| Common Name: | NI-CD BATTERY, 53RH94(EXIT SIGN), 53RH95(EXIT SIGN), 53RH96(EXIT SIGN), 53RH947( |
| Manufacturer: | GRAINGER GLOBAL SOURCING |
| SDS Revision Date: | (No Date) |
| SDS Format: | GHS-US |
| Item Number(s): | 53RH94, 53RH95, 53RH96, 53RH97 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
ATTACHMENT 1
GHS REQUIRES THAT THE NEW SAFETY DATA SHEETS CONFORM TO A NEW 16 PART
FORMAT AND CONTAIN CERTAIN INFORMATION. THE INFORMATION BELOW WAS TAKEN
FROM THE APPENDIX D OF THE OSHA REGULATION.
SUPPLIERS SHOULD CONSULT THE FULL FINAL REGULATION TO DETERMINE THE
REQUIREMENTS FOR SAFETY DATA SHEETS.
SAFETY DATE SHEET
A SAFETY DATA SHEET (SDS) SHALL INCLUDE THE INFORMATION SPECIFIED BELOW
UNDER THE SECTION NUMBER AND HEADING INDICATED FOR SECTIONS 1-11 AND 16. IF
NO RELEVANT INFORMATION IS FOUND FOR ANY GIVEN SUBHEADING, THE SDS SHALL
CLEARLY INDICATE THAT NO APPLICABLE INFORMATION IS AVAILABLE. SECTIONS
12-15 MAY BE INCLUDED IN THE SDS, BUT ARE NOT MANDATORY.
| SECTION 1: PRODUCTS AND COMPANY IDENTIFICATION |  |
PRODUCTS NAME: NI-CD BATTERY
53RH94(EXIT SIGN), 53RH95(EXIT SIGN), 53RH96(EXIT SIGN), 53RH947(EXIT SIG)
BATTERY SIZE: AA, AAA, AAAA, AAAAA,
COMPANY: GRAINGER GLOBAL SOURCING
ADDRESS:
100 GRAINGER PARKWAY
LAKE FOREST, IL 60045
USA
TELEPHONE: +847-535-1000
EMERGENCY PHONE NUMBER:
IN CASE OF EMERGENCY, CONTACT:
GRAINGER TECHNICAL SUPPORT AT: 1-800-356-2501
IN THE CASE OF POISONING, CONTACT CHEMTREC:
1-800-424-9300 (TOLL-FREE)
00 + 1-703-527-3887 (NON-US)
| SECTION 2: HAZARD(S) IDENTIFICATION | |
FOR NI-CD BATTERY, PLEASE REFER TO BELOW INFORMATION
HAZARD PICTOGRAPH: EXCLAMATION MARK
SIGNAL WORD: CAUTION
HAZARD STATEMENT:
IRRITATING EYES, NOSE, THROAT AND SKIN
IRRITATING AND POSSIBLY CAUSING INFLAMMATION
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS INGREDIENTS CONCENTRATION OR CAS NUMBER
(CHEMICAL NAME) CONCENTRATION RANGES (%)
NICKELOUS HYDROXIDE NI(OH)2 18 N/A
COBALT OXIDE (CoO) 2 N/A
CADMIUM HYDROXIDE Cd(OH)2 30 N/A
HIGH-CARBON STEEL (Fe) 23 N/A
NICKEL 8 7440-02-0
ZINC (Zn) 2 N/A
OTHERS 17 N/A
| SECTION 4: FIRST-AID MEASURES | |
THERE IS NO PROBLEM IN THE NORMAL STATE. BUT TAKE THE FOLLOWING MEASURES
WHEN THE CONTENTS HAVE BEGUN TO LEAK BY THE DESTRUCTION OF THE BATTERY.
INHALATION:
IF A PERSON INHALED STEAM, MOVE TO THE PLACE WHERE AIR IS FRESH
IMMEDIATELY. IF HE/HER FEELS ILL, IMMEDIATELY CALL A DOCTOR FOR
THERAPY AND TREATMENT.
SKIN:
IF THE CONTENT ADHERES TO SKIN, IMMEDIATELY WASH IT WITH A LARGE AMOUNT OF
CLEAN WATER AND SOAP PROMPTLY. IF IRRITATING, CONSULT A DOCTOR.
EYES:
IF THE CONTENT ENTERS EYES, RINSE EYES WITH A LARGE AMOUNT OF CLEAN WATER
FOR MORE THAN 15 MINUTES, AND CONSULT A DOCTOR.
INGESTION:
IF A CELL IS SWALLOWED, IMMEDIATELY CALL A DOCTOR FOR THERAPY AND
TREATMENT.
| SECTION 5: FIRE-FIGHTING MEASURES | |
FIRE EXTINGUISHERS: CO2, DRY CHEMICAL
SPECIFIC FIRE FIGHTING METHOD:
IN THE INITIAL STATE OF A FIRE, MOVE CELLS/BATTERIES FROM NEAR THE FIRE
SOURCE, TO A SAFE LOCATION. AT THAT TIME, WORK AT A WINDWARD LOCATION, AS
FAR AS POSSIBLE, AND BE SURE TO PUT ON A PROTECTIVE BREATHING MASK.
PROTECTION OF FIRE FIGHTING PERSONNEL:
BE WEAR PROTECTIVE BREATHING MASKS, GLOVES, GLASSES AND HELMET FOR THE
KEEPING SAFE. (PREFERABLY, USE A SELF-FEEDING TYPE MASK.)
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES:
RESTRICT ACCESS TO AREA UNTIL COMPLETION OF CLEAN-UP. DO NOT TOUCH THE
SPILLED MATERIAL. WEAR ADEQUATE PERSONAL PROTECTIVE EQUIPMENT AS INDICATED
IN SECTION 8.
ENVIRONMENTAL PRECAUTIONS:
PREVENT MATERIAL FROM CONTAMINATING SOIL AND FROM ENTERING SEWERS OR
WATERWAYS.
METHODS AND MATERIALS FOR CONTAINMENT:
STOP THE LEAK IF SAFE TO DO SO. CONTAIN THE SPILLED LIQUID WITH DRY SAND OR
EARTH. CLEAN UP SPILLS IMMEDIATELY.
METHODS AND MATERIALS FOR CLEANING UP:
ABSORB SPILLED MATERIAL WITH AN INERT ABSORBENT (DRY SAND OR EARTH). SCOOP
CONTAMINATED ABSORBENT INTO AN ACCEPTABLE WASTE CONTAINER-COLLECT ALL
CONTAMINATED ABSORBENT AND DISPOSE OF ACCORDING TO DIRECTIONS IN SECTION
13. SCRUB THE AREA WITH DETERGENT AND WATER; COLLECT ALL CONTAMINATED WASH
WATER FOR PROPER DISPOSAL.
| SECTION 7: HANDLING AND STORAGE | |
HANDLING:
ANY LEAKAGE OR OBNOXIOUS ODOR OF A CELL, IT SHOULD BE DISPOSED. NEVER
SOLDER A CELL BODY.
DO NOT CONTACT CELL TERMINALS BETWEEN EACH OTHER, OR WITH ANOTHER
CONDUCTOR. NEITHER THROWS INTO FIRE, DECOMPOSE, HEAT, DENT, DEFORM,
CHARGE NOR DROP A BATTERY. DO NOT DIP A CELL IN WATER OR SEAWATER.
STORAGE:
STORE CELLS WITHOUT DIRECT SUNLIGHT, HIGH TEMPERATURE, HIGH HUMIDITY, RAIN,
DEW, ETC., AND SELECT A STORAGE LOCATION WITH A TEMPERATURE AS LOW AS
POSSIBLE (PREFERABLE TEMPERATURE 20+/-15 DEG. C AND RELATIVE HUMIDITY 70%
OR LESS). IN ADDITION, KEEP CELLS AWAY FROM DANGEROUS MATTER SUCH AS
COMBUSTIBLE OR IGNITABLE MATERIALS. ABSOLUTELY NEVER PLACE A CELL IN
CONTACT WITH A COMBUSTIBLE OR CONDUCTIVE SUBSTANCE. PREPARE APPROPRIATE
FIREFIGHTING EQUIPMENT.
NOTE:
SEE HANDLING AND STORING PRECAUTIONS DESCRIBED IN THE PRODUCT CATALOG,
SPECIFICATION, ETC.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PROTECTION OF RESPIRATORY ORGANS: NOT REQUIRED IN A NORMAL OPERATING STATE
PROTECTION OF EYES: NOT REQUIRED IN A NORMAL OPERATING STATE
OTHER PROTECTIVE TOOLS ETC.: NOT REQUIRED IN A NORMAL OPERATING STATE
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
SHAPE: COIN-SHAPE. CONTENTS ARE SEALED IN A STIFF STAINLESS STEEL VESSEL.
PH: NOT APPLICABLE BECAUSE A CELL IS NOT SOLUBLE WITH WATER.
BOILING POINT/BOILING RANGE: NO INFORMATION
MELTING POINT: NO INFORMATION
DECOMPOSITION TEMPERATURE: NO INFORMATION
FLASH POINT: NO INFORMATION
| SECTION 10: STABILITY AND REACTIVITY | |
CONDITIONS TO BE AVOIDED: IF A NUMBER OF CELLS ARE MIXED UP WITHOUT
INSULATING TERMINALS, THEY MAY SHORT AND POSSIBLY HEAT, BREAK AND IGNITE.
WHEN A CELL IS CHARGED, POSSIBLY IN BURSTING THE ELECTROLYTE ETC. OR, IT
MAY POSSIBLY BURST OR FIRE. IF A CELL IS HEATED OR THROWN INTO FIRE, IT MAY
EXPLODE OR FIRE WITH THE ELECTROLYTE ETC. BURSTING FROM INSIDE OF THE CELL.
IF DECOMPOSED, THERE IS A POSSIBILITY OF OVERHEATING OR FIRE DUE TO SHORT
CIRCUIT, AND IGNITION OF SOME MATERIAL AROUND ETC.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THERE IS NO TOXICITY BECAUSE CHEMICAL SUBSTANCES ARE HERMETICALLY SEALED IN
A METAL VESSEL.
AS A REFERENCE, CHEMICAL SUBSTANCES COMPOSING A CELL ARE DESCRIBED BELOW.
MANGANESE DIOXIDE:
IRRITATION: IRRITATING EYES, NOSE, THROAT AND SKIN.
CHRONIC TOXICITY:
IF A PERSON IS EXPOSED TO POWDER FOR A LONG TIME OR REPEATEDLY, THE LUNG
AND THE NERVOUS SYSTEM MAY BE AFFECTED, POSSIBLY CAUSING BRONCHITIS,
PNEUMONIA, NERVOUS DISEASE OR MENTAL DISEASE.
GRAPHITE:
CHRONIC TOXICITY:
IF INHALED FOR A LONG TIME WITHOUT PROTECTIVE TOOLS, LOCAL VENTILATION,
ETC., GRAPHITE LUNG MAY RESULT.
BREATHING TOXICITY:
IF INHALED FOR A LONG TIME WITHOUT PROTECTIVE TOOLS, LOCAL VENTILATION,
ETC., GRAPHITE LUNG MAY RESULT.
DIMETHOXYETHANE:
IRRITATION: IRRITATING AND POSSIBLY CAUSING INFLAMMATION
CHRONIC TOXICITY:
LONG-TERM EXPOSURE MAY CAUSE INFLAMMATION. IF EXPOSED FURTHER, LIVER OR
KIDNEY MAY BE TROUBLED.
| SECTION 12: ECOLOGICAL INFORMATION | |
NO INFORMATION AS BATTERIES.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
DISPOSAL OF THE SUBSTANCE SHOULD BE DONE ACCORDING TO THE LAWS AND
REGULATIONS.
ALTHOUGH USED CELLS CAN BE DISCARDED BASICALLY AS "NONFLAMMABLE REFUSE,"
SOME LOCAL GOVERNMENTS SORT AND COLLECT THEM AT THEIR OWN DISCRETION.
THEREFORE, OBSERVE INSTRUCTIONS OF THE GOVERNMENT YOU BELONG TO, TO DISPOSE
OF THE SUBSTANCE.
KEEP THE FOLLOWING DISCARDING PRECAUTIONS:
EVEN A USED CELL SOMETIMES STORES ELECTRIC ENERGY. THEREFORE, TO PREVENT
THE BATTERY FROM SHORT-CIRCUIT, ISOLATE CELLS FROM EACH OTHER BY A METHOD
SUCH AS TAPING +, - TERMINALS OF CELLS, OR USING THE INDIVIDUAL HOUSING
CASE OF A CELL, USED WHEN YOU BOUGHT THE BATTERY, AND ORDERLY ENCASING
BATTERIES IN A BOX, THEN SUBMIT AN APPLICATION OF DISPOSAL TO THE LOCAL
GOVERNMENT OF YOUR RESIDENCE, USING THE DESIGNATED FORM.
PACKING CELLS SO THAT THEY ARE NOT SHORTED, AND PREVENT THE PACKAGE FROM
BEING WETTED.
IF CELLS MUST BE DISCARDED IN A COUNTRY OTHER THAN JAPAN, OBSERVE THE
INSTRUCTIONS OF THE COUNTRY AND LOCAL GOVERNMENT.
| SECTION 14: TRANSPORT INFORMATION | |
IT IS REQUIRED TO PERFORM THE CONFIRMATION SUCH AS LAWS AND ORDINANCES /
THE REGULATION ABOUT THE TRANSPORTATION BY SHIPPER RESPONSIBILITY. AFTER
OUR PRODUCT WAS DELIVERED TO A CUSTOMER, IF A CUSTOMER TRANSPORTS A PRODUCT
AS A SHIPPER, IT IS NECESSARY TO CONFIRM LAWS AND ORDINANCES / REGULATION
WITH THE CUSTOMER. THE FOLLOWING INFORMATION IS NOT THINGS TO GUARANTEE
WITH A THING TO OFFER AS REFERENCE INFORMATION ABOUT THE TRANSPORTATION.
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AREA METHOD REGULATIONS
INTERNATIONAL AIR ICAO-TI / IATA DGR
INTERNATIONAL WATER IMO-IMDG CODE
U.S.A. AIR, RAIL, HIGHWAY, WATER US DOT-49 CFR
EUROPE RAIL, HIGHWAY RID, ADR
THESE REGULATIONS ARE BASED ON THE UN RECOMMENDATIONS. EACH SPECIAL
PROVISION PROVIDES SPECIFICATIONS ON EXCEPTIONS AND PACKAGING FOR NI-CD
BATTERIES SHIPPING.
| SECTION 15: REGULATORY INFORMATION | |
THE LAWS AND ORDINANCES ABOUT THE BATTERY OBEY LAWS AND ORDINANCES SET IN
EACH COUNTRY.
MAJOR APPLICABLE REGULATIONS FOR THE TRANSPORTATION OF LITHIUM METAL CELLS
AND BATTERIES ARE AS FOLLOWS:
RECOMMENDATIONS ON THE TRANSPORT OF DANGEROUS GOODS, 18TH REVISED EDITION
(UN)
DANGEROUS GOODS REGULATIONS, 56TH EDITION (IATA)
TECHNICAL INSTRUCTIONS FOR THE SAFETY TRANSPORT OF DANGEROUS GOODS BY AIR,
2015-2016 EDITION (ICAO)
INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG) CODE, 2014 EDITION (IMO)
| SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
THE BATTERY IS CONSIDERED TO BE AN ARTICLE FOR PURPOSES OF THE TSCA AND NOT
A CHEMICAL. THEREFORE, THE BATTERY IS EXEMPT FORM THE TSCA REQUIREMENTS.
CONTENTS OF THIS MANUAL HAVE BEEN EDITED BASED ON DATA, INFORMATION, ETC.
THAT TOSHIBA COULD ACQUIRE WHEN EDITING THE MANUAL, SO THE MANUAL MAY BE
REVISED BY NEW INFORMATION, IF ANY. CONTENTS OF THE MANUAL ASSUME NORMAL
HANDLING OF BATTERIES, AND ARE PROVIDED AS REFERENTIAL INFORMATION.
THEREFORE, THE MANUAL PROVIDES NO WARRANTIES. THE CUSTOMER IS REQUESTED TO
USE BATTERIES ON THE BASIS OF APPROPRIATE MEASURES ESTABLISHED DEPENDING ON
INDIVIDUAL CONDITIONS, APPLICATION AND OPERATION. ANY NUMERALS SUCH AS
CONTENTS AND CONCENTRATION RANGES, AND OTHERS ARE NOT GUARANTEED.
"ALL INFORMATION IS BEING PROVIDED BY GRAINGER GLOBAL SOURCING, ("GGS"),
FOR INFORMATION PURPOSES ONLY. THE SUPPLIER IS ULTIMATELY RESPONSIBLE FOR
ENSURING COMPLIANCE WITH ALL LAWS AND REGULATIONS AND SHOULD NOT RELY ON
THIS INFORMATION SOLELY."