| Common Name: | PENTANE |
| Manufacturer: | HONEYWELL INTERNATIONAL |
| SDS Revision Date: | 9/29/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 53AZ48 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HONEYWELL
SAFETY DATA SHEET
PENTANE
000000020211
VERSION: 1.0
REVISION DATE: 09/29/2016
PRINT DATE: 10/10/2019
| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: PENTANE
NUMBER: 000000020211
PRODUCT USE DESCRIPTION: LABORATORY CHEMICALS
MANUFACTURER OR SUPPLIER'S DETAILS:
HONEYWELL INTERNATIONAL INC.
115 TABOR ROAD
MORRIS PLAINS, NJ 07950-2546
FOR MORE INFORMATION CALL:
1-800-368-0050
+1-231-726-3171
(MONDAY-FRIDAY, 9:00 AM-5:00 PM)
IN CASE OF EMERGENCY CALL:
MEDICAL: 1-800-498-5701 OR +1-303-389-1414
TRANSPORTATION (CHEMTREC): 1-800-424-9300 OR +1-703-527-3887
(24 HOURS/DAY, 7 DAYS/WEEK)
| SECTION 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
FORM: LIQUID
COLOR: COLOURLESS
ODOR: CHARACTERISTIC
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE LIQUIDS, CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, CATEGORY 3, CENTRAL
NERVOUS SYSTEM
ASPIRATION HAZARD, CATEGORY 1
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
SYMBOL(S):
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOUR.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
MAY CAUSE DROWSINESS AND DIZZINESS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
KEEP CONTAINER TIGHTLY CLOSED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER/DOCTOR.
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
DO NOT INDUCE VOMITING.
IN CASE OF FIRE:
USE DRY SAND, DRY CHEMICAL OR ALCOHOL-RESISTANT FOAM FOR EXTINCTION.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
KEEP COOL.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
CARCINOGENICITY:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP, IARC, OR
OSHA.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
FORMULA: C5H12
CHEMICAL NATURE: SUBSTANCE
CHEMICAL NAME CAS-NO. CONCENTRATION
PENTANE 109-66-0 >/=90.00 - </=100.00%
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
FIRST AIDER NEEDS TO PROTECT HIMSELF. MOVE OUT OF DANGEROUS AREA. TAKE OFF
ALL CONTAMINATED CLOTHING IMMEDIATELY. IF UNCONSCIOUS PLACE IN RECOVERY
POSITION AND SEEK MEDICAL ADVICE.
INHALATION:
IN CASE OF ACCIDENT BY INHALATION: REMOVE CASUALTY TO FRESH AIR AND KEEP AT
REST. CONSULT A PHYSICIAN.
SKIN CONTACT:
AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER. CALL A
PHYSICIAN IF IRRITATION DEVELOPS OR PERSISTS.
EYE CONTACT:
RINSE THOROUGHLY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS. PROTECT
UNHARMED EYE. CONSULT A PHYSICIAN.
INGESTION:
WHEN SWALLOWED, ALLOW WATER TO BE DRUNK. DO NOT INDUCE VOMITING. CALL A
PHYSICIAN IMMEDIATELY.
| SECTION 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY
FOAM
CARBON DIOXIDE (CO2)
DRY POWDER
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A SOLID WATER STREAM AS IT MAY SCATTER AND SPREAD FIRE.
SPECIFIC HAZARDS DURING FIREFIGHTING:
FLAMMABLE.
VAPOURS MAY FORM EXPLOSIVE MIXTURES WITH AIR.
VAPOURS ARE HEAVIER THAN AIR AND MAY SPREAD ALONG FLOORS.
VAPORS MAY TRAVEL TO AREAS AWAY FROM WORK SITE BEFORE IGNITING/FLASHING
BACK TO VAPOR SOURCE.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
WEAR AN APPROVED POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS IN
ADDITION TO STANDARD FIRE FIGHTING GEAR.
FURTHER INFORMATION:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
COLLECT CONTAMINATED FIRE EXTINGUISHING WATER SEPARATELY. THIS MUST NOT BE
DISCHARGED INTO DRAINS.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
EVACUATE PERSONNEL TO SAFE AREAS.
WEAR PERSONAL PROTECTIVE EQUIPMENT. UNPROTECTED PERSONS MUST BE KEPT AWAY.
ENSURE ADEQUATE VENTILATION.
REMOVE ALL SOURCES OF IGNITION.
ENVIRONMENTAL PRECAUTIONS:
DO NOT FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM.
METHODS FOR CLEANING UP:
VENTILATE THE AREA.
DO NOT USE SPARKING TOOLS.
USE EXPLOSION-PROOF EQUIPMENT.
CONTAIN SPILLAGE, SOAK UP WITH NON-COMBUSTIBLE ABSORBENT MATERIAL, (E.G.
SAND, EARTH, DIATOMACEOUS EARTH, VERMICULITE) AND TRANSFER TO A CONTAINER
FOR DISPOSAL ACCORDING TO LOCAL / NATIONAL REGULATIONS (SEE SECTION 13).
| SECTION 7. HANDLING AND STORAGE | |
HANDLING:
HANDLING:
WEAR PERSONAL PROTECTIVE EQUIPMENT.
USE ONLY IN WELL-VENTILATED AREAS.
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
KEEP PRODUCT AND EMPTY CONTAINER AWAY FROM HEAT AND
SOURCES OF IGNITION.
NO SMOKING.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES.
VAPOURS MAY FORM EXPLOSIVE MIXTURES WITH AIR.
STORAGE:
REQUIREMENTS FOR STORAGE AREAS AND CONTAINERS:
STORE IN AREA DESIGNED FOR STORAGE OF FLAMMABLE LIQUIDS. PROTECT FROM
PHYSICAL DAMAGE.
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
STORE IN ORIGINAL CONTAINER.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PROTECTIVE MEASURES:
ENSURE THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE
WORKSTATION LOCATION.
LEGAL REQUIREMENTS ARE TO BE CONSIDERED IN REGARD OF THE SELECTION, USE AND
CARE OF PERSONAL PROTECTIVE EQUIPMENT.
DO NOT BREATHE VAPOURS OR SPRAY MIST.
ENGINEERING MEASURES:
USE WITH LOCAL EXHAUST VENTILATION.
PREVENT VAPOUR BUILDUP BY PROVIDING ADEQUATE VENTILATION DURING AND AFTER
USE.
EYE PROTECTION: SAFETY GLASSES WITH SIDE-SHIELDS
HAND PROTECTION:
WEAR NITRILE RUBBER GLOVES TO AVOID CONTACT WITH THE SKIN.
GLOVES MUST BE INSPECTED PRIOR TO USE.
REPLACE WHEN WORN.
SKIN AND BODY PROTECTION: PROTECTIVE SUIT
RESPIRATORY PROTECTION:
IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT.
HYGIENE MEASURES:
TAKE OFF ALL CONTAMINATED CLOTHING IMMEDIATELY.
REMOVE AND WASH CONTAMINATED CLOTHING BEFORE RE-USE.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
WHEN USING DO NOT EAT OR DRINK.
EXPOSURE GUIDELINES:
COMPONENTS CAS-NO. VALUE CONTROL UPDATE BASIS
PARAMETERS
PENTANE 109-66-0 TWA: (1,000 PPM) 02 2014 ACGIH:
TIME WEIGHTED US. ACGIH
AVERAGE THRESHOLD
LIMIT VALUES
PENTANE 109-66-0 REL: 350 MG/M3 2005 NIOSH/GUIDE:
RECOMMENDED (120 PPM) US. NIOSH:
EXPOSURE LIMIT POCKET GUIDE
(REL): TO CHEMICAL
HAZARDS
PENTANE 109-66-0 CEIL TIME: 1,800 MG/M3 2005 NIOSH/GUIDE:
CEILING LIMIT (610 PPM) US. NIOSH:
VALUE AND TIME POCKET GUIDE
PERIOD (IF TO CHEMICAL
SPECIFIED): HAZARDS
PENTANE 109-66-0 PEL: 2,950 MG/M3 02 2006 OSHA_TRANS:
PERMISSIBLE (1,000 PPM) US. OSHA
EXPOSURE TABLE Z-1
LIMIT LIMITS FOR
AIR
CONTAMINANTS
(29 CFR
1910.1000)
PENTANE 109-66-0 STEL: 2,250 MG/M3 1989 Z1A:
SHORT TERM (750 PPM) US. OSHA
EXPOSURE LIMIT TABLE Z-1-A
(29 CFR
1910.1000)
PENTANE 109-66-0 TWA: 1,800 MG/M3 1989 Z1A:
TIME WEIGHTED (600 PPM) US. OSHA
AVERAGE TABLE Z-1-A
(29 CFR
1910.1000)
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: COLOURLESS
ODOR: CHARACTERISTIC
PH:
NOTE: NOT APPLICABLE
MELTING POINT/RANGE: -131 DEG. C
BOILING POINT/BOILING RANGE: 36 - 37 DEG. C
FLASH POINT: < -31 DEG. F (< -35 DEG. C)
LOWER EXPLOSION LIMIT: 1.4 %(V)
UPPER EXPLOSION LIMIT: 8 %(V)
VAPOR PRESSURE:
1,599 HPA AT 50 DEG. C(122 DEG. F)
684 HPA AT 25 DEG. C(77 DEG. F)
DENSITY: 0.631 G/CM3 AT 15 DEG. C
WATER SOLUBILITY:
NOTE: INSOLUBLE
IGNITION TEMPERATURE: 285 DEG. C
DECOMPOSITION TEMPERATURE:
NOTE: AT NORMAL PRESSURE MAY BE DISTILLED WITHOUT DECOMPOSITION.
VISCOSITY, DYNAMIC: 0.25 MPA.S AT 20 DEG. C
MOLECULAR WEIGHT: 72.15 G/MOL
| SECTION 10. STABILITY AND REACTIVITY | |
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID: HEAT, FLAMES AND SPARKS.
INCOMPATIBLE MATERIALS TO AVOID: STRONG OXIDIZING AGENTS
HAZARDOUS DECOMPOSITION PRODUCTS:
IN CASE OF FIRE HAZARDOUS DECOMPOSITION PRODUCTS MAY BE PRODUCED SUCH AS:
CARBON MONOXIDE, CARBON DIOXIDE AND UNBURNED HYDROCARBONS (SMOKE).
| SECTION 11. TOXICOLOGICAL INFORMATION | |
ACUTE ORAL TOXICITY:
LD50: >2,000 MG/KG
SPECIES: RAT
METHOD: OECD TEST GUIDELINE 401
ACUTE INHALATION TOXICITY:
LC50: 364 MG/L
EXPOSURE TIME: 4 H
SPECIES: RAT
SKIN IRRITATION:
NOTE: NON-IRRITANT
EYE IRRITATION:
NOTE: NON-IRRITANT
SENSITIZATION:
NOTE: NO DATA AVAILABLE
REPEATED DOSE TOXICITY:
PENTANE:
SPECIES: RAT
APPLICATION ROUTE: INHALATION
90-DAY INHALATION STUDY
NO OBSERVED ADVERSE EFFECT LEVEL
20,000 MG/M3
SPECIES: RAT
APPLICATION ROUTE: INHALATION
DEVELOPMENTAL TOXICITY
NO ADVERSE RESPONSE.
10,000 PPM
GENOTOXICITY IN VITRO:
GENOTOXICITY IN VIVO:
PENTANE:
SPECIES: RAT
CELL TYPE: MICRONUCLEUS
APPLICATION ROUTE: INHALATION
RESULT: NEGATIVE
ASPIRATION TOXICITY: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY EFFECTS:
TOXICITY TO FISH:
NOTE: NO DATA AVAILABLE
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50: 9.74 MG/L
EXPOSURE TIME: 48 H
SPECIES: DAPHNIA MAGNA (WATER FLEA)
TOXICITY TO ALGAE:
EC50: 1 MG/L
EXPOSURE TIME: 8 H
SPECIES: ALGAE
FURTHER INFORMATION ON ECOLOGY:
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
OBSERVE ALL FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT:
UN/ID NO.: UN 1265
PROPER SHIPPING NAME: PENTANES
CLASS: 3
PACKING GROUP: II
HAZARD LABELS: 3
IATA:
UN/ID NO.: UN 1265
DESCRIPTION OF THE GOODS: PENTANES
CLASS: 3
PACKAGING GROUP: II
HAZARD LABELS: 3
PACKING INSTRUCTION (CARGO AIRCRAFT): 364
PACKING INSTRUCTION (PASSENGER AIRCRAFT): 353
PACKING INSTRUCTION (PASSENGER AIRCRAFT): Y341
IMDG:
UN/ID NO.: UN 1265
DESCRIPTION OF THE GOODS: PENTANES
CLASS: 3
PACKAGING GROUP: II
HAZARD LABELS: 3
EMS NUMBER: F-E, S-D
MARINE POLLUTANT: NO
| SECTION 15. REGULATORY INFORMATION | |
INVENTORIES:
US. TOXIC SUBSTANCES CONTROL ACT: ON TSCA INVENTORY
AUSTRALIA. INDUSTRIAL CHEMICAL (NOTIFICATION AND ASSESSMENT) ACT:
ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
CANADA. CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA). DOMESTIC SUBSTANCES
LIST (DSL): ALL COMPONENTS OF THIS PRODUCT ARE ON THE CANADIAN DSL
JAPAN. KASHIN-HOU LAW LIST:
ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
KOREA. TOXIC CHEMICAL CONTROL LAW (TCCL) LIST:
ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
PHILIPPINES. THE TOXIC SUBSTANCES AND HAZARDOUS AND NUCLEAR WASTE CONTROL
ACT: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
CHINA. INVENTORY OF EXISTING CHEMICAL SUBSTANCES:
ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
NEW ZEALAND. INVENTORY OF CHEMICALS (NZIOC), AS PUBLISHED BY ERMA NEW
ZEALAND: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
NATIONAL REGULATORY INFORMATION:
SARA 302 COMPONENTS:
NO CHEMICALS IN THIS MATERIAL ARE SUBJECT TO THE REPORTING REQUIREMENTS OF
SARA TITLE III, SECTION 302.
SARA 313 COMPONENTS:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS ESTABLISHED
BY SARA TITLE III, SECTION 313.
SARA 311/312 HAZARDS: FIRE HAZARD
CALIFORNIA PROP. 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO STATE OF CALIFORNIA TO
CAUSE CANCER, BIRTH DEFECTS, OR ANY OTHER REPRODUCTIVE HARM.
MASSACHUSETTS RTK:
PENTANE 109-66-0
NEW JERSEY RTK:
PENTANE 109-66-0
PENNSYLVANIA RTK:
PENTANE 109-66-0
| SECTION 16. OTHER INFORMATION | |
HMIS III NFPA
HEALTH HAZARD 1 1
FLAMMABILITY 4 4
PHYSICAL HAZARD 0
INSTABILITY 0
HAZARD RATING AND RATING SYSTEMS (E.G. HMIS(R*) III, NFPA):
THIS INFORMATION IS INTENDED SOLELY FOR THE USE OF INDIVIDUALS TRAINED IN
THE PARTICULAR SYSTEM.
FURTHER INFORMATION
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT. FINAL DETERMINATION OF SUITABILITY
OF ANY MATERIAL IS THE SOLE RESPONSIBILITY OF THE USER. THIS INFORMATION
SHOULD NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT PROPERTIES.
CHANGES SINCE THE LAST VERSION ARE HIGHLIGHTED IN THE MARGIN. THIS VERSION
REPLACES ALL PREVIOUS VERSIONS.
PREPARED BY HONEYWELL PERFORMANCE MATERIALS AND TECHNOLOGIES PRODUCT
STEWARDSHIP GROUP