| Common Name: | LOCTITE EA E-04 A, 2061385_2024310 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 1/24/2022 |
| SDS Format: | No Format Specified |
| Item Number(s): | 52XF90 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 004.0
ISSUE DATE: 01/24/2022
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE EA E-04 A
IDH NUMBER: 2068407
PRODUCT TYPE/USE: EPOXY RESIN
ITEM NUMBER: 2061385_2024310
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER
HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. CONTAMINATED WORK
CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE
GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED
NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF
CHEMICALS (GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
EPICHLOROHYDRIN-4,4'-ISOPROPYLIDENE 25068-38-6 30 - 60
DIPHENOL RESIN
TALC 14807-96-6 10 - 30
2,3-EPOXYPROPYL NEODECANOATE 26761-45-5 5 - 10
TITANIUM DIOXIDE 13463-67-7 1 - 5
TRIPHENYL PHOSPHITE 101-02-0 1 - 5
SILICA, AMORPHOUS, FUMED, CRYST.-FREE 112945-52-5 1 - 5
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE
IS PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES
BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF
SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
UNCONTROLLED POLYMERIZATION MAY OCCUR AT HIGH TEMPERATURES RESULTING IN
EXPLOSIONS OR RUPTURE OF STORAGE CONTAINERS. CLOSED CONTAINERS MAY RUPTURE
(DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. OXIDES OF PHOSPHORUS. HYDROGEN
CYANIDE. PHENOLICS. IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
ENSURE ADEQUATE VENTILATION. WEAR APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION"
PRIOR TO CLEAN UP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND,
SILICA GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP SPILLED
MATERIAL AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. USE ONLY WITH ADEQUATE VENTILATION.
KEEP CONTAINER CLOSED.
STORAGE:
FOR SAFE STORAGE, STORE BETWEEN 2 DEG. C (35.6 DEG. F) AND 8 DEG. C
(46.4 DEG. F)
KEEP CONTAINER TIGHTLY CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY
FROM INCOMPATIBLE MATERIALS. KEEP AWAY FROM HEAT, SPARK AND FLAME. PROTECT
FROM DIRECT SUNLIGHT.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
EPICHLOROHYDRIN-4,4'- NONE NONE NONE NONE
ISOPROPYLIDENE
DIPHENOL RESIN
TALC 2 MG/M3 TWA 0.1 MG/M3 TWA NONE 50 PPM
RESPIRABLE RESPIRABLE.
FRACTION.
20 MPPCF TWA
2.4 MPPCF TWA
RESPIRABLE.
2,3-EPOXYPROPYL NONE NONE NONE NONE
NEODECANOATE
TITANIUM DIOXIDE 10 MG/M3 TWA 15 MG/M3 PEL NONE NONE
TOTAL DUST.
15 MPPCF TWA
RESPIRABLE
FRACTION.
15 MG/M3 TWA
TOTAL DUST.
50 MPPCF TWA
TOTAL DUST.
5 MG/M3 TWA
RESPIRABLE
FRACTION.
TRIPHENYL PHOSPHITE NONE NONE NONE NONE
SILICA, AMORPHOUS, 3 MG/M3 TWA 20 MPPCF TWA NONE NONE
FUMED, CRYST.-FREE RESPIRABLE
PARTICLES. 0.8 MG/M3 TWA
10 MG/M3 TWA 50 MPPCF TWA
INHALABLE TOTAL DUST.
PARTICLES.
5 MG/M3 TWA
RESPIRABLE
FRACTION.
15 MG/M3 TWA
TOTAL DUST.
15 MPPCF TWA
RESPIRABLE
FRACTION.
ENGINEERING CONTROLS:
USE LOCAL VENTILATION IF GENERAL VENTILATION IS INSUFFICIENT TO MAINTAIN
VAPOR CONCENTRATION BELOW ESTABLISHED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE, LIQUID
COLOR: WHITE
ODOR: SLIGHT
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.32
VAPOR DENSITY: >1
FLASH POINT: >100 DEG. C (>212 DEG. F) NO METHOD
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0%
VISCOSITY: 19,000.00 - 35,000.00 MPA.S
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. OXIDES OF PHOSPHORUS. HYDROGEN
CYANIDE. PHENOLICS. IRRITATING VAPORS.
INCOMPATIBLE MATERIALS:
ACIDS. BASES. OXIDIZING AGENTS. AMINES. REDUCING AGENTS. ISOCYANATES.
WATER.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS. PROTECT
FROM DIRECT SUNLIGHT.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
EPICHLOROHYDRIN-4,4'- NONE ALLERGEN, IRRITANT
ISOPROPYLIDENE DIPHENOL
RESIN
TALC NONE IRRITANT, LUNG, SOME
EVIDENCE OF
CARCINOGENICITY
2,3-EPOXYPROPYL NEODECANOATE INHALATION LC50 IRRITANT, ALLERGEN
(RAT, 4 H):
>240 MG/M3
TITANIUM DIOXIDE INHALATION LC50 IRRITANT, RESPIRATORY,
(RAT, 4 H): SOME EVIDENCE OF
>6.82 MG/L CARCINOGENICITY
INHALATION LC50
(RAT, 4 H):
>2.28 MG/L
INHALATION LC50
(RAT, 4 H):
>3.56 MG/L
TRIPHENYL PHOSPHITE ORAL LD50 (MOUSE): IRRITANT, ALLERGEN,
1,330 MG/KG NERVOUS SYSTEM
ORAL LD50 (RAT):
1,600 MG/KG
SILICA, AMORPHOUS, FUMED, NONE NO DATA
CRYST.-FREE
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY REGULATED)
EPICHLOROHYDRIN-4,4'- NO NO NO
ISOPROPYLIDENE DIPHENOL
RESIN
TALC NO NO NO
2,3-EPOXYPROPYL NO NO NO
NEODECANOATE
TITANIUM DIOXIDE NO GROUP 2B NO
TRIPHENYL PHOSPHITE NO NO NO
SILICA, AMORPHOUS, NO NO NO
FUMED, CRYST.-FREE
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES
TO THE MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
MARINE POLLUTANT: EPOXY RESIN
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED AS ACTIVE OR ARE EXEMPT FROM LISTING ON THE
TOXIC SUBSTANCES CONTROL ACT (TSCA) INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
CONTAINS ONE OR MORE COMPONENTS LISTED ON THE NON-DOMESTIC SUBSTANCES LIST.
ALL OTHER COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE
DOMESTIC SUBSTANCES LIST. COMPONENTS LISTED ON THE NDSL MUST BE TRACKED
BY ALL CANADIAN IMPORTERS OF RECORD AS REQUIRED BY ENVIRONMENT CANADA.
THEY MAY BE IMPORTED INTO CANADA IN LIMITED QUANTITIES. PLEASE CONTACT
REGULATORY AFFAIRS FOR ADDITIONAL DETAILS.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 3,8,9,11,13,15
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 01/24/2022
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION IN
ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION OF
ANY KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF ANY
OTHER JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION PROVIDED
HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY OTHER
JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY AND
REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.