| Common Name: | GUNK ENGINE DEGREASER - HEAVY DUTY GEL |
| Manufacturer: | RSC CHEMICAL SOLUTIONS |
| SDS Revision Date: | 10/2/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 54XU69 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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GUNK(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: GUNK ENGINE DEGREASER - HEAVY DUTY GEL
OTHER MEANS OF IDENTIFICATION:
SDS NUMBER: EBGEL
PART NO.: EBGEL
TARIFF CODE: 3814.00.5090
RECOMMENDED USE: DEGREASER
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURER:
COMPANY NAME: RSC CHEMICAL SOLUTIONS
ADDRESS:
600 RADIATOR ROAD
INDIAN TRAIL, NC 28079
UNITED STATES
TELEPHONE:
CUSTOMER SERVICE: (704) 821-7643
TECHNICAL: (704) 821-7643
WEBSITE: WWW.RSCBRANDS.COM
E-MAIL: SDS@RSCBRANDS.COM
EMERGENCY PHONE NUMBER:
EMERGENCY TELEPHONE: (303) 623-5716
EMERGENCY CONTACT:
RMPDC: (877) 740-5015
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE AEROSOLS: CATEGORY 2
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
SENSITIZATION, SKIN: CATEGORY 1
CARCINOGENICITY: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE: CATEGORY 1
ASPIRATION HAZARD: CATEGORY 1
ENVIRONMENTAL HAZARDS:
HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD: CATEGORY 2
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
ENVIRONMENT
SIGNAL WORD: DANGER
HAZARD STATEMENT:
FLAMMABLE AEROSOL. MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. CAUSES
SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE
IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. SUSPECTED OF CAUSING CANCER.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. TOXIC TO
AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENT:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN
FLAMES/HOT SURFACES. - NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR OTHER
IGNITION SOURCE.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT BREATHE MIST OR VAPOR. WASH
THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. CONTAMINATED WORK
CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE. AVOID RELEASE TO THE
ENVIRONMENT. WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE
PROTECTION.
RESPONSE:
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER/DOCTOR. DO NOT INDUCE VOMITING.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. CALL A POISON CENTER/DOCTOR IF YOU FEEL
UNWELL. IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. COLLECT SPILLAGE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): COMBUSTIBLE.
SUPPLEMENTAL INFORMATION:
90.53, 162.9% OF THE MIXTURE CONSISTS OF COMPONENT(S) OF UNKNOWN ACUTE ORAL
TOXICITY.
92.18, 164.28% OF THE MIXTURE CONSISTS OF COMPONENT(S) OF UNKNOWN ACUTE
DERMAL TOXICITY.
84.39% OF THE MIXTURE CONSISTS OF COMPONENT(S) OF UNKNOWN ACUTE INHALATION
TOXICITY.
85.22% OF THE MIXTURE CONSISTS OF COMPONENT(S) OF UNKNOWN ACUTE HAZARDS TO
THE AQUATIC ENVIRONMENT.
NOTE:
THIS PRODUCT IS A CONSUMER PRODUCT AND IS LABELED IN ACCORDANCE WITH THE US
CONSUMER PRODUCT SAFETY COMMISSION REGULATIONS WHICH TAKE PRECEDENCE OVER
OSHA HAZARD COMMUNICATION LABELING. THE CONTAINER LABEL MAY NOT INCLUDE THE
OSHA LABEL ELEMENTS LISTED IN THIS DOCUMENT. ALWAYS CAREFULLY REVIEW THE
ENTIRE SDS AND THE PRODUCT LABEL PRIOR TO USE IN THE WORKPLACE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
DISTILLATES (PETROLEUM), 64742-47-8 70 - <80
HYDROTREATED LIGHT
PETROLEUM NAPHTHA 64742-94-5 5 - <10
POLY(OXYETHYLENE) SORBITOL 57171-56-9 3 - <5
HEXAOLEATE
CARBON DIOXIDE 124-38-9 1 - <3
D-(+)-LIMONENE 5989-27-5 1 - <3
TERT-BUTYLBENZENE 98-06-6 1 - <3
NAPHTHALENE 91-20-3 <1
BENZENE, 1,3-DIETHYL- 141-93-5 <0.2
DIETHYLBENZENE 25340-17-4 <0.2
QUARTZ [SILICA 14808-60-7 <0.2
CRYSTALLINE]
OTHER COMPONENTS BELOW 5 - <10
REPORTABLE LEVELS
*DESIGNATES THAT A SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF
COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH SKIN WITH SOAP AND WATER.
IN CASE OF ECZEMA OR OTHER SKIN DISORDERS:
SEEK MEDICAL ATTENTION AND TAKE ALONG THESE INSTRUCTIONS. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION:
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. RINSE MOUTH. DO NOT
INDUCE VOMITING. IF VOMITING OCCURS, KEEP HEAD LOW SO THAT STOMACH CONTENT
DOESN'T GET INTO THE LUNGS.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
ASPIRATION MAY CAUSE PULMONARY EDEMA AND PNEUMONITIS. MAY CAUSE DROWSINESS
AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. SEVERE EYE IRRITATION. SYMPTOMS
MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED VISION. SKIN
IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN ALLERGIC SKIN
REACTION. DERMATITIS. RASH. PROLONGED EXPOSURE MAY CAUSE CHRONIC EFFECTS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
(SHOW THE LABEL WHERE POSSIBLE). ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF
THE MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
ALCOHOL RESISTANT FOAM. POWDER. DRY CHEMICALS. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY EXPLODE WHEN EXPOSED
TO HEAT OR FLAME. DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
FIREFIGHTERS MUST USE STANDARD PROTECTIVE EQUIPMENT INCLUDING FLAME
RETARDANT COAT, HELMET WITH FACE SHIELD, GLOVES, RUBBER BOOTS, AND IN
ENCLOSED SPACES, SCBA.
FIRE FIGHTING EQUIPMENT/INSTRUCTIONS:
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT RISK. COOL
CONTAINERS EXPOSED TO HEAT WITH WATER SPRAY AND REMOVE CONTAINER, IF NO
RISK IS INVOLVED. CONTAINERS SHOULD BE COOLED WITH WATER TO PREVENT VAPOR
PRESSURE BUILD UP. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER
OR MONITOR NOZZLES, IF POSSIBLE. IF NOT, WITHDRAW AND LET FIRE BURN OUT.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO
WITHOUT RISK. IN THE EVENT OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
GENERAL FIRE HAZARDS: FLAMMABLE AEROSOL. COMBUSTIBLE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING DURING
CLEAN-UP. DO NOT BREATHE MIST OR VAPOR. DO NOT TOUCH DAMAGED CONTAINERS OR
SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. VENTILATE
CLOSED SPACES BEFORE ENTERING THEM. LOCAL AUTHORITIES SHOULD BE ADVISED IF
SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE
SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
REFER TO ATTACHED SAFETY DATA SHEETS AND/OR INSTRUCTIONS FOR USE. STOP LEAK
IF YOU CAN DO SO WITHOUT RISK. MOVE THE CYLINDER TO A SAFE AND OPEN AREA IF
THE LEAK IS IRREPARABLE. USE WATER SPRAY TO REDUCE VAPORS OR DIVERT VAPOR
CLOUD DRIFT. KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED
MATERIAL. THIS PRODUCT IS MISCIBLE IN WATER. PREVENT PRODUCT FROM ENTERING
DRAINS. ABSORB IN VERMICULITE, DRY SAND OR EARTH AND PLACE INTO CONTAINERS.
FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH WATER.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. PUT MATERIAL IN SUITABLE,
COVERED, LABELED CONTAINERS. FOR WASTE DISPOSAL, SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. INFORM APPROPRIATE MANAGERIAL OR
SUPERVISORY PERSONNEL OF ALL ENVIRONMENTAL RELEASES. PREVENT FURTHER
LEAKAGE OR SPILLAGE IF SAFE TO DO SO. AVOID DISCHARGE INTO DRAINS, WATER
COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT USE IF SPRAY BUTTON IS
MISSING OR DEFECTIVE. DO NOT SPRAY ON A NAKED FLAME OR ANY OTHER
INCANDESCENT MATERIAL. DO NOT SMOKE WHILE USING OR UNTIL SPRAYED SURFACE IS
THOROUGHLY DRY. DO NOT CUT, WELD, SOLDER, DRILL, GRIND, OR EXPOSE
CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. ALL
EQUIPMENT USED WHEN HANDLING THE PRODUCT MUST BE GROUNDED. DO NOT RE-USE
EMPTY CONTAINERS. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID
PROLONGED OR REPEATED CONTACT WITH SKIN. AVOID PROLONGED EXPOSURE. WHEN
USING, DO NOT EAT, DRINK OR SMOKE. SHOULD BE HANDLED IN CLOSED SYSTEMS, IF
POSSIBLE. USE ONLY IN WELL-VENTILATED AREAS. WEAR APPROPRIATE PERSONAL
PROTECTIVE EQUIPMENT. WASH HANDS THOROUGHLY AFTER HANDLING. AVOID RELEASE
TO THE ENVIRONMENT. OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
LEVEL 3 AEROSOL.
STORE LOCKED UP. PRESSURIZED CONTAINER. PROTECT FROM SUNLIGHT AND DO NOT
EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. DO NOT PUNCTURE,
INCINERATE OR CRUSH. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR
OTHER SOURCES OF IGNITION. THIS MATERIAL CAN ACCUMULATE STATIC CHARGE WHICH
MAY CAUSE SPARK AND BECOME AN IGNITION SOURCE. STORE IN TIGHTLY CLOSED
CONTAINER. KEEP OUT OF THE REACH OF CHILDREN. STORE AWAY FROM INCOMPATIBLE
MATERIALS (SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
THE FOLLOWING CONSTITUENTS ARE THE ONLY CONSTITUENTS OF THE PRODUCT WHICH
HAVE A PEL, TLV OR OTHER RECOMMENDED EXPOSURE LIMIT. AT THIS TIME, THE
OTHER CONSTITUENTS HAVE NO KNOWN EXPOSURE LIMITS.
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE FORM
CARBON DIOXIDE PEL 9000 MG/M3
(CAS 124-38-9) 5000 PPM
DISTILLATES (PETROLEUM), PEL 400 MG/M3
HYDROTREATED LIGHT 100 PPM
(CAS 64742-47-8)
NAPHTHALENE PEL 50 MG/M3
(CAS 91-20-3) 10 PPM
PETROLEUM NAPHTHA PEL 400 MG/M3
(CAS 64742-94-5) 100 PPM
QUARTZ [SILICA PEL 0.05 MG/M3 RESPIRABLE DUST.
CRYSTALLINE]
(CAS 14808-60-7)
US. OSHA TABLE Z-3 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE FORM
QUARTZ [SILICA TWA 0.1 MG/M3 RESPIRABLE.
CRYSTALLINE]
(CAS 14808-60-7) 2.4 MPPCF RESPIRABLE.
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE FORM
CARBON DIOXIDE STEL 30000 PPM
(CAS 124-38-9)
TWA 5000 PPM
NAPHTHALENE TWA 10 PPM
(CAS 91-20-3)
PETROLEUM NAPHTHA TWA 200 MG/M3 NON-AEROSOL.
(CAS 64742-94-5)
QUARTZ [SILICA TWA 0.025 MG/M3 RESPIRABLE
CRYSTALLINE] FRACTION.
(CAS 14808-60-7)
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE FORM
CARBON DIOXIDE STEL 54000 MG/M3
(CAS 124-38-9) 30000 PPM
TWA 9000 MG/M3
5000 PPM
NAPHTHALENE STEL 75 MG/M3
(CAS 91-20-3) 15 PPM
TWA 50 MG/M3
10 PPM
QUARTZ [SILICA TWA 0.05 MG/M3 RESPIRABLE DUST.
CRYSTALLINE]
(CAS 14808-60-7)
US. WORKPLACE ENVIRONMENTAL EXPOSURE LEVEL (WEEL) GUIDES:
COMPONENTS TYPE VALUE
BENZENE, 1,3-DIETHYL- TWA 5 PPM
(CAS 141-93-5)
D-(+)-LIMONENE TWA 165.5 MG/M3
(CAS 5989-27-5) 30 PPM
DIETHYLBENZENE TWA 5 PPM
(CAS 25340-17-4)
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENT(S).
EXPOSURE GUIDELINES:
US - CALIFORNIA OELS SKIN DESIGNATION
NAPHTHALENE (CAS 91-20-3) CAN BE ABSORBED THROUGH THE SKIN.
US ACGIH THRESHOLD LIMIT VALUES SKIN DESIGNATION
NAPHTHALENE (CAS 91-20-3) CAN BE ABSORBED THROUGH THE SKIN.
PETROLEUM NAPHTHA (CAS 64742-94-5) CAN BE ABSORBED THROUGH THE SKIN.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE
PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL. PROVIDE EYEWASH STATION AND SAFETY SHOWER.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
CHEMICAL RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE AND FULL FACEPIECE.
APPLICABLE FOR INDUSTRIAL SETTINGS ONLY.
SKIN PROTECTION:
HAND PROTECTION:
WEAR APPROPRIATE CHEMICAL RESISTANT GLOVES. APPLICABLE FOR INDUSTRIAL
SETTINGS ONLY.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON IS
RECOMMENDED. APPLICABLE FOR INDUSTRIAL SETTINGS ONLY.
RESPIRATORY PROTECTION:
CHEMICAL RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE AND FULL FACEPIECE.
CHEMICAL RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE AND FULL FACEPIECE IF
THRESHOLD LIMITS ARE EXCEEDED. APPLICABLE FOR INDUSTRIAL SETTINGS ONLY.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
OBSERVE ANY MEDICAL SURVEILLANCE REQUIREMENTS. WHEN USING DO NOT SMOKE.
ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER
HANDLING THE MATERIAL AND BEFORE EATING, DRINKING, AND/OR SMOKING.
ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO REMOVE
CONTAMINANTS. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: DARK GREY LIQUID SLURRY
PHYSICAL STATE: LIQUID.
FORM: AEROSOL.
COLOR: DARK GREY
ODOR: PETROLEUM
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE:
440.6 DEG. F (227 DEG. C) ESTIMATED
FLASH POINT: 190.0 DEG. F (87.8 DEG. C) TAG CLOSED CUP
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 0.7% ESTIMATED
FLAMMABILITY LIMIT - UPPER (%): 5% ESTIMATED
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: 0.59 HPA ESTIMATED
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES):
SOLUBILITY (WATER): EMULSIFIES
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: 40 CP
VISCOSITY TEMPERATURE: 77 DEG. F (25 DEG. C)
OTHER INFORMATION:
DENSITY: 7.68 LBS/GAL
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
FLAME EXTENSION: NONE
FLAMMABILITY (FLASH BACK): NO
FLAMMABILITY CLASS: COMBUSTIBLE IIIA ESTIMATED
HEAT OF COMBUSTION (NFPA 30B): 35.4 KJ/G
OXIDIZING PROPERTIES: NOT OXIDIZING.
PERCENT VOLATILE: 2.09% ESTIMATED
SPECIFIC GRAVITY: 0.91
VOC: <10% W/W
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. AVOID TEMPERATURES EXCEEDING THE FLASH POINT. CONTACT WITH
INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
NO HAZARDOUS DECOMPOSITION PRODUCTS ARE KNOWN.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. PROLONGED
INHALATION MAY BE HARMFUL.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
DROPLETS OF THE PRODUCT ASPIRATED INTO THE LUNGS THROUGH INGESTION OR
VOMITING MAY CAUSE A SERIOUS CHEMICAL PNEUMONIA.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
ASPIRATION MAY CAUSE PULMONARY EDEMA AND PNEUMONITIS. MAY CAUSE DROWSINESS
AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. SEVERE EYE IRRITATION. SYMPTOMS
MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED VISION. SKIN
IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN ALLERGIC SKIN
REACTION. DERMATITIS. RASH.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
COMPONENTS SPECIES TEST RESULTS
D-(+)-LIMONENE (CAS 5989-27-5):
ACUTE:
DERMAL:
LD50 RABBIT 5 G/KG
ORAL:
LD50 MOUSE 5600 - 6600 MG/KG
NAPHTHALENE (CAS 91-20-3):
ACUTE:
DERMAL:
LD50 RABBIT >2 G/KG
ORAL:
LD50 RAT 490 MG/KG
PETROLEUM NAPHTHA (CAS 64742-94-5):
ACUTE:
INHALATION:
LC50 RAT 61 MG/L, 4 HOURS
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY: SUSPECTED OF CAUSING CANCER.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
D-(+)-LIMONENE (CAS 5989-27-5):
3: NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
NAPHTHALENE (CAS 91-20-3):
2B: POSSIBLY CARCINOGENIC TO HUMANS.
QUARTZ [SILICA CRYSTALLINE] (CAS 14808-60-7):
1: CARCINOGENIC TO HUMANS.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
QUARTZ [SILICA CRYSTALLINE] (CAS 14808-60-7): CANCER
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS:
NAPHTHALENE (CAS 91-20-3): REASONABLY ANTICIPATED TO BE A HUMAN CARCINOGEN.
QUARTZ [SILICA CRYSTALLINE] (CAS 14808-60-7): KNOWN TO BE HUMAN CARCINOGEN.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS AND DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CHRONIC EFFECTS:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. PROLONGED
INHALATION MAY BE HARMFUL. PROLONGED EXPOSURE MAY CAUSE CHRONIC EFFECTS.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
COMPONENTS SPECIES TEST RESULTS
BENZENE, 1,3-DIETHYL- (CAS 141-93-5):
AQUATIC:
FISH LC50 FATHEAD MINNOW 4.05 - 4.25 MG/L,
(PIMEPHALES PROMELAS) 96 HOURS
D-(+)-LIMONENE (CAS 5989-27-5):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA 69.6 MG/L, 48 HOURS
PULEX)
FISH LC50 FATHEAD MINNOW 0.619 - 0.796 MG/L,
(PIMEPHALES PROMELAS) 96 HOURS
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-47-8):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA 2.7 - 5.1 MG/L, 48 HOURS
PULEX)
FISH LC50 RAINBOW TROUT, 2.9 MG/L, 96 HOURS
DONALDSON TROUT
(ONCORHYNCHUS MYKISS)
NAPHTHALENE (CAS 91-20-3):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA 1.09 - 3.4 MG/L, 48 HOURS
MAGNA)
FISH LC50 PINK SALMON 1.11 - 1.68 MG/L,
(ONCORHYNCHUS 96 HOURS
GORBUSCHA)
PETROLEUM NAPHTHA (CAS 64742-94-5):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA 2.7 - 5.1 MG/L, 48 HOURS
PULEX)
FISH LC50 RAINBOW TROUT, 8.8 MG/L, 96 HOURS
DONALDSON TROUT 8.8 MG/L, 96 HOURS
(ONCORHYNCHUS MYKISS)
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF ANY INGREDIENTS IN THE
MIXTURE.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
BENZENE, 1,3-DIETHYL-: 4.44
D-(+)-LIMONENE: 4.232
NAPHTHALENE: 3.3
TERT-BUTYLBENZENE: 4.11
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
THE PRODUCT CONTAINS VOLATILE ORGANIC COMPOUNDS WHICH HAVE A PHOTOCHEMICAL
OZONE CREATION POTENTIAL.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE OR
CRUSH. DO NOT ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES. DO
NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED
CONTAINER. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL. DO NOT RE-USE EMPTY
CONTAINERS.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: NOT AVAILABLE.
UN PROPER SHIPPING NAME: CONSUMER COMMODITY
TRANSPORT HAZARD CLASS(ES):
CLASS: ORM-D
SUBSIDIARY RISK:
PACKING GROUP: NOT AVAILABLE.
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: T75, TP5
PACKAGING EXCEPTIONS: 306
PACKAGING NON BULK: 304
PACKAGING BULK: 314, 315
IATA:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOL, FLAMMABLE
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
PACKING GROUP: NOT AVAILABLE.
ENVIRONMENTAL HAZARDS: YES
ERG CODE: 9L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED WITH RESTRICTIONS.
CARGO AIRCRAFT ONLY: ALLOWED WITH RESTRICTIONS.
IMDG:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, MARINE POLLUTANT
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
PACKING GROUP: NOT AVAILABLE.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: YES
EMS: F-D, S-U
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT ESTABLISHED.
IATA; IMDG: CLASS 2.1, FLAMMABLE GASES
MARINE POLLUTANT: ENVIRONMENT
GENERAL INFORMATION: IMDG REGULATED MARINE POLLUTANT.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
NAPHTHALENE (CAS 91-20-3): LISTED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
QUARTZ [SILICA CRYSTALLINE] (CAS 14808-60-7):
CANCER
LUNG EFFECTS
IMMUNE SYSTEM EFFECTS
KIDNEY EFFECTS
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 311/312 HAZARDOUS CHEMICAL: NO (EXEMPT)
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
NAPHTHALENE 91-20-3 <1
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
NAPHTHALENE (CAS 91-20-3)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION (40 CFR
68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO CHEMICALS INCLUDING NAPHTHALENE, WHICH IS
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. FOR MORE INFORMATION GO
TO WWW.P65WARNINGS.CA.GOV.
CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/CARCINOGENIC SUBSTANCE
BENZENE,1-METHYLETHYL- (CAS 98-82-8) LISTED: APRIL 6, 2010
CRYSTALLINE SILICA (CAS 15468-32-3) LISTED: OCTOBER 1, 1988
NAPHTHALENE (CAS 91-20-3) LISTED: APRIL 19, 2002
QUARTZ [SILICA CRYSTALLINE] LISTED: OCTOBER 1, 1988
(CAS 14808-60-7)
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
NAPHTHALENE (CAS 91-20-3)
QUARTZ [SILICA CRYSTALLINE] (CAS 14808-60-7)
TERT-BUTYLBENZENE (CAS 98-06-6)
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL NO
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) NO
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL NO
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING NO
COMMERCIAL CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW NO
CHEMICAL SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) NO
NEW ZEALAND NEW ZEALAND INVENTORY NO
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS NO
AND CHEMICAL SUBSTANCES (PICCS)
TAIWAN TAIWAN CHEMICAL SUBSTANCE INVENTORY NO
(TCSI)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH
THE INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 05-28-2015
REVISION DATE: 10-02-2018
VERSION #: 08
HMIS(R*) RATINGS:
HEALTH 3*
FLAMMABILITY 2
PHYSICAL HAZARD 0
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 2
INSTABILITY 0
NFPA RATINGS:
2
2
0
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.
REVISION INFORMATION:
THIS DOCUMENT HAS UNDERGONE SIGNIFICANT CHANGES AND SHOULD BE REVIEWED IN
ITS ENTIRETY.
MATERIAL NAME: GUNK ENGINE DEGREASER - HEAVY DUTY GEL
SDS US