| Common Name: | RUST TOUGH RUST PREVENTIVE ENAMEL (AEROSOL), SAFETY RED (OSHA RED) |
| Manufacturer: | KRYLON PRODUCTS |
| SDS Revision Date: | 5/22/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 54TH77 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
R00639
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME:
RUST TOUGH(R*) RUST PREVENTIVE ENAMEL (AEROSOL)
SAFETY RED (OSHA RED)
PRODUCT CODE: R00639
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS #: NOT APPLICABLE.
PRODUCT TYPE: AEROSOL.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: NOT APPLICABLE.
MANUFACTURER:
KRYLON PRODUCTS GROUP
101 PROSPECT AVENUE NW
CLEVELAND, OH 44115
EMERGENCY TELEPHONE NUMBER OF THE COMPANY: (216) 566-2917
PRODUCT INFORMATION TELEPHONE NUMBER: (800) 247-3266
REGULATORY INFORMATION TELEPHONE NUMBER: (216) 566-2902
TRANSPORTATION EMERGENCY TELEPHONE NUMBER: (800) 424-9300
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: COMPRESSED GAS
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE / EYE IRRITATION: CATEGORY 2A
SKIN SENSITIZATION: CATEGORY 1
CARCINOGENICITY: CATEGORY 2
TOXIC TO REPRODUCTION (UNBORN CHILD): CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (RESPIRATORY TRACT
IRRITATION): CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (NARCOTIC EFFECTS):
CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2
ASPIRATION HAZARD: CATEGORY 1
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN ACUTE
TOXICITY: 32.9%
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
SUSPECTED OF DAMAGING THE UNBORN CHILD.
SUSPECTED OF CAUSING CANCER.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. WEAR PROTECTIVE GLOVES. WEAR
EYE OR FACE PROTECTION. WEAR PROTECTIVE CLOTHING. KEEP AWAY FROM HEAT, HOT
SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. NO SMOKING. DO
NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE. USE ONLY OUTDOORS OR
IN A WELL-VENTILATED AREA. DO NOT BREATHE DUST OR MIST. WASH HANDS
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED
OUT OF THE WORKPLACE.
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
RESPONSE:
GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. DO NOT INDUCE VOMITING.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE:
STORE LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES
EXCEEDING 50 DEG. C/122 DEG. F. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. CONTAINS SOLVENTS WHICH CAN
CAUSE PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL OR
FATAL.
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. FOR INDUSTRIAL USE
ONLY.
PLEASE REFER TO THE SDS FOR ADDITIONAL INFORMATION. KEEP OUT OF REACH OF
CHILDREN. KEEP UPRIGHT IN A COOL, DRY PLACE. DO NOT DISCARD EMPTY CAN IN
TRASH COMPACTOR.
HAZARDS NOT OTHERWISE CLASSIFIED:
DANGER:
RAGS, STEEL WOOL, OTHER WASTE SOAKED WITH THIS PRODUCT, AND SANDING RESIDUE
MAY SPONTANEOUSLY CATCH FIRE IF IMPROPERLY DISCARDED. IMMEDIATELY PLACE
RAGS, STEEL WOOL, OTHER WASTE SOAKED WITH THIS PRODUCT, AND SANDING RESIDUE
IN A SEALED, WATER-FILLED, METAL CONTAINER. DISPOSE OF IN ACCORDANCE WITH
LOCAL FIRE REGULATIONS.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS NUMBER/OTHER IDENTIFIERS:
INGREDIENT NAME % BY WEIGHT CAS NUMBER
PROPANE 20.4 74-98-6
ACETONE 19.26 67-64-1
N-BUTYL ACETATE 12.08 123-86-4
LT. ALIPHATIC HYDROCARBON SOLVENT 11.23 64742-89-8
BUTANE 9.6 106-97-8
ETHYL 3-ETHOXYPROPIONATE 4 763-69-9
XYLENE 1.66 1330-20-7
TITANIUM DIOXIDE 0.52 13463-67-7
ETHYLBENZENE 0.44 100-41-4
UNSATURATED FATTY ACIDS 0.2 85711-46-2
ZIRCONIUM 2-ETHYLHEXANOATE 0.13 22464-99-9
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH AND HENCE REQUIRE REPORTING IN THIS
SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IF
NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST OCCURS,
PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED PERSONNEL. IT MAY BE
DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION.
GET MEDICAL ATTENTION. IF NECESSARY, CALL A POISON CENTER OR PHYSICIAN. IF
UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL ATTENTION
IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A
COLLAR, TIE, BELT OR WAISTBAND. IN CASE OF INHALATION OF DECOMPOSITION
PRODUCTS IN A FIRE, SYMPTOMS MAY BE DELAYED. THE EXPOSED PERSON MAY NEED
TO BE KEPT UNDER MEDICAL SURVEILLANCE FOR 48 HOURS.
SKIN CONTACT:
WASH WITH PLENTY OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES.
WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING IT, OR
WEAR GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL
ATTENTION. IN THE EVENT OF ANY COMPLAINTS OR SYMPTOMS, AVOID FURTHER
EXPOSURE. WASH CLOTHING BEFORE REUSE. CLEAN SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. WASH
OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH AIR
AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL HAS
BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES
OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS VOMITING MAY
BE DANGEROUS. ASPIRATION HAZARD IF SWALLOWED. CAN ENTER LUNGS AND CAUSE
DAMAGE. DO NOT INDUCE VOMITING. IF VOMITING OCCURS, THE HEAD SHOULD BE
KEPT LOW SO THAT VOMIT DOES NOT ENTER THE LUNGS. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION
AND GET MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN
TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS
OR DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY BE FATAL IF
SWALLOWED AND ENTERS AIRWAYS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
NAUSEA OR VOMITING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
IN CASE OF INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY BE
DELAYED. THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL SURVEILLANCE
FOR 48 HOURS.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT
MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
EXTREMELY FLAMMABLE AEROSOL. IN A FIRE OR IF HEATED, A PRESSURE INCREASE
WILL OCCUR AND THE CONTAINER MAY BURST, WITH THE RISK OF A SUBSEQUENT
EXPLOSION. GAS MAY ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL A
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK, CAUSING FIRE
OR EXPLOSION. BURSTING AEROSOL CONTAINERS MAY BE PROPELLED FROM A FIRE AT
HIGH SPEED. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
NITROGEN OXIDES
SULFUR OXIDES
PHOSPHORUS OXIDES
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE AREA
IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. IN THE CASE OF AEROSOLS BEING RUPTURED, CARE
SHOULD BE TAKEN DUE TO THE RAPID ESCAPE OF THE PRESSURIZED CONTENTS AND
PROPELLANT. IF A LARGE NUMBER OF CONTAINERS ARE RUPTURED, TREAT AS A BULK
MATERIAL SPILLAGE ACCORDING TO THE INSTRUCTIONS IN THE CLEAN-UP SECTION.
DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. SHUT OFF ALL IGNITION
SOURCES. NO FLARES, SMOKING OR FLAMES IN HAZARD AREA. AVOID BREATHING
VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR
WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE
ALSO THE INFORMATION IN "FOR NONEMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. DILUTE WITH WATER AND MOP UP IF
WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE, ABSORB WITH AN INERT
DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER. DISPOSE
OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH
SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN
AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND,
EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR
DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF VIA A
LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY
POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). PERSONS
WITH A HISTORY OF SKIN SENSITIZATION PROBLEMS SHOULD NOT BE EMPLOYED IN ANY
PROCESS IN WHICH THIS PRODUCT IS USED.
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER USE. AVOID EXPOSURE - OBTAIN
SPECIAL INSTRUCTIONS BEFORE USE. AVOID EXPOSURE DURING PREGNANCY. DO NOT
HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT
GET IN EYES OR ON SKIN OR CLOTHING. DO NOT BREATHE VAPOR OR MIST. DO NOT
SWALLOW. AVOID BREATHING GAS. USE ONLY WITH ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. STORE AND USE AWAY
FROM HEAT, SPARKS, OPEN FLAME OR ANY OTHER IGNITION SOURCE. USE
EXPLOSION-PROOF ELECTRICAL (VENTILATING, LIGHTING AND MATERIAL HANDLING)
EQUIPMENT. USE ONLY NON-SPARKING TOOLS. EMPTY CONTAINERS RETAIN PRODUCT
RESIDUE AND CAN BE HAZARDOUS.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE AWAY FROM DIRECT SUNLIGHT
IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10) AND FOOD AND DRINK. PROTECT FROM SUNLIGHT. STORE LOCKED
UP. ELIMINATE ALL IGNITION SOURCES. USE APPROPRIATE CONTAINMENT TO AVOID
ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS (OSHA UNITED STATES):
INGREDIENT NAME EXPOSURE LIMITS
PROPANE NIOSH REL (UNITED STATES, 10/2013).
TWA: 1000 PPM 10 HOURS.
TWA: 1800 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 6/2016).
TWA: 1000 PPM 8 HOURS.
TWA: 1800 MG/M3 8 HOURS.
ACETONE ACGIH TLV (UNITED STATES, 3/2016).
TWA: 250 PPM 8 HOURS.
STEL: 500 PPM 15 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 250 PPM 10 HOURS.
TWA: 590 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 6/2016).
TWA: 1000 PPM 8 HOURS.
TWA: 2400 MG/M3 8 HOURS.
N-BUTYL ACETATE NIOSH REL (UNITED STATES, 10/2013).
TWA: 150 PPM 10 HOURS.
TWA: 710 MG/M3 10 HOURS.
STEL: 200 PPM 15 MINUTES.
STEL: 950 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 6/2016).
TWA: 150 PPM 8 HOURS.
TWA: 710 MG/M3 8 HOURS.
ACGIH TLV (UNITED STATES, 3/2016).
STEL: 150 PPM 15 MINUTES.
TWA: 50 PPM 8 HOURS.
LT. ALIPHATIC HYDROCARBON SOLVENT NONE.
BUTANE NIOSH REL (UNITED STATES, 10/2013).
TWA: 800 PPM 10 HOURS.
TWA: 1900 MG/M3 10 HOURS.
ACGIH TLV (UNITED STATES, 3/2016).
STEL: 1000 PPM 15 MINUTES.
ETHYL 3-ETHOXYPROPIONATE NONE.
XYLENE ACGIH TLV (UNITED STATES, 3/2016).
TWA: 100 PPM 8 HOURS.
TWA: 434 MG/M3 8 HOURS.
STEL: 150 PPM 15 MINUTES.
STEL: 651 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 6/2016).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
TITANIUM DIOXIDE ACGIH TLV (UNITED STATES, 3/2016).
TWA: 10 MG/M3 8 HOURS.
OSHA PEL (UNITED STATES, 6/2016).
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
ETHYLBENZENE ACGIH TLV (UNITED STATES, 3/2016).
TWA: 20 PPM 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 100 PPM 10 HOURS.
TWA: 435 MG/M3 10 HOURS.
STEL: 125 PPM 15 MINUTES.
STEL: 545 MG/M3 15 MINUTES.
OSHA PEL (UNITED STATES, 6/2016).
TWA: 100 PPM 8 HOURS.
TWA: 435 MG/M3 8 HOURS.
UNSATURATED FATTY ACIDS NONE.
ZIRCONIUM 2-ETHYLHEXANOATE ACGIH TLV (UNITED STATES, 3/2016).
TWA: 5 MG/M3, (AS Zr) 8 HOURS.
STEL: 10 MG/M3, (AS Zr) 15 MINUTES.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 5 MG/M3, (AS Zr) 10 HOURS.
STEL: 10 MG/M3, (AS Zr) 15 MINUTES.
OSHA PEL (UNITED STATES, 6/2016).
TWA: 5 MG/M3, (AS Zr) 8 HOURS.
OCCUPATIONAL EXPOSURE LIMITS (CANADA):
INGREDIENT NAME EXPOSURE LIMITS
PROPANE CA ALBERTA PROVINCIAL (CANADA, 4/2009).
8 HRS OEL: 1000 PPM 8 HOURS.
CA BRITISH COLUMBIA PROVINCIAL (CANADA, 5/2015).
TWA: 1000 PPM 8 HOURS.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 1000 PPM 8 HOURS.
TWAEV: 1800 MG/M3 8 HOURS.
CA ONTARIO PROVINCIAL (CANADA, 7/2015).
TWA: 1000 PPM 8 HOURS.
CA SASKATCHEWAN PROVINCIAL (CANADA, 7/2013).
STEL: 1250 PPM 15 MINUTES.
TWA: 1000 PPM 8 HOURS.
ACETONE CA ALBERTA PROVINCIAL (CANADA, 4/2009).
8 HRS OEL: 1200 MG/M3 8 HOURS.
15 MIN OEL: 1800 MG/M3 15 MINUTES.
8 HRS OEL: 500 PPM 8 HOURS.
15 MIN OEL: 750 PPM 15 MINUTES.
CA BRITISH COLUMBIA PROVINCIAL (CANADA, 5/2015).
TWA: 250 PPM 8 HOURS.
STEL: 500 PPM 15 MINUTES.
CA ONTARIO PROVINCIAL (CANADA, 7/2015).
TWA: 500 PPM 8 HOURS.
STEL: 750 PPM 15 MINUTES.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 500 PPM 8 HOURS.
TWAEV: 1190 MG/M3 8 HOURS.
STEV: 1000 PPM 15 MINUTES.
STEV: 2380 MG/M3 15 MINUTES.
CA SASKATCHEWAN PROVINCIAL (CANADA, 7/2013).
STEL: 750 PPM 15 MINUTES.
TWA: 500 PPM 8 HOURS.
N-BUTYL ACETATE CA ALBERTA PROVINCIAL (CANADA, 4/2009).
15 MIN OEL: 200 PPM 15 MINUTES.
15 MIN OEL: 950 MG/M3 15 MINUTES.
8 HRS OEL: 150 PPM 8 HOURS.
8 HRS OEL: 713 MG/M3 8 HOURS.
CA BRITISH COLUMBIA PROVINCIAL (CANADA, 5/2015).
TWA: 20 PPM 8 HOURS.
CA ONTARIO PROVINCIAL (CANADA, 7/2015).
TWA: 150 PPM 8 HOURS.
STEL: 200 PPM 15 MINUTES.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 150 PPM 8 HOURS.
TWAEV: 713 MG/M3 8 HOURS.
STEV: 200 PPM 15 MINUTES.
STEV: 950 MG/M3 15 MINUTES.
CA SASKATCHEWAN PROVINCIAL (CANADA, 7/2013).
STEL: 200 PPM 15 MINUTES.
TWA: 150 PPM 8 HOURS.
ZIRCONIUM CA ALBERTA PROVINCIAL (CANADA, 4/2009).
2-ETHYLHEXANOATE 8 HRS OEL: 5 MG/M3, (AS Zr) 8 HOURS.
15 MIN OEL: 10 MG/M3, (AS Zr) 15 MINUTES.
CA BRITISH COLUMBIA PROVINCIAL (CANADA, 5/2015).
TWA: 5 MG/M3, (AS Zr) 8 HOURS.
STEL: 10 MG/M3, (AS Zr) 15 MINUTES.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 5 MG/M3, (AS Zr) 8 HOURS.
STEV: 10 MG/M3, (AS Zr) 15 MINUTES.
CA ONTARIO PROVINCIAL (CANADA, 7/2015).
STEL: 10 MG/M3, (AS Zr) 15 MINUTES.
TWA: 5 MG/M3, (AS Zr) 8 HOURS.
OCCUPATIONAL EXPOSURE LIMITS (MEXICO):
INGREDIENT NAME EXPOSURE LIMITS
PROPANE NOM-010-STPS (MEXICO, 4/2016).
LMPE-PPT: 1000 PPM 8 HOURS.
ACETONE NOM-010-STPS (MEXICO, 4/2016).
LMPE-PPT: 500 PPM 8 HOURS.
LMPE-CT: 750 PPM 15 MINUTES.
N-BUTYL ACETATE NOM-010-STPS (MEXICO, 4/2016).
LMPE-PPT: 150 PPM 8 HOURS.
LMPE-CT: 200 PPM 15 MINUTES.
BUTANE NOM-010-STPS (MEXICO, 4/2016).
LMPE-PPT: 1000 PPM 8 HOURS.
XYLENE NOM-010-STPS (MEXICO, 4/2016).
LMPE-CT: 150 PPM 15 MINUTES.
LMPE-PPT: 100 PPM 8 HOURS.
ZIRCONIUM 2-ETHYLHEXANOATE NOM-010-STPS (MEXICO, 4/2016).
LMPE-PPT: 5 MG/M3, (AS Zr) 8 HOURS.
LMPE-CT: 10 MG/M3, (AS Zr) 15 MINUTES.
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS. THE
ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS
BELOW ANY LOWER EXPLOSIVE LIMITS. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE THAT
EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTISTATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
BASED ON THE HAZARD AND POTENTIAL FOR EXPOSURE, SELECT A RESPIRATOR THAT
MEETS THE APPROPRIATE STANDARD OR CERTIFICATION. RESPIRATORS MUST BE USED
ACCORDING TO A RESPIRATORY PROTECTION PROGRAM TO ENSURE PROPER FITTING,
TRAINING, AND OTHER IMPORTANT ASPECTS OF USE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: NOT AVAILABLE.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: 7
MELTING POINT: NOT AVAILABLE.
BOILING POINT: NOT AVAILABLE.
FLASH POINT:
CLOSED CUP: -29 DEG. C (-20.2 DEG. F) [PENSKY-MARTENS CLOSED CUP]
EVAPORATION RATE: 5.6 (BUTYL ACETATE = 1)
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 0.9%
UPPER: 12.8%
VAPOR PRESSURE: 101.3 KPA (760 MMHg) [AT 20 DEG. C]
VAPOR DENSITY: 1.55 [AIR = 1]
RELATIVE DENSITY: 0.75
SOLUBILITY: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (40 DEG. C (104 DEG. F)): <0.205 CM2/S (<20.5 CST)
MOLECULAR WEIGHT: NOT APPLICABLE.
AEROSOL PRODUCT:
TYPE OF AEROSOL: SPRAY
HEAT OF COMBUSTION: 28.68 KJ/G
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME).
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT NAME RESULT SPECIES DOSE EXPOSURE
ACETONE LD50 ORAL RAT 5800 MG/KG
N-BUTYL ACETATE LD50 DERMAL RABBIT >17600 MG/KG
LD50 ORAL RAT 10768 MG/KG
BUTANE LC50 INHALATION RAT 658000 MG/M3 4 HOURS
VAPOR
ETHYL 3-ETHOXYPROPIONATE LD50 ORAL RAT 3200 MG/KG
XYLENE LC50 INHALATION RAT 5000 PPM 4 HOURS
GAS.
LD50 ORAL RAT 4300 MG/KG
ETHYLBENZENE LD50 DERMAL RABBIT >5000 MG/KG
LD50 ORAL RAT 3500 MG/KG
ZIRCONIUM LD50 DERMAL RABBIT >5 G/KG
2-ETHYLHEXANOATE LD50 ORAL RAT >5 G/KG
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVATION
NAME
ACETONE EYES: HUMAN 186300 PARTS
MILD PER MILLION
IRRITANT
EYES: RABBIT 10 MICROLITERS
MILD
IRRITANT
EYES: RABBIT 24 HOURS
MODERATE 20 MILLIGRAMS
IRRITANT
EYES: RABBIT 20 MILLIGRAMS
SEVERE
IRRITANT
SKIN: RABBIT 24 HOURS
MILD 500 MILLIGRAMS
IRRITANT
SKIN: RABBIT 395 MILLIGRAMS
MILD
IRRITANT
N-BUTYL ACETATE EYES: RABBIT 100 MILLIGRAMS
MODERATE
IRRITANT
SKIN: RABBIT 24 HOURS
MODERATE 500 MILLIGRAMS
IRRITANT
ETHYL SKIN: RABBIT 24 HOURS
3-ETHOXYPROPIONATE MILD 500 MILLIGRAMS
IRRITANT
XYLENE EYES: RABBIT 87 MILLIGRAMS
MILD
IRRITANT
EYES: RABBIT 24 HOURS
SEVERE 5 MILLIGRAMS
IRRITANT
SKIN: RAT 8 HOURS
MILD 60 MICROLITERS
IRRITANT
SKIN: RABBIT 24 HOURS
MODERATE 500 MILLIGRAMS
IRRITANT
SKIN: RABBIT 100 PERCENT
MODERATE
IRRITANT
TITANIUM DIOXIDE SKIN: HUMAN 72 HOURS
MILD 300 MICROGRAMS
IRRITANT INTERMITTENT
ETHYLBENZENE EYES: RABBIT 500 MILLIGRAMS
SEVERE
IRRITANT
SKIN: RABBIT 24 HOURS
MILD 15 MILLIGRAMS
IRRITANT
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
XYLENE 3
TITANIUM DIOXIDE 2B
ETHYLBENZENE 2B
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
PROPANE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
ACETONE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
N-BUTYL ACETATE CATEGORY 3 NOT APPLICABLE. NARCOTIC EFFECTS
LT. ALIPHATIC CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
HYDROCARBON SOLVENT IRRITATION AND
NARCOTIC EFFECTS
BUTANE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
XYLENE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
ETHYLBENZENE CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION AND
NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
PROPANE CATEGORY 2 NOT DETERMINED NOT DETERMINED
ACETONE CATEGORY 2 NOT DETERMINED NOT DETERMINED
LT. ALIPHATIC CATEGORY 2 NOT DETERMINED NOT DETERMINED
HYDROCARBON SOLVENT
BUTANE CATEGORY 2 NOT DETERMINED NOT DETERMINED
XYLENE CATEGORY 2 NOT DETERMINED NOT DETERMINED
ETHYLBENZENE CATEGORY 2 NOT DETERMINED NOT DETERMINED
ASPIRATION HAZARD:
NAME RESULT
PROPANE ASPIRATION HAZARD - CATEGORY 1
LT. ALIPHATIC HYDROCARBON SOLVENT ASPIRATION HAZARD - CATEGORY 1
BUTANE ASPIRATION HAZARD - CATEGORY 1
XYLENE ASPIRATION HAZARD - CATEGORY 1
ETHYLBENZENE ASPIRATION HAZARD - CATEGORY 1
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS
OR DIZZINESS. MAY CAUSE RESPIRATORY IRRITATION.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY BE FATAL IF
SWALLOWED AND ENTERS AIRWAYS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
IRRITATION
REDNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
NAUSEA OR VOMITING
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. ONCE
SENSITIZED, A SEVERE ALLERGIC REACTION MAY OCCUR WHEN SUBSEQUENTLY EXPOSED
TO VERY LOW LEVELS.
CARCINOGENICITY:
SUSPECTED OF CAUSING CANCER. RISK OF CANCER DEPENDS ON DURATION AND LEVEL
OF EXPOSURE.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: SUSPECTED OF DAMAGING THE UNBORN CHILD.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 40996 MG/KG
INHALATION (GASES) 202064.4 PPM
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
ACETONE ACUTE EC50: ALGAE - SELENASTRUM SP. 96 HOURS
7200000 (MICRO)G/L
FRESH WATER
ACUTE LC50: CRUSTACEANS - GAMMARUS 48 HOURS
6000000 (MICRO)G/L PULEX
FRESH WATER
ACUTE LC50: DAPHNIA - DAPHNIA MAGNA 48 HOURS
6900 MG/L
FRESH WATER
ACUTE LC50: FISH - POECILIA 96 HOURS
5600 PPM RETICULATA
FRESH WATER
CHRONIC NOEC: ALGAE - ULVA PERTUSA 96 HOURS
4.95 MG/L
MARINE WATER
CHRONIC NOEC: CRUSTACEANS - DAPHNIIDAE 21 DAYS
0.016 ML/L
FRESH WATER
CHRONIC NOEC: DAPHNIA - DAPHNIA 21 DAYS
0.1 ML/L MAGNA - NEONATE
FRESH WATER
N-BUTYL ACETATE ACUTE LC50: CRUSTACEANS - ARTEMIA 48 HOURS
32 MG/L SALINA
MARINE WATER
ACUTE LC50: FISH - PIMEPHALES 96 HOURS
18000 (MICRO)G/L PROMELAS
FRESH WATER
LT. ALIPHATIC ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
HYDROCARBON >100000 PPM MYKISS
SOLVENT FRESH WATER
XYLENE ACUTE LC50: CRUSTACEANS - 48 HOURS
8500 (MICRO)G/L PALAEMONETES PUGIO
MARINE WATER
ACUTE LC50: FISH - PIMEPHALES 96 HOURS
13400 (MICRO)G/L PROMELAS
FRESH WATER
TITANIUM DIOXIDE ACUTE LC50: FISH - FUNDULUS 96 HOURS
>1000000 (MICRO)G/L HETEROCLITUS
MARINE WATER
ETHYLBENZENE ACUTE EC50: ALGAE - 72 HOURS
4600 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: ALGAE - 96 HOURS
3600 (MICRO)G/L PSEUDOKIRCHNERIELLA
FRESH WATER SUBCAPITATA
ACUTE EC50: CRUSTACEANS - ARTEMIA 48 HOURS
6530 (MICRO)G/L SP. - NAUPLII
FRESH WATER
ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
2930 (MICRO)G/L MAGNA - NEONATE
FRESH WATER
ACUTE LC50: FISH - ONCORHYNCHUS 96 HOURS
4200 (MICRO)G/L MYKISS
FRESH WATER
PERSISTENCE AND DEGRADABILITY:
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
ACETONE READILY
N-BUTYL ACETATE READILY
XYLENE READILY
ETHYLBENZENE READILY
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
LT. ALIPHATIC HYDROCARBON SOLVENT 10 TO 2500 HIGH
XYLENE 8.1 TO 25.9 LOW
ZIRCONIUM 2-ETHYLHEXANOATE 2.96 LOW
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. EMPTY CONTAINERS OR LINERS MAY RETAIN
SOME PRODUCT RESIDUES. DO NOT PUNCTURE OR INCINERATE CONTAINER.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
UN NUMBER UN1950 UN1950 UN1950
UN PROPER SHIPPING NAME AEROSOLS AEROSOLS AEROSOLS
TRANSPORT HAZARD 2.1 2.1 2.1
CLASS(ES)
FLAMMABLE GAS, CLASS 2.1, CLASS 2.1,
CLASS/DIVISION FLAMMABLE FLAMMABLE
2.1 GASES GASES
PACKING GROUP
ENVIRONMENTAL HAZARDS NO. NO. NO.
ADDITIONAL INFORMATION PRODUCT
CLASSIFIED
AS PER THE
FOLLOWING
SECTIONS
OF THE
TRANSPORTATION
OF DANGEROUS
GOODS
REGULATIONS:
2.13-2.17
(CLASS 2).
ERG NO.: 126 ERG NO.: 126 ERG NO.: 126
IATA IMDG
UN NUMBER UN1950 UN1950
UN PROPER SHIPPING NAME AEROSOLS, FLAMMABLE AEROSOLS
TRANSPORT HAZARD CLASS(ES) 2.1 2.1
CLASS 2.1, FLAMMABLE CLASS 2.1 - FLAMMABLE
GASES GASES
PACKING GROUP
ENVIRONMENTAL HAZARDS NO. NO.
ADDITIONAL INFORMATION EMERGENCY SCHEDULES
(EMS): F-D, S-U
SPECIAL PRECAUTIONS FOR USER:
MULTI-MODAL SHIPPING DESCRIPTIONS ARE PROVIDED FOR INFORMATIONAL PURPOSES
AND DO NOT CONSIDER CONTAINER SIZES. THE PRESENCE OF A SHIPPING DESCRIPTION
FOR A PARTICULAR MODE OF TRANSPORT (SEA, AIR, ETC.), DOES NOT INDICATE THAT
THE PRODUCT IS PACKAGED SUITABLY FOR THAT MODE OF TRANSPORT. ALL PACKAGING
MUST BE REVIEWED FOR SUITABILITY PRIOR TO SHIPMENT, AND COMPLIANCE WITH THE
APPLICABLE REGULATIONS IS THE SOLE RESPONSIBILITY OF THE PERSON OFFERING
THE PRODUCT FOR TRANSPORT. PEOPLE LOADING AND UNLOADING DANGEROUS GOODS
MUST BE TRAINED ON ALL OF THE RISKS DERIVING FROM THE SUBSTANCES AND ON ALL
ACTIONS IN CASE OF EMERGENCY SITUATIONS.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT AVAILABLE.
PROPER SHIPPING NAME: NOT AVAILABLE.
SHIP TYPE: NOT AVAILABLE.
POLLUTION CATEGORY: NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
SARA 313:
SARA 313 (40 CFR 372.45) SUPPLIER NOTIFICATION CAN BE FOUND ON THE
ENVIRONMENTAL DATA SHEET.
CALIFORNIA PROP. 65:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 2*
FLAMMABILITY 3
PHYSICAL HAZARDS 0
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON SDSS UNDER 29 CFR 1910.1200,
THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED MARK
OF THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA). HMIS(R*) MATERIALS
MAY BE PURCHASED EXCLUSIVELY FROM J. J. KELLER (800) 327-6868.
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
FLAMMABLE AEROSOLS - CATEGORY 1 ON BASIS OF TEST DATA
GASES UNDER PRESSURE - COMPRESSED GAS CALCULATION METHOD
SKIN CORROSION/IRRITATION - CATEGORY 2 CALCULATION METHOD
SERIOUS EYE DAMAGE / EYE IRRITATION - CATEGORY 2A CALCULATION METHOD
SKIN SENSITIZATION - CATEGORY 1 CALCULATION METHOD
CARCINOGENICITY - CATEGORY 2 CALCULATION METHOD
TOXIC TO REPRODUCTION (UNBORN CHILD) - CATEGORY 2 CALCULATION METHOD
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CALCULATION METHOD
(RESPIRATORY TRACT IRRITATION) - CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CALCULATION METHOD
(NARCOTIC EFFECTS) - CATEGORY 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED CALCULATION METHOD
EXPOSURE) - CATEGORY 2
ASPIRATION HAZARD - CATEGORY 1 CALCULATION METHOD
HISTORY:
DATE OF PRINTING: 5/22/2017
DATE OF ISSUE/DATE OF REVISION: 5/22/2017
DATE OF PREVIOUS ISSUE: 9/23/2016
VERSION: 4
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
NOTICE TO READER:
IT IS RECOMMENDED THAT EACH CUSTOMER OR RECIPIENT OF THIS SAFETY DATA
SHEET (SDS) STUDY IT CAREFULLY AND CONSULT RESOURCES, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THIS INFORMATION IS
PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE
DATE HEREIN. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. THE
INFORMATION PRESENTED HERE APPLIES ONLY TO THE PRODUCT AS SHIPPED. THE
ADDITION OF ANY MATERIAL CAN CHANGE THE COMPOSITION, HAZARDS AND RISKS OF
THE PRODUCT. PRODUCTS SHALL NOT BE REPACKAGED, MODIFIED, OR TINTED EXCEPT
AS SPECIFICALLY INSTRUCTED BY SHERWIN-WILLIAMS, INCLUDING BUT NOT LIMITED
TO THE INCORPORATION OF NON SHERWIN-WILLIAMS PRODUCTS OR THE USE OR
ADDITION OF PRODUCTS IN PROPORTIONS NOT SPECIFIED BY SHERWIN-WILLIAMS.
REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER BETWEEN
VARIOUS LOCATIONS AND JURISDICTIONS. THE CUSTOMER/BUYER/USER IS RESPONSIBLE
TO ENSURE THAT HIS ACTIVITIES COMPLY WITH ALL COUNTRY, FEDERAL, STATE,
PROVINCIAL OR LOCAL LAWS. THE CONDITIONS FOR USE OF THE PRODUCT ARE NOT
UNDER THE CONTROL OF THE MANUFACTURER; THE CUSTOMER/BUYER/USER IS
RESPONSIBLE TO DETERMINE THE CONDITIONS NECESSARY FOR THE SAFE USE OF THIS
PRODUCT. THE CUSTOMER/BUYER/USER SHOULD NOT USE THE PRODUCT FOR ANY PURPOSE
OTHER THAN THE PURPOSE SHOWN IN THE APPLICABLE SECTION OF THIS SDS WITHOUT
FIRST REFERRING TO THE SUPPLIER AND OBTAINING WRITTEN HANDLING
INSTRUCTIONS. DUE TO THE PROLIFERATION OF SOURCES FOR INFORMATION SUCH AS
MANUFACTURER-SPECIFIC SDS, THE MANUFACTURER CANNOT BE RESPONSIBLE FOR SDSS
OBTAINED FROM ANY OTHER SOURCE.