| Common Name: | PR-4040 PRIME COAT |
| Manufacturer: | DOW CORNING |
| SDS Revision Date: | 10/29/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 53DD06, 53DD07 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DOW CORNING
SAFETY DATA SHEET
DOW CORNING(R) PR-4040 PRIME COAT
VERSION: 1.2
REVISION DATE: 10/29/2015
SDS NUMBER: 999475-00003
DATE OF LAST ISSUE: 04/27/2015
DATE OF FIRST ISSUE: 12/23/2014
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: DOW CORNING(R) PR-4040 PRIME COAT
PRODUCT CODE: 000000000004093630
MANUFACTURER OR SUPPLIER'S DETAILS:
COMPANY NAME OF SUPPLIER: DOW CORNING CORPORATION
ADDRESS:
SOUTH SAGINAW ROAD
MIDLAND MICHIGAN 48686
TELEPHONE: (989) 496-6000
EMERGENCY TELEPHONE:
24 HOUR EMERGENCY TELEPHONE: (989) 496-5900
CHEMTREC: (800) 424-9300
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVE, BINDING AGENTS
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION
FLAMMABLE LIQUIDS: CATEGORY 2
SKIN IRRITATION: CATEGORY 2
EYE IRRITATION: CATEGORY 2A
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY - SINGLE EXPOSURE: CATEGORY 3
ASPIRATION HAZARD: CATEGORY 1
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P210:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES.
NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P261: AVOID BREATHING SPRAY.
P264: WASH SKIN THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280: WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
P301 + P310:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P303 + P361 + P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P304 + P340 + P312:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P331: DO NOT INDUCE VOMITING.
P332 + P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P337 + P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P362 + P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
P370 + P261:
IN CASE OF FIRE: AVOID BREATHING FUME.
STORAGE:
P403 + P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405: STORE LOCKED UP.
DISPOSAL:
P501: DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS:
VAPORS MAY FORM EXPLOSIVE MIXTURE WITH AIR.
STATIC-ACCUMULATING FLAMMABLE LIQUID.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
CHEMICAL NATURE: SILICONE IN SOLVENT
HAZARDOUS INGREDIENTS:
CHEMICAL NAME CAS-NO. CONCENTRATION (% W/W)
HEPTANE 142-82-5 >=70 - <90
TITANIUM TETRABUTANOLATE 5593-70-4 >=1 - <5
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
IN THE CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY.
WHEN SYMPTOMS PERSIST OR IN ALL CASES OF DOUBT SEEK MEDICAL ADVICE.
IF INHALED:
IF INHALED, REMOVE TO FRESH AIR.
GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
IN CASE OF SKIN CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
GET MEDICAL ATTENTION.
WASH CLOTHING BEFORE REUSE.
THOROUGHLY CLEAN SHOES BEFORE REUSE.
IN CASE OF EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES.
IF EASY TO DO, REMOVE CONTACT LENS, IF WORN.
GET MEDICAL ATTENTION.
IF SWALLOWED:
IF SWALLOWED, DO NOT INDUCE VOMITING.
IF VOMITING OCCURS HAVE PERSON LEAN FORWARD.
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
RINSE MOUTH THOROUGHLY WITH WATER.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
PROTECTION OF FIRST-AIDERS:
FIRST AID RESPONDERS SHOULD PAY ATTENTION TO SELF-PROTECTION, AND USE THE
RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT WHEN THE POTENTIAL FOR EXPOSURE
EXISTS.
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
| SECTION 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY
ALCOHOL-RESISTANT FOAM
CARBON DIOXIDE (CO2)
DRY CHEMICAL
UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET
SPECIFIC HAZARDS DURING FIRE:
DO NOT USE A SOLID WATER STREAM AS IT MAY SCATTER AND SPREAD FIGHTING FIRE.
FLASH BACK POSSIBLE OVER CONSIDERABLE DISTANCE.
VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR.
VERY TOXIC VAPORS ARE EVOLVED.
EXPOSURE TO COMBUSTION PRODUCTS MAY BE A HAZARD TO HEALTH.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON OXIDES
SILICON OXIDES
FLUORINE COMPOUNDS
FORMALDEHYDE
METAL OXIDES
SPECIFIC EXTINGUISHING METHODS:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
USE WATER SPRAY TO COOL UNOPENED CONTAINERS.
REMOVE UNDAMAGED CONTAINERS FROM FIRE AREA IF IT IS SAFE TO DO SO.
EVACUATE AREA.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
USE PERSONAL PROTECTIVE EQUIPMENT.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
REMOVE ALL SOURCES OF IGNITION.
VENTILATE THE AREA.
USE PERSONAL PROTECTIVE EQUIPMENT.
FOLLOW SAFE HANDLING ADVICE AND PERSONAL PROTECTIVE EQUIPMENT
RECOMMENDATIONS.
ENVIRONMENTAL PRECAUTIONS:
DISCHARGE INTO THE ENVIRONMENT MUST BE AVOIDED.
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
PREVENT SPREADING OVER A WIDE AREA (E.G. BY CONTAINMENT OR OIL BARRIERS).
RETAIN AND DISPOSE OF CONTAMINATED WASH WATER.
LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE
CONTAINED.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
NON-SPARKING TOOLS SHOULD BE USED.
SOAK UP WITH INERT ABSORBENT MATERIAL.
SUPPRESS (KNOCK DOWN) GASES/VAPORS/MISTS WITH A WATER SPRAY JET.
FOR LARGE SPILLS, PROVIDE DIKING OR OTHER APPROPRIATE CONTAINMENT TO KEEP
MATERIAL FROM SPREADING. IF DIKED MATERIAL CAN BE PUMPED, STORE RECOVERED
MATERIAL IN APPROPRIATE CONTAINER. CLEAN UP REMAINING MATERIALS FROM SPILL
WITH SUITABLE ABSORBENT.
LOCAL OR NATIONAL REGULATIONS MAY APPLY TO RELEASES AND DISPOSAL OF THIS
MATERIAL, AS WELL AS THOSE MATERIALS AND ITEMS EMPLOYED IN THE CLEANUP OF
RELEASES. YOU WILL NEED TO DETERMINE WHICH REGULATIONS ARE APPLICABLE.
SECTIONS 13 AND 15 OF THIS SDS PROVIDE INFORMATION REGARDING CERTAIN LOCAL
OR NATIONAL REQUIREMENTS.
| SECTION 7. HANDLING AND STORAGE | |
TECHNICAL MEASURES:
ENSURE ALL EQUIPMENT IS ELECTRICALLY GROUNDED BEFORE BEGINNING TRANSFER
OPERATIONS.
THIS MATERIAL CAN ACCUMULATE STATIC CHARGE DUE TO ITS INHERENT PHYSICAL
PROPERTIES AND CAN THEREFORE CAUSE AN ELECTRICAL IGNITION SOURCE TO VAPORS.
IN ORDER TO PREVENT A FIRE HAZARD, AS BONDING AND GROUNDING MAY BE
INSUFFICIENT TO REMOVE STATIC ELECTRICITY, IT IS NECESSARY TO PROVIDE AN
INERT GAS PURGE BEFORE BEGINNING TRANSFER OPERATIONS.
RESTRICT FLOW VELOCITY IN ORDER TO REDUCE THE ACCUMULATION OF STATIC
ELECTRICITY.
LOCAL/TOTAL VENTILATION:
USE WITH LOCAL EXHAUST VENTILATION.
USE ONLY IN AN AREA EQUIPPED WITH EXPLOSION PROOF EXHAUST VENTILATION.
ADVICE ON SAFE HANDLING:
DO NOT GET ON SKIN OR CLOTHING.
DO NOT BREATHE VAPORS OR SPRAY MIST.
DO NOT SWALLOW.
DO NOT GET IN EYES.
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
NON-SPARKING TOOLS SHOULD BE USED.
KEEP CONTAINER TIGHTLY CLOSED.
KEEP AWAY FROM WATER.
PROTECT FROM MOISTURE.
KEEP AWAY FROM HEAT AND SOURCES OF IGNITION.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES.
TAKE CARE TO PREVENT SPILLS, WASTE AND MINIMIZE RELEASE TO THE ENVIRONMENT.
CONDITIONS FOR SAFE STORAGE:
KEEP IN PROPERLY LABELED CONTAINERS.
STORE LOCKED UP.
KEEP TIGHTLY CLOSED.
KEEP IN A COOL, WELL-VENTILATED PLACE.
STORE IN ACCORDANCE WITH THE PARTICULAR NATIONAL REGULATIONS.
KEEP AWAY FROM HEAT AND SOURCES OF IGNITION.
MATERIALS TO AVOID:
DO NOT STORE WITH THE FOLLOWING PRODUCT TYPES:
STRONG OXIDIZING AGENTS
ORGANIC PEROXIDES
FLAMMABLE SOLIDS
PYROPHORIC LIQUIDS
PYROPHORIC SOLIDS
SELF-HEATING SUBSTANCES AND MIXTURES
SUBSTANCES AND MIXTURES WHICH IN CONTACT WITH WATER EMIT
FLAMMABLE GASES
EXPLOSIVES
GASES
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
INGREDIENTS WITH WORKPLACE CONTROL PARAMETERS:
INGREDIENTS CAS-NO. VALUE TYPE CONTROL PARAME- BASIS
(FORM OF TERS / PERMISSIBLE
EXPOSURE) CONCENTRATION
HEPTANE 142-82-5 TWA 85 PPM NIOSH REL
350 MG/M3
C 440 PPM NIOSH REL
1,800 MG/M3
TWA 500 PPM OSHA Z-1
2,000 MG/M3
TWA 400 PPM ACGIH
STEL 500 PPM ACGIH
HAZARDOUS COMPONENTS WITHOUT WORKPLACE CONTROL PARAMETERS:
INGREDIENTS CAS-NO.
TITANIUM TETRABUTANOLATE 5593-70-4
OCCUPATIONAL EXPOSURE LIMITS OF DECOMPOSITION PRODUCTS:
INGREDIENTS CAS-NO. VALUE TYPE CONTROL PARAME- BASIS
(FORM OF TERS / PERMISSIBLE
EXPOSURE) CONCENTRATION
METHANOL 67-56-1 TWA 200 PPM ACGIH
STEL 250 PPM ACGIH
TWA 200 PPM NIOSH REL
260 MG/M3
ST 250 PPM NIOSH REL
325 MG/M3
TWA 200 PPM OSHA Z-1
260 MG/M3
BUTAN-1-OL 71-36-3 TWA 20 PPM ACGIH
C 50 PPM NIOSH REL
150 MG/M3
TWA 100 PPM OSHA Z-1
300 MG/M3
ENGINEERING MEASURES:
PROCESSING MAY FORM HAZARDOUS COMPOUNDS (SEE SECTION 10).
MINIMIZE WORKPLACE EXPOSURE CONCENTRATIONS.
USE ONLY IN AN AREA EQUIPPED WITH EXPLOSION PROOF EXHAUST VENTILATION.
USE WITH LOCAL EXHAUST VENTILATION.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
GENERAL AND LOCAL EXHAUST VENTILATION IS RECOMMENDED TO MAINTAIN VAPOR
EXPOSURES BELOW RECOMMENDED LIMITS. WHERE CONCENTRATIONS ARE ABOVE
RECOMMENDED LIMITS OR ARE UNKNOWN, APPROPRIATE RESPIRATORY PROTECTION
SHOULD BE WORN. FOLLOW OSHA RESPIRATOR REGULATIONS (29 CFR 1910.134) AND
USE NIOSH/MSHA APPROVED RESPIRATORS. PROTECTION PROVIDED BY AIR PURIFYING
RESPIRATORS AGAINST EXPOSURE TO ANY HAZARDOUS CHEMICAL IS LIMITED. USE A
POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR IF THERE IS ANY POTENTIAL FOR
UNCONTROLLED RELEASE, EXPOSURE LEVELS ARE UNKNOWN, OR ANY OTHER
CIRCUMSTANCE WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
HAND PROTECTION:
MATERIAL: ANTISTATIC GLOVES
MATERIAL: IMPERVIOUS GLOVES
MATERIAL: FLAME RETARDANT GLOVES
REMARKS:
CHOOSE GLOVES TO PROTECT HANDS AGAINST CHEMICALS DEPENDING ON THE
CONCENTRATION SPECIFIC TO PLACE OF WORK. BREAKTHROUGH TIME IS NOT
DETERMINED FOR THE PRODUCT. CHANGE GLOVES OFTEN! FOR SPECIAL APPLICATIONS,
WE RECOMMEND CLARIFYING THE RESISTANCE TO CHEMICALS OF THE AFOREMENTIONED
PROTECTIVE GLOVES WITH THE GLOVE MANUFACTURER. WASH HANDS BEFORE BREAKS AND
AT THE END OF WORKDAY.
EYE PROTECTION:
WEAR THE FOLLOWING PERSONAL PROTECTIVE EQUIPMENT: SAFETY GOGGLES
SKIN AND BODY PROTECTION:
SELECT APPROPRIATE PROTECTIVE CLOTHING BASED ON CHEMICAL RESISTANCE DATA
AND AN ASSESSMENT OF THE LOCAL EXPOSURE POTENTIAL.
WEAR THE FOLLOWING PERSONAL PROTECTIVE EQUIPMENT:
FLAME RETARDANT ANTISTATIC PROTECTIVE CLOTHING.
SKIN CONTACT MUST BE AVOIDED BY USING IMPERVIOUS PROTECTIVE CLOTHING
(GLOVES, APRONS, BOOTS, ETC).
HYGIENE MEASURES:
ENSURE THAT EYE FLUSHING SYSTEMS AND SAFETY SHOWERS ARE LOCATED CLOSE TO
THE WORKING PLACE.
WHEN USING DO NOT EAT, DRINK OR SMOKE.
WASH CONTAMINATED CLOTHING BEFORE RE-USE.
THESE PRECAUTIONS ARE FOR ROOM TEMPERATURE HANDLING. USE AT ELEVATED
TEMPERATURE OR AEROSOL/SPRAY APPLICATIONS MAY REQUIRE ADDED PRECAUTIONS.
FOR FURTHER INFORMATION REGARDING THE USE OF SILICONES / ORGANIC OILS IN
CONSUMER AEROSOL APPLICATIONS, PLEASE REFER TO THE GUIDANCE DOCUMENT
REGARDING THE USE OF THESE TYPE OF MATERIALS IN CONSUMER AEROSOL
APPLICATIONS THAT HAS BEEN DEVELOPED BY THE SILICONE INDUSTRY
(WWW.SEHSC.COM) OR CONTACT THE DOW CORNING CUSTOMER SERVICE GROUP.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
COLOR: COLORLESS TO PALE YELLOW
ODOR: SLIGHT
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
INITIAL BOILING POINT AND BOILING: >90 DEG. C RANGE
FLASH POINT: -12.8 DEG. C
METHOD: PENSKY-MARTENS CLOSED CUP
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY: 0.74
SOLUBILITY(IES) WATER SOLUBILITY: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY:
VISCOSITY, KINEMATIC: 1 MM2/S
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
OXIDIZING PROPERTIES:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS OXIDIZING.
MOLECULAR WEIGHT: NO DATA AVAILABLE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NOT CLASSIFIED AS A REACTIVITY HAZARD.
CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
VAPORS MAY FORM EXPLOSIVE MIXTURE WITH AIR.
USE AT ELEVATED TEMPERATURES MAY FORM HIGHLY HAZARDOUS COMPOUNDS.
CAN REACT WITH STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS WILL BE FORMED UPON CONTACT WITH WATER OR
HUMID AIR.
HAZARDOUS DECOMPOSITION PRODUCTS WILL BE FORMED AT ELEVATED TEMPERATURES.
CONDITIONS TO AVOID:
EXPOSURE TO MOISTURE.
HANDLING OPERATIONS THAT CAN PROMOTE ACCUMULATION OF STATIC CHARGES.
HEAT, FLAMES AND SPARKS.
INCOMPATIBLE MATERIALS:
OXIDIZING AGENTS
WATER
HAZARDOUS DECOMPOSITION PRODUCTS:
CONTACT WITH WATER OR HUMID AIR:
METHANOL
BUTAN-1-OL
THERMAL DECOMPOSITION:
FORMALDEHYDE
TRIFLUOROPROPIONALDEHYDE
HYDROGEN FLUORIDE
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION
SKIN CONTACT
INGESTION
EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
ACUTE ORAL TOXICITY:
ACUTE TOXICITY ESTIMATE: >5,000 MG/KG
METHOD: CALCULATION METHOD
INGREDIENTS:
HEPTANE:
ACUTE ORAL TOXICITY:
LD50 (RAT): >5,000 MG/KG
METHOD: OECD TEST GUIDELINE 401
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE ORAL TOXICITY
ACUTE INHALATION TOXICITY:
LC50 (RAT): >29.29 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOR
METHOD: OECD TEST GUIDELINE 403
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE INHALATION TOXICITY
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >2,000 MG/KG
METHOD: OECD TEST GUIDELINE 402
ASSESSMENT: THE SUBSTANCE OR MIXTURE HAS NO ACUTE DERMAL TOXICITY
TITANIUM TETRABUTANOLATE:
ACUTE ORAL TOXICITY:
LD50 (RAT): >2,000 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): 11 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: DUST/MIST
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
INGREDIENTS:
HEPTANE:
SPECIES: RABBIT
METHOD: OECD TEST GUIDELINE 404
RESULT: SKIN IRRITATION
TITANIUM TETRABUTANOLATE:
RESULT: SKIN IRRITATION
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
INGREDIENTS:
HEPTANE:
SPECIES: RABBIT
RESULT: NO EYE IRRITATION
METHOD: OECD TEST GUIDELINE 405
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
TITANIUM TETRABUTANOLATE:
SPECIES: RABBIT
RESULT: IRREVERSIBLE EFFECTS ON THE EYE
RESPIRATORY OR SKIN SENSITIZATION:
SKIN SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
RESPIRATORY SENSITIZATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
HEPTANE:
TEST TYPE: MAXIMIZATION TEST
ROUTES OF EXPOSURE: SKIN CONTACT
SPECIES: GUINEA PIG
METHOD: OECD TEST GUIDELINE 406
RESULT: NEGATIVE
TITANIUM TETRABUTANOLATE:
TEST TYPE: LOCAL LYMPH NODE ASSAY (LLNA)
ROUTES OF EXPOSURE: SKIN CONTACT
SPECIES: MOUSE
RESULT: NEGATIVE
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
HEPTANE:
GENOTOXICITY IN VITRO:
TEST TYPE: CHROMOSOME ABERRATION TEST IN VITRO
METHOD: OECD TEST GUIDELINE 473
RESULT: NEGATIVE
TITANIUM TETRABUTANOLATE:
GENOTOXICITY IN VITRO:
TEST TYPE: BACTERIAL REVERSE MUTATION ASSAY (AMES)
METHOD: OECD TEST GUIDELINE 471
RESULT: NEGATIVE
CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
IARC:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
OSHA:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
NTP:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
REPRODUCTIVE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
INGREDIENTS:
HEPTANE:
EFFECTS ON FERTILITY:
TEST TYPE: TWO-GENERATION REPRODUCTION TOXICITY STUDY
SPECIES: RAT
APPLICATION ROUTE: INHALATION (VAPOR)
RESULT: NEGATIVE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
EFFECTS ON FETAL DEVELOPMENT:
TEST TYPE: EMBRYO-FETAL DEVELOPMENT
SPECIES: MOUSE
APPLICATION ROUTE: INHALATION (VAPOR)
RESULT: NEGATIVE
REMARKS: BASED ON DATA FROM SIMILAR MATERIALS
STOT-SINGLE EXPOSURE: MAY CAUSE DROWSINESS OR DIZZINESS.
INGREDIENTS:
HEPTANE:
ASSESSMENT: MAY CAUSE DROWSINESS OR DIZZINESS.
TITANIUM TETRABUTANOLATE:
ASSESSMENT: MAY CAUSE RESPIRATORY IRRITATION.
ASSESSMENT: MAY CAUSE DROWSINESS OR DIZZINESS.
STOT-REPEATED EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
REPEATED DOSE TOXICITY
INGREDIENTS:
HEPTANE:
SPECIES: RAT
NOAEL: 12.47 MG/L
APPLICATION ROUTE: INHALATION (VAPOR)
EXPOSURE TIME: 16 WEEKS
ASPIRATION TOXICITY: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
INGREDIENTS:
HEPTANE:
THE SUBSTANCE OR MIXTURE IS KNOWN TO CAUSE HUMAN ASPIRATION TOXICITY
HAZARDS OR HAS TO BE REGARDED AS IF IT CAUSES A HUMAN ASPIRATION TOXICITY
HAZARD.
FURTHER INFORMATION:
PRODUCT:
REMARKS:
PRODUCT CONTAINS TETRAMETHOXYSILANE WHICH IS HIGHLY TOXIC BY INHALATION.
THE 4 HOUR LC50 IN RATS IS 63 PPM. SEVERE EYE INJURY RANGING FROM EYE PAIN
TO BLINDNESS AND EYE LOSS HAS RESULTED FROM OCCUPATIONAL EXPOSURE TO
TETRAMETHOXYSILANE. EXPOSURE TO AIR CONCENTRATIONS OF 200 TO 300 PPM FOR 15
MINUTES CAN INDUCE MINIMAL EYE LESIONS AND EXPOSURE AT 1000 PPM CAN PRODUCE
CORNEAL DAMAGE.
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
INGREDIENTS:
HEPTANE:
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (DAPHNIA MAGNA (WATER FLEA)): 0.2 MG/L
EXPOSURE TIME: 48 H
M-FACTOR (ACUTE AQUATIC TOXICITY): 1
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL:
INGREDIENTS:
HEPTANE:
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: 4.5
TITANIUM TETRABUTANOLATE:
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: 0.88
MOBILITY IN SOIL: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
RESOURCE CONSERVATION AND RECOVERY ACT (RCRA):
WHEN A DECISION IS MADE TO DISCARD THIS MATERIAL AS SUPPLIED, IT IS
CLASSIFIED AS A RCRA HAZARDOUS WASTE.
WASTE CODE:
D001: IGNITABILITY
D018
WASTE FROM RESIDUES: DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
DO NOT BURN, OR USE A CUTTING TORCH ON, THE EMPTY DRUM.
IF NOT OTHERWISE SPECIFIED: DISPOSE OF AS UNUSED PRODUCT.
| SECTION 14. TRANSPORT INFORMATION | |
INTERNATIONAL REGULATION:
UNRTDG:
UN NUMBER: UN 1206
PROPER SHIPPING NAME: HEPTANES SOLUTION
CLASS: 3
PACKING GROUP: II
LABELS: 3
IATA-DGR:
UN/ID NO.: UN 1206
PROPER SHIPPING NAME: HEPTANES SOLUTION
CLASS: 3
PACKING GROUP: II
LABELS: FLAMMABLE LIQUIDS
PACKING INSTRUCTION (CARGO AIRCRAFT): 364
PACKING INSTRUCTION (PASSENGER AIRCRAFT): 353
IMDG-CODE:
UN NUMBER: UN 1206
PROPER SHIPPING NAME: HEPTANES SOLUTION (HEPTANE)
CLASS: 3
PACKING GROUP: II
LABELS: 3
EMS CODE: F-E, S-D
MARINE POLLUTANT: YES
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE FOR PRODUCT AS SUPPLIED.
DOMESTIC REGULATION:
49 CFR:
UN/ID/NA NUMBER: UN 1206
PROPER SHIPPING NAME: HEPTANES SOLUTION
CLASS: 3
PACKING GROUP: II
LABELS: FLAMMABLE LIQUID
ERG CODE: 128
MARINE POLLUTANT: YES (HEPTANE)
| SECTION 15. REGULATORY INFORMATION | |
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW:
CERCLA REPORTABLE QUANTITY:
INGREDIENTS CAS-NO. COMPONENT RQ (LBS) CALCULATED PRODUCT RQ (LBS)
BUTAN-1-OL 71-36-3 5000 *
*: CALCULATED RQ EXCEEDS REASONABLY ATTAINABLE UPPER LIMIT.
SARA 304 EXTREMELY HAZARDOUS SUBSTANCES REPORTABLE QUANTITY:
THIS MATERIAL DOES NOT CONTAIN ANY COMPONENTS WITH A SECTION 304 EHS RQ.
SARA 311/312 HAZARDS:
FIRE HAZARD
ACUTE HEALTH HAZARD
SARA 302:
NO CHEMICALS IN THIS MATERIAL ARE SUBJECT TO THE REPORTING REQUIREMENTS OF
SARA TITLE III, SECTION 302.
SARA 313:
THIS MATERIAL DOES NOT CONTAIN ANY CHEMICAL COMPONENTS WITH KNOWN CAS
NUMBERS THAT EXCEED THE THRESHOLD (DE MINIMIS) REPORTING LEVELS ESTABLISHED
BY SARA TITLE III, SECTION 313.
US STATE REGULATIONS:
PENNSYLVANIA RIGHT TO KNOW:
HEPTANE 142-82-5 70 - 90%
TRIFLUOROPROPYL TRIMETHOXYSILANE 429-60-7 10 - 20%
ALLYLTRIMETHOXYSILANE 2551-83-9 1 - 5%
BUTAN-1-OL 71-36-3 0 - 0.1%
NEW JERSEY RIGHT TO KNOW:
HEPTANE 142-82-5 70 - 90%
TRIFLUOROPROPYLTRIMETHOXYSILANE 429-60-7 10 - 20%
ALLYLTRIMETHOXYSILANE 2551-83-9 1 - 5%
TITANIUM TETRABUTANOLATE 5593-70-4 1 - 5%
CALIFORNIA PROP. 65:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH, OR ANY OTHER REPRODUCTIVE DEFECTS.
THE INGREDIENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES:
NZIOC: ONE OR MORE INGREDIENTS ARE NOT LISTED OR EXEMPT.
REACH: ALL INGREDIENTS (PRE-)REGISTERED OR EXEMPT.
TSCA:
ALL CHEMICAL SUBSTANCES IN THIS MATERIAL ARE INCLUDED ON OR EXEMPTED FROM
LISTING ON THE TSCA INVENTORY OF CHEMICAL SUBSTANCES.
PICCS: ALL INGREDIENTS LISTED OR EXEMPT.
KECI: ALL INGREDIENTS LISTED, EXEMPT OR NOTIFIED.
ENCS/ISHL:
ALL COMPONENTS ARE LISTED ON ENCS/ISHL OR EXEMPTED FROM INVENTORY LISTING.
IECSC: ALL INGREDIENTS LISTED OR EXEMPT.
AICS: ALL INGREDIENTS LISTED OR EXEMPT.
DSL:
ALL CHEMICAL SUBSTANCES IN THIS PRODUCT COMPLY WITH THE CEPA 1999 AND NSNR
AND ARE ON OR EXEMPT FROM LISTING ON THE CANADIAN DOMESTIC SUBSTANCES LIST
(DSL).
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
NFPA:
HEALTH 2
FLAMMABILITY 3
INSTABILITY 0
SPECIAL HAZARD.
HMIS III:
HEALTH 3
FLAMMABILITY 3
PHYSICAL HAZARD 0
0 = NOT SIGNIFICANT
1 = SLIGHT
2 = MODERATE
3 = HIGH
4 = EXTREME
* = CHRONIC
FULL TEXT OF OTHER ABBREVIATIONS:
ACGIH: USA. ACGIH THRESHOLD LIMIT VALUES (TLV)
NIOSH REL: USA. NIOSH RECOMMENDED EXPOSURE LIMITS
OSHA Z-1:
USA. OCCUPATIONAL EXPOSURE LIMITS (OSHA) - TABLE Z-1 LIMITS FOR AIR
CONTAMINANTS
ACGIH / TWA: 8-HOUR, TIME-WEIGHTED AVERAGE
ACGIH / STEL: SHORT-TERM EXPOSURE LIMIT
NIOSH REL / TWA:
TIME-WEIGHTED AVERAGE CONCENTRATION FOR UP TO A 10-HOUR WORKDAY DURING A
40-HOUR WORKWEEK
NIOSH REL / ST:
STEL -15-MINUTE TWA EXPOSURE THAT SHOULD NOT BE EXCEEDED AT ANY TIME DURING
A WORKDAY
NIOSH REL / C: CEILING VALUE NOT BE EXCEEDED AT ANY TIME.
OSHA Z-1 / TWA: 8-HOUR TIME WEIGHTED AVERAGE
AICS: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES
ASTM: AMERICAN SOCIETY FOR THE TESTING OF MATERIALS
BW: BODY WEIGHT
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
CMR: CARCINOGEN, MUTAGEN OR REPRODUCTIVE TOXICANT
DIN: STANDARD OF THE GERMAN INSTITUTE FOR STANDARDIZATION
DOT: DEPARTMENT OF TRANSPORTATION
DSL: DOMESTIC SUBSTANCES LIST (CANADA)
ECX: CONCENTRATION ASSOCIATED WITH X% RESPONSE
EHS: EXTREMELY HAZARDOUS SUBSTANCE
ELX: LOADING RATE ASSOCIATED WITH X% RESPONSE
EMS: EMERGENCY SCHEDULE
ENCS: EXISTING AND NEW CHEMICAL SUBSTANCES (JAPAN)
ERCX: CONCENTRATION ASSOCIATED WITH X% GROWTH RATE RESPONSE
ERG: EMERGENCY RESPONSE GUIDE
GHS: GLOBALLY HARMONIZED SYSTEM
GLP: GOOD LABORATORY PRACTICE
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC:
INTERNATIONAL CODE FOR THE CONSTRUCTION AND EQUIPMENT OF SHIPS CARRYING
DANGEROUS CHEMICALS IN BULK
IC50: HALF MAXIMAL INHIBITORY CONCENTRATION
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
IECSC: INVENTORY OF EXISTING CHEMICAL SUBSTANCES IN CHINA
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
IMO: INTERNATIONAL MARITIME ORGANIZATION
ISHL: INDUSTRIAL SAFETY AND HEALTH LAW (JAPAN)
ISO: INTERNATIONAL ORGANIZATION FOR STANDARDIZATION
KECI: KOREA EXISTING CHEMICALS INVENTORY
LC50: LETHAL CONCENTRATION TO 50% OF A TEST POPULATION
LD50: LETHAL DOSE TO 50% OF A TEST POPULATION (MEDIAN LETHAL DOSE)
MARPOL: INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS
MSHA: MINE SAFETY AND HEALTH ADMINISTRATION
N.O.S.: NOT OTHERWISE SPECIFIED
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NO(A)EC: NO OBSERVED (ADVERSE) EFFECT CONCENTRATION
NO(A)EL: NO OBSERVED (ADVERSE) EFFECT LEVEL
NOELR: NO OBSERVABLE EFFECT LOADING RATE
NTP: NATIONAL TOXICOLOGY PROGRAM
NZIOC: NEW ZEALAND INVENTORY OF CHEMICALS
OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
OPPTS: OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC SUBSTANCE
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
(Q)SAR: (QUANTITATIVE) STRUCTURE ACTIVITY RELATIONSHIP
RCRA: RESOURCE CONSERVATION AND RECOVERY ACT
REACH:
REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL
CONCERNING THE REGISTRATION, EVALUATION, AUTHORIZATION AND RESTRICTION OF
CHEMICALS
RQ: REPORTABLE QUANTITY
SADT: SELF-ACCELERATING DECOMPOSITION TEMPERATURE
SARA: SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
SDS: SAFETY DATA SHEET
TCSI: TAIWAN CHEMICAL SUBSTANCE INVENTORY
TSCA: TOXIC SUBSTANCES CONTROL ACT (UNITED STATES)
UN: UNITED NATIONS
UNRTDG: UNITED NATIONS RECOMMENDATIONS ON THE TRANSPORT OF DANGEROUS GOODS
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
SOURCES OF KEY DATA USED TO COMPILE THE MATERIAL SAFETY DATA SHEET:
INTERNAL TECHNICAL DATA, DATA FROM RAW MATERIAL SDSS, OECD ECHEM PORTAL
SEARCH RESULTS AND EUROPEAN CHEMICALS AGENCY, HTTP://ECHA.EUROPA.EU/
REVISION DATE: 10/29/2015
ITEMS WHERE CHANGES HAVE BEEN MADE TO THE PREVIOUS VERSION ARE HIGHLIGHTED
IN THE BODY OF THIS DOCUMENT BY TWO VERTICAL LINES.
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING, USE,
PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND SHALL NOT BE
CONSIDERED A WARRANTY OR QUALITY SPECIFICATION OF ANY TYPE. THE INFORMATION
PROVIDED RELATES ONLY TO THE SPECIFIC MATERIAL IDENTIFIED AT THE TOP OF
THIS SDS AND MAY NOT BE VALID WHEN THE SDS MATERIAL IS USED IN COMBINATION
WITH ANY OTHER MATERIALS OR IN ANY PROCESS, UNLESS SPECIFIED IN THE TEXT.
MATERIAL USERS SHOULD REVIEW THE INFORMATION AND RECOMMENDATIONS IN THE
SPECIFIC CONTEXT OF THEIR INTENDED MANNER OF HANDLING, USE, PROCESSING AND
STORAGE, INCLUDING AN ASSESSMENT OF THE APPROPRIATENESS OF THE SDS MATERIAL
IN THE USER'S END PRODUCT, IF APPLICABLE.
US / Z8