| Common Name: | LOCTITE PC 3965 RESIN, 235605_653386, LOCTITE PC 3965 HARDENER, 235605_1948480 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 8/12/2020 |
| SDS Format: | GHS-US |
| Item Number(s): | 52WX57 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 004.1
ISSUE DATE: 08/12/2020
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE PC 3965 RESIN
PRODUCT TYPE/USE: ADHESIVE
IDH NUMBER: 2335634
ITEM NUMBER: 235605_653386
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING DUST OR FUMES. WASH AFFECTED AREA THOROUGHLY AFTER
HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF
THE WORKPLACE. WEAR PROTECTIVE GLOVES, EYE PROTECTION, AND FACE
PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: NOT PRESCRIBED
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/
PROVINCIAL AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
EPICHLOROHYDRIN-4,4'-ISOPROPYLIDENE DIPHENOL RESIN 25068-38-6 60 - 80
DIIRON TRIOXIDE 1309-37-1 10 - 30
TREATED FUMED SILICA 67762-90-7 1 - 5
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. GET MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY. CLOSED CONTAINERS
MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. ACIDS. ALDEHYDES. PHENOLICS. IRRITATING ORGANIC
FRAGMENTS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. IMMEDIATELY CONTACT EMERGENCY PERSONNEL.
EVACUATE AND VENTILATE SPILL AREA; DIKE SPILL TO PREVENT ENTRY INTO WATER
SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT DURING CLEAN-UP. SOAK UP WITH INERT
ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER, UNIVERSAL BINDER,
SAWDUST). SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. CLEAN RESIDUE WITH SOAP
AND WATER. STORE IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL.
REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO
CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
KEEP CONTAINER CLOSED. REFER TO SECTION 8.
STORAGE:
STORE IN ORIGINAL CONTAINER UNTIL READY TO USE. KEEP CONTAINER TIGHTLY
CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY FROM INCOMPATIBLE
MATERIALS. STORE AWAY FROM HEAT, SPARKS, FLAMES, OR OTHER SOURCES OF
IGNITION.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
EPICHLOROHYDRIN-4,4'- NONE NONE NONE NONE
ISOPROPYLIDENE DIPHENOL
RESIN
DIIRON TRIOXIDE 5 MG/M3 TWA 10 MG/M3 PEL NONE NONE
RESPIRABLE FUME.
FRACTION. 50 MPPCF TWA
TOTAL DUST.
5 MG/M3 TWA
RESPIRABLE
FRACTION.
15 MG/M3 TWA
TOTAL DUST.
15 MPPCF TWA
RESPIRABLE
FRACTION.
TREATED FUMED 10 MG/M3 TWA 15 MG/M3 TWA NONE NONE
SILICA INHALABLE TOTAL DUST.
DUST. 5 MG/M3 TWA
3 MG/M3 TWA RESPIRABLE
RESPIRABLE FRACTION.
FRACTION.
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE
COLOR: GRAY, WHITE
ODOR: MILD
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NEGLIGIBLE
BOILING POINT/RANGE: >149 DEG. C (>300.2 DEG. F)
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.663
VAPOR DENSITY: HEAVIER THAN AIR.
FLASH POINT: >93 DEG. C (>199.4 DEG. F) PENSKY MARTENS CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: SLOWER THAN BUTYL ACETATE.
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT:
<1.0 %; <10 G/L (VALUE FOR RESIN AND HARDENER TOGETHER) (ESTIMATED)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. ACIDS. ALDEHYDES. PHENOLICS. IRRITATING ORGANIC
FRAGMENTS.
INCOMPATIBLE MATERIALS:
STRONG ACIDS. STRONG OXIDIZING AGENTS. STRONG LEWIS ACIDS. STRONG MINERAL
ACIDS. BASES. AMINES. MERCAPTANS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
EXCESSIVE HEAT. STORE AWAY FROM INCOMPATIBLE MATERIALS. HEAT, FLAMES,
SPARKS AND OTHER SOURCES OF IGNITION.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE DIZZINESS, INCOORDINATION, HEADACHE, NAUSEA, AND VOMITING. MAY
CAUSE IRRITATION TO NOSE AND THROAT. MAY CAUSE LUNG DAMAGE.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
EPICHLOROHYDRIN-4,4'- NONE ALLERGEN, IRRITANT
ISOPROPYLIDENE DIPHENOL
RESIN
DIIRON TRIOXIDE NONE ALLERGEN, CARDIAC, CENTRAL
NERVOUS SYSTEM, IRRITANT,
KIDNEY, LIVER, LUNG
TREATED FUMED SILICA NONE IRRITANT
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
EPICHLOROHYDRIN-4,4'- NO NO NO
ISOPROPYLIDENE DIPHENOL
RESIN
DIIRON TRIOXIDE NO NO NO
TREATED FUMED SILICA NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY PACKAGE/
CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BISPHENOL-A
EPICHLORHYDRIN RESIN)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BISPHENOL-A
EPICHLORHYDRIN RESIN)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
MARINE POLLUTANT: BISPHENOL-A EPICHLORHYDRIN RESIN
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED AS ACTIVE OR ARE EXEMPT FROM LISTING ON THE
TOXIC SUBSTANCES CONTROL ACT (TSCA) INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 3,15
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 08/12/2020
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO
ADOPT SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY
AND PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND
USE OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL
SPECIFICALLY DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING
WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE,
ARISING FROM SALE OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS
ANY LIABILITY FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND,
INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION IN
ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION OF
ANY KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF ANY
OTHER JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION
PROVIDED HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY
OTHER JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY
AND REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 003.1
ISSUE DATE: 08/14/2020
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: LOCTITE PC 3965 HARDENER
IDH NUMBER: 2335629
ITEM NUMBER: 235605_1948480
PRODUCT TYPE/USE: 2-COMPONENT EPOXY ADHESIVE
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE AN ALLERGIC SKIN REACTION.
HAZARD CLASS HAZARD CATEGORY
SKIN CORROSION 1C - CORROSIVE
SERIOUS EYE DAMAGE 1
SKIN SENSITIZATION 1
PICTOGRAM(S):
CORROSION
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY
AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF
THE WORKPLACE. WEAR PROTECTIVE GLOVES, CLOTHING, EYE AND FACE PROTECTION.
RESPONSE:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR): TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL,
STATE/PROVINCIAL AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL 90-72-2 5 - 10
TITANIUM DIOXIDE 13463-67-7 1 - 5
ALUMINUM 7429-90-5 1 - 5
BIS[(DIMETHYLAMINO)METHYL]PHENOL 71074-89-0 1 - 5
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE
IS PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. IMMEDIATELY FLUSH SKIN WITH
PLENTY OF WATER (USING SOAP, IF AVAILABLE). GET MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING,
SUCH AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
PERSONNEL IN VICINITY AND DOWNWIND SHOULD BE EVACUATED. BURNING PRODUCES
OBNOXIOUS AND TOXIC FUMES. DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO
ENTER DRAINS OR WATER COURSES. USE OF WATER MAY RESULT IN THE FORMATION
OF VERY TOXIC AQUEOUS SOLUTIONS.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. OXIDES OF SULFUR. AMMONIA. HYDROGEN
SULFIDE. NITRIC ACID. TOXIC FUMES. IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
ENSURE ADEQUATE VENTILATION. WEAR APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION"
PRIOR TO CLEAN UP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND,
SILICA GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP SPILLED
MATERIAL AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. DO NOT TASTE OR SWALLOW. USE ONLY
WITH ADEQUATE VENTILATION. KEEP CONTAINER CLOSED.
STORAGE:
STORE IN ORIGINAL CONTAINER UNTIL READY TO USE. KEEP CONTAINER TIGHTLY
CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY FROM INCOMPATIBLE
MATERIALS. KEEP AWAY FROM HEAT, SPARK AND FLAME. PROTECT FROM DIRECT
SUNLIGHT.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL
2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL NONE NONE
TITANIUM DIOXIDE 10 MG/M3 TWA 15 MG/M3 PEL TOTAL
DUST.
15 MPPCF TWA
RESPIRABLE FRACTION.
15 MG/M3 TWA
TOTAL DUST.
50 MPPCF TWA
TOTAL DUST.
5 MG/M3 TWA
RESPIRABLE FRACTION.
ALUMINUM 1 MG/M3 TWA 15 MG/M3 PEL (AS AL)
RESPIRABLE TOTAL DUST.
FRACTION. 5 MG/M3 PEL (AS AL)
RESPIRABLE FRACTION.
15 MPPCF TWA
RESPIRABLE FRACTION.
50 MPPCF TWA
TOTAL DUST.
5 MG/M3 TWA
RESPIRABLE FRACTION.
15 MG/M3 TWA
TOTAL DUST.
BIS[(DIMETHYLAMINO)METHYL]PHENOL NONE NONE
HAZARDOUS COMPONENT(S) AIHA WEEL OTHER
2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL NONE NONE
TITANIUM DIOXIDE NONE NONE
ALUMINUM NONE NONE
BIS[(DIMETHYLAMINO)METHYL]PHENOL NONE NONE
ENGINEERING CONTROLS:
USE LOCAL VENTILATION IF GENERAL VENTILATION IS INSUFFICIENT TO MAINTAIN
VAPOR CONCENTRATION BELOW ESTABLISHED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: HIGHLY VISCOUS, PASTE
COLOR: GRAY
ODOR: MILD
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/ RANGE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: >96.11 DEG. C (>205 DEG. F) ASTM D3278 SETAFLASH CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0 %; 0 G/L CALIFORNIA SCAQMD METHOD 316B
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. OXIDES OF SULFUR. AMMONIA. HYDROGEN
SULFIDE. NITRIC ACID. TOXIC FUMES. IRRITATING VAPORS.
INCOMPATIBLE MATERIALS:
ACIDS. BASES. NITROUS ACID AND OTHER NITROSATING AGENTS. OXIDIZING AGENTS.
PEROXIDES. SODIUM HYPOCHLORITE. THIS PRODUCT SLOWLY CORRODES COPPER,
ALUMINUM, ZINC AND GALVANIZED SURFACES. CAUTION! N-NITROSAMINES (MANY
OF WHICH ARE KNOWN TO BE POTENT CARCINOGENS) MAY BE FORMED WHEN THE
PRODUCT COMES IN CONTACT WITH NITROUS ACID, NITRITES OR ATMOSPHERES
WITH HIGH NITROUS OXIDE CONCENTRATIONS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS. PROTECT
FROM DIRECT SUNLIGHT.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
INHALATION OF VAPORS OR MISTS OF THE PRODUCT MAY BE IRRITATING TO THE
RESPIRATORY SYSTEM.
SKIN CONTACT: CAUSES SKIN BURNS. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND
DELAYED HEALTH
EFFECTS
2,4,6-TRIS- NONE IRRITANT, ALLERGEN
(DIMETHYLAMINOMETHYL)-
PHENOL
TITANIUM DIOXIDE NONE IRRITANT, RESPIRATORY,
SOME EVIDENCE OF
CARCINOGENICITY
ALUMINUM NONE CENTRAL NERVOUS SYSTEM,
IRRITANT, LUNG
BIS[(DIMETHYLAMINO)- NONE NO RECORDS
METHYL]PHENOL
HAZARDOUS NTP IARC OSHA
COMPONENT(S) CARCINOGEN CARCINOGEN CARCINOGEN
(SPECIFICALLY REGULATED)
2,4,6-TRIS-
(DIMETHYLAMINOMETHYL)- NO NO NO
PHENOL
TITANIUM DIOXIDE NO GROUP 2B NO
ALUMINUM NO NO NO
BIS[(DIMETHYLAMINO)- NO NO NO
METHYL]PHENOL
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL GOVERNMENTAL REGULATIONS.
HAZARDOUS WASTE NUMBER:
IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE IF AN ITEM IS HAZARDOUS
AS DEFINED IN THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) AT THE
TIME OF DISPOSAL. PRODUCT USES, TRANSFORMATIONS, MIXTURES, PROCESSES,
ETC., MAY RENDER THE RESULTING MATERIAL HAZARDOUS, UNDER THE CRITERIA OF
IGNITABILITY, CORROSIVITY, REACTIVITY AND TOXICITY CHARACTERISTICS OF THE
TOXICITY CHARACTERISTICS LEACHING PROCEDURE (TCLP) 40 CFR 261.20-24.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES
TO THE MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED AS ACTIVE OR ARE EXEMPT FROM LISTING ON
THE TOXIC SUBSTANCES CONTROL ACT (TSCA) INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372).
ALUMINUM (CAS# 7429-90-5).
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO
CAUSE CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 15
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 08/14/2020
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR
ANY PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND
TO ADOPT SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF
PROPERTY AND PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE
HANDLING AND USE OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING,
HENKEL SPECIFICALLY DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED,
INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR
PURPOSE, ARISING FROM SALE OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER
DISCLAIMS ANY LIABILITY FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY
KIND, INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION IN
ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION OF
ANY KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF ANY
OTHER JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION
PROVIDED HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY
OTHER JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY
AND REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.