| Common Name: | MARINE FIRESTOP CABLE COATING |
| Manufacturer: | SPECIFIED TECHNOLOGIES |
| SDS Revision Date: | 12/30/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 52ZW82 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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STI(R*)
SAFETY DATA SHEET
PREPARED TO U.S. OSHA, CMA, ANSI, CANADIAN WHMIS, THE KOREAN ISHA
(NOTICE 2009-68), THE JAPANESE INDUSTRIAL STANDARD JIS Z 7250:2000,
MEXICAN NOM018-STPS 2000, SPRING SINGAPORE, AND THE GLOBAL HARMONIZATION
STANDARD
| 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY UNDERTAKING
IDENTIFICATION OF THE MIXTURE:
TRADE/MATERIAL NAME: MARINE FIRESTOP(R*) CABLE COATING
RELEVANT USE OF THE SUBSTANCE: CABLE PROTECTION
USES ADVISED AGAINST: NONE
SUPPLIER/MANUFACTURER'S NAME (USA/CANADA):
STI MARINE: A DIVISION OF SPECIFIED TECHNOLOGIES, INC.
ADDRESS:
210 EVANS WAY,
SOMERVILLE, NEW JERSEY 08876
BUSINESS PHONE: (908) 526-8000 (8:00AM TO 5:00PM EASTERN STANDARD TIME)
EMERGENCY PHONE:
U.S., CANADA: 1-800-255-3924 (24 HRS)
INTERNATIONAL: +1-813-248-0585 (COLLECT-24 HRS)
SUPPLIER/IMPORTER'S NAME (ASIA):
ADDRESS:
BUSINESS PHONE:
EMAIL OF COMPETENT PERSON FOR INFORMATION ON SDS: TECHSERV@STIFIRESTOP.COM
NOTE:
ALL UNITED STATES OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION STANDARD
(29 CFR 1910.1200), U.S. STATE EQUIVALENT STANDARDS, CANADIAN WHMIS
[CONTROLLED PRODUCTS REGULATIONS], MEXICAN NOM018-STPS 2000, SPRING
SINGAPORE, AND JAPANESE JIS Z7250 REQUIRED INFORMATION IS INCLUDED IN
APPROPRIATE SECTIONS BASED ON THE U.S. ANSI Z400.1-2010 FORMAT. THIS
PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE COUNTRIES LISTED ABOVE.
| 2. HAZARD IDENTIFICATION | |
GLOBAL HARMONIZATION AND JAPANESE JIS Z7253 LABELING AND CLASSIFICATION:
THIS PRODUCT HAS BEEN CLASSIFIED PER UN GHS STANDARDS UNDER U.S., JAPANESE
AND OTHER APPLICABLE REGULATIONS THAT REQUIRE GLOBAL HARMONIZATION
COMPLIANCE.
CLASSIFICATION:
CARCINOGENIC CATEGORY 2, ACUTE ORAL TOXICITY CATEGORY 5, EYE IRRITATION
CATEGORY 2A, SKIN SENSITIZATION CATEGORY 1B, SPECIFIC TARGET ORGAN TOXICITY
(INHALATION-RESPIRATORY IRRITATION) SINGLE EXPOSURE CATEGORY 3, SPECIFIC
TARGET ORGAN TOXICITY (NEUROLOGICAL/ENDOCRINE SYSTEM) REPEATED EXPOSURE
CATEGORY 3, AQUATIC ACUTE TOXICITY CATEGORY 2, AQUATIC CHRONIC TOXICITY
CATEGORY 2
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
H351: SUSPECTED OF CAUSING CANCER.
H303: MAY BE HARMFUL IF SWALLOWED.
H319: CAUSES SERIOUS EYE IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H373:
MAY CAUSE DAMAGE TO NEUROLOGICAL AND ENDOCRINE SYSTEMS THROUGH PROLONGED
OR REPEATED EXPOSURE.
H401: TOXIC TO AQUATIC LIFE.
H411: TOXIC TO AQUATIC LIFE WITH LONG-LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P260: DO NOT BREATHE VAPORS, FUME.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280: WEAR PROTECTIVE GLOVES, CLOTHING, EYE PROTECTION AND FACE PROTECTION.
P284: WEAR RESPIRATORY PROTECTION.
RESPONSE:
P308 + P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO.
P337 + P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P302 + P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P333 + P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P304 + P340:
IF INHALED, REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION
COMFORTABLE FOR BREATHING.
P362 + P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
P312: CALL A POISON CENTER OR DOCTOR IF YOU FEEL UNWELL.
P321: SPECIFIC TREATMENT (REMOVE FROM EXPOSURE AND TREAT SYMPTOMS).
P391: COLLECT SPILLAGE.
STORAGE:
P403 + P233 + P405:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
P501:
DISPOSE OF CONTENTS/CONTAINERS IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
HAZARD SYMBOLS:
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
KOREAN ISHA (NOTICE 2009-68) LABELING AND CLASSIFICATION:
CLASSIFIED IN ACCORDANCE WITH ISHA NOTICE 2009-68. UNDER ISHA, NO
DIFFERENCES IN CLASSIFICATION ARE APPLICABLE.
| 3. COMPOSITION AND INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS WT%
ALUMINUM TRIHYDRATE 21645-51-2 20-30%
GROUND LIMESTONE 1317-65-3 10-20%
PROPRIETARY ACRYLIC POLYMER NOT AVAILABLE 5-15%
TERT-BUTYL DIPHENYL PHOSPHATE 56803-37-3 1-3%
TRIPHENYL PHOSPHATE 115-86-6 1-3%
FULLER'S EARTH 8031-18-3 1-2%
PROPYLENE GLYCOL 57-55-6 1-2%
TITANIUM DIOXIDE 13463-67-7 0.7-0.9%
CRYSTALLINE SILICA 14808-60-7 0.02-0.3%
WATER AND OTHER TRACE INGREDIENTS BALANCE
CHEMICAL CHINESE JAPANESE KOREAN TAIWAN LABEL ELEMENTS
NAME IECSC ENCS # ECL # NESCI GHS & JAPANESE
INVENTORY ECS JIS Z7253
CLASSIFICATION
KOREAN ISHA
CLASSIFICATION
GHS HAZARD
CODES
ALUMINUM LISTED 1-17 KE-00980 LISTED SELF
TRIHYDRATE CLASSIFICATION
GHS & JAPANESE
JIS Z7253:
CLASSI-
FICATION:
EYE IRRITATION
CAT. 2A
HAZARD CODES:
H319
KOREAN ISHA:
CLASSI-
FICATION:
EYE IRRITATION
CAT. 2A
HAZARD CODES:
H319
GROUND LISTED EXCEPTED KE-21996 LISTED CLASSIFICATION
LIMESTONE AS NOT APPLICABLE
MINERRAL
PROPRIETARY NOT NOT NOT NOT CLASSIFICATION
ACRYLIC DETERMINED DETERMINED DETERMINED DETERMINED NOT APPLICABLE
POLYMER
TERT-BUTYL LISTED NOT LISTED KE-28568 LISTED SELF
DIPHENYL CLASSIFICATION
PHOSPHATE
GHS & JAPANESE
JIS Z7253,
KOREAN ISHA:
CLASSI-
FICATION:
(NEUROLOGICAL/
ENDOCRINE
SYSTEMS)
RE CAT. 3,
AQUATIC
CHRONIC
TOXICITY
CAT. 1
HAZARD
STATEMENT
CODES:
H373, H400
TRIPHENYL LISTED 3-2522, KE-28568 LISTED SELF
PHOSPHATE 3-3363 CLASSIFICATION
GHS & JAPANESE
JIS Z7253,
KOREAN ISHA:
CLASSI-
FICATION:
ACUTE ORAL
TOXICITY
CAT. 4, SKIN
SENSITIZATION
CAT. 1B, STOT
(NEUROLOGICAL/
ENDOCRINE
SYSTEMS)
RE CAT. 3,
AQUATIC ACUTE
TOXICITY
CAT. 2,
AQUATIC
CHRONIC
TOXICITY
CAT. 2
HAZARD
STATEMENT
CODES:
H302, H317,
H373, H401,
H410
FULLER'S LISTED EXCEPTED KE-17288 LISTED CLASSIFICATION
EARTH AS MINERAL NOT APPLICABLE
PROPYLENE LISTED 2-234 KE-29267 LISTED CLASSIFICATION
GLYCOL NOT APPLICABLE
TITANIUM LISTED 1-558 KE-33390 LISTED SELF
DIOXIDE CLASSIFICATION
GHS & JAPANESE
JIS Z7253,
KOREAN ISHA:
CLASSI-
FICATION:
CARCINOGENIC
CAT. 2
HAZARD CODES:
H351I
CRYSTALLINE LISTED 1-548 KE-29983 LISTED SELF
SILICA CLASSIFICATION
GHS & JAPANESE
JIS Z7253,
KOREAN ISHA:
CLASSI-
FICATION:
CARCINOGENIC
CAT. 1, STOT
(INHALATION-
LUNGS)
RE CAT. 2
HAZARD
STATEMENT
CODES:
H350, H373
WATER AND CLASSIFICATION
OTHER TRACE NOT APPLICABLE
INGREDIENTS
SEE SECTION 16 FOR FULL TEXT OF CLASSIFICATION
| 4. FIRST-AID MEASURES | |
SKIN EXPOSURE:
IF ADVERSE SKIN EFFECTS OCCUR, DISCONTINUE USE AND FLUSH CONTAMINATED
AREA. SEEK MEDICAL ATTENTION IF ADVERSE EFFECT OCCURS AFTER FLUSHING.
INHALATION:
IF FUMES OR VAPORS ARE INHALED, REMOVE VICTIM TO FRESH AIR. SEEK MEDICAL
ATTENTION IF ADVERSE EFFECT CONTINUES AFTER REMOVAL TO FRESH AIR.
EYE EXPOSURE:
IF THIS PRODUCT CONTAMINATES THE EYES, RINSE EYES UNDER GENTLY RUNNING
WATER. USE SUFFICIENT FORCE TO OPEN EYELIDS AND THEN "ROLL" EYES WHILE
FLUSHING. MINIMUM FLUSHING IS FOR 20 MINUTES. THE CONTAMINATED INDIVIDUAL
MUST SEEK MEDICAL ATTENTION IF ANY ADVERSE EFFECT CONTINUES AFTER RINSING.
INGESTION:
IF THIS PRODUCT IS SWALLOWED, CALL PHYSICIAN OR POISON CONTROL CENTER FOR
MOST CURRENT INFORMATION. IF PROFESSIONAL ADVICE IS NOT AVAILABLE, DO NOT
INDUCE VOMITING. NEVER INDUCE VOMITING OR GIVE DILUENTS (MILK OR WATER) TO
SOMEONE WHO IS UNCONSCIOUS, HAVING CONVULSIONS, OR UNABLE TO SWALLOW.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
PRE-EXISTING RESPIRATORY, SKIN OR NEUROMUSCULAR DISORDERS MAY BE
AGGRAVATED BY OVEREXPOSURES TO THIS PRODUCT.
| 5. FIRE-FIGHTING MEASURES | |
NFPA RATING:
HEALTH 2
FLAMMABILITY 0
INSTABILITY 0
OTHER
HAZARD SCALE:
0 = MINIMAL
1 = SLIGHT
2 = MODERATE
3 = SERIOUS
4 = SEVERE
FLASH POINT: 260 DEG. C (500 DEG. F)
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABLE LIMITS (IN AIR BY VOLUME, %): NOT APPLICABLE.
FIRE EXTINGUISHING MEDIA:
USE EXTINGUISHING MATERIALS SUITABLE FOR THE SURROUNDING AREA.
UNSUITABLE FIRE EXTINGUISHING MEDIA: NONE KNOWN.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
THIS PRODUCT IS FORMULATED TO BE NON-FLAMMABLE AND NON-COMBUSTIBLE. WHEN
INVOLVED IN A FIRE, THIS MATERIAL MAY DECOMPOSE AND PRODUCE IRRITATING
VAPORS AND TOXIC GASES
EXPLOSION SENSITIVITY TO MECHANICAL IMPACT: NOT SENSITIVE.
EXPLOSION SENSITIVITY TO STATIC DISCHARGE: NOT SENSITIVE.
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS AND EMERGENCY PROCEDURES:
UNCONTROLLED RELEASES SHOULD BE RESPONDED TO BY TRAINED PERSONNEL USING
PRE-PLANNED PROCEDURES. PROPER PROTECTIVE EQUIPMENT SHOULD BE USED. CALL
CHEMTREC (1800-424-9300) FOR EMERGENCY ASSISTANCE. OR IF IN CANADA, CALL
CANUTEC (613-996-6666)
PERSONAL PROTECTIVE EQUIPMENT: PROPER PROTECTIVE EQUIPMENT SHOULD BE USED.
SMALL SPILLS: WEAR RUBBER GLOVES.
LARGE SPILLS:
MINIMUM PERSONAL PROTECTIVE EQUIPMENT SHOULD BE RUBBER GLOVES, RUBBER
BOOTS, FACE SHIELD.
METHODS FOR CLEAN-UP AND CONTAINMENT:
SPILLS OF THIS PRODUCT PRESENT MINIMAL HAZARD.
SMALL SPILLS:
SMALL RELEASES CAN BE CAREFULLY SWEPT UP OR CLEANED UP USING A DAMP SPONGE
OR POLYPADS.
LARGE SPILLS:
ACCESS TO THE SPILL AREA SHOULD BE RESTRICTED. FOR LARGE SPILLS, DIKE OR
OTHERWISE CONTAIN SPILL AND SWEEP-UP OR VACUUM WITH NON-SPARKING VACUUM.
ALL SPILLS:
PLACE ALL SPILL RESIDUE IN A DOUBLE PLASTIC BAG OR OTHER CONTAINMENT AND
SEAL. CLOSE OFF SEWERS AND TAKE OTHER MEASURES TO PROTECT HUMAN HEALTH AND
THE ENVIRONMENT AS NECESSARY. RINSE AREA WITH SOAP AND WATER SOLUTION AND
FOLLOW WITH A WATER RINSE. DISPOSE OF IN ACCORDANCE WITH APPLICABLE
FEDERAL, STATE, AND LOCAL PROCEDURES (SEE SECTION 13, DISPOSAL
CONSIDERATIONS). FOR SPILLS ON WATER, CONTAIN, MINIMIZE DISPERSION AND
COLLECT. DISPOSE OF RECOVERED MATERIAL AND REPORT SPILL PER REGULATORY
REQUIREMENTS.
ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
| 7. HANDLING AND USE | |
PRECAUTIONS FOR SAFE HANDLING:
AS WITH ALL CHEMICALS, AVOID GETTING THIS MATERIAL ON YOU OR IN YOU. DO
NOT EAT, DRINK, SMOKE, OR APPLY COSMETICS WHILE HANDLING THIS PRODUCT.
WASH HANDS THOROUGHLY AFTER HANDLING THIS PRODUCT OR CONTAINERS OF THIS
PRODUCT. AVOID BREATHING FUMES OR VAPORS GENERATED BY THIS PRODUCT. USE
IN A WELL-VENTILATED LOCATION.
CONDITIONS FOR SAFE STORAGE:
STORE CONTAINERS IN A COOL, DRY LOCATION, AWAY FROM DIRECT SUNLIGHT,
SOURCES OF INTENSE HEAT. DO NOT STORE ABOVE 55 DEG. C (131 DEG. F)
| 8. EXPOSURE CONTROLS - PERSONAL PROTECTION | |
EXPOSURE LIMITS/CONTROL PARAMETERS:
VENTILATION AND ENGINEERING CONTROLS:
USE WITH ADEQUATE VENTILATION TO ENSURE EXPOSURE LEVELS ARE MAINTAINED
BELOW THE LIMITS PROVIDED BELOW (IF APPLICABLE). EXHAUST DIRECTLY TO THE
OUTSIDE, TAKING NECESSARY PRECAUTIONS FOR ENVIRONMENTAL PROTECTION.
WORKPLACE EXPOSURE LIMITS/CONTROL PARAMETERS:
CHEMICAL NAME CAS # EXPOSURE LIMITS IN AIR
ACGIH-TLVS OSHA-PELS
TWA STEL TWA STEL
MG/M3 MG/M3 MG/M3 MG/M3
ALUMINUM 21645-51-2 NE NE NE NE
TRIHYDRATE
TERT-BUTYL 56803-37-3 NE NE NE NE
DIPHENYL
PHOSPHATE
CRYSTALLINE 14808-60-7 0.025 NE 30 MG/M3 (TOTAL DUST)/
SILICA (QUARTZ) (RESP. % SO2 + 2
FRACT.)
0.1 (VACATED 1989 PEL)
250 MPPCF (RESP. DUST)/
% SiO2 + 5
OR
10 MG/M3 (RESP. DUST)/
% SO2 + 2
FULLER'S EARTH 8031-18-3 NE NE NE NE
GROUND LIMESTONE 1317-65-3 NE NE 15 NE
(TOTAL
DUST)
1 (RESP.
TRACT.)
PROPRIETARY VINYL NE NE NE NE
ACETATE-BASED
POLYMER
PROPYLENE GLYCOL 57-55-6 NE NE NE NE
TITANIUM DIOXIDE 13463-67-7 10 NE 15 NE
(TOTAL
DUST)
10
(VACATED
1989 PEL)
TRIPHENYL PHOSPHATE 115-86-6 3 NE 3 NE
CHEMICAL NAME EXPOSURE LIMITS IN AIR
NIOSH-RELS NIOSH OTHER
TWA STEL IDLH MG/M3
MG/M3 MG/M3 MG/M3
ALUMINUM TRIHYDRATE NE NE NE DFG MAKS:
TWA: 4 MG/M3
(INHALABLE FRACTION)
1.5 MG/M3
(RESPIRABLE FRACTION)
DFG MAK PREGNANCY
RISK CLASSIFICATION: D
TERT-BUTYL DIPHENYL NE NE NE NE
PHOSPHATE
CRYSTALLINE SILICA 0.05 NE 50 CARCINOGEN:
(QUARTZ) (RESP. IARC-1
DUST) MAK-1
(RESPIRABLE FRACTION),
NOSH-CA,
NTP-K
(RESPIRABLE FRACTION),
TLV-A2
FULLER'S EARTH NE NE NE NE
GROUND LIMESTONE 10 (TOTAL NE NE NE
DUST)
1 (RESP.
TRACT.)
PROPRIETARY VINYL NE NE NE NE
ACETATE-BASED
POLYMER
PROPYLENE GLYCOL NE NE NE AIHA WEEL:
TWA: 10
TITANIUM DIOXIDE SEE POCKET 5000 CARCINOGEN:
GUIDE APP. A (Ca) IARC-2B
MAK-3A
NIOSH-CA
TLV-A3
TRIPHENYL PHOSPHATE 3 NE 1000 CARCINOGEN:
TLV-A4
NE = NOT ESTABLISHED.
MPPCF: MILLIONS OF PARTICLES PER CUBIC FOOT
SEE SECTION 16 FOR DEFINITIONS OF OTHER TERMS USED
INTERNATIONAL OCCUPATIONAL EXPOSURE LIMITS:
CURRENTLY, THE FOLLOWING ADDITIONAL EXPOSURE LIMIT VALUES HAVE BEEN
ESTABLISHED BY VARIOUS COUNTRIES FOR THE COMPONENTS OF THIS MIXTURE.
MORE CURRENT LIMITS MAY BE AVAILABLE; INDIVIDUAL COUNTRIES SHOULD BE
CONSULTED TO DETERMINE IF NEWER LIMITS ARE AVAILABLE.
ALUMINUM HYDROXIDE:
AUSTRALIA:
TWA: 2 MG(Al)/M3, JUL 2008
BELGIUM:
TWA: 2 MG(Al)/M3, MAR 2002
FINLAND:
TWA: 2 MG(Al)/M3, NOV 2011
FRANCE:
VME: 2 MG(Al)/M3, FEB 2006
KOREA:
TWA: 2 MG(Al)/M3, 2006
NEW ZEALAND:
TWA: 2 MG(Al)/M3, JAN 2002
RUSSIA:
TWA: 6 MG/M3, JUN 2003
SWEDEN:
TWA: 1 MG(Al)/M3, JUN 2005
SWITZERLAND:
MAK-W: 3 MG/M3, RESP, JAN 2011
UNITED KINGDOM:
TWA: 2 MG(Al)/M3, OCT 2007
IN ARGENTINA, BULGARIA, COLOMBIA, JORDAN, SINGAPORE, VIETNAM CHECK ACGIH
TLV
CRYSTALLINE SILICA:
AUSTRALIA:
TWA: 0.1 MG/M3, JUL 2008
BELGIUM:
TWA: 0.1 MG/M3 (RESP. DUST), MAR 2002
DENMARK:
TWA: 0.1 MG/M3 (RESPIRABLE), CARC, MAY 2011
DENMARK:
TWA: 0.1 MG/M3 (RESP.), CARC, MAY2011
DENMARK:
TWA: 0.3 MG/M3 (TOTAL), MAY 2011
FINLAND:
TWA: 0.05 MG/M3, RESP. DUST, SEP 2009
FRANCE:
VME: 0.1 MG/M3, (RESP), FEB 2006
ICELAND:
TWA: 0.1 MG/M3 (RESP. DUST), NOV 2011
JAPAN:
OEL-C: 0.03 MG/M3 (RESPIRABLE), APR 2007
KOREA:
TWA: 0.1 MG/M3, 2006
MEXICO:
TWA: 0.1 MG/M3 (RESPIRABLE), 2004
THE NETHERLANDS:
MAC-TGG: 0.075 MG/M3, 2003
NEW ZEALAND:
TWA: 0.2 MG/M3 (RESPIRABLE DUST), JAN 2002
NORWAY:
TWA: 0.1 MG/M3 (RESP. DUST), JAN 1999
NORWAY:
TWA: 0.3 MG/M3 (TOTAL DUST), JAN 1999
PERU:
TWA: 0.05 MG/M3, JUL 2005
RUSSIA:
TWA: 1 MG/M3
STEL: 3 MG/M3, JUN 2003
SWEDEN:
TWA: 0.1 MG/M3 (RESP. DUST), JUN 2005
SWITZERLAND:
MAK-W: 0.15 MG/M3, DEC 2006
THAILAND:
TWA: 10 MG/M3 (RESP. DUST), JAN 1993
THAILAND:
TWA: 30 MG/M3 (TOTAL DUST), JAN 1993
UNITED KINGDOM:
TWA: 0.1 MG/M3 (RESP. DUST), OCT 2007
IN ARGENTINA, BULGARIA, COLOMBIA, JORDAN, SINGAPORE, VIETNAM CHECK ACGIH
TLV
GROUND LIMESTONE:
BELGIUM:
TWA: 10 MG/M3, MAR 2002
HUNGARY:
TWA: 10 MG/M3, SEP 2000
JAPAN:
OEL: 2 MG/M3 (RESP. DUST), 84 MG/M3 (TOTAL DUST), MAY 2012
KOREA:
TWA: 10 MG/M3, 2006
MEXICO:
TWA: 10 MG/M3
STEL: 20 MG/M3 (INHALABLE), 2004
THE NETHERLANDS:
MAC-TGG: 10 MG/M3, 2003
NEW ZEALAND:
TWA: 10 MG/M3 (INSPIRABLE DUST), JAN 2002
POLAND:
MAC(TWA) DUST: 10 MG/M3, JAN 1999
RUSSIA:
STEL: 6 MG/M3, JUN 2003
SWITZERLAND:
MAK-W: 3 MG/M3, RESP, JAN 2011
UNITED KINGDOM:
TWA: 10 MG/M3 (INHAL. DUST), OCT 2007
UNITED KINGDOM:
TWA: 4 MG/M3 (RESPIRABLE DUST), OCT 2007
IN ARGENTINA, BULGARIA, COLOMBIA, JORDAN, SINGAPORE, VIETNAM CHECK ACGIH
TLV
PROPYLENE GLYCOL:
AUSTRALIA:
TWA: 10 MG/M3 (PARTICULATES), JUL 2008
AUSTRALIA:
TWA: 150 PPM (474 MG/M3) (TOTAL), JUL 2008
NEW ZEALAND:
TWA: 10 MG/M3 (PARTICULATES ONLY), JAN 2002
NEW ZEALAND:
TWA: 150 PPM (474 MG/M3) (VAPOR AND PARTICULATES), JAN 2002
RUSSIA:
STEL: 7 MG/M3, JUN 2003
UNITED KINGDOM:
TWA: 10 MG/M3 (PARTICULATE), OCT 2007
UNITED KINGDOM:
TWA: 150 PPM (474 MG/M3) (TOTAL VAPOR AND PARTICULATE), OCT 2007
TITANIUM DIOXIDE:
ARAB REPUBLIC OF EGYPT:
TWA: 15 MG/M3, JAN 1993
AUSTRIA:
MAK-TMW: 5 MG/M3
KZW: 10 MG/M3, RESP, 2007
BELGIUM:
TWA: 10 MG/M3, MAR 2002
DENMARK:
TWA: 6 MG(Ti)/M3, MAY 2011
FRANCE:
VME: 10 MG/M3, FEB 2006
GERMANY:
MAK: 1.5 MG/M3 (RESPIRABLE), 2005
ICELAND:
TWA: 6 MG(Ti)/M3, NOV 2011
JAPAN:
OEL: 1 MG/M3 (RESP. DUST), 4 MG/M3 (TOTAL DUST), MAY 2009
KOREA:
TWA: 10 MG/M3, 2006
MEXICO:
TWA: 10 MG(Ti)/M3
STEL: 20 MG(Ti)/M3, 2004
THE NETHERLANDS:
MAC-TGG: 10 MG/M3, 2003
NEW ZEALAND:
TWA: 10 MG/M3 (INSPIRABLE DUST), JAN 2002
NORWAY:
TWA: 5 MG/M3, JAN 1999
PERU:
TWA: 10 MG/M3, JUL 2005
POLAND:
MAC(TWA): 10 MG(Ti)/M3
MAC(STEL): 30 MG(Ti)/M3, JAN 1999
RUSSIA:
TWA: 10 MG/M3, JUN 2003
SWEDEN:
TWA: 5 MG/M3 (TOTAL DUST), JUN 2005
SWITZERLAND:
MAK-W: 3 MG/M3, DEC 2006
TURKEY:
TWA: 15 MG/M3, JAN 1993
UNITED KINGDOM:
TWA: 10 MG/M3 (INHAL. DUST), OCT 2007
UNITED KINGDOM:
TWA: 4 MG/M3 (RESP. DUST), OCT 2007
IN ARGENTINA, BULGARIA, COLOMBIA, JORDAN, SINGAPORE, VIETNAM CHECK ACGIH
TLV
TRIPHENYL PHOSPHATE:
AUSTRALIA:
TWA: 3 MG/M3, JUL 2008
AUSTRIA:
MAK-TMW: 3 MG/M3
KZW: 6 MG/M3, INHAL, 2007
BELGIUM:
TWA: 3 MG/M3, MAR 2002
DENMARK:
TWA: 3 MG/M3, MAY 2011
FINLAND:
TWA: 3 MG/M3
STEL: 6 MG/M3, NOV 2011
FRANCE:
VME: 3 MG/M3, FEB 2006
ICELAND:
TWA: 3 MG/M3, NOV 2011
KOREA:
TWA: 3 MG/M3, 2006
MEXICO:
TWA: 3 MG/M3
STEL: 6 MG/M3, 2004
THE NETHERLANDS:
MAC-TGG: 3 MG/M3, 2003
NEW ZEALAND:
TWA: 3 MG/M3, JAN 2002
NORWAY:
TWA: 3 MG/M3, JAN 1999
PERU:
TWA: 3 MG/M3, JUL 2005
RUSSIA:
STEL: 1 MG/M3, JUN 2003
SWITZERLAND:
MAK-W: 3 MG/M3, INHAL, JAN 2011
UNITED KINGDOM:
TWA: 3 MG/M3
STEL: 6 MG/M3, OCT 2007
IN ARGENTINA, BULGARIA, COLOMBIA, JORDAN, SINGAPORE, VIETNAM CHECK ACGIH
TLV
PROTECTIVE EQUIPMENT:
THE FOLLOWING INFORMATION ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT IS
PROVIDED TO ASSIST EMPLOYERS IN COMPLYING WITH OSHA REGULATIONS FOUND IN
29 CFR SUBPART I (BEGINNING AT 1910.132, INCLUDING U.S. FEDERAL OSHA
RESPIRATORY PROTECTION (29 CFR 1910.134), OSHA EYE PROTECTION 29 CFR
1910.133, OSHA HARD PROTECTION 29 CFR 1910.138, OSHA FOOT PROTECTION
29 CFR 1910.136 AND OSHA BODY PROTECTION 29 CFR 1910.132), EQUIVALENT
STANDARDS OF CANADA (INCLUDING CSA RESPIRATORY STANDARD Z94.4-02,
Z94.3-M1982, INDUSTRIAL EYE AND FACE PROTECTORS AND CSA STANDARD Z195-02,
PROTECTIVE FOOTWEAR), OR STANDARDS OF JAPAN (INCLUDING JIS T 8116:2005 FOR
GLOVE SELECTION, JIS T 8150:2006 FOR RESPIRATORY PPE, JIS T 8147:2003 FOR
EYE PROTECTORS, AND JIS T 8030:2005 FOR PROTECTIVE CLOTHING). PLEASE
REFERENCE APPLICABLE REGULATIONS AND STANDARDS FOR RELEVANT DETAILS.
RESPIRATORY PROTECTION:
MAINTAIN AIRBORNE CONTAMINANT CONCENTRATIONS BELOW EXPOSURE LIMITS LISTED
ABOVE. FOR MATERIALS WITHOUT LISTED EXPOSURE LIMITS, MINIMIZE RESPIRATORY
EXPOSURE. IF NECESSARY, USE ONLY RESPIRATORY PROTECTION AUTHORIZED UNDER
APPROPRIATE REGULATIONS.
EYE PROTECTION:
WEAR SPLASH GOGGLES OR SAFETY GLASSES AS APPROPRIATE FOR THE TASK.
HAND PROTECTION:
DURING MANUFACTURE OR OTHER SIMILAR OPERATIONS, WEAR THE APPROPRIATE HAND
PROTECTION FOR THE PROCESS.
SKIN PROTECTION:
USE APPROPRIATE PROTECTIVE CLOTHING. IF NECESSARY, REFER TO THE U.S. OSHA
TECHNICAL MANUAL (SECTION VII: PERSONAL PROTECTIVE EQUIPMENT) OR OTHER
APPROPRIATE REGULATIONS. FULL-BODY CHEMICAL PROTECTIVE CLOTHING IS
RECOMMENDED FOR EMERGENCY RESPONSE PROCEDURES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
FORM: PASTE.
COLOR: WHITE.
MOLECULAR FORMULA: MIXTURE.
MOLECULAR WEIGHT: MIXTURE.
ODOR: MILD ACRYLIC.
ODOR THRESHOLD: NOT AVAILABLE.
FLAMMABLE LIMITS (IN AIR BY VOLUME, %): NOT APPLICABLE.
OXIDIZING PROPERTIES: NOT APPLICABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
PERCENT VOLATILE: 22 +/- -2
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLASH POINT: NOT AVAILABLE.
FREEZING/MELTING POINT: NOT AVAILABLE.
BOILING POINT: >100 DEG. C (>212 DEG. F)
VAPOR PRESSURE: NOT AVAILABLE.
SPECIFIC GRAVITY (WATER = 1): 1.1
VAPOR DENSITY (AIR = 1): NOT AVAILABLE.
CARB VOC: 0.65 WT % (CALC.)
EVAPORATION RATE (N-BUAC = 1): >1
SCAQMD (U.S. EPA METHOD 24): 35 GM/L
SOLUBILITY IN WATER: INSOLUBLE.
SOLUBILITY IN SOLVENTS: NOT AVAILABLE.
COEFFICIENT WATER/OIL DISTRIBUTION: NOT ESTABLISHED.
PH: NOT AVAILABLE.
PERCENT SOLIDS: 74 +/- -2
HOW TO DETECT THIS SUBSTANCE (WARNING PROPERTIES IN EVENT OF ACCIDENTAL
RELEASE):
THE APPEARANCE MAY BE CHARACTERISTICS TO DISTINGUISH A RELEASE OF THIS
PRODUCT.
| 10. STABILITY AND REACTIVITY | |
CHEMICAL STABILITY:
THIS PRODUCT IS STABLE WHEN PROPERLY STORED AT NORMAL TEMPERATURE AND
PRESSURES (SEE SECTION 7, HANDLING AND STORAGE).
DECOMPOSITION PRODUCTS:
COMBUSTION:
IF EXPOSED TO EXTREMELY HIGH TEMPERATURES, THERMAL DECOMPOSITION MAY
GENERATE IRRITATING FUMES AND TOXIC GASES (E.G., ALUMINUM, CALCIUM,
CARBON, MAGNESIUM, PHOSPHOROUS AND TITANIUM OXIDES, AND ACRYLIC MONOMERS).
HYDROLYSIS: NONE KNOWN.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE:
THIS PRODUCT IS INCOMPATIBLE WITH STRONG OXIDIZERS.
POSSIBILITY OF HAZARDOUS POLYMERIZATION OR REACTION: WILL NOT OCCUR.
CONDITIONS TO AVOID:
AVOID EXPOSURE TO OR CONTACT WITH EXTREME TEMPERATURES AND INCOMPATIBLE
CHEMICALS.
| 11. TOXICOLOGICAL INFORMATION | |
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM:
HEALTH HAZARD (BLUE) 2*
FLAMMABILITY HAZARD (RED) 0
PHYSICAL HAZARD (YELLOW) 0
PROTECTIVE EQUIPMENT:
EYES: CHEMICAL GOGGLES
RESPIRATORY: SEE SECTION 8
HANDS: GLOVES
BODY: SEE SECTION 8
FOR ROUTINE INDUSTRIAL USE AND HANDLING APPLICATIONS
HAZARD SCALE:
0 = MINIMAL
1 = SLIGHT
2 = MODERATE
3 = SERIOUS
4 = SEVERE
* = CHRONIC HAZARD
SYMPTOMS OF EXPOSURE BY ROUTE OF EXPOSURE:
THE HEALTH HAZARD INFORMATION PROVIDED BELOW IS PERTINENT TO EMPLOYEES
USING THIS PRODUCT IN AN OCCUPATIONAL SETTING. THE FOLLOWING PARAGRAPHS
DESCRIBE THE SYMPTOMS OF EXPOSURE BY ROUTE OF EXPOSURE.
INHALATION:
INHALATION OF FUMES OR VAPORS MAY CAUSE IRRITATION OF THE NOSE, THROAT,
AND LUNGS AND CAUSE COUGHING. THIS PRODUCT CONTAINS TRACE AMOUNTS OF A
SUSPECTED HUMAN CARCINOGEN BY INHALATION; HOWEVER, THIS HAZARD IS NOT
EXPECTED TO BE SIGNIFICANT DUE TO VISCOSITY AND CONSISTENCY OF THE MIXTURE.
CONTACT WITH SKIN OR EYES:
DIRECT EYE CONTACT MAY CAUSE IRRITATION, REDNESS, AND TEARING FROM
MECHANICAL IRRITATION. PROLONGED OR REPEATED SKIN EXPOSURES MAY CAUSE
DERMATITIS (DRY RED SKIN).
SKIN ABSORPTION:
COMPONENTS ARE NOT KNOWN TO BE ABSORBED THROUGH INTACT SKIN.
INGESTION:
INGESTION IS NOT A SIGNIFICANT ROUTE OF OCCUPATIONAL EXPOSURE AND IS
UNLIKELY TO OCCUR.
INJECTION:
ACCIDENTAL INJECTION OF THIS PRODUCT, VIA LACERATION OR PUNCTURE BY A
CONTAMINATED OBJECT CAN CAUSE REDNESS AT THE SITE OF INJECTION. ANIMAL
DATA FOR THE CRYSTALLINE SILICA COMPONENT INDICATE THAT IT MAY CAUSE
CARCINOGENIC EFFECTS BY THIS ROUTE OF EXPOSURE.
OTHER HEALTH EFFECTS:
THE TRIPHENYL PHOSPHATE COMPONENT IS SUSPECTED TO BE AN ENDOCRINE
DISRUPTOR. CHRONIC EXPOSURE MAY CAUSE ADVERSE EFFECTS TO THE NEUROLOGICAL
SYSTEM DUE TO THE TRIPHENYL PHOSPHATE COMPONENT.
HEALTH EFFECTS OR RISKS FROM EXPOSURE:
EXPOSURE TO THIS PRODUCT MAY CAUSE THE FOLLOWING HEALTH EFFECTS:
ACUTE:
INHALATION OF FUMES OR VAPORS MAY CAUSE IRRITATION OF RESPIRATORY SYSTEM.
EYE CONTACT MAY CAUSE MECHANICAL IRRITATION.
CHRONIC:
PROLONGED OR REPEATED SKIN EXPOSURE MAY CAUSE DERMATITIS (DRY RED SKIN).
THIS PRODUCT CONTAINS TRACE AMOUNTS OF A SUSPECTED HUMAN CARCINOGEN BY
INHALATION; HOWEVER, THIS HAZARD IS NOT EXPECTED TO BE SIGNIFICANT DUE
TO VISCOSITY AND CONSISTENCY OF THE MIXTURE.
TARGET ORGANS: ACUTE: SKIN, EYES, RESPIRATORY SYSTEM.
CHRONIC: SKIN, NEUROLOGICAL SYSTEM, ENDOCRINE SYSTEM.
TOXICITY DATA:
CURRENTLY, THE FOLLOWING TOXICOLOGICAL DATA ARE AVAILABLE FOR COMPONENTS
OF 1% OR MORE CONCENTRATION.
ALUMINUM TRIHYDRATE:
TDLO (ORAL-CHILD):
79 GM/KG/2 YEARS-INTERMITTENT:
BEHAVIORAL:
CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY), MUSCLE CONTRACTION OR
SPASTICITY
MUSCULOSKELETAL: OSTEOMALACIA
TDLO (ORAL-CHILD):
122 GM/KG/4 DAYS:
GASTROINTESTINAL: OTHER CHANGES
NUTRITIONAL AND GROSS METABOLIC: BODY TEMPERATURE INCREASE
TDLO (ORAL-WOMAN):
84 GM/KG:
FEMALE 1-40 WEEK(S) AFTER CONCEPTION:
REPRODUCTIVE:
EFFECTS ON NEWBORN: PHYSICAL
TDLO (ORAL-INFANT):
68040 MG/KG/24 WEEKS-INTERMITTENT:
MUSCULOSKELETAL: OSTEOPOROSIS
NUTRITIONAL AND GROSS METABOLIC:
WEIGHT LOSS OR DECREASED WEIGHT GAIN, CHANGES IN PHOSPHORUS
TDLO (ORAL-WOMAN):
73912.5 MG/KG/26 WEEKS-INTERMITTENT:
BLOOD:
CHANGES IN SERUM COMPOSITION (E.G. TP, BILIRUBIN, CHOLESTEROL)
MUSCULOSKELETAL: OSTEOPOROSIS
NUTRITIONAL AND GROSS:
METABOLIC: CHANGES IN PHOSPHORUS
TDLO (UNREPORTED-INFANT):
39 GM/KG/24 DAYS-INTERMITTENT:
MUSCULOSKELETAL: OSTEOMALACIA
TDLO (ORAL-RAT):
15 MG/KG:
GASTROINTESTINAL: OTHER CHANGES
TDLO (ORAL-RAT):
8040 MG/KG/67 DAYS-CONTINUOUS:
BLOOD: CHANGES IN SERUM COMPOSITION (E.G. TP, BILIRUBIN, CHOLESTEROL)
NUTRITIONAL AND GROSS METABOLIC: CHANGES IN PHOSPHORUS
TDLO (ORAL-MOUSE):
80,880 MG/KG/23 WEEKS-CONTINUOUS:
LIVER: OTHER CHANGES
MUSCULOSKELETAL: OTHER CHANGES
NUTRITIONAL AND GROSS METABOLIC: CHANGES IN METALS, NOT OTHERWISE SPECIFIED
TDLO (INTRAPERITONEAL-RAT): 150 MG/KG
TDLO (INTRAPERITONEAL-RAT):
6240 MG/KG/26 WEEKS-INTERMITTENT:
BLOOD: PIGMENTED OR NUCLEATED RED BLOOD CELLS
NUTRITIONAL AND GROSS METABOLIC:
WEIGHT LOSS OR DECREASED WEIGHT GAIN, CHANGES IN IRON
TDLO (INTRAPERITONEAL-RAT):
1920 MG/KG/8 WEEKS-INTERMITTENT:
BLOOD: MICROCYTOSIS WITH OR WITHOUT ANEMIA
TDLO (INTRAPERITONEAL-RAT):
960 MG/KG/4 WEEKS-INTERMITTENT:
BLOOD: CHANGES IN ERYTHROCYTE (RBC) COUNT
GROUND LIMESTONE:
TDLO (INTRAVENOUS-RAT):
30 MG/KG:
VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION
LUNGS, THORAX, OR RESPIRATION: CHANGES IN LUNG WEIGHT
BLOOD: OTHER CHANGES
TCLO (INHALATION-RAT):
84 MG/M3/4 HOURS/40 WEEKS-INTERMITTENT:
LUNGS, THORAX, OR RESPIRATION: FIBROSIS (INTERSTITIAL)
LIVER: OTHER CHANGES
KIDNEY/URETER/BLADDER: OTHER CHANGES
TCLO (INHALATION-RAT):
250 MG/M3/2 HOURS/24 WEEKS-INTERMITTENT:
LUNGS, THORAX, OR RESPIRATION: FIBROSIS, FOCAL (PNEUMOCONIOSIS)
PROPYLENE GLYCOL:
STANDARD DRAIZE TEST (SKIN-HUMAN):
500 MG/7 DAYS: MILD
STANDARD DRAIZE TEST (SKIN-HUMAN):
104 MG/3 DAYS-INTERMITTENT: MODERATE
STANDARD DRAIZE TEST (SKIN-MAN): 10%/2 DAYS
STANDARD DRAIZE TEST (SKIN-CHILD):
30%/96 HOURS-CONTINUOUS: MODERATE
OPEN IRRITATION TEST (SKIN-WOMAN) 30%/96 HOURS: MILD
TDLO (ORAL-CHILD):
79 GM/KG/56 WEEKS-INTERMITTENT:
BRAIN AND COVERINGS: CHANGES IN SURFACE EEG
BEHAVIORAL: GENERAL ANESTHETIC, CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
TDLO (SKIN-HUMAN):
10 PPH:
SKIN AND APPENDAGES: DERMATITIS, ALLERGIC (AFTER TOPICAL EXPOSURE)
TDLO (PARENTERAL-INFANT):
10 GM/KG/3 DAYS-CONTINUOUS:
NUTRITIONAL AND GROSS METABOLIC: OTHER CHANGES
TDLO (SKIN-HUMAN):
5 MG/KG/7 DAYS-INTERMITTENT:
SKIN AND APPENDAGES: PRIMARY IRRITATION (AFTER TOPICAL EXPOSURE)
TDLO (SKIN-HUMAN):
4.5 MG/KG/3 DAYS-INTERMITTENT:
SKIN AND APPENDAGES: PRIMARY IRRITATION (AFTER TOPICAL EXPOSURE)
TDLO (SKIN-HUMAN):
10 PPH/48 HOURS-CONTINUOUS:
SKIN AND APPENDAGES: DERMATITIS, ALLERGIC (AFTER TOPICAL EXPOSURE)
TDLO (SKIN-MAN):
0.03 ML/KG/22 DAYS-INTERMITTENT:
SKIN AND APPENDAGES:
CUTANEOUS SENSITIZATION, EXPERIMENTAL (AFTER TOPICAL EXPOSURE)
TDLO (INTRAVENOUS-WOMAN):
5167 MG/KG/13 DAYS-CONTINUOUS:
NUTRITIONAL AND GROSS METABOLIC: METABOLIC ACIDOSIS
STANDARD DRAIZE TEST (EYE-RABBIT):
100 MG: MILD
STANDARD DRAIZE TEST (EYE-RABBIT):
500 MG/24 HOURS: MILD
LD50 (ORAL-RAT): 20 GM/KG
LD50 (ORAL-MOUSE): 22 GM/KG
LD50 (ORAL-MOUSE):
20,300 MG/KG:
BEHAVIORAL:
ATAXIA, TETANY; LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION
LD50 (SKIN-RABBIT): 20,800 MG/KG
LD50 (SKIN-RABBIT):
20,800 MG/KG:
BEHAVIORAL:
ATAXIA, TETANY LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION
DNA INHIBITION (SUBCUTANEOUS-MOUSE): 8000 MG/KG
CYTOGENETIC ANALYSIS (SUBCUTANEOUS-MOUSE): 8000 MG/KG
CYTOGENETIC ANALYSIS (HAMSTER FIBROBLAST): 32 GM/L
TRIPHENYL PHOSPHATE:
LD50 (ORAL-RAT):
3500 MG/KG:
BEHAVIORAL:
TREMOR, ATAXIA; GASTROINTESTINAL: HYPERMOTILITY, DIARRHEA
LD50 (ORAL-MOUSE):
1320 MG/KG:
SENSE ORGANS AND SPECIAL SENSES (OLFACTION):
EFFECT, NOT OTHERWISE SPECIFIED
BEHAVIORAL:
SOMNOLENCE (GENERAL DEPRESSED ACTIVITY), CHANGES IN MOTOR ACTIVITY
(SPECIFIC ASSAY)
LD50 (SKIN-RABBIT): >7900 MG/KG
LD50 (SKIN-GUINEA PIG): >4 GM/KG
LD50 (INTRAPERITONEAL-MOUSE): 1273 MG/KG
LC50 (INHALATION-MAMMAL-SPECIES UNSPECIFIED):
4200 MG/M3:
SENSE ORGANS AND SPECIAL SENSES (OLFACTION):
EFFECT, NOT OTHERWISE SPECIFIED
BEHAVIORAL:
SOMNOLENCE (GENERAL DEPRESSED ACTIVITY), CHANGES IN MOTOR ACTIVITY
(SPECIFIC ASSAY)
LD (ORAL-GUINEA PIG): >4 GM/KG
LD (INTRAPERITONEAL-RAT):
>5 GM/KG:
GASTROINTESTINAL: OTHER CHANGES
SKIN AND APPENDAGES: HAIR
LD (SUBCUTANEOUS-RAT): >3 GM/KG
LD (SUBCUTANEOUS-MOUSE): >3 GM/KG
LD (INTRAPERITONEAL-CAT):
>400 MG/KG:
PERIPHERAL NERVE AND SENSATION:
SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY), MUSCLE WEAKNESS
LD (SUBCUTANEOUS-GUINEA PIG): >3 GM/KG
LD (INTRAMUSCULAR-RABBIT): >1 GM/KG
LDLO (ORAL-CAT):
2 GM/KG:
BEHAVIORAL:
ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX), TREMOR, MUSCLE
WEAKNESS
LDLO (ORAL-RABBIT): 3 GM/KG
LDLO (ORAL-CHICKEN):
5 GM/KG:
SPINAL CORD: OTHER DEGENERATIVE CHANGES
LDLO (SUBCUTANEOUS-RABBIT): 1 GM/KG
LDLO (SUBCUTANEOUS-CAT):
300 MG/KG:
PERIPHERAL NERVE AND SENSATION:
FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE)
BEHAVIORAL: TREMOR, MUSCLE WEAKNESS
LDLO (SUBCUTANEOUS-MONKEY): 500 MG/KG
TDLO (ORAL-RAT):
65 GM/KG/65 DAYS-CONTINUOUS:
SPINAL CORD: OTHER DEGENERATIVE CHANGES
PERIPHERAL NERVE AND SENSATION:
SENSORY SYNDROME DIAGNOSTIC OF CENTRAL LESION
NUTRITIONAL AND GROSS METABOLIC: WEIGHT LOSS OR DECREASED WEIGHT GAIN
TDLO (ORAL-RAT):
59,353 MG/KG/35 DAYS-CONTINUOUS:
LIVER: CHANGES IN LIVER WEIGHT
TDLO (ORAL-CAT):
600 MG/KG/10 DAYS-INTERMITTENT:
BEHAVIORAL: TREMOR
NUTRITIONAL AND GROSS METABOLIC: OTHER CHANGES
TDLO (ORAL-CHICKEN):
25 GM/KG/5 DAYS-INTERMITTENT:
SPINAL CORD: OTHER DEGENERATIVE CHANGES
BEHAVIORAL: ATAXIA
TDLO (SKIN-BIRD-DOMESTIC):
1200 MG/KG/3 DAYS-INTERMITTENT:
SPINAL CORD: OTHER DEGENERATIVE CHANGES
BEHAVIORAL: ATAXIA
IRRITANCY OF PRODUCT:
INHALATION OF FUMES OR VAPORS MAY CAUSE RESPIRATORY IRRITATION. EYE CONTACT
MAY CAUSE IRRITATION. PROLONGED SKIN CONTACT MAY CAUSE IRRITATION.
SENSITIZATION OF PRODUCT:
DERMAL PATCH TESTS HAVE SHOWN THAT ALLERGIC CONTACT DERMATITIS MAY OCCUR
IN PERSONS SENSITIVE TO TRIPHENYL PHOSPHATE. CONTACT WITH THIS PRODUCT MAY
CAUSE ALLERGIC SKIN REACTIONS DUE TO THIS COMPONENT.
CARCINOGENIC POTENTIAL OF COMPONENTS:
COMPONENTS OF THIS PRODUCT ARE LISTED BY AGENCIES TRACKING THE CARCINOGENIC
POTENTIAL OF CHEMICAL COMPOUNDS, AS FOLLOWS:
CRYSTALLINE SILICA:
ACGIH-TLV-A2 (SUSPECTED HUMAN CARCINOGEN); IARC-1 (CARCINOGENIC TO HUMANS);
MAK-1 (SUBSTANCES THAT CAUSE CANCER IN MAN AND CAN BE ASSUMED TO MAKE A
SIGNIFICANT CONTRIBUTION TO CANCER RISK); NIOSH-CA (POTENTIAL OCCUPATIONAL
CARCINOGEN WITH NO FURTHER CATEGORIZATION); NTP-K (KNOWN TO BE A HUMAN
CARCINOGEN)
TITANIUM DIOXIDE:
ACGIH TLV-A4 (NOT CLASSIFIABLE AS A HUMAN CARCINOGEN); IARC-3
(UNCLASSIFIABLE AS TO CARCINOGENICITY IN HUMANS); NIOSH-CA (POTENTIAL
OCCUPATIONAL CARCINOGEN, WITH NO FURTHER CATEGORIZATION)
TRIPHENYL PHOSPHATE: ACGIH TLV-A4 (NOT CLASSIFIABLE AS A HUMAN CARCINOGEN)
THE REMAINING COMPONENTS ARE NOT FOUND ON THE FOLLOWING LISTS:
U.S. EPA, U.S. NTP, U.S. OSHA, U.S. NIOSH, GERMAN MAK, IARC, OR ACGIH AND
THEREFORE IS NEITHER CONSIDERED TO BE NOR SUSPECTED TO BE A CANCER-CAUSING
AGENT BY THESE AGENCIES.
REPRODUCTIVE TOXICITY INFORMATION:
COMPONENTS OF THIS PRODUCT HAVE NO REPORTED MUTAGENIC, EMBRYOTOXIC,
TERATOGENIC OR REPRODUCTIVE TOXICITY.
ACGIH BIOLOGICAL EXPOSURE INDICES (BEIS):
CURRENTLY, THERE ARE NO ACGIH BIOLOGICAL EXPOSURE INDICES (BEIS) DETERMINED
FOR THIS MATERIAL.
DEGREE OF EFFECT TO THE HEALTH OF THE POLLUTING AGENT OF ENVIRONMENT OF
WORK (PER MEXICAN NOM-010 STPS-1999): 0
| 12. ECOLOGICAL INFORMATION | |
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL
CONTAMINATION.
MOBILITY: THIS PRODUCT HAS NOT BEEN TESTED FOR MOBILITY IN SOIL.
PERSISTENCE AND BIODEGRADABILITY:
THIS PRODUCT HAS NOT BEEN TESTED FOR PERSISTENCE OR BIODEGRADABILITY.
THE MINERAL COMPONENTS ARE NOT EXPECTED TO BIODEGRADE TO GREAT EXTENT.
BIO-ACCUMULATION POTENTIAL:
THIS PRODUCT HAS NOT BEEN TESTED FOR BIO-ACCUMULATION POTENTIAL. THE
TERT-BUTYLPHENYL DIPHENYL PHOSPHATE COMPONENT HAS BCF VALUES 528, 785 AND
1096 IN FISH WHICH SUGGEST BIOCONCENTRATION IN AQUATIC ORGANISMS IS HIGH
TO VERY HIGH. THE TRIPHENYL PHOSPHATE COMPONENT HAS BCF VALUES RANGING
FROM 132 TO 573 AND SUGGEST THAT BIOCONCENTRATION IN AQUATIC ORGANISMS
IS HIGH.
ECOTOXICITY:
THIS PRODUCT HAS NOT BEEN TESTED FOR AQUATIC OR ANIMAL TOXICITY. ALL
RELEASES TO TERRESTRIAL, ATMOSPHERIC AND AQUATIC ENVIRONMENTS SHOULD BE
AVOIDED. THE FOLLOWING AQUATIC TOXICITY DATA ARE AVAILABLE FOR THE
TRIPHENYL PHOSPHATE COMPONENT.
TRIPHENYL PHOSPHATE:
LC50 (PIMEPHALES PROMELAS FATHEAD MINNOW) 96 HOURS: 0.87 MG/L
LC50 (PIMEPHALES PROMELAS FATHEAD MINNOW) 96 HOURS: 0.51 MG/L
LC50 (LEPTOMIS MACROCHIRUS) 96 HOURS: 290 MG/L, STATIC BIOASSAY
LC50 (MENIDIA BERYLLINA) 96 HOURS: 95 MG/L, STATIC BIOASSAY
LC50 (RAINBOW TROUT) 96 HOURS: 0.3 MG/L/STATIC BIOASSAY
LC50 (ORYZIAS LATIPES KILLFISH) 0.1-0.2 G) 96 HOURS:
1.2 MG/L; STATIC BIOASSAY AT 25 DEG. C
LC50 (CARASSIUS AURATUS GOLDFISH) 0.8-2.8 G) 96 HOURS:
0.70 MG/L; STATIC BIOASSAY
LC50 (ICTALURUS PUNCTATUS CHANNEL CATFISH); 0.23 G) 96 HOURS: 0.42 MG/L
LC50 (GAMMARUS PSEUDOLIMNAEUS SCUD) 96 HOURS: 250 PG/L
LC50 (POMACEA CANALICULATA SNAIL) 72 HOURS: 38,200 PG/L
LC50 (CHIRONOMUS RIPARIUS MIDGE) 48 HOURS: 360 PG/L
OTHER ADVERSE EFFECTS:
THIS MATERIAL IS NOT LISTED AS HAVING OZONE DEPLETION POTENTIAL.
ENVIRONMENTAL EXPOSURE CONTROLS:
CONTROLS SHOULD BE ENGINEERED TO PREVENT RELEASE TO THE ENVIRONMENT,
INCLUDING PROCEDURES TO PREVENT SPILLS, ATMOSPHERIC RELEASE AND RELEASE
TO WATERWAYS.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
IT IS THE RESPONSIBILITY OF THE GENERATOR TO DETERMINE AT THE TIME OF
DISPOSAL WHETHER THE PRODUCT MEETS THE CRITERIA OF A HAZARDOUS WASTE PER
REGULATIONS OF THE AREA IN WHICH THE WASTE IS GENERATED AND/OR DISPOSED
OF. WASTE DISPOSAL MUST BE IN ACCORDANCE WITH APPROPRIATE FEDERAL, STATE,
AND LOCAL REGULATIONS. THIS PRODUCT, IF UNALTERED BY USE, MAY BE DISPOSED
OF BY TREATMENT AT A PERMITTED FACILITY OR AS ADVISED BY YOUR LOCAL
HAZARDOUS WASTE REGULATORY AUTHORITY. SHIPMENT OF WASTES MUST BE DONE
WITH APPROPRIATELY PERMITTED AND REGISTERED TRANSPORTERS.
DISPOSAL CONTAINERS:
WASTE MATERIALS MUST BE PLACED IN AND SHIPPED IN APPROPRIATE 5-GALLON
OR 55-GALLON POLY OR METAL WASTE PAILS OR DRUMS. PERMEABLE CARDBOARD
CONTAINERS ARE NOT APPROPRIATE AND SHOULD NOT BE USED. ENSURE THAT ANY
REQUIRED MARKING OR LABELING OF THE CONTAINERS BE DONE TO ALL APPLICABLE
REGULATIONS.
PRECAUTIONS TO BE FOLLOWED DURING WASTE HANDLING:
WEAR PROPER PROTECTIVE EQUIPMENT WHEN HANDLING WASTE MATERIALS.
U.S. EPA WASTE NUMBER: NOT APPLICABLE.
| 14. TRANSPORTATION INFORMATION | |
U.S. DEPARTMENT OF TRANSPORTATION REGULATIONS:
THIS PRODUCT IS NOT CLASSIFIED AS DANGEROUS GOODS, PER U.S. DOT
REGULATIONS, UNDER 49 CFR 172.101.
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS:
THIS PRODUCT IS NOT CLASSIFIED AS DANGEROUS GOODS, PER REGULATIONS OF
TRANSPORT CANADA.
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA):
THIS PRODUCT IS NOT CLASSIFIED AS DANGEROUS GOODS UNDER RULES OF IATA.
INTERNATIONAL MARITIME ORGANIZATION (IMO) DESIGNATION:
THIS PRODUCT IS NOT CLASSIFIED AS DANGEROUS GOODS BY THE INTERNATIONAL
MARITIME ORGANIZATION.
OFFICIAL MEXICAN STANDARD; REGULATION FOR THE TRANSPORT OF DANGEROUS
GOODS AND RESIDUES:
THIS PRODUCT IS NOT CLASSIFIED AS DANGEROUS GOODS, PER TRANSPORT
REGULATIONS OF MEXICO.
SINGAPORE STANDARD 286:
PART A:
THIS PRODUCT HAS NO REQUIREMENTS UNDER THE SPECIFICATION FOR CAUTION
LABELING FOR HAZARDOUS SUBSTANCES
PART 4:
MARKING OF PACKAGES, CONTAINERS AND VEHICLES, AS IT DOES NOT MEET THE
CRITERIA FOR ANY HAZARD CLASS UNDER THIS REGULATION.
TRANSPORT IN BULK ACCORDING TO THE IBC CODE:
SEE THE INFORMATION UNDER THE INDIVIDUAL JURISDICTION LISTINGS FOR IBC
INFORMATION.
ENVIRONMENTAL HAZARDS:
THIS MATERIAL DOES NOT MEET THE CRITERIA OF ENVIRONMENTALLY HAZARDOUS
ACCORDING TO THE CRITERIA OF THE UN MODEL REGULATIONS (AS REFLECTED IN
THE IMDG CODE, ADR, RID, AND ADN) AND IS NOT LISTED IN ANNEX III UNDER
MARPOL 73/78.
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS:
THIS PRODUCT IS NOT SUBJECT TO THE REPORTING REQUIREMENTS OF SECTIONS
302, 304, AND 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND
REAUTHORIZATION ACT.
U.S. SARA HAZARD CATEGORIES (SECTION 311/312, 40 CFR 370-21):
ACUTE: YES
CHRONIC: YES
FIRE: NO
REACTIVE: NO
SUDDEN RELEASE: NO
U.S. SARA THRESHOLD PLANNING QUANTITY (TPQ):
THERE ARE NO SPECIFIC THRESHOLD PLANNING QUANTITIES FOR COMPONENTS. THE
DEFAULT FEDERAL SDS SUBMISSION AND INVENTORY REQUIREMENT FILING THRESHOLD
OF 10,000 LB (4,540 KG) MAY APPLY, PER 40 CFR 370.20.
U.S. CERCLA REPORTABLE QUANTITY (RQ): NOT APPLICABLE.
U.S. TSCA INVENTORY STATUS:
COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65):
THE CRYSTALLINE SILICA COMPONENT IS ON THE CALIFORNIA PROPOSITION 65 LISTS.
WARNING!
THIS PRODUCT CONTAINS A COMPOUND KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS:
COMPONENTS ARE ON THE DSL OR NDSL INVENTORIES.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS:
COMPONENTS ARE NOT ON THE CEPA PRIORITIES SUBSTANCES LISTS.
CANADIAN WHMIS CLASSIFICATION AND SYMBOLS:
THIS PRODUCT WOULD BE CATEGORIZED AS A CONTROLLED PRODUCT, D2B (OTHER TOXIC
EFFECTS-POTENTIAL CARCINOGENIC EFFECT, IRRITATION) AS PER THE CONTROLLED
PRODUCT REGULATIONS.
D2 - MATERIALS CAUSING OTHER TOXIC EFFECTS
CHINESE REGULATIONS:
CHINESE INVENTORY OF EXISTING CHEMICAL SUBSTANCES STATUS:
COMPONENTS LISTED BY CAS# ARE LISTED ON THE CHINESE INVENTORY OF EXISTING
CHEMICAL SUBSTANCES (IECSC).
JAPANESE REGULATIONS:
JAPANESE ENCS:
COMPONENTS LISTED BY CAS# ARE ON THE ENCS INVENTORY OR ARE EXCEPTED.
JAPANESE MINISTRY OF ECONOMY, TRADE, AND INDUSTRY (METI) STATUS:
COMPONENTS ARE NOT LISTED AS CLASS I SPECIFIED CHEMICAL SUBSTANCES,
CLASS II SPECIFIED CHEMICAL SUBSTANCES, OR DESIGNATED CHEMICAL SUBSTANCES
BY THE JAPANESE METI.
POISONOUS AND DELETERIOUS SUBSTANCES CONTROL LAW:
COMPONENTS ARE NOT LISTED AS A SPECIFIED POISONOUS SUBSTANCE UNDER THE
POISONOUS AND DELETERIOUS SUBSTANCES CONTROL LAW.
KOREAN REGULATIONS:
KOREAN EXISTING CHEMICALS LIST (ECL) STATUS:
COMPONENTS LISTED BY CAS# ARE LISTED ON THE KOREAN ECL INVENTORY.
MEXICAN REGULATIONS:
MEXICAN WORKPLACE REGULATIONS (NOM-018-STPS-2000):
THIS PRODUCT IS CLASSIFIED AS HAZARDOUS.
SINGAPORE REGULATIONS:
LIST OF CONTROLLED HAZARDOUS SUBSTANCES:
COMPONENTS LISTED BY CAS# ARE NOT LISTED ON THE SINGAPORE LIST OF
CONTROLLED SUBSTANCES.
CODE OF PRACTICE ON POLLUTION CONTROL REQUIREMENTS:
THE COMPONENTS IDENTIFIED BY CAS# IN SECTION 2 (COMPOSITION AND INFORMATION
ON INGREDIENTS) NOT ARE SUBJECT TO THE REQUIREMENTS UNDER THE SINGAPORE
CODE OF PRACTICE ON POLLUTION CONTROL.
TAIWANESE REGULATIONS:
TAIWAN EXISTING CHEMICAL SUBSTANCES INVENTORY STATUS:
COMPONENTS LISTED BY CAS# ARE LISTED ON THE TAIWAN EXISTING CHEMICALS LIST.
| 16. OTHER INFORMATION | |
REVISION DETAILS:
DECEMBER 30: ADDITION OF TITANIUM DIOXIDE TO INGREDIENTS.
REFERENCES AND DATA SOURCES: CONTACT THE SUPPLIER FOR INFORMATION.
METHODS OF EVALUATING INFORMATION FOR THE PURPOSE OF CLASSIFICATION:
CRITERIA OF THE GHS WERE USED FOR CLASSIFICATION.
PREPARED BY:
CHEMICAL SAFETY ASSOCIATES, INC.
PO BOX 1961
HILO, HI 96721 - 1961
(800) 441 -3365
DATE OF PRINTING: MAY 23, 2016
REVISION HISTORY: NEW.
SPECSEAL(R*) CABLE SPRAY SDS
EFFECTIVE DATE: DECEMBER 30, 2014