| Common Name: | 730 FS SOLVENT RESISTANT SEALANT |
| Manufacturer: | DOW CORNING |
| SDS Revision Date: | 11/10/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 53DC65, 53DC66, 53DC67 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DOW CORNING
SAFETY DATA SHEET
DOW CORNING(R) 730 FS SOLVENT RESISTANT SEALANT
VERSION: 5.1
REVISION DATE: 11/10/2016
SDS NUMBER: 970187-00009
DATE OF LAST ISSUE: 10/14/2016
DATE OF FIRST ISSUE: 03/20/2015
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: DOW CORNING(R) 730 FS SOLVENT RESISTANT SEALANT
PRODUCT CODE: 000000000004097353
MANUFACTURER OR SUPPLIER'S DETAILS:
COMPANY NAME OF SUPPLIER: DOW CORNING CORPORATION
ADDRESS:
SOUTH SAGINAW ROAD
MIDLAND MICHIGAN 48686
TELEPHONE: (989) 496-6000
EMERGENCY TELEPHONE:
24 HOUR EMERGENCY TELEPHONE: (989) 496-5900
CHEMTREC: (800) 424-9300
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE:
CORROSION INHIBITORS
ADHESIVE, BINDING AGENTS
COATINGS
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION IN ACCORDANCE WITH 29 CFR 1910.1200:
SKIN CORROSION: CATEGORY 1B
SERIOUS EYE DAMAGE: CATEGORY 1
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS: CORROSION
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P260: DO NOT BREATHE DUSTS OR MISTS.
P264: WASH SKIN THOROUGHLY AFTER HANDLING.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
P301 + P330 + P331 + P310:
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. IMMEDIATELY CALL A POISON
CENTER/DOCTOR.
P303 + P361 + P353 + P310:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER. IMMEDIATELY CALL A POISON CENTER/DOCTOR.
P304 + P340 + P310:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. IMMEDIATELY
CALL A POISON CENTER/DOCTOR.
P305 + P351 + P338 + P310:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER/DOCTOR.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
P370 + P261:
IN CASE OF FIRE: AVOID BREATHING FUME.
STORAGE:
P405: STORE LOCKED UP.
DISPOSAL:
P501: DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
CHEMICAL NATURE: FLUOROSILICONE ELASTOMER
HAZARDOUS INGREDIENTS:
CHEMICAL NAME CAS-NO. CONCENTRATION (% W/W)
HEXAMETHYLDISILAZANE REACTION 68909-20-6 >=7 - <=8
WITH SILICA
TITANIUM DIOXIDE 13463-67-7 >=6 - <=7
VINYLTRIACETOXYSILANE 4130-08-9 >=5 - <=7
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
IN THE CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY.
WHEN SYMPTOMS PERSIST OR IN ALL CASES OF DOUBT SEEK MEDICAL ADVICE.
IF INHALED:
IF INHALED, REMOVE TO FRESH AIR.
IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION.
IF BREATHING IS DIFFICULT, GIVE OXYGEN.
GET MEDICAL ATTENTION IMMEDIATELY.
IN CASE OF SKIN CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR
AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
GET MEDICAL ATTENTION IMMEDIATELY.
WASH CLOTHING BEFORE REUSE.
THOROUGHLY CLEAN SHOES BEFORE REUSE.
IN CASE OF EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES.
IF EASY TO DO, REMOVE CONTACT LENS, IF WORN.
GET MEDICAL ATTENTION IMMEDIATELY.
IF SWALLOWED:
IF SWALLOWED, DO NOT INDUCE VOMITING.
IF VOMITING OCCURS HAVE PERSON LEAN FORWARD.
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
RINSE MOUTH THOROUGHLY WITH WATER.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
CAUSES DIGESTIVE TRACT BURNS.
CAUSES SERIOUS EYE DAMAGE.
CAUSES SEVERE BURNS.
PROTECTION OF FIRST-AIDERS:
FIRST AID RESPONDERS SHOULD PAY ATTENTION TO SELF-PROTECTION, AND USE THE
RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT WHEN THE POTENTIAL FOR EXPOSURE
EXISTS.
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
| SECTION 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY
ALCOHOL-RESISTANT FOAM
CARBON DIOXIDE (CO2)
DRY CHEMICAL
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS DURING FIRE FIGHTING:
VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR.
VERY TOXIC VAPORS ARE EVOLVED.
EXPOSURE TO COMBUSTION PRODUCTS MAY BE A HAZARD TO HEALTH.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON OXIDES
SILICON OXIDES
FLUORINE COMPOUNDS
FORMALDEHYDE
NITROGEN OXIDES (NOX)
METAL OXIDES
SPECIFIC EXTINGUISHING METHODS:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES
AND THE SURROUNDING ENVIRONMENT.
USE WATER SPRAY TO COOL UNOPENED CONTAINERS.
REMOVE UNDAMAGED CONTAINERS FROM FIRE AREA IF IT IS SAFE TO DO SO.
EVACUATE AREA.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
USE PERSONAL PROTECTIVE EQUIPMENT.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT.
FOLLOW SAFE HANDLING ADVICE AND PERSONAL PROTECTIVE EQUIPMENT
RECOMMENDATIONS.
ENVIRONMENTAL PRECAUTIONS:
DISCHARGE INTO THE ENVIRONMENT MUST BE AVOIDED.
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
RETAIN AND DISPOSE OF CONTAMINATED WASH WATER.
LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE
CONTAINED.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SOAK UP WITH INERT ABSORBENT MATERIAL.
FOR LARGE SPILLS, PROVIDE DIKING OR OTHER APPROPRIATE CONTAINMENT TO KEEP
MATERIAL FROM SPREADING. IF DIKED MATERIAL CAN BE PUMPED, STORE RECOVERED
MATERIAL IN APPROPRIATE CONTAINER.
CLEAN UP REMAINING MATERIALS FROM SPILL WITH SUITABLE ABSORBENT.
LOCAL OR NATIONAL REGULATIONS MAY APPLY TO RELEASES AND DISPOSAL OF THIS
MATERIAL, AS WELL AS THOSE MATERIALS AND ITEMS EMPLOYED IN THE CLEANUP OF
RELEASES. YOU WILL NEED TO DETERMINE WHICH REGULATIONS ARE APPLICABLE.
SECTIONS 13 AND 15 OF THIS SDS PROVIDE INFORMATION REGARDING CERTAIN LOCAL
OR NATIONAL REQUIREMENTS.
| SECTION 7. HANDLING AND STORAGE | |
TECHNICAL MEASURES:
SEE ENGINEERING MEASURES UNDER EXPOSURE CONTROLS/PERSONAL PROTECTION
SECTION.
LOCAL/TOTAL VENTILATION: USE WITH LOCAL EXHAUST VENTILATION.
ADVICE ON SAFE HANDLING:
DO NOT GET ON SKIN OR CLOTHING.
DO NOT SWALLOW.
DO NOT GET IN EYES.
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
KEEP CONTAINER TIGHTLY CLOSED.
KEEP AWAY FROM WATER.
PROTECT FROM MOISTURE.
TAKE CARE TO PREVENT SPILLS, WASTE AND MINIMIZE RELEASE TO THE ENVIRONMENT.
CONDITIONS FOR SAFE STORAGE:
KEEP IN PROPERLY LABELED CONTAINERS.
STORE LOCKED UP.
KEEP TIGHTLY CLOSED.
STORE IN ACCORDANCE WITH THE PARTICULAR NATIONAL REGULATIONS.
MATERIALS TO AVOID:
DO NOT STORE WITH THE FOLLOWING PRODUCT TYPES:
STRONG OXIDIZING AGENTS
ORGANIC PEROXIDES
EXPLOSIVES
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENTS WITH WORKPLACE CONTROL PARAMETERS:
INGREDIENTS CAS-NO. VALUE TYPE CONTROL BASIS
(FORM OF PARAMETERS /
EXPOSURE) PERMISSIBLE
CONCENTRATION
HEXAMETHYLDISILAZANE 68909-20-6 TWA (DUST) 20 MILLION OSHA Z-3
REACTION WITH SILICA PARTICLES
PER CUBIC
FOOT (SILICA)
TWA (DUST) 80 MG/M3 / OSHA Z-3
%SiO2 (SILICA)
TITANIUM DIOXIDE 13463-67-7 TWA 15 MG/M3 OSHA Z-1
(TOTAL DUST)
TWA 10 MG/M3 ACGIH
(TITANIUM
DIOXIDE)
HAZARDOUS COMPONENTS WITHOUT WORKPLACE CONTROL PARAMETERS:
INGREDIENTS CAS-NO.
VINYLTRIACETOXYSILANE 4130-08-9
THESE SUBSTANCE(S) ARE INEXTRICABLY BOUND IN THE PRODUCT AND THEREFORE
DO NOT CONTRIBUTE TO A DUST INHALATION HAZARD.
HEXAMETHYLDISILAZANE REACTION WITH SILICA
TITANIUM DIOXIDE
OCCUPATIONAL EXPOSURE LIMITS OF DECOMPOSITION PRODUCTS:
INGREDIENTS CAS-NO. VALUE TYPE CONTROL BASIS
(FORM OF PARAMETERS /
EXPOSURE) PERMISSIBLE
CONCENTRATION
ACETIC ACID 64-19-7 TWA 10 PPM ACGIH
STEL 15 PPM ACGIH
ST 15 PPM NIOSH REL
37 MG/M3
TWA 10 PPM NIOSH REL
25 MG/M3
TWA 10 PPM OSHA Z-1
25 MG/M3
ENGINEERING MEASURES:
PROCESSING MAY FORM HAZARDOUS COMPOUNDS (SEE SECTION 10).
MINIMIZE WORKPLACE EXPOSURE CONCENTRATIONS.
USE WITH LOCAL EXHAUST VENTILATION.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
GENERAL AND LOCAL EXHAUST VENTILATION IS RECOMMENDED TO MAINTAIN VAPOR
EXPOSURES BELOW RECOMMENDED LIMITS. WHERE CONCENTRATIONS ARE ABOVE
RECOMMENDED LIMITS OR ARE UNKNOWN, APPROPRIATE RESPIRATORY PROTECTION
SHOULD BE WORN. FOLLOW OSHA RESPIRATOR REGULATIONS (29 CFR 1910.134) AND
USE NIOSH/MSHA APPROVED RESPIRATORS. PROTECTION PROVIDED BY AIR PURIFYING
RESPIRATORS AGAINST EXPOSURE TO ANY HAZARDOUS CHEMICAL IS LIMITED. USE A
POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR
UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE UNKNOWN, OR ANY OTHER
CIRCUMSTANCE WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
HAND PROTECTION:
MATERIAL: CHEMICAL-RESISTANT GLOVES
REMARKS:
CHOOSE GLOVES TO PROTECT HANDS AGAINST CHEMICALS DEPENDING ON THE
CONCENTRATION SPECIFIC TO PLACE OF WORK. BREAKTHROUGH TIME IS NOT
DETERMINED FOR THE PRODUCT.
CHANGE GLOVES OFTEN!
FOR SPECIAL APPLICATIONS, WE RECOMMEND CLARIFYING THE RESISTANCE
TO CHEMICALS OF THE AFOREMENTIONED PROTECTIVE GLOVES WITH THE GLOVE
MANUFACTURER. WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
EYE PROTECTION:
WEAR THE FOLLOWING PERSONAL PROTECTIVE EQUIPMENT:
CHEMICAL RESISTANT GOGGLES MUST BE WORN.
IF SPLASHES ARE LIKELY TO OCCUR, WEAR: FACE-SHIELD
SKIN AND BODY PROTECTION:
SELECT APPROPRIATE PROTECTIVE CLOTHING BASED ON CHEMICAL RESISTANCE DATA
AND AN ASSESSMENT OF THE LOCAL EXPOSURE POTENTIAL.
SKIN CONTACT MUST BE AVOIDED BY USING IMPERVIOUS PROTECTIVE CLOTHING
(GLOVES, APRONS, BOOTS, ETC).
HYGIENE MEASURES:
ENSURE THAT EYE FLUSHING SYSTEMS AND SAFETY SHOWERS ARE LOCATED CLOSE TO
THE WORKING PLACE.
WHEN USING DO NOT EAT, DRINK OR SMOKE.
WASH CONTAMINATED CLOTHING BEFORE RE-USE.
THESE PRECAUTIONS ARE FOR ROOM TEMPERATURE HANDLING. USE AT ELEVATED
TEMPERATURE OR AEROSOL/SPRAY APPLICATIONS MAY REQUIRE ADDED PRECAUTIONS.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: PASTE
COLOR: WHITE
ODOR: ACETIC ACID
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
INITIAL BOILING POINT AND BOILING RANGE: NOT APPLICABLE
FLASH POINT: 95 DEG. C
METHOD: SETA CLOSED CUP
EVAPORATION RATE: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT CLASSIFIED AS A FLAMMABILITY HAZARD
SELF-IGNITION:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS PYROPHORIC. THE SUBSTANCE
OR MIXTURE IS NOT CLASSIFIED AS SELF HEATING.
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOR PRESSURE: NOT APPLICABLE
RELATIVE VAPOR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY: 1.41
SOLUBILITY(IES):
WATER SOLUBILITY: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY:
VISCOSITY, DYNAMIC: NOT APPLICABLE
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
OXIDIZING PROPERTIES:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS OXIDIZING.
MOLECULAR WEIGHT: NO DATA AVAILABLE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NOT CLASSIFIED AS A REACTIVITY HAZARD.
CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
VAPORS MAY FORM EXPLOSIVE MIXTURE WITH AIR.
USE AT ELEVATED TEMPERATURES MAY FORM HIGHLY HAZARDOUS COMPOUNDS.
CAN REACT WITH STRONG OXIDIZING AGENTS.
WHEN HEATED TO TEMPERATURES ABOVE 180 DEG. C (356 DEG. F) IN THE PRESENCE
OF AIR, TRACE QUANTITIES OF FORMALDEHYDE MAY BE RELEASED.
ADEQUATE VENTILATION IS REQUIRED.
SEE OSHA FORMALDEHYDE STANDARD, 29 CFR 1910.1048 HAZARDOUS DECOMPOSITION
PRODUCTS WILL BE FORMED UPON CONTACT WITH WATER OR HUMID AIR.
HAZARDOUS DECOMPOSITION PRODUCTS WILL BE FORMED AT ELEVATED TEMPERATURES.
CONDITIONS TO AVOID: EXPOSURE TO MOISTURE.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
WATER
HAZARDOUS DECOMPOSITION PRODUCTS:
CONTACT WITH WATER OR HUMID AIR: ACETIC ACID
THERMAL DECOMPOSITION:
FORMALDEHYDE
TRIFLUOROPROPIONALDEHYDE
HYDROGEN FLUORIDE
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
SKIN CONTACT
INGESTION
EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
HEXAMETHYLDISILAZANE REACTION WITH SILICA:
ACUTE ORAL TOXICITY:
LD50 (RAT): >5,000 MG/KG
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE ORAL TOXICITY
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
TITANIUM DIOXIDE:
ACUTE ORAL TOXICITY:
LD50 (RAT): >5,000 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): >6.82 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: DUST/MIST
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE INHALATION TOXICITY
VINYLTRIACETOXYSILANE:
ACUTE INHALATION TOXICITY:
LC50 (RAT): 2300 PPM
EXPOSURE TIME: 7 H
TEST ATMOSPHERE: VAPOR
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE INHALATION TOXICITY
REMARKS: ON BASIS OF TEST DATA.
SKIN CORROSION/IRRITATION: CAUSES SEVERE BURNS.
INGREDIENTS:
HEXAMETHYLDISILAZANE REACTION WITH SILICA:
ASSESSMENT: REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
TITANIUM DIOXIDE:
SPECIES: RABBIT
RESULT: NO SKIN IRRITATION
VINYLTRIACETOXYSILANE:
RESULT: CORROSIVE AFTER 3 MINUTES TO 1 HOUR OF EXPOSURE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE DAMAGE.
INGREDIENTS:
HEXAMETHYLDISILAZANE REACTION WITH SILICA:
SPECIES: RABBIT
RESULT: NO EYE IRRITATION
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
TITANIUM DIOXIDE:
SPECIES: RABBIT
RESULT: NO EYE IRRITATION
VINYLTRIACETOXYSILANE:
RESULT: IRREVERSIBLE EFFECTS ON THE EYE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
RESPIRATORY OR SKIN SENSITIZATION:
SKIN SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
RESPIRATORY SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
TITANIUM DIOXIDE:
TEST TYPE: LOCAL LYMPH NODE ASSAY (LLNA)
ROUTES OF EXPOSURE: SKIN CONTACT
SPECIES: MOUSE
RESULT: NEGATIVE
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
HEXAMETHYLDISILAZANE REACTION WITH SILICA:
GENOTOXICITY IN VITRO:
TEST TYPE: BACTERIAL REVERSE MUTATION ASSAY (AMES)
RESULT: NEGATIVE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
TITANIUM DIOXIDE:
GENOTOXICITY IN VITRO:
TEST TYPE: BACTERIAL REVERSE MUTATION ASSAY (AMES)
RESULT: NEGATIVE
GENOTOXICITY IN VIVO:
TEST TYPE: IN VIVO MICRONUCLEUS TEST
SPECIES: MOUSE
RESULT: NEGATIVE
VINYLTRIACETOXYSILANE:
GENOTOXICITY IN VITRO:
TEST TYPE: BACTERIAL REVERSE MUTATION ASSAY (AMES)
RESULT: NEGATIVE
REMARKS: ON BASIS OF TEST DATA.
CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
TITANIUM DIOXIDE:
SPECIES: RAT
APPLICATION ROUTE: INHALATION (DUST/MIST/FUME)
EXPOSURE TIME: 24 MONTHS
METHOD: OECD TEST GUIDELINE 453
RESULT: POSITIVE
REMARKS: THE MECHANISM OR MODE OF ACTION MAY NOT BE RELEVANT IN HUMANS.
THESE SUBSTANCE(S) ARE INEXTRICABLY BOUND IN THE PRODUCT AND THEREFORE
DO NOT CONTRIBUTE TO A DUST INHALATION HAZARD.
CARCINOGENICITY - ASSESSMENT:
LIMITED EVIDENCE OF CARCINOGENICITY IN INHALATION STUDIES WITH ANIMALS.
IARC:
GROUP 2B: POSSIBLY CARCINOGENIC TO HUMANS
TITANIUM DIOXIDE 13463-67-7
OSHA:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL
TO 0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
NTP:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL
TO 0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
REPRODUCTIVE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT-SINGLE EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT-REPEATED EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
REPEATED DOSE TOXICITY:
INGREDIENTS:
TITANIUM DIOXIDE:
SPECIES: RAT
NOAEL: 24,000 MG/KG
APPLICATION ROUTE: INGESTION
EXPOSURE TIME: 28 DAYS
SPECIES: RAT
NOAEL: 10 MG/M3
APPLICATION ROUTE: INHALATION (DUST/MIST/FUME)
EXPOSURE TIME: 2 Y
REMARKS:
THESE SUBSTANCE(S) ARE INEXTRICABLY BOUND IN THE PRODUCT AND THEREFORE
DO NOT CONTRIBUTE TO A DUST INHALATION HAZARD.
ASPIRATION TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
INGREDIENTS:
TITANIUM DIOXIDE:
TOXICITY TO FISH:
LC50 (ONCORHYNCHUS MYKISS (RAINBOW TROUT)): >100 MG/L
EXPOSURE TIME: 96 H
METHOD: OECD TEST GUIDELINE 203
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (DAPHNIA MAGNA (WATER FLEA)): >100 MG/L
EXPOSURE TIME: 48 H
TOXICITY TO ALGAE:
EC50 (SKELETONEMA COSTATUM (MARINE DIATOM)): >10,000 MG/L
EXPOSURE TIME: 72 H
TOXICITY TO MICROORGANISMS:
EC50: >1,000 MG/L
EXPOSURE TIME: 3 H
METHOD: OECD TEST GUIDELINE 209
VINYLTRIACETOXYSILANE:
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (DAPHNIA MAGNA (WATER FLEA)): >100 MG/L
EXPOSURE TIME: 48 H
REMARKS: ON BASIS OF TEST DATA.
TOXICITY TO ALGAE:
EC50 (SELENASTRUM CAPRICORNUTUM (GREEN ALGAE)): >100 MG/L
EXPOSURE TIME: 72 H
METHOD: EPA-679/4-73-001
REMARKS: ON BASIS OF TEST DATA.
ECOTOXICOLOGY ASSESSMENT:
ACUTE AQUATIC TOXICITY: THIS PRODUCT HAS NO KNOWN ECOTOXICOLOGICAL EFFECTS.
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
MOBILITY IN SOIL: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
RESOURCE CONSERVATION AND RECOVERY ACT (RCRA):
THIS PRODUCT HAS BEEN EVALUATED FOR RCRA CHARACTERISTICS AND DOES NOT
MEET THE CRITERIA OF HAZARDOUS WASTE IF DISCARDED IN ITS PURCHASED FORM.
WASTE FROM RESIDUES: DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
IF NOT OTHERWISE SPECIFIED: DISPOSE OF AS UNUSED PRODUCT.
| SECTION 14. TRANSPORT INFORMATION | |
INTERNATIONAL REGULATIONS:
UNRTDG:
UN NUMBER: UN 1759
PROPER SHIPPING NAME: CORROSIVE SOLID, N.O.S. (VINYLTRIACETOXYSILANE)
CLASS: 8
PACKING GROUP: II
LABELS: 8
IATA-DGR:
UN/ID NO.: UN 1759
PROPER SHIPPING NAME: CORROSIVE SOLID, N.O.S. (VINYLTRIACETOXYSILANE)
CLASS: 8
PACKING GROUP: II
LABELS: CORROSIVE
PACKING INSTRUCTION (CARGO AIRCRAFT): 863
PACKING INSTRUCTION (PASSEN GER AIRCRAFT): 859
IMDG-CODE:
UN NUMBER: UN 1759
PROPER SHIPPING NAME: CORROSIVE SOLID, N.O.S. (VINYLTRIACETOXYSILANE)
CLASS: 8
PACKING GROUP: II
LABELS: 8
EMS CODE: F-A, S-B
MARINE POLLUTANT: NO
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE FOR PRODUCT AS SUPPLIED.
DOMESTIC REGULATION:
49 CFR:
UN/ID/NA NUMBER: UN 1759
PROPER SHIPPING NAME: CORROSIVE SOLIDS, N.O.S. (VINYLTRIACETOXYSILANE)
CLASS: 8
PACKING GROUP: II
LABELS: CORROSIVE
ERG CODE: 154
MARINE POLLUTANT: NO
| SECTION 15. REGULATORY INFORMATION | |
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW:
CERCLA REPORTABLE QUANTITY:
INGREDIENTS CAS-NO. COMPONENT RQ CALCULATED PRODUCT RQ
(LBS) (LBS)
ACETIC ACID 64-19-7 5000 *
ACETIC ANHYDRIDE 108-24-7 5000 *
*: CALCULATED RQ EXCEEDS REASONABLY ATTAINABLE UPPER LIMIT.
SARA 304 EXTREMELY HAZARDOUS SUBSTANCES REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 304 EHS RQ.
SARA 302 EXTREMELY HAZARDOUS SUBSTANCES THRESHOLD PLANNING QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 302 EHS TPQ.
SARA 311/312 HAZARDS: ACUTE HEALTH HAZARD
SARA 313:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS ESTABLISHED
BY SARA TITLE III, SECTION 313.
US STATE REGULATIONS:
PENNSYLVANIA RIGHT TO KNOW:
TRIFLUOROPROPYLMETHYL SILOXANE, HYDROXY-TERMINATED 68607-77-2
HEXAMETHYLDISILAZANE REACTION WITH SILICA 68909-20-6
TITANIUM DIOXIDE 13463-67-7
VINYLTRIACETOXYSILANE 4130-08-9
ACETIC ACID 64-19-7
ACETIC ANHYDRIDE 108-24-7
CALIFORNIA PROP. 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH, OR ANY OTHER REPRODUCTIVE DEFECTS.
CALIFORNIA PERMISSIBLE EXPOSURE LIMITS FOR CHEMICAL CONTAMINANTS:
TITANIUM DIOXIDE 13463-67-7
THE INGREDIENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES:
TSCA:
ALL CHEMICAL SUBSTANCES IN THIS PRODUCT ARE EITHER LISTED ON THE TSCA
INVENTORY OR ARE IN COMPLIANCE WITH A TSCA INVENTORY EXEMPTION.
AICS: ALL INGREDIENTS LISTED OR EXEMPT.
IECSC: ALL INGREDIENTS LISTED OR EXEMPT.
ENCS/ISHL:
ALL COMPONENTS ARE LISTED ON ENCS/ISHL OR EXEMPTED FROM INVENTORY LISTING.
DSL:
ALL CHEMICAL SUBSTANCES IN THIS PRODUCT COMPLY WITH THE CEPA 1999 AND NSNR
AND ARE ON OR EXEMPT FROM LISTING ON THE CANADIAN DOMESTIC SUBSTANCES LIST
(DSL).
REACH:
FOR PURCHASES FROM DOW CORNING EU LEGAL ENTITIES, ALL INGREDIENTS ARE
CURRENTLY PRE/REGISTERED OR EXEMPT UNDER REACH. PLEASE REFER TO SECTION 1
FOR RECOMMENDED USES. FOR PURCHASES FROM NON-EU DOW CORNING LEGAL ENTITIES
WITH THE INTENTION TO EXPORT INTO EEA PLEASE CONTACT YOUR DC
REPRESENTATIVE/LOCAL OFFICE.
KECI: ONE OR MORE INGREDIENTS ARE NOT LISTED OR EXEMPT.
TCSI: ALL INGREDIENTS LISTED OR EXEMPT.
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
NFPA:
HEALTH 3
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARD.
HMIS(R*) IV:
HEALTH /3
FLAMMABILITY 1
PHYSICAL HAZARD 0
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS.
THE "*" REPRESENTS A CHRONIC HAZARD, WHILE THE "/" REPRESENTS THE ABSENCE
OF A CHRONIC HAZARD.
FULL TEXT OF OTHER ABBREVIATIONS:
ACGIH: USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
NIOSH REL: USA. NIOSH RECOMMENDED EXPOSURE LIMITS
OSHA Z-1:
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z-1 LIMITS FOR AIR
CONTAMINANTS
OSHA Z-3:
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z-3 MINERAL DUSTS
ACGIH / TWA: 8-HOUR, TIME-WEIGHTED AVERAGE
ACGIH / STEL: SHORT-TERM EXPOSURE LIMIT
NIOSH REL / TWA:
TIME-WEIGHTED AVERAGE CONCENTRATION FOR UP TO A 10-HOUR WORKDAY DURING A
40-HOUR WORKWEEK
NIOSH REL / ST:
STEL - 15-MINUTE TWA EXPOSURE THAT SHOULD NOT BE EXCEEDED AT ANY TIME
DURING A WORKDAY
OSHA Z-1 / TWA: 8-HOUR TIME WEIGHTED AVERAGE
OSHA Z-3 / TWA: 8-HOUR TIME WEIGHTED AVERAGE
AICS: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES
ASTM: AMERICAN SOCIETY FOR THE TESTING OF MATERIALS
BW: BODY WEIGHT
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
CMR: CARCINOGEN, MUTAGEN OR REPRODUCTIVE TOXICANT
DIN: STANDARD OF THE GERMAN INSTITUTE FOR STANDARDISATION
DOT: DEPARTMENT OF TRANSPORTATION
DSL: DOMESTIC SUBSTANCES LIST (CANADA)
ECX: CONCENTRATION ASSOCIATED WITH X% RESPONSE
EHS: EXTREMELY HAZARDOUS SUBSTANCE
ELX: LOADING RATE ASSOCIATED WITH X% RESPONSE
EMS: EMERGENCY SCHEDULE
ENCS: EXISTING AND NEW CHEMICAL SUBSTANCES (JAPAN)
ERCX: CONCENTRATION ASSOCIATED WITH X% GROWTH RATE RESPONSE
ERG: EMERGENCY RESPONSE GUIDE
GHS: GLOBALLY HARMONIZED SYSTEM
GLP: GOOD LABORATORY PRACTICE
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC:
INTERNATIONAL CODE FOR THE CONSTRUCTION AND EQUIPMENT OF SHIPS CARRYING
DANGEROUS CHEMICALS IN BULK
IC50: HALF MAXIMAL INHIBITORY CONCENTRATION
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
IECSC: INVENTORY OF EXISTING CHEMICAL SUBSTANCES IN CHINA
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
IMO: INTERNATIONAL MARITIME ORGANIZATION
ISHL: INDUSTRIAL SAFETY AND HEALTH LAW (JAPAN)
ISO: INTERNATIONAL ORGANISATION FOR STANDARDIZATION
KECI: KOREA EXISTING CHEMICALS INVENTORY
LC50: LETHAL CONCENTRATION TO 50% OF A TEST POPULATION
LD50: LETHAL DOSE TO 50% OF A TEST POPULATION (MEDIAN LETHAL DOSE)
MARPOL: INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS
MSHA: MINE SAFETY AND HEALTH ADMINISTRATION
N.O.S.: NOT OTHERWISE SPECIFIED
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NO(A)EC: NO OBSERVED (ADVERSE) EFFECT CONCENTRATION
NO(A)EL: NO OBSERVED (ADVERSE) EFFECT LEVEL
NOELR: NO OBSERVABLE EFFECT LOADING RATE
NTP: NATIONAL TOXICOLOGY PROGRAM
NZIOC: NEW ZEALAND INVENTORY OF CHEMICALS
OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
OPPTS: OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC SUBSTANCE
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
(Q)SAR: (QUANTITATIVE) STRUCTURE ACTIVITY RELATIONSHIP
RCRA: RESOURCE CONSERVATION AND RECOVERY ACT
REACH:
REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
CONCERNING THE REGISTRATION, EVALUATION, AUTHORISATION AND RESTRICTION OF
CHEMICALS
RQ: REPORTABLE QUANTITY
SADT: SELF-ACCELERATING DECOMPOSITION TEMPERATURE
SARA: SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
SDS: SAFETY DATA SHEET
TCSI: TAIWAN CHEMICAL SUBSTANCE INVENTORY
TSCA: TOXIC SUBSTANCES CONTROL ACT (UNITED STATES)
UN: UNITED NATIONS
UNRTDG: UNITED NATIONS RECOMMENDATIONS ON THE TRANSPORT OF DANGEROUS GOODS
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
SOURCES OF KEY DATA USED TO COMPILE THE MATERIAL SAFETY DATA SHEET:
INTERNAL TECHNICAL DATA, DATA FROM RAW MATERIAL SDSS, OECD ECHEM PORTAL
SEARCH RESULTS AND EUROPEAN CHEMICALS AGENCY, HTTP://ECHA.EUROPA.EU/
REVISION DATE: 11/10/2016
ITEMS WHERE CHANGES HAVE BEEN MADE TO THE PREVIOUS VERSION ARE HIGHLIGHTED
IN THE BODY OF THIS DOCUMENT BY TWO VERTICAL LINES.
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING, USE,
PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND SHALL NOT
BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION OF ANY TYPE. THE
INFORMATION PROVIDED RELATES ONLY TO THE SPECIFIC MATERIAL IDENTIFIED AT
THE TOP OF THIS SDS AND MAY NOT BE VALID WHEN THE SDS MATERIAL IS USED IN
COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS, UNLESS SPECIFIED
IN THE TEXT. MATERIAL USERS SHOULD REVIEW THE INFORMATION AND
RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THEIR INTENDED MANNER OF
HANDLING, USE, PROCESSING AND STORAGE, INCLUDING AN ASSESSMENT OF THE
APPROPRIATENESS OF THE SDS MATERIAL IN THE USER'S END PRODUCT, IF
APPLICABLE.
US / Z8