| Common Name: | PRO-GRADE PITCH POCKET & SELF-LEVELING ROOF SEALER |
| Manufacturer: | HENRY |
| SDS Revision Date: | 3/26/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 54EP14 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENRY(R*)
SAFETY DATA SHEET
ISSUE DATE: 26-MAR-2016
REVISION DATE: 26-MAR-2016
VERSION: 1
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: PRO-GRADE(R*) PITCH POCKET & SELF-LEVELING ROOF SEALER
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: PG928
SYNONYMS: NONE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: SEALANT
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER ADDRESS:
HENRY COMPANY
999 N. SEPULVEDA BLVD., SUITE 800
EL SEGUNDO, CA 90245-2716
WEB SITE:
WWW.HENRY.COM
WWW.CA.HENRY.COM
EMERGENCY TELEPHONE NUMBER:
COMPANY PHONE NUMBER: 800-486-1278
EMERGENCY TELEPHONE:
CHEMTREC: 800-424-9300
CHEMTREC: 703-527-3887
CANUTEC: 613-966-6666
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
OSHA REGULATORY STATUS:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
LABEL ELEMENTS:
EMERGENCY OVERVIEW:
WARNING
HAZARD STATEMENTS:
CAUSES SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
EXCLAMATION MARK
APPEARANCE: VISCOUS
PHYSICAL STATE: LIQUID
ODOR: SLIGHT
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
PRECAUTIONARY STATEMENTS - RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION
TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
OTHER INFORMATION: NOT APPLICABLE.
UNKNOWN ACUTE TOXICITY:
63% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE: NOT APPLICABLE
MIXTURE:
CHEMICAL NAME CAS NO WEIGHT-%
POLYSILOXANES * PROPRIETARY 15 - 40
NEPHELINE SYENITE * 37244-96-5 15 - 40
POLY[OXY(DIMETHYLSILYLENE)] * 9016-00-6 10 - 30
2-BUTANONE, O,O,O-(METHYLSILYLIDYNE)TRIOXIME * 22984-54-9 1 - 5
CARBON BLACK * 1333-86-4 0.1 - 1
*THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS
A TRADE SECRET.
| 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
IN CASE OF ACCIDENT OR UNWELLNESS, SEEK MEDICAL ADVICE IMMEDIATELY (SHOW
DIRECTIONS FOR USE OR SAFETY DATA SHEET IF POSSIBLE). IF SYMPTOMS PERSIST,
CALL A PHYSICIAN.
EYE CONTACT:
IMMEDIATELY FLUSH WITH PLENTY OF WATER. AFTER INITIAL FLUSHING, REMOVE ANY
CONTACT LENSES AND CONTINUE FLUSHING FOR AT LEAST 15 MINUTES. KEEP EYE WIDE
OPEN WHILE RINSING. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER WHILE REMOVING ALL
CONTAMINATED CLOTHES AND SHOES. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
INHALATION:
REMOVE TO FRESH AIR. IF BREATHING IS IRREGULAR OR STOPPED, ADMINISTER
ARTIFICIAL RESPIRATION. AVOID DIRECT CONTACT WITH SKIN. USE BARRIER TO
GIVE MOUTH-TO-MOUTH RESUSCITATION. IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
INGESTION:
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. DO NOT INDUCE
VOMITING WITHOUT MEDICAL ADVICE. RINSE MOUTH. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON.
SELF-PROTECTION OF THE FIRST AIDER:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS:
MAY CAUSE REDNESS AND TEARING OF THE EYES. MAY CAUSE SKIN IRRITATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTE TO PHYSICIANS: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT. CO2, DRY CHEMICAL, DRY SAND, ALCOHOL-RESISTANT
FOAM.
UNSUITABLE EXTINGUISHING MEDIA:
CAUTION: USE OF WATER SPRAY WHEN FIGHTING FIRE MAY BE INEFFICIENT.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
THERMAL DECOMPOSITION CAN LEAD TO RELEASE OF IRRITATING AND TOXIC GASES AND
VAPORS.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NONE.
SENSITIVITY TO STATIC DISCHARGE: NONE.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. ENSURE ADEQUATE VENTILATION,
ESPECIALLY IN CONFINED AREAS.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS. DO NOT
FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
COVER LIQUID SPILL WITH SAND, EARTH OR OTHER NON-COMBUSTIBLE ABSORBENT
MATERIAL. USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. DAM UP. TAKE UP
MECHANICALLY, PLACING IN APPROPRIATE CONTAINERS FOR DISPOSAL. CLEAN
CONTAMINATED SURFACE THOROUGHLY.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
AVOID CONTACT WITH SKIN, EYES OR CLOTHING. USE PERSONAL PROTECTIVE
EQUIPMENT AS REQUIRED. WASH CONTAMINATED CLOTHING BEFORE REUSE. DO NOT
BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT EAT, DRINK OR SMOKE WHEN
USING THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. KEEP OUT
OF THE REACH OF CHILDREN.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. STRONG ACIDS. STRONG BASES.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
CARBON BLACK TWA: 3 MG/M3 TWA: 3.5 MG/M3 IDLH: 1750 MG/M3
1333-86-4 INHALABLE FRACTION TWA: 3.5 MG/M3
TWA: 0.1 MG/M3
CARBON BLACK IN
PRESENCE OF POLYCYCLIC
AROMATIC HYDROCARBONS
PAH
NIOSH IDLH IMMEDIATELY DANGEROUS TO LIFE OR HEALTH
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS:
SHOWERS
EYEWASH STATIONS
VENTILATION SYSTEMS.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN AND BODY PROTECTION: WEAR PROTECTIVE GLOVES AND PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
IF EXPOSURE LIMITS ARE EXCEEDED OR IRRITATION IS EXPERIENCED, NIOSH/MSHA
APPROVED RESPIRATORY PROTECTION SHOULD BE WORN. POSITIVE-PRESSURE SUPPLIED
AIR RESPIRATORS MAY BE REQUIRED FOR HIGH AIRBORNE CONTAMINANT
CONCENTRATIONS. RESPIRATORY PROTECTION MUST BE PROVIDED IN ACCORDANCE WITH
CURRENT LOCAL REGULATIONS.
GENERAL HYGIENE CONSIDERATIONS:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: VISCOUS
COLOR: PIGMENTED
ODOR: SLIGHT
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES REMARKS - METHOD
PH 6-11
MELTING POINT / FREEZING POINT NO INFORMATION AVAILABLE
BOILING POINT / BOILING RANGE >100 DEG. C / 212 DEG. F
FLASH POINT >100 DEG. C / 212 DEG. F PENSKY-MARTENS
CLOSED CUP (PMCC)
EVAPORATION RATE NO INFORMATION AVAILABLE
FLAMMABILITY (SOLID, GAS) NO INFORMATION AVAILABLE
FLAMMABILITY LIMIT IN AIR:
UPPER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
LOWER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
VAPOR PRESSURE NO INFORMATION AVAILABLE
VAPOR DENSITY NO INFORMATION AVAILABLE
RELATIVE DENSITY 1.2 - 1.3
WATER SOLUBILITY INSOLUBLE IN WATER
SOLUBILITY IN OTHER SOLVENTS NO INFORMATION AVAILABLE
PARTITION COEFFICIENT NO INFORMATION AVAILABLE
AUTOIGNITION TEMPERATURE NO INFORMATION AVAILABLE
DECOMPOSITION TEMPERATURE NO INFORMATION AVAILABLE
KINEMATIC VISCOSITY NO INFORMATION AVAILABLE
DYNAMIC VISCOSITY NO INFORMATION AVAILABLE
EXPLOSIVE PROPERTIES NOT AN EXPLOSIVE
OXIDIZING PROPERTIES NOT APPLICABLE
OTHER INFORMATION:
SOFTENING POINT NO INFORMATION AVAILABLE
MOLECULAR WEIGHT NO INFORMATION AVAILABLE
VOC CONTENT (%) NO INFORMATION AVAILABLE
DENSITY NO INFORMATION AVAILABLE
BULK DENSITY NO INFORMATION AVAILABLE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: ELEVATED TEMPERATURE. INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. STRONG ACIDS. STRONG BASES.
HAZARDOUS DECOMPOSITION PRODUCTS:
THERMAL DECOMPOSITION CAN LEAD TO RELEASE OF IRRITATING AND TOXIC GASES AND
VAPORS.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
INHALATION: NO DATA AVAILABLE.
EYE CONTACT: SEVERELY IRRITATING TO EYES.
SKIN CONTACT: IRRITATING TO SKIN.
INGESTION: NO DATA AVAILABLE.
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50
POLYSILOXANES >15400 MG/KG (RAT) >16 ML/KG (RABBIT) >8750 MG/M3
(RAT) 7 H
CARBON BLACK >15400 MG/KG (RAT) >3 G/KG (RABBIT)
1333-86-4
INFORMATION ON TOXICOLOGICAL EFFECTS:
SYMPTOMS:
MAY CAUSE REDNESS AND TEARING OF THE EYES. MAY CAUSE SKIN IRRITATION.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
SENSITIZATION: NO INFORMATION AVAILABLE.
GERM CELL MUTAGENICITY: NO INFORMATION AVAILABLE.
CARCINOGENICITY:
THIS PRODUCT CONTAINS CARBON BLACK WHICH IS CLASSIFIED AS A POSSIBLE
CARCINOGEN WHEN PRESENT AS RESPIRABLE DUST. THIS IS NOT RELEVANT FOR THIS
PRODUCT SINCE IT IS NOT IN A RESPIRABLE FORM. THE TABLE BELOW INDICATES
WHETHER EACH AGENCY HAS LISTED ANY INGREDIENT AS A CARCINOGEN.
CHEMICAL NAME ACGIH IARC NTP OSHA
CARBON BLACK A3 GROUP 2B X
1333-86-4
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS):
A3 - ANIMAL CARCINOGEN
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
GROUP 2B - POSSIBLY CARCINOGENIC TO HUMANS
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT OF
LABOR): X - PRESENT
REPRODUCTIVE TOXICITY: NO INFORMATION AVAILABLE.
STOT - SINGLE EXPOSURE: TARGET ORGANS. EYES. SKIN.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
TARGET ORGAN EFFECTS: EYES, SKIN, LUNGS, RESPIRATORY SYSTEM.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
NUMERICAL MEASURES OF TOXICITY - PRODUCT INFORMATION:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT.:
ATEMIX (ORAL): 9,380.00 MG/KG
ATEMIX (DERMAL): 19,693.81 MG/KG
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
79% OF THE MIXTURE CONSISTS OF COMPONENTS(S) OF UNKNOWN HAZARDS TO THE
AQUATIC ENVIRONMENT
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION: BIOACCUMULATIVE POTENTIAL.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
DISPOSAL OF WASTES:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING: DO NOT REUSE CONTAINER.
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED
TDG: NOT REGULATED
IATA: NOT REGULATED
IMDG: NOT REGULATED
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA: COMPLIES
DSL/NDSL: COMPLIES
EINECS/ELINCS: COMPLIES
IECSC: COMPLIES
KECL: COMPLIES
PICCS: COMPLIES
AICS: COMPLIES
LEGEND:
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
EINECS/ELINCS:
EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES/EUROPEAN LIST OF
NOTIFIED CHEMICAL SUBSTANCES
ENCS: JAPAN EXISTING AND NEW CHEMICAL SUBSTANCES
IECSC: CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES
KECL: KOREAN EXISTING AND EVALUATED CHEMICAL SUBSTANCES
PICCS: PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL SUBSTANCES
AICS: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES
US FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: NO
FIRE HAZARD: NO
REACTIVE HAZARD: NO
SUDDEN RELEASE OF PRESSURE HAZARD: NO
CWA (CLEAN WATER ACT):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42)
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS
HAZARDOUS SUBSTANCES UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302) OR THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) (40 CFR 355). THERE MAY BE
SPECIFIC REPORTING REQUIREMENTS AT THE LOCAL, REGIONAL, OR STATE LEVEL
PERTAINING TO RELEASES OF THIS MATERIAL
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS THE FOLLOWING PROPOSITION 65 CHEMICALS
CHEMICAL NAME CALIFORNIA PROPOSITION 65
CARBON BLACK - 1333-86-4 CARCINOGEN
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
CHEMICAL NAME NEW JERSEY MASSACHUSETTS PENNSYLVANIA
CARBON BLACK X X X
1333-86-4
U.S. EPA LABEL INFORMATION:
EPA PESTICIDE REGISTRATION NUMBER: NOT APPLICABLE
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OF THE LAST REVISION
NFPA:
HEALTH HAZARDS 1
FLAMMABILITY 1
INSTABILITY 0
PHYSICAL AND CHEMICAL PROPERTIES
HMIS:
HEALTH HAZARDS 1
FLAMMABILITY 1
PHYSICAL HAZARDS 0
PERSONAL PROTECTION X
ISSUE DATE: 26-MAR-2016
REVISION DATE: 26-MAR-2016
REVISION NOTE: NO INFORMATION AVAILABLE
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS MATERIAL SAFETY DATA SHEET IS CORRECT TO
THE BEST OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS
PUBLICATION. THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE
HANDLING, USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE
AND IS NOT TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE
INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT
BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS
OR IN ANY PROCESS, UNLESS SPECIFIED IN THE TEXT.