| Common Name: | BATHROOM CLEANER CONCENTRATE (PRODUCT NO. 44, CHEMICAL MANAGEMENT SYSTEMS) |
| Manufacturer: | 3M |
| SDS Revision Date: | 7/1/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 3GZX2, 53ZG68 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
3M(TM) BATHROOM CLEANER CONCENTRATE (PRODUCT NO. 44, 3M(TM) CHEMICAL
MANAGEMENT SYSTEMS)
07/01/16
3M
SAFETY DATA SHEET
COPYRIGHT, 2016, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFITTHEREON.
DOCUMENT GROUP: 22-4730-2
VERSION NUMBER: 8.00
ISSUE DATE: 07/01/16
SUPERCEDES DATE: 10/07/15
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) BATHROOM CLEANER CONCENTRATE (PRODUCT NO. 44, 3M(TM) CHEMICAL
MANAGEMENT SYSTEMS)
PRODUCT IDENTIFICATION NUMBERS:
ID NUMBER UPC
61-0000-6360-4
61-0000-6424-8
70-0713-1362-4 500-48011-59165-5
70-0716-8326-5 500-48011-59164-8
61-0000-6395-0
70-0713-1361-6 500-48011-59164-8
70-0716-5993-5 500-51125-85929-0
70-0716-8327-3 500-48011-59165-5
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
MILD ACID CLEANER REMOVES SOAP SCUM AND SCALE FROM BATHROOM SURFACES
INCLUDING PLASTIC, PORCELAIN, CERAMIC, FIBERGLASS, FLOORS AND FIXTURES. DO
NOT USE ON MARBLE SURFACES., THIS PRODUCT MEETS GREEN SEAL(TM) STANDARD
GS-37 BASED ON EFFECTIVE PERFORMANCE, CONCENTRATED VOLUME,
MINIMIZED/RECYCLED PACKAGING, AND PROTECTIVE LIMITS ON: VOCS AND HUMAN &
ENVIRONMENTAL TOXICITY. ACUTE TOXICITY AND SKIN/EYE DAMAGE MET REQUIREMENTS
AT THE AS-USED DILUTION, AS SPECIFIED FOR CLOSED DILUTION SYSTEMS.
GREENSEAL.ORG., HARD SURFACE CLEANER
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: COMMERCIAL SOLUTIONS DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION
CORROSIVE TO METAL: CATEGORY 1.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
CORROSION
EXCLAMATION MARK
PICTOGRAMS:
CORROSION
EXCLAMATION MARK
HAZARD STATEMENTS:
MAY BE CORROSIVE TO METALS.
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE RESPIRATORY IRRITATION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP ONLY IN ORIGINAL CONTAINER.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE/FACE PROTECTION.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
SPECIFIC TREATMENT (SEE NOTES TO PHYSICIAN ON THIS LABEL).
ABSORB SPILLAGE TO PREVENT MATERIAL DAMAGE.
STORAGE:
STORE IN A CORROSIVE RESISTANT CONTAINER WITH A RESISTANT INNER LINER.
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED
MAY CAUSE CHEMICAL GASTROINTESTINAL BURNS. MAY CAUSE CHEMICAL RESPIRATORY
TRACT BURNS.
33% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
1-OCTYL-2-PYRROLIDINONE 2687-94-7 10 - 30 TRADE SECRET *
WATER 7732-18-5 10 - 30 TRADE SECRET *
HYDROXYACETIC ACID 79-14-1 10 - 30 TRADE SECRET *
MALIC ACID 6915-15-7 10 - 30 TRADE SECRET *
AMINES, COCO ALKYLDIMETHYL, 61788-90-7 1 - 5 TRADE SECRET *
N-OXIDES
ETHOXYLATED C9-11 ALCOHOLS 68439-46-3 1 - 5 TRADE SECRET *
FRAGRANCE ADDED MIXTURE 0.1 - 1.5 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION: REMOVE PERSON TO FRESH AIR. GET IMMEDIATE MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTAMINATED CLOTHING. GET IMMEDIATE MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA
MATERIAL WILL NOT BURN. USE A FIRE FIGHTING AGENT SUITABLE FOR THE
SURROUNDING FIRE. NON-COMBUSTIBLE. USE A FIRE FIGHTING AGENT SUITABLE FOR
SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A METAL CONTAINER APPROVED FOR USE IN TRANSPORTATION BY
APPROPRIATE AUTHORITIES. THE CONTAINER MUST BE LINED WITH POLYETHYLENE
PLASTIC OR CONTAIN A PLASTIC DRUM LINER MADE OF POLYETHYLENE. CLEAN UP
RESIDUE WITH WATER. COVER, BUT DO NOT SEAL FOR 48 HOURS. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. THIS PRODUCT IS NOT INTENDED TO BE
USED WITHOUT PRIOR DILUTION AS SPECIFIED ON THE PRODUCT LABEL. GROUNDING OR
SAFETY SHOES WITH ELECTROSTATIC DISSIPATING SOLES (ESD) ARE NOT REQUIRED
WITH A CHEMICAL DISPENSING SYSTEM. KEEP OUT OF REACH OF CHILDREN. DO NOT
BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. WASH
CONTAMINATED CLOTHING BEFORE REUSE. KEEP AWAY FROM REACTIVE METALS (EG.
ALUMINUM, ZINC ETC.) TO AVOID THE FORMATION OF HYDROGEN GAS THAT COULD
CREATE AN EXPLOSION HAZARD.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. KEEP ONLY
IN ORIGINAL CONTAINER. STORE IN A CORROSIVE RESISTANT CONTAINER WITH A
RESISTANT INNER LINER. STORE AWAY FROM STRONG BASES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL COMMENTS
HYDROXYACETIC ACID 79-14-1 CMRG TWA: 10 MG/M3
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE IN A WELL-VENTILATED AREA. USE GENERAL DILUTION VENTILATION AND/OR
LOCAL EXHAUST VENTILATION TO CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT
EXPOSURE LIMITS AND/OR CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF
VENTILATION IS NOT ADEQUATE, USE RESPIRATORY PROTECTION EQUIPMENT.
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, SPECIAL
VENTILATION IS NOT REQUIRED.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, EYE CONTACT WITH
THE CONCENTRATE IS NOT EXPECTED TO OCCUR. IF THE PRODUCT IS NOT USED WITH
A CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN ACCIDENTAL RELEASE, WEAR
PROTECTIVE EYE/FACE PROTECTION.
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN
ACCIDENTAL RELEASE: SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT
BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE
PROTECTION(S) ARE RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, SKIN CONTACT WITH
THE CONCENTRATE IS NOT EXPECTED TO OCCUR. IF PRODUCT IS NOT USED WITH A
CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN ACCIDENTAL RELEASE: SELECT AND
USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL STANDARDS
TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE LEVELS,
CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION, PHYSICAL
CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS. CONSULT
WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR SELECTION OF
APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYVINYL CHLORIDE
POLYMER LAMINATE
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN
ACCIDENTAL RELEASE:
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT. THE FOLLOWING
PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - POLYMER LAMINATE
APRON - PVC
RESPIRATORY PROTECTION
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, RESPIRATORY
PROTECTION IS NOT REQUIRED.
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN
ACCIDENTAL RELEASE:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: GREEN COLOR WITH FLORAL FRAGRANCE.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: APPROXIMATELY 0.9 - 1.5
BOILING POINT: >95 DEG. F
FLASH POINT: NO FLASH POINT
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
VAPOR PRESSURE: 15 PSIA - 40 PSIA [@ 131 DEG. F]
SPECIFIC GRAVITY: APPROXIMATELY 1.12 [REF STD: WATER=1]
SOLUBILITY IN WATER: COMPLETE
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: APPROXIMATELY 100 CENTIPOISE
HAZARDOUS AIR POLLUTANTS: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS:
<0.00001 [TEST METHOD: CALCULATED PER CARB TITLE 2]
PERCENT VOLATILE: NO DATA AVAILABLE
VOC LESS H2O & EXEMPT SOLVENTS:
</=0 G/L [TEST METHOD: CALCULATED PER CARB TITLE 2]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: STRONG BASES
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION: MAY BE HARMFUL IF INHALED.
RESPIRATORY TRACT CORROSION:
SIGNS/SYMPTOMS MAY INCLUDE NASAL DISCHARGE, SEVERE NOSE AND THROAT PAIN,
CHEST TIGHTNESS AND PAIN, COUGHING UP BLOOD, WHEEZING, AND BREATHLESSNESS,
POSSIBLY PROGRESSING TO RESPIRATORY FAILURE.
SKIN CONTACT:
CORROSIVE (SKIN BURNS):
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, INTENSE
PAIN, BLISTERING, ULCERATION, AND TISSUE DESTRUCTION.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION: MAY BE HARMFUL IF SWALLOWED.
GASTROINTESTINAL CORROSION:
SIGNS/SYMPTOMS MAY INCLUDE SEVERE MOUTH, THROAT AND ABDOMINAL PAIN; NAUSEA;
VOMITING; AND DIARRHEA; BLOOD IN THE FECES AND/OR VOMITUS MAY ALSO BE SEEN.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
DUST/MIST(4 CALCULATED ATE
HR) 5 - 12.5 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE
2,000 - 5,000 MG/KG
1-OCTYL-2- DERMAL RABBIT LD50: >2,000 MG/KG
PYRROLIDINONE
1-OCTYL-2- INGESTION RAT LD50: 2,050 MG/KG
PYRROLIDINONE
HYDROXYACETIC ACID INHALATION- RAT LC50: 2.5 MG/L
DUST/MIST
(4 HOURS)
HYDROXYACETIC ACID INGESTION RAT LD50: 2,040 MG/KG
MALIC ACID INGESTION RAT LD50: >3,200 MG/KG
MALIC ACID DERMAL SIMILAR LD50: >20,000 MG/KG
COMPOUNDS
MALIC ACID INHALATION- SIMILAR LC50: >1.306 MG/L
DUST/MIST COMPOUNDS
(4 HOURS)
AMINES, COCO DERMAL LD50 ESTIMATED TO BE
ALKYLDIMETHYL, 2,000 - 5,000 MG/KG
N-OXIDES
AMINES, COCO INGESTION RAT LD50: >2,000 MG/KG
ALKYLDIMETHYL,
N-OXIDES
ETHOXYLATED C9-11 DERMAL RABBIT LD50: >2,000 MG/KG
ALCOHOLS
ETHOXYLATED C9-11 INGESTION RAT LD50: 1,378 MG/KG
ALCOHOLS
FRAGRANCE ADDED DERMAL RABBIT LD50: >5,000 MG/KG
FRAGRANCE ADDED INGESTION RAT LD50: 4,498 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
HYDROXYACETIC ACID RABBIT CORROSIVE
MALIC ACID RABBIT MILD IRRITANT
AMINES, COCO PROFESSIONAL MILD IRRITANT
ALKYLDIMETHYL, JUDGMENT
N-OXIDES
ETHOXYLATED C9-11 RABBIT IRRITANT
ALCOHOLS
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
HYDROXYACETIC ACID RABBIT CORROSIVE
MALIC ACID RABBIT SEVERE IRRITANT
AMINES, COCO PROFESSIONAL CORROSIVE
ALKYLDIMETHYL, JUDGEMENT
N-OXIDES
ETHOXYLATED C9-11 PROFESSIONAL CORROSIVE
ALCOHOLS JUDGEMENT
SKIN SENSITIZATION:
NAME SPECIES VALUE
HYDROXYACETIC ACID GUINEA PIG NOT SENSITIZING
MALIC ACID SIMILAR COMPOUNDS NOT SENSITIZING
AMINES, COCO ALKYLDIMETHYL, N-OXIDES SIMILAR COMPOUNDS NOT SENSITIZING
ETHOXYLATED C9-11 ALCOHOLS GUINEA PIG NOT SENSITIZING
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
HYDROXYACETIC ACID IN VITRO NOT MUTAGENIC
HYDROXYACETIC ACID IN VIVO NOT MUTAGENIC
MALIC ACID IN VITRO NOT MUTAGENIC
ETHOXYLATED C9-11 ALCOHOLS IN VITRO NOT MUTAGENIC
CARCINOGENICITY:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
HYDROXYACETIC ACID INGESTION SOME POSITIVE DEVELOPMENTAL DATA EXIST,
BUT THE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
MALIC ACID INGESTION NOT TOXIC TO FEMALE REPRODUCTION
MALIC ACID INGESTION NOT TOXIC TO DEVELOPMENT
MALIC ACID INGESTION SOME POSITIVE MALE REPRODUCTIVE DATA
EXIST, BUT THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
ETHOXYLATED C9-11 DERMAL NOT TOXIC TO FEMALE REPRODUCTION
ALCOHOLS
ETHOXYLATED C9-11 DERMAL NOT TOXIC TO DEVELOPMENT
ALCOHOLS
ETHOXYLATED C9-11 DERMAL SOME POSITIVE MALE REPRODUCTIVE DATA
ALCOHOLS EXIST, BUT THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
HYDROXYACETIC ACID RAT NOAEL: DURING
150 MG/KG/DAY GESTATION
MALIC ACID RAT NOAEL: 2 GENERATION
10000 PPM IN
THE DIET
MALIC ACID RAT NOAEL: DURING
350 MG/KG/DAY ORGANOGENESIS
MALIC ACID RAT NOAEL: 104 WEEKS
2,000 MG/KG/DAY
ETHOXYLATED C9-11 RAT NOAEL: 2 GENERATION
ALCOHOLS 250 MG/KG/DAY
ETHOXYLATED C9-11 RAT NOAEL: 2 GENERATION
ALCOHOLS 250 MG/KG/DAY
ETHOXYLATED C9-11 RAT NOAEL: 2 GENERATION
ALCOHOLS 100 MG/KG/DAY
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
AMINES, COCO INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
ALKYLDIMETHYL, IRRITATION BUT THE DATA ARE NOT
N-OXIDES SUFFICIENT FOR CLASSIFICATION
ETHOXYLATED INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
C9-11 ALCOHOLS IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
AMINES, COCO NOAEL:
ALKYLDIMETHYL, NOT AVAILABLE
N-OXIDES
ETHOXYLATED NOT NOAEL: NOT AVAILABLE
C9-11 ALCOHOLS AVAILABLE NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
HYDROXYACETIC INHALATION HEART | SOME POSITIVE
ACID HEMATOPOIETIC DATA EXIST, BUT
SYSTEM | LIVER | THE DATA ARE NOT
IMMUNE SYSTEM | SUFFICIENT FOR
KIDNEY AND/OR CLASSIFICATION
BLADDER |
RESPIRATORY
SYSTEM
HYDROXYACETIC INGESTION KIDNEY AND/OR SOME POSITIVE
ACID BLADDER DATA EXIST, BUT
THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
HYDROXYACETIC INGESTION HEMATOPOIETIC SOME POSITIVE
ACID SYSTEM DATA EXIST, BUT
THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
HYDROXYACETIC INGESTION LIVER SOME POSITIVE
ACID DATA EXIST, BUT
THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
HYDROXYACETIC INGESTION MUSCLES | NERVOUS ALL DATA ARE
ACID SYSTEM NEGATIVE
HYDROXYACETIC INGESTION RESPIRATORY ALL DATA ARE
ACID SYSTEM NEGATIVE
MALIC ACID INGESTION HEART | ENDOCRINE SOME POSITIVE
SYSTEM | DATA EXIST, BUT
HEMATOPOIETIC THE DATA ARE NOT
SYSTEM | LIVER | SUFFICIENT FOR
KIDNEY AND/OR CLASSIFICATION
BLADDER
ETHOXYLATED C9-11 DERMAL KIDNEY AND/OR SOME POSITIVE
ALCOHOLS BLADDER DATA EXIST, BUT
THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ETHOXYLATED C9-11 DERMAL HEMATOPOIETIC ALL DATA ARE
ALCOHOLS SYSTEM NEGATIVE
NAME SPECIES TEST RESULT EXPOSURE DURATION
HYDROXYACETIC RAT NOAEL: 2 WEEKS
ACID 1.4 MG/L
HYDROXYACETIC RAT NOAEL: 248 DAYS
ACID 400 MG/KG/DAY
HYDROXYACETIC RAT NOAEL: 90 DAYS
ACID 600 MG/KG/DAY
HYDROXYACETIC OTHER LOAEL: 59 DAYS
ACID 97 MG/KG/DAY
HYDROXYACETIC RAT NOAEL: 90 DAYS
ACID 600 MG/KG/DAY
HYDROXYACETIC DOG NOAEL: 119 DAYS
ACID 500 MG/KG/DAY
MALIC ACID RAT NOAEL: 104 WEEKS
2,500 MG/KG/DAY
ETHOXYLATED C9-11 RAT NOAEL: 13 WEEKS
ALCOHOLS 125 MG/KG/DAY
ETHOXYLATED C9-11 RAT NOAEL: 13 WEEKS
ALCOHOLS 125 MG/KG/DAY
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION ONE OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION ONE OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION ONE OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR ITS
COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): D002 (CORROSIVE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT HTTP://3M.COM/TRANSPORTINFO OR CALL
1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
REACTIVITY HAZARD: NO
PRESSURE HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
15.2. STATE REGULATIONS:
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
AUSTRALIA NATIONAL INDUSTRIAL CHEMICAL NOTIFICATION AND ASSESSMENT SCHEME
(NICNAS). CERTAIN RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR
ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE NEW SUBSTANCE
NOTIFICATION REQUIREMENTS OF CEPA.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE CHINA "MEASURES
ON ENVIRONMENTAL MANAGEMENT OF NEW CHEMICAL SUBSTANCE". CERTAIN
RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR ADDITIONAL
INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
THE KOREAN TOXIC CHEMICAL CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
PHILIPPINES RA 6969 REQUIREMENTS. CERTAIN RESTRICTIONS MAY APPLY. CONTACT
THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
15.4. INTERNATIONAL REGULATIONS:
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 0
INSTABILITY 0
SPECIAL HAZARDS NONE
ACID/BASE: ACID
CORROSIVE: YES
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
HMIS HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) IV) HAZARD RATINGS ARE
DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE. THESE
RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL UNDER EXPECTED
CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE IN EMERGENCY
SITUATIONS. HMIS(R*) IV RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED
HMIS(R*) IV PROGRAM. HMIS(R*) IS A REGISTERED MARK OF THE AMERICAN COATINGS
ASSOCIATION (ACA).
DOCUMENT GROUP: 22-4730-2
VERSION NUMBER: 8.00
ISSUE DATE: 07/01/16
SUPERCEDES DATE: 10/07/15
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