA PETROLEUM EXCLUSION,
THEREFORE RELEASES TO THE ENVIRONMENT ARE NOT RE-PORTABLE UNDER CERCLA.,
THE COMPONENTS WITH RQS ARE GIVEN FOR INFORMATION.
SARA 304 EXTREMELY HAZARDOUS SUBSTANCES REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 304 EHS RQ.
SARA 302 EXTREMELY HAZARDOUS SUBSTANCES THRESHOLD PLANNING QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 302 EHS TPQ.
SARA 311/312 HAZARDS: NO SARA HAZARDS
SARA 313:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS ESTABLISHED
BY SARA TITLE III, SECTION 313.
CLEAN WATER ACT:
THE FOLLOWING HAZARDOUS CHEMICALS ARE LISTED UNDER THE U.S. CLEANWATER
ACT, SECTION 311, TABLE 117.3:
BENZENE 71-43-2 0.0002 %
US STATE REGULATIONS:
PENNSYLVANIA RIGHT TO KNOW:
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT PARAFFINIC 64742-55-8
DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC 64742-65-0
ZINC DIALKYL DITHIOPHOSPHATE 84605-29-8
DIPHENYLAMINE 122-39-4
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO CHEMICALS INCLUDING BENZENE, WHICH IS/ARE
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM. FOR MORE IN-FORMATION GO TO WWW.P65WARNINGS.CA.GOV.
CALIFORNIA LIST OF HAZARDOUS SUBSTANCES:
DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT PARAFFINIC 64742-55-8
OTHER REGULATIONS:
THE REGULATORY INFORMATION IS NOT INTENDED TO BE COMPREHENSIVE. OTHER
REGULATIONS MAY APPLY TO THIS MATERIAL.
THE COMPONENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES:
EINECS: NOT ALL COMPONENTS LISTED.
TSCA: ALL COMPONENTS LISTED.
DSL: ALL COMPONENTS LISTED.
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
NFPA RATING:
HEALTH 0
FIRE 1
REACTIVITY 0
FULL TEXT OF OTHER ABBREVIATIONS:
ACGIH: USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
OSHA Z-1:
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z-1 LIM-ITS FOR AIR
CONTAMINANTS
ACGIH / TWA: 8-HOUR, TIME-WEIGHTED AVERAGE
OSHA Z-1 / TWA: 8-HOUR TIME WEIGHTED AVERAGE
ABBREVIATIONS AND ACRONYMS:
THE STANDARD ABBREVIATIONS AND ACRONYMS USED IN THIS DOCU-MENT CAN BE
LOOKED UP IN REFERENCE LITERATURE (E.G. SCIENTIFIC DICTIONARIES) AND/OR
WEBSITES.
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
ADR:
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD
AICS: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES
ASTM: AMERICAN SOCIETY FOR TESTING AND MATERIALS
BEL: BIOLOGICAL EXPOSURE LIMITS
BTEX: BENZENE, TOLUENE, ETHYLBENZENE, XYLENES
CAS: CHEMICAL ABSTRACTS SERVICE
CEFIC: EUROPEAN CHEMICAL INDUSTRY COUNCIL
CLP: CLASSIFICATION PACKAGING AND LABELLING
COC: CLEVELAND OPEN-CUP
DIN: DEUTSCHES INSTITUT FUR NORMUNG
DMEL: DERIVED MINIMAL EFFECT LEVEL
DNEL: DERIVED NO EFFECT LEVEL
DSL: CANADA DOMESTIC SUBSTANCE LIST
EC: EUROPEAN COMMISSION
EC50: EFFECTIVE CONCENTRATION FIFTY
ECETOC: EUROPEAN CENTER ON ECOTOXICOLOGY AND TOXICOLO-GY OF CHEMICALS
ECHA: EUROPEAN CHEMICALS AGENCY
EINECS: THE EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
EL50: EFFECTIVE LOADING FIFTY
ENCS: JAPANESE EXISTING AND NEW CHEMICAL SUBSTANCES INVENTORY
EWC: EUROPEAN WASTE CODE
GHS:
GLOBALLY HARMONISED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IC50: INHIBITORY CONCENTRATION FIFTY
IL50: INHIBITORY LEVEL FIFTY
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
INV: CHINESE CHEMICALS INVENTORY
IP346:
INSTITUTE OF PETROLEUM TEST METHOD NO 346 FOR THE DETERMINATION OF
POLYCYCLIC AROMATICS DMSO-EXTRACTABLES
KECI: KOREA EXISTING CHEMICALS INVENTORY
LC50: LETHAL CONCENTRATION FIFTY
LD50: LETHAL DOSE FIFTY PER CENT.
LL/EL/IL: LETHAL LOADING/EFFECTIVE LOADING/INHIBITORY LOADING
LL50: LETHAL LOADING FIFTY
MARPOL: INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS
NOEC/NOEL: NO OBSERVED EFFECT CONCENTRATION / NO OB-SERVED EFFECT LEVEL
OE_HPV: OCCUPATIONAL EXPOSURE - HIGH PRODUCTION VOLUME
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
PICCS: PHILIPPINE INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
PNEC: PREDICTED NO EFFECT CONCENTRATION
REACH: REGISTRATION EVALUATION AND AUTHORISATION OF CHEMICALS
RID:
REGULATIONS RELATING TO INTERNATIONAL CARRIAGE OF DAN-GEROUS GOODS BY RAIL
SKIN_DES: SKIN DESIGNATION
STEL: SHORT TERM EXPOSURE LIMIT
TRA: TARGETED RISK ASSESSMENT
TSCA: US TOXIC SUBSTANCES CONTROL ACT
TWA: TIME-WEIGHTED AVERAGE
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
A VERTICAL BAR (|) IN THE LEFT MARGIN INDICATES AN AMENDMENT FROM THE
PREVIOUS VERSION.
SOURCES OF KEY DATA USED TO COMPILE THE SAFETY DATA SHEET:
THE QUOTED DATA ARE FROM, BUT NOT LIMITED TO, ONE OR MORE SOURCES OF
INFORMATION (E.G. TOXICOLOGICAL DATA FROM SHELL HEALTH SERVICES, MATERIAL
SUPPLIERS' DATA, CONCAWE, EU IUCLID DATE BASE, EC 1272 REGULATION, ETC).
REVISION DATE: 05/22/2019
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFOR-MATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUID-ANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.
US / EN