| Common Name: | DOWSIL 9-1363 INDUSTRIAL ASSEMBLY ADHESIVE SEALANT GREY |
| Manufacturer: | DOW CHEMICAL |
| SDS Revision Date: | 11/18/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 53DC56 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DOW(R*)
SAFETY DATA SHEET
THE DOW CHEMICAL COMPANY
PRODUCT NAME: DOWSIL(TM) 9-1363 INDUSTRIAL ASSEMBLY ADHESIVE SEALANT GREY
ISSUE DATE: 11/18/2019
PRINT DATE: 04/23/2020
THE DOW CHEMICAL COMPANY ENCOURAGES AND EXPECTS YOU TO READ AND UNDERSTAND
THE ENTIRE (M)SDS, AS THERE IS IMPORTANT INFORMATION THROUGHOUT THE
DOCUMENT. WE EXPECT YOU TO FOLLOW THE PRECAUTIONS IDENTIFIED IN THIS
DOCUMENT UNLESS YOUR USE CONDITIONS WOULD NECESSITATE OTHER APPROPRIATE
METHODS OR ACTIONS.
| 1. IDENTIFICATION |  |
PRODUCT NAME: DOWSIL(TM) 9-1363 INDUSTRIAL ASSEMBLY ADHESIVE SEALANT GREY
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
IDENTIFIED USES: ADHESIVE, BINDING AGENTS
COMPANY IDENTIFICATION:
THE DOW CHEMICAL COMPANY
2211 H.H. DOW WAY
MIDLAND MI 48674
UNITED STATES
CUSTOMER INFORMATION NUMBER: 800-258-2436
SDSQUESTION@DOW.COM
EMERGENCY TELEPHONE NUMBER:
24-HOUR EMERGENCY CONTACT:
CHEMTREC: +1 800-424-9300
LOCAL EMERGENCY CONTACT: 800-424-9300
| 2. HAZARDS IDENTIFICATION | |
HAZARD CLASSIFICATION:
GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910.1200
NOT A HAZARDOUS SUBSTANCE OR MIXTURE.
OTHER HAZARDS: NO DATA AVAILABLE
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NATURE: SILICONE
THIS PRODUCT IS A MIXTURE.
COMPONENT CASRN CONCENTRATION
TITANIUM(4+) 2-METHYLPROPAN-2- 3087-39-6 >=1.1 - <=2.5 %
OLATE
QUARTZ 14808-60-7 >=0.11 - <=0.2 %
| 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
FIRST AID RESPONDERS SHOULD PAY ATTENTION TO SELF-PROTECTION AND USE THE
RECOMMENDED PROTECTIVE CLOTHING (CHEMICAL RESISTANT GLOVES, SPLASH
PROTECTION). IF POTENTIAL FOR EXPOSURE EXISTS REFER TO SECTION 8 FOR
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT.
INHALATION:
MOVE PERSON TO FRESH AIR; IF EFFECTS OCCUR, CONSULT A PHYSICIAN.
EYE CONTACT:
FLUSH EYES THOROUGHLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES
AFTER THE INITIAL 1-2 MINUTES AND CONTINUE FLUSHING FOR SEVERAL ADDITIONAL
MINUTES. IF EFFECTS OCCUR, CONSULT A PHYSICIAN, PREFERABLY AN
OPHTHALMOLOGIST.
INGESTION: NO EMERGENCY MEDICAL TREATMENT NECESSARY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ASIDE FROM THE INFORMATION FOUND UNDER DESCRIPTION OF FIRST AID MEASURES
(ABOVE) AND INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED (BELOW), ANY ADDITIONAL IMPORTANT SYMPTOMS AND EFFECTS ARE DESCRIBED
IN SECTION 11: TOXICOLOGY INFORMATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN:
NO SPECIFIC ANTIDOTE. TREATMENT OF EXPOSURE SHOULD BE DIRECTED AT THE
CONTROL OF SYMPTOMS AND THE CLINICAL CONDITION OF THE PATIENT.
| 5. FIREFIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY. ALCOHOL-RESISTANT FOAM. CARBON DIOXIDE (CO2). DRY CHEMICAL.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN..
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HAZARDOUS COMBUSTION PRODUCTS:
SILICON OXIDES. FORMALDEHYDE. CARBON OXIDES. METAL OXIDES.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
EXPOSURE TO COMBUSTION PRODUCTS MAY BE A HAZARD TO HEALTH..
ADVICE FOR FIREFIGHTERS:
FIRE FIGHTING PROCEDURES:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT. USE WATER SPRAY TO COOL UNOPENED CONTAINERS.
COLLECT CONTAMINATED FIRE EXTINGUISHING WATER SEPARATELY. THIS MUST NOT BE
DISCHARGED INTO DRAINS. REMOVE UNDAMAGED CONTAINERS FROM FIRE AREA IF IT
IS SAFE TO DO SO. EVACUATE AREA.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS..
USE PERSONAL PROTECTIVE EQUIPMENT..
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT. FOLLOW SAFE HANDLING ADVICE AND PERSONAL
PROTECTIVE EQUIPMENT RECOMMENDATIONS.
ENVIRONMENTAL PRECAUTIONS:
DISCHARGE INTO THE ENVIRONMENT MUST BE AVOIDED. PREVENT FURTHER LEAKAGE OR
SPILLAGE IF SAFE TO DO SO. RETAIN AND DISPOSE OF CONTAMINATED WASH WATER.
LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE
CONTAINED.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
WIPE UP OR SCRAPE UP AND CONTAIN FOR SALVAGE OR DISPOSAL. LOCAL OR NATIONAL
REGULATIONS MAY APPLY TO RELEASES AND DISPOSAL OF THIS MATERIAL, AS WELL AS
THOSE MATERIALS AND ITEMS EMPLOYED IN THE CLEANUP OF RELEASES. YOU WILL
NEED TO DETERMINE WHICH REGULATIONS ARE APPLICABLE. FOR LARGE SPILLS,
PROVIDE DYKING OR OTHER APPROPRIATE CONTAINMENT TO KEEP MATERIAL FROM
SPREADING. IF DYKED MATERIAL CAN BE PUMPED, SECTIONS 13 AND 15 OF THIS SDS
PROVIDE INFORMATION REGARDING CERTAIN LOCAL OR NATIONAL REQUIREMENTS.
SEE SECTIONS: 7, 8, 11, 12 AND 13.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
DO NOT GET ON SKIN OR CLOTHING. DO NOT SWALLOW. AVOID CONTACT WITH EYES.
TAKE CARE TO PREVENT SPILLS, WASTE AND MINIMIZE RELEASE TO THE ENVIRONMENT.
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
USE ONLY WITH ADEQUATE VENTILATION. SEE ENGINEERING MEASURES UNDER EXPOSURE
CONTROLS/PERSONAL PROTECTION SECTION.
CONDITIONS FOR SAFE STORAGE:
KEEP IN PROPERLY LABELLED CONTAINERS. STORE IN ACCORDANCE WITH THE
PARTICULAR NATIONAL REGULATIONS.
DO NOT STORE WITH THE FOLLOWING PRODUCT TYPES: STRONG OXIDIZING AGENTS.
UNSUITABLE MATERIALS FOR CONTAINERS: NONE KNOWN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
IF EXPOSURE LIMITS EXIST, THEY ARE LISTED BELOW. IF NO EXPOSURE LIMITS
ARE DISPLAYED, THEN NO VALUES ARE APPLICABLE.
METHANOL ACGIH TWA 200 PPM
FURTHER INFORMATION: HEADACHE: HEADACHE; NAUSEA:
NAUSEA; DIZZINESS: DIZZINESS; EYE DAM: EYE DAMAGE;
BEI: SUBSTANCES FOR WHICH THERE IS A BIOLOGICAL
EXPOSURE INDEX OR INDICES (SEE BEI(R*) SECTION);
SKIN: DANGER OF CUTANEOUS ABSORPTION
ACGIH STEL 250 PPM
FURTHER INFORMATION: HEADACHE: HEADACHE; NAUSEA:
NAUSEA; DIZZINESS: DIZZINESS; EYE DAM: EYE DAMAGE;
BEI: SUBSTANCES FOR WHICH THERE IS A BIOLOGICAL
EXPOSURE INDEX OR INDICES (SEE BEI(R*) SECTION);
SKIN: DANGER OF CUTANEOUS ABSORPTION
OSHA Z-1 TWA 260 MG/M3
200 PPM
FURTHER INFORMATION: (B): THE VALUE IN MG/M3 IS
APPROXIMATE.
OSHA P0 STEL 325 MG/M3
250 PPM
FURTHER INFORMATION: X: SKIN NOTATION
OSHA P0 TWA 260 MG/M3
200 PPM
FURTHER INFORMATION: X: SKIN NOTATION
ALTHOUGH SOME OF THE COMPONENTS OF THIS PRODUCT MAY HAVE EXPOSURE
GUIDELINES, NO EXPOSURE WOULD BE EXPECTED UNDER NORMAL HANDLING
CONDITIONS DUE TO THE PHYSICAL STATE OF THE MATERIAL.
THE FOLLOWING SUBSTANCE(S), WHICH HAVE OCCUPATIONAL EXPOSURE LIMIT(S)
(OEL), MAY BE FORMED DURING HANDLING OR PROCESSING:
METHANOL.
BIOLOGICAL OCCUPATIONAL EXPOSURE LIMITS:
COMPONENTS CAS-NO. CONTROL BIOLOGICAL SAMPLING
PARAMETERS SPECIMEN TIME
METHANOL 67-56-1 METHANOL URINE END OF SHIFT (AS SOON AS
POSSIBLE AFTER EXPOSURE
CEASES)
COMPONENTS PERMISSIBLE CONCENTRATION BASIS
METHANOL 15 MG/L ACGIH BEI
EXPOSURE CONTROLS:
ENGINEERING CONTROLS:
USE LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN
AIRBORNE LEVELS BELOW EXPOSURE LIMIT REQUIREMENTS OR GUIDELINES. IF THERE
ARE NO APPLICABLE EXPOSURE LIMIT REQUIREMENTS OR GUIDELINES, GENERAL
VENTILATION SHOULD BE SUFFICIENT FOR MOST OPERATIONS. LOCAL EXHAUST
VENTILATION MAY BE NECESSARY FOR SOME OPERATIONS.
INDIVIDUAL PROTECTION MEASURES:
EYE/FACE PROTECTION: USE SAFETY GLASSES (WITH SIDE SHIELDS).
SKIN PROTECTION:
HAND PROTECTION:
USE GLOVES CHEMICALLY RESISTANT TO THIS MATERIAL. EXAMPLES OF PREFERRED
GLOVE BARRIER MATERIALS INCLUDE: BUTYL RUBBER. NEOPRENE. NITRILE/BUTADIENE
RUBBER ("NITRILE" OR "NBR"). ETHYL VINYL ALCOHOL LAMINATE ("EVAL").
POLYVINYL ALCOHOL ("PVA"). POLYVINYL CHLORIDE ("PVC" OR "VINYL"). VITON.
EXAMPLES OF ACCEPTABLE GLOVE BARRIER MATERIALS INCLUDE: NATURAL RUBBER
("LATEX"). NOTICE: THE SELECTION OF A SPECIFIC GLOVE FOR A PARTICULAR
APPLICATION AND DURATION OF USE IN A WORKPLACE SHOULD ALSO TAKE INTO
ACCOUNT ALL RELEVANT WORKPLACE FACTORS SUCH AS, BUT NOT LIMITED TO:
OTHER CHEMICALS WHICH MAY BE HANDLED, PHYSICAL REQUIREMENTS (CUT/PUNCTURE
PROTECTION, DEXTERITY, THERMAL PROTECTION), POTENTIAL BODY REACTIONS TO
GLOVE MATERIALS, AS WELL AS THE INSTRUCTIONS/SPECIFICATIONS PROVIDED BY
THE GLOVE SUPPLIER.
OTHER PROTECTION:
USE PROTECTIVE CLOTHING CHEMICALLY RESISTANT TO THIS MATERIAL. SELECTION
OF SPECIFIC ITEMS SUCH AS FACE SHIELD, BOOTS, APRON, OR FULL BODY SUIT
WILL DEPEND ON THE TASK.
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION SHOULD BE WORN WHEN THERE IS A POTENTIAL TO EXCEED
THE EXPOSURE LIMIT REQUIREMENTS OR GUIDELINES. IF THERE ARE NO APPLICABLE
EXPOSURE LIMIT REQUIREMENTS OR GUIDELINES, USE AN APPROVED RESPIRATOR. WHEN
RESPIRATORY PROTECTION IS REQUIRED, USE AN APPROVED POSITIVE-PRESSURE
SELF-CONTAINED BREATHING APPARATUS OR POSITIVE-PRESSURE AIRLINE WITH
AUXILIARY SELF-CONTAINED AIR SUPPLY.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: PASTE
COLOR: GREY
ODOR: ALCOHOL-LIKE
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT/RANGE: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT (760 MMHG): NOT APPLICABLE
FLASH POINT: NOT APPLICABLE
EVAPORATION RATE (BUTYL ACETATE = 1): NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT CLASSIFIED AS A FLAMMABILITY HAZARD
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOR PRESSURE: NOT APPLICABLE
RELATIVE VAPOR DENSITY (AIR = 1): NO DATA AVAILABLE
RELATIVE DENSITY (WATER = 1): 1.35
WATER SOLUBILITY: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
DYNAMIC VISCOSITY: NOT APPLICABLE
KINEMATIC VISCOSITY: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
OXIDIZING PROPERTIES:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS OXIDIZING.
MOLECULAR WEIGHT: NO DATA AVAILABLE
NOTE:
THE PHYSICAL DATA PRESENTED ABOVE ARE TYPICAL VALUES AND SHOULD
NOT BE CONSTRUED AS A SPECIFICATION.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NOT CLASSIFIED AS A REACTIVITY HAZARD.
CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: CAN REACT WITH STRONG OXIDIZING AGENTS.
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS
HAZARDOUS DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS CAN INCLUDE AND ARE NOT LIMITED TO:
FORMALDEHYDE. METHANOL. 1-BUTENE.
| 11. TOXICOLOGICAL INFORMATION | |
TOXICOLOGICAL INFORMATION APPEARS IN THIS SECTION WHEN SUCH DATA
IS AVAILABLE.
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
EYE CONTACT, SKIN CONTACT, INGESTION.
ACUTE TOXICITY (REPRESENTS SHORT TERM EXPOSURES WITH IMMEDIATE
EFFECTS - NO CHRONIC/DELAYED EFFECTS KNOWN UNLESS OTHERWISE NOTED):
ACUTE ORAL TOXICITY:
VERY LOW TOXICITY IF SWALLOWED. HARMFUL EFFECTS NOT ANTICIPATED FROM
SWALLOWING SMALL AMOUNTS.
AS PRODUCT: SINGLE DOSE ORAL LD50 HAS NOT BEEN DETERMINED.
BASED ON INFORMATION FOR COMPONENT(S):
LD50, RAT, >5,000 MG/KG ESTIMATED.
INFORMATION FOR COMPONENTS:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE:
LD50, RAT, 3,500 MG/KG
QUARTZ:
SINGLE DOSE ORAL LD50 HAS NOT BEEN DETERMINED.
ACUTE DERMAL TOXICITY:
PROLONGED SKIN CONTACT IS UNLIKELY TO RESULT IN ABSORPTION OF HARMFUL
AMOUNTS.
AS PRODUCT: THE DERMAL LD50 HAS NOT BEEN DETERMINED.
FOR THIS FAMILY OF MATERIALS:
LD50, RABBIT, >2,000 MG/KG ESTIMATED.
INFORMATION FOR COMPONENTS:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE:
THE DERMAL LD50 HAS NOT BEEN DETERMINED.
QUARTZ: THE DERMAL LD50 HAS NOT BEEN DETERMINED.
ACUTE INHALATION TOXICITY:
NO ADVERSE EFFECTS ARE ANTICIPATED FROM INHALATION. VAPOR FROM HEATED
MATERIAL MAY CAUSE RESPIRATORY IRRITATION.
AS PRODUCT: THE LC50 HAS NOT BEEN DETERMINED.
INFORMATION FOR COMPONENTS:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE: THE LC50 HAS NOT BEEN DETERMINED.
QUARTZ: THE LC50 HAS NOT BEEN DETERMINED.
SKIN CORROSION/IRRITATION:
BASED ON INFORMATION FOR COMPONENT(S):
BRIEF CONTACT MAY CAUSE SKIN IRRITATION WITH LOCAL REDNESS.
INFORMATION FOR COMPONENTS:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE:
BRIEF CONTACT MAY CAUSE SKIN IRRITATION WITH LOCAL REDNESS.
QUARTZ:
MAY CAUSE SKIN IRRITATION DUE TO MECHANICAL ABRASION.
MAY CAUSE DRYING AND FLAKING OF THE SKIN.
SERIOUS EYE DAMAGE/EYE IRRITATION:
BASED ON INFORMATION FOR COMPONENT(S): MAY CAUSE SLIGHT EYE IRRITATION.
INFORMATION FOR COMPONENTS:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE: MAY CAUSE EYE IRRITATION.
QUARTZ:
SOLID OR DUST MAY CAUSE IRRITATION OR CORNEAL INJURY DUE TO MECHANICAL
ACTION.
SENSITIZATION:
FOR SKIN SENSITIZATION: NO RELEVANT DATA FOUND.
FOR RESPIRATORY SENSITIZATION: NO RELEVANT DATA FOUND.
INFORMATION FOR COMPONENTS:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE:
FOR SKIN SENSITIZATION: NO RELEVANT DATA FOUND.
FOR RESPIRATORY SENSITIZATION: NO RELEVANT DATA FOUND.
QUARTZ:
FOR SKIN SENSITIZATION: NO RELEVANT DATA FOUND.
FOR RESPIRATORY SENSITIZATION: NO RELEVANT DATA FOUND.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE):
EVALUATION OF AVAILABLE DATA SUGGESTS THAT THIS MATERIAL IS NOT
AN STOT-SE TOXICANT.
INFORMATION FOR COMPONENTS:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE:
AVAILABLE DATA ARE INADEQUATE TO DETERMINE SINGLE EXPOSURE SPECIFIC
TARGET ORGAN TOXICITY.
QUARTZ:
EVALUATION OF AVAILABLE DATA SUGGESTS THAT THIS MATERIAL IS NOT AN
STOT-SE TOXICANT.
ASPIRATION HAZARD:
BASED ON AVAILABLE INFORMATION, ASPIRATION HAZARD COULD NOT BE DETERMINED.
INFORMATION FOR COMPONENTS:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE:
BASED ON AVAILABLE INFORMATION, ASPIRATION HAZARD COULD NOT BE DETERMINED.
QUARTZ:
BASED ON PHYSICAL PROPERTIES, NOT LIKELY TO BE AN ASPIRATION HAZARD.
CHRONIC TOXICITY (REPRESENTS LONGER TERM EXPOSURES WITH REPEATED DOSE
RESULTING IN CHRONIC/DELAYED EFFECTS - NO IMMEDIATE EFFECTS KNOWN
UNLESS OTHERWISE NOTED):
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (REPEATED EXPOSURE):
CONTAINS A COMPONENT(S) THAT IS/ARE NOT EXPECTED TO BE BIOAVAILABLE DUE
TO THE PHYSICAL STATE OF THE MATERIAL UNDER NORMAL HANDLING AND PROCESSING
CONDITIONS.
INFORMATION FOR COMPONENTS:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE: NO RELEVANT DATA FOUND.
QUARTZ:
IN HUMANS, EFFECTS HAVE BEEN REPORTED ON THE FOLLOWING ORGANS:
KIDNEY.
REPEATED EXCESSIVE EXPOSURE TO CRYSTALLINE SILICA MAY CAUSE SILICOSIS,
A PROGRESSIVE AND DISABLING DISEASE OF THE LUNGS.
DUE TO THE PHYSICAL STATE OF THE MATERIAL, THIS COMPONENT IS NOT
EXPECTED TO BE BIOAVAILABLE UNDER NORMAL HANDLING AND PROCESSING
CONDITIONS.
CARCINOGENICITY:
BASED ON INFORMATION FOR COMPONENT(S):
DID NOT CAUSE CANCER IN LONG-TERM ANIMAL STUDIES WHICH USED ROUTES OF
EXPOSURE CONSIDERED RELEVANT TO INDUSTRIAL HANDLING. POSITIVE RESULTS
HAVE BEEN REPORTED IN OTHER STUDIES USING ROUTES OF EXPOSURE NOT
RELEVANT TO INDUSTRIAL HANDLING.
CONTAINS A COMPONENT(S) THAT IS/ARE NOT EXPECTED TO BE BIOAVAILABLE DUE
TO THE PHYSICAL STATE OF THE MATERIAL UNDER NORMAL HANDLING AND PROCESSING
CONDITIONS.
INFORMATION FOR COMPONENTS:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE: NO RELEVANT DATA FOUND.
QUARTZ:
HAS CAUSED CANCER IN HUMANS. HAS CAUSED CANCER IN LABORATORY ANIMALS. DUE
TO THE PHYSICAL STATE OF THE MATERIAL, THIS COMPONENT IS NOT EXPECTED TO
BE BIOAVAILABLE UNDER NORMAL HANDLING AND PROCESSING CONDITIONS.
TERATOGENICITY:
CONTAINS COMPONENT(S) WHICH DID NOT CAUSE BIRTH DEFECTS OR ANY OTHER FETAL
EFFECTS IN LAB ANIMALS.
INFORMATION FOR COMPONENTS:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE: NO RELEVANT DATA FOUND.
QUARTZ:
FOR SIMILAR MATERIAL(S):
DID NOT CAUSE BIRTH DEFECTS OR ANY OTHER FETAL EFFECTS IN LABORATORY
ANIMALS.
REPRODUCTIVE TOXICITY:
CONTAINS COMPONENT(S) WHICH DID NOT INTERFERE WITH REPRODUCTION IN ANIMAL
STUDIES. CONTAINS COMPONENT(S) WHICH DID NOT INTERFERE WITH FERTILITY IN
ANIMAL STUDIES.
INFORMATION FOR COMPONENTS:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE: NO RELEVANT DATA FOUND.
QUARTZ: NO RELEVANT DATA FOUND.
MUTAGENICITY:
CONTAINS A COMPONENT(S) WHICH WERE NEGATIVE IN IN VITRO GENETIC TOXICITY
STUDIES.
INFORMATION FOR COMPONENTS:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE: NO RELEVANT DATA FOUND.
QUARTZ:
IN VITRO GENETIC TOXICITY STUDIES WERE NEGATIVE IN SOME CASES AND POSITIVE
IN OTHER CASES.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION APPEARS IN THIS SECTION WHEN SUCH DATA
IS AVAILABLE.
TOXICITY:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE:
ACUTE TOXICITY TO FISH: NO RELEVANT DATA FOUND.
QUARTZ:
ACUTE TOXICITY TO FISH:
NOT EXPECTED TO BE ACUTELY TOXIC TO AQUATIC ORGANISMS.
PERSISTENCE AND DEGRADABILITY:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE:
BIODEGRADABILITY: NO RELEVANT DATA FOUND.
QUARTZ:
BIODEGRADABILITY: BIODEGRADATION IS NOT APPLICABLE.
BIOACCUMULATIVE POTENTIAL:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE:
BIOACCUMULATION: NO RELEVANT DATA FOUND.
QUARTZ:
BIOACCUMULATION: PARTITIONING FROM WATER TO N-OCTANOL IS NOT APPLICABLE.
MOBILITY IN SOIL:
TITANIUM(4+) 2-METHYLPROPAN-2-OLATE: NO RELEVANT DATA FOUND.
QUARTZ: NO RELEVANT DATA FOUND.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. ALL
DISPOSAL PRACTICES MUST BE IN COMPLIANCE WITH ALL FEDERAL, STATE/PROVINCIAL
AND LOCAL LAWS AND REGULATIONS. REGULATIONS MAY VARY IN DIFFERENT
LOCATIONS. WASTE CHARACTERIZATIONS AND COMPLIANCE WITH APPLICABLE LAWS ARE
THE RESPONSIBILITY SOLELY OF THE WASTE GENERATOR. AS YOUR SUPPLIER, WE HAVE
NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF
PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE
PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS
DESCRIBED IN MSDS SECTION: COMPOSITION INFORMATION. FOR
UNUSED & UNCONTAMINATED PRODUCT, THE PREFERRED OPTIONS INCLUDE SENDING TO A
LICENSED, PERMITTED: INCINERATOR OR OTHER THERMAL DESTRUCTION DEVICE. FOR
ADDITIONAL INFORMATION, REFER TO: HANDLING & STORAGE INFORMATION, MSDS
SECTION 7 STABILITY & REACTIVITY INFORMATION, MSDS SECTION10 REGULATORY
INFORMATION, MSDS SECTION 15
TREATMENT AND DISPOSAL METHODS OF USED PACKAGING:
EMPTY CONTAINERS SHOULD BE RECYCLED OR OTHERWISE DISPOSED OF BY AN APPROVED
WASTE MANAGEMENT FACILITY. WASTE CHARACTERIZATIONS AND COMPLIANCE WITH
APPLICABLE LAWS ARE THE RESPONSIBILITY SOLELY OF THE WASTE GENERATOR. DO
NOT RE-USE CONTAINERS FOR ANY PURPOSE.
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED FOR TRANSPORT
CLASSIFICATION FOR SEA TRANSPORT (IMO-IMDG): NOT REGULATED FOR TRANSPORT
TRANSPORT IN BULK ACCORDING TO ANNEX I OR II OF MARPOL 73/78 AND THE
IBC OR IGC CODE:
CONSULT IMO REGULATIONS BEFORE TRANSPORTING OCEAN BULK
CLASSIFICATION FOR AIR TRANSPORT (IATA/ICAO): NOT REGULATED FOR TRANSPORT
THIS INFORMATION IS NOT INTENDED TO CONVEY ALL SPECIFIC REGULATORY OR
OPERATIONAL REQUIREMENTS/INFORMATION RELATING TO THIS PRODUCT.
TRANSPORTATION CLASSIFICATIONS MAY VARY BY CONTAINER VOLUME AND MAY BE
INFLUENCED BY REGIONAL OR COUNTRY VARIATIONS IN REGULATIONS. ADDITIONAL
TRANSPORTATION SYSTEM INFORMATION CAN BE OBTAINED THROUGH AN AUTHORIZED
SALES OR CUSTOMER SERVICE REPRESENTATIVE. IT IS THE RESPONSIBILITY OF THE
TRANSPORTING ORGANIZATION TO FOLLOW ALL APPLICABLE LAWS, REGULATIONS AND
RULES RELATING TO THE TRANSPORTATION OF THE MATERIAL.
| 15. REGULATORY INFORMATION | |
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY
PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986) SECTIONS 311 AND 312:
NO SARA HAZARDS
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EMERGENCY
PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986) SECTION 313:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS
ESTABLISHED BY SARA TITLE III, SECTION 313.
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
OF 1980 (CERCLA) SECTION 103:
CALCULATED RQ EXCEEDS REASONABLY ATTAINABLE UPPER LIMIT.
COMPONENTS CASRN RQ (RCRA CODE)
METHANOL 67-56-1 5000 LBS RQ
METHANOL 67-56-1 100 LBS RQ (F003)
METHANOL 67-56-1 5000 LBS RQ
METHANOL 67-56-1 100 LBS RQ (F003)
PENNSYLVANIA RIGHT TO KNOW:
THE FOLLOWING CHEMICALS ARE LISTED BECAUSE OF THE ADDITIONAL REQUIREMENTS
OF PENNSYLVANIA LAW:
COMPONENTS CASRN
DIMETHYL SILOXANE, TRIMETHOXYSILYL-TERMINATED NOT AVAILABLE
CALCIUM CARBONATE TREATED WITH STEARIC ACID NOT AVAILABLE
SILOXANES AND SILICONES, DIMETHYL 63148-62-9
AMORPHOUS FUMED SILICA 112945-52-5
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO CHEMICALS INCLUDING METHANOL, WHICH IS/ARE
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM. FOR MORE INFORMATION GO TO WWW.P65WARNINGS.CA.GOV.
UNITED STATES TSCA INVENTORY (TSCA):
ALL COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE INVENTORY LISTING
REQUIREMENTS OF THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL
SUBSTANCE INVENTORY.
| 16. OTHER INFORMATION | |
HAZARD RATING SYSTEM:
NFPA:
HEALTH 1
FLAMMABILITY 1
INSTABILITY 0
HMIS:
HEALTH 0/
FLAMMABILITY 1
PHYSICAL HAZARD 0
REVISION:
IDENTIFICATION NUMBER: 4001590 / A001
ISSUE DATE: 11/18/2019
VERSION: 7.0
MOST RECENT REVISION(S) ARE NOTED BY THE BOLD, DOUBLE BARS IN LEFT-HAND
MARGIN THROUGHOUT THIS DOCUMENT.
LEGEND:
ACGIH: USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
ACGIH BEI: ACGIH - BIOLOGICAL EXPOSURE INDICES (BEI)
OSHA P0: USA. OSHA - TABLE Z-1 LIMITS FOR AIR CONTAMINANTS - 1910.1000
OSHA Z-1:
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z-1 LIMITS FOR AIR
CONTAMINANTS
STEL: SHORT-TERM EXPOSURE LIMIT
TWA: 8-HOUR, TIME-WEIGHTED AVERAGE
FULL TEXT OF OTHER ABBREVIATIONS:
AICS: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES
ASTM: AMERICAN SOCIETY FOR THE TESTING OF MATERIALS
BW: BODY WEIGHT
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
CMR: CARCINOGEN, MUTAGEN OR REPRODUCTIVE TOXICANT
DIN: STANDARD OF THE GERMAN INSTITUTE FOR STANDARDISATION
DOT: DEPARTMENT OF TRANSPORTATION
DSL: DOMESTIC SUBSTANCES LIST (CANADA)
ECX: CONCENTRATION ASSOCIATED WITH X% RESPONSE
EHS: EXTREMELY HAZARDOUS SUBSTANCE
ELX: LOADING RATE ASSOCIATED WITH X% RESPONSE
EMS: EMERGENCY SCHEDULE
ENCS: EXISTING AND NEW CHEMICAL SUBSTANCES (JAPAN)
ERCX: CONCENTRATION ASSOCIATED WITH X% GROWTH RATE RESPONSE
ERG: EMERGENCY RESPONSE GUIDE
GHS: GLOBALLY HARMONIZED SYSTEM
GLP: GOOD LABORATORY PRACTICE
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC:
INTERNATIONAL CODE FOR THE CONSTRUCTION AND EQUIPMENT OF SHIPS CARRYING
DANGEROUS CHEMICALS IN BULK
IC50: HALF MAXIMAL INHIBITORY CONCENTRATION
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
IECSC: INVENTORY OF EXISTING CHEMICAL SUBSTANCES IN CHINA
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
IMO: INTERNATIONAL MARITIME ORGANIZATION
ISHL: INDUSTRIAL SAFETY AND HEALTH LAW (JAPAN)
ISO: INTERNATIONAL ORGANISATION FOR STANDARDIZATION
KECI: KOREA EXISTING CHEMICALS INVENTORY
LC50: LETHAL CONCENTRATION TO 50 % OF A TEST POPULATION
LD50: LETHAL DOSE TO 50% OF A TEST POPULATION (MEDIAN LETHAL DOSE)
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS
MSHA: MINE SAFETY AND HEALTH ADMINISTRATION
N.O.S.: NOT OTHERWISE SPECIFIED
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NO(A)EC: NO OBSERVED (ADVERSE) EFFECT CONCENTRATION
NO(A)EL: NO OBSERVED (ADVERSE) EFFECT LEVEL
NOELR: NO OBSERVABLE EFFECT LOADING RATE
NTP: NATIONAL TOXICOLOGY PROGRAM
NZIOC: NEW ZEALAND INVENTORY OF CHEMICALS
OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
OPPTS: OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC SUBSTANCE
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES;
(Q)SAR: (QUANTITATIVE) STRUCTURE ACTIVITY RELATIONSHIP
RCRA: RESOURCE CONSERVATION AND RECOVERY ACT
REACH:
REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
CONCERNING THE REGISTRATION, EVALUATION, AUTHORISATION AND RESTRICTION OF
CHEMICALS
RQ: REPORTABLE QUANTITY
SADT: SELF-ACCELERATING DECOMPOSITION TEMPERATURE
SARA: SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
SDS: SAFETY DATA SHEET
TCSI: TAIWAN CHEMICAL SUBSTANCE INVENTORY
TSCA: TOXIC SUBSTANCES CONTROL ACT (UNITED STATES)
UN: UNITED NATIONS
UNRTDG: UNITED NATIONS RECOMMENDATIONS ON THE TRANSPORT OF DANGEROUS GOODS
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
INFORMATION SOURCE AND REFERENCES:
THIS SDS IS PREPARED BY PRODUCT REGULATORY SERVICES AND HAZARD
COMMUNICATIONS GROUPS FROM INFORMATION SUPPLIED BY INTERNAL
REFERENCES WITHIN OUR COMPANY.
THE DOW CHEMICAL COMPANY URGES EACH CUSTOMER OR RECIPIENT OF THIS (M)SDS
TO STUDY IT CAREFULLY AND CONSULT APPROPRIATE EXPERTISE, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
(M)SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THE INFORMATION HEREIN
IS PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE
DATE SHOWN ABOVE. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN.
REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN
VARIOUS LOCATIONS. IT IS THE BUYER'S/USER'S RESPONSIBILITY TO ENSURE THAT
HIS ACTIVITIES COMPLY WITH ALL FEDERAL, STATE, PROVINCIAL OR LOCAL LAWS.
THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED.
SINCE CONDITIONS FOR USE OF THE PRODUCT ARE NOT UNDER THE CONTROL OF THE
MANUFACTURER, IT IS THE BUYER'S/USER'S DUTY TO DETERMINE THE CONDITIONS
NECESSARY FOR THE SAFE USE OF THIS PRODUCT. DUE TO THE PROLIFERATION OF
SOURCES FOR INFORMATION SUCH AS MANUFACTURER-SPECIFIC (M)SDSS, WE ARE
NOT AND CANNOT BE RESPONSIBLE FOR (M)SDSS OBTAINED FROM ANY SOURCE OTHER
THAN OURSELVES. IF YOU HAVE OBTAINED AN (M)SDS FROM ANOTHER SOURCE OR IF
YOU ARE NOT SURE THAT THE (M)SDS YOU HAVE IS CURRENT, PLEASE CONTACT US
FOR THE MOST CURRENT VERSION.
US
(R*) (TM) TRADEMARK OF THE DOW CHEMICAL COMPANY ("DOW") OR AN AFFILIATED
COMPANY OF DOW