| Common Name: | 85W/90 GL-5 HEAVY DUTY AUTOMOTIVE GEAR OIL, VALVE REGULATED LEAD ACID BATTERY, E |
| Manufacturer: | SINOPEC LUBRICANT CHINA |
| SDS Revision Date: | 2/3/2015 |
| SDS Format: | No Format Specified |
| Item Number(s): | 53ZA06, 53ZA07, 53ZA08, 53ZA10 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SINOPEC
SAFETY DATA SHEET
ACCORDING TO SS586:2014
85W/90 GL-5 HEAVY DUTY AUTOMOTIVE GEAR OIL
VERSION: 1.0
ISSUE DATE: 03/02/2015
REVISION DATE: 03/02/2015
SDS RECORD NUMBER: CSSS-TCO-010-116178
| SECTION 1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
PRODUCT IDENTIFIER:
IDENTIFICATION ON THE LABEL/TRADE NAME:
85W/90 GL-5 HEAVY DUTY AUTOMOTIVE GEAR OIL
ADDITIONAL IDENTIFICATION: NOT AVAILABLE
IDENTIFICATION OF THE PRODUCT: SEE SECTION 3
INDEX NUMBER: NOT AVAILABLE
REACH REGISTRATION NO.: NOT AVAILABLE
RELEVANT IDENTIFIED USES OF THE SUBSTANCE AND USES ADVISED AGAINST:
IDENTIFIED USES:
SUITABLE FOR LUBRICATION OF DRIVE AXLE (FRONT/REAR AXLE) AND SOME
TRANSMISSION GEARS, ESPECIALLY FOR VEHICLES WITH HYPERBOLIC GEARS,
ADAPTABLE TO CONDITIONS OF HIGH SPEED/LOW TORQUE, LOW SPEED/LARGE
TORQUE OR HIGH SPEED/SHOCK LOAD.
USES ADVISED AGAINST: NOT AVAILABLE.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER(MANUFACTURER): SINOPEC LUBRICANT CO., LTD.
ADDRESS:
NO. 6 ANNING ZHUANG WEST ROAD
HAIDIAN DISTRICT, BEIJING, PR.
CHINA
CONTACT PERSON(E-MAIL): CSC.LUBE@SINOPEC.COM
TELEPHONE: 86-400-810-9886
FAX: 86-10-82410856
EMERGENCY TELEPHONE NUMBER:
86-400-810-9886 ONLY AVAILABLE DURING OFFICE HOURS
(8:30A.M.-17:30P.M. BEIJING TIME ZONE)
AVAILABLE OUTSIDE OFFICE HOURS?:
YES ( )
NO (X)
| SECTION 2 HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE/MIXTURE:
GHS CLASSIFICATION: NOT CLASSIFIED
LABEL ELEMENTS:
HAZARD PICTOGRAMS: NO HAZARD PICTOGRAM IS USED.
SIGNAL WORD(S): NO SIGNAL WORD IS USED.
HAZARD STATEMENT: NOT APPLICABLE.
PRECAUTIONARY STATEMENT: NOT APPLICABLE.
OTHER HAZARDS: NOT AVAILABLE.
| SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
INGREDIENT(S):
CHEMICAL NAME REGISTRATION CAS NO. EC NO. CONCENTRATION
NO.
HIGHLY REFINED N/A 64742-44-5 265-146-1 90-98%
MINERAL OIL
ADDITIVE N/A 2-10%
| SECTION 4 FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
IN ALL CASES OF DOUBT, OR WHEN SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION.
IN CASE OF INHALATION:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. IF EXPOSED TO EXCESSIVE LEVELS
OF MATERIAL IN THE AIR, MOVE THE EXPOSED PERSON TO FRESH AIR. GET MEDICAL
ATTENTION IF COUGHING OR RESPIRATORY DISCOMFORT OCCURS.
IN CASE OF SKIN CONTACT:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. AS A PRECAUTION, REMOVE
CLOTHING AND SHOES IF CONTAMINATED. TO REMOVE THE MATERIAL FROM SKIN,
USE SOAP AND WATER. DISCARD CONTAMINATED CLOTHING AND SHOES OR THOROUGHLY
CLEAN BEFORE REUSE.
IN CASE OF EYES CONTACT:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. AS A PRECAUTION, REMOVE
CONTACT LENSES, IF WORN, AND FLUSH EYES WITH WATER.
IN CASE OF INGESTION:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. DO NOT INDUCE VOMITING. AS A
PRECAUTION, GET MEDICAL ADVICE.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
THE PRODUCT IS NOT CLASSIFIED AS HARMFUL TO HUMAN HEALTH EFFECT.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
IF SKIN IRRITATION OR RASH OCCURS, GET MEDICAL ADVICE/ATTENTION.
| SECTION 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE WATER FOG, FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH FLAMES.
UNSUITABLE EXTINGUISHING MEDIA: WATER.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
IN CASE OF HEAT, FIRE AND STRONG OXIDANTS CAN LEAD TO BURNING. FUMES,
SMOKE, CARBON MONOXIDE, SULFUR OXIDES, ALDEHYDES, NITROGEN OXIDES,
PHOSPHATE, CERTAIN METAL OXIDES AND OTHER DECOMPOSITION PRODUCTS, IN
THE CASE OF INCOMPLETE COMBUSTION.
SPECIAL FIRE FIGHTING METHODS AND SPECIAL PROTECTIVE ACTIONS FOR
FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
PROVIDE ADEQUATE VENTILATION. AVOID SKIN AND EYE CONTACT. REFER TO
SECTION 8 OF SDS FOR PERSONAL PROTECTION DETAILS.
FOR EMERGENCY RESPONDERS:
WEAR AN APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR IF DUST IS GENERATED.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW MATERIAL TO BE RELEASED TO THE ENVIRONMENT WITHOUT PROPER
GOVERNMENTAL PERMITS.
METHODS FOR CONTAINMENT AND CLEANING UP:
STOP THE SOURCE OF THE RELEASE IF YOU CAN DO IT WITHOUT RISK. CONTAIN
RELEASE TO PREVENT FURTHER CONTAMINATION OF SOIL, SURFACE WATER OR
GROUNDWATER. CLEAN UP SPILL AS SOON AS POSSIBLE, OBSERVING PRECAUTIONS IN
EXPOSURE CONTROLS/PERSONAL PROTECTION. USE APPROPRIATE TECHNIQUES SUCH AS
APPLYING NON-COMBUSTIBLE ABSORBENT MATERIALS OR PUMPING. WHERE FEASIBLE
AND APPROPRIATE, REMOVE CONTAMINATED SOIL. PLACE CONTAMINATED MATERIALS
IN DISPOSABLE CONTAINERS AND DISPOSE OF IN A MANNER CONSISTENT WITH
APPLICABLE REGULATIONS.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR INFORMATION ON DISPOSAL.
ADDITIONAL INFORMATION: NOT APPLICABLE.
| SECTION 7 HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, MAY CONTAIN EXPLOSIVE
VAPOURS. DO NOT CUT, DRILL, GRIND, WELD OR PERFORM SIMILAR OPERATIONS
ON OR NEAR CONTAINERS. ELECTROSTATIC DISCHARGE MAY BE GENERATED DURING
PUMPING - THIS MAY RESULT IN FIRE. ENSURE ELECTRICAL CONTINUITY BY BONDING
AND GROUNDING (EARTHING) ALL EQUIPMENT.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
DO NOT EAT, DRINK AND SMOKE IN WORK AREAS. WASH HANDS AFTER USE. REMOVE
CONTAMINATED CLOTHING AND PROTECTIVE EQUIPMENT BEFORE ENTERING EATING
AREAS.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
DO NOT STORE IN OPEN OR UNLABELED CONTAINERS. STORE IN A COOL, DRY
PLACE WITH ADEQUATE VENTILATION. KEEP AWAY FROM OPEN FLAMES AND HIGH
TEMPERATURES.
SPECIFIC END USE(S): NOT APPLICABLE.
| SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS (OEL):
INGREDIENT DATA: NOT AVAILABLE
EMERGENCY LIMITS:
INGREDIENT MATERIAL NAME TEEL-1 TEEL-2 TEEL-3
SINOPEC GREATWALL NOT NOT NOT NOT
UTTO AVAILABLE AVAILABLE AVAILABLE AVAILABLE
INGREDIENT ORIGINAL IDLH REVISED IDLH
HIGHLY REFINED MINERAL OIL NOT AVAILABLE NOT AVAILABLE
EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION TO CONTROL AIRBORNE CONCENTRATIONS BELOW THE
EXPOSURE GUIDELINES/LIMITS.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
NO SPECIAL EYE PROTECTION IS NORMALLY REQUIRED. WHERE SPLASHING IS
POSSIBLE, WEAR SAFETY GLASSES WITH SIDE SHIELDS AS A GOOD SAFETY PRACTICE.
HAND PROTECTION:
USE PROTECTIVE GLOVES WHICH IS CHEMICALLY RESISTANT TO THIS MATERIAL.
BODY PROTECTION:
NO SPECIAL PROTECTIVE CLOTHING IS NORMALLY REQUIRED. WHERE SPLASHING IS
POSSIBLE, SELECT PROTECTIVE CLOTHING DEPENDING ON OPERATIONS CONDUCTED,
PHYSICAL REQUIREMENTS AND OTHER SUBSTANCES IN THE WORKPLACE.
SUGGESTED MATERIALS FOR PROTECTIVE GLOVES INCLUDE:
NEOPRENE, NITRILE RUBBER.
RESPIRATORY PROTECTION:
NO RESPIRATORY PROTECTION IS NORMALLY REQUIRED. NO RESPIRATORY PROTECTION
IS ORDINARILY REQUIRED UNDER NORMAL CONDITIONS OF USE. IN ACCORDANCE WITH
GOOD INDUSTRIAL HYGIENE PRACTICES, PRECAUTIONS SHOULD BE TAKEN TO AVOID
BREATHING OF MATERIAL. IF USER OPERATIONS GENERATE AN OIL MIST, DETERMINE
IF AIRBORNE CONCENTRATIONS ARE BELOW THE OCCUPATIONAL EXPOSURE LIMIT FOR
MINERAL OIL MIST. IF NOT, WEAR AN APPROVED RESPIRATOR THAT PROVIDES
ADEQUATE PROTECTION FROM THE MEASURED CONCENTRATIONS OF THIS MATERIAL. FOR
AIR-PURIFYING RESPIRATORS USE A PARTICULATE CARTRIDGE. USE A POSITIVE
PRESSURE AIR-SUPPLYING RESPIRATOR IN CIRCUMSTANCES WHERE AIR-PURIFYING
RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION.
THERMAL HAZARDS: WEAR SUITABLE PROTECTIVE CLOTHING TO PREVENT HEAT.
ENVIRONMENTAL EXPOSURE CONTROLS:
AVOID DISCHARGE INTO THE ENVIRONMENT.
ACCORDING TO LOCAL REGULATIONS, FEDERAL AND OFFICIAL REGULATIONS.
| SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: YELLOW TO BROWN TRANSPARENT OILY LIQUID
COLOUR: YELLOW TO BROWN
ODOUR: ODORLESS OR SLIGHT ODOR
ODOUR THRESHOLD: NOT AVAILABLE
PH: NOT AVAILABLE
MELTING POINT/RANGE (DEG. C): 0 DEG. C (HIGHLY REFINED MINERAL OIL)
BOILING POINT/RANGE (DEG. C): >280 DEG. C (TYP)
FLASH POINT (DEG. C): 200 DEG. C (OPEN CUP) (TYP)
EVAPORATION RATE: NOT AVAILABLE
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE
IGNITION TEMPERATURE (DEG. C): NOT AVAILABLE
UPPER/LOWER FLAMMABILITY/EXPLOSIVE LIMITS: NOT AVAILABLE
VAPOUR PRESSURE (40 DEG. C): <0.5MPA (40 DEG. C)
VAPOUR DENSITY: >1 (AIR=1)
DENSITY: 0.88 KG/L - 0.92 KG/L (20 DEG. C)
BULK DENSITY (KG/M3): NOT AVAILABLE
WATER SOLUBILITY (G/L): INSOLUBLE
N-OCTANOL/WATER (LOG PO/W): >6 (ESTIMATED VALUE)
AUTO-IGNITION TEMPERATURE: >260 DEG. C
DECOMPOSITION TEMPERATURE: NOT AVAILABLE
VISCOSITY: 14.5 MM/S2-18.5 MM/S2 (100 DEG. C)
EXPLOSIVE PROPERTIES: NON EXPLOSIVE
OXIDISING PROPERTIES: NOT OXIDIZING
MOLECULAR FORMULA: NOT AVAILABLE
MOLECULAR WEIGHT: NOT AVAILABLE
OTHER INFORMATION:
FAT SOLUBILITY(SOLVENT-OIL TO BE SPECIFIED) ETC: NOT AVAILABLE
SURFACE TENSION: NOT AVAILABLE
DISSOCIATION CONSTANT IN WATER(PKA): NOT AVAILABLE
OXIDATION-REDUCTION POTENTIAL: NOT AVAILABLE
SPECIFIC GRAVITY: NOT AVAILABLE
| SECTION 10 STABILITY AND REACTIVITY | |
REACTIVITY:
THE SUBSTANCE IS STABLE UNDER NORMAL STORAGE AND HANDLING CONDITIONS.
CHEMICAL STABILITY:
STABLE AT ROOM TEMPERATURE IN CLOSED CONTAINERS UNDER NORMAL STORAGE AND
HANDLING CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
CONTACT WITH STRONG OXIDANTS CAN LEAD TO BURNING.
CONDITIONS TO AVOID:
EXTREME HEAT AND HIGH ENERGY SOURCES OF IGNITION AND STRONG OXIDIZERS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
FUMES, SMOKE, CARBON MONOXIDE, SULFUR OXIDES, ALDEHYDES, NITROGEN OXIDES,
PHOSPHATE, CERTAIN METAL OXIDES AND OTHER DECOMPOSITION PRODUCTS, IN THE
CASE OF INCOMPLETE COMBUSTION.
| SECTION 11 TOXICOLOGICAL INFORMATION | |
TOXICOKINETICS, METABOLISM AND DISTRIBUTION:
NON-HUMAN TOXIKOLOGICAL DATA: NOT AVAILABLE
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD50 (ORAL, RAT): >5000 MG/KG BW
LD50 (DERMAL, RABBIT): >5000 MG/KG BW
LC50 (INHALATION, RAT): >10000 MG/M3 BW
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
STOT-SINGLE EXPOSURE: NOT CLASSIFIED
STOT-REPEATED EXPOSURE: NOT CLASSIFIED
| SECTION 12 ECOLOGICAL INFORMATION | |
TOXICITY:
HIGHLY REFINED MINERAL OIL (CAS: 64742-44-5):
ACUTE TOXICITY TIME SPECIES METHOD EVALUATION REMARKS
LL50: >100 MG/L 96H FISH OECD 203 N/A N/A
LL50: >10000 MG/L 48H DAPHNIA OECD 202 N/A N/A
EC50: N/A 72H ALGAE OECD 201 N/A N/A
PERSISTENCE AND DEGRADABILITY:
THIS PRODUCT IS EXPECTED TO BE INHERENTLY BIODEGRADABLE.
BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATION IS UNLIKELY DUE TO THE VERY LOW WATER SOLUBILITY OF THIS
PRODUCT; THEREFORE BIOAVAILABILITY TO AQUATIC ORGANISMS IS MINIMAL.
MOBILITY IN SOIL:
WHEN RELEASED INTO THE ENVIRONMENT, ADSORPTION TO SEDIMENT AND SOIL WILL
BE THE PREDOMINANT BEHAVIOR.
RESULTS OF PBT & VPVB ASSESSMENT: NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NOT AVAILABLE.
| SECTION 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
THE MATERIAL SHOULD BE DISPOSED OF BY INCINERATION IN A CHEMICAL
INCINERATOR IN COMPLIANCE WITH NATIONAL AND REGIONAL REQUIREMENTS.
PRODUCT / PACKAGING DISPOSAL:
IF EMPTY CONTAINER RETAINS PRODUCT RESIDUES, ALL LABEL PRECAUTIONS MUST
BE OBSERVED.
RETURN FOR REUSE OR DISPOSE ACCORDING TO NATIONAL OR LOCAL REGULATIONS.
| SECTION 14 TRANSPORT INFORMATION | |
LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT
(ADR/RID) (IMDG) (ICAO/IATA)
UN-NUMBER NOT REGULATED NOT REGULATED NOT REGULATED
UN PROPER SHIPPING NOT REGULATED NOT REGULATED NOT REGULATED
NAME
TRANSPORT HAZARD NOT REGULATED NOT REGULATED NOT REGULATED
CLASS
PACKAGING GROUP NOT REGULATED NOT REGULATED NOT REGULATED
ENVIRONMENTAL HAZARDS NO NO NO
SPECIAL PRECAUTIONS SEE SECTION 2.2 SEE SECTION 2.2 SEE SECTION 2.2
FOR USER
TRANSPORT IN BULK NOT REGULATED NOT REGULATED NOT REGULATED
ACCORDING TO ANNEX II
OF MARPOL 73/78 AND
THE IBC CODE
| SECTION 15 REGULATION INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
HIGHLY REFINED MINERAL OIL (64742-44-5) IS FOUND ON THE FOLLOWING
REGULATORY LISTS: "NOT APPLICABLE"
| SECTION 16 OTHER INFORMATION | |
FURTHER INFORMATION:
THIS INFORMATION IS BASED UPON THE PRESENT STATE OF OUR KNOWLEDGE.
THIS SDS HAS BEEN COMPILED AND IS SOLELY INTENDED FOR THIS PRODUCT.
NOTICE TO READER:
EMPLOYERS SHOULD USE THIS INFORMATION ONLY AS A SUPPLEMENT TO OTHER
INFORMATION GATHERED BY THEM, AND SHOULD MAKE INDEPENDENT JUDGMENT OF
SUITABILITY OF THIS INFORMATION TO ENSURE PROPER USE AND PROTECT THE
HEALTH AND SAFETY OF EMPLOYEES. THIS INFORMATION IS FURNISHED WITHOUT
WARRANTY, AND ANY USE OF THE PRODUCT NOT IN CONFORMANCE WITH THIS SAFETY
DATA SHEET, OR IN COMBINATION WITH ANY OTHER PRODUCT OR PROCESS, IS THE
RESPONSIBILITY OF THE USER.
AUTHOR: HANGZHOU CIRS CO., LIMITED
WEBSITE: WWW.CIRS-GROUP.COM
TEL: 0571-87206555
EMAIL: INFO@CIRS-GROUP.COM
PRODUCT NAME: 85W/90 GL-5 HEAVY DUTYAUTOMOTIVE GEAR OIL
VERSION #: 1.0
SDS SG
DISCOVER ENERGY CORP(R*)
SUITE 880 - 999 WEST BROADWAY
VANCOUVER BC V5Z 1K5
CANADA
T: 604.730.2877
F: 604.730.2898
E: INFO@DISCOVER-ENERGY.COM
WWW.DISCOVER-ENERGY.COM
SAFETY DATA SHEET
VALVE REGULATED LEAD ACID BATTERY, NON-SPILLABLE (US, CN, EU VERSION FOR
INTERNATIONAL TRADE)
| SECTION 1: IDENTIFICATION | |
PRODUCT/CHEMICAL NAME: VALVE REGULATED LEAD ACID BATTERY
CHEMICAL FAMILY/CLASSIFICATION: ELECTROLYTE TYPE LEAD ACID STORAGE BATTERY
OTHER PRODUCT NAMES:
EV TRACTION DRY CELL, GEL ABSORBED ELECTROLYTE SEALED VALVE REGULATED
BATTERY NON-SPILLABLE 49 CFR 173, 159(D).
PRODUCT USE:
ELECTRICAL STORAGE BATTERIES FOR INDUSTRIAL, COMMERCIAL AND PERSONAL USE.
MANUFACTURER'S NAME AND ADDRESS:
DISCOVER ENERGY CORP. / UNIVISION
SUITE 880 - 999 WEST BROADWAY
VANCOUVER BC V5Z 1K5
CANADA
TELEPHONE: 1.604.730.2877
EMERGENCY TELEPHONE NUMBER:
US:
INFOTRAC: 1.800.535.5053
CN:
CHEMTREC: 1.800.424.9300
| SECTION 2: HAZARD(S) IDENTIFICATION | |
GHS CLASSIFICATION:
HEALTH:
ACUTE TOXICITY - NOT LISTED (NL)
EYE CORROSION (NL)
SKIN CORROSION (NL)
SKIN SENSITIZATION (NL)
MUTAGENICITY / CARCINOGENICITY (NL)
REPRODUCTIVE / DEVELOPMENTAL (NL)
TARGET ORGAN TOXICITY [REPEATED] (NL)
ENVIRONMENTAL: AQUATIC TOXICITY (NL)
PHYSICAL:
NFPA (NL)
CN (NL)
EU (NL)
HAZARD STATEMENTS:
CONTACT WITH INTERNAL COMPONENTS MAY CAUSE IRRITATION OR SEVERE BURNS.
IRRITATING TO EYES, RESPIRATORY SYSTEM, AND SKIN.
PRECAUTIONARY STATEMENTS:
KEEP OUT OF REACH OF CHILDREN. KEEP CONTAINERS TIGHTLY CLOSED. AVOID HEAT,
SPARKS, AND OPEN FLAME WHILE CHARGING BATTERIES. AVOID CONTACT WITH
INTERNAL ACID / GEL.
EMERGENCY OVERVIEW:
MAY FORM EXPLOSIVE AIR/GAS MIXTURE DURING CHARGING. CONTACT WITH INTERNAL
COMPONENTS MAY CAUSE IRRITATION OF SEVERE BURNS. IRRITATING TO EYES,
RESPIRATORY SYSTEM, AND SKIN. PROLONGED INHALATION OR INGESTION MAY RESULT
IN SERIOUS DAMAGE TO HEALTH. PREGNANT WOMEN EXPOSED TO INTERNAL COMPONENTS
MAY EXPERIENCE REPRODUCTIVE/DEVELOPMENTAL EFFECTS.
POTENTIAL HEALTH EFFECTS:
EYES:
DIRECT CONTACT OF INTERNAL ELECTROLYTE GEL WITH EYES MAY CAUSE SEVERE
BURNS OR BLINDNESS.
SKIN:
DIRECT CONTACT OF INTERNAL ELECTROLYTE GEL WITH THE SKIN MAY CAUSE SKIN
IRRITATION OR DAMAGING BURNS.
INGESTION:
SWALLOWING THIS PRODUCT MAY CAUSE SEVERE BURNS TO THE ESOPHAGUS AND
DIGESTIVE TRACT AND HARMFUL OR FATAL LEAD POISONING. LEAD INGESTION MAY
CAUSE NAUSEA, VOMITING, WEIGHT LOSS, ABDOMINAL SPASMS, FATIGUE, AND PAIN
IN THE ARMS, LEGS AND JOINTS.
INHALATION: RESPIRATORY TRACT IRRITATION AND POSSIBLE LONG TERM EFFECTS.
ACUTE HEALTH HAZARDS:
REPEATED OR PROLONGED CONTACT MAY CAUSE MILD SKIN IRRITATION.
CHRONIC HEALTH HAZARDS:
LEAD POISONING IF PERSONS ARE EXPOSED TO INTERNAL COMPONENTS OF THE
BATTERIES. LEAD ABSORPTION MAY CAUSE NAUSEA, VOMITING, WEIGHT LOSS,
ABDOMINAL SPASMS, FATIGUE, AND PAIN IN THE ARMS, LEGS AND JOINTS. OTHER
EFFECTS MAY INCLUDE CENTRAL NERVOUS SYSTEM DAMAGE, KIDNEY DYSFUNCTION, AND
POTENTIAL REPRODUCTIVE EFFECTS. CHRONIC INHALATION OF SULFURIC ACID MIST
MAY INCREASE THE RISK OF LUNG CANCER.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
RESPIRATORY AND SKIN DISEASES MAY PREDISPOSE ONE TO ACUTE AND CHRONIC
EFFECTS OF SULFURIC ACID AND/OR LEAD. CHILDREN AND PREGNANT WOMEN MUST BE
PROTECTED FROM LEAD EXPOSURE. PERSONS WITH KIDNEY DISEASE MAY BE AT
INCREASED RISK OF KIDNEY FAILURE.
ADDITIONAL INFORMATION:
NO HEALTH EFFECTS ARE EXPECTED RELATED TO NORMAL USE OF THIS PRODUCT AS
SOLD.
SIGNAL WORD: DANGER
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
ENVIRONMENT
HAZARD STATEMENT:
SEVERE SKIN BURNS AND EYE DAMAGE
SERIOUS EYE DAMAGE
MAY DAMAGE FERTILITY OR THE UNBORN CHILD IF INGESTED OR INHALED
MAY CAUSE CANCER IF INGESTED OR INHALED
CAUSES DAMAGE TO CENTRAL NERVOUS SYSTEM, BLOOD AND KIDNEYS THROUGH
PROLONGED OR REPEATED EXPOSURE
MAY FORM EXPLOSIVE AIR/GAS MIXTURE DURING CHARGING
EXTREMELY FLAMMABLE GAS (HYDROGEN)
EXPLOSIVE, FIRE, BLAST OR PROJECTION HAZARD
ENVIRONMENTAL STATEMENT:
WASH THOROUGHLY AFTER HANDLING
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT
WEAR PROTECTIVE GLOVES AND CLOTHING, AS WELL AS EYE AND FACE PROTECTION
AVOID BREATHING DUST, FUME, GAS, MIST, VAPOR OR SPRAY
OUTDOORS USE ONLY OR IN A WELL VENTILATED AREA
CAUSES SKIN AND RESPIRATORY SYSTEM, AS WELL AS SERIOUS EYE DAMAGE
CONTACT WITH INTERNAL COMPONENTS MAY CAUSE IRRITATION OR SEVERE BURNS
AVOID CONTACT WITH INTERNAL ACID
| SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS | |
INGREDIENTS (CHEMICAL/COMMON NAMES) CAS NUMBER % BY WEIGHT EU NUMBER
LEAD, INORGANIC 7439-92-1 60 - 80 231-100-4
SULFURIC ACID 7664-93-9 5 - 15 231-639-5
ANTIMONY 7440-36-0 0 - 0.1 231-146-5
ARSENIC 7440-38-2 <0.1 231-148-6
TIN 7440-31-5 0 - 0.1 231-141-8
POLYPROPYLENE 9003-07-0 2 - 10 N/A
ACRYLONITRILE BUTADIENE STYRENE 9003-56-0 4 - 12 N/A
(ABS)
ADDITIONAL INFORMATION THESE INGREDIENTS REFLECT COMPONENTS
OF THE FINISHED PRODUCT RELATED TO
PERFORMANCE OF THE PRODUCT AS
DISTRIBUTED INTO COMMERCE.
| SECTION 4: FIRST AID MEASURES | |
EYE CONTACT:
FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SEEK
IMMEDIATE MEDICAL ATTENTION IF EYES HAVE BEEN EXPOSED DIRECTLY TO ACID
GEL.
SKIN CONTACT:
FLUSH AFFECTED AREA(S) WITH LARGE AMOUNTS OF WATER USING DELUGE EMERGENCY
SHOWER, IF AVAILABLE, SHOWER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED
CLOTHING. IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION.
INGESTION:
IF SWALLOWED, GIVE LARGE AMOUNTS OF WATER. DO NOT INDUCE VOMITING OR
ASPIRATION INTO THE LUNGS MAY OCCUR AND CAN CAUSE PERMANENT INJURY OR
DEATH.
INHALATION:
IF BREATHING DIFFICULTIES DEVELOP, REMOVE PERSON TO FRESH AIR. IF SYMPTOMS
PERSIST, SEEK MEDICAL ATTENTION.
| SECTION 5: FIRE FIGHTING MEASURES | |
SUITABLE/UNSUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL, CARBON DIOXIDE, WATER, FOAM. DO NOT USE WATER ON LIVE
ELECTRICAL CIRCUITS.
SPECIAL FIRE FIGHTING PROCEDURES & PROTECTIVE EQUIPMENT:
USE APPROPRIATE MEDIA FOR SURROUNDING FIRE. DO NOT USE CARBON DIOXIDE
DIRECTLY ON CELLS. AVOID BREATHING VAPOURS. USE FULL PROTECTIVE EQUIPMENT
(BUNKER GEAR) AND SELF-CONTAINED BREATHING APPARATUS.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
BATTERIES EVOLVE FLAMMABLE HYDROGEN GAS DURING CHARGING AND MAY INCREASE
FIRE RISK IN POORLY VENTILATED AREAS NEAR SPARKS EXCESSIVE HEAT OR OPEN
FLAMES.
SPECIFIC HAZARDS IN CASE OF FIRE:
THERMAL SHOCK MAY CAUSE BATTERY CASE TO CRACK OPEN. CONTAINERS MAY EXPLODE
WHEN HEATED.
ADDITIONAL INFORMATION:
FIREFIGHTING WATER RUNOFF AND DILUTION WATER MAY BE TOXIC AND CORROSIVE.
MAY CAUSE ADVERSE ENVIRONMENTAL IMPACTS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS:
AVOID CONTACT WITH SKIN. NEUTRALIZE ANY SPILLED ELECTROLYTE WITH
NEUTRALIZING AGENTS, SUCH AS SODA ASH, SODIUM BICARBONATE, OR VERY
DILUTE SODIUM HYDROXIDE SOLUTIONS.
ENVIRONMENTAL PRECAUTIONS:
PREVENT SPILLED MATERIAL FROM ENTERING SEWERS AND WATERWAYS.
SPILL CONTAINMENT & CLEANUP METHODS/MATERIALS:
ADD NEUTRALIZER/ABSORBENT TO SPILL AREA. SWEEP OR SHOVEL SPILLED MATERIAL
AND ABSORBENT AND PLACE IN APPROVED CONTAINER. DISPOSE OF ANY
NON-RECYCLABLE MATERIALS IN ACCORDANCE WITH LOCAL, STATE, PROVINCIAL OR
FEDERAL REGULATIONS.
ADDITIONAL INFORMATION:
LEAD ACID BATTERIES AND THEIR PLASTIC CASES ARE RECYCLABLE. CONTACT A
DISCOVER REPRESENTATIVE FOR RECYCLING INFO.
| SECTION 7: HANDLING & STORAGE | |
PRECAUTIONS FOR SAFE HANDLING/STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE.
IF BATTERY CASE IS BROKEN, AVOID CONTACT WITH INTERNAL COMPONENTS.
DO NOT HANDLE NEAR HEAT, SPARKS, OR OPEN FLAMES.
PROTECT CONTAINERS FROM PHYSICAL DAMAGE TO AVOID LEAKS AND SPILLS.
PLACE CARDBOARD BETWEEN LAYERS OF STACKED BATTERIES TO AVOID DAMAGE AND
SHORT CIRCUITS.
DO NOT ALLOW CONDUCTIVE MATERIAL TO TOUCH THE BATTERY TERMINALS. A
DANGEROUS SHORT-CIRCUIT MAY OCCUR AND CAUSE BATTERY FAILURE AND FIRE.
KEEP AWAY FROM COMBUSTIBLE MATERIALS, ORGANIC CHEMICALS, REDUCING
SUBSTANCES, METALS, STRONG OXIDIZERS AND WATER.
| SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION | |
ENGINEERING CONTROLS/SYSTEM DESIGN:
CHARGE IN AREAS WITH ADEQUATE VENTILATION.
VENTILATION GENERAL: DILUTION VENTILATION IS ACCEPTABLE.
RESPIRATORY PROTECTION:
NOT REQUIRED FOR NORMAL CONDITION USE. SEE SPECIAL FIREFIGHTING PROCEDURES
(SECTION 5)
EYE PROTECTION: WEAR PROTECTIVE GLASSES WITH SIDE SHIELDS OR GOGGLES.
SKIN PROTECTION:
WEAR CHEMICAL RESISTANT GLOVES AS A STANDARD PROCEDURE TO PREVENT SKIN
CONTACT.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
NONE REQUIRED UNDER NORMAL USE CONDITIONS FOR EV TRACTION DRY CELL, AND
GEL ABSORBED ELECTROLYTE SEALED, VALVE REGULATED BATTERY. WASH HANDS AFTER
HANDLING.
EXPOSURE GUIDELINES & LIMITS:
OSHA:
PERMISSIBLE EXPOSURE LIMIT (PEL/TWA):
LEAD, INORGANIC (AS Pb): 0.05 MG/M3
SULFURIC ACID: 1 MG/M3
ANTIMONY: 0.5 MG/M3
ARSENIC: MG/M3
TIN: 2 MG/M3
ACGIH:
2007 THRESHOLD LIMIT VALUE (TLV):
LEAD, INORGANIC (AS Pb): 0.05 MG/M3
SULFURIC ACID: 0.2 MG/M3
ANTIMONY: 0.5 MG/M3
ARSENIC: 0.01 MG/M3
TIN: 2 MG/M3
QUEBEC:
PERMISSIBLE EXPOSURE VALUE (PEV):
LEAD, INORGANIC (AS Pb): 0.15 MG/M3
SULFURIC ACID:
1 MG/M3 TWA
3 MG/M3 STEV
ANTIMONY: 0.5 MG/M3
ARSENIC: 0.1 MG/M3
TIN: 2 MG/M3
ONTARIO:
OCCUPATIONAL EXPOSURE LEVEL (OEL):
LEAD (DESIGNATED SUBSTANCE): 0.10 MG/M3
SULFURIC ACID:
1 MG/M3 TWAEV
3 MG/M3 STEV
ANTIMONY: 0.5 MG/M3
ARSENIC (DESIGNATED SUBSTANCE): 0.01 MG/M3
TIN: 2 MG/M3
NETHERLANDS:
MAXIMAAL AANVAARDE CONCENTRATIE (MAC):
LEAD, INORGANIC (AS Pb): 0.15 MG/M3
SULFURIC ACID: 1 MG/M3
GERMANY:
MAXIMALE ARBEITSPLATZKONZENTRATIONEN (MAK):
LEAD, INORGANIC (AS Pb): 0.1 MG/M3
SULFURIC ACID:
1 MG/M3 TWA
2 MG/M3 STEL
ANTIMONY: 0.5 MG/M3
UNITED KINGDOM:
OCCUPATIONAL EXPOSURE STANDARD (OES):
LEAD: 0.15 MG/M3
ANTIMONY: 0.5 MG/M3
ARSENIC: 0.1 MG/M3
TIN: 2 MG/M3
TWA: 8 HOUR TIME WEIGHTED AVERAGE
STE: SHORT TERM EXPOSURE
MG/M3: MILLIGRAMS PER CUBIC METER OF AIR
NE: NOT ESTABLISHED
ADDITIONAL INFORMATION:
BATTERIES ARE HOUSED IN CASES WHICH ARE REGULATED AS TOTAL DUST OR
RESPIRABLE DUST ONLY WHEN THEY ARE GROUND UP DURING RECYCLING. MAY BE
REQUIRED TO MEET DOMESTIC REQUIREMENTS FOR A SPECIFIC DESTINATION(S).
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: INDUSTRIAL/COMMERCIAL LEAD ACID GEL BATTERY
ODOR: ODORLESS
ODOR THRESHOLD: N/A
PHYSICAL STATE: SULFURIC ACID, GELATINOUS/ LEAD, SOLID
PH: <1
BOILING POINT: 235-240 DEG. F (AS SULFURIC ACID)
MELTING POINT: N/A
FREEZING POINT: N/A
VAPOR PRESSURE: 10 MMHg
VAPOR DENSITY (AIR = 1): >1
SPECIFIC GRAVITY (H2O = 1): 1.27-1.33
EVAPORATION RATE (N-BUAC=1): <1
SOLUBILITY IN WATER: 100% (AS SULFURIC ACID)
FLASH POINT: BELOW ROOM TEMPERATURE (AS HYDROGEN GAS)
AUTO-IGNITION TEMPERATURE: N/A
LOWER EXPLOSIVE LIMIT (LEL): 4% (AS HYDROGEN GAS)
UPPER EXPLOSIVE LIMIT (UEL): 74% (AS HYDROGEN GAS)
PARTITION COEFFICIENT: N/A
VISCOSITY (POISE @ 25 DEG. C): N/A
DECOMPOSITION TEMPERATURE: N/A
FLAMMABILITY/HMIS HAZARD CLASSIFICATION (US/CN/EU):
AS SULFURIC ACID:
HEALTH 3
FLAMMABILITY 0
REACTIVITY 2
| SECTION 10: STABILITY & REACTIVITY | |
STABILITY:
THIS PRODUCT IS STABLE UNDER NORMAL CONDITIONS AT AMBIENT TEMPERATURE.
INCOMPATIBILITY (MATERIALS TO AVOID):
STRONG BASES, COMBUSTIBLE ORGANIC MATERIALS, REDUCING AGENTS, FINELY
DIVIDED METALS, STRONG OXIDIZERS, AND WATER.
HAZARDOUS DECOMPOSITION / BY-PRODUCTS:
THERMAL DECOMPOSITION WILL PRODUCE SULFUR DIOXIDE, SULFUR TRIOXIDE,
CARBON MONOXIDE, SULFURIC ACID MIST, AND HYDROGEN.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
CONDITIONS TO AVOID: OVERCHARGING, SOURCES OF IGNITION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY (TEST RESULTS BASIS & COMMENTS):
SULFURIC ACID:
LD50, RAT: 21409 MG/KG
LC50, GUINEA PIG: 510 MG/M3
LEAD:
REPEATED EXPOSURE TO LEAD AND LEAD COMPOUNDS IN THE WORKPLACE MAY RESULT
IN NERVOUS SYSTEM TOXICITY. SOME TOXICOLOGISTS REPORT THAT ABNORMAL
CONDUCTION VELOCITIES IN PERSON WITH BLOOD LEAD LEVELS OF 50 PG/100 ML OR
HIGHER. HEAVY LEAD EXPOSURE MAY RESULT IN CENTRAL NERVOUS SYSTEM DAMAGE,
ENCEPHALOPATHY AND DAMAGE TO THE BLOOD-FORMING (HEMATOPOIETIC) TISSUES.
ADDITIONAL INFORMATION:
VERY LITTLE CHRONIC TOXICITY DATA AVAILABLE FOR ELEMENTAL LEAD.
LEAD IS LISTED BY IARC AS A 2B CARCINOGEN:
POSSIBLE CARCINOGEN IN HUMANS. ARSENIC IS LISTED BY IARC, ACGIH, AND NTP
AS A CARCINOGEN, BASED ON STUDIES WITH HIGH DOSES OVER LONG PERIODS OF
TIME. THE OTHER INGREDIENTS IN THIS PRODUCT, PRESENT AT EQUAL TO OR GREATER
THAN 0.1% OF THE PRODUCT, ARE NOT LISTED BY OSHA, NTP, OR IARC AS SUSPECT
CARCINOGENS. THE 19TH AMENDMENT TO EC DIRECTIVE 67/548/EEC CLASSIFIED LEAD
COMPOUNDS, BUT NOT LEAD IN METAL FORM, AS POSSIBLY TOXIC TO REPRODUCTION.
RISK PHRASE 61: MAY CAUSE HARM TO THE UNBORN CHILD, APPLIES TO LEAD
COMPOUNDS, ESPECIALLY SOLUBLE FORMS.
| SECTION 12: ECOLOGICAL INFORMATION | |
PERSISTENCE & DEGRADABILITY:
LEAD IS VERY PERSISTENT IN SOILS / SEDIMENTS. NO DATA AVAILABLE ON
BIODEGRADATION.
BIO-ACCUMULATIVE POTENTIAL (INC. MOBILITY):
MOBILITY OF METALLIC LEAD BETWEEN ECOLOGICAL COMPARTMENTS IS LOW.
BIOACCUMULATION OF LEAD OCCURS IN AQUATIC AND TERRESTRIAL ANIMALS AND
PLANTS, BUT VERY LITTLE BIOACCUMULATION OCCURS THROUGH THE FOOD CHAIN.
MOST STUDIES HAVE INCLUDED LEAD COMPOUNDS, NOT SOLID INORGANIC LEAD.
AQUATIC TOXICITY (TEST RESULTS & COMMENTS):
SULFURIC ACID:
24-HOUR LC50, FRESH WATER FISH (BRACHYDANIO RERIO): 82 MG/L
96-HOUR LOEC*, FRESH WATER FISH (CYPRINUS CARPIO): 22 MG/L
LEAD (METAL): NO DATA AVAILABLE
*LOWEST OBSERVABLE EFFECT CONCENTRATION
| SECTION 13: DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
LEAD ACID BATTERIES ARE RECYCLABLE WHEN SENT TO A SECONDARY LEAD SMELTER.
FOLLOW LOCAL, STATE / PROVINCIAL, AND FEDERAL / NATIONAL REGULATIONS
APPLICABLE TO AS-USED, END-OF-LIFE CHARACTERISTICS TO BE DETERMINED BY
END-USER.
HAZARDOUS WASTE CLASS / CODE:
US:
NOT APPLICABLE TO FINISHED PRODUCT AS MANUFACTURED FOR DISTRIBUTION INTO
COMMERCE.
CN:
NOT APPLICABLE TO FINISHED PRODUCT AS MANUFACTURED FOR DISTRIBUTION INTO
COMMERCE.
EWC:
NOT APPLICABLE TO FINISHED PRODUCT AS MANUFACTURED FOR DISTRIBUTION INTO
COMMERCE.
ADDITIONAL INFORMATION:
NOT INCLUDED. RECYCLE OR DISPOSE AS ALLOWED BY LOCAL JURISDICTION FOR THE
END-OF-LIFE CHARACTERISTICS AS-DISPOSED.
| SECTION 14: TRANSPORT INFORMATION | |
GROUND: NOT REGULATED AS A HAZARDOUS MATERIAL
US-DOT / CAN-TDG / EU-ADR / APEC-ADR PROPER SHIPPING NAME:
AIRCRAFT: NOT REGULATED AS A HAZARDOUS MATERIALS
ICAO-IATA:
PROPER SHIPPING NAME:
DISCOVER BATTERIES MEET THE TEST REQUIREMENTS FOR "NON-SPILLABLE AND WET
ELECTRONIC STORAGE BATTERIES" AS PROVIDED IN 49 CFR 173.159 (D) AND
IATA/ICAO, AND ARE NON-REGULATED WHEN PROTECTED AGAINST SHORT CIRCUITS,
KEPT UPRIGHT, AND SECURELY PACKAGED.
VESSEL: NOT REGULATED AS A HAZARDOUS MATERIAL
IMO-IMDG:
PROPER SHIPPING NAME:
ADDITIONAL INFORMATION:
EACH BATTERY AND THE OUTER PACKAGING MUST BE PLAINLY AND DURABLY MARKED
"NONSPILLABLE" OR "NONSPILLABLE BATTERY" NON-SPILLABLE BATTERY COMPLIES
WITH THE PROVISIONS LISTED IN 49 CFR 173.159(D), THEREFORE MUST NOT BE
MARKED WITH AN IDENTIFICATION NUMBER OR HAZARDOUS LABEL AND IS NOT SUBJECT
TO HAZARDOUS SHIPPING PAPER REQUIREMENTS. TRANSPORT REQUIRES PROPER
PACKAGING AND PAPERWORK, INCLUDING THE NATURE AND QUANTITY OF GOODS, PER
APPLICABLE ORIGIN/DESTINATION/CUSTOMS POINTS AS-SHIPPED.
| SECTION 15: REGULATORY INFORMATION | |
INVENTORY STATUS (ALL COMPONENTS ARE LISTED ON THE TSCA; EINECS / ELINCS;
AND DSL, UNLESS NOTED OTHERWISE BELOW)
US FEDERAL REGULATIONS:
TSCA SECTION 8B - INVENTORY STATUS:
ALL CHEMICALS COMPRISING THIS PRODUCT ARE EITHER EXEMPT OR LISTED ON THE
TSCA INVENTORY.
TSCA SECTION 12B - EXPORT NOTIFICATION:
IF THE FINISHED PRODUCT CONTAINS CHEMICALS SUBJECT TO TSCA SECTION 12B
EXPORT NOTIFICATION, THEY ARE LISTED BELOW:
CHEMICAL CAS#
NONE N/A
CERCLA (COMPREHENSIVE RESPONSIVE COMPENSATION AND LIABILITY ACT):
CHEMICALS PRESENT IN THE PRODUCT WHICH COULD REQUIRE REPORTING UNDER THE
STATUTE:
CHEMICAL CAS#
LEAD 7439-92-1
SULFURIC ACID 7664-93-9
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT):
THE FINISHED PRODUCT CONTAINS CHEMICALS SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF SARA TITLE III.
CHEMICAL CAS# %WT
LEAD 7439-92-1 67
SULFURIC ACID 7664-93-9 10
CERCLA SECTION 311/312 HAZARD CATEGORIES:
THE FINISHED PRODUCT IS EXEMPT FROM THESE REGULATIONS, BUT LEAD AND
SULFURIC ACID ABOVE THE THRESHOLDS ARE REPORTABLE ON TIER II REPORTS.
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: NO (INTERNAL ACID GEL IS CORROSIVE)
DELAYED HAZARD: NO
SULFURIC ACID IS REGULATED AS AN EHS (EXTREMELY HAZARDOUS SUBSTANCE):
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THE FOLLOWING CHEMICALS IDENTIFIED TO EXIST IN THE FINISHED PRODUCT AS
DISTRIBUTED INTO COMMERCE ARE KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM:
CHEMICAL CAS# %WT
ARSENIC (AS ARSENIC OXIDES) 7440-38-2 <0.1
STRONG INORGANIC ACID MISTS N/A 10
(INCLUDING SULFURIC ACID)
LEAD 7439-92-1 67
CALIFORNIA CONSUMER PRODUCT VOLATILE ORGANIC COMPOUND EMISSIONS:
THIS PRODUCT IS NOT REGULATED AS A CONSUMER PRODUCT FOR PURPOSES OF
CARB / OTC VOC REGULATIONS, AS SOLD FOR THE INTENDED PURPOSE AND INTO
THE INDUSTRIAL / COMMERCIAL SUPPLY CHAIN.
INTERNATIONAL REGULATIONS (NON-US):
CANADIAN DOMESTIC SUBSTANCE LIST (DSL):
ALL INGREDIENTS REMAINING IN THE FINISHED PRODUCT AS DISTRIBUTED INTO
COMMERCE ARE INCLUDED ON THE DOMESTIC SUBSTANCES LIST.
WHMIS CLASSIFICATIONS:
CLASS E: CORROSIVE MATERIALS PRESENT AT GREATER THAN 1 %.
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA
OF THE CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS ALL
THE INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
NPRI AND ONTARIO REGULATION 127/01:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS SUBJECT TO THE REPORTING
REQUIREMENTS OF CANADA NPRI +/OR ONT. REG. 127/01:
CHEMICAL CAS# %WT
LEAD 7439-92-1 67
SULFURIC ACID 7664-93-9 10
EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES (EINECS):
ALL INGREDIENTS REMAINING IN THE FINISHED PRODUCT AS DISTRIBUTED INTO
COMMERCE ARE EXEMPT FROM, OR INCLUDED ON, THE EUROPEAN INVENTORY OF
EXISTING COMMERCIAL CHEMICAL SUBSTANCES.
EUROPEAN COMMUNITIES (EC) HAZARD CLASSIFICATION ACCORDING TO DIRECTIVES
67/548/EEC AND 1999/45/EC:
R-PHRASES: 35 36 38
S-PHRASES: 1/2 26 30 45
ADDITIONAL INFORMATION:
THIS PRODUCT MAY BE SUBJECT TO RESTRICTION OF HAZARDOUS SUBSTANCES (ROHS)
REGULATIONS IN EUROPE AND CHINA, OR MAY BE REGULATED UNDER ADDITIONAL
REGULATIONS AND LAWS NOT IDENTIFIED ABOVE, SUCH AS FOR USES OTHER THAN
DESCRIBED OR AS DESIGNED / AS-INTENDED BY THE MANUFACTURER, OR FOR
DISTRIBUTION INTO SPECIFIC DOMESTIC DESTINATIONS.
| SECTION 16: OTHER INFORMATION | |
OTHER INFORMATION:
DISTRIBUTION INTO QUEBEC TO FOLLOW CANADIAN CONTROLLED PRODUCT REGULATIONS
(CPR) 24(1) AND 24(2). DISTRIBUTION INTO THE EU TO FOLLOW APPLICABLE
DIRECTIVES TO THE USE, IMPORT/EXPORT OF THE PRODUCT AS-SOLD.
SOURCES OF INFORMATION:
INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (1987), IARC MONOGRAPHS ON THE
EVALUATION OF CARCINOGENIC RISKS TO HUMANS:
OVERALL EVALUATIONS OF CARCINOGENICITY:
AN UPDATING OF IARC MONOGRAPHS VOLUMES 1-42, SUPPLEMENT 7, LYON, FRANCE.
ONTARIO MINISTRY OF LABOUR REGULATION 654/86. REGULATIONS RESPECTING
EXPOSURE TO CHEMICAL OR BIOLOGICAL AGENTS.
MSDS/SDS PREPARATION INFORMATION:
DATE OF ISSUE: JUNE 1, 2015 / SUPERSEDES ALL PREVIOUS VERSIONS
DISCLAIMER:
THIS SAFETY DATA SHEET IS BASED UPON INFORMATION AND SOURCES AVAILABLE AT
THE TIME OF PREPARATION OR REVISION DATE. THE INFORMATION IN THE MSDS WAS
OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE, BUT ARE BEYOND OUR
DIRECT SUPERVISION OR CONTROL. WE MAKE NO WARRANTY OF MERCHANTABILITY,
FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY, EXPRESSED OR
IMPLIED, WITH RESPECT TO SUCH INFORMATION, AND WE ASSUME NO LIABILITY
RESULTING FROM ITS USE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME
RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE
ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE, USE OF,
OR DISPOSAL OF THE PRODUCT. IT IS THE OBLIGATION OF EACH USER OF THE
PRODUCT TO DETERMINE THE SUITABILITY OF THIS PRODUCT AND COMPLY WITH THE
REQUIREMENTS OF ALL APPLICABLE LAWS REGARDING USE AND DISPOSAL OF THIS
PRODUCT. FOR ADDITIONAL INFORMATION CONCERNING DISCOVER ENERGY CORP.
PRODUCTS OR QUESTIONS CONCERNING THE CONTENT OF THIS MSDS, PLEASE CONTACT
YOUR DISCOVER REPRESENTATIVE.
INNOVATIVE POWER SOLUTIONS
DG1501141E
ENERGY STORAGE BATTERY(GEL) CNJ-1600
SDS
SAFETY DATA SHEET
ACCORDING TO GHS (FIFTH REVISED EDITION)
HUAFU HIGH TECHNOLOGY ENERGY STORAGE CO., LTD.
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: ENERGY STORAGE BATTERY(GEL) CNJ-1600
APPLICANT NAME: HUAFU HIGH TECHNOLOGY ENERGY STORAGE CO., LTD.
APPLICATION ADDRESS:
BATTERY INDUSTRIAL PARK OF GAOYOU CITY, GAOYOU ECONOMIC DEVELOPMENT
ZONE, YANGZHOU CITY, JIANGSU PROVINCE
CHINA
APPLICANT POST CODE: 225600
APPLICANT FAX: +86-514-84540807
APPLICANT EMERGENCY NUMBER: +86-514-84540807
APPLICANT EMAIL: YUEXIAMOYAN@SINA.COM
MANUFACTURER NAME: HUAFU HIGH TECHNOLOGY ENERGY STORAGE CO., LTD.
MANUFACTURER ADDRESS:
BATTERY INDUSTRIAL PARK OF GAOYOU CITY, GAOYOU ECONOMIC DEVELOPMENT
ZONE, YANGZHOU CITY, JIANGSU PROVINCE
CHINA
MANUFACTURER POST CODE: 225600
MANUFACTURER FAX: +86-514-84540807
MANUFACTURER EMERGENCY NUMBER: +86-514-84540807
SDS NUMBER: DG1501141E
EFFECTIVE DATE: FEB 03, 2015
| SECTION 2 - HAZARDS IDENTIFICATION | |
HAZARD CLASS AND LABEL ELEMENTS OF THE SUBSTANCE ACCORDING TO GHS
(THE FIFTH REVISED EDITION):
GHS HAZARD CLASS:
HEALTH HAZARD(S):
ACUTE TOXICITY, ORAL: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 1
GERM CELL MUTAGENICITY: CATEGORY 2
CARCINOGENICITY: CATEGORY 2
REPRODUCTIVE TOXICITY: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE: CATEGORY 1
ENVIRONMENTAL HAZARD(S):
HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD: CATEGORY 1
PICTOGRAM:
CORROSION
EXCLAMATION MARK
HEALTH HAZARD
ENVIRONMENT
SIGNAL: DANGER
HAZARD STATEMENT(S):
H302: HARMFUL IF SWALLOWED
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H341: SUSPECTED OF CAUSING GENETIC DEFECTS
H351: SUSPECTED OF CAUSING CANCER
H360: MAY DAMAGE FERTILITY OR THE UNBORN CHILD
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
PRECAUTIONARY STATEMENTS:
PREVENTION:
P260: DO NOT BREATHE DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P264: WASH THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
P301+P312 IF SWALLOWED: CALL A POISON CENTER/DOCTOR/IF YOU FEEL UNWELL.
P301+P330+P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER
[OR SHOWER].
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P310: IMMEDIATELY CALL A POISON CENTER/DOCTOR.
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
P330: RINSE MOUTH.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
P391: COLLECT SPILLAGE.
STORAGE:
P405: STORE LOCKED UP.
DISPOSAL:
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
COMPONENT CONCENTRATION(%) CAS NO. EC NO.
LEAD COMMERCIAL SECRETS 7439-92-1 231-100-4
SULFURIC ACID COMMERCIAL SECRETS 7664-93-9 231-639-5
POLYMER MICROPOROUS SEPARATOR COMMERCIAL SECRETS
BATTERY CASE COMMERCIAL SECRETS
| SECTION 4 - FIRST AID MEASURES | |
AFTER SKIN CONTACT:
TAKE OFF THE CONTAMINATED CLOTHING AND SHOES IMMEDIATELY. WASH OFF WITH
SOAP AND PLENTY OF WATER. CONSULT A PHYSICIAN.
AFTER EYE CONTACT:
RINSE THOROUGHLY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND CONSULT
A PHYSICIAN.
AFTER INGESTION:
DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. RINSE MOUTH WITH WATER. CONSULT A PHYSICIAN.
AFTER INHALATION:
IF BREATHED IN, MOVE PERSON INTO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. CONSULT A PHYSICIAN.
| SECTION 5 - FIRE FIGHTING MEASURES | |
HAZARDOUS PRODUCTS OF COMBUSTION: LEAD OXIDES, SULPHUR OXIDES
EXTINGUISHING METHOD:
USE WATER SPRAY, ALCOHOL-RESISTANT FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL PROTECTIVE EQUIPMENT:
WEAR SELF CONTAINED BREATHING APPARATUS FOR FIRE FIGHTING IF NECESSARY.
| SECTION 6 - ACCIDENTAL RELEASE MEASURE | |
PERSONAL PROTECTIVE MEASURES:
USE PERSONAL PROTECTIVE EQUIPMENT. ENSURE ADEQUATE VENTILATION. AVOID
BREATHING VAPORS, MIST OR GAS. EVACUATE PERSONNEL TO SAFE AREAS.
ENVIRONMENTAL PROTECTIVE MEASURES:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO. DO NOT LET PRODUCT
ENTER DRAINS.
METHODS FOR TAKING IN AND CLEANING UP:
SOAK UP WITH INERT ABSORBENT MATERIAL AND DISPOSE OF AS HAZARDOUS WASTE.
KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
| SECTION 7 - HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH SKIN AND EYES. AVOID INHALATION OF VAPOUR OR MIST.
STORAGE:
STORE IN COOL PLACE. KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND
WELL-VENTILATED PLACE.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
SAFETY SHOWER AND EYE BATH. MECHANICAL EXHAUST REQUIRED.
RESPIRATORY PROTECTION: USE A FULL-FACE SUPPLIED AIR RESPIRATOR.
EYE PROTECTION: WEAR CHEMICAL GOGGLES.
HAND PROTECTION: WEAR IMPERVIOUS CHEMICAL RESISTANT GLOVES.
BODY PROTECTION: PROTECTIVE WORK CLOTHING.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE AND PROPERTIES: 2V1600AH, GREY WHITE SHELL BATTERY
ODOR: NO DATA AVAILABLE
ODOR THRESHOLD: NO DATA AVAILABLE
PH VALUE: NO DATA AVAILABLE
INITIAL BOILING POINT AND BOILING RANGE (DEG. C): NO DATA AVAILABLE
MELTING POINT/FREEZING POINT (DEG. C): NO DATA AVAILABLE
FLASH POINT (DEG. C) (CLOSED CUP): NO DATA AVAILABLE
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY: NO DATA AVAILABLE
UPPER EXPLOSIVE LIMIT%(V/V): NO DATA AVAILABLE
LOWER EXPLOSIVE LIMIT%(V/V): NO DATA AVAILABLE
VAPOR PRESSURE(MPA): NO DATA AVAILABLE
VAPOR DENSITY(G/ML): NO DATA AVAILABLE
RELATIVE DENSITY(G/CM3): NO DATA AVAILABLE
SOLUBILITY: NO DATA AVAILABLE
OCTANOL / WATER PARTITION COEFFICIENT: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE (DEG. C): NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE(C): NO DATA AVAILABLE
KINEMATIC VISCOSITY (MM2/S): NO DATA AVAILABLE
| SECTION 10 - STABILITY AND REACTIVITY | |
REACTIVE: NO DATA AVAILABLE
CHEMICAL STABILITY: STABLE UNDER THE CONDITION RECOMMENDED.
POSSIBILITY OF HAZARDOUS REACTIONS: NO DATA AVAILABLE
AVOID CONDITIONS: HEAT, FLAMES AND SPARKS.
INCOMPATIBLE MATERIALS:
BASES, HALIDES, ORGANIC MATERIALS, CARBIDES, FULMINATES, NITRATES,
PICRATES, CYANIDES, CHLORATES, ALKALI
HAZARDOUS DECOMPOSITION PRODUCTS: NO DATA AVAILABLE
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
SULFURIC ACID:
LD50 (RAT, ORAL): 2140 MG/KG
LC50 (RAT, INHALATION, 2H): 0.51 MG/L
SKIN CORROSION/IRRITATION: CAUSE SERIOUS SKIN BURNS
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSE SERIOUS EYE DAMAGE
RESPIRATORY OR SKIN SENSITIZATION: NO DATA AVAILABLE
GERM CELL MUTAGENICITY: NO DATA AVAILABLE
CARCINOGENICITY:
LEAD (CAS NO. 7439-92-1): GROUP 2B POSSIBLY CARCINOGENIC TO HUMANS
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NO DATA AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NO DATA AVAILABLE
ASPIRATION HAZARD: NO DATA AVAILABLE
| SECTION 12 - ECOLOGICAL INFORMATION | |
TOXICITY: NO DATA AVAILABLE
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE
MOBILITY IN SOIL: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS:
VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
PROPERTY OF WASTE: NO DATA AVAILABLE.
METHODS OF DISPOSAL:
DISPOSAL OF THE FORMER SHOULD REFER TO THE RELEVANT NATIONAL AND LOCAL
LAWS AND REGULATIONS.
RECOMMENDED BY PROFESSIONAL RECYCLING COMPANY.
PRECAUTIONS OF DISPOSAL:
OPERATORS MUST HAVE RECEIVED SPECIALIZED TRAINING IN EXPLOSIVE NATURE
DISPOSAL.
| SECTION 14 - TRANSPORT INFORMATION | |
UN NUMBER: 2794
UN PROPER SHIPPING NAME:
BATTERIES, WET, FILLED WITH ACID, ELECTRIC STORAGE
TRANSPORTATION PRIMARY HAZARD CLASS: 8
TRANSPORTATION SECONDARY HAZARD CLASS:
PACKING GROUP:
| SECTION 15 - REGULATORY INFORMATION | |
COMPONENT CHINA TSCA ENCS EINECS
LEAD $ $ $ $
SULFURIC ACID $ $ $ $
POLYMER MICROPOROUS SEPARATOR - - - -
BATTERY CASE - - - -
NOTE 1:
CHINA: CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES (IECSC)
TSCA:
UNITED STATES INVENTORY OF TOXIC SUBSTANCES CONTROL ACT CHEMICAL SUBSTANCES
(TSCA)
ENCS: JAPAN EXISTING AND NEW CHEMICAL SUBSTANCES (ENCS)
EINECS:
EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES (EINECS)
NOTE 2:
"$" INDICATES THAT THE SUBSTANCE INCLUDED IN THE REGULATIONS
"-" THAT NO DATA OR INCLUDED IN THE REGULATIONS
| SECTION 16 - ADDITIONAL INFORMATION | |
PREPARED BY:
CHANGZHOU TESTING CENTER OF ENTRY. EXIT INDUSTRIAL AND CONSUMABLE PRODUCTS
COMPLETION DATE: FEB 03, 2015
MODIFICATION STATEMENT:
ORIGINAL. PLEASE UPDATE BEFORE THE IMPLEMENTATION OF THE GHS SIXTH REVISED
EDITION.
OTHER INFORMATION:
THIS SAFETY DATA SHEET (SDS) WAS PREPARED ACCORDING TO UN GHS (THE FIFTH
REVISED EDITION) AND THE INFORMATION INCLUDED IS BASED ON THE PRESENT
STATE OF OUR KNOWLEDGE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY
WARRANTY, EXPRESS OR IMPLIED, REGARDING ITS CORRECTNESS AND IS ONLY FOR
USERS REFERENCE. USERS SHOULD MAKE THEIR INDEPENDENT JUDGEMENT OF
SUITABILITY OF THESE INFORMATION FOR THEIR PARTICULAR PURPOSES. WE DO NOT
ASSUME RESPONSIBILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY
WAY CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT.
SINOPEC
SAFETY DATA SHEET
ACCORDING TO SS586:2014
L-HM 46 ANTI-WEAR HYDRAULIC OIL
VERSION: 1.0
ISSUE DATE: 03/02/2015
REVISION DATE: 03/02/2015
SDS RECORD NUMBER: CSSS-TCO-010-116188
| SECTION 1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE | |
AND OF THE COMPANY/UNDERTAKING
PRODUCT IDENTIFIER:
IDENTIFICATION ON THE LABEL/TRADE NAME: L-HM 46 ANTI-WEAR HYDRAULIC OIL
ADDITIONAL IDENTIFICATION: NOT AVAILABLE
IDENTIFICATION OF THE PRODUCT: SEE SECTION 3
INDEX NUMBER: NOT AVAILABLE
REACH REGISTRATION NO.: NOT AVAILABLE
RELEVANT IDENTIFIED USES OF THE SUBSTANCE AND USES ADVISED AGAINST:
IDENTIFIED USES:
SUITABLE FOR HIGH PRESSURE HYDRAULIC SYSTEMS, HYDRAULIC SYSTEM OF MOBILE
EQUIPMENT AND INDUSTRIAL EQUIPMENT, SUCH AS SHIPPING, MOBILE TYPE MACHINERY
AND SO ON.
USES ADVISED AGAINST: NOT AVAILABLE.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER (MANUFACTURER): SINOPEC LUBRICANT CO., LTD.
ADDRESS:
NO. 6 ANNING ZHUANG WEST ROAD
HAIDIAN DISTRICT, BEIJING, PR.
CHINA
CONTACT PERSON(E-MAIL): CSC.LUBE@SINOPEC.COM
TELEPHONE: 86-400-810-9886
FAX: 86-10-82410856
EMERGENCY TELEPHONE NUMBER:
86-400-810-9886 ONLY AVAILABLE DURING OFFICE HOURS (8:30A.M.-17:30P.M.
BEIJING TIME ZONE)
AVAILABLE OUTSIDE OFFICE HOURS?:
YES ( )
NO (X)
| SECTION 2 HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE/MIXTURE:
GHS CLASSIFICATION: NOT CLASSIFIED
LABEL ELEMENTS:
HAZARD PICTOGRAMS: NO HAZARD PICTOGRAM IS USED.
SIGNAL WORD(S): NO SIGNAL WORD IS USED.
HAZARD STATEMENT: NOT APPLICABLE.
PRECAUTIONARY STATEMENT: NOT APPLICABLE.
OTHER HAZARDS: NOT AVAILABLE.
| SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
INGREDIENT(S):
CHEMICAL NAME REGISTRATION CAS NO. EC NO. CONCENTRATION
NO.
HIGHLY REFINED N/A 64742-65-0 265-169-7 90-99%
MINERAL OIL
PHOSPHORODITHIOIC N/A 68649-42-3 272-028-3 0.3-06%
ACID, O,O-DI-C1-
14-ALKYL ESTERS,
ZINC SALTS
| SECTION 4 FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
IN ALL CASES OF DOUBT, OR WHEN SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION.
IN CASE OF INHALATION:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. IF EXPOSED TO EXCESSIVE LEVELS
OF MATERIAL IN THE AIR, MOVE THE EXPOSED PERSON TO FRESH AIR. GET MEDICAL
ATTENTION IF COUGHING OR RESPIRATORY DISCOMFORT OCCURS.
IN CASE OF SKIN CONTACT:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. AS A PRECAUTION, REMOVE
CLOTHING AND SHOES IF CONTAMINATED. TO REMOVE THE MATERIAL FROM SKIN, USE
SOAP AND WATER. DISCARD CONTAMINATED CLOTHING AND SHOES OR THOROUGHLY CLEAN
BEFORE REUSE.
IN CASE OF EYES CONTACT:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. AS A PRECAUTION, REMOVE
CONTACT LENSES, IF WORN, AND FLUSH EYES WITH WATER.
IN CASE OF INGESTION:
NO SPECIFIC FIRST AID MEASURES ARE REQUIRED. DO NOT INDUCE VOMITING. AS A
PRECAUTION, GET MEDICAL ADVICE.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
THE PRODUCT IS NOT CLASSIFIED AS HARMFUL TO HUMAN HEALTH EFFECT.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
IF SKIN IRRITATION OR RASH OCCURS, GET MEDICAL ADVICE/ATTENTION.
| SECTION 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE WATER FOG, FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH FLAMES.
UNSUITABLE EXTINGUISHING MEDIA: WATER.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
IN CASE OF HEAT, FIRE AND STRONG OXIDANTS CAN LEAD TO BURNING. FUMES,
SMOKE, CARBON MONOXIDE, SULFUR OXIDES, ALDEHYDES, NITROGEN OXIDES,
PHOSPHATE, CERTAIN METAL OXIDES AND OTHER DECOMPOSITION PRODUCTS, IN
THE CASE OF INCOMPLETE COMBUSTION.
SPECIAL FIRE FIGHTING METHODS AND SPECIAL PROTECTIVE ACTIONS FOR
FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
PROVIDE ADEQUATE VENTILATION. AVOID SKIN AND EYE CONTACT. REFER TO
SECTION 8 OF SDS FOR PERSONAL PROTECTION DETAILS.
FOR EMERGENCY RESPONDERS:
WEAR AN APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR IF DUST IS GENERATED.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW MATERIAL TO BE RELEASED TO THE ENVIRONMENT WITHOUT PROPER
GOVERNMENTAL PERMITS.
METHODS FOR CONTAINMENT AND CLEANING UP:
STOP THE SOURCE OF THE RELEASE IF YOU CAN DO IT WITHOUT RISK. CONTAIN
RELEASE TO PREVENT FURTHER CONTAMINATION OF SOIL, SURFACE WATER OR
GROUNDWATER. CLEAN UP SPILL AS SOON AS POSSIBLE, OBSERVING PRECAUTIONS IN
EXPOSURE CONTROLS/PERSONAL PROTECTION. USE APPROPRIATE TECHNIQUES SUCH AS
APPLYING NON-COMBUSTIBLE ABSORBENT MATERIALS OR PUMPING. WHERE FEASIBLE
AND APPROPRIATE, REMOVE CONTAMINATED SOIL. PLACE CONTAMINATED MATERIALS
IN DISPOSABLE CONTAINERS AND DISPOSE OF IN A MANNER CONSISTENT WITH
APPLICABLE REGULATIONS.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR INFORMATION ON DISPOSAL.
ADDITIONAL INFORMATION: NOT APPLICABLE.
| SECTION 7 HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, MAY CONTAIN EXPLOSIVE
VAPOURS. DO NOT CUT, DRILL, GRIND, WELD OR PERFORM SIMILAR OPERATIONS
ON OR NEAR CONTAINERS. ELECTROSTATIC DISCHARGE MAY BE GENERATED DURING
PUMPING - THIS MAY RESULT IN FIRE. ENSURE ELECTRICAL CONTINUITY BY BONDING
AND GROUNDING (EARTHING) ALL EQUIPMENT.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
DO NOT EAT, DRINK AND SMOKE IN WORK AREAS. WASH HANDS AFTER USE. REMOVE
CONTAMINATED CLOTHING AND PROTECTIVE EQUIPMENT BEFORE ENTERING EATING
AREAS.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
DO NOT STORE IN OPEN OR UNLABELED CONTAINERS. STORE IN A COOL, DRY
PLACE WITH ADEQUATE VENTILATION. KEEP AWAY FROM OPEN FLAMES AND HIGH
TEMPERATURES.
SPECIFIC END USE(S): NOT APPLICABLE.
| SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS (OEL):
INGREDIENT DATA:
SOURCE INGREDIENT MATERIAL TWA STEL PEAK NOTES
NAME
US ACGIH HIGHLY MINERAL OIL, 5 MG/M3 NOT NOT TLV(R*)
THRESHOLD REFINED EXCLUDING AVAILABLE AVAILABLE BASIS:
LIMIT MINERAL METAL URT IRR
VALUES OIL WORKING
(TLV) FLUIDS -
PURE,
HIGHLY AND
SEVERELY
REFINED /
MINERAL OIL,
EXCLUDING
METAL
WORKING
FLUIDS -
POORLY AND
MILDLY
REFINED
EMERGENCY LIMITS:
INGREDIENT MATERIAL NAME TEEL-1 TEEL-2 TEEL-3
HIGHLY REFINED PUMP OIL 15 MG/M3 170 MG/M3 990 MG/M3
MINERAL OIL
INGREDIENT ORIGINAL IDLH REVISED IDLH
HIGHLY REFINED MINERAL OIL NOT AVAILABLE NOT AVAILABLE
PHOSPHORODITHIOIC ACID, NOT AVAILABLE NOT AVAILABLE
O,O-DI-C1-14-ALKYL ESTERS, ZINC SALTS
EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION TO CONTROL AIRBORNE CONCENTRATIONS BELOW THE
EXPOSURE GUIDELINES/LIMITS.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
NO SPECIAL EYE PROTECTION IS NORMALLY REQUIRED. WHERE SPLASHING IS
POSSIBLE, WEAR SAFETY GLASSES WITH SIDE SHIELDS AS A GOOD SAFETY PRACTICE.
HAND PROTECTION:
USE PROTECTIVE GLOVES WHICH IS CHEMICALLY RESISTANT TO THIS MATERIAL.
BODY PROTECTION:
NO SPECIAL PROTECTIVE CLOTHING IS NORMALLY REQUIRED. WHERE SPLASHING IS
POSSIBLE, SELECT PROTECTIVE CLOTHING DEPENDING ON OPERATIONS CONDUCTED,
PHYSICAL REQUIREMENTS AND OTHER SUBSTANCES IN THE WORKPLACE.
SUGGESTED MATERIALS FOR PROTECTIVE GLOVES INCLUDE:
NEOPRENE, NITRILE RUBBER.
RESPIRATORY PROTECTION:
NO RESPIRATORY PROTECTION IS NORMALLY REQUIRED. NO RESPIRATORY PROTECTION
IS ORDINARILY REQUIRED UNDER NORMAL CONDITIONS OF USE. IN ACCORDANCE WITH
GOOD INDUSTRIAL HYGIENE PRACTICES, PRECAUTIONS SHOULD BE TAKEN TO AVOID
BREATHING OF MATERIAL. IF USER OPERATIONS GENERATE AN OIL MIST, DETERMINE
IF AIRBORNE CONCENTRATIONS ARE BELOW THE OCCUPATIONAL EXPOSURE LIMIT FOR
MINERAL OIL MIST. IF NOT, WEAR AN APPROVED RESPIRATOR THAT PROVIDES
ADEQUATE PROTECTION FROM THE MEASURED CONCENTRATIONS OF THIS MATERIAL.
FOR AIR-PURIFYING RESPIRATORS USE A PARTICULATE CARTRIDGE. USE A POSITIVE
PRESSURE AIR-SUPPLYING RESPIRATOR IN CIRCUMSTANCES WHERE AIR-PURIFYING
RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION.
THERMAL HAZARDS: WEAR SUITABLE PROTECTIVE CLOTHING TO PREVENT HEAT.
ENVIRONMENTAL EXPOSURE CONTROLS:
AVOID DISCHARGE INTO THE ENVIRONMENT.
ACCORDING TO LOCAL REGULATIONS, FEDERAL AND OFFICIAL REGULATIONS.
| SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: YELLOW TO BROWN TRANSPARENT OILY LIQUID
COLOUR: YELLOW TO BROWN
ODOUR: ODORLESS OR SLIGHT ODOR
ODOUR THRESHOLD: NOT AVAILABLE
PH: NOT AVAILABLE
MELTING POINT/RANGE (DEG. C): NOT AVAILABLE
BOILING POINT/RANGE (DEG. C): >280 DEG. C (TYP)
FLASH POINT (DEG. C): 220 DEG. C (OPEN CUP) (TYP)
EVAPORATION RATE: NOT AVAILABLE
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE
IGNITION TEMPERATURE (DEG. C): NOT AVAILABLE
UPPER/LOWER FLAMMABILITY/EXPLOSIVE LIMITS: NOT AVAILABLE
VAPOUR PRESSURE (40 DEG. C): <0.5PA (20 DEG. C)
VAPOUR DENSITY: >1 (AIR=1)
DENSITY: 0.84 KG/L - 0.93 KG/L (20 DEG. C)
BULK DENSITY (KG/M3): NOT AVAILABLE
WATER SOLUBILITY (G/L): INSOLUBLE
N-OCTANOL/WATER (LOG PO/W): >6 (ESTIMATED VALUE)
AUTO-IGNITION TEMPERATURE: >320 DEG. C
DECOMPOSITION TEMPERATURE: NOT AVAILABLE
VISCOSITY: 41.4MM/S2-50.6MM/S2 (40 DEG. C)
EXPLOSIVE PROPERTIES: NON EXPLOSIVE
OXIDISING PROPERTIES: NOT OXIDIZING
MOLECULAR FORMULA: NOT AVAILABLE
MOLECULAR WEIGHT: NOT AVAILABLE
OTHER INFORMATION:
FAT SOLUBILITY(SOLVENT-OIL TO BE SPECIFIED) ETC: NOT AVAILABLE
SURFACE TENSION: NOT AVAILABLE
DISSOCIATION CONSTANT IN WATER(PKA): NOT AVAILABLE
OXIDATION-REDUCTION POTENTIAL: NOT AVAILABLE
SPECIFIC GRAVITY: NOT AVAILABLE
| SECTION 10 STABILITY AND REACTIVITY | |
REACTIVITY:
THE SUBSTANCE IS STABLE UNDER NORMAL STORAGE AND HANDLING CONDITIONS.
CHEMICAL STABILITY:
STABLE AT ROOM TEMPERATURE IN CLOSED CONTAINERS UNDER NORMAL STORAGE AND
HANDLING CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
CONTACT WITH STRONG OXIDANTS CAN LEAD TO BURNING.
CONDITIONS TO AVOID:
EXTREME HEAT AND HIGH ENERGY SOURCES OF IGNITION AND STRONG OXIDIZERS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
FUMES, SMOKE, CARBON MONOXIDE, SULFUR OXIDES, ALDEHYDES, NITROGEN OXIDES,
PHOSPHATE, CERTAIN METAL OXIDES AND OTHER DECOMPOSITION PRODUCTS, IN THE
CASE OF INCOMPLETE COMBUSTION.
| SECTION 11 TOXICOLOGICAL INFORMATION | |
TOXICOKINETICS, METABOLISM AND DISTRIBUTION:
NON-HUMAN TOXIKOLOGICAL DATA: NOT AVAILABLE
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD50 (ORAL, RAT): >5000 MG/KG BW
LD50 (DERMAL, RABBIT): >5000 MG/KG BW
LC50 (INHALATION, RAT): >10000 MG/M3 BW
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
STOT-SINGLE EXPOSURE: NOT CLASSIFIED
STOT-REPEATED EXPOSURE: NOT CLASSIFIED
| SECTION 12 ECOLOGICAL INFORMATION | |
TOXICITY:
HIGHLY REFINED MINERAL OIL (CAS: 64742-65-0):
ACUTE TOXICITY TIME SPECIES METHOD EVALUATION REMARKS
LL50: >100 MG/L 96H FISH OECD 203 N/A N/A
LL50: >10000 MG/L 48H DAPHNIA OECD 202 N/A N/A
EC50: N/A 72H ALGAE OECD 201 N/A N/A
PERSISTENCE AND DEGRADABILITY:
THIS PRODUCT IS EXPECTED TO BE INHERENTLY BIODEGRADABLE.
BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATION IS UNLIKELY DUE TO THE VERY LOW WATER SOLUBILITY OF THIS
PRODUCT; THEREFORE BIOAVAILABILITY TO AQUATIC ORGANISMS IS MINIMAL.
MOBILITY IN SOIL:
WHEN RELEASED INTO THE ENVIRONMENT, ADSORPTION TO SEDIMENT AND SOIL WILL
BE THE PREDOMINANT BEHAVIOR.
RESULTS OF PBT & VPVB ASSESSMENT: NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NOT AVAILABLE.
| SECTION 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
THE MATERIAL SHOULD BE DISPOSED OF BY INCINERATION IN A CHEMICAL
INCINERATOR IN COMPLIANCE WITH NATIONAL AND REGIONAL REQUIREMENTS.
PRODUCT / PACKAGING DISPOSAL:
IF EMPTY CONTAINER RETAINS PRODUCT RESIDUES, ALL LABEL PRECAUTIONS MUST
BE OBSERVED.
RETURN FOR REUSE OR DISPOSE ACCORDING TO NATIONAL OR LOCAL REGULATIONS.
| SECTION 14 TRANSPORT INFORMATION | |
LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT
(ADR/RID) (IMDG) (ICAO/IATA)
UN-NUMBER NOT REGULATED NOT REGULATED NOT REGULATED
UN PROPER SHIPPING NOT REGULATED NOT REGULATED NOT REGULATED
NAME
TRANSPORT HAZARD NOT REGULATED NOT REGULATED NOT REGULATED
CLASS
PACKAGING GROUP NOT REGULATED NOT REGULATED NOT REGULATED
ENVIRONMENTAL HAZARDS NO NO NO
SPECIAL PRECAUTIONS SEE SECTION 2.2 SEE SECTION 2.2 SEE SECTION 2.2
FOR USER
TRANSPORT IN BULK NOT REGULATED NOT REGULATED NOT REGULATED
ACCORDING TO ANNEX II
OF MARPOL 73/78 AND
THE IBC CODE
| SECTION 15 REGULATION INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
HIGHLY REFINED MINERAL OIL (64742-65-0) IS FOUND ON THE FOLLOWING
REGULATORY LISTS: "NOT APPLICABLE"
PHOSPHORODITHIOIC ACID, O,O-DI-C1-14-ALKYL ESTERS, ZINC SALTS (68649-42-3)
IS FOUND ON THE FOLLOWING REGULATORY LISTS: "NOT APPLICABLE"
| SECTION 16 OTHER INFORMATION | |
FURTHER INFORMATION:
THIS INFORMATION IS BASED UPON THE PRESENT STATE OF OUR KNOWLEDGE.
THIS SDS HAS BEEN COMPILED AND IS SOLELY INTENDED FOR THIS PRODUCT.
NOTICE TO READER:
EMPLOYERS SHOULD USE THIS INFORMATION ONLY AS A SUPPLEMENT TO OTHER
INFORMATION GATHERED BY THEM, AND SHOULD MAKE INDEPENDENT JUDGMENT OF
SUITABILITY OF THIS INFORMATION TO ENSURE PROPER USE AND PROTECT THE
HEALTH AND SAFETY OF EMPLOYEES. THIS INFORMATION IS FURNISHED WITHOUT
WARRANTY, AND ANY USE OF THE PRODUCT NOT IN CONFORMANCE WITH THIS SAFETY
DATA SHEET, OR IN COMBINATION WITH ANY OTHER PRODUCT OR PROCESS, IS THE
RESPONSIBILITY OF THE USER.
AUTHOR: HANGZHOU CIRS CO., LIMITED
WEBSITE: WWW.CIRS-GROUP.COM
TEL: 0571-87206555
EMAIL: INFO@CIRS-GROUP.COM
PRODUCT NAME: L-HM 46 ANTI-WEAR HYDRAULIC OIL
VERSION #: 1.0
SDS SG
N
NIPPON PAINT
NIPPON PAINT
NIPPON PAINT (CHINA) CO., LTD.
SAFETY DATA SHEET (SDS)
SDS CODE: NP-SDS-GIU-GIC-30FML-0030
VERSION: 0.0
(E) EFFECTIVE DATE: NOV. 1ST., 2011
PRODUCT NAME: PC 2000 TOP COATING
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: PC 2000 TOP COATING
MANUFACTURE: NIPPON PAINT (CHINA) CO., LTD.
ADDRESS:
NO. 287 CHUANG YE ROAD
JIN QIAO DEVELOPMENT ZONE
NEW PUDONG DISTRICT
SHANGHAI 201201 P. R.
CHINA
TEL.: 86021-58384799 (T)
FAX: 86021-58382599 (F)
NATION EMERGENCY TELEPHONE NUMBER: (86) 532-83889090
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION CODE:
FLAMMABLE LIQUID: CATEGORY 3
ACUTE TOXIDITY (INHALATION) (DUST, MIST): CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 3
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
CARSINOGENICITY: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY FOLLOWING SINGLE EXPOSURE:
CATEGORY 1, CATEGORY 2
ACUTE HAZARDS TO THE AQUATIC INVIRONMENT: CATEGORY 3
CHRONIC HAZARDS TO THE AQUATIC INVIRONMENT: CATEGORY 3
SYMBOL:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL: DANGER
HAZARD STATEMENT:
H226: FLAMMABLE LIQUID AND VAPOUR
H332: HARMFUL IF INHALED
H316: CAUSES MILD SKIN IRRITATION
H319: CAUSES SERIOUS EYE DAMAGE
H351: SUSPECTED OF CAUSING CANCER
H370: CAUSES DAMAGE TO ORGANS
H402: HARMFUL TO AQUATIC LIFE
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECT
PRECAUTIONARY STATEMENTS (PREVENTIVE):
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACE.-NO SMOKING
P233: KEEP CONTAINER TIGHTLY CLOSED
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOL.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P264: WASH HANDS AND MOUTH THOROUGHLY AFTER HANDLING.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P273: AVOID RELEASE TO THE ENVIRONMENT, IF THIS IS NOT THE INTENDED USE.
P272:
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
PRECAUTIONARY STATEMENTS (RESPOND):
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING RINSE SKIN WITH
WATER/SHOWER.
P309+P312:
IF EXPOSED OR IF YOU FEEL UNWELL:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P302+P350:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P321: SPECIFIC TREATMENT (SEE ON THIS LABEL).
P333+P315:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P361+P363: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
P305+P351:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES
IF PRESENT AND EASY TO DO, CONTINUE RINSING.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
PRECAUTIONARY STATEMENTS (SAFETY STORAGE):
P403+P215: STORE IN A WELL-VENTILATED PLACE..
P405: STORE LOCKED UP AWAY FROM CHILDREN.
PRECAUTIONARY STATEMENTS (REJECT DISPOSE):
P501: ACCORDING THE REGULATION TO DISPOSE OF CONTENTS AND CONTAINERS.
| 3. COMPOSITION/INFORMATION ON INGREDIENT | |
INGREDIENT CAS NO CONCENTRATION (%)
HYDROXYLATED ACRYLIC RESIN PROPRIETARY 50-55
PARTICULAR ACRYLIC RESIN PROPRIETARY 3-5
INORGANIC PIGMENT PROPRIETARY 25-30
(TITANIUM DIOXIDE ETC.)
ORGANIC COLOUR PIGMENTS PROPRIETARY 4-7
(CARBON BLACK ETC.)
S-100 SOLVENT 64742-95-6 0-0.5
TOLUENE 108-8-3 3-5
XYLENE 1330-20-7 1-3
ETHYL ACETATE 141-78-6 3-5
BUTYL ACETATE (N-BUTYL ACETATE) 123-86-4 3-5
OTHER PIGMENT PROPRIETARY 0.1-1
| 4. FIRST-AID MEASURES | |
SKIN CONTACT:
IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES WHILE REMOVING CONTAMINATION CLOTHING AND SHOES.
EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES. IF EASY TO DO, REMOVE CONTACT LENSES, IF WORN. GET
MEDICAL ATTENTION IMMEDIATELY.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESUSCITATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL
ATTENTION IMMEDIATELY.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
COMBUSTIBILITY: FLAMMABILITY
SUITABLE FIRE-EXTINGUISHING MEDIUM: CO2, FOAM, DRY CHEMICALS, DRY SAND.
DECOMPOSITION PRODUCTS: CO, CO2
NOTICE:
(1) AVOID ALL SOURCES OF IGNITION ALL AROUND.
(2) WEAR PROTECTIVE CLOTHING AND SELF-CONTAINED BREATHING APPARATUS WHEN
DEALING WITH SPILLAGE OR FIRE.
(3) USING THE WATER FOG TO LET CONTAINERS COOLING.
| 6. ACCIDENTAL RELEASE MEASURES | |
VENTILATE THE AREA AND AVOID BREATHING VAPOR. COLLECT SPILLAGE, WHERE
PRACTICABLE, FOR SAFE DISPOSAL. SHOULD BE DISPOSED WASTES AND EMPTY
CONTAINERS IN ACCORDANCE WITH REGULATIONS MADE UNDER THE CONTROL OF
POLLUTION ACTS AND THE ENVIRONMENTAL PROTECTION ACTS. COLLECT SPILLAGE,
WHERE POSSIBLE, USING ABSORBENT MATERIAL, AND DISPOSE SPILLAGE ON THE FLOOR
IN A SAFE MANNER. DO NOT ALLOW SPILLS TOENTER DRAINS OR WATER COURSES.
| 7. HANDLING AND STORAGE | |
HANDING:
KEEP AWAY FROM HEAT, SPARKS, AND FLAME.
KEEP CONTAINERS CLOSED AND THE STORAGE DRAFTY.
THE PRODUCT MAY CHARGE ELECTRO STATICALLY.
OPERATORS SHOULD WEAR CLOTHING DOES NOT GENERATE STATIC (AT LEAST 60%
NATURAL FIBER) AND ANTISTATIC FOOD WEAR.
DO NOT BREATHE (DUST, VAPOR, MIST, GAS).
USE ONLY WITH VENTILATION.
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN.
WASH THOROUGHLY AFTER HANDING.
PROTECTION IS AS SHOWN IN SECTION 8.
STORAGE:
KEEP CONTAINER CLOSED.
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN AND INHALATION.
KEEP AWAY FROM HEAT, SPARKS AND FLAME.
BE STORED IN A WELL-VENTILATED, DRY PLACE AWAY FROM SOURCE OF HEAT AND
DIRECT SUNSHINE.
DO NOT STORE ABOVE 40 DEG. C. (104 DEG. F.)
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS (GBZ2-2002):
XYLENE:
CHINA:
TWA: 50 MG/M3
STEL: 100 MG/M3
TOLUENE:
CHINA:
TWA: 50 MG/M3
STEL: 100 MG/M3
MIBK:
CHINA:
TWA: 50 MG/M3
STEL: 75 MG/M3
N-BUTYL ACETATE:
CHINA:
TWA: 200 MG/M3
STEL: 300 MG/M3
PMA: NO DATA
S-100: NO DATA
ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION. KEEP CONTAINERS CLOSED WHEN NOT USING.
RESPIRATORY PROTECTION: WEAR RESPIRATOR WHEN CONTACT...
EYE PROTECTION:
WEAR CHEMICAL SPLASH GOGGLES AND FACE SHIELD WHEN EYE AND FACE CONTACT IS
POSSIBLE DUE TO SPLASHING OR SPRAYING OF MATERIAL.
SKIN PROTECTION:
WEAR CHEMICAL RESISTANT CLOTHING SUCH AS GLOVES, APRON, BOOTS OR WHOLE
BODY SUITS MADE FROM NEOPRENE, AS APPROPRIATE.
HAND PROTECTION: WEAR IMPERVIOUS GLOVES.
PHYSICAL EXAMINATION IS NEEDED PERIODIC.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: COLORFUL
ODOR: SOLVENT ODOR
PH: NO DATA
BOILING POINT (RANGE): NO DATA
FLASH POINT: 22 (DEG. C)
IGNITION TEMPERATURE: NO DATA
LOWER EXPLOSIVE LIMIT: NO DATA
HIGHER EXPLOSIVE LIMIT: NO DATA
VAPOR PRESSURE: NO DATA
SPECIFIC DENSITY: 1.150 +/- 0.05G/CM3 (20 DEG. C)
VAPOR DENSITY: THE VAPOR AND GAS ARE HEAVIER THAN WATER
SOLUBILITY IN WATER: NONE OR POOR IN WATER
PERCENTAGE VOLATILE: NO DATA
| 10. STABILITY AND REACTIVITY | |
STABILITY:
STABLE UNDER RECOMMENDED STORAGE AND HANDING CONDITIONS. WHEN EXPOSED TO
HIGH TEMPERATURE, MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS SUCH AS
CARBON DIOXIDE, OXIDES OF NITROGEN AND SMOKE.
HAZARDOUS REACTION: HAZARDOUS REACTION WILL NOT OCCUR.
CONDITION TO AVOID:
KEEP AWAY FROM OXIDIZING AGENTS, STRONGLY ALKALINE AND STRONGLY ACID
MATERIAL IN ORDER TO AVOID POSSIBLE EXOTHERMIC REACTIONS.
HAZARDOUS DECOMPOSITION PRODUCTS:
THE PRODUCTS DECOMPOSED ON HEATING PRODUCING THEIR OXIDE OR MONOMERS.
THERE ARE NO DATA AVAILABLE ON THE PRODUCT ITSELF.
| 11. TOXICOLOGICAL INFORMATION | |
XYLENE:
MOUSE INGESTION LD50: 4300 MG/KG
RABBIT INHALATION LD50: >1700 MG/KG
MIBK:
MOUSE INGESTION LD50: 2080 MG/KG
RABBIT INHALATION LD50: >5990 MG/KG
TOLUENE:
MOUSE INGESTION LD50: 5000 MG/KG
RABBIT INHALATION LD50: >12124 MG/KG
N-BUTYL ACETATE:
MOUSE INGESTION LD50: 13100 MG/KG
RABBIT INHALATION LD50: >500 MG/KG
PMA:
MOUSE INGESTION LD50: 8532 MG/KG
RABBIT INHALATION LD50: >5000 MG/KG
S-100:
MOUSE INGESTION LD50: 5000 MG/KG
RABBIT INHALATION LD50: >2000 MG/KG
SKIN STIMULATE: NO DATA
EYE STIMULATE: NO DATA
SKIN STIMULATE: NO DATA
REPRODUCTIVE TOXICITY: NO DATA
SPECIFIC TARGET ORGAN TOXICITY FOLLOWING SINGLE EXPOSURE: NO DATA
SPECIFIC TARGET ORGAN TOXICITY FOLLOWING REPEATED EXPOSURE: NO DATA
INHALATION HARMFUL: NO DATA
| 12. ECOLOGICAL INFORMATION | |
FOR SPILLS OR WASTE, TAKE CARE TO AVOID CONTAMINATING ENVIRONMENT.
PREVENT SPILL FROM ENTERING SEWERS, WATER COURSES OR LAW AREAS TO AVOID
POLLUTION.
THERE ARE NO DATA AVAILABLE ON THE PRODUCT ITSELF.
| 13. DISPOSAL CONSIDERATIONS | |
THE PRODUCT SHOULD NOT BE ALLOWED TO INTER DRAINS AND WATERCOURSE...
ALL NOTIFICATION, CLEAN-UP AND DISPOSAL SHOULD BE CARRIED OUT IN ACCORDANCE
WITH FEDERAL, STATE AND LOCAL REGULATIONS.
PREFERRED METHOD OF WASTE DISPOSAL IS INCINERATION OR BIOLOGICAL TREATMENT
IN FEDERAL/STATE APPROVED FACILITY.
WASTES AND EMPTY CONTAINERS SHOULD BE DISPOSED OF IN ACCORDANCE WITH
REGULATIONS MADE UNDER THE CONTROL OF POLLUTION ACTS AND THE ENVIRONMENTAL
PROTECTION ACTS.
EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED
WASTE MANAGEMENT FACILITY.
IT IS STRONGLY ADVISED NOT TO LET THE CHEMICAL ENTER INTO THE ENVIRONMENT.
| 14. TRANSPORT INFORMATION | |
UN REGULATION:
UN SHIPPING NAME:
PAINT (INCLUDING PAINT, ENAMEL, STAIN, SHELLAC, VARNISH, POLISH, LIQUID
FILLER) OR PAINT RELATED MATERIAL (INCLUDING PAINT THINNING OR REDUCING
COMPOUND)
UN IDENTIFICATION NUMBER: 1263
UN CLASS: CLASS 3 FLAMMABLE LIQUIDS
UN PACKING GROUP: II
IMDG CLASS: CLASS 3.2 INTERMEDIATE FLASHPOINT GROUP
STORAGE TEMPERATURE: STORE BELLOW 40 DEG. C. (104 DEG. F.).
| 15. STATUTE INFORMATION | |
1. STATE FATALNESS CHEMICALS PROTECTION: NO. 344
2. GB 12268-2005 FATALNESS PRODUCT LISTING
3. GB/T 16483-2008 SAFETY DATA SHEET FOR CHEMICAL PRODUCTS-CONTENT AND
ORDER OF SECTIONS.
4. GB 15258-2009 GENERAL RULES FOR PREPARATION OF PRECAUTIONARY LABEL FOR
CHEMICALS
5. GB 13690-2009 THE RULES OF FATALNESS CLASSIFY
6. GB/T 22234-2008 LABEL OF CHEMICALS BASED ON GHS.
| 16. OTHER INFORMATION | |
THE INFORMATION PROVIDED IN THIS SDS ONLY PERTAINS TO THE USAGE OF THIS
PRODUCT UNDER NORMAL CONDITION AND FOR USE AS A SAFETY MEASURE AT WORK.
IT DOES NOT CONSTITUTE ANY PRODUCT STANDARD NOR SERVE AS ANY FORM OF
GUARANTEE. USERS OF THIS INFORMATION MUST EXERCISE PERSONAL JUDGMENT.
COMPILE DATE: OCT. 2011
COMPILE DEPT: TECHNOLOGY OF GIU
CHECK DEPT: NIPPON PAINT (CHINA) CO., LTD
REMARK:
ALL INFORMATION IS JUST ACCORDING THE PRESENT STATE OF OUR KNOWLEDGE, AND
MAKE THE DESCRIPTION IN THE TERMS OF HEALTH AND SAFETY AND SAFETY
REQUIREMENT. IF YOU HAVE PROBLEM, PLEASE CONTACT WITH NIPPON PAINT (CHINA)
CO., LTD
N
NIPPON PAINT
NIPPON PAINT
NIPPON PAINT (CHINA) CO., LTD.
SAFETY DATA SHEET (SDS)
SDS CODE: NP-SDS-GIU-GIC-32JANZH-0001-T-701 THINNER
VERSION: 0.0(E)
EFFECTIVE DATE: 1ST, NOV, 2011
PRODUCT NAME: T-701 THINNER
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: T-701 THINNER
MANUFACTURE: NIPPON PAINT (CHINA) CO., LTD.
ADDRESS:
NO. 287 CHUANG YE ROAD
JIN QIAO DEVELOPMENT ZONE
NEW PUDONG DISTRICT
SHANGHAI 201201 P. R.
CHINA
TEL.: 86021-58384799 (T)
FAX: 86021-58382599 (F)
NATION EMERGENCY TELEPHONE NUMBER: (86) 532-83889090
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION CODE:
FLAMMABLE LIQUID: CATEGORY 3
ACUTE TOXICITY (ORAL): CATEGORY 5
ACUTE TOXICITY (SKIN): CATEGORY 5
ACUTE TOXICITY (GAS, VAPOR, DUST, SMOG): CATEGORY 5
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
REPRODUCTIVE TOXICITY: CATEGORY 1
ACUTE HAZARDS TO THE AQUATIC ENVIRONMENT: CATEGORY 2
SYMBOL:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL: DANGER
HAZARD STATEMENT:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H303: MAY BE HARMFUL IF SWALLOWED
H333: MAY BE HARMFUL IF INHALED
H315: CAUSES SKIN IRRITATION
H319: CAUSES SERIOUS EYE DAMAGE
H360: MAY DAMAGE FERTILITY OR THE UNBORN CHILD
H401: TOXIC TO AQUATIC LIFE
PRECAUTIONARY STATEMENTS (PREVENTIVE):
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACE.-NO SMOKING
P233: KEEP CONTAINER TIGHTLY CLOSED
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOL.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P264: WASH HANDS AND MOUTH THOROUGHLY AFTER HANDLING.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P273: AVOID RELEASE TO THE ENVIRONMENT, IF THIS IS NOT THE INTENDED USE.
P272:
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
PRECAUTIONARY STATEMENTS (RESPOND):
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING RINSE SKIN WITH
WATER/SHOWER.
P309+P312:
IF EXPOSED OR IF YOU FEEL UNWELL:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P302+P350:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P321: SPECIFIC TREATMENT (SEE ON THIS LABEL).
P333+P315:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P361+P363: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
P305+P351:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
REMOVE CONTACT LENSES IF PRESENT AND EASY TO DO, CONTINUE RINSING.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
PRECAUTIONARY STATEMENTS (SAFETY STORAGE):
P403+P215: STORE IN A WELL-VENTILATED PLACE
P405: STORE LOCKED UP AWAY FROM CHILDREN.
PRECAUTIONARY STATEMENTS (REJECT DISPOSE):
P501: ACCORDING THE REGULATION TO DISPOSE OF CONTENTS AND CONTAINERS.
| 3. COMPOSITION/INFORMATION ON INGREDIENT | |
INGREDIENT CAS NO CONCENTRATION (%)
TOLUENE 108-88-3 35-45
ETHYL ACETATE 141-78-6 25-35
N-BUTYL ACETATE 123-86-4 5-15
MIBK 108-10-1 15-25
| 4. FIRST-AID MEASURES | |
SKIN CONTACT:
IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES WHILE REMOVING CONTAMINATION CLOTHING AND SHOES.
EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES.
IF EASY TO DO, REMOVE CONTACT LENSES, IF WORN. GET MEDICAL ATTENTION
IMMEDIATELY.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESUSCITATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL
ATTENTION IMMEDIATELY.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
COMBUSTIBILITY: FLAMMABILITY
SUITABLE FIRE-EXTINGUISHING MEDIUM: CO2, FOAM, DRY CHEMICALS, DRY SAND.
DECOMPOSITION PRODUCTS: CO, CO2
NOTICE:
(1) AVOID ALL SOURCES OF IGNITION ALL AROUND.
(2) WEAR PROTECTIVE CLOTHING AND SELF-CONTAINED BREATHING APPARATUS WHEN
DEALING WITH SPILLAGE OR FIRE.
(3) USING THE WATER FOG TO LET CONTAINERS COOLING.
| 6. ACCIDENTAL RELEASE MEASURES | |
VENTILATE THE AREA AND AVOID BREATHING VAPOR. COLLECT SPILLAGE, WHERE
PRACTICABLE, FOR SAFE DISPOSAL. SHOULD BE DISPOSED WASTES AND EMPTY
CONTAINERS IN ACCORDANCE WITH REGULATIONS MADE UNDER THE CONTROL OF
POLLUTION ACTS AND THE ENVIRONMENTAL PROTECTION ACTS. COLLECT SPILLAGE,
WHERE POSSIBLE, USING ABSORBENT MATERIAL, AND DISPOSE SPILLAGE ON THE
FLOOR IN A SAFE MANNER. DO NOT ALLOW SPILLS TO ENTER DRAINS OR WATER
COURSES.
| 7. HANDLING AND STORAGE | |
HANDING:
KEEP AWAY FROM HEAT, SPARKS, AND FLAME.
KEEP CONTAINERS CLOSED AND THE STORAGE DRAFTY.
THE PRODUCT MAY CHARGE ELECTRO STATICALLY.
OPERATORS SHOULD WEAR CLOTHING DOES NOT GENERATE STATIC (AT LEAST 60%
NATURAL FIBER) AND ANTISTATIC FOOD WEAR.
DO NOT BREATHE (DUST, VAPOR, MIST, GAS).
USE ONLY WITH VENTILATION.
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN.
WASH THOROUGHLY AFTER HANDING.
PROTECTION IS AS SHOWN IN SECTION 8.
STORAGE:
KEEP CONTAINER CLOSED.
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN AND INHALATION.
KEEP AWAY FROM HEAT, SPARKS AND FLAME.
BE STORED IN A WELL-VENTILATED, DRY PLACE AWAY FROM SOURCE OF HEAT AND
DIRECT SUNSHINE.
DO NOT STORE ABOVE 40 DEG. C. (104 DEG. F.)
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS (GBZ2-2002):
XYLENE:
CHINA:
TWA: 50 MG/M3
STEL: 100 MG/M3
N-BUTYL ACETATE:
CHINA:
TWA: 200 MG/M3
STEL: 300 MG/M3
MIBK:
CHINA:
TWA: 50 MG/M3
STEL: 75 MG/M3
TOLUENE:
CHINA:
TWA: 50 MG/M3
STEL: 100 MG/M3
ETHYL ACETATE:
TWA: 300 MG/M3
PMA: NO DATA
ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION. KEEP CONTAINERS CLOSED WHEN NOT USING.
RESPIRATORY PROTECTION: WEAR RESPIRATOR WHEN CONTACT.
EYE PROTECTION:
WEAR CHEMICAL SPLASH GOGGLES AND FACE SHIELD WHEN EYE AND FACE CONTACT
IS POSSIBLE DUE TO SPLASHING OR SPRAYING OF MATERIAL.
SKIN PROTECTION:
WEAR CHEMICAL RESISTANT CLOTHING SUCH AS GLOVES, APRON, BOOTS OR WHOLE
BODYSUITS MADE FROM NEOPRENE, AS APPROPRIATE.
HAND PROTECTION:
WEAR IMPERVIOUS GLOVES.
PHYSICAL EXAMINATION IS NEEDED PERIODIC.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: TRANSPARENT
ODOR: SOLVENT ODOR
PH: NO DATA
BOILING POINT (RANGE): NO DATA
FLASH POINT: 11 (DEG. C)
IGNITION TEMPERATURE: NO DATA
LOWER EXPLOSIVE LIMIT: NO DATA
HIGHER EXPLOSIVE LIMIT: NO DATA
VAPOR PRESSURE: NO DATA
SPECIFIC DENSITY: 0.900 +/- 0.050G/CM3 (20 DEG. C)
VAPOR DENSITY: THE VAPOR AND GAS ARE HEAVIER THAN WATER
SOLUBILITY IN WATER: NONE OR POOR IN WATER
PERCENTAGE VOLATILE: NO DATA
| 10. STABILITY AND REACTIVITY | |
STABILITY:
STABLE UNDER RECOMMENDED STORAGE AND HANDING CONDITIONS. WHEN EXPOSED TO
HIGH TEMPERATURE, MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS SUCH AS
CARBON DIOXIDE, OXIDES OF NITROGEN AND SMOKE.
HAZARDOUS REACTION: HAZARDOUS REACTION WILL NOT OCCUR.
CONDITION TO AVOID:
KEEP AWAY FROM OXIDIZING AGENTS, STRONGLY ALKALINE AND STRONGLY ACID
MATERIAL IN ORDER TO AVOID POSSIBLE EXOTHERMIC REACTIONS.
HAZARDOUS DECOMPOSITION PRODUCTS:
THE PRODUCTS DECOMPOSED ON HEATING PRODUCING THEIR OXIDE OR MONOMERS.
THERE ARE NO DATA AVAILABLE ON THE PRODUCT ITSELF.
| 11. TOXICOLOGICAL INFORMATION | |
N-BUTYL ACETATE:
MOUSE INGESTION LD50: 13100 MG/KG
RABBIT INHALATION LD50: >500 MG/KG
XYLENE:
MOUSE INGESTION LD50: 4300 MG/KG
RABBIT INHALATION LD50: >1700 MG/KG
MIBK:
MOUSE INGESTION LD50: 2080 MG/KG
RABBIT INHALATION LD50: >5990 MG/KG
TOLUENE:
MOUSE INGESTION LD50: 5000 MG/KG
RABBIT INHALATION LD50: >12124 MG/KG
PMA:
MOUSE INGESTION LD50: 8532 MG/KG
RABBIT INHALATION LD50: >5000 MG/KG
ETHYL ACETATE:
MOUSE INGESTION LD50: 5620 MG/KG
SKIN STIMULATE: NO DATA
EYE STIMULATE: NO DATA
SKIN STIMULATE: NO DATA
REPRODUCTIVE TOXICITY: NO DATA
SPECIFIC TARGET ORGAN TOXICITY FOLLOWING SINGLE EXPOSURE: NO DATA
SPECIFIC TARGET ORGAN TOXICITY FOLLOWING REPEATED EXPOSURE: NO DATA
INHALATION HARMFUL: NO DATA
| 12. ECOLOGICAL INFORMATION | |
FOR SPILLS OR WASTE, TAKE CARE TO AVOID CONTAMINATING ENVIRONMENT.
PREVENT SPILL AND WASTEWATER FROM ENTERING SEWERS, WATER COURSES OR LAW
AREAS TO AVOID POLLUTION.
THERE ARE NO DATA AVAILABLE ON THE PRODUCT ITSELF.
| 13. DISPOSAL CONSIDERATIONS | |
THE PRODUCT SHOULD NOT BE ALLOWED TO INTER DRAINS AND WATERCOURSES.
ALL NOTIFICATION, CLEAN-UP AND DISPOSAL SHOULD BE CARRIED OUT IN ACCORDANCE
WITH FEDERAL, STATE AND LOCAL REGULATIONS.
PREFERRED METHOD OF WASTE DISPOSAL IS INCINERATION OR BIOLOGICAL TREATMENT
IN FEDERAL/STATE APPROVED FACILITY.
WASTES AND EMPTY CONTAINERS SHOULD BE DISPOSED OF IN ACCORDANCE WITH
REGULATIONS MADE UNDER THE CONTROL OF POLLUTION ACTS AND THE ENVIRONMENTAL
PROTECTION ACTS.
EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED
WASTE MANAGEMENT FACILITY.
IT IS STRONGLY ADVISED NOT TO LET THE CHEMICAL ENTER INTO THE ENVIRONMENT.
| 14. TRANSPORT INFORMATION | |
UN REGULATION:
UN SHIPPING NAME:
PAINT (INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC, VARNISH, POLISH,
LIQUID FILLER) OR PAINT RELATED MATERIAL (INCLUDING PAINT THINNING OR
REDUCING COMPOUND)
UN IDENTIFICATION NUMBER: 1263
UN CLASS: CLASS 3 FLAMMABLE LIQUIDS
UN PACKING GROUP: II
IMDG CLASS: CLASS 3.2 INTERMEDIATE FLASHPOINT GROUP
STORAGE TEMPERATURE: STORE BELLOW 40 DEG. C. (104 DEG. F.).
| 15. STATUTE INFORMATION | |
1. STATE FATALNESS CHEMICALS PROTECTION: NO.344
2. GB 12268-2005 FATALNESS PRODUCT LISTING
3. GB/T 16483-2008 SAFETY DATA SHEET FOR CHEMICAL PRODUCTS-CONTENT AND
ORDER OF SECTIONS.
4. GB 15258-2009 GENERAL RULES FOR PREPARATION OF PRECAUTIONARY LABEL
FOR CHEMICALS
5. GB 13690-2009 THE RULES OF FATALNESS CLASSIFY
6. GB/T 22234-2008 LABEL OF CHEMICALS BASED ON GHS.
| 16. OTHER INFORMATION | |
THE INFORMATION PROVIDED IN THIS SDS ONLY PERTAINS TO THE USAGE OF THIS
PRODUCT UNDER NORMAL CONDITION AND FOR USE AS A SAFETY MEASURE AT WORK.
IT DOES NOT CONSTITUTE ANY PRODUCT STANDARD NOR SERVE AS ANY FORM OF
GUARANTEE. USERS OF THIS INFORMATION MUST EXERCISE PERSONAL JUDGMENT.
COMPILE DATE: APRIL 2011
COMPILE DEPT: TECHNOLOGY OF AUTO REPAIR
CHECK DEPT: NIPPON PAINT (CHINA) CO., LTD
REMARK:
ALL INFORMATION IS JUST ACCORDING THE PRESENT STATE OF OUR KNOWLEDGE, AND
MAKE THE DESCRIPTION IN THE TERMS OF HEALTH AND SAFETY AND SAFETY
REQUIREMENT. IF YOU HAVE PROBLEM, PLEASE CONTACT WITH NIPPON PAINT(CHINA)
CO., LTD
N
NIPPON PAINT
NIPPON PAINT
NIPPON PAINT (CHINA) CO., LTD.
SAFETY DATA SHEET (SDS)
SDS CODE: NP-SDS-GIU-GIC-32JANZH-0002-T-801 THINNER
VERSION: 0.0(E)
EFFECTIVE DATE: 1ST, NOV, 2011
PRODUCT NAME: T-801 THINNER
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: T-801 THINNER
MANUFACTURE: NIPPON PAINT (CHINA) CO., LTD.
ADDRESS:
NO. 287 CHUANG YE ROAD
JIN QIAO DEVELOPMENT ZONE
NEW PUDONG DISTRICT
SHANGHAI 201201 P. R.
CHINA
TEL.: 86021-58384799 (T)
FAX: 86021-58382599 (F)
NATION EMERGENCY TELEPHONE NUMBER: (86) 532-83889090
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION CODE:
FLAMMABLE LIQUID: CATEGORY 3
ACUTE TOXICITY (ORAL): CATEGORY 5
ACUTE TOXICITY (SKIN): CATEGORY 5
ACUTE TOXICITY (GAS, VAPOR, DUST, SMOG): CATEGORY 5
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
REPRODUCTIVE TOXICITY: CATEGORY 1
ACUTE HAZARDS TO THE AQUATIC ENVIRONMENT: CATEGORY 2
SYMBOL:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL: DANGER
HAZARD STATEMENT:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H303: MAY BE HARMFUL IF SWALLOWED
H333: MAY BE HARMFUL IF INHALED
H315: CAUSES SKIN IRRITATION
H319: CAUSES SERIOUS EYE DAMAGE
H360: MAY DAMAGE FERTILITY OR THE UNBORN CHILD
H401: TOXIC TO AQUATIC LIFE
PRECAUTIONARY STATEMENTS (PREVENTIVE):
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACE.-NO SMOKING
P233: KEEP CONTAINER TIGHTLY CLOSED
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOL.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P264: WASH HANDS AND MOUTH THOROUGHLY AFTER HANDLING.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P273: AVOID RELEASE TO THE ENVIRONMENT, IF THIS IS NOT THE INTENDED USE.
P272:
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
PRECAUTIONARY STATEMENTS (RESPOND):
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING RINSE SKIN WITH
WATER/SHOWER.
P309+P312:
IF EXPOSED OR IF YOU FEEL UNWELL:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P302+P350:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P321: SPECIFIC TREATMENT (SEE ON THIS LABEL).
P333+P315:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P361+P363: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
P305+P351:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
REMOVE CONTACT LENSES IF PRESENT AND EASY TO DO, CONTINUE RINSING.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
PRECAUTIONARY STATEMENTS (SAFETY STORAGE):
P403+P215: STORE IN A WELL-VENTILATED PLACE
P405: STORE LOCKED UP AWAY FROM CHILDREN.
PRECAUTIONARY STATEMENTS (REJECT DISPOSE):
P501: ACCORDING THE REGULATION TO DISPOSE OF CONTENTS AND CONTAINERS.
| 3. COMPOSITION/INFORMATION ON INGREDIENT | |
INGREDIENT CAS NO CONCENTRATION (%)
XYLENE 1330-20-7 20-30
S-100 SOLVENT 64742-95-6 25-35
N-BUTYL ACETATE 123-86-4 25-35
PMA 108-65-6 15-25
| 4. FIRST-AID MEASURES | |
SKIN CONTACT:
IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES WHILE REMOVING CONTAMINATION CLOTHING AND SHOES.
EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES.
IF EASY TO DO, REMOVE CONTACT LENSES, IF WORN. GET MEDICAL ATTENTION
IMMEDIATELY.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESUSCITATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL
ATTENTION IMMEDIATELY.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
COMBUSTIBILITY: FLAMMABILITY
SUITABLE FIRE-EXTINGUISHING MEDIUM: CO2, FOAM, DRY CHEMICALS, DRY SAND.
DECOMPOSITION PRODUCTS: CO, CO2
NOTICE:
(1) AVOID ALL SOURCES OF IGNITION ALL AROUND.
(2) WEAR PROTECTIVE CLOTHING AND SELF-CONTAINED BREATHING APPARATUS WHEN
DEALING WITH SPILLAGE OR FIRE.
(3) USING THE WATER FOG TO LET CONTAINERS COOLING.
| 6. ACCIDENTAL RELEASE MEASURES | |
VENTILATE THE AREA AND AVOID BREATHING VAPOR. COLLECT SPILLAGE, WHERE
PRACTICABLE, FOR SAFE DISPOSAL. SHOULD BE DISPOSED WASTES AND EMPTY
CONTAINERS IN ACCORDANCE WITH REGULATIONS MADE UNDER THE CONTROL OF
POLLUTION ACTS AND THE ENVIRONMENTAL PROTECTION ACTS. COLLECT SPILLAGE,
WHERE POSSIBLE, USING ABSORBENT MATERIAL, AND DISPOSE SPILLAGE ON THE FLOOR
IN A SAFE MANNER. DO NOT ALLOW SPILLS TO ENTER DRAINS OR WATER COURSES.
| 7. HANDLING AND STORAGE | |
HANDING:
KEEP AWAY FROM HEAT, SPARKS, AND FLAME.
KEEP CONTAINERS CLOSED AND THE STORAGE DRAFTY.
THE PRODUCT MAY CHARGE ELECTRO STATICALLY.
OPERATORS SHOULD WEAR CLOTHING DOES NOT GENERATE STATIC (AT LEAST 60%
NATURAL FIBER) AND ANTISTATIC FOOD WEAR.
DO NOT BREATHE (DUST, VAPOR, MIST, GAS).
USE ONLY WITH VENTILATION.
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN.
WASH THOROUGHLY AFTER HANDING.
PROTECTION IS AS SHOWN IN SECTION 8.
STORAGE:
KEEP CONTAINER CLOSED.
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN AND INHALATION.
KEEP AWAY FROM HEAT, SPARKS AND FLAME.
BE STORED IN A WELL-VENTILATED, DRY PLACE AWAY FROM SOURCE OF HEAT AND
DIRECT SUNSHINE.
DO NOT STORE ABOVE 40 DEG. C. (104 DEG. F.)
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS (GBZ2-2002):
XYLENE:
CHINA:
TWA: 50 MG/M3
STEL: 100 MG/M3
N-BUTYL ACETATE:
CHINA:
TWA: 200 MG/M3
STEL: 300 MG/M3
MIBK:
CHINA:
TWA: 50 MG/M3
STEL: 75 MG/M3
TOLUENE:
CHINA:
TWA: 50 MG/M3
STEL: 100 MG/M3
ETHYL ACETATE:
TWA: 300 MG/M3
PMA: NO DATA
ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION. KEEP CONTAINERS CLOSED WHEN NOT USING.
RESPIRATORY PROTECTION: WEAR RESPIRATOR WHEN CONTACT.
EYE PROTECTION:
WEAR CHEMICAL SPLASH GOGGLES AND FACE SHIELD WHEN EYE AND FACE CONTACT
IS POSSIBLE DUE TO SPLASHING OR SPRAYING OF MATERIAL.
SKIN PROTECTION:
WEAR CHEMICAL RESISTANT CLOTHING SUCH AS GLOVES, APRON, BOOTS OR WHOLE
BODYSUITS MADE FROM NEOPRENE, AS APPROPRIATE.
HAND PROTECTION:
WEAR IMPERVIOUS GLOVES.
PHYSICAL EXAMINATION IS NEEDED PERIODIC.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: TRANSPARENT
ODOR: SOLVENT ODOR
PH: NO DATA
BOILING POINT (RANGE): NO DATA
FLASH POINT: 12 (DEG. C)
IGNITION TEMPERATURE: NO DATA
LOWER EXPLOSIVE LIMIT: NO DATA
HIGHER EXPLOSIVE LIMIT: NO DATA
VAPOR PRESSURE: NO DATA
SPECIFIC DENSITY: 0.900 +/- 0.050G/CM3 (20 DEG. C)
VAPOR DENSITY: THE VAPOR AND GAS ARE HEAVIER THAN WATER
SOLUBILITY IN WATER: NONE OR POOR IN WATER
PERCENTAGE VOLATILE: NO DATA
| 10. STABILITY AND REACTIVITY | |
STABILITY:
STABLE UNDER RECOMMENDED STORAGE AND HANDING CONDITIONS. WHEN EXPOSED TO
HIGH TEMPERATURE, MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS SUCH AS
CARBON DIOXIDE, OXIDES OF NITROGEN AND SMOKE.
HAZARDOUS REACTION: HAZARDOUS REACTION WILL NOT OCCUR.
CONDITION TO AVOID:
KEEP AWAY FROM OXIDIZING AGENTS, STRONGLY ALKALINE AND STRONGLY ACID
MATERIAL IN ORDER TO AVOID POSSIBLE EXOTHERMIC REACTIONS.
HAZARDOUS DECOMPOSITION PRODUCTS:
THE PRODUCTS DECOMPOSED ON HEATING PRODUCING THEIR OXIDE OR MONOMERS.
THERE ARE NO DATA AVAILABLE ON THE PRODUCT ITSELF.
| 11. TOXICOLOGICAL INFORMATION | |
N-BUTYL ACETATE:
MOUSE INGESTION LD50: 13100 MG/KG
RABBIT INHALATION LD50: >500 MG/KG
XYLENE:
MOUSE INGESTION LD50: 4300 MG/KG
RABBIT INHALATION LD50: >1700 MG/KG
MIBK:
MOUSE INGESTION LD50: 2080 MG/KG
RABBIT INHALATION LD50: >5990 MG/KG
TOLUENE:
MOUSE INGESTION LD50: 5000 MG/KG
RABBIT INHALATION LD50: >12124 MG/KG
PMA:
MOUSE INGESTION LD50: 8532 MG/KG
RABBIT INHALATION LD50: >5000 MG/KG
ETHYL ACETATE:
MOUSE INGESTION LD50: 5620 MG/KG
SKIN STIMULATE: NO DATA
EYE STIMULATE: NO DATA
SKIN STIMULATE: NO DATA
REPRODUCTIVE TOXICITY: NO DATA
SPECIFIC TARGET ORGAN TOXICITY FOLLOWING SINGLE EXPOSURE: NO DATA
SPECIFIC TARGET ORGAN TOXICITY FOLLOWING REPEATED EXPOSURE: NO DATA
INHALATION HARMFUL: NO DATA
| 12. ECOLOGICAL INFORMATION | |
FOR SPILLS OR WASTE, TAKE CARE TO AVOID CONTAMINATING ENVIRONMENT.
PREVENT SPILL AND WASTEWATER FROM ENTERING SEWERS, WATER COURSES OR LAW
AREAS TO AVOID POLLUTION.
THERE ARE NO DATA AVAILABLE ON THE PRODUCT ITSELF.
| 13. DISPOSAL CONSIDERATIONS | |
THE PRODUCT SHOULD NOT BE ALLOWED TO INTER DRAINS AND WATERCOURSES.
ALL NOTIFICATION, CLEAN-UP AND DISPOSAL SHOULD BE CARRIED OUT IN ACCORDANCE
WITH FEDERAL, STATE AND LOCAL REGULATIONS.
PREFERRED METHOD OF WASTE DISPOSAL IS INCINERATION OR BIOLOGICAL TREATMENT
IN FEDERAL/STATE APPROVED FACILITY.
WASTES AND EMPTY CONTAINERS SHOULD BE DISPOSED OF IN ACCORDANCE WITH
REGULATIONS MADE UNDER THE CONTROL OF POLLUTION ACTS AND THE ENVIRONMENTAL
PROTECTION ACTS.
EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED
WASTE MANAGEMENT FACILITY.
IT IS STRONGLY ADVISED NOT TO LET THE CHEMICAL ENTER INTO THE ENVIRONMENT.
| 14. TRANSPORT INFORMATION | |
UN REGULATION:
UN SHIPPING NAME:
PAINT (INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC, VARNISH, POLISH,
LIQUID FILLER) OR PAINT RELATED MATERIAL (INCLUDING PAINT THINNING OR
REDUCING COMPOUND)
UN IDENTIFICATION NUMBER: 1263
UN CLASS: CLASS 3 FLAMMABLE LIQUIDS
UN PACKING GROUP: II
IMDG CLASS: CLASS 3.2 INTERMEDIATE FLASHPOINT GROUP
STORAGE TEMPERATURE: STORE BELLOW 40 DEG. C. (104 DEG. F.).
| 15. STATUTE INFORMATION | |
1. STATE FATALNESS CHEMICALS PROTECTION: NO. 344
2. GB 12268-2005 FATALNESS PRODUCT LISTING
3. GB/T 16483-2008 SAFETY DATA SHEET FOR CHEMICAL PRODUCTS-CONTENT AND
ORDER OF SECTIONS.
4. GB 15258-2009 GENERAL RULES FOR PREPARATION OF PRECAUTIONARY LABEL FOR
CHEMICALS
5. GB 13690-2009 THE RULES OF FATALNESS CLASSIFY
6. GB/T 22234-2008 LABEL OF CHEMICALS BASED ON GHS.
| 16. OTHER INFORMATION | |
THE INFORMATION PROVIDED IN THIS SDS ONLY PERTAINS TO THE USAGE OF THIS
PRODUCT UNDER NORMAL CONDITION AND FOR USE AS A SAFETY MEASURE AT WORK.
IT DOES NOT CONSTITUTE ANY PRODUCT STANDARD NOR SERVE AS ANY FORM OF
GUARANTEE. USERS OF THIS INFORMATION MUST EXERCISE PERSONAL JUDGMENT.
COMPILE DATE: APRIL 2011
COMPILE DEPT: TECHNOLOGY OF AUTO REPAIR
CHECK DEPT: NIPPON PAINT (CHINA) CO., LTD
REMARK:
ALL INFORMATION IS JUST ACCORDING THE PRESENT STATE OF OUR KNOWLEDGE,
AND MAKE THE DESCRIPTION IN THE TERMS OF HEALTH AND SAFETY AND SAFETY
REQUIREMENT. IF YOU HAVE PROBLEM, PLEASE CONTACT WITH NIPPON PAINT(CHINA)
CO., LTD
N
NIPPON PAINT
NIPPON PAINT
NIPPON PAINT (CHINA) CO., LTD.
SAFETY DATA SHEET (SDS)
SDS CODE: NP-SDS-GIU-GIC-33JANZH-0001-PC 2000 HARDENER
VERSION: 0.0(E)
EFFECTIVE DATE: 1ST, NOV, 2011
PRODUCT NAME: PC 2000 HARDENER
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: PC 2000 HARDENER
MANUFACTURE: NIPPON PAINT (CHINA) CO., LTD.
ADDRESS:
NO. 287 CHUANG YE ROAD
JIN QIAO DEVELOPMENT ZONE
NEW PUDONG DISTRICT, SHANGHAI 201201 P. R.
CHINA
TEL.: 86021-58384799 (T)
FAX: 86021-58382599 (F)
NATION EMERGENCY TELEPHONE NUMBER: (86) 532-83889090
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION CODE:
FLAMMABLE LIQUID: CATEGORY 3
ACUTE TOXICITY (ORAL): CATEGORY 5
ACUTE TOXICITY (SKIN): CATEGORY 5
ACUTE TOXICITY (GAS, VAPOR, DUST, SMOG): CATEGORY 5
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
ACUTE HAZARDS TO THE AQUATIC ENVIRONMENT: CATEGORY 3
SYMBOL:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
SIGNAL: DANGER
HAZARD STATEMENT:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H303: MAY BE HARMFUL IF SWALLOWED
H333: MAY BE HARMFUL IF INHALED
H315: CAUSES SKIN IRRITATION
H319: CAUSES SERIOUS EYE DAMAGE
H360: MAY DAMAGE FERTILITY OR THE UNBORN CHILD
H401: TOXIC TO AQUATIC LIFE
PRECAUTIONARY STATEMENTS (PREVENTIVE):
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACE.-NO SMOKING
P233: KEEP CONTAINER TIGHTLY CLOSED
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOL.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P264: WASH HANDS AND MOUTH THOROUGHLY AFTER HANDLING.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P273: AVOID RELEASE TO THE ENVIRONMENT, IF THIS IS NOT THE INTENDED USE.
P272:
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
PRECAUTIONARY STATEMENTS (RESPOND):
P303+P361+P353:
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING RINSE SKIN WITH
WATER/SHOWER.
P309+P312:
IF EXPOSED OR IF YOU FEEL UNWELL:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P302+P350:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P321: SPECIFIC TREATMENT (SEE ON THIS LABEL).
P333+P315:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P361+P363: TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
P305+P351:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES IF
PRESENT AND EASY TO DO, CONTINUE RINSING.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
PRECAUTIONARY STATEMENTS (SAFETY STORAGE):
P403+P215: STORE IN A WELL-VENTILATED PLACE.
P405: STORE LOCKED UP AWAY FROM CHILDREN.
PRECAUTIONARY STATEMENTS (REJECT DISPOSE):
P501: ACCORDING THE REGULATION TO DISPOSE OF CONTENTS AND CONTAINERS.
| 3. COMPOSITION/INFORMATION ON INGREDIENT | |
INGREDIENT CAS NO CONCENTRATION (%)
ALIPHATIC POLYISOCYANATE PROPRIETARY 100
| 4. FIRST-AID MEASURES | |
SKIN CONTACT:
IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES WHILE REMOVING CONTAMINATION CLOTHING AND SHOES.
EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES.
IF EASY TO DO, REMOVE CONTACT LENSES, IF WORN. GET MEDICAL ATTENTION
IMMEDIATELY.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESUSCITATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL
ATTENTION IMMEDIATELY.
INGESTION:
IF SWALLOWED, DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| 5. FIRE-FIGHTING MEASURES | |
COMBUSTIBILITY: FLAMMABILITY
SUITABLE FIRE-EXTINGUISHING MEDIUM: CO2, FOAM, DRY CHEMICALS, DRY SAND.
DECOMPOSITION PRODUCTS: CO, CO2
NOTICE:
(1) AVOID ALL SOURCES OF IGNITION ALL AROUND.
(2) WEAR PROTECTIVE CLOTHING AND SELF-CONTAINED BREATHING APPARATUS WHEN
DEALING WITH SPILLAGE OR FIRE.
(3) USING THE WATER FOG TO LET CONTAINERS COOLING.
| 6. ACCIDENTAL RELEASE MEASURES | |
VENTILATE THE AREA AND AVOID BREATHING VAPOR. COLLECT SPILLAGE, WHERE
PRACTICABLE, FOR SAFE DISPOSAL. SHOULD BE DISPOSED WASTES AND EMPTY
CONTAINERS IN ACCORDANCE WITH REGULATIONS MADE UNDER THE CONTROL OF
POLLUTION ACTS AND THE ENVIRONMENTAL PROTECTION ACTS. COLLECT SPILLAGE,
WHERE POSSIBLE, USING ABSORBENT MATERIAL, AND DISPOSE SPILLAGE ON THE FLOOR
IN A SAFE MANNER. DO NOT ALLOW SPILLS TO ENTER DRAINS OR WATER COURSES.
| 7. HANDLING AND STORAGE | |
HANDING:
KEEP AWAY FROM HEAT, SPARKS, AND FLAME.
KEEP CONTAINERS CLOSED AND THE STORAGE DRAFTY.
THE PRODUCT MAY CHARGE ELECTRO STATICALLY.
OPERATORS SHOULD WEAR CLOTHING DOES NOT GENERATE STATIC (AT LEAST 60%
NATURAL FIBER) AND ANTISTATIC FOOD WEAR.
DO NOT BREATHE (DUST, VAPOR, MIST, GAS).
USE ONLY WITH VENTILATION.
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN.
WASH THOROUGHLY AFTER HANDING.
PROTECTION IS AS SHOWN IN SECTION 8.
STORAGE:
KEEP CONTAINER CLOSED.
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN AND INHALATION.
KEEP AWAY FROM HEAT, SPARKS AND FLAME.
BE STORED IN A WELL-VENTILATED, DRY PLACE AWAY FROM SOURCE OF HEAT AND
DIRECT SUNSHINE.
DO NOT STORE ABOVE 40 DEG. C. (104 DEG. F.)
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS (GBZ2-2002):
XYLENE:
CHINA:
TWA: 50 MG/M3
STEL: 100 MG/M3
N-BUTYL ACETATE:
CHINA:
TWA: 200 MG/M3
STEL: 300 MG/M3
PMA: NO DATA
ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION. KEEP CONTAINERS CLOSED WHEN NOT USING.
RESPIRATORY PROTECTION: WEAR RESPIRATOR WHEN CONTACT.
EYE PROTECTION:
WEAR CHEMICAL SPLASH GOGGLES AND FACE SHIELD WHEN EYE AND FACE CONTACT IS
POSSIBLE DUE TO SPLASHING OR SPRAYING OF MATERIAL.
SKIN PROTECTION:
WEAR CHEMICAL RESISTANT CLOTHING SUCH AS GLOVES, APRON, BOOTS OR WHOLE
BODYSUITS MADE FROM NEOPRENE, AS APPROPRIATE.
HAND PROTECTION: WEAR IMPERVIOUS GLOVES.
PHYSICAL EXAMINATION IS NEEDED PERIODIC.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: TRANSPARENT
ODOR: SOLVENT ODOR
PH: NO DATA
BOILING POINT (RANGE): NO DATA
FLASH POINT: 37.5 (DEG. C)
IGNITION TEMPERATURE: NO DATA
LOWER EXPLOSIVE LIMIT: NO DATA
HIGHER EXPLOSIVE LIMIT: NO DATA
VAPOR PRESSURE: NO DATA
SPECIFIC DENSITY: 1.025 +/- 0.025 G/CM3 (20 DEG. C)
VAPOR DENSITY: THE VAPOR AND GAS ARE HEAVIER THAN WATER
SOLUBILITY IN WATER: NONE OR POOR IN WATER
PERCENTAGE VOLATILE: NO DATA
| 10. STABILITY AND REACTIVITY | |
STABILITY:
STABLE UNDER RECOMMENDED STORAGE AND HANDING CONDITIONS. WHEN EXPOSED TO
HIGH TEMPERATURE, MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS SUCH AS
CARBON DIOXIDE, OXIDES OF NITROGEN AND SMOKE.
HAZARDOUS REACTION: HAZARDOUS REACTION WILL NOT OCCUR.
CONDITION TO AVOID:
KEEP AWAY FROM OXIDIZING AGENTS, STRONGLY ALKALINE AND STRONGLY ACID
MATERIAL IN ORDER TO AVOID POSSIBLE EXOTHERMIC REACTIONS.
HAZARDOUS DECOMPOSITION PRODUCTS:
THE PRODUCTS DECOMPOSED ON HEATING PRODUCING THEIR OXIDE OR MONOMERS.
THERE ARE NO DATA AVAILABLE ON THE PRODUCT ITSELF.
| 11. TOXICOLOGICAL INFORMATION | |
N-BUTYL ACETATE:
MOUSE INGESTION LD50: 13100 MG/KG
RABBIT INHALATION LD50: >500 MG/KG
XYLENE:
MOUSE INGESTION LD50: 4300 MG/KG
RABBIT INHALATION LD50: >1700 MG/KG
PMA:
MOUSE INGESTION LD50: 8532 MG/KG
RABBIT INHALATION LD50: >5000 MG/KG
SKIN STIMULATE: NO DATA
EYE STIMULATE: NO DATA
SKIN STIMULATE: NO DATA
REPRODUCTIVE TOXICITY: NO DATA
SPECIFIC TARGET ORGAN TOXICITY FOLLOWING SINGLE EXPOSURE: NO DATA
SPECIFIC TARGET ORGAN TOXICITY FOLLOWING REPEATED EXPOSURE: NO DATA
INHALATION HARMFUL: NO DATA
| 12. ECOLOGICAL INFORMATION | |
FOR SPILLS OR WASTE, TAKE CARE TO AVOID CONTAMINATING ENVIRONMENT.
PREVENT SPILL AND WASTEWATER FROM ENTERING SEWERS, WATER COURSES OR LAW
AREAS TO AVOID POLLUTION. THERE ARE NO DATA AVAILABLE ON THE PRODUCT
ITSELF.
| 13. DISPOSAL CONSIDERATIONS | |
THE PRODUCT SHOULD NOT BE ALLOWED TO INTER DRAINS AND WATERCOURSES.
ALL NOTIFICATION, CLEAN-UP AND DISPOSAL SHOULD BE CARRIED OUT IN ACCORDANCE
WITH FEDERAL, STATE AND LOCAL REGULATIONS.
PREFERRED METHOD OF WASTE DISPOSAL IS INCINERATION OR BIOLOGICAL TREATMENT
IN FEDERAL/STATE APPROVED FACILITY.
WASTES AND EMPTY CONTAINERS SHOULD BE DISPOSED OF IN ACCORDANCE WITH
REGULATIONS MADE UNDER THE CONTROL OF POLLUTION ACTS AND THE ENVIRONMENTAL
PROTECTION ACTS.
EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED
WASTE MANAGEMENT FACILITY.
IT IS STRONGLY ADVISED NOT TO LET THE CHEMICAL ENTER INTO THE ENVIRONMENT.
| 14. TRANSPORT INFORMATION | |
UN REGULATION:
UN SHIPPING NAME:
PAINT (INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC, VARNISH, POLISH,
LIQUID FILLER AND LIQUID LACQUER BASE) OR PAINT RELATED MATERIAL (INCLUDING
PAINT THINNING OR REDUCING COMPOUND)
UN IDENTIFICATION NUMBER: 1263
UN CLASS: CLASS 3 FLAMMABLE LIQUIDS
UN PACKING GROUP: II
IMDG CLASS: CLASS 3.2 INTERMEDIATE FLASHPOINT GROUP
STORAGE TEMPERATURE: STORE BELLOW 40 DEG. C. (104 DEG. F.).
| 15. STATUTE INFORMATION | |
1. STATE FATALNESS CHEMICALS PROTECTION: NO. 344
2. GB 12268-2005 FATALNESS PRODUCT LISTING
3. GB/T 16483-2008 SAFETY DATA SHEET FOR CHEMICAL PRODUCTS-CONTENT AND
ORDER OF SECTIONS.
4. GB 15258-2009 GENERAL RULES FOR PREPARATION OF PRECAUTIONARY LABEL FOR
CHEMICALS
5. GB 13690-2009 THE RULES OF FATALNESS CLASSIFY
6. GB/T 22234-2008 LABEL OF CHEMICALS BASED ON GHS.
| 16. OTHER INFORMATION | |
THE INFORMATION PROVIDED IN THIS SDS ONLY PERTAINS TO THE USAGE OF THIS
PRODUCT UNDER NORMAL CONDITION AND FOR USE AS A SAFETY MEASURE AT WORK.
IT DOES NOT CONSTITUTE ANY PRODUCT STANDARD NOR SERVE AS ANY FORM OF
GUARANTEE. USERS OF THIS INFORMATION MUST EXERCISE PERSONAL JUDGMENT.
COMPILE DATE: APRIL 2011
COMPILE DEPT: TECHNOLOGY OF AUTO REPAIR
CHECK DEPT: NIPPON PAINT (CHINA) CO., LTD
REMARK:
ALL INFORMATION IS JUST ACCORDING THE PRESENT STATE OF OUR KNOWLEDGE, AND
MAKE THE DESCRIPTION IN THE TERMS OF HEALTH AND SAFETY AND SAFETY
REQUIREMENT. IF YOU HAVE PROBLEM, PLEASE CONTACT WITH NIPPON PAINT (CHINA)
CO., LTD
FULLRIVER(R*) BATTERY
FULLRIVER BATTERY VALVE REGULATED LEAD ACID BATTERY
SAFETY DATA SHEET
HAZARD RATING:
H 3
F 0
R 2
COR
| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: VALVE REGULATED SEALED NON-SPILLABLE LEAD ACID BATTERY
PRODUCT USE: ELECTRIC STORAGE BATTERY
MANUFACTURER'S NAME: FULLRIVER BATTERY MANUFACTURE CO. LTD.
ADDRESS:
P.O. BOX 511475
TAISHI INDUSTRIAL AREA
YUWOTOU TOWN
PANYU ZONE, GUANGZHOU
CHINA
PHONE:
800.522.8191 (TOLL FREE)
805.484.7900 (INT'L)
REVISED DATE: JUNE 4, 2015
PERSON RESPONSIBLE FOR PREPARATION: CRAIG QUENTIN, CHIEF PROJECT ENGINEER
COMMON NAME:
(USED ON LABEL): VALVE REGULATED SEALED NON-SPILLABLE LEAD-ACID BATTERY
(TRADE NAME & SYNONYMS):
VRB, VRLA, SLAB, RECOMBINANT LEAD ACID: RG, D8565 SERIES
| SECTION 2 - HAZARD IDENTIFICATION | |
GHS CLASSIFICATION:
HEALTH:
ACUTE TOXICITY (ORAL/DERMAL/INHALATION): CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 1A
EYE DAMAGE: CATEGORY 1
REPRODUCTIVE: CATEGORY 1A
CARCINOGENICITY (LEAD): CATEGORY 1B
CARCINOGENICITY (ARSENIC): CATEGORY 1A
CARCINOGENICITY (ACID MIST): CATEGORY 1B
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXP.): CATEGORY 2
ENVIRONMENTAL:
AQUATIC CHRONIC 1
AQUATIC ACUTE 1
PHYSICAL: EXPLOSIVE CHEMICAL, DIVISION 1.3
GHS LABEL:
HEALTH:
EXCLAMATION MARK
CORROSION
HEALTH HAZARD
ENVIRONMENTAL: ENVIRONMENT
PHYSICAL: EXPLODING BOMB
HAZARD STATEMENTS:
DANGER!
NORMAL OPERATING CONDITIONS:
MAY DAMAGE FERTILITY OR THE UNBORN CHILD IF INGESTED OR INHALED.
MAY CAUSE CANCER IF INGESTED OR INHALED.
CAUSES DAMAGE TO CENTRAL NERVOUS SYSTEM, BLOOD AND KIDNEYS THROUGH
PROLONGED OR REPEATED EXPOSURE.
ABNORMAL CONDITIONS (BROKEN CASE OR EXTREME OVERCHARGING):
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE. CAUSES SERIOUS EYE DAMAGE.
MAY FORM EXPLOSIVE AIR/GAS MIXTURE DURING CHARGING.
EXTREMELY FLAMMABLE GAS (HYDROGEN).
EXPLOSIVE, FIRE, BLAST OR PROJECTION HAZARD.
PRECAUTIONARY STATEMENTS:
WASH THOROUGHLY AFTER HANDLING.
DO NOT EAT DRINK OR SMOKE WHEN USING THIS PRODUCT.
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING, EYE PROTECTION/FACE PROTECTION.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS /SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
CAUSES SKIN IRRITATION, SERIOUS EYE DAMAGE.
CONTACT WITH INTERNAL COMPONENTS MAY CAUSE IRRITATION OR SEVERE BURNS.
AVOID CONTACT WITH INTERNAL ACID.
IRRITATING TO EYES, RESPIRATORY SYSTEM, AND SKIN.
| SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
C.A.S. PRINCIPAL HAZARDOUS HAZARD CATEGORY % WEIGHT ACGIH OSHA
COMPONENT(S) TLV PEL/TWA
(CHEMICAL & COMMON
NAME(S)
7439-92-1 LEAD/LEAD OXIDE ACUTE-CHRONIC 60-70 0.05 0.05
(LITHARGE)/LEAD MG/M3 MG/M3
SULFATE
7440-70-2 CALCIUM REACTIVE <0.15 NOT NOT
ESTAB- ESTAB-
LISHED LISHED
7440-31-5 TIN CHRONIC <1 2 2
7440-38-2 ARSENIC (INORGANIC) ACUTE-CHRONIC <1 0.01 0.01
7664-93-9 SULFURIC ACID REACTIVE- 10-15 1.0 1.0
(BATTERY OXIDIZER
ELECTROLYTE) ACUTE-CHRONIC
NOTE:
PEL'S FOR INDIVIDUAL STATES MAY DIFFER FROM OSHA'S PEL'S. CHECK WITH LOCAL
AUTHORITIES FOR THE APPLICABLE STATE PEL'S.
OSHA - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
ACGIH - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
NIOSH - NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH.
| SECTION 4 - FIRST AID MEASURES | |
EMERGENCY AND FIRST AID PROCEDURES:
CONTACT WITH INTERNAL COMPONENTS IF BATTERY IS OPENED/BROKEN.
INHALATION:
SULFURIC ACID:
REMOVE TO FRESH AIR AND PROVIDE MEDICAL OXYGEN/CPR IF NEEDED. OBTAIN
MEDICAL ATTENTION.
LEAD:
REMOVE FROM EXPOSURE, GARGLE, WASH NOSE AND LIPS; OBTAIN MEDICAL ATTENTION.
INGESTION:
SULFURIC ACID:
DO NOT INDUCE VOMITING. IF CONSCIOUS DRINK LARGE AMOUNTS OF WATER. OBTAIN
MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
LEAD: CONSULT PHYSICIAN IMMEDIATELY.
SKIN:
SULFURIC ACID:
FLUSH CONTACTED AREA WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTAMINATED CLOTHING AND OBTAIN MEDICAL ATTENTION IF NECESSARY.
LEAD: WASH IMMEDIATELY WITH SOAP AND WATER
EYES:
SULFURIC ACID AND/OR LEAD:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER, HOLD EYELIDS OPEN. OBTAIN
MEDICAL ATTENTION.
| SECTION 5 - FIREFIGHTING MEASURES | |
FLASH POINT: NOT APPLICABLE
FLAMMABLE LIMITS IN AIR % BY VOLUME: NOT APPLICABLE
EXTINGUISHING MEDIA:
CLASS ABC, CO2, HALON. DO NOT USE CARBON DIOXIDE DIRECTLY ON CELLS. AVOID
BREATHING VAPORS.
AUTO-IGNITION TEMPERATURE: 675 DEG. F (POLYPROPYLENE)
FIRE FIGHTING PROCEDURES:
LEAD/ACID BATTERIES DO NOT BURN, OR BURN WITH DIFFICULTY. DO NOT USE WATER
ON FIRES WHERE MOLTEN METAL IS PRESENT. EXTINGUISH FIRE WITH AGENT SUITABLE
FOR SURROUNDING COMBUSTIBLE MATERIALS. COOL EXTERIOR OF BATTERY IF EXPOSED
TO FIRE TO PREVENT RUPTURE. THE ACID MIST AND VAPORS GENERATED BY HEAT OR
FIRE ARE CORROSIVE. USE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS
(SCBA) AND FULL PROTECTIVE EQUIPMENT OPERATED IN POSITIVE PRESSURE MODE.
HAZARDOUS COMBUSTION PRODUCTS:
DURING NORMAL OPERATIONS, SMALL AMOUNTS OF HIGHLY FLAMMABLE HYDROGEN GAS
MAY BE GENERATED DURING CHARGING AND OPERATION OF BATTERIES. AVOID OPEN
FLAMES/SPARKS/OTHER SOURCES OF IGNITION NEAR BATTERY.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
SULFURIC ACID VAPORS ARE GENERATED UPON OVERCHARGE AND POLYPROPYLENE CASE
FAILURE. USE ADEQUATE VENTILATION. AVOID OPEN FLAMES/SPARKS/OTHER SOURCES
OF IGNITION NEAR BATTERY. CAREFULLY FOLLOW MANUFACTURER'S INSTRUCTIONS FOR
INSTALLATION AND SERVICE. DO NOT ALLOW METALLIC ARTICLES TO SIMULTANEOUSLY
CONTACT THE NEGATIVE AND POSITIVE TERMINALS OF A BATTERY, AS A SHORT
CIRCUIT WILL CAUSE HIGH CURRENT FLOW; CREATE HIGH HEAT AND THE POSSIBILITY
OF FIRE. USE ADEQUATE VENTILATION.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PROCEDURES FOR CLEANUP:
AVOID CONTACT WITH ANY SPILLED MATERIAL. CONTAIN SPILL, ISOLATE HAZARD
AREA, AND DENY ENTRY. LIMIT SITE ACCESS TO EMERGENCY RESPONDERS. NEUTRALIZE
WITH SODIUM BICARBONATE, SODA ASH, LIME OR OTHER NEUTRALIZING AGENT. PLACE
BATTERY IN SUITABLE CONTAINER FOR DISPOSAL. DISPOSE OF CONTENTS/CONTAINER
IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
SODIUM BICARBONATE, SODA ASH, SAND, LIME OR OTHER NEUTRALIZING AGENT SHOULD
BE KEPT ON-SITE FOR SPILL REMEDIATION.
PERSONAL PRECAUTIONS:
ACID RESISTANT APRONS, BOOTS AND PROTECTIVE CLOTHING. ANSI APPROVED SAFETY
GLASSES WITH SIDE SHIELDS/FACE SHIELD RECOMMENDED.
ENVIRONMENTAL PRECAUTIONS:
LEAD AND ITS COMPOUNDS AND SULFURIC ACID CAN POSE A SEVERE THREAT TO THE
ENVIRONMENT. CONTAMINATION OF WATER, SOIL AND AIR SHOULD BE PREVENTED.
| SECTION 7 - HANDLING AND STORAGE | |
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
STORE AWAY FROM REACTIVE MATERIALS, OPEN FLAMES AND SOURCES OF IGNITION AS
DEFINED IN SECTION 10 - STABILITY AND REACTIVITY DATA. STORE BATTERIES IN
COOL, DRY, WELL-VENTILATED AREAS. BATTERIES SHOULD BE STORED UNDER ROOF FOR
PROTECTION AGAINST ADVERSE WEATHER CONDITIONS. AVOID DAMAGE TO CONTAINERS.
DO NOT ALLOW THE POSITIVE AND NEGATIVE TERMINALS TO CONTACT EACH OTHER, A
SHORT CIRCUIT WILL CAUSE HIGH CURRENT FLOW, CREATING HIGH HEAT AND THE
POSSIBILITY OF A FIRE.
PRECAUTIONS DURING CHARGING:
USE PROPER VOLTAGES DURING CHARGING (SEE BATTERY LABEL). NEVER USE A
BATTERY THAT HAS LESS THAN 80% OF RATED CAPACITY AND NEVER "JUMP START" AN
AIRCRAFT THAT HAS A "DEAD" OR DISCHARGED BATTERY. ALWAYS REMOVE A "DEAD"
BATTERY FROM THE AIRCRAFT AND PERFORM A CAPACITY TEST TO VERIFY
AIRWORTHINESS. CHARGE AT CONSTANT POTENTIAL (CONSTANT VOLTAGE) ONLY. FOR
OPTIMUM LIFE, BATTERY CHARGE VOLTAGE SHOULD BE ADJUSTED WITH THE BATTERY
OPERATING TEMPERATURE.
OTHER PRECAUTIONS:
GOOD PERSONAL HYGIENE AND WORK PRACTICES ARE MANDATORY. REFRAIN FROM
EATING, DRINKING OR SMOKING IN WORK AREAS. THOROUGHLY WASH HANDS, FACE,
NECK AND ARMS, BEFORE EATING, DRINKING AND SMOKING. WORK CLOTHES AND
EQUIPMENT SHOULD REMAIN IN DESIGNATED LEAD CONTAMINATED AREAS, AND NEVER
TAKEN HOME OR LAUNDERED WITH PERSONAL CLOTHING. WASH SOILED CLOTHING, WORK
CLOTHES AND EQUIPMENT BEFORE REUSE.
| SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
RESPIRATORY PROTECTION:
NONE REQUIRED UNDER NORMAL CONDITIONS. ACID/GAS NIOSH APPROVED RESPIRATOR
IS REQUIRED WHEN THE PEL IS EXCEEDED OR EMPLOYEE EXPERIENCES RESPIRATORY
IRRITATION.
VENTILATION:
STORE AND HANDLE IN DRY VENTILATED AREA. IF MECHANICAL VENTILATION IS USED,
COMPONENTS MUST BE ACID-RESISTANT.
SKIN PROTECTION:
WEAR RUBBER OR PLASTIC ACID RESISTANT GLOVES. UNDER SEVERE EXPOSURE OR
EMERGENCY CONDITIONS, WEAR ACID-RESISTANT CLOTHING, GLOVES, AND BOOTS.
EYE PROTECTION:
ANSI APPROVED SAFETY GLASSES WITH SIDE SHIELDS/FACE SHIELD RECOMMENDED
OTHER PROTECTION:
SAFETY SHOWER AND EYEWASH. CHEMICALLY IMPERVIOUS APRON AND FACE SHIELD
RECOMMENDED WHEN ADDING WATER OR ELECTROLYTE TO BATTERIES (NOT REQUIRED
FOR SEALED, NON-SPILLABLE BATTERIES)
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING POINT: NOT APPLICABLE
VAPOR PRESSURE: NOT APPLICABLE
SPECIFIC GRAVITY: 1.250-1.320
PH: <2
MELTING POINT: >320 DEG. F (POLYPROPYLENE)
PERCENT VOLATILE BY VOLUME: NOT APPLICABLE
VAPOR DENSITY:
HYDROGEN: 0.069 (AIR = 1)
ELECTROLYTE: 3.4 @ STP (AIR = 1)
EVAPORATION RATE: NOT APPLICABLE
SOLUBILITY IN WATER: 100% SOLUBLE (ELECTROLYTE)
REACTIVITY IN WATER: ELECTROLYTE - WATER REACTIVE (1)
APPEARANCE AND ODOR:
BATTERY:
CO-POLYMER POLYPROPYLENE, SOLID; MAY BE CONTAINED WITHIN AN OUTER CASING OF
ALUMINUM OR STEEL. CASE HAS METAL TERMINALS.
LEAD: GRAY, METALLIC, SOLID; BROWN/GREY OXIDE
ELECTROLYTE: ODORLESS, LIQUID ABSORBED IN GLASS MAT MATERIAL.
NO APPARENT ODOR.
| SECTION 10 - STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID:
AVOID OVERCHARGING AND SMOKING, OR SPARKS NEAR BATTERY SURFACE. HIGH
TEMPERATURES-CASES DECOMPOSE AT >320 DEG. F.
INCOMPATIBILITY (MATERIALS TO AVOID):
SPARKS, OPEN FLAMES, KEEP BATTERY AWAY FROM STRONG OXIDIZERS.
HAZARDOUS DECOMPOSITION PRODUCTS:
COMBUSTION CAN PRODUCE SULFUR DIOXIDE, CARBON MONOXIDE, SULFUR TRIOXIDE,
HYDROGEN SULFIDE, AND SULFURIC ACID MIST.
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
LEAD:
THE PRIMARY ROUTES OF EXPOSURE TO LEAD ARE INGESTION OR INHALATION OF DUST
AND FUMES.
ACUTE:
INHALATION/INGESTION:
EXPOSURE TO LEAD AND ITS COMPOUNDS MAY CAUSE HEADACHE, NAUSEA, VOMITING,
ABDOMINAL SPASMS, FATIGUE, SLEEP DISTURBANCES, WEIGHT LOSS, ANEMIA, AND
PAIN IN THE LEGS, ARMS AND JOINTS. KIDNEY DAMAGE, AS WELL AS ANEMIA, CAN
OCCUR FROM ACUTE EXPOSURE.
CHRONIC:
INHALATION/INGESTION:
PROLONGED EXPOSURE TO LEAD AND ITS COMPOUNDS MAY PRODUCE MANY OF THE
SYMPTOMS OF SHORT-TERM EXPOSURE AND MAY ALSO CAUSE CENTRAL NERVOUS SYSTEM
DAMAGE, GASTROINTESTINAL DISTURBANCES, ANEMIA, AND WRIST DROP. SYMPTOMS OF
CENTRAL NERVOUS SYSTEM DAMAGE INCLUDE FATIGUE, HEADACHES, TREMORS,
HYPERTENSION, HALLUCINATION, CONVULSIONS AND DELIRIUM. KIDNEY DYSFUNCTION
AND POSSIBLE INJURY HAS ALSO BEEN ASSOCIATED WITH CHRONIC LEAD POISONING.
CHRONIC OVER-EXPOSURE TO LEAD HAS BEEN IMPLICATED AS A CAUSATIVE AGENT FOR
THE IMPAIRMENT OF MALE AND FEMALE REPRODUCTIVE CAPACITY. PREGNANT WOMEN
SHOULD BE PROTECTED FROM EXCESSIVE EXPOSURE. LEAD CAN CROSS THE PLACENTAL
BARRIER AND UNBORN CHILDREN MAY SUFFER NEUROLOGICAL DAMAGE OR DEVELOPMENTAL
PROBLEMS DUE TO EXCESSIVE LEAD EXPOSURE IN PREGNANT WOMEN.
SULFURIC ACID:
HARMFUL EXPOSURE TO SULFURIC ACID CAN OCCUR BY ALL ROUTES OF ENTRY.
ACUTE: SEVERE IRRITATION, BURNS, AND ULCERATION. CAN CAUSE BLINDNESS.
CARCENOGENICITY:
SULFURIC ACID:
THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) HAS CLASSIFIED
"STRONG INORGANIC ACID MIST CONTAINING SULFURIC ACID" AS A CATEGORY I
CARCINOGEN, A SUBSTANCE THAT IS CARCINOGENIC TO HUMANS. INORGANIC SULFURIC
ACID MIST IS NOT GENERATED UNDER NORMAL USE.
LEAD:
LEAD IS LISTED AS A 2B CARCINOGEN, LIKELY CARCINOGENIC TO ANIMALS, OTHER
THAN HUMANS, AT EXTREME DOSE LEVELS. LEAD COMPOUNDS, BUT NOT LEAD, ARE
CLASSIFIED AS POSSIBLY TOXIC TO REPRODUCTION:
MAY CAUSE HARM TO THE UNBORN CHILD.
| SECTION 12 - ECOLOGICAL INFORMATION | |
ENVIRONMENTAL FATE:
LEAD IS PERSISTENT IN SOIL AND SEDIMENT. IN MOST SURFACE WATER AND
GROUNDWATER, LEAD FORMS COMPOUNDS WITH ANIONS SUCH AS HYDROXIDES,
CARBONATES, SULFATES, AND PHOSPHATES, AND PRECIPITATES OUT OF THE WATER.
MOBILITY OF METALLIC LEAD BETWEEN ECOLOGICAL COMPARTMENTS IS SLOW. MOST
LEAD IS STRONGLY RETAINED IN SOIL, RESULTING IN LITTLE MOBILITY. LEAD MAY
BE IMMOBILIZED BY ION EXCHANGE WITH HYDROUS OXIDES OR CLAYS OR BY CHELATION
WITH HUMIC OR FULVIC ACIDS IN THE SOIL. LEAD (DISSOLVED PHASE) IS
BIOACCUMULATED BY PLANTS AND ANIMALS, BOTH AQUATIC AND TERRESTRIAL.
AQUATIC TOXICITY:
SULFURIC ACID:
24-HR LC50, FRESHWATER FISH (BRACHYDANIO RERIO): 82 MG/L
96-HR LOEC, FRESHWATER FISH (CYPRINUS CARPIO): 22 MG/L
LEAD:
48-HR LC50 (MODELED FOR AQUATIC INVERTEBRATES:
<1 MG/L, BASED ON LEAD BULLION
ADDITIONAL INFORMATION:
VOLATILE ORGANIC COMPOUNDS (VOC): 0% (BY VOLUME)
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
FULLRIVER BATTERIES ARE 100% RECYCLABLE BY ANY LICENSED RECLAMATION
OPERATION. BECAUSE THESE BATTERIES CONTAIN LEAD, SULFURIC ACID, AND OTHER
HAZARDOUS MATERIALS, THEY MUST NEVER BE DISCARDED IN THE TRASH OR IN A
LANDFILL. SMALL QUANTITIES CAN BE TAKEN TO LOCAL HOUSEHOLD HAZARDOUS WASTE
MANAGEMENT FACILITIES, WHICH ARE LICENSED TO HANDLE THEM. FOR ASSISTANCE,
PLEASE CALL FULLRIVER BATTERY AT 800-522-8191 OR USE EITHER OF THE
FOLLOWING LINKS:
HTTP://WWW.EHSO.COM/FIND A RECYCLING CENTER.PHP.
HTTP://WWW.EHSO.COM/EHSHOME/BATTERIES.PHP
| SECTION 14 - TRANSPORT INFORMATION | |
ALL FULLRIVER AGM BATTERIES ARE VALVE REGULATED LEAD ACID (VRLA)
BATTERIES - HGL, DC, HGHL, AND FFD SERIES. FULLRIVER'S VRLA BATTERIES HAVE
PASSED VIBRATION, PRESSURE DIFFERENTIAL AND FREE FLOWING ACID TESTS UNDER
49 CFR173.159A, THE VIBRATION AND PRESSURE DIFFERENTIAL TEST UNDER IATA
PACKING INSTRUCTION 872, MEET IATA SPECIAL PROVISIONS A48, A67, A164 &
A183, AND IMDG SPECIAL PROVISIONS 238.1 & 238.2. THE BATTERIES ARE SECURELY
PACKAGED, PROTECTED FROM SHORT CIRCUITS AND LABELED "NON-SPILLABLE."
FULLRIVER'S VRLA BATTERIES ARE EXEMPT FROM DOT HAZARDOUS MATERIAL
REGULATIONS, IATA DANGEROUS GOODS REGULATIONS, AND IMDG CODE.
US DOT:
EXEMPTED FROM THE REQUIREMENTS BECAUSE BATTERIES HAVE PASSED THE VIBRATION
AND PRESSURE DIFFERENTIAL PERFORMANCE TESTS, AND RUPTURED CASE TEST FOR
NONSPILLABLE DESIGNATION.
IMO:
EXEMPTED FROM THE REQUIREMENTS BECAUSE BATTERIES HAVE PASSED THE VIBRATION
AND PRESSURE DIFFERENTIAL PERFORMANCE TESTS, AND RUPTURED CASE TEST FOR
NONSPILLABLE DESIGNATION.
AND, WHEN PACKAGED FOR TRANSPORT, THE TERMINALS ARE PROTECTED FROM SHORT
CIRCUIT.
IATA:
EXEMPTED FROM THE REQUIREMENTS BECAUSE BATTERIES HAVE PASSED THE VIBRATION
AND PRESSURE DIFFERENTIAL PERFORMANCE TESTS, AND RUPTURED CASE TEST FOR
NONSPILLABLE DESIGNATION.
AND WHEN PACKAGED FOR TRANSPORT, THE TERMINALS ARE PROTECTED FROM SHORT
CIRCUIT. THE WORDS "NOT RESTRICTED" AND THE SPECIAL PROVISION NUMBERS MUST
BE INCLUDED IN THE DESCRIPTION OF THE SUBSTANCE ON THE AIR WAYBILL AS
REQUIRED BY 8.2.6, WHEN AN AIR WAYBILL IS ISSUED.
| SECTION 15 - REGULATORY INFORMATION | |
U.S. HAZARDOUS UNDER HAZARD COMMUNICATION STANDARD:
LEAD: YES
ARSENIC: YES
SULFURIC ACID: YES
INGREDIENTS LISTED ON TSCA INVENTORY: YES
CERCLA SECTION 304 HAZARDOUS SUBSTANCES:
LEAD: YES
RQ: N/A*
ARSENIC: YES
RQ: 1 POUND
SULFURIC ACID: YES
RQ: 1000 POUNDS
* RQ:
REPORTING NOT REQUIRED WHEN DIAMETER OF THE PIECES OF SOLID METAL RELEASED
IS EQUAL TO OR EXCEEDS 100 HM (MICROMETERS).
EPCRA SECTION 302 EXTREMELY HAZARDOUS SUBSTANCE:
SULFURIC ACID: YES
EPCRA SECTION 313 TOXIC RELEASE INVENTORY:
LEAD - CAS NO: 7439-92-1
ARSENIC - CAS NO: 7440-38-2
SULFURIC ACID - CAS NO: 7664-93-9
STATE REGULATIONS (US):
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS LEAD, LEAD COMPOUNDS, AND OTHER CHEMICALS, ALL KNOWN
TO STATE TO CAUSE CANCER AND REPRODUCTIVE HARM: LEAD (CAS# 7439-921).
INTERNATIONAL REGULATIONS:
DISTRIBUTION INTO QUEBEC TO FOLLOW CANADIAN CONTROLLED PRODUCT REGULATIONS
(CPR) 24(1) AND 24(2).
DISTRIBUTION INTO THE EU TO FOLLOW APPLICABLE DIRECTIVES TO THE USE,
IMPORT/EXPORT OF THE PRODUCT AS-SOLD.
| SECTION 16 - OTHER INFORMATION | |
THE INFORMATION ABOVE IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST
INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, FULLRIVER BATTERY MAKES NO
WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED,
WITH RESPECT TO SUCH INFORMATION, AND WE ASSUME NO LIABILITY RESULTING FROM
ITS USE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE
SUITABILITY OF THE INFORMATION FOR THEIR PARTICULAR PURPOSES. ALTHOUGH
REASONABLE PRECAUTIONS HAVE BEEN TAKEN IN THE PREPARATION OF THE DATA
CONTAINED HEREIN, IT IS OFFERED SOLELY FOR YOUR INFORMATION, CONSIDERATION
AND INVESTIGATION. THIS SAFETY DATA SHEET PROVIDES GUIDELINES FOR THE SAFE
HANDLING AND USE OF THIS PRODUCT; IT DOES NOT AND CANNOT ADVISE ON ALL
POSSIBLE SITUATIONS, THEREFORE, YOUR SPECIFIC USE OF THIS PRODUCT SHOULD
BE EVALUATED TO DETERMINE IF ADDITIONAL PRECAUTIONS ARE REQUIRED.
THE DATA/INFORMATION CONTAINED HEREIN HAS BEEN REVIEWED AND APPROVED FOR
GENERAL RELEASE ON THE BASIS THAT THIS DOCUMENT CONTAINS NO
EXPORT-CONTROLLED INFORMATION.
FORM SDS REV.: 06/04/2015
SAFETY DATA SHEET
F77XXY16174-4357
| SECTION 1. IDENTIFICATION | |
PRODUCT NAME: QUICK DRY ENAMEL EP-YELLOW 908232
PRODUCT CODE: F77XXY16174-4357
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS #: NOT APPLICABLE.
PRODUCT TYPE: LIQUID.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: NOT APPLICABLE.
MANUFACTURER:
THE SHERWIN-WILLIAMS COMPANY
101 PROSPECT AVENUE N.W.
CLEVELAND, OHIO 44115
EMERGENCY TELEPHONE NUMBER OF THE COMPANY: (216) 566-2917
PRODUCT INFORMATION TELEPHONE NUMBER: NOT AVAILABLE.
REGULATORY INFORMATION TELEPHONE NUMBER: (216) 566-2902
TRANSPORTATION EMERGENCY TELEPHONE NUMBER: (800) 424-9300
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE LIQUIDS: CATEGORY 2
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/ EYE IRRITATION: CATEGORY 2A
CARCINOGENICITY: CATEGORY 2
TOXIC TO REPRODUCTION (UNBORN CHILD): CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (RESPIRATORY TRACT
IRRITATION): CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (NARCOTIC EFFECTS):
CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2
ASPIRATION HAZARD: CATEGORY 1
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN ACUTE
TOXICITY: 10.3%
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
SUSPECTED OF DAMAGING THE UNBORN CHILD.
SUSPECTED OF CAUSING CANCER.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE GLOVES. WEAR EYE
OR FACE PROTECTION. WEAR PROTECTIVE CLOTHING. KEEP AWAY FROM HEAT, HOT
SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. NO SMOKING. USE
EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING AND ALL MATERIAL-HANDLING
EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST
STATIC DISCHARGE. KEEP CONTAINER TIGHTLY CLOSED. USE ONLY OUTDOORS OR IN A
WELL-VENTILATED AREA. DO NOT BREATHE VAPOR. WASH HANDS THOROUGHLY AFTER
HANDLING.
RESPONSE: GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER OR
SHOWER.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. TAKE OFF CONTAMINATED CLOTHING AND WASH
IT BEFORE REUSE.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE: STORE LOCKED UP. STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. CONTAINS SOLVENTS WHICH CAN
CAUSE PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL OR
FATAL.
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. FOR INDUSTRIAL USE
ONLY.
PLEASE REFER TO THE SDS FOR ADDITIONAL INFORMATION. KEEP OUT OF REACH OF
CHILDREN. DO NOT TRANSFER CONTENTS TO OTHER CONTAINERS FOR STORAGE.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS NUMBER/OTHER IDENTIFIERS:
INGREDIENT NAME % BY WEIGHT CAS NUMBER
TOLUENE 17.35 108-88-3
XYLENE 15.95 1330-20-7
LT. ALIPHATIC HYDROCARBON SOLVENT 10.29 64742-89-8
1-METHOXY-2-PROPANOL ACETATE 5.45 108-65-6
ETHYLBENZENE 2.91 100-41-4
1,2,4-TRIMETHYLBENZENE 1.45 95-63-6
CUMENE 0.19 98-82-8
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH AND HENCE REQUIRE REPORTING IN THIS
SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IF
NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST OCCURS,
PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED PERSONNEL. IT MAY BE
DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION.
GET MEDICAL ATTENTION. IF NECESSARY, CALL A POISON CENTER OR PHYSICIAN. IF
UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL ATTENTION
IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A
COLLAR, TIE, BELT OR WAISTBAND. IN CASE OF INHALATION OF DECOMPOSITION
PRODUCTS IN A FIRE, SYMPTOMS MAY BE DELAYED. THE EXPOSED PERSON MAY NEED
TO BE KEPT UNDER MEDICAL SURVEILLANCE FOR 48 HOURS.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL
ATTENTION. WASH CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. WASH
OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH AIR
AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL HAS
BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES
OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS VOMITING MAY BE
DANGEROUS. ASPIRATION HAZARD IF SWALLOWED. CAN ENTER LUNGS AND CAUSE
DAMAGE. DO NOT INDUCE VOMITING. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT
LOW SO THAT VOMIT DOES NOT ENTER THE LUNGS. NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET
MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT
CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS OR
DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
INGESTION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY BE FATAL IF
SWALLOWED AND ENTERS AIRWAYS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
NAUSEA OR VOMITING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
IN CASE OF INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY BE
DELAYED. THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL SURVEILLANCE
FOR 48 HOURS.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT
MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE DRY CHEMICAL, CO2, WATER SPRAY (FOG) OR FOAM.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER JET.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HIGHLY FLAMMABLE LIQUID AND VAPOR. IN A FIRE OR IF HEATED, A PRESSURE
INCREASE WILL OCCUR AND THE CONTAINER MAY BURST, WITH THE RISK OF A
SUBSEQUENT EXPLOSION. THE VAPOR/GAS IS HEAVIER THAN AIR AND WILL SPREAD
ALONG THE GROUND. VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL
A CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. RUNOFF TO
SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
NITROGEN OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF THE
INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE AREA
IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
SHUT OFF ALL IGNITION SOURCES. NO FLARES, SMOKING OR FLAMES IN HAZARD AREA.
AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. DILUTE WITH WATER AND MOP UP IF
WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE, ABSORB WITH AN INERT
DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER. DISPOSE
OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH
SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN
AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND,
EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR
DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF VIA A
LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY
POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). AVOID
EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. AVOID EXPOSURE DURING
PREGNANCY. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD. DO NOT GET IN EYES OR ON SKIN OR CLOTHING. DO NOT BREATHE VAPOR
OR MIST. DO NOT SWALLOW. USE ONLY WITH ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. DO NOT ENTER STORAGE
AREAS AND CONFINED SPACES UNLESS ADEQUATELY VENTILATED. KEEP IN THE
ORIGINAL CONTAINER OR AN APPROVED ALTERNATIVE MADE FROM A COMPATIBLE
MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT IN USE. STORE AND USE AWAY FROM
HEAT, SPARKS, OPEN FLAME OR ANY OTHER IGNITION SOURCE. USE EXPLOSION-PROOF
ELECTRICAL (VENTILATING, LIGHTING AND MATERIAL HANDLING) EQUIPMENT. USE
ONLY NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST ELECTROSTATIC
DISCHARGES. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS.
DO NOT REUSE CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN A SEGREGATED AND
APPROVED AREA. STORE IN ORIGINAL CONTAINER PROTECTED FROM DIRECT SUNLIGHT
IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10) AND FOOD AND DRINK. STORE LOCKED UP. ELIMINATE ALL
IGNITION SOURCES. SEPARATE FROM OXIDIZING MATERIALS. KEEP CONTAINER TIGHTLY
CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS THAT HAVE BEEN OPENED
MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT LEAKAGE. DO NOT
STORE IN UNLABELED CONTAINERS. USE APPROPRIATE CONTAINMENT TO AVOID
ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS (OSHA UNITED STATES):
INGREDIENT NAME EXPOSURE LIMITS
TOLUENE OSHA PEL Z2 (UNITED STATES, 2/2013).
TWA: 200 PPM 8 HOURS.
CEIL: 300 PPM
AMP: 500 PPM 10 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 100 PPM 10 HOURS.
TWA: 375 MG/M3 10 HOURS.
STEL: 150 PPM 15 MINUTES.
STEL: 560 MG/M3 15 MINUTES.
ACGIH TLV (UNITED STATES, 3/2016).
TWA: 20 PPM 8 HOURS.
XYLENE ACGIH TLV (UNITED STATES, 3/2016).
TWA: 100 PPM 8 HOURS.
TWA: 434 MG/M3 8 HOURS.
STEL: 150 PPM 15 MINUTES.
STEL: 651 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 6/2016).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
LT. ALIPHATIC HYDROCARBON SOLVENT NONE.
1-METHOXY-2-PROPANOL ACETATE AIHA WEEL (UNITED STATES, 10/2011).
TWA: 50 PPM 8 HOURS.
ETHYLBENZENE ACGIH TLV (UNITED STATES, 3/2016).
TWA: 20 PPM 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 100 PPM 10 HOURS.
TWA: 435 MG/M3 10 HOURS.
STEL: 125 PPM 15 MINUTES.
STEL: 545 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 6/2016).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
1,2,4-TRIMETHYLBENZENE ACGIH TLV (UNITED STATES, 3/2016).
TWA: 25 PPM 8 HOURS.
TWA: 123 MG/M3 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 25 PPM 10 HOURS.
TWA: 125 MG/M3 10 HOURS.
CUMENE ACGIH TLV (UNITED STATES, 3/2016).
TWA: 50 PPM 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
ABSORBED THROUGH SKIN.
TWA: 50 PPM 10 HOURS.
TWA: 245 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 6/2016).
ABSORBED THROUGH SKIN.
TWA: 50 PPM 8 HOURS.
TWA: 245 MG/M3 8 HOURS.
OCCUPATIONAL EXPOSURE LIMITS (CANADA):
INGREDIENT NAME EXPOSURE LIMITS
TOLUENE CA ALBERTA PROVINCIAL (CANADA, 4/2009).
ABSORBED THROUGH SKIN.
8 HRS OEL: 50 PPM 8 HOURS.
8 HRS OEL: 188 MG/M3 8 HOURS.
CA BRITISH COLUMBIA PROVINCIAL (CANADA,
5/2015).
TWA: 20 PPM 8 HOURS.
CA ONTARIO PROVINCIAL (CANADA, 7/2015).
TWA: 20 PPM 8 HOURS.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
ABSORBED THROUGH SKIN.
TWAEV: 50 PPM 8 HOURS.
TWAEV: 188 MG/M3 8 HOURS.
CA SASKATCHEWAN PROVINCIAL (CANADA,
7/2013). ABSORBED THROUGH SKIN.
STEL: 60 PPM 15 MINUTES.
TWA: 50 PPM 8 HOURS.
XYLENE CA ALBERTA PROVINCIAL (CANADA, 4/2009).
8 HRS OEL: 100 PPM 8 HOURS.
15 MIN OEL: 651 MG/M3 15 MINUTES.
15 MIN OEL: 150 PPM 15 MINUTES.
8 HRS OEL: 434 MG/M3 8 HOURS.
CA BRITISH COLUMBIA PROVINCIAL (CANADA,
5/2015).
TWA: 100 PPM 8 HOURS.
STEL: 150 PPM 15 MINUTES.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 100 PPM 8 HOURS.
TWAEV: 434 MG/M3 8 HOURS.
STEV: 150 PPM 15 MINUTES.
STEV: 651 MG/M3 15 MINUTES.
CA ONTARIO PROVINCIAL (CANADA, 7/2015).
STEL: 150 PPM 15 MINUTES.
TWA: 100 PPM 8 HOURS.
CA SASKATCHEWAN PROVINCIAL (CANADA,
7/2013).
STEL: 150 PPM 15 MINUTES.
TWA: 100 PPM 8 HOURS.
OCCUPATIONAL EXPOSURE LIMITS (MEXICO):
INGREDIENT NAME EXPOSURE LIMITS
TOLUENE NOM-010-STPS (MEXICO, 4/2016).
LMPE-PPT: 20 PPM 8 HOURS.
XYLENE NOM-010-STPS (MEXICO, 4/2016).
LMPE-CT: 150 PPM 15 MINUTES.
LMPE-PPT: 100 PPM 8 HOURS.
ETHYLBENZENE NOM-010-STPS (MEXICO, 4/2016).
LMPE-PPT: 20 PPM 8 HOURS.
1,2,4-TRIMETHYLBENZENE NOM-010-STPS (MEXICO, 4/2016).
LMPE-PPT: 25 PPM 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS. THE
ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS
BELOW ANY LOWER EXPLOSIVE LIMITS. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD.
APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY CONTAMINATED
CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE THAT EYEWASH
STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTISTATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
BASED ON THE HAZARD AND POTENTIAL FOR EXPOSURE, SELECT A RESPIRATOR THAT
MEETS THE APPROPRIATE STANDARD OR CERTIFICATION. RESPIRATORS MUST BE USED
ACCORDING TO A RESPIRATORY PROTECTION PROGRAM TO ENSURE PROPER FITTING,
TRAINING, AND OTHER IMPORTANT ASPECTS OF USE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: VARIOUS
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT: NOT AVAILABLE.
BOILING POINT: 105 DEG. C (221 DEG. F)
FLASH POINT:
CLOSED CUP: 10 DEG. C (50 DEG. F) [PENSKY-MARTENS CLOSED CUP]
EVAPORATION RATE: 2 (BUTYL ACETATE = 1)
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 0.9%
UPPER: 13.1%
VAPOR PRESSURE: 0.27 KPA (2 MMHg) [AT 20 DEG. C]
VAPOR DENSITY: 3.1 [AIR = 1]
RELATIVE DENSITY: 0.99
SOLUBILITY: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (40 DEG. C (104 DEG. F)): <0.205 CM2/S (<20.5 CST)
MOLECULAR WEIGHT: NOT APPLICABLE.
AEROSOL PRODUCT:
HEAT OF COMBUSTION: 18.7 KJ/G
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME). DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT OR
SOURCES OF IGNITION. DO NOT ALLOW VAPOR TO ACCUMULATE IN LOW OR CONFINED
AREAS.
INCOMPATIBLE MATERIALS:
REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS: OXIDIZING MATERIALS
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
TOLUENE LC50 INHALATION VAPOR RAT 49 G/M3 4 HOURS
LD50 ORAL RAT 636 MG/KG
XYLENE LC50 INHALATION GAS. RAT 5000 PPM 4 HOURS
LD50 ORAL RAT 4300 MG/KG
1-METHOXY-2- LD50 DERMAL RABBIT >5 G/KG
PROPANOL ACETATE LD50 ORAL RAT 8532 MG/KG
ETHYLBENZENE LD50 DERMAL RABBIT >5000 MG/KG
LD50 ORAL RAT 3500 MG/KG
1,2,4-TRIMETHYL- LC50 INHALATION VAPOR RAT 18000 MG/M3 4 HOURS
BENZENE LD50 ORAL RAT 5 G/KG
CUMENE LC50 INHALATION VAPOR RAT 39000 MG/M3 4 HOURS
LD50 ORAL RAT 1400 MG/KG
IRRITATION/CORROSION:
PRODUCT/ RESULT SPECIES SCORE EXPOSURE OBSERVATION
INGREDIENT
NAME
TOLUENE EYES: RABBIT 0.5 MINUTES
MILD IRRITANT 100 MILLIGRAMS
EYES: RABBIT 870 MICROGRAMS
MILD IRRITANT
EYES: RABBIT 24 HOURS
SEVERE 2 MILLIGRAMS
IRRITANT
SKIN: PIG 24 HOURS
MILD IRRITANT 250 MICROLITERS
SKIN: RABBIT 435 MILLIGRAMS
MILD IRRITANT
SKIN: RABBIT 24 HOURS
MODERATE 20 MILLIGRAMS
IRRITANT
SKIN: RABBIT 500 MILLIGRAMS
MODERATE
IRRITANT
XYLENE EYES: RABBIT 87 MILLIGRAMS
MILD IRRITANT
EYES: RABBIT 24 HOURS
SEVERE 5 MILLIGRAMS
IRRITANT
SKIN: RAT 8 HOURS
MILD IRRITANT 60 MICROLITERS
SKIN: RABBIT 24 HOURS
MODERATE 500 MILLIGRAMS
IRRITANT
SKIN: RABBIT 100 PERCENT
MODERATE
IRRITANT
ETHYLBENZENE EYES: RABBIT 500 MILLIGRAMS
SEVERE
IRRITANT
SKIN: RABBIT 24 HOURS
MILD IRRITANT 15 MILLIGRAMS
CUMENE EYES: RABBIT 24 HOURS
MILD IRRITANT 500 MILLIGRAMS
EYES: RABBIT 86 MILLIGRAMS
MILD IRRITANT
SKIN: RABBIT 24 HOURS
MILD IRRITANT 10 MILLIGRAMS
SKIN: RABBIT 24 HOURS
MODERATE 100 MILLIGRAMS
IRRITANT
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
TOLUENE 3
XYLENE 3
ETHYLBENZENE 2B
CUMENE 2B REASONABLY ANTICIPATED TO
BE A HUMAN CARCINOGEN.
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF TARGET ORGANS
EXPOSURE
TOLUENE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
XYLENE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
LT. ALIPHATIC CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
HYDROCARBON SOLVENT IRRITATION AND
NARCOTIC EFFECTS
ETHYLBENZENE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
1,2,4-TRIMETHYLBENZENE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION
CUMENE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY ROUTE OF TARGET ORGANS
EXPOSURE
TOLUENE CATEGORY 2 NOT DETERMINED NOT DETERMINED
XYLENE CATEGORY 2 NOT DETERMINED NOT DETERMINED
LT. ALIPHATIC CATEGORY 2 NOT DETERMINED NOT DETERMINED
HYDROCARBON SOLVENT
ETHYLBENZENE CATEGORY 2 NOT DETERMINED NOT DETERMINED
CUMENE CATEGORY 2 NOT DETERMINED NOT DETERMINED
ASPIRATION HAZARD:
NAME RESULT
TOLUENE ASPIRATION HAZARD - CATEGORY 1
XYLENE ASPIRATION HAZARD - CATEGORY 1
LT. ALIPHATIC HYDROCARBON SOLVENT ASPIRATION HAZARD - CATEGORY 1
ETHYLBENZENE ASPIRATION HAZARD - CATEGORY 1
1,2,4-TRIMETHYLBENZENE ASPIRATION HAZARD - CATEGORY 1
CUMENE ASPIRATION HAZARD - CATEGORY 1
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS OR
DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION.
INGESTION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY BE FATAL IF
SWALLOWED AND ENTERS AIRWAYS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
NAUSEA OR VOMITING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
CARCINOGENICITY:
SUSPECTED OF CAUSING CANCER. RISK OF CANCER DEPENDS ON DURATION AND LEVEL
OF EXPOSURE.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: SUSPECTED OF DAMAGING THE UNBORN CHILD.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 2795.3 MG/KG
INHALATION (GASES) 28129.2 PPM
INHALATION (VAPORS) 1113 MG/L
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
TOLUENE ACUTE EC50: ALGAE - 72 HOURS
12500 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: CRUSTACEANS - GAMMARUS 48 HOURS
11600 (MICRO)G/L PSEUDOLIMNAEUS - ADULT
FRESH WATER
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
6000 (MICRO)G/L MAGNA - JUVENILE
FRESH WATER (FLEDGLING, HATCHLING,
WEANLING)
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
5500 (MICRO)G/L KISUTCH - FRY
FRESH WATER
CHRONIC NOEC: DAPHNIA - DAPHNIA 21 DAYS
1000 (MICRO)G/L MAGNA
FRESH WATER
XYLENE ACUTE LC50: CRUSTACEANS - 48 HOURS
8500 (MICRO)G/L PALAEMONETES PUGIO
MARINE WATER
ACUTE LC50: FISH - PIMEPHALES 96 HOURS
13400 (MICRO)G/L PROMELAS
FRESH WATER
LT. ALIPHATIC ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
HYDROCARBON >100000 PPM MYKISS
SOLVENT FRESH WATER
ETHYLBENZENE ACUTE EC50: ALGAE - 72 HOURS
4600 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: ALGAE - 96 HOURS
3600 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: CRUSTACEANS - ARTEMIA 48 HOURS
6530 (MICRO)G/L SP. - NAUPLII
FRESH WATER
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
2930 (MICRO)G/L MAGNA - NEONATE
FRESH WATER
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
4200 (MICRO)G/L MYKISS
FRESH WATER
1,2,4-TRIMETHYL- ACUTE LC50: CRUSTACEANS - 48 HOURS
BENZENE 4910 (MICRO)G/L ELASMOPUS PECTENICRUS
MARINE WATER - ADULT
ACUTE LC50: FISH - PIMEPHALES 96 HOURS
7720 (MICRO)G/L PROMELAS
FRESH WATER
CUMENE ACUTE EC50: ALGAE - 72 HOURS
2600 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: CRUSTACEANS - ARTEMIA 48 HOURS
7400 (MICRO)G/L SP. - NAUPLII
FRESH WATER
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
10600 (MICRO)G/L MAGNA - NEONATE
FRESH WATER
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
2700 (MICRO)G/L MYKISS
FRESH WATER
PERSISTENCE AND DEGRADABILITY:
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
TOLUENE READILY
XYLENE READILY
1-METHOXY-2-PROPANOL READILY
ACETATE
ETHYLBENZENE READILY
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
TOLUENE 90 LOW
XYLENE 8.1 TO 25.9 LOW
LT. ALIPHATIC HYDROCARBON 10 TO 2500 HIGH
SOLVENT
1,2,4-TRIMETHYLBENZENE 243 LOW
CUMENE 35.48 LOW
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING
EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. VAPOR FROM PRODUCT
RESIDUES MAY CREATE A HIGHLY FLAMMABLE OR EXPLOSIVE ATMOSPHERE INSIDE THE
CONTAINER. DO NOT CUT, WELD OR GRIND USED CONTAINERS UNLESS THEY HAVE BEEN
CLEANED THOROUGHLY INTERNALLY. AVOID DISPERSAL OF SPILLED MATERIAL AND
RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
UN NUMBER UN1263 UN1263 UN1263
UN PROPER SHIPPING NAME PAINT PAINT PAINT
TRANSPORT HAZARD CLASS(ES) 3 3 3
FLAMMABLE CLASS 3, CLASS 3,
LIQUID, CLASS/ FLAMMABLE FLAMMABLE
DIVISION 3.1, LIQUIDS LIQUIDS
3.2, 3.3
PACKING GROUP II II II
ENVIRONMENTAL HAZARDS NO. NO. NO.
ADDITIONAL INFORMATION PRODUCT
CLASSIFIED
AS PER THE
FOLLOWING
SECTIONS
OF THE
TRANSPORTATION
OF DANGEROUS
GOODS
REGULATIONS:
2.18-2.19
(CLASS 3).
ERG NO.: ERG NO.: ERG NO.:
128 128 128
IATA IMDG
UN NUMBER UN1263 UN1263
UN PROPER SHIPPING NAME PAINT PAINT
TRANSPORT HAZARD CLASS(ES) 3 3
CLASS 3, CLASS 3 - FLAMMABLE
FLAMMABLE LIQUIDS LIQUIDS
PACKING GROUP II II
ENVIRONMENTAL HAZARDS NO. NO.
ADDITIONAL INFORMATION EMERGENCY SCHEDULES
(EMS): F-E, S-E
SPECIAL PRECAUTIONS FOR USER:
MULTI-MODAL SHIPPING DESCRIPTIONS ARE PROVIDED FOR INFORMATIONAL PURPOSES
AND DO NOT CONSIDER CONTAINER SIZES. THE PRESENCE OF A SHIPPING DESCRIPTION
FOR A PARTICULAR MODE OF TRANSPORT (SEA, AIR, ETC.), DOES NOT INDICATE THAT
THE PRODUCT IS PACKAGED SUITABLY FOR THAT MODE OF TRANSPORT. ALL PACKAGING
MUST BE REVIEWED FOR SUITABILITY PRIOR TO SHIPMENT, AND COMPLIANCE WITH THE
APPLICABLE REGULATIONS IS THE SOLE RESPONSIBILITY OF THE PERSON OFFERING
THE PRODUCT FOR TRANSPORT. PEOPLE LOADING AND UNLOADING DANGEROUS GOODS
MUST BE TRAINED ON ALL OF THE RISKS DERIVING FROM THE SUBSTANCES AND ON
ALL ACTIONS IN CASE OF EMERGENCY SITUATIONS.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT AVAILABLE.
PROPER SHIPPING NAME: NOT AVAILABLE.
SHIP TYPE: NOT AVAILABLE.
POLLUTION CATEGORY: NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
SARA 313:
SARA 313 (40 CFR 372.45) SUPPLIER NOTIFICATION CAN BE FOUND ON THE
ENVIRONMENTAL DATA SHEET.
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 2*
FLAMMABILITY 3
PHYSICAL HAZARDS 0
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON SDSS UNDER 29 CFR 1910.1200,
THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED MARK OF
THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA). HMIS(R*) MATERIALS MAY BE
PURCHASED EXCLUSIVELY FROM J. J. KELLER (800) 327-6868.
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
FLAMMABLE LIQUIDS - CATEGORY 2 ON BASIS OF TEST DATA
SKIN CORROSION/IRRITATION - CATEGORY 2 CALCULATION METHOD
SERIOUS EYE DAMAGE/ EYE IRRITATION - CATEGORY 2A CALCULATION METHOD
CARCINOGENICITY - CATEGORY 2 CALCULATION METHOD
TOXIC TO REPRODUCTION (UNBORN CHILD) - CATEGORY 2 CALCULATION METHOD
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CALCULATION METHOD
(RESPIRATORY TRACT IRRITATION) - CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CALCULATION METHOD
(NARCOTIC EFFECTS) - CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED CALCULATION METHOD
EXPOSURE) - CATEGORY 2
ASPIRATION HAZARD - CATEGORY 1 CALCULATION METHOD
HISTORY:
DATE OF PRINTING: 2/28/2017
DATE OF ISSUE/DATE OF REVISION: 2/28/2017
DATE OF PREVIOUS ISSUE: NO PREVIOUS VALIDATION
VERSION: 1
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
NOTICE TO READER:
IT IS RECOMMENDED THAT EACH CUSTOMER OR RECIPIENT OF THIS SAFETY DATA SHEET
(SDS) STUDY IT CAREFULLY AND CONSULT RESOURCES, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THIS INFORMATION IS
PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE DATE
HEREIN. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. THE INFORMATION
PRESENTED HERE APPLIES ONLY TO THE PRODUCT AS SHIPPED. THE ADDITION OF ANY
MATERIAL CAN CHANGE THE COMPOSITION, HAZARDS AND RISKS OF THE PRODUCT.
PRODUCTS SHALL NOT BE REPACKAGED, MODIFIED, OR TINTED EXCEPT AS
SPECIFICALLY INSTRUCTED BY SHERWIN-WILLIAMS, INCLUDING BUT NOT LIMITED TO
THE INCORPORATION OF NON SHERWIN-WILLIAMS PRODUCTS OR THE USE OR ADDITION
OF PRODUCTS IN PROPORTIONS NOT SPECIFIED BY SHERWIN-WILLIAMS. REGULATORY
REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN VARIOUS LOCATIONS
AND JURISDICTIONS. THE CUSTOMER/BUYER/USER IS RESPONSIBLE TO ENSURE THAT
HIS ACTIVITIES COMPLY WITH ALL COUNTRY, FEDERAL, STATE, PROVINCIAL OR LOCAL
LAWS. THE CONDITIONS FOR USE OF THE PRODUCT ARE NOT UNDER THE CONTROL OF
THE MANUFACTURER; THE CUSTOMER/BUYER/USER IS RESPONSIBLE TO DETERMINE THE
CONDITIONS NECESSARY FOR THE SAFE USE OF THIS PRODUCT. THE
CUSTOMER/BUYER/USER SHOULD NOT USE THE PRODUCT FOR ANY PURPOSE OTHER THAN
THE PURPOSE SHOWN IN THE APPLICABLE SECTION OF THIS SDS WITHOUT FIRST
REFERRING TO THE SUPPLIER AND OBTAINING WRITTEN HANDLING INSTRUCTIONS. DUE
TO THE PROLIFERATION OF SOURCES FOR INFORMATION SUCH AS
MANUFACTURER-SPECIFIC SDS, THE MANUFACTURER CANNOT BE RESPONSIBLE FOR SDSS
OBTAINED FROM ANY OTHER SOURCE.
MATERIAL SAFETY DATA SHEET
F77XXY16174-4357
00 01
DATE OF PREPARATION: FEB 28, 2017
| SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NUMBER: F77XXY16174-4357
PRODUCT NAME: QUICK DRY ENAMEL, EP-YELLOW 908232
MANUFACTURER'S NAME:
THE SHERWIN-WILLIAMS COMPANY
101 PROSPECT AVENUE N.W.
CLEVELAND, OH 44115
TELEPHONE NUMBERS AND WEBSITES:
REGULATORY INFORMATION: (216) 566-2902
MEDICAL EMERGENCY: (216) 566-2917
TRANSPORTATION EMERGENCY*: (800) 424-9300
*FOR CHEMICAL EMERGENCY ONLY (SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT)
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |
% BY WEIGHT CAS NUMBER INGREDIENT UNITS VAPOR PRESSURE
10 64742-89-8 LT. ALIPHATIC HYDROCARBON SOLVENT 12 MM
ACGIH TLV: 300 PPM
OSHA PEL: 300 PPM
17 108-88-3 TOLUENE 22 MM
ACGIH TLV: 20 PPM
OSHA PEL: 100 PPM (SKIN)
OSHA PEL: 150 PPM (SKIN) STEL
3 100-41-4 ETHYLBENZENE 7.1 MM
ACGIH TLV: 20 PPM
OSHA PEL: 100 PPM
OSHA PEL: 125 PPM STEL
16 1330-20-7 XYLENE 5.9 MM
ACGIH TLV: 100 PPM
ACGIH TLV: 150 PPM STEL
OSHA PEL: 100 PPM
OSHA PEL: 150 PPM STEL
1 95-63-6 1,2,4-TRIMETHYLBENZENE 2.03 MM
ACGIH TLV: 25 PPM
OSHA PEL: 25 PPM
5 108-65-6 1-METHOXY-2-PROPANOL ACETATE 1.8 MM
ACGIH TLV: NOT AVAILABLE
OSHA PEL: NOT AVAILABLE
| SECTION 3 - HAZARDS IDENTIFICATION | |
HMIS CODES:
HEALTH 2*
FLAMMABILITY 3
REACTIVITY 0
ROUTES OF EXPOSURE:
INHALATION OF VAPOR OR SPRAY MIST.
EYE OR SKIN CONTACT WITH THE PRODUCT, VAPOR OR SPRAY MIST.
EFFECTS OF OVEREXPOSURE:
EYES: IRRITATION.
SKIN: PROLONGED OR REPEATED EXPOSURE MAY CAUSE IRRITATION.
INHALATION: IRRITATION OF THE UPPER RESPIRATORY SYSTEM.
MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN
UNCONSCIOUSNESS AND POSSIBLY DEATH.
PROLONGED OVEREXPOSURE TO HAZARDOUS INGREDIENTS IN SECTION 2 MAY CAUSE
ADVERSE CHRONIC EFFECTS TO THE FOLLOWING ORGANS OR SYSTEMS:
THE LIVER
THE URINARY SYSTEM
THE HEMATOPOIETIC (BLOOD-FORMING) SYSTEM
THE CARDIOVASCULAR SYSTEM
THE REPRODUCTIVE SYSTEM
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF COORDINATION ARE INDICATIONS OF
EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS.
REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN
EXPOSURE.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NONE GENERALLY RECOGNIZED.
CANCER INFORMATION:
FOR COMPLETE DISCUSSION OF TOXICOLOGY DATA REFER TO SECTION 11.
| SECTION 4 - FIRST AID MEASURES | |
EYES:
FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET MEDICAL
ATTENTION.
SKIN:
WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
INHALATION:
IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET.
INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
| SECTION 5 - FIRE FIGHTING MEASURES | |
FLASH POINT: 50 DEG. F TCC
LEL: 0.9
UEL: 13.1
FLAMMABILITY CLASSIFICATION:
RED LABEL - FLAMMABLE, FLASH BELOW 100 DEG. F (38 DEG. C)
EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS.
DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY
CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN
MEDICAL ATTENTION.
SPECIAL FIRE FIGHTING PROCEDURES:
FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS
SHOULD BE USED.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT
PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED
TO EXTREME HEAT.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
REMOVE ALL SOURCES OF IGNITION. VENTILATE THE AREA.
REMOVE WITH INERT ABSORBENT.
| SECTION 7 - HANDLING AND STORAGE | |
STORAGE CATEGORY: DOL STORAGE CLASS IB
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
CONTENTS ARE FLAMMABLE. KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.
DURING USE AND UNTIL ALL VAPORS ARE GONE:
KEEP AREA VENTILATED - DO NOT SMOKE - EXTINGUISH ALL FLAMES, PILOT LIGHTS,
AND HEATERS - TURN OFF STOVES, ELECTRIC TOOLS AND APPLIANCES, AND ANY OTHER
SOURCES OF IGNITION.
CONSULT NFPA CODE. USE APPROVED BONDING AND GROUNDING PROCEDURES.
KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED CONTAINERS
WITH COMPLETE AND APPROPRIATE LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF
THE REACH OF CHILDREN.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
PRECAUTIONS TO BE TAKEN IN USE:
USE ONLY WITH ADEQUATE VENTILATION.
AVOID CONTACT WITH SKIN AND EYES. AVOID BREATHING VAPOR AND SPRAY MIST.
WASH HANDS AFTER USING.
THIS COATING MAY CONTAIN MATERIALS CLASSIFIED AS NUISANCE PARTICULATES
(LISTED "AS DUST" IN SECTION 2) WHICH MAY BE PRESENT AT HAZARDOUS LEVELS
ONLY DURING SANDING OR ABRADING OF THE DRIED FILM. IF NO SPECIFIC DUSTS
ARE LISTED IN SECTION 2, THE APPLICABLE LIMITS FOR NUISANCE DUSTS ARE
ACGIH TLV 10 MG/M3 (TOTAL DUST), 3 MG/M3 (RESPIRABLE FRACTION),
OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION).
VENTILATION:
LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE EXPOSURE TO
MATERIALS IN SECTION 2 IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION:
IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY
VENTILATION, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR
APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST MATERIALS IN SECTION 2.
WHEN SANDING OR ABRADING THE DRIED FILM, WEAR A DUST/MIST RESPIRATOR
APPROVED BY NIOSH/MSHA FOR DUST WHICH MAY BE GENERATED FROM THIS PRODUCT,
UNDERLYING PAINT, OR THE ABRASIVE.
PROTECTIVE GLOVES:
WEAR GLOVES WHICH ARE RECOMMENDED BY GLOVE SUPPLIER FOR PROTECTION AGAINST
MATERIALS IN SECTION 2.
EYE PROTECTION: WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
OTHER PRECAUTIONS:
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS
CAN BE HARMFUL OR FATAL.
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
PRODUCT WEIGHT:
8.23 LB/GAL
985 G/L
SPECIFIC GRAVITY: 0.99
BOILING POINT:
222 - 337 DEG. F
105 - 169 DEG. C
MELTING POINT: NOT AVAILABLE
VOLATILE VOLUME: 66%
EVAPORATION RATE: SLOWER THAN ETHER
VAPOR DENSITY: HEAVIER THAN AIR
SOLUBILITY IN WATER: NOT AVAILABLE
VOLATILE ORGANIC COMPOUNDS (VOC THEORETICAL - AS PACKAGED):
4.68 LB/GAL 561 G/L LESS WATER AND FEDERALLY EXEMPT SOLVENTS
4.68 LB/GAL 561 G/L EMITTED VOC
| SECTION 10 - STABILITY AND REACTIVITY | |
STABILITY: STABLE
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBILITY: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS:
BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
CHRONIC HEALTH HAZARDS:
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS
WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
ETHYLBENZENE IS CLASSIFIED BY IARC AS POSSIBLY CARCINOGENIC TO HUMANS (2B)
BASED ON INADEQUATE EVIDENCE IN HUMANS AND SUFFICIENT EVIDENCE IN
LABORATORY ANIMALS. LIFETIME INHALATION EXPOSURE OF RATS AND MICE TO HIGH
ETHYLBENZENE CONCENTRATIONS RESULTED IN INCREASES IN CERTAIN TYPES OF
CANCER, INCLUDING KIDNEY TUMORS IN RATS AND LUNG AND LIVER TUMORS IN MICE.
THESE EFFECTS WERE NOT OBSERVED IN ANIMALS EXPOSED TO LOWER CONCENTRATIONS.
THERE IS NO EVIDENCE THAT ETHYLBENZENE CAUSES CANCER IN HUMANS.
TOXICOLOGY DATA:
CAS NO. INGREDIENT NAME
64742-89-8 LT. ALIPHATIC HYDROCARBON SOLVENT
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
108-88-3 TOLUENE
LC50 RAT 4HR: 4000 PPM
LD50 RAT: 5000 MG/KG
100-41-4 ETHYLBENZENE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 3500 MG/KG
1330-20-7 XYLENE
LC50 RAT 4HR: 5000 PPM
LD50 RAT: 4300 MG/KG
95-63-6 1,2,4-TRIMETHYLBENZENE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: NOT AVAILABLE
108-65-6 1-METHOXY-2-PROPANOL ACETATE
LC50 RAT 4HR: NOT AVAILABLE
LD50 RAT: 8500 MG/KG
| SECTION 12 - ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION: NO DATA AVAILABLE.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL METHOD:
WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS DEFINED UNDER THE RESOURCE
CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261.
WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA
HAZARDOUS WASTE NUMBERS.
INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINER.
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE/PROVINCIAL, AND LOCAL
REGULATIONS REGARDING POLLUTION.
| SECTION 14 - TRANSPORT INFORMATION | |
MULTI-MODAL SHIPPING DESCRIPTIONS ARE PROVIDED FOR INFORMATIONAL PURPOSES
AND DO NOT CONSIDER CONTAINER SIZES. THE PRESENCE OF A SHIPPING DESCRIPTION
FOR A PARTICULAR MODE OF TRANSPORT (OCEAN, AIR, ETC.), DOES NOT INDICATE
THAT THE PRODUCT IS PACKAGED SUITABLY FOR THAT MODE OF TRANSPORT. ALL
PACKAGING MUST BE REVIEWED FOR SUITABILITY PRIOR TO SHIPMENT, AND
COMPLIANCE WITH THE APPLICABLE REGULATIONS IS THE SOLE RESPONSIBILITY OF
THE PERSON OFFERING THE PRODUCT FOR TRANSPORT.
US GROUND (DOT):
5 LITERS (1.3 GALLONS) AND LESS MAY BE CLASSED AS LTD. QTY. (PAINT OR
RELATED).
LARGER CONTAINERS ARE REGULATED AS: UN1263, PAINT, 3, PG II, (ERG#128)
DOT (DEPT OF TRANSPORTATION) HAZARDOUS SUBSTANCES & REPORTABLE QUANTITIES:
TOLUENE: 1000 LB RQ
XYLENES (MIXED ISOMERS): 100 LB RQ
BULK CONTAINERS MAY BE SHIPPED AS (CHECK REPORTABLE QUANTITIES):
RQ, UN1263, PAINT, 3, PG II, (XYLENES (MIXED ISOMERS)), (ERG#128)
CANADA (TDG): UN1263, PAINT, 3, PG II, LIMITED QUANTITY, (ERG#128)
IMO:
5 LITERS (1.3 GALLONS) AND LESS MAY BE SHIPPED AS LIMITED QUANTITY.
UN1263, PAINT, 3, PG II, (10 C C.C.), EMS F-E, S-E
IMO:
5 LITERS (1.3 GALLONS) AND LESS MAY BE SHIPPED AS LIMITED QUANTITY.
UN1263, PAINT, 3, PG II, (10 C C.C.), EMS F-E, S-E
IATA/ICAO: UN1263, PAINT, 3, PG II
| SECTION 15 - REGULATORY INFORMATION | |
SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION:
CAS NO. CHEMICAL/COMPOUND % BY WT % ELEMENT
108-88-3 TOLUENE 17
100-41-4 ETHYLBENZENE 3
1330-20-7 XYLENE 16
95-63-6 1,2,4-TRIMETHYLBENZENE 1
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
TSCA CERTIFICATION:
ALL CHEMICALS IN THIS PRODUCT ARE LISTED, OR ARE EXEMPT FROM LISTING, ON
THE TSCA INVENTORY.
| SECTION 16 - OTHER INFORMATION | |
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CANADIAN CONTROLLED PRODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS
ALL OF THE INFORMATION REQUIRED BY THE CPR.
THE ABOVE INFORMATION PERTAINS TO THIS PRODUCT AS CURRENTLY FORMULATED, AND
IS BASED ON THE INFORMATION AVAILABLE AT THIS TIME. ADDITION OF REDUCERS OR
OTHER ADDITIVES TO THIS PRODUCT MAY SUBSTANTIALLY ALTER THE COMPOSITION AND
HAZARDS OF THE PRODUCT. SINCE CONDITIONS OF USE ARE OUTSIDE OUR CONTROL, WE
MAKE NO WARRANTIES, EXPRESS OR IMPLIED, AND ASSUME NO LIABILITY IN
CONNECTION WITH ANY USE OF THIS INFORMATION.
SINOPEC
SAFETY DATA SHEET
ACCORDING TO SS586:2014
SINOPEC EXTREME PRESSURE LITHIUM GREASE NLGI 2
VERSION: 1.0
ISSUE DATE: 12/01/2015
REVISION DATE: 12/01/2015
SDS RECORD NUMBER: CSSS-TCO-010-116055
| SECTION 1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE | |
AND OF THE COMPANY/UNDERTAKING
PRODUCT IDENTIFIER:
IDENTIFICATION ON THE LABEL/TRADE NAME:
SINOPEC EXTREME PRESSURE LITHIUM GREASE NLGI 2
ADDITIONAL IDENTIFICATION: NOT AVAILABLE
IDENTIFICATION OF THE PRODUCT: SEE SECTION 3
INDEX NUMBER: NOT AVAILABLE
REACH REGISTRATION NO.: NOT AVAILABLE
RELEVANT IDENTIFIED USES OF THE SUBSTANCE AND USES ADVISED AGAINST:
IDENTIFIED USES:
SUITABLE FOR LUBRICATING BEARINGS AND GEARS OF HIGH LOAD MECHANICAL
EQUIPMENT WHICH WORK ON TEMPERATURES OF -20 DEG. C TO 120 DEG. C. AND
IT CAN ALSO BE USED FOR CENTRALIZED LUBRICATION SYSTEM.
USES ADVISED AGAINST: NOT AVAILABLE.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER(MANUFACTURER): SINOPEC LUBRICANT CO., LTD.
ADDRESS:
NO. 6 ANNING ZHUANG WEST ROAD
HAIDIAN DISTRICT, BEIJING, P.R.
CHINA
CONTACT PERSON (E-MAIL): CSC.LUBE@SINOPEC.COM
TELEPHONE: 86-400-810-9886
FAX: 86-10-82410856
EMERGENCY TELEPHONE NUMBER:
86-400-810-9886 ONLY AVAILABLE DURING OFFICE HOURS (8:30A.M.-17:30P.M.
BEIJING TIME ZONE)
AVAILABLE OUTSIDE OFFICE HOURS?:
YES ( )
NO (X)
| SECTION 2 HAZARDS IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE/MIXTURE:
GHS CLASSIFICATION: NOT CLASSIFIED
LABEL ELEMENTS:
HAZARD PICTOGRAMS: NO HAZARD PICTOGRAM IS USED.
SIGNAL WORD(S): NO SIGNAL WORD IS USED.
HAZARD STATEMENT: NOT APPLICABLE.
PRECAUTIONARY STATEMENT: NOT APPLICABLE.
OTHER HAZARDS: NOT AVAILABLE.
| SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
INGREDIENT(S):
CHEMICAL NAME REGISTRATION NO. CAS NO. EC NO. CONCENTRATION
BASE OIL N/A 64742-44-5 265-146-1 75-88%
LITHIUM 12- N/A 7620-77-1 31-536-5 5-20%
HYDROXYSTEARATE
ADDITIVE N/A 68649-42-3 272-028-3 <8%
| SECTION 4 FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
IN ALL CASES OF DOUBT, OR WHEN SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION.
IN CASE OF INHALATION:
REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN. GET MEDICAL ATTENTION.
IN CASE OF SKIN CONTACT:
FLUSH SKIN WITH WATER, AND THEN WASH WITH SOAP AND WATER. GET MEDICAL
ATTENTION.
IN CASE OF EYES CONTACT:
FLUSH WITH WATER FOR 15 MINUTES. IF IRRITATION OCCURS, GET MEDICAL
ATTENTION.
IN CASE OF INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
THE PRODUCT IS NOT CLASSIFIED AS HARMFUL TO HUMAN HEALTH EFFECT.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
IF SKIN IRRITATION OR RASH OCCURS, GET MEDICAL ADVICE/ATTENTION.
| SECTION 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE WATER CARBON DIOXIDE, FOAM, DRY CHEMICAL AND WATER FOG.
UNSUITABLE EXTINGUISHING MEDIA: WATER.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
IN CASE OF HEAT, FIRE AND STRONG OXIDANTS CAN LEAD TO BURNING. FUMES,
SMOKE, CARBON MONOXIDE, SULFUR OXIDES, ALDEHYDES, NITROGEN OXIDES,
PHOSPHATE, CERTAIN METAL OXIDES AND OTHER DECOMPOSITION PRODUCTS, IN
THE CASE OF INCOMPLETE COMBUSTION.
SPECIAL FIRE FIGHTING METHODS AND SPECIAL PROTECTIVE ACTIONS FOR
FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
PROVIDE ADEQUATE VENTILATION. AVOID SKIN AND EYE CONTACT. REFER TO SECTION
8 OF SDS FOR PERSONAL PROTECTION DETAILS.
FOR EMERGENCY RESPONDERS:
WEAR AN APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR IF DUST IS GENERATED.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW MATERIAL TO BE RELEASED TO THE ENVIRONMENT WITHOUT PROPER
GOVERNMENTAL PERMITS.
METHODS FOR CONTAINMENT AND CLEANING UP:
FOR LARGE SPILLS:
REMOVE WITH VACUUM TRUCK OR PUMP TO STORAGE/SALVAGE VESSELS.
FOR SMALL SPILLS:
SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY, SAND OR OTHER SUITABLE
MATERIAL. PLACE IN NON-LEAKING CONTAINER AND SEAL TIGHTLY FOR PROPER
DISPOSAL.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR INFORMATION ON DISPOSAL.
ADDITIONAL INFORMATION: NOT APPLICABLE.
| SECTION 7 HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, MAY CONTAIN EXPLOSIVE
VAPOURS. DO NOT CUT, DRILL, GRIND, WELD OR PERFORM SIMILAR OPERATIONS ON OR
NEAR CONTAINERS. ELECTROSTATIC DISCHARGE MAY BE GENERATED DURING PUMPING -
THIS MAY RESULT IN FIRE. ENSURE ELECTRICAL CONTINUITY BY BONDING AND
GROUNDING (EARTHING) ALL EQUIPMENT.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
DO NOT EAT, DRINK AND SMOKE IN WORK AREAS. WASH HANDS AFTER USE. REMOVE
CONTAMINATED CLOTHING AND PROTECTIVE EQUIPMENT BEFORE ENTERING EATING
AREAS.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
DO NOT STORE IN OPEN OR UNLABELED CONTAINERS. STORE IN A COOL, DRY
PLACE WITH ADEQUATE VENTILATION. KEEP AWAY FROM OPEN FLAMES AND HIGH
TEMPERATURES.
SPECIFIC END USE(S): NOT APPLICABLE.
| SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS (OEL):
INGREDIENT DATA:
SOURCE INGREDIENT MATERIAL TWA STEL PEAK NOTES
NAME
US ACGIH LITHIUM STEARATES(J) 10 NOT NOT TLV(R*)
THRESHOLD 12-HYDROXYS- MG/M3 AVAILABLE AVAILABLE BASIS:
LIMIT TEARATE EYE,
VALUES SKIN, &
(TLV) URT IRR
EMERGENCY LIMITS:
INGREDIENT ORIGINAL IDLH REVISED IDLH
LITHIUM 12-HYDROXYSTEARATE NOT AVAILABLE NOT AVAILABLE
BASE OIL NOT AVAILABLE NOT AVAILABLE
ADDITIVE NOT AVAILABLE NOT AVAILABLE
EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
PROVIDE ADEQUATE VENTILATION TO CONTROL AIRBORNE CONCENTRATIONS BELOW THE
EXPOSURE GUIDELINES/LIMITS.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: CHEMICAL GOGGLES, OR SAFETY GLASSES WITH SIDE SHIELDS.
HAND PROTECTION:
USE PROTECTIVE GLOVES WHICH IS CHEMICALLY RESISTANT TO THIS MATERIAL.
BODY PROTECTION:
USE PROTECTIVE CLOTHING AND SHOES WHICH ARE CHEMICALLY RESISTANT TO THIS
MATERIAL.
RESPIRATORY PROTECTION:
IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS TO A LEVEL
WHICH IS ADEQUATE TO PROTECT WORKER HEALTH, AN APPROVED RESPIRATOR MUST BE
WORN.
THERMAL HAZARDS: WEAR SUITABLE PROTECTIVE CLOTHING TO PREVENT HEAT.
ENVIRONMENTAL EXPOSURE CONTROLS:
AVOID DISCHARGE INTO THE ENVIRONMENT.
ACCORDING TO LOCAL REGULATIONS, FEDERAL AND OFFICIAL REGULATIONS.
| SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: LIGHT BROWN SMOOTH OINTMENT
COLOUR: LIGHT BROWN
ODOUR: SLIGHTLY PUNGENT ODOR
ODOUR THRESHOLD: NOT AVAILABLE
PH: NOT AVAILABLE
MELTING POINT/RANGE (DEG. C): 0 DEG. C (BASE OIL)
BOILING POINT/RANGE (DEG. C): >= 207 <= 750 DEG. C (BASE OIL)
FLASH POINT (DEG. C): 245 DEG. C (OPEN CUP)
EVAPORATION RATE: >260 DEG. C
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE
IGNITION TEMPERATURE (DEG. C): NOT AVAILABLE
UPPER/LOWER FLAMMABILITY/EXPLOSIVE LIMITS: NOT AVAILABLE
VAPOUR PRESSURE: <.0.5 MPA (40 DEG. C)
VAPOUR DENSITY: >1 (AIR=1)
DENSITY: 0.85-1.0 KG/L (20 DEG. C)
BULK DENSITY (KG/M3): NOT AVAILABLE
WATER SOLUBILITY (G/L): INSOLUBLE IN WATER
N-OCTANOL/WATER (LOG PO/W): >6
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE
DECOMPOSITION TEMPERATURE: NOT AVAILABLE
VISCOSITY, DYNAMIC (MPA.S): NOT AVAILABLE
EXPLOSIVE PROPERTIES: NON EXPLOSIVE
OXIDISING PROPERTIES: NOT OXIDIZING
MOLECULAR FORMULA: NOT AVAILABLE
MOLECULAR WEIGHT: NOT AVAILABLE
OTHER INFORMATION:
FAT SOLUBILITY(SOLVENT-OIL TO BE SPECIFIED) ETC: NOT AVAILABLE
SURFACE TENSION: NOT AVAILABLE
DISSOCIATION CONSTANT IN WATER (PKA): NOT AVAILABLE
OXIDATION-REDUCTION POTENTIAL: NOT AVAILABLE
SPECIFIC GRAVITY: NOT AVAILABLE
| SECTION 10 STABILITY AND REACTIVITY | |
REACTIVITY:
THE SUBSTANCE IS STABLE UNDER NORMAL STORAGE AND HANDLING CONDITIONS.
CHEMICAL STABILITY:
STABLE AT ROOM TEMPERATURE IN CLOSED CONTAINERS UNDER NORMAL STORAGE AND
HANDLING CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
CONTACT WITH STRONG OXIDANTS CAN LEAD TO BURNING.
CONDITIONS TO AVOID:
EXTREME HEAT AND HIGH ENERGY SOURCES OF IGNITION AND STRONG OXIDIZERS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
FUMES, SMOKE, CARBON MONOXIDE, SULFUR OXIDES, ALDEHYDES, NITROGEN OXIDES,
PHOSPHATE, CERTAIN METAL OXIDES AND OTHER DECOMPOSITION PRODUCTS, IN THE
CASE OF INCOMPLETE COMBUSTION.
| SECTION 11 TOXICOLOGICAL INFORMATION | |
TOXICOKINETICS, METABOLISM AND DISTRIBUTION:
NON-HUMAN TOXIKOLOGICAL DATA: NOT AVAILABLE
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD50 (ORAL, RAT): >5000 MG/KG BW
LD50 (DERMAL, RAT): >2000 MG/KG BW
LC50 (INHALATION, RAT): >10000 MG/M3 BW
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
STOT- SINGLE EXPOSURE: NOT CLASSIFIED
STOT-REPEATED EXPOSURE: NOT CLASSIFIED
| SECTION 12 ECOLOGICAL INFORMATION | |
TOXICITY:
BASE OIL (CAS: 64742-44-5):
ACUTE TOXICITY TIME SPECIES METHOD EVALUATION REMARKS
LL50: >100 MG/L 96H FISH OECD 203 N/A N/A
LL50: >10000 MG/L 48H DAPHNIA OECD 202 N/A N/A
EC50: N/A 72H ALGAE OECD 201 N/A N/A
LITHIUM 12-HYDROXYSTEARATE (CAS: 7620-77-1):
ACUTE TOXICITY TIME SPECIES METHOD EVALUATION REMARKS
LL50: >100 MG/L 96H FISH OECD 203 N/A N/A
EC50: >100 MG/L 48H DAPHNIA OECD 202 N/A N/A
EL50: >160 MG/L 72H ALGAE OECD 201 N/A N/A
PERSISTENCE AND DEGRADABILITY:
THIS PRODUCT IS EXPECTED TO BE INHERENTLY BIODEGRADABLE.
BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATION IS UNLIKELY DUE TO THE VERY LOW WATER SOLUBILITY OF THIS
PRODUCT; THEREFORE BIOAVAILABILITY TO AQUATIC ORGANISMS IS MINIMAL.
MOBILITY IN SOIL:
WHEN RELEASED INTO THE ENVIRONMENT, ADSORPTION TO SEDIMENT AND SOIL WILL BE
THE PREDOMINANT BEHAVIOR.
RESULTS OF PBT & VPVB ASSESSMENT: NOT AVAILABLE.
OTHER ADVERSE EFFECTS:
THOUGH LONG TIME INFILTRATION, IT MAY PRODUCE ECOLOGICAL TOXICITY.
| SECTION 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
THE MATERIAL SHOULD BE DISPOSED OF BY INCINERATION IN A CHEMICAL
INCINERATOR IN COMPLIANCE WITH NATIONAL AND REGIONAL REQUIREMENTS.
PRODUCT / PACKAGING DISPOSAL:
IF EMPTY CONTAINER RETAINS PRODUCT RESIDUES, ALL LABEL PRECAUTIONS MUST
BE OBSERVED. RETURN FOR REUSE OR DISPOSE ACCORDING TO NATIONAL OR LOCAL
REGULATIONS.
| SECTION 14 TRANSPORT INFORMATION | |
LAND TRANSPORT SEA TRANSPORT AIR TRANSPORT
(ADR/RID) (IMDG) (ICAO/IATA)
UN-NUMBER NOT REGULATED NOT REGULATED NOT REGULATED
UN PROPER SHIPPING NAME NOT REGULATED NOT REGULATED NOT REGULATED
TRANSPORT HAZARD CLASS NOT REGULATED NOT REGULATED NOT REGULATED
PACKAGING GROUP NOT REGULATED NOT REGULATED NOT REGULATED
ENVIRONMENTAL HAZARDS NO NO NO
SPECIAL PRECAUTIONS FOR SEE SECTION 2.2 SEE SECTION 2.2 SEE SECTION 2.2
USER
TRANSPORT IN BULK NOT REGULATED NOT REGULATED NOT REGULATED
ACCORDING TO ANNEX II
OF MARPOL 73/78 AND
THE IBC CODE
| SECTION 15 REGULATION INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
LITHIUM 12-HYDROXYSTEARATE (7620-77-1) IS FOUND ON THE FOLLOWING REGULATORY
LISTS: "SINGAPORE PERMISSIBLE EXPOSURE LIMITS OF TOXIC SUBSTANCES"
BASE OIL (64742-44-5) IS FOUND ON THE FOLLOWING REGULATORY LISTS:
"SINGAPORE PERMISSIBLE EXPOSURE LIMITS OF TOXIC SUBSTANCES", "INTERNATIONAL
AGENCY FOR RESEARCH ON CANCER (IARC) - AGENTS CLASSIFIED BY THE IARC
MONOGRAPHS"
ADDITIVE (68649-42-3) IS FOUND ON THE FOLLOWING REGULATORY LISTS:
"NOT APPLICABLE"
| SECTION 16 OTHER INFORMATION | |
FURTHER INFORMATION:
THIS INFORMATION IS BASED UPON THE PRESENT STATE OF OUR KNOWLEDGE. THIS
SDS HAS BEEN COMPILED AND IS SOLELY INTENDED FOR THIS PRODUCT.
NOTICE TO READER:
EMPLOYERS SHOULD USE THIS INFORMATION ONLY AS A SUPPLEMENT TO OTHER
INFORMATION GATHERED BY THEM, AND SHOULD MAKE INDEPENDENT JUDGMENT OF
SUITABILITY OF THIS INFORMATION TO ENSURE PROPER USE AND PROTECT THE HEALTH
AND SAFETY OF EMPLOYEES. THIS INFORMATION IS FURNISHED WITHOUT WARRANTY,
AND ANY USE OF THE PRODUCT NOT IN CONFORMANCE WITH THIS SAFETY DATA SHEET,
OR IN COMBINATION WITH ANY OTHER PRODUCT OR PROCESS, IS THE RESPONSIBILITY
OF THE USER.
AUTHOR: HANGZHOU CIRS CO., LIMITED
WEBSITE: WWW.CIRS-GROUP.COM
TEL: 0571-87206555
EMAIL: INFO@CIRS-GROUP.COM
PRODUCT NAME: SINOPEC EXTREME PRESSURE LITHIUM GREASE NLGI 2
VERSION #: 1.0
SDS SG
ANBOTEK PRODUCT SAFETY
SHENZHEN ANBOTEK COMPLIANCE LABORATORY LIMITED
REPORT NO.: R011509882B
SAFETY DATA SHEET
ACCORDING TO HCS-2012 APPENDIX D TO SUBSECTION 1910.1200 (VERSION: 1.0/EN)
| SECTION 1. IDENTIFICATION | |
(A) PRODUCT IDENTIFIER:
PRODUCT NAME: LEAD ACID BATTERY
(B) OTHER MEANS OF IDENTIFICATION:
PRODUCT DESCRIPTION:
MODEL:
6-EVF-50, 6-EVF-60, 6-EVF-60T, 6-EVF-80, 6-EVF-100, 6-EVF-120, 6-EVF-150,
6-EVF-135, 4-EVF-150, 3-EVF-200, 3-EVF-150
NOMINAL VOLTAGE: 12V
RATED CAPACITY: 120AH
WEIGHT: 41.0KG
(C) RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: LEAD ACID BATTERY
RESTRICTION ON USE: NO INFORMATION AVAILABLE.
(D) DETAILS OF THE SUPPLIER OF THE PRODUCT:
COMPANY NAME(CHINA): TIANNENG BATTERY GROUP CO., LTD.
ADDRESS:
MEISHAN INDUSTRIAL ZONE
CHANGXING, ZHEJIANG PROVINCE
CHINA
TELEPHONE NO.: 0572-6176698
FAX: 0572-6058018
| SECTION 2. HAZARD(S) IDENTIFICATION | |
(A) PREPARATION HAZARDS AND CLASSIFICATION:
NO HARM AT THE NORMAL USE. WHEN THE BATTERY IS IN EXTREME PRESSURE
DEFORMATION, HIGH-TEMPERATURE ENVIRONMENT, OVERLOAD, SHORT-CIRCUIT
CONDITION, OR DISASSEMBLE THE BATTERY, AN EXPLOSION OF FIRE AND
CHEMICAL BURN HAZARDS MAY OCCUR.
(B) PRIMARY ROUTE(S) OF EXPOSURE:
THESE CHEMICALS ARE CONTAINED IN A PLASTIC ENCLOSURE. RISK OF EXPOSURE
OCCURS ONLY IF THE CELL IS MECHANICALLY, THERMALLY OR ELECTRICALLY ABUSED
TO THE POINT OF COMPROMISING THE ENCLOSURE. IF THIS OCCURS, EXPOSURE TO THE
ELECTROLYTE SOLUTION CONTAINED WITHIN CAN OCCUR BY INHALATION, INGESTION,
EYE CONTACT AND SKIN CONTACT.
(C) POTENTIAL HEALTH EFFECTS:
ACUTE (SHORT TERM):
SEE SECTION 8 FOR EXPOSURE CONTROLS IN THE EVENT THAT THIS BATTERY HAS BEEN
RUPTURED, THE ELECTROLYTE SOLUTION CONTAINED WITHIN THE BATTERY WOULD BE
CORROSIVE AND CAN CAUSE BURNS.
INHALATION:
A BATTERY VOLATILIZES NO GAS UNLESS IT WAS DAMAGED. DAMAGED BATTERY WILL
VOLATILIZE LITTLE GAS THAT MAY STIMULATE THE RESPIRATORY TRACT OR CAUSE
AN ANAPHYLAXIS IN SERIOUS CONDITION.
INGESTION:
SWALLOWING BATTERY WILL BE DAMAGED TO THE RESPIRATORY TRACT AND CAUSE
CHEMICAL BURNS TO THE STOMACH; INSERIOUS CONDITIONS IT WILL CAUSE PERMANENT
DAMAGE.
SKIN:
IN NORMAL CONDITION, CONTACT BETWEEN THE BATTERY AND SKIN WILL NOT CAUSE
ANY HARMS. CONTACT WITH A DAMAGED BATTERY MAY CAUSE SKIN ALLERGIES OR
CHEMICAL BURNS.
EYE:
IN NORMAL CONDITION, CONTACT BETWEEN THE BATTERY AND EYES WILL NOT CAUSE
ANY HARMS. HOWEVER, THE GAS VOLATILIZE FROM A DAMAGED BATTERY MAY BE
HARMFUL TO EYES.
CHRONIC (LONG TERM): SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL DATA.
(D) MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NO INFORMATION AVAILABLE.
(E) REPORTED AS CARCINOGEN: NO INFORMATION AVAILABLE.
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
GHS02: FLAME
GHS05: CORROSION
GHS06: SKULLS AND CROSSBONES
SIGNAL WORD: WARNING
HAZARD STATEMENT(S):
H242: HEATING MAY CAUSE A FIRE
H311: TOXIC IN CONTACT WITH SKIN
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE
H302: HARMFUL IF SWALLOWED
H332: HARMFUL IF INHALED
PRECAUTIONARY STATEMENTS:
PREVENTION:
P264: WASH THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P261: AVOID BRETHING DUST/FUME/GAS/MIST/VAPOURS/SPRAY.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
RESPONSE:
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P302+P350:
IF ON SKIN: GENTLY WASH WITH PLENTY OF SOAP AND WATER
P301+P330+P331:
IF SWALLOWED: RISE MOUTH. DO NOT INDUCE VOMITING
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
DISPOSAL:
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/NATIONAL
REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
(A) MIXTURES INFORMATION:
CHEMICAL NAME CONCENTRATION% CAS NO.
LEAD (Pb, PbO2, PbSO4) 70 7439-92-1
SULFURIC ACID 20 7664-93-9
FIBERGLASS SEPARATOR 5
ABS OR PP 5 9003-56-9
9003-07-0
| SECTION 4. FIRST-AID MEASURES | |
(A) DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
SULFURIC ACID:
REMOVE TO FRESH AIR IMMEDIATELY. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
LEAD: REMOVE FROM EXPOSURE, GARGLE, WASH NOSE AND LIPS; CONSULT PHYSICIAN.
SKIN CONTACT:
SULFURIC ACID:
FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES; REMOVE
CONTAMINATED CLOTHING COMPLETELY, INCLUDING SHOES.
LEAD: WASH IMMEDIATELY WITH SOAP AND WATER.
EYE CONTACT:
SULFURIC ACID AND LEAD:
FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR A LEAST 15 MINUTES;
CONSULT PHYSICIAN.
INGESTION:
SULFURIC ACID:
GIVE LARGE QUANTITIES OF WATER; DO NOT INDUCE VOMITING; CONSULT PHYSICIAN.
LEAD: CONSULT PHYSICIAN IMMEDIATELY.
(B) MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
CONTACT WITH INTERNAL COMPONENTS MAY CAUSE ALLERGIC SKIN SENSITIZATION
(RASH) AND IRRITATE EYES, SKIN, NOSE, THROAT, RESPIRATORY SYSTEM. LEAD
AND LEAD COMPOUNDS ARE CONSIDERED TO BE POSSIBLE HUMAN CARCINOGEN(S).
(C) IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT:
NO INFORMATION AVAILABLE.
| SECTION 5. FIRE-FIGHTING MEASURES | |
(A) EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE FOAM, DRY POWDER OR DRY SAND, CO2 AS APPROPRIATE.
UNSUITABLE EXTINGUISHING MEDIA: NO INFORMATION AVAILABLE.
(B) SPECIAL HAZARDS ARISING FROM THE CHEMICAL:
UNDER FIRE CONDITIONS, BATTERIES MAY BURST AND RELEASE HAZARDOUS
DECOMPOSITION PRODUCTS WHEN EXPOSED TO A FIRE SITUATION. THIS COULD
RESULT IN THE RELEASE OF FLAMMABLE OR CORROSIVE MATERIALS.
HAZARDOUS COMBUSTION PRODUCTS: CO, CO2, METAL OXIDES, IRRITATING FUMES.
(C) SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS:
FIREFIGHTERS MUST WEAR FIRE RESISTANT PROTECTIVE EQUIPMENT AND APPROPRIATE
BREATHING APPARATUS. THE STAFF MUST EQUIP WITH FILTERMASK (FULL MASK) OR
ISOLATED BREATHING APPARATUS. THE STAFF MUST WEAR THE CLOTHES WHICH CAN
DEFENSE THE FIRE AND THE TOXIC GAS. PUT OUT THE FIRE IN THE UPWIND
DIRECTION. REMOVE THE CONTAINER TO THE OPEN SPACE AS SOON AS POSSIBLE.
SPRAY WATER ON THE CONTAINERS IN THE FIREPLACE TO KEEP THEM COOL UNTIL
FINISH EXTINGUISHMENT.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
(A) PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
STOP RELEASE, IF POSSIBLE. AVOID CONTACT WITH ANY SPILLED MATERIAL. CONTAIN
SPILL, ISOLATE HAZARD AREA, AND DENY ENTRY. LIMIT SITE ACCESS TO EMERGENCY
RESPONDERS. NEUTRALIZE WITH SODIUM BICARBONATE, SODA ASH, LIME OR OTHER
NEUTRALIZING AGENT. PLACE BATTERY IN SUITABLE CONTAINER FOR DISPOSAL.
DISPOSE OF CONTAMINATED MATERIAL IN ACCORDANCE WITH APPLICABLE LOCAL, STATE
AND FEDERAL REGULATIONS. SODIUM BICARBONATE, SODA ASH, SAND, LIME OR OTHER
NEUTRALIZING AGENT SHOULD BE KEPT ON-SITE FOR SPILL REMEDIATION. ACID
RESISTANT APRONS, BOOTS AND PROTECTIVE CLOTHING. ANSI APPROVED SAFETY
GLASSES WITH SIDE SHIELDS/FACE SHIELD RECOMMENDED. VENTILATE ENCLOSED
AREAS.
(B) ENVIRONMENTAL PRECAUTIONS:
LEAD AND ITS COMPOUNDS AND SULFURIC ACID CAN POSE A SEVERE THREAT TO THE
ENVIRONMENT. CONTAMINATION OF WATER, SOIL, AND AIR SHOULD BE PREVENTED.
(C) METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
IF BATTERY CASING IS DISMANTLED, SMALL AMOUNTS OF ELECTROLYTE MAY LEAK.
COLLECT ALL RELEASED MATERIAL IN A PLASTIC LINED CONTAINER. DISPOSE OFF
ACCORDING TO THE LOCAL LAW AND RULES. AVOID LEACHED SUBSTANCES TO GET
INTO THE EARTH, CANALIZATION OR WATERS.
| SECTION 7. HANDLING AND STORAGE | |
(A) PRECAUTIONS FOR SAFE HANDLING:
ALWAYS FOLLOW THE WARNING INFORMATION ON THE BATTERIES AND IN THE MANUALS
OF DEVICES. ONLY USE THE RECOMMENDED BATTERY TYPES. KEEP BATTERIES AWAY
FROM CHILDREN. FOR DEVICES TO BE USED BY CHILDREN, THE BATTERY CASING
SHOULD BE PROTECTED AGAINST UNAUTHORIZED ACCESS. UNPACKED BATTERIES SHALL
NOT LIE ABOUT IN BULK. IN CASE OF BATTERY CHANGE ALWAYS REPLACE ALL
BATTERIES BY NEW ONES OF IDENTICAL TYPE AND BRAND. DO NOT SWALLOW
BATTERIES. DO NOT THROW BATTERIES INTO WATER. DO NOT THROW BATTERIES INTO
FIRE. AVOID DEEP DISCHARGE. DO NOT SHORT-CIRCUIT BATTERIES USE RECOMMENDED
CHARGING TIME AND CURRENT.
(B) CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
IF THE LEAD ACID BATTERY IS SUBJECT TO STORAGE FOR SUCH A LONG TERM AS
MORE THAN 3 MONTHS, IT IS RECOMMENDED TORECHARGE THE LEAD ACID BATTERY
PERIODICALLY.
OPERATING TEMPERATURE:
CHARGE: 0 DEG. C - 45 DEG. C.
DISCHARGE: -10 DEG. C - 50 DEG. C.
AND RECOMMENDED AT -10 DEG. C - 45 DEG. C FOR 1 MONTH STORAGE, AT
-10 - 35 DEG. C FOR 3 MONTHS STORAGE. THE CAPACITY RECOVERY RATE IN THE
DELIVERY STATE (50% CAPACITY OF FULLY CHARGED) AFTER STORAGE IS ASSUMED TO
BE 80% OR MORE. THE VOLTAGE FOR A LONG TIME STORAGE SHALL BE 10.5V-14.4V
RANGE. DO NOT STORAGE LEAD ACID BATTERY HAPHAZARDLY IN A BOX OR DRAWER
WHERE THEY MAY SHORT-CIRCUIT EACH OTHER OR BE SHORT-CIRCUITED BY OTHER
METAL OBJECTS. KEEP OUT OF REACH OF CHILDREN.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
(A) ENGINEERING CONTROLS:
STORE AND HANDLE IN WELL-VENTILATED AREA. IF MECHANICAL VENTILATION IS
USED, COMPONENTS MUST BE ACID-RESISTANT.
(B) PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
NONE REQUIRED UNDER NORMAL CONDITIONS. WHEN CONCENTRATIONS OF SULFURIC ACID
MIST ARE KNOWN TO EXCEED THE PEL, USE NIOSH OR MSHA-APPROVED RESPIRATORY
PROTECTION.
HAND PROTECTION:
RUBBER OR PLASTIC ACID-RESISTANT GLOVES WITH ELBOW-LENGTH GAUNTLET.
EYE PROTECTION: CHEMICAL GOGGLES OR FACE SHIELD.
WORK PRACTICES:
HANDLE BATTERIES CAUTIOUSLY TO AVOID SPILLS. MAKE CERTAIN VENT CAPS ARE ON
SECURELY. AVOID CONTACT WITH INTERNAL COMPONENTS. WEAR PROTECTIVE CLOTHING
WHEN FILLING OR HANDLING BATTERIES.
(C) OTHER PROTECTIVE EQUIPMENT:
ACID-RESISTANT APRON. UNDER SEVERE EXPOSURE EMERGENCY CONDITIONS, WEAR
ACID-RESISTANT CLOTHING AND BOOTS.
(D) HYGIENE MEASURES:
DO NOT EAT, DRINK, OR SMOKE IN WORK AREA. MAINTAIN GOOD HOUSEKEEPING.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
(A) APPEARANCE: BLACK SOLID
(B) ODOR: MONOTONY
(C) ODOR THRESHOLD: NOT AVAILABLE.
(D) PH: PH<2
(E) MELTING POINT/FREEZING POINT: NOT AVAILABLE.
(F) INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE.
(G) FLASH POINT: NOT APPLICABLE.
(H) EVAPORATION RATE: NOT APPLICABLE.
(I) FLAMMABILITY: NON FLAMMABLE.
(J) UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NOT AVAILABLE.
(K) VAPOR PRESSURE: 10 MMHg
(L) VAPOR DENSITY: GREATER THAN 1 (AIR =1)
(M) RELATIVE DENSITY: NOT AVAILABLE.
(N) SOLUBILITY(IES): INSOLUBLE IN WATER.
(O) PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
(P) AUTO-IGNITION TEMPERATURE: 130 DEG. C
(Q) DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
(R) VISCOSITY: NOT AVAILABLE.
| SECTION 10. STABILITY AND REACTIVITY | |
(A) REACTIVITY: STABLE UNDER RECOMMENDED STORAGE AND HANDLING CONDITIONS.
(B) CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
(C) POSSIBILITY OF HAZARDOUS REACTIONS:
WHEN HEATED ABOVE 150 DEG. C THE RISK OF RUPTURE OCCURS. DUE TO SPECIAL
SAFETY CONSTRUCTION, RUPTURE IMPLIES CONT RELEASE OF PRESSURE WITHOUT
IGNITION.
(D) CONDITIONS TO AVOID: PROLONGED OVERCHARGE; SOURCES OF IGNITION
(E) INCOMPATIBLE MATERIALS:
SULFURIC ACID:
CONTACT WITH COMBUSTIBLES AND ORGANIC MATERIALS MAY CAUSE FIRE AND
EXPLOSION. ALSO REACTS VIOLENTLY WITH STRONG REDUCING AGENTS, METALS,
SULFUR TRIOXIDE GAS, STRONG OXIDIZERS AND WATER. CONTACT WITH METALS MAY
PRODUCE TOXIC SULFUR DIOXIDE FUMES AND MAY RELEASE FLAMMABLE HYDROGEN GAS.
LEAD COMPOUNDS:
AVOID CONTACT WITH STRONG ACIDS, BASES, HALIDES, HALOGENATES, POTASSIUM
NITRATE, PERMANGANATE, PEROXIDES, NASCENT HYDROGEN AND REDUCING AGENTS.
(F) HAZARDOUS DECOMPOSITION PRODUCTS:
SULFURIC ACID:
SULFUR TRIOXIDE, CARBON MONOXIDE, SULFURIC ACID MIST, SULFUR DIOXIDE, AND
HYDROGEN.
LEAD COMPOUNDS:
HIGH TEMPERATURES LIKELY TO PRODUCE TOXIC METAL FUME, VAPOR, OR DUST;
CONTACT WITH STRONG ACID OR BASE OR PRESENCE OF NASCENT HYDROGEN MAY
GENERATE HIGHLY TOXIC ARSINE GAS.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
(A) INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
INHALATION:
INHALATION OF A LARGE NUMBER OF VAPORS OR FUMES RELEASED DUE TO HEAT MAY
CAUSE RESPIRATORY.
INGESTION:
INGESTION OF BATTERY CONTENTS MAY CAUSE MOUTH, THROAT AND INTESTINAL BURNS
AND DAMAGE.
SKIN CONTACT:
CONTACT WITH BATTERY ELECTROLYTE MAY CAUSE BURNS AND SKIN IRRITATION.
EYE CONTACT:
CONTACT WITH BATTERY ELECTROLYTE MAY CAUSE BURNS. EYE DAMAGE IS POSSIBLE.
UNDER NORMAL CONDITIONS (DURING CHARGE AND DISCHARGE) RELEASE OF
INGREDIENTS DOES NOT OCCUR. IF ACCIDENTAL RELEASE OCCURS SEE INFORMATION IN
SECTION 2, AND 4. SWALLOWING OF A BATTERY CAN BE HARMFUL. CALL THE LOCAL
POISON CONTROL CENTRE FOR ADVICE AND FOLLOW-UP.
(B) INFORMATION ON TOXICOLOGICAL CHARACTERISTICS:
ACUTE TOXICITY: NO DATA AVAILABLE.
SKIN CORROSION/IRRITATION: THE LIQUID IN THE BATTERY IRRITATES.
SERIOUS EYE DAMAGE/IRRITATION: THE LIQUID IN THE BATTERY IRRITATES.
RESPIRATORY SENSITIZATION:
THE LIQUID IN THE BATTERY MAY CAUSE SENSITIZATION TO SOME PERSON.
SKIN SENSITIZATION:
THE LIQUID IN THE BATTERY MAY CAUSE SENSITIZATION TO SOME PERSON.
CARCINOGENICITY:
COBALT AND COBALT COMPOUNDS ARE CONSIDERED TO BE POSSIBLE HUMAN
CARCINOGEN(S).
GERM CELL MUTAGENICITY: NO DATA AVAILABLE.
REPRODUCTIVE TOXICITY: NO DATA AVAILABLE.
STOT-SINGLE EXPOSURE: NO DATA AVAILABLE.
STOT-REPEATED EXPOSURE: NO DATA AVAILABLE.
ASPIRATION HAZARD: NO DATA AVAILABLE.
| SECTION 12. ECOLOGICAL INFORMATION | |
(A) ECOTOXICITY:
WATER HAZARD CLASS 1 (SELF-ASSESSMENT): SLIGHTLY HAZARDOUS FOR WATER.
(B) PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
(C) BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
(D) MOBILITY IN SOIL: NO INFORMATION AVAILABLE.
(E) OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
(A) SAFE HANDLING AND METHODS OF DISPOSAL:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS. LOCAL REGULATIONS MAY BE MORE STRINGENT THAN
REGIONAL OR NATIONAL REQUIREMENTS.
PRODUCT DISPOSAL RECOMMENDATION:
OBSERVE LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS.
PACKAGING DISPOSAL RECOMMENDATION:
BE AWARE DISCARDED BATTERIES MAY CAUSE FIRE, TAPE THE BATTERY TERMINALS TO
INSULATE THEM. DON'T DISASSEMBLY THE BATTERY. COMPLETELY DISCHARGE
CONTAINERS (NO TEAR DROPS, NO POWDER REST, SCRAPED CAREFULLY). CONTAINERS
MAY BE RECYCLED OR RE-USED. OBSERVE LOCAL, STATE AND FEDERAL LAWS AND
REGULATIONS. THE POTENTIAL EFFECTS ON THE ENVIRONMENT AND HUMAN HEALTH OF
THE SUBSTANCES USED IN BATTERIES AND ACCUMULATORS; THE DESIRABILITY OF NOT
DISPOSING OF WASTE BATTERIES AND ACCUMULATORS AS UNSORTED MUNICIPAL WASTE
AND OF PARTICIPATING IN THEIR SEPARATE COLLECTION SO AS TO FACILITATE
TREATMENT AND RECYCLING.
| SECTION 14. TRANSPORT INFORMATION | |
IMDG:
BATTERIES THAT ARE CLASSIFIED AS NONSPILLABLE HAVE BEEN TESTED AND MEET THE
NONSPILLABLE CRITERIA LISTED IN SPECIAL PROVISION 238. NON-SPILLABLE
BATTERIES MUST BE PACKED ACCORDING TO IMDG PACKING INSTRUCTION P003. THESE
BATTERIES ARE EXCEPTED FROM ALL IMDG CODE PROVIDED TH AT THE BATTERIES'
TERMINALS ARE PROTECTED AGAINST SHORT CIRCUITS PER PP16.
IATA:
BATTERIES THAT ARE CLASSIFIED AS NONSPILLABLE HAVE BEEN TESTED AND MEET THE
NONSPILLABLE CRITERIA LISTED IN IATA PACKING INSTRUCTION 806 AND SPECIAL
PROVISION A67. NONSPILLABLE BATTERIES M UST BE PACKED ACCORDING TO IATA
PACKING INSTRUCTION 806. THESE BATTERIES ARE EXCEPTED FROM ALL IATA
REGULATIONS PROVIDED THAT THE BATTERIES' TERMINALS ARE PROTECTED AGAINST
SHORT CIRCUITS. THE BATTERY ACCORDING TO THE 2015 IATA DANGEROUS GOODS
REGULATIONS 56TH EDITION MAY BE TRANSPORTED AND APPLICABLE U.S. DOT
REGULATIONS FOR THE SAFE TRANSPORT OF THE BATTERY.
(A) UN NUMBER: 2800
(B) UN PROPER SHIPPING NAME:
BATTERIES, VRLA GEL TYPE, ACID IS ADSORBED INTO THE SEPARATOR, ELECTRIC
STORAGE
(C) TRANSPORT HAZARD CLASS(ES): 8
(D) PACKING INSTRUCTION (IF APPLICABLE): NO INFORMATION AVAILABLE.
(E) MARINE POLLUTANT (YES/NO): NO
(F) TRANSPORT IN BULK (ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC
CODE): NO INFORMATION AVAILABLE.
(G) SPECIAL PRECAUTIONS: NO INFORMATION AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200):
( ) HAZARDOUS
(X) NON-HAZARDOUS
| SECTION 16. OTHER INFORMATION | |
(A) PREPARATION AND REVISION INFORMATION:
DATE OF PREVIOUS REVISION: NOT APPLICABLE.
DATE OF THIS REVISION: 2015-10-09
REVISION SUMMARY: THE FIRST NEW SDS
(B) ABBREVIATIONS AND ACRONYMS:
TSCA: TOXIC SUBSTANCES CONTROL ACT, THE AMERICAN CHEMICAL INVENTORY.
DSL: DOMESTIC SUBSTANCES LIST
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ENCS: JAPANESE EXISTING AND NEW CHEMICAL SUBSTANCES
ECL: EXISTING CHEMICALS LIST, THE KOREAN CHEMICAL INVENTORY
IECSC: INVENTORY OF EXISTING CHEMICAL SUBSTANCES IN CHINA.
(C) DISCLAIMER:
BECAUSE ALL OF OUR BATTERIES ARE DEFINED AS "ARTICLES", THEY ARE EXEMPTED
FROM THE REQUIREMENTS OF THE HAZARD COMMUNICATION STANDARD. THE INFORMATION
IN THIS SDS IS PROVIDED ALL THE RELEVANT DATA FULLY AND TRULY. HOWEVER, THE
INFORMATION IS PROVIDED WITHOUT ANY WARRANTY ON THEIR ABSOLUTE
EXTENSIVENESS AND ACCURACY. THIS SDS WAS PREPARED TO PROVIDE SAFETY
PREVENTIVE MEASURES FOR THE USERS WHO HAVE GOT PROFESSIONAL TRAINING. THE
PERSONAL USER WHO OBTAINED THIS SDS SHOULD MAKE INDEPENDENT JUDGMENT FOR
THE APPLICABILITY OF THIS SDS UNDER SPECIAL CONDITIONS. IN THESE SPECIAL
CASES, WE DO NOT ASSUME RESPONSIBILITY FOR THE DAMAGE.
SHENZHEN ANBOTEK COMPLIANCE LABORATORY LIMITED
ADDRESS:
1/F., BUILDING 1, SEC INDUSTRIAL PARK
NO. 0409 QIANHAI ROAD
NANSHAN DISTRICT, SHENZHEN, GUANGDONG
CHINA
TEL: (86) 755-26066544
FAX: (86)755-26014772
EMAIL: SERVICE@ANBOTEK.COM
HTTP://WWW.ANBOTEK.COM.CN