| Common Name: | PR-1204 RTV PRIME COAT |
| Manufacturer: | DOW CORNING |
| SDS Revision Date: | 2/15/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 53DD02, 53DD03 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DOW CORNING
SAFETY DATA SHEET
DOW CORNING(R) PR-1204 RTV PRIME COAT
VERSION: 3.1
REVISION DATE: 02/15/2016
SDS NUMBER: 999250-00005
DATE OF LAST ISSUE: 12/09/2015
DATE OF FIRST ISSUE: 12/23/2014
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: DOW CORNING(R) PR-1204 RTV PRIME COAT
PRODUCT CODE: 000000000004093285
MANUFACTURER OR SUPPLIER'S DETAILS:
COMPANY NAME OF SUPPLIER: DOW CORNING CORPORATION
ADDRESS:
SOUTH SAGINAW ROAD
MIDLAND MICHIGAN 48686
TELEPHONE: (989) 496-6000
EMERGENCY TELEPHONE:
24 HOUR EMERGENCY TELEPHONE: (989) 496-5900
CHEMTREC: (800) 424-9300
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVE, BINDING AGENTS
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
FLAMMABLE LIQUIDS: CATEGORY 2
SKIN IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE: CATEGORY 1
REPRODUCTIVE TOXICITY: CATEGORY 2
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY - SINGLE EXPOSURE: CATEGORY 3
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY - REPEATED EXPOSURE:
CATEGORY 2 (CENTRAL NERVOUS SYSTEM) ASPIRATION HAZARD: CATEGORY 1
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
HEALTH HAZARD
CORROSION
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H315: CAUSES SKIN IRRITATION.
H318: CAUSES SERIOUS EYE DAMAGE.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
H373:
MAY CAUSE DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM) THROUGH PROLONGED OR
REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
P233:
KEEP CONTAINER TIGHTLY CLOSED. P240 GROUND/BOND CONTAINER AND RECEIVING
EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P260: DO NOT BREATHE MIST OR VAPORS.
P264: WASH SKIN THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
P301 + P310:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER/DOCTOR.
P303 + P361 + P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P304 + P340 + P312:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
P305 + P351 + P338 + P310:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER/DOCTOR.
P308 + P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P331: DO NOT INDUCE VOMITING.
P332 + P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P362 + P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
STORAGE:
P403 + P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405: STORE LOCKED UP.
DISPOSAL:
P501: DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS:
VAPORS MAY FORM EXPLOSIVE MIXTURE WITH AIR.
STATIC-ACCUMULATING FLAMMABLE LIQUID.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
CHEMICAL NATURE:
INORGANIC AND ORGANIC COMPOUNDS
MIXTURE
HAZARDOUS INGREDIENTS:
CHEMICAL NAME CAS-NO. CONCENTRATION
(% W/W)
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. 64742-89-8 >=50 - <70
TOLUENE 108-88-3 >=10 - <20
TETRAKIS(2-BUTOXYETHYL)ORTHOSILICATE 18765-38-3 >=1 - <5
TITANIUM TETRABUTANOLATE 5593-70-4 >=1 - <5
BUTAN-1-OL 71-36-3 >=1 - <5
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
IN THE CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL AD- VICE
IMMEDIATELY.
WHEN SYMPTOMS PERSIST OR IN ALL CASES OF DOUBT SEEK MEDICAL ADVICE.
IF INHALED:
IF INHALED, REMOVE TO FRESH AIR.
GET MEDICAL ATTENTION.
IN CASE OF SKIN CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
GET MEDICAL ATTENTION.
WASH CLOTHING BEFORE REUSE.
THOROUGHLY CLEAN SHOES BEFORE REUSE.
IN CASE OF EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES.
IF EASY TO DO, REMOVE CONTACT LENS, IF WORN.
GET MEDICAL ATTENTION IMMEDIATELY.
IF SWALLOWED:
IF SWALLOWED, DO NOT INDUCE VOMITING.
IF VOMITING OCCURS HAVE PERSON LEAN FORWARD.
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
RINSE MOUTH THOROUGHLY WITH WATER.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE DAMAGE.
MAY CAUSE DROWSINESS OR DIZZINESS.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PROTECTION OF FIRST-AIDERS:
FIRST AID RESPONDERS SHOULD PAY ATTENTION TO SELF-PROTECTION, AND USE THE
RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT WHEN THE POTENTIAL FOR EXPOSURE
EXISTS.
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
| SECTION 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY
ALCOHOL-RESISTANT FOAM
CARBON DIOXIDE (CO2)
DRY CHEMICAL
UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET
SPECIFIC HAZARDS DURING FIRE FIGHTING:
DO NOT USE A SOLID WATER STREAM AS IT MAY SCATTER AND SPREAD FIRE.
FLASH BACK POSSIBLE OVER CONSIDERABLE DISTANCE.
VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR.
EXPOSURE TO COMBUSTION PRODUCTS MAY BE A HAZARD TO HEALTH.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON OXIDES
SILICON OXIDES
FORMALDEHYDE
METAL OXIDES
SPECIFIC EXTINGUISHING METHODS:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
USE WATER SPRAY TO COOL UNOPENED CONTAINERS.
REMOVE UNDAMAGED CONTAINERS FROM FIRE AREA IF IT IS SAFE TO DO SO.
EVACUATE AREA.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
USE PERSONAL PROTECTIVE EQUIPMENT.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
REMOVE ALL SOURCES OF IGNITION.
VENTILATE THE AREA.
USE PERSONAL PROTECTIVE EQUIPMENT.
FOLLOW SAFE HANDLING ADVICE AND PERSONAL PROTECTIVE EQUIPMENT
RECOMMENDATIONS.
ENVIRONMENTAL PRECAUTIONS:
DISCHARGE INTO THE ENVIRONMENT MUST BE AVOIDED.
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
PREVENT SPREADING OVER A WIDE AREA (E.G. BY CONTAINMENT OR OIL BARRIERS).
RETAIN AND DISPOSE OF CONTAMINATED WASH WATER.
LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE
CONTAINED.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
NON-SPARKING TOOLS SHOULD BE USED.
SOAK UP WITH INERT ABSORBENT MATERIAL.
SUPPRESS (KNOCK DOWN) GASES/VAPORS/MISTS WITH A WATER SPRAY JET.
FOR LARGE SPILLS, PROVIDE DIKING OR OTHER APPROPRIATE CONTAINMENT TO KEEP
MATERIAL FROM SPREADING. IF DIKED MATERIAL CAN BE PUMPED, STORE RECOVERED
MATERIAL IN APPROPRIATE CONTAINER.
CLEAN UP REMAINING MATERIALS FROM SPILL WITH SUITABLE ABSORBENT.
LOCAL OR NATIONAL REGULATIONS MAY APPLY TO RELEASES AND DISPOSAL OF THIS
MATERIAL, AS WELL AS THOSE MATERIALS AND ITEMS EMPLOYED IN THE CLEANUP OF
RELEASES. YOU WILL NEED TO DETERMINE WHICH REGULATIONS ARE APPLICABLE.
SECTIONS 13 AND 15 OF THIS SDS PROVIDE INFORMATION REGARDING CERTAIN LOCAL
OR NATIONAL REQUIREMENTS.
| SECTION 7. HANDLING AND STORAGE | |
TECHNICAL MEASURES:
ENSURE ALL EQUIPMENT IS ELECTRICALLY GROUNDED BEFORE BEGINNING TRANSFER
OPERATIONS.
THIS MATERIAL CAN ACCUMULATE STATIC CHARGE DUE TO ITS INHERENT PHYSICAL
PROPERTIES AND CAN THEREFORE CAUSE AN ELECTRICAL IGNITION SOURCE TO VAPORS.
IN ORDER TO PREVENT A FIRE HAZARD, AS BONDING AND GROUNDING MAY BE
INSUFFICIENT TO REMOVE STATIC ELECTRICITY, IT IS NECESSARY TO PROVIDE AN
INERT GAS PURGE BEFORE BEGINNING TRANSFER OPERATIONS.
RESTRICT FLOW VELOCITY IN ORDER TO REDUCE THE ACCUMULATION OF STATIC
ELECTRICITY.
LOCAL/TOTAL VENTILATION:
USE WITH LOCAL EXHAUST VENTILATION.
USE ONLY IN AN AREA EQUIPPED WITH EXPLOSION PROOF EXHAUST VENTILATION.
ADVICE ON SAFE HANDLING:
DO NOT GET ON SKIN OR CLOTHING.
DO NOT BREATHE VAPORS OR SPRAY MIST.
DO NOT SWALLOW.
DO NOT GET IN EYES.
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
NON-SPARKING TOOLS SHOULD BE USED.
KEEP CONTAINER TIGHTLY CLOSED.
KEEP AWAY FROM WATER.
PROTECT FROM MOISTURE.
KEEP AWAY FROM HEAT AND SOURCES OF IGNITION.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES.
TAKE CARE TO PREVENT SPILLS, WASTE AND MINIMIZE RELEASE TO THE ENVIRONMENT.
CONDITIONS FOR SAFE STORAGE:
KEEP IN PROPERLY LABELED CONTAINERS.
STORE LOCKED UP.
KEEP TIGHTLY CLOSED.
KEEP IN A COOL, WELL-VENTILATED PLACE.
STORE IN ACCORDANCE WITH THE PARTICULAR NATIONAL REGULATIONS.
KEEP AWAY FROM HEAT AND SOURCES OF IGNITION.
MATERIALS TO AVOID:
DO NOT STORE WITH THE FOLLOWING PRODUCT TYPES:
STRONG OXIDIZING AGENTS
ORGANIC PEROXIDES
FLAMMABLE SOLIDS
PYROPHORIC LIQUIDS
PYROPHORIC SOLIDS
SELF-HEATING SUBSTANCES AND MIXTURES SUBSTANCES AND MIXTURES WHICH IN
CONTACT WITH WATER EMIT FLAMMABLE GASES
EXPLOSIVES
GASES
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENTS WITH WORKPLACE CONTROL PARAMETERS:
INGREDIENTS CAS-NO. VALUE TYPE CONTROL PARAMETERS BASIS
(FORM OF / PERMISSIBLE
EXPOSURE) CONCENTRATION
SOLVENT NAPHTHA 64742-89-8 TWA 500 PPM OSHA Z-1
(PETROLEUM), 2,000 MG/M3
LIGHT ALIPH.
TOLUENE 108-88-3 TWA 20 PPM ACGIH
TWA 100 PPM NIOSH REL
375 MG/M3
ST 150 PPM NIOSH REL
560 MG/M3
TWA 200 PPM OSHA Z-2
CEIL 300 PPM OSHA Z-2
PEAK 500 PPM OSHA Z-2
(10 MINUTES)
BUTAN-1-OL 71-36-3 TWA 20 PPM ACGIH
C 50 PPM NIOSH REL
150 MG/M3
TWA 100 PPM OSHA Z-1
300 MG/M3
HAZARDOUS COMPONENTS WITHOUT WORKPLACE CONTROL PARAMETERS:
INGREDIENTS CAS-NO.
TETRAKIS(2-BUTOXYETHYL) ORTHOSILICATE 18765-38-3
TITANIUM TETRABUTANOLATE 5593-70-4
OCCUPATIONAL EXPOSURE LIMITS OF DECOMPOSITION PRODUCTS:
INGREDIENTS CAS-NO. VALUE TYPE CONTROL PARAMETERS BASIS
(FORM OF / PERMISSIBLE
EXPOSURE) CONCENTRATION
PROPAN-1-OL 71-23-8 TWA 100 PPM ACGIH
TWA 200 PPM NIOSH REL
500 MG/M3
ST 250 PPM NIOSH REL
625 MG/M3
TWA 200 PPM OSHA Z-1
500 MG/M3
2-BUTOXY- 111-76-2 TWA 20 PPM ACGIH
ETHANOL
TWA 5 PPM NIOSH REL
24 MG/M3
TWA 50 PPM OSHA Z-1
240 MG/M3
BUTAN-1-OL 71-36-3 TWA 20 PPM ACGIH
C 50 PPM NIOSH REL
150 MG/M3
TWA 100 PPM OSHA Z-1
300 MG/M3
BIOLOGICAL OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENTS CAS-NO. CONTROL BIOLOGICAL SAMPLING PERMISSIBLE BASIS
PARAMETERS SPECIMEN TIME CONCENTRA-
TION
TOLUENE 108-88-3 TOLUENE IN BLOOD PRIOR TO 0.02 MG/L ACGIH
LAST BEI
SHIFT OF
WORK-
WEEK
TOLUENE URINE END OF 0.03 MG/L ACGIH
SHIFT BEI
(AS
SOON AS
POSSIBLE
AFTER
EXPOSURE
CEASES)
O-CRESOL URINE END OF 0.3 MG/G ACGIH
SHIFT CREATININE BEI
(AS SOON
AS
POSSIBLE
AFTER
EXPOSURE
CEASES)
ENGINEERING MEASURES:
PROCESSING MAY FORM HAZARDOUS COMPOUNDS (SEE SECTION 10).
MINIMIZE WORKPLACE EXPOSURE CONCENTRATIONS.
USE ONLY IN AN AREA EQUIPPED WITH EXPLOSION PROOF EXHAUST VENTILATION.
USE WITH LOCAL EXHAUST VENTILATION.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
GENERAL AND LOCAL EXHAUST VENTILATION IS RECOMMENDED TO MAINTAIN VAPOR
EXPOSURES BELOW RECOMMENDED LIMITS. WHERE CONCENTRATIONS ARE ABOVE
RECOMMENDED LIMITS OR ARE UNKNOWN, APPROPRIATE RESPIRATORY PROTECTION
SHOULD BE WORN.
FOLLOW OSHA RESPIRATOR REGULATIONS (29 CFR 1910.134) AND USE NIOSH/MSHA
APPROVED RESPIRATORS. PROTECTION PROVIDED BY AIR PURIFYING RESPIRATORS
AGAINST EXPOSURE TO ANY HAZARDOUS CHEMICAL IS LIMITED. USE A POSITIVE
PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR UNCONTROLLED
RELEASE, EXPOSURE LEVELS ARE UNKNOWN, OR ANY OTHER CIRCUMSTANCE WHERE AIR
PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION.
HAND PROTECTION:
MATERIAL: ANTISTATIC GLOVES
MATERIAL: IMPERVIOUS GLOVES
MATERIAL: FLAME RETARDANT GLOVES
REMARKS:
CHOOSE GLOVES TO PROTECT HANDS AGAINST CHEMICALS DEPENDING ON THE
CONCENTRATION SPECIFIC TO PLACE OF WORK. BREAKTHROUGH TIME IS NOT
DETERMINED FOR THE PRODUCT. CHANGE GLOVES OFTEN! FOR SPECIAL APPLICATIONS,
WE RECOMMEND CLARIFYING THE RESISTANCE TO CHEMICALS OF THE AFOREMENTIONED
PROTECTIVE GLOVES WITH THE GLOVE MANUFACTURER. WASH HANDS BEFORE BREAKS
AND AT THE END OF WORKDAY.
EYE PROTECTION:
WEAR THE FOLLOWING PERSONAL PROTECTIVE EQUIPMENT:
CHEMICAL RESISTANT GOGGLES MUST BE WORN.
IF SPLASHES ARE LIKELY TO OCCUR, WEAR: FACE-SHIELD
SKIN AND BODY PROTECTION:
SELECT APPROPRIATE PROTECTIVE CLOTHING BASED ON CHEMICAL RESISTANCE DATA
AND AN ASSESSMENT OF THE LOCAL EXPOSURE POTENTIAL.
WEAR THE FOLLOWING PERSONAL PROTECTIVE EQUIPMENT:
FLAME RETARDANT ANTISTATIC PROTECTIVE CLOTHING.
SKIN CONTACT MUST BE AVOIDED BY USING IMPERVIOUS PROTECTIVE CLOTHING
(GLOVES, APRONS, BOOTS, ETC).
HYGIENE MEASURES:
ENSURE THAT EYE FLUSHING SYSTEMS AND SAFETY SHOWERS ARE LOCATED CLOSE TO
THE WORKING PLACE.
WHEN USING DO NOT EAT, DRINK OR SMOKE.
WASH CONTAMINATED CLOTHING BEFORE RE-USE.
THESE PRECAUTIONS ARE FOR ROOM TEMPERATURE HANDLING. USE AT ELEVATED
TEMPERATURE OR AEROSOL/SPRAY APPLICATIONS MAY REQUIRE ADDED PRECAUTIONS.
FOR FURTHER INFORMATION REGARDING THE USE OF SILICONES / ORGANIC OILS IN
CONSUMER AEROSOL APPLICATIONS, PLEASE REFER TO THE GUIDANCE DOCUMENT
REGARDING THE USE OF THESE TYPE OF MATERIALS IN CONSUMER AEROSOL
APPLICATIONS THAT HAS BEEN DEVELOPED BY THE SILICONE INDUSTRY
(WWW.SEHSC.COM) OR CONTACT THE DOW CORNING CUSTOMER SERVICE GROUP.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
COLOR: COLORLESS TO PALE YELLOW
ODOR: SOLVENT
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
INITIAL BOILING POINT AND BOILING RANGE: >65 DEG. C
FLASH POINT: 6 DEG. C
METHOD: TAG CLOSED CUP
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY: 0.8
SOLUBILITY(IES):
WATER SOLUBILITY: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY:
VISCOSITY, KINEMATIC: 1 MM2/S
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
OXIDIZING PROPERTIES:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS OXIDIZING.
MOLECULAR WEIGHT: NO DATA AVAILABLE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NOT CLASSIFIED AS A REACTIVITY HAZARD.
CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
VAPORS MAY FORM EXPLOSIVE MIXTURE WITH AIR.
USE AT ELEVATED TEMPERATURES MAY FORM HIGHLY HAZARDOUS COMPOUNDS.
CAN REACT WITH STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS WILL BE FORMED UPON CONTACT WITH WATER OR
HUMID AIR.
HAZARDOUS DECOMPOSITION PRODUCTS WILL BE FORMED AT ELEVATED TEMPERATURES.
CONDITIONS TO AVOID:
EXPOSURE TO MOISTURE.
HANDLING OPERATIONS THAT CAN PROMOTE ACCUMULATION OF STATIC CHARGES.
HEAT, FLAMES AND SPARKS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
WATER
HAZARDOUS DECOMPOSITION PRODUCTS:
CONTACT WITH WATER OR HUMID AIR:
PROPAN-1-OL
2-BUTOXYETHANOL
BUTAN-1-OL
THERMAL DECOMPOSITION: FORMALDEHYDE
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION
SKIN CONTACT
INGESTION
EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
ACUTE ORAL TOXICITY:
ACUTE TOXICITY ESTIMATE: >5,000 MG/KG
METHOD: CALCULATION METHOD
ACUTE INHALATION TOXICITY:
ACUTE TOXICITY ESTIMATE: 147.89 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOR
METHOD: CALCULATION METHOD
ACUTE DERMAL TOXICITY:
ACUTE TOXICITY ESTIMATE: >5,000 MG/KG
METHOD: CALCULATION METHOD
INGREDIENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
ACUTE ORAL TOXICITY:
LD50 (RAT): >5,000 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): >5.6 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOR
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE INHALATION TOXICITY
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >2,000 MG/KG
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE DERMAL TOXICITY
TOLUENE:
ACUTE ORAL TOXICITY:
LD50 (RAT): >5,000 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): 28.1 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOR
METHOD: OECD TEST GUIDELINE 403
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >5,000 MG/KG
TETRAKIS(2-BUTOXYETHYL) ORTHOSILICATE:
ACUTE ORAL TOXICITY:
LD50 (RAT): >2,000 MG/KG
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE ORAL TOXICITY
REMARKS: INFORMATION TAKEN FROM REFERENCE WORKS AND THE LITERATURE.
ACUTE DERMAL TOXICITY:
LD50 (RAT): >2,000 MG/KG
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE DERMAL TOXICITY
REMARKS: INFORMATION TAKEN FROM REFERENCE WORKS AND THE LITERATURE.
TITANIUM TETRABUTANOLATE:
ACUTE ORAL TOXICITY:
LD50 (RAT): >2,000 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): 11 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: DUST/MIST
BUTAN-1-OL:
ACUTE ORAL TOXICITY:
LD50 (RAT): 790 MG/KG
ACUTE INHALATION TOXICITY:
LCO (RAT): >17.76 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOR
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): 3,430 MG/KG
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
INGREDIENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
SPECIES: RABBIT
METHOD: OECD TEST GUIDELINE 404
RESULT: SKIN IRRITATION
TOLUENE:
SPECIES: RABBIT
METHOD: DIRECTIVE 67/548/EEC, ANNEX V, B.4.
RESULT: SKIN IRRITATION
TETRAKIS(2-BUTOXYETHYL) ORTHOSILICATE:
SPECIES: RABBIT
RESULT: SKIN IRRITATION
REMARKS: BASED ON TEST DATA
TITANIUM TETRABUTANOLATE:
RESULT: SKIN IRRITATION
BUTAN-1-OL:
SPECIES: RABBIT
RESULT: SKIN IRRITATION
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE DAMAGE.
INGREDIENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
SPECIES: RABBIT
RESULT: NO EYE IRRITATION
TOLUENE:
SPECIES: RABBIT
RESULT: NO EYE IRRITATION
METHOD: OECD TEST GUIDELINE 405
TETRAKIS(2-BUTOXYETHYL) ORTHOSILICATE:
SPECIES: RABBIT
RESULT: NO EYE IRRITATION
REMARKS: INFORMATION TAKEN FROM REFERENCE WORKS AND THE LITERATURE.
TITANIUM TETRABUTANOLATE:
SPECIES: RABBIT
RESULT: IRREVERSIBLE EFFECTS ON THE EYE
BUTAN-1-OL:
SPECIES: RABBIT
RESULT: IRREVERSIBLE EFFECTS ON THE EYE
METHOD: OECD TEST GUIDELINE 405
RESPIRATORY OR SKIN SENSITIZATION:
SKIN SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
RESPIRATORY SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
TEST TYPE: BUEHLER TEST
ROUTES OF EXPOSURE: SKIN CONTACT
SPECIES: GUINEA PIG
RESULT: NEGATIVE
TOLUENE:
TEST TYPE: MAXIMIZATION TEST
ROUTES OF EXPOSURE: SKIN CONTACT
SPECIES: GUINEA PIG
METHOD: OECD TEST GUIDELINE 406
RESULT: NEGATIVE
TETRAKIS(2-BUTOXYETHYL) ORTHOSILICATE:
ASSESSMENT: DOES NOT CAUSE SKIN SENSITIZATION.
TEST TYPE: BUEHLER TEST
REMARKS: NO KNOWN SENSITIZING EFFECT.
INFORMATION TAKEN FROM REFERENCE WORKS AND THE LITERATURE.
TITANIUM TETRABUTANOLATE:
TEST TYPE: LOCAL LYMPH NODE ASSAY (LLNA)
ROUTES OF EXPOSURE: SKIN CONTACT
SPECIES: MOUSE
RESULT: NEGATIVE
BUTAN-1-OL:
TEST TYPE: MAXIMIZATION TEST
ROUTES OF EXPOSURE: SKIN CONTACT
SPECIES: GUINEA PIG
RESULT: NEGATIVE
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
GENOTOXICITY IN VITRO:
REMARKS: IN VITRO TESTS DID NOT SHOW MUTAGENIC EFFECTS
GENOTOXICITY IN VIVO:
TEST TYPE:
MAMMALIAN ERYTHROCYTE MICRONUCLEUS TEST (IN VIVO CYTOGENETIC ASSAY)
SPECIES: RAT
APPLICATION ROUTE: INHALATION
RESULT: NEGATIVE
TOLUENE:
GENOTOXICITY IN VITRO:
TEST TYPE: IN VITRO MAMMALIAN CELL GENE MUTATION TEST
RESULT: NEGATIVE
TEST TYPE: BACTERIAL REVERSE MUTATION ASSAY (AMES)
RESULT: NEGATIVE
GENOTOXICITY IN VIVO:
TEST TYPE:
MUTAGENICITY (IN VIVO MAMMALIAN BONE-MARROW CYTOGENETIC TEST, CHROMOSOMAL
ANALYSIS)
SPECIES: MOUSE
APPLICATION ROUTE: INGESTION
RESULT: NEGATIVE
TITANIUM TETRABUTANOLATE:
GENOTOXICITY IN VITRO:
TEST TYPE: BACTERIAL REVERSE MUTATION ASSAY (AMES)
METHOD: OECD TEST GUIDELINE 471
RESULT: NEGATIVE
BUTAN-1-OL:
GENOTOXICITY IN VITRO:
TEST TYPE: IN VITRO MAMMALIAN CELL GENE MUTATION TEST
METHOD: OECD TEST GUIDELINE 476
RESULT: NEGATIVE
CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
SPECIES: MOUSE
APPLICATION ROUTE: SKIN CONTACT
EXPOSURE TIME: 102 WEEKS
RESULT: NEGATIVE
TOLUENE:
SPECIES: RAT
APPLICATION ROUTE: INHALATION (VAPOR)
EXPOSURE TIME: 24 MONTHS
RESULT: NEGATIVE
IARC:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
OSHA:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
NTP:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
INGREDIENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
EFFECTS ON FERTILITY:
TEST TYPE: TWO-GENERATION REPRODUCTION TOXICITY STUDY
SPECIES: RAT
APPLICATION ROUTE: INHALATION (VAPOR)
RESULT: NEGATIVE
EFFECTS ON FETAL DEVELOPMENT:
TEST TYPE: EMBRYO-FETAL DEVELOPMENT
SPECIES: RAT
APPLICATION ROUTE: INHALATION (VAPOR)
RESULT: NEGATIVE
TOLUENE:
EFFECTS ON FERTILITY:
TEST TYPE: ONE-GENERATION REPRODUCTION TOXICITY STUDY
SPECIES: RAT
APPLICATION ROUTE: INHALATION (VAPOR)
RESULT: NEGATIVE
EFFECTS ON FETAL DEVELOPMENT:
TEST TYPE: EMBRYO-FETAL DEVELOPMENT
SPECIES: RAT
APPLICATION ROUTE: INHALATION (VAPOR)
RESULT: POSITIVE
REPRODUCTIVE TOXICITY - ASSESSMENT:
SOME EVIDENCE OF ADVERSE EFFECTS ON DEVELOPMENT, BASED ON ANIMAL
EXPERIMENTS.
BUTAN-1-OL:
EFFECTS ON FERTILITY:
TEST TYPE: TWO-GENERATION REPRODUCTION TOXICITY STUDY
SPECIES: RAT
APPLICATION ROUTE: INHALATION (VAPOR)
METHOD: OECD TEST GUIDELINE 416
RESULT: NEGATIVE
EFFECTS ON FETAL DEVELOPMENT:
TEST TYPE: EMBRYO-FETAL DEVELOPMENT
SPECIES: RAT
APPLICATION ROUTE: INGESTION
RESULT: NEGATIVE
STOT-SINGLE EXPOSURE: MAY CAUSE DROWSINESS OR DIZZINESS.
INGREDIENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
ASSESSMENT: MAY CAUSE DROWSINESS OR DIZZINESS.
TOLUENE:
ASSESSMENT: MAY CAUSE DROWSINESS OR DIZZINESS.
TITANIUM TETRABUTANOLATE:
ASSESSMENT: MAY CAUSE RESPIRATORY IRRITATION.
ASSESSMENT: MAY CAUSE DROWSINESS OR DIZZINESS.
BUTAN-1-OL:
ASSESSMENT: MAY CAUSE RESPIRATORY IRRITATION.
ASSESSMENT: MAY CAUSE DROWSINESS OR DIZZINESS.
STOT-REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS (CENTRAL NERVOUS SYSTEM) THROUGH PROLONGED OR
REPEATED EXPOSURE.
INGREDIENTS:
TOLUENE:
TARGET ORGANS: CENTRAL NERVOUS SYSTEM
ASSESSMENT:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
REPEATED DOSE TOXICITY:
INGREDIENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
SPECIES: RAT
NOAEL: >20 MG/L
APPLICATION ROUTE: INHALATION (VAPOR)
EXPOSURE TIME: 13 WEEKS
METHOD: OPPTS 870.3465
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
TOLUENE:
SPECIES: RAT
LOAEL: 1.875 MG/L
APPLICATION ROUTE: INHALATION (VAPOR)
EXPOSURE TIME: 6 MONTHS
BUTAN-1-OL:
SPECIES: RAT
NOAEL: 125 MG/KG
APPLICATION ROUTE: INGESTION
EXPOSURE TIME: 13 WEEKS
ASPIRATION TOXICITY: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
INGREDIENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
THE SUBSTANCE OR MIXTURE IS KNOWN TO CAUSE HUMAN ASPIRATION TOXICITY
HAZARDS OR HAS TO BE REGARDED AS IF IT CAUSES A HUMAN ASPIRATION TOXICITY
HAZARD.
TOLUENE:
THE SUBSTANCE OR MIXTURE IS KNOWN TO CAUSE HUMAN ASPIRATION TOXICITY
HAZARDS OR HAS TO BE REGARDED AS IF IT CAUSES A HUMAN ASPIRATION TOXICITY
HAZARD.
EXPERIENCE WITH HUMAN EXPOSURE:
INGREDIENTS:
TOLUENE:
INHALATION:
TARGET ORGANS: CENTRAL NERVOUS SYSTEM
SYMPTOMS: NEUROLOGICAL DISORDERS, FATIGUE, VERTIGO
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
INGREDIENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
TOXICITY TO FISH:
LC50 (PIMEPHALES PROMELAS (FATHEAD MINNOW)): 8.2 MG/L
EXPOSURE TIME: 96 H
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (DAPHNIA MAGNA (WATER FLEA)): 4.5 MG/L
EXPOSURE TIME: 48 H
METHOD: OECD TEST GUIDELINE 202
TOXICITY TO ALGAE:
ERC50 (PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE)): 3.1 MG/L
EXPOSURE TIME: 72 H
METHOD: OECD TEST GUIDELINE 201
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY):
NOEC (DAPHNIA MAGNA (WATER FLEA)): 2.6 MG/L
EXPOSURE TIME: 21 D
METHOD: OECD TEST GUIDELINE 211
TOLUENE:
TOXICITY TO FISH:
LC50 (ONCORHYNCHUS KISUTCH (COHO SALMON)): 5.5 MG/L
EXPOSURE TIME: 96 H
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (CERIODAPHNIA DUBIA (WATER FLEA)): 3.78 MG/L
EXPOSURE TIME: 48 H
TOXICITY TO ALGAE:
NOEC (SKELETONEMA COSTATUM (MARINE DIATOM)): 10 MG/L
EXPOSURE TIME: 72 H
TOXICITY TO FISH (CHRONIC TOXICITY):
NOEC (ONCORHYNCHUS KISUTCH (COHO SALMON)): 1.39 MG/L
EXPOSURE TIME: 40 D
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY):
NOEC (DAPHNIA MAGNA (WATER FLEA)): 1 MG/L
EXPOSURE TIME: 21 D
NOEC (CERIODAPHNIA DUBIA (WATER FLEA)): 0.74 MG/L
EXPOSURE TIME: 7 D
TOXICITY TO BACTERIA:
EC50 (NITROSOMONAS SP.): 84 MG/L
EXPOSURE TIME: 24 H
TETRAKIS(2-BUTOXYETHYL) ORTHOSILICATE:
TOXICITY TO FISH:
LC50 (DANIO RERIO (ZEBRA FISH)): >201 MG/L
EXPOSURE TIME: 96 H
METHOD: OECD TEST GUIDELINE 203
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (DAPHNIA SP.): >90 MG/L
EXPOSURE TIME: 48 H
METHOD: EG 84/449
REMARKS: NO TOXICITY AT THE LIMIT OF SOLUBILITY.
TOXICITY TO ALGAE:
ERC50 (SCENEDESMUS SUBSPICATUS): >161 MG/L
EXPOSURE TIME: 72 H
METHOD: 88/302/EC
ECOTOXICOLOGY ASSESSMENT:
ACUTE AQUATIC TOXICITY: THIS PRODUCT HAS NO KNOWN ECOTOXICOLOGICAL EFFECTS.
BUTAN-1-OL:
TOXICITY TO FISH:
LC50 (PIMEPHALES PROMELAS (FATHEAD MINNOW)): 1,376 MG/L
EXPOSURE TIME: 96 H
METHOD: OECD TEST GUIDELINE 203
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (DAPHNIA MAGNA (WATER FLEA)): 1,328 MG/L
EXPOSURE TIME: 48 H
METHOD: OECD TEST GUIDELINE 202
TOXICITY TO ALGAE:
EC50 (DESMODESMUS SUBSPICATUS (GREEN ALGAE)): 225 MG/L
EXPOSURE TIME: 96 H
METHOD: OECD TEST GUIDELINE 201
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY):
NOEC (DAPHNIA MAGNA (WATER FLEA)): 4.1 MG/L
EXPOSURE TIME: 21 D
METHOD: OECD TEST GUIDELINE 211
TOXICITY TO BACTERIA:
EC50 (PSEUDOMONAS PUTIDA): 4,390 MG/L
EXPOSURE TIME: 17 H
PERSISTENCE AND DEGRADABILITY:
INGREDIENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
BIODEGRADABILITY:
RESULT: READILY BIODEGRADABLE.
BIODEGRADATION: 77.07%
EXPOSURE TIME: 28 D
METHOD: OECD TEST GUIDELINE 301F
TOLUENE:
BIODEGRADABILITY:
RESULT: READILY BIODEGRADABLE.
BIODEGRADATION: 86%
EXPOSURE TIME: 20 D
TETRAKIS(2-BUTOXYETHYL) ORTHOSILICATE:
BIODEGRADABILITY:
RESULT: READILY BIODEGRADABLE.
BIODEGRADATION: 83%
METHOD: OECD TEST GUIDELINE 301B
BUTAN-1-OL:
BIODEGRADABILITY:
RESULT: READILY BIODEGRADABLE.
BIODEGRADATION: 92%
EXPOSURE TIME: 20 D
BIOACCUMULATIVE POTENTIAL:
INGREDIENTS:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.:
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: >4
REMARKS: EXPERT JUDGMENT
TOLUENE:
BIOACCUMULATION:
SPECIES: LEUCISCUS IDUS (GOLDEN ORFE)
BIOCONCENTRATION FACTOR (BCF): 90
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: 2.73
TITANIUM TETRABUTANOLATE:
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: 0.88
BUTAN-1-OL:
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: 1
MOBILITY IN SOIL: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
RESOURCE CONSERVATION AND RECOVERY ACT (RCRA):
WHEN A DECISION IS MADE TO DISCARD THIS MATERIAL AS SUPPLIED, IT IS
CLASSIFIED AS A RCRA HAZARDOUS WASTE.
WASTE CODE:
D001: IGNITABILITY
D018
WASTE FROM RESIDUES: DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
DO NOT BURN, OR USE A CUTTING TORCH ON, THE EMPTY DRUM.
IF NOT OTHERWISE SPECIFIED: DISPOSE OF AS UNUSED PRODUCT.
| SECTION 14. TRANSPORT INFORMATION | |
INTERNATIONAL REGULATION:
UNRTDG:
UN NUMBER: UN 1993
PROPER SHIPPING NAME:
FLAMMABLE LIQUID, N.O.S. (SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.,
TOLUENE)
CLASS: 3
PACKING GROUP: II
LABELS: 3
IATA-DGR:
UN/ID NO.: UN 1993
PROPER SHIPPING NAME:
FLAMMABLE LIQUID, N.O.S. (SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.,
TOLUENE)
CLASS: 3
PACKING GROUP: II
LABELS: FLAMMABLE LIQUIDS
PACKING INSTRUCTION (CARGO AIRCRAFT): 364
PACKING INSTRUCTION (PASSENGER AIRCRAFT): 353
IMDG-CODE:
UN NUMBER: UN 1993
PROPER SHIPPING NAME:
FLAMMABLE LIQUID, N.O.S. (SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.,
TOLUENE)
CLASS: 3
PACKING GROUP: II
LABELS: 3
EMS CODE: F-E, S-E
MARINE POLLUTANT: YES
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE FOR PRODUCT AS SUPPLIED.
DOMESTIC REGULATION:
49 CFR:
UN/ID/NA NUMBER: UN 1993
PROPER SHIPPING NAME:
FLAMMABLE LIQUIDS, N.O.S. (SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.,
TOLUENE)
CLASS: 3
PACKING GROUP: II
LABELS: FLAMMABLE LIQUID
ERG CODE: 128
MARINE POLLUTANT: YES (SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH.)
| SECTION 15. REGULATORY INFORMATION | |
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW:
CERCLA REPORTABLE QUANTITY:
INGREDIENTS CAS-NO. COMPONENT RQ (LBS) CALCULATED PRODUCT RQ (LBS)
TOLUENE 108-88-3 1000 5263
BUTAN-1-OL 71-36-3 5000 *
ETHYLBENZENE 100-41-4 1000 *
*: CALCULATED RQ EXCEEDS REASONABLY ATTAINABLE UPPER LIMIT.
SARA 304 EXTREMELY HAZARDOUS SUBSTANCES REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 304 EHS RQ.
SARA 311/312 HAZARDS:
FIRE HAZARD
ACUTE HEALTH HAZARD
CHRONIC HEALTH HAZARD
SARA 302:
NO CHEMICALS IN THIS MATERIAL ARE SUBJECT TO THE REPORTING REQUIREMENTS OF
SARA TITLE III, SECTION 302.
SARA 313:
THE FOLLOWING COMPONENTS ARE SUBJECT TO REPORTING LEVELS ESTABLISHED BY
SARA TITLE III, SECTION 313:
TOLUENE 108-88-3 19%
BUTAN-1-OL 71-36-3 2.4%
US STATE REGULATIONS:
PENNSYLVANIA RIGHT TO KNOW:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. 64742-89-8 50 - 70%
TOLUENE 108-88-3 10 - 20%
TETRAPROPYL ORTHOSILICATE 682-01-9 1 - 5 %
TETRAKIS(2-BUTOXYETHYL)ORTHOSILICATE 18765-38-3 1 - 5%
TITANIUM TETRABUTANOLATE 5593-70-4 1 - 5 %
BUTAN-1-OL 71-36-3 1 - 5%
ETHYLBENZENE 100-41-4 0 - 0.1%
NEW JERSEY RIGHT TO KNOW:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. 64742-89-8 50 - 70%
TOLUENE 108-88-3 10 - 20%
TETRAPROPYL ORTHOSILICATE 682-01-9 1 - 5%
TETRAKIS(2-BUTOXYETHYL) ORTHOSILICATE 18765-38-3 1 - 5%
TITANIUM TETRABUTANOLATE 5593-70-4 1 - 5 %
BUTAN-1-OL 71-36-3 1 - 5%
CALIFORNIA PROP. 65:
WARNING!
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
ETHYLBENZENE 100-41-4
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
TOLUENE 108-88-3
THE INGREDIENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES:
TSCA:
ALL CHEMICAL SUBSTANCES IN THIS MATERIAL ARE INCLUDED ON OR EXEMPTED FROM
LISTING ON THE TSCA INVENTORY OF CHEMICAL SUBSTANCES.
IECSC: ALL INGREDIENTS LISTED OR EXEMPT.
ENCS/ISHL:
ALL COMPONENTS ARE LISTED ON ENCS/ISHL OR EXEMPTED FROM INVENTORY LISTING.
PICCS: ALL INGREDIENTS LISTED OR EXEMPT.
DSL:
THIS PRODUCT CONTAINS ONE OR MORE SUBSTANCES WHICH ARE NOT ON THE CANADIAN
DOMESTIC SUBSTANCES LIST (DSL). IMPORT OF THIS PRODUCT INTO CANADA HAS
VOLUME LIMITATIONS. FOR VOLUME LIMITS PLEASE CONSULT DOW CORNING REGULATORY
COMPLIANCE.
REACH:
FOR PURCHASES FROM DOW CORNING EU LEGAL ENTITIES, ALL INGREDIENTS ARE
CURRENTLY PRE/REGISTERED OR EXEMPT UNDER REACH. FOR PURCHASES FROM NON-EU
DOW CORNING LEGAL ENTITIES WITH THE INTENTION TO EXPORT INTO EEA PLEASE
CONTACT YOUR DC REPRESENTATIVE/LOCAL OFFICE.
AICS: CONSULT YOUR LOCAL DOW CORNING OFFICE.
KECI: ONE OR MORE INGREDIENTS ARE NOT LISTED OR EXEMPT.
TCSI: ALL INGREDIENTS LISTED OR EXEMPT.
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
NFPA:
HEALTH 3
FLAMMABILITY 3
INSTABILITY 0
SPECIAL HAZARD.
HMIS III:
HEALTH 3*
FLAMMABILITY 3
PHYSICAL HAZARD 0
0 = NOT SIGNIFICANT
1 = SLIGHT
2 = MODERATE
3 = HIGH
4 = EXTREME
* = CHRONIC
FULL TEXT OF OTHER ABBREVIATIONS:
ACGIH: USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
ACGIH BEI: ACGIH - BIOLOGICAL EXPOSURE INDICES (BEI)
NIOSH REL: USA. NIOSH RECOMMENDED EXPOSURE LIMITS
OSHA Z-1:
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z-1 LIMITS FOR AIR
CONTAMINANTS
OSHA Z-2: USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z-2
ACGIH / TWA: 8-HOUR, TIME-WEIGHTED AVERAGE
NIOSH REL / TWA:
TIME-WEIGHTED AVERAGE CONCENTRATION FOR UP TO A 10-HOUR WORKDAY DURING A
40-HOUR WORKWEEK
NIOSH REL / ST:
STEL - 15-MINUTE TWA EXPOSURE THAT SHOULD NOT BE EXCEEDED AT ANY TIME
DURING A WORKDAY
NIOSH REL / C: CEILING VALUE NOT BE EXCEEDED AT ANY TIME.
OSHA Z-1 / TWA: 8-HOUR TIME WEIGHTED AVERAGE
OSHA Z-2 / TWA: 8-HOUR TIME WEIGHTED AVERAGE
OSHA Z-2 / CEIL: ACCEPTABLE CEILING CONCENTRATION
OSHA Z-2 / PEAK:
ACCEPTABLE MAXIMUM PEAK ABOVE THE ACCEPTABLE CEILING CONCENTRATION FOR AN
8-HR SHIFT
AICS: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES
ASTM: AMERICAN SOCIETY FOR THE TESTING OF MATERIALS
BW: BODY WEIGHT
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
CMR: CARCINOGEN, MUTAGEN OR REPRODUCTIVE TOXICANT
DIN: STANDARD OF THE GERMAN INSTITUTE FOR STANDARDIZATION
DOT: DEPARTMENT OF TRANSPORTATION
DSL: DOMESTIC SUBSTANCES LIST (CANADA)
ECX: CONCENTRATION ASSOCIATED WITH X% RESPONSE
EHS: EXTREMELY HAZARDOUS SUBSTANCE
ELX: LOADING RATE ASSOCIATED WITH X% RESPONSE
EMS: EMERGENCY SCHEDULE
ENCS: EXISTING AND NEW CHEMICAL SUBSTANCES (JAPAN)
ERCX: CONCENTRATION ASSOCIATED WITH X% GROWTH RATE RESPONSE
ERG: EMERGENCY RESPONSE GUIDE
GHS: GLOBALLY HARMONIZED SYSTEM
GLP: GOOD LABORATORY PRACTICE
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC:
INTERNATIONAL CODE FOR THE CONSTRUCTION AND EQUIPMENT OF SHIPS CARRYING
DANGEROUS CHEMICALS IN BULK
IC50: HALF MAXIMAL INHIBITORY CONCENTRATION
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
IECSC: INVENTORY OF EXISTING CHEMICAL SUBSTANCES IN CHINA
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
IMO: INTERNATIONAL MARITIME ORGANIZATION
ISHL: INDUSTRIAL SAFETY AND HEALTH LAW (JAPAN)
ISO: INTERNATIONAL ORGANIZATION FOR STANDARDIZATION
KECI: KOREA EXISTING CHEMICALS INVENTORY
LC50: LETHAL CONCENTRATION TO 50% OF A TEST POPULATION
LD50: LETHAL DOSE TO 50% OF A TEST POPULATION (MEDIAN LETHAL DOSE)
MARPOL: INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS
MSHA: MINE SAFETY AND HEALTH ADMINISTRATION
N.O.S.: NOT OTHERWISE SPECIFIED
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NO(A)EC: NO OBSERVED (ADVERSE) EFFECT CONCENTRATION
NO(A)EL: NO OBSERVED (ADVERSE) EFFECT LEVEL
NOELR: NO OBSERVABLE EFFECT LOADING RATE
NTP: NATIONAL TOXICOLOGY PROGRAM
NZIOC: NEW ZEALAND INVENTORY OF CHEMICALS
OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
OPPTS: OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC SUBSTANCE
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
(Q)SAR: (QUANTITATIVE) STRUCTURE ACTIVITY RELATIONSHIP
RCRA: RESOURCE CONSERVATION AND RECOVERY ACT
REACH:
REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
CONCERNING THE REGISTRATION, EVALUATION, AUTHORIZATION AND RESTRICTION OF
CHEMICALS
RQ: REPORTABLE QUANTITY
SADT: SELF-ACCELERATING DECOMPOSITION TEMPERATURE
SARA: SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
SDS: SAFETY DATA SHEET
TCSI: TAIWAN CHEMICAL SUBSTANCE INVENTORY
TSCA: TOXIC SUBSTANCES CONTROL ACT (UNITED STATES)
UN: UNITED NATIONS
UNRTDG: UNITED NATIONS RECOMMENDATIONS ON THE TRANSPORT OF DANGEROUS GOODS
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
SOURCES OF KEY DATA USED TO COMPILE THE MATERIAL SAFETY DATA SHEET:
INTERNAL TECHNICAL DATA, DATA FROM RAW MATERIAL SDSS, OECD ECHEM PORTAL
SEARCH RESULTS AND EUROPEAN CHEMICALS AGENCY, HTTP://ECHA.EUROPA.EU/
REVISION DATE: 02/15/2016
ITEMS WHERE CHANGES HAVE BEEN MADE TO THE PREVIOUS VERSION ARE HIGHLIGHTED
IN THE BODY OF THIS DOCUMENT BY TWO VERTICAL LINES.
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING, USE,
PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND SHALL NOT BE
CONSIDERED A WARRANTY OR QUALITY SPECIFICATION OF ANY TYPE. THE INFORMATION
PROVIDED RELATES ONLY TO THE SPECIFIC MATERIAL IDENTIFIED AT THE TOP OF
THIS SDS AND MAY NOT BE VALID WHEN THE SDS MATERIAL IS USED IN COMBINATION
WITH ANY OTHER MATERIALS OR IN ANY PROCESS, UNLESS SPECIFIED IN THE TEXT.
MATERIAL USERS SHOULD REVIEW THE INFORMATION AND RECOMMENDATIONS IN THE
SPECIFIC CONTEXT OF THEIR INTENDED MANNER OF HANDLING, USE, PROCESSING AND
STORAGE, INCLUDING AN ASSESSMENT OF THE APPROPRIATENESS OF THE SDS MATERIAL
IN THE USER'S END PRODUCT, IF APPLICABLE.
US / Z8