| Common Name: | KLEENSCRIBE LAYOUT DYE AEROSOL |
| Manufacturer: | L.S. STARRETT |
| SDS Revision Date: | 4/20/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 53VF12 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
STARRETT(R*)
SAFETY DATA SHEET
ACC. TO OSHA HCS (29 CFR 1910.1200) AND WHMIS 2015 REGULATIONS
PRINTING DATE: 04/20/2016
REVISION: 04/20/2016
| 1 IDENTIFICATION |  |
PRODUCT IDENTIFIER:
TRADE NAME: STARRETT KLEENSCRIBE LAYOUT DYE AEROSOL
PRODUCT CODE: #1611
RECOMMENDED USE AND RESTRICTION ON USE:
RECOMMENDED USE: PRINTING INKS
RESTRICTIONS ON USE: CONTACT MANUFACTURER
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
THE L.S. STARRETT COMPANY
121 CRESCENT ST.
ATHOL, MA 01331
(978) 249-3551
INFORMATION DEPARTMENT: PRODUCT SAFETY DEPARTMENT
EMERGENCY TELEPHONE NUMBER:
CHEMTEL INC.:
+1 (800)255-3924
+1 (813)248-0585
| 2 HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAM. AEROSOL 1:
H222: EXTREMELY FLAMMABLE AEROSOL.
PRESS. GAS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
ACUTE TOX. 4:
H302: HARMFUL IF SWALLOWED.
ACUTE TOX. 4:
H312: HARMFUL IN CONTACT WITH SKIN.
ACUTE TOX. 4:
H332: HARMFUL IF INHALED.
EYE IRRIT. 2A:
H319: CAUSES SERIOUS EYE IRRITATION.
MUTA. 1B:
H340: MAY CAUSE GENETIC DEFECTS.
CARC. 1B:
H350: MAY CAUSE CANCER.
REPR. 2:
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
STOT SE 2:
H371: MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM AND OPTIC NERVE.
STOT RE 2:
H373:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ROUTE OF EXPOSURE: INHALATION.
ADDITIONAL INFORMATION:
THERE ARE NO OTHER HAZARDS NOT OTHERWISE CLASSIFIED THAT HAVE BEEN
IDENTIFIED.
0% OF THE MIXTURE CONSISTS OF COMPONENT(S) OF UNKNOWN TOXICITY.
LABEL ELEMENTS:
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE GLOBALLY HARMONIZED
SYSTEM (GHS).
HAZARD PICTOGRAMS:
GHS02: FLAME
GHS04: GAS CYLINDER
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H222: EXTREMELY FLAMMABLE AEROSOL.
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H302+H312+H332: HARMFUL IF SWALLOWED, IN CONTACT WITH SKIN OR IF INHALED.
H319: CAUSES SERIOUS EYE IRRITATION.
H340: MAY CAUSE GENETIC DEFECTS.
H350: MAY CAUSE CANCER.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
H371: MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM AND OPTIC NERVE.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ROUTE OF EXPOSURE: INHALATION.
PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
P251:
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P260: DO NOT BREATHE MIST/VAPORS/SPRAY.
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P264: WASH THOROUGHLY AFTER HANDLING.
P280: WEAR PROTECTIVE GLOVES AND EYE PROTECTION.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF WATER.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P330: RINSE MOUTH.
P308+P311:
IF EXPOSED OR CONCERNED: CALL A POISON CENTER/DOCTOR.
P362+P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
P405: STORE LOCKED UP.
P410+P403: PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
P410+P412:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
CLASSIFICATION SYSTEM:
NFPA RATINGS (SCALE 0 - 4):
HEALTH 1
FIRE 4
REACTIVITY 1
HMIS-RATINGS (SCALE 0 - 4):
* - INDICATES A LONG TERM HEALTH HAZARD FROM REPEATED OR PROLONGED
EXPOSURES.
HEALTH 1*
FIRE 4
REACTIVITY 1
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENTS:
68476-86-8 PETROLEUM GASES, LIQUEFIED, SWEETENED 25-40%
FLAM. GAS 1, H220
PRESS. GAS, H280
MUTA. 1B, H340; CARC. 1A, H350
123-86-4 N-BUTYL ACETATE 10-20%
FLAM. LIQ. 3, H226
STOT SE 3, H336
67-56-1 METHANOL 5-<10%
FLAM. LIQ. 2, H225
ACUTE TOX. 3, H301; ACUTE TOX. 3, H311;
ACUTE TOX. 3, H331
STOT SE 1, H370
EYE IRRIT. 2B, H320
141-78-6 ETHYL ACETATE 5-<10%
FLAM. LIQ. 2, H225
EYE IRRIT. 2, H319; STOT SE 3, H336
9004-70-0 NITROCELLULOSE, COLLOIDED, GRANULAR 5-<10%
EXPL. 1.1, H201
67-63-0 PROPAN-2-OL 2.5-5%
FLAM. LIQ. 2, H225
EYE IRRIT. 2, H319; STOT SE 3, H336
108-88-3 TOLUENE 3-5%
FLAM. LIQ. 2, H225
REPR. 2, H361; STOT RE 2, H373;
ASP. TOX. 1, H304
SKIN IRRIT. 2, H315; STOT SE 3, H336
EYE IRRIT. 2B, H320
64742-89-8 SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. 2.5-5%
MUTA. 1B, H340; CARE. 1B, H350;
ASP. TOX. 1, H304
67-64-1 ACETONE 2.5-5%
FLAM. LIQ. 2, H225
EYE IRRIT. 2A, H319; STOT SE 3, H336
ADDITIONAL INFORMATION:
FOR THE WORDING OF THE LISTED HAZARD STATEMENTS REFER TO SECTION 16.
FOR THE LISTED INGREDIENT(S), THE IDENTITY AND/OR EXACT PERCENTAGE(S)
ARE BEING WITHHELD AS A TRADE SECRET.
| 4 FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
SYMPTOMS OF POISONING MAY EVEN OCCUR AFTER SEVERAL HOURS; THEREFORE
MEDICAL OBSERVATION FOR AT LEAST 48 HOURS AFTER THE ACCIDENT.
TAKE AFFECTED PERSONS OUT INTO THE FRESH AIR.
MEDICAL SUPERVISION FOR AT LEAST 48 HOURS.
AFTER INHALATION:
SUPPLY FRESH AIR.
SEEK IMMEDIATE MEDICAL ADVICE.
PROVIDE OXYGEN TREATMENT IF AFFECTED PERSON HAS DIFFICULTY BREATHING.
IN CASE OF IRREGULAR BREATHING OR RESPIRATORY ARREST PROVIDE ARTIFICIAL
RESPIRATION.
IN CASE OF UNCONSCIOUSNESS PLACE PATIENT STABLY IN SIDE POSITION FOR
TRANSPORTATION.
AFTER SKIN CONTACT:
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
IF SKIN IRRITATION CONTINUES, CONSULT A DOCTOR.
AFTER EYE CONTACT:
REMOVE CONTACT LENSES IF WORN.
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. IF SYMPTOMS
PERSIST, CONSULT A DOCTOR.
AFTER SWALLOWING:
UNLIKELY ROUTE OF EXPOSURE.
RINSE OUT MOUTH AND THEN DRINK PLENTY OF WATER.
A PERSON VOMITING WHILE LYING ON THEIR BACK SHOULD BE TURNED ONTO THEIR
SIDE.
DO NOT INDUCE VOMITING; IMMEDIATELY CALL FOR MEDICAL HELP.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
HEADACHE
BREATHING DIFFICULTY
COUGHING
DIZZINESS
ACIDOSIS
DISORIENTATION
UNCONSCIOUSNESS
DANGER:
CAUSES SERIOUS EYE IRRITATION.
HARMFUL IF SWALLOWED, IN CONTACT WITH SKIN OR IF INHALED.
MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM AND OPTIC NERVE.
VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NO RELEVANT INFORMATION AVAILABLE.
| 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
CO2, EXTINGUISHING POWDER OR WATER SPRAY. FIGHT LARGER FIRES WITH WATER
SPRAY OR ALCOHOL RESISTANT FOAM.
FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: NONE.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOR PRESSURE IF HEATED.
EXTREMELY FLAMMABLE AEROSOL.
FORMATION OF TOXIC GASES IS POSSIBLE DURING HEATING OR IN CASE OF FIRE.
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION:
COOL ENDANGERED RECEPTACLES WITH WATER SPRAY.
USE LARGE QUANTITIES OF FOAM AS IT IS PARTIALLY DESTROYED BY THE PRODUCT.
| 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION.
KEEP AWAY FROM IGNITION SOURCES.
ENVIRONMENTAL PRECAUTIONS:
INFORM RESPECTIVE AUTHORITIES IN CASE OF SEEPAGE INTO WATER COURSE OR
SEWAGE SYSTEM.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ALLOW TO EVAPORATE.
ABSORB LIQUID COMPONENTS WITH LIQUID-BINDING MATERIAL.
CLEAN THE AFFECTED AREA CAREFULLY; SUITABLE CLEANERS ARE:
WARM WATER AND CLEANSING AGENT
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
KEEP AWAY FROM HEAT AND DIRECT SUNLIGHT.
AVOID SPLASHES OR SPRAY IN ENCLOSED AREAS.
INFORMATION ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES:
EXTREMELY FLAMMABLE AEROSOL.
KEEP IGNITION SOURCES AWAY - DO NOT SMOKE.
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING
120 DEG. F / 49 DEG. C, I.E. ELECTRIC LIGHTS. DO NOT PIERCE OR BURN,
EVEN AFTER USE.
DO NOT SPRAY ON A NAKED FLAME OR ANY INCANDESCENT MATERIAL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
STORE IN A COOL LOCATION.
OBSERVE OFFICIAL REGULATIONS ON STORING PACKAGINGS WITH PRESSURIZED
CONTAINERS.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM FOODSTUFFS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
STORE IN A COOL PLACE. HEAT WILL INCREASE PRESSURE AND MAY LEAD TO THE
RECEPTACLE BURSTING.
SPECIFIC END USE(S): NO RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
123-86-4 N-BUTYL ACETATE:
PEL (USA):
LONG-TERM VALUE: 710 MG/M3, 150 PPM
REL (USA):
SHORT-TERM VALUE: 950 MG/M3, 200 PPM
LONG-TERM VALUE: 710 MG/M3, 150 PPM
TLV (USA):
SHORT-TERM VALUE: (950) NIC-712 MG/M3, (200) NIC-150 PPM
LONG-TERM VALUE: (713) NIC-238 MG/M3, (150) NIC-50 PPM
EL (CANADA):
LONG-TERM VALUE: 20 PPM
EV (CANADA):
SHORT-TERM VALUE: 950 MG/M3, 200 PPM
LONG-TERM VALUE: 710 MG/M3, 150 PPM
LMPE (MEXICO):
SHORT-TERM VALUE: 200 PPM
LONG-TERM VALUE: 150 PPM
67-56-1 METHANOL:
PEL (USA):
LONG-TERM VALUE: 260 MG/M3, 200 PPM
REL (USA):
SHORT-TERM VALUE: 325 MG/M3, 250 PPM
LONG-TERM VALUE: 260 MG/M3, 200 PPM
SKIN
TLV (USA):
SHORT-TERM VALUE: 328 MG/M3, 250 PPM
LONG-TERM VALUE: 262 MG/M3, 200 PPM
SKIN; BEI
EL (CANADA):
SHORT-TERM VALUE: 250 PPM
LONG-TERM VALUE: 200 PPM
SKIN
EV (CANADA):
SHORT-TERM VALUE: 325 MG/M3, 250 PPM
LONG-TERM VALUE: 260 MG/M3, 200 PPM
SKIN
LMPE (MEXICO):
SHORT-TERM VALUE: 250 PPM
LONG-TERM VALUE: 200 PPM
PIEL, IBE
141-78-6 ETHYL ACETATE:
PEL (USA):
LONG-TERM VALUE: 1400 MG/M3, 400 PPM
REL (USA):
LONG-TERM VALUE: 1400 MG/M3, 400 PPM
TLV (USA):
LONG-TERM VALUE: 1440 MG/M3, 400 PPM
EL:
(CANADA) LONG-TERM VALUE: 150 PPM
EV (CANADA):
LONG-TERM VALUE: 1.440 MG/M3, 400 PPM
LMPE (MEXICO):
LONG-TERM VALUE: 400 PPM
67-63-0 PROPAN-2-OL:
PEL (USA):
LONG-TERM VALUE: 980 MG/M3, 400 PPM
REL (USA):
SHORT-TERM VALUE: 1225 MG/M3, 500 PPM
LONG-TERM VALUE: 980 MG/M3, 400 PPM
TLV (USA):
SHORT-TERM VALUE: 984 MG/M3, 400 PPM
LONG-TERM VALUE: 492 MG/M3, 200 PPM
BEI
EL (CANADA):
SHORT-TERM VALUE: 400 PPM
LONG-TERM VALUE: 200 PPM
EV (CANADA):
SHORT-TERM VALUE: 400 PPM
LONG-TERM VALUE: 200 PPM
LMPE (MEXICO):
SHORT-TERM VALUE: 400 PPM
LONG-TERM VALUE: 200 PPM
A4, IBE
108-88-3 TOLUENE:
PEL (USA):
LONG-TERM VALUE: 200 PPM
CEILING LIMIT VALUE: 300; 500* PPM
*10-MIN PEAK PER 8-HR SHIFT
REL (USA):
SHORT-TERM VALUE: 560 MG/M3, 150 PPM
LONG-TERM VALUE: 375 MG/M3, 100 PPM
TLV (USA):
LONG-TERM VALUE: 75 MG/M3, 20 PPM
BEI
EL (CANADA):
LONG-TERM VALUE: 20 PPM
R
EV (CANADA):
LONG-TERM VALUE: 20 PPM
LMPE (MEXICO):
LONG-TERM VALUE: 20 PPM
A4, IBE
67-64-1 ACETONE:
PEL (USA):
LONG-TERM VALUE: 2400 MG/M3, 1000 PPM
REL (USA):
LONG-TERM VALUE: 590 MG/M3, 250 PPM
TLV (USA):
SHORT-TERM VALUE: 1187 MG/M3, 500 PPM
LONG-TERM VALUE: 594 MG/M3, 250 PPM
BEI
EL (CANADA):
SHORT-TERM VALUE: 500 PPM
LONG-TERM VALUE: 250 PPM
EV (CANADA):
SHORT-TERM VALUE: 750 PPM
LONG-TERM VALUE: 500 PPM
LMPE (MEXICO):
SHORT-TERM VALUE: 750 PPM
LONG-TERM VALUE: 500 PPM
A4, IBE
INGREDIENTS WITH BIOLOGICAL LIMIT VALUES:
67-56-1 METHANOL:
BEI (USA): 115 MG/L
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: METHANOL (BACKGROUND, NONSPECIFIC)
67-63-0 PROPAN-2-OL:
BEI (USA): 140 MG/L
MEDIUM: URINE
TIME: END OF SHIFT AT END OF WORKWEEK
PARAMETER: ACETONE (BACKGROUND, NONSPECIFIC)
108-88-3 TOLUENE:
BEI (USA):
0.02 MG/L
MEDIUM: BLOOD
TIME: PRIOR TO LAST SHIFT OF WORKWEEK
PARAMETER: TOLUENE
0.03 MG/L
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: TOLUENE
0.3 MG/G CREATININE
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: O-CRESOL WITH HYDROLYSIS (BACKGROUND)
67-64-1 ACETONE:
BEI (USA): 50 MG/L
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: ACETONE (NONSPECIFIC)
EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
AVOID CONTACT WITH THE EYES AND SKIN.
DO NOT INHALE GASES / FUMES / AEROSOLS.
ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION.
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
BREATHING EQUIPMENT:
USE SUITABLE RESPIRATORY PROTECTIVE DEVICE IN CASE OF INSUFFICIENT
VENTILATION.
NIOSH OR EN APPROVED ORGANIC VAPOR RESPIRATOR EQUIPPED WITH A DUST/MIST
PREFILTER SHOULD BE USED.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/THE
SUBSTANCE/THE PREPARATION. DUE TO MISSING TESTS NO RECOMMENDATION TO THE
GLOVE MATERIAL CAN BE GIVEN FOR THE PRODUCT/THE PREPARATION/THE CHEMICAL
MIXTURE.
SELECTION OF THE GLOVE MATERIAL ON CONSIDERATION OF THE PENETRATION TIMES,
RATES OF DIFFUSION AND THE DEGRADATION
MATERIAL OF GLOVES:
THE SELECTION OF THE SUITABLE GLOVES DOES NOT ONLY DEPEND ON THE MATERIAL,
BUT ALSO ON FURTHER MARKS OF QUALITY AND VARIES FROM MANUFACTURER TO
MANUFACTURER. AS THE PRODUCT IS A PREPARATION OF SEVERAL SUBSTANCES, THE
RESISTANCE OF THE GLOVE MATERIAL CAN NOT BE CALCULATED IN ADVANCE AND HAS
THEREFORE TO BE CHECKED PRIOR TO THE APPLICATION.
PENETRATION TIME OF GLOVE MATERIAL:
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF
THE PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
EYE PROTECTION: SAFETY GLASSES
BODY PROTECTION: IMPERVIOUS PROTECTIVE CLOTHING
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
FORM: AEROSOL
COLOR: BLUE
ODOR: CHARACTERISTIC
ODOR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
MELTING POINT/MELTING RANGE: NOT DETERMINED.
BOILING POINT/BOILING RANGE: NOT APPLICABLE, AS AEROSOL.
FLASH POINT:
EXTREMELY FLAMMABLE AEROSOL.
NOT APPLICABLE, AS AEROSOL.
FLAMMABILITY (SOLID, GASEOUS): EXTREMELY FLAMMABLE AEROSOL.
AUTO-IGNITION TEMPERATURE: 370 DEG. C (698 DEG. F)
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
DANGER OF EXPLOSION:
PRODUCT IS NOT EXPLOSIVE. HOWEVER, FORMATION OF EXPLOSIVE AIR/VAPOR
MIXTURES ARE POSSIBLE.
EXPLOSION LIMITS:
LOWER: 1.2 VOL %
UPPER: 7.5 VOL %
VAPOR PRESSURE AT 20 DEG. C (68 DEG. F): 133 HPA (100 MMHg)
DENSITY AT 20 DEG. C (68 DEG. F):
0.89 G/CM3 (7.427 LBS/GAL) (LIQUID CONTENTS ONLY)
RELATIVE DENSITY: NOT DETERMINED.
VAPOR DENSITY: NOT DETERMINED.
EVAPORATION RATE: >1 (N-BUTYL ACETATE = 1)
SOLUBILITY IN / MISCIBILITY WITH WATER: FULLY MISCIBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC: NOT DETERMINED.
OTHER INFORMATION: NO RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
REACTIVITY: NO RELEVANT INFORMATION AVAILABLE.
CHEMICAL STABILITY:
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
NO DECOMPOSITION IF USED ACCORDING TO SPECIFICATIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
EXTREMELY FLAMMABLE AEROSOL.
DANGER OF RECEPTACLES BURSTING BECAUSE OF HIGH VAPOR PRESSURE IF HEATED.
CAN REACT VIOLENTLY WITH OXYGEN RICH (OXIDIZING) MATERIAL. DANGER OF
EXPLOSION.
TOXIC FUMES MAY BE RELEASED IF HEATED ABOVE THE DECOMPOSITION POINT.
CONDITIONS TO AVOID: NO RELEVANT INFORMATION AVAILABLE.
INCOMPATIBLE MATERIALS: NO RELEVANT INFORMATION AVAILABLE.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE AND CARBON DIOXIDE
NITROGEN OXIDES
SMALL QUANTITIES OF FORMALDEHYDE MAY BE FORMED.
| 11 TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
67-56-1 METHANOL:
ORAL:
LD50: 5628 MG/KG (RAT)
DERMAL:
LD50: 15800 MG/KG (RABBIT)
108-88-3 TOLUENE:
ORAL:
LD50: 5000 MG/KG (RAT)
DERMAL:
LD50: 12124 MG/KG (RABBIT)
INHALATIVE:
LC50/4 H: 5320 MG/L (MOUSE)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: CAUSES MILD SKIN IRRITATION.
ON THE EYE: IRRITATING EFFECT.
SENSITIZATION: NO SENSITIZING EFFECTS KNOWN.
SUBACUTE TO CHRONIC TOXICITY:
MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM AND OPTIC NERVE.
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
67-63-0 PROPAN-2-OL 3
108-88-3 TOLUENE 3
NTP (NATIONAL TOXICOLOGY PROGRAM): NONE OF THE INGREDIENTS ARE LISTED.
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS ARE LISTED.
PROBABLE ROUTE(S) OF EXPOSURE:
INHALATION.
EYE CONTACT.
SKIN CONTACT.
ACUTE EFFECTS (ACUTE TOXICITY, IRRITATION AND CORROSIVITY):
HARMFUL IF SWALLOWED, IN CONTACT WITH SKIN OR IF INHALED.
MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM AND OPTIC NERVE.
IRRITATING TO EYES.
REPEATED DOSE TOXICITY: DANGER OF VERY SERIOUS IRREVERSIBLE EFFECTS.
CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION):
MUTA. 1B, CARC. 1B, REPR. 2
GERM CELL MUTAGENICITY: MAY CAUSE GENETIC DEFECTS.
CARCINOGENICITY: MAY CAUSE CANCER.
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
STOT-SINGLE EXPOSURE:
MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM AND OPTIC NERVE.
STOT-REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ROUTE OF EXPOSURE: INHALATION.
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
| 12 ECOLOGICAL INFORMATION | |
TOXICITY:
AQUATIC TOXICITY: NO RELEVANT INFORMATION AVAILABLE.
PERSISTENCE AND DEGRADABILITY: NO RELEVANT INFORMATION AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NO RELEVANT INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO RELEVANT INFORMATION AVAILABLE.
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
DO NOT ALLOW PRODUCT TO REACH GROUND WATER, WATER COURSE OR SEWAGE SYSTEM,
EVEN IN SMALL QUANTITIES. DANGER TO DRINKING WATER IF EVEN EXTREMELY SMALL
QUANTITIES LEAK INTO THE GROUND.
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
OTHER ADVERSE EFFECTS: NO RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
RECOMMENDATION:
MUST NOT BE DISPOSED OF TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW
PRODUCT TO REACH SEWAGE SYSTEM. INCINERATE IN ACCORDANCE WITH LOCAL,
STATE AND FEDERAL REGULATIONS.
THE USER OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED
MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL,
STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND
DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES. RESIDUAL MATERIALS SHOULD
BE TREATED AS HAZARDOUS.
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
RECOMMENDED CLEANSING AGENT: WATER, IF NECESSARY WITH CLEANSING AGENTS.
| 14 TRANSPORT INFORMATION | |
UN-NUMBER:
DOT, ADR, IMDG, IATA: UN1950
UN PROPER SHIPPING NAME:
DOT, IATA: AEROSOLS, FLAMMABLE
ADR: 1950 AEROSOLS, FLAMMABLE
IMDG: AEROSOLS, FLAMMABLE
TRANSPORT HAZARD CLASS(ES):
DOT: FLAMMABLE GAS, CLASS/DIVISION 2.1
CLASS: 2.1
LABEL: 2.1
ADR: CLASS 2.1, FLAMMABLE GASES
CLASS: 2 5F GASES
LABEL: 2.1
IMDG, IATA: CLASS 2.1, FLAMMABLE GASES
CLASS: 2.1
LABEL: 2.1
PACKING GROUP:
DOT, ADR, IMDG, IATA: N/A
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER:
WARNING: GASES
DANGER CODE (KEMLER): 23
EMS NUMBER: F-D,S-U
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE:
NOT APPLICABLE.
| 15 REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
UNITED STATES (USA):
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS ARE LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
67-56-1 METHANOL
67-63-0 PROPAN-2-OL
108-88-3 TOLUENE
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED.
PROPOSITION 65 (CALIFORNIA):
CHEMICALS KNOWN TO CAUSE CANCER: NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
108-88-3 TOLUENE
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
67-56-1 METHANOL
108-88-3 TOLUENE
CARCINOGENIC CATEGORIES:
EPA (ENVIRONMENTAL PROTECTION AGENCY):
108-88-3 TOLUENE II
67-64-1 ACETONE I
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
67-63-0 PROPAN-2-OL 3
108-88-3 TOLUENE 3
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
NONE OF THE INGREDIENTS ARE LISTED.
CANADIAN DOMESTIC SUBSTANCES LIST (DSL): ALL INGREDIENTS ARE LISTED.
CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| 16 OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL
NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
DATE OF PREPARATION / LAST REVISION: 04/20/2016 / -
ABBREVIATIONS AND ACRONYMS:
ADR:
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION (USA)
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (USA)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY
OSHA: OCCUPATIONAL SAFETY & HEALTH
EXPL. 1.1: EXPLOSIVES, DIVISION 1.1
FLAM. GAS 1: FLAMMABLE GASES, HAZARD CATEGORY 1
FLAM. AEROSOL 1: FLAMMABLE AEROSOLS, HAZARD CATEGORY 1
PRESS. GAS:
GASES UNDER PRESSURE: COMPRESSED GAS
FLAM. LIQ. 2: FLAMMABLE LIQUIDS, HAZARD CATEGORY 2
FLAM. LIQ. 3: FLAMMABLE LIQUIDS, HAZARD CATEGORY 3
ACUTE TOX. 3: ACUTE TOXICITY, HAZARD CATEGORY 3
ACUTE TOX. 4: ACUTE TOXICITY, HAZARD CATEGORY 4
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION, HAZARD CATEGORY 2
EYE IRRIT. 2: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2A
EYE IRRIT. 2B: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2B
MUTA. 1B: GERM CELL MUTAGENICITY, HAZARD CATEGORY 1B
CARC. 1A: CARCINOGENICITY, HAZARD CATEGORY 1A
CARC. 1B: CARCINOGENICITY, HAZARD CATEGORY 1B
REPR. 2: REPRODUCTIVE TOXICITY, HAZARD CATEGORY 2
STOT SE 1:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, HAZARD CATEGORY 1
STOT SE 2:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, HAZARD CATEGORY 2
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, HAZARD CATEGORY 3
STOT RE 2:
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE, HAZARD CATEGORY 2
ASP. TOX. 1: ASPIRATION HAZARD, HAZARD CATEGORY 1