| Common Name: | LITHIUM-ION RECHARGEABLE BATTERY PACK BL1021B, LITHIUM-ION RECHARGEABLE BATTERY |
| Manufacturer: | MAKITA |
| SDS Revision Date: | 3/12/2019 |
| SDS Format: | ANSI-OSHA |
| Item Number(s): | 55FD32, 55FD35, 55FD36, 55FD38, 55FD40 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD: 29 CFR 1910 1200
| SECTION 1. CHEMICAL PRODUCT AND COMPANY NAME |  |
LITHIUM-ION RECHARGEABLE BATTERY PACK BL1021B
MAKITA U.S.A., INC.
14930-C NORTHAM STREET
LA MIRADA, CA 90638
PREPARED BY: STAN RODRIGUES
DATE REVISED: 03/12/2019
EMERGENCY CONTACT INFORMATION:
TELEPHONE NUMBER FOR INFORMATION:
MAKITA: 1-510-657-9881
EMERGENCY RESPONSE:
FOR CHEMICAL EMERGENCY SPILLS, LEAK, FIRE, EXPOSURE, OR ACCIDENT CALL
CHEMTREC DAY OR NIGHT WITHIN USA AND CANADA: 1-800-424-9300
| SECTION 2. HAZARD IDENTIFICATION | |
THE PRODUCT IS A LITHIUM ION BATTERY AND IS THEREFORE CLASSIFIED AS AN
ARTICLE AND IS NOT HAZARDOUS WHEN USED ACCORDING TO THE RECOMMENDATIONS OF
THE MANUFACTURER. THE HAZARD IS ASSOCIATED WITH THE CONTENTS OF THE CELL OR
BATTERY. UNDER RECOMMENDED USE CONDITIONS, THE ELECTRODE MATERIALS AND
LIQUID ELECTROLYTE ARE NON-REACTIVE.
| SECTION 3. COMPOSITION, INFORMATION OR INGREDIENTS | |
* SUBSTANCE OR PREPARATION: PREPARATION
* INFORMATION ABOUT THE CHEMICAL NATURE OF PRODUCT: *1
PORTION MATERIAL NAME CAS NO. CONCENTRATION
RANGE (WT %)
POSITIVE ELECTRODE LITHIUM TRANSITION METAL 12190-79-3 20-60
OXIDATE (Li[M]m[O]n *2) 12031-65-1
12057-17-9
182442-95-1
207803-51-8
POSITIVE ALUMINUM 7429-90-5 1-10
ELECTRODE'S BASE
NEGATIVE ELECTRODE CARBON 7782-42-5 10-30
7440-44-0
NEGATIVE COPPER 7440-50-8 1-15
ELECTRODE'S BASE
ELECTROLYTE ETHYL METHYL CARBONATE 623-53-0
DIETHYL CARBONATE 105-58-8 5-25
ETHYLENE CARBONATE 96-49-1
LITHIUM 21324-40-3
HEXAFLUOROPHOSHATE
OUTER CASE ALUMINUM, IRON, 7429-90-5 1-30
ALUMINUM LAMINATED 7439-89-6
PLASTIC
*1 NOT EVERY PRODUCT INCLUDES ALL OF THESE MATERIALS
*2 THE LETTER M MEANS TRANSITION METAL AND CANDIDATES OF M ARE Co, MN, Ni
AND Al. ONE COMPOUND INCLUDES ONE OR MORE OF THESE METALS AND ONE PRODUCT
INCLUDE ONE OR MORE OF THE COMPOUNDS. THE LETTER M AND N MEANS THE NUMBER
OF ATOMS.
| SECTION 4. FIRST AID MEASURE | |
SPILLED INTERNAL CELL MATERIALS:
INHALATION:
MAKE THE VICTIM BLOW HIS/HER NOSE, GARGLE. SEEK MEDICAL ATTENTION IF
NECESSARY.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHES AND SHOES IMMEDIATELY. WASH EXTRANEOUS MATTER
OR CONTACT REGION WITH SOAP AND PLENTY OF WATER IMMEDIATELY.
EYE CONTACT:
DO NOT RUB ONE'S EYE. IMMEDIATELY FLUSH EYES WITH WATER CONTINUOUSLY FOR AT
LEAST 15 MINUTES. SEEK MEDICAL ATTENTION IMMEDIATELY.
A BATTERY CELL AND SPILLED INTERNAL CELL MATERIALS:
INGESTION:
WASH OUT MOUTH THOROUGHLY. DO NOT MAKE THE VICTIM VOMIT, UNLESS INSTRUCTED
BY MEDICAL PERSONNEL. SEEK MEDICAL ATTENTION IMMEDIATELY.
| SECTION 5. FIRE FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
PLENTY OF WATER, CARBON DIOXIDE GAS, NITROGEN GAS, CHEMICAL POWDER FIRE
EXTINGUISHING MEDIUM AND FIRE FOAM.
SPECIFIC HAZARDS: CORROSIVE GAS MAY BE EMITTED DURING FIRE.
SPECIFIC METHODS OF FIRE-FIGHTING:
WHEN THE BATTERY BURNS WITH OTHER COMBUSTIBLES SIMULTANEOUSLY, TAKE
FIRE-EXTINGUISHING METHOD WHICH CORRESPOND TO THE COMBUSTIBLES. EXTINGUISH
A FIRE FROM THE WINDWARD AS MUCH AS POSSIBLE.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
REFER TO SECTION 8-EXPOSURE CONTROLS I PERSONAL PROTECTION
(WHEN THE ELECTROLYTE LEAKS)
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
SPILLED INTERNAL CELL MATERIALS, SUCH AS ELECTROLYTE LEAKED FROM A BATTERY
CELL, ARE CAREFULLY DEALT WITH ACCORDING TO THE FOLLOWINGS.
PRECAUTIONS FOR HUMAN BODY:
REMOVE SPILLED MATERIALS WITH PROTECTIVE EQUIPMENT (REFER TO SECTION
8-EXPOSURE CONTROLS I PERSONAL PROTECTION (WHEN THE ELECTROLYTE LEAKS)).
DO NOT INHALE THE GAS AS MUCH AS POSSIBLE. MOREOVER, AVOID TOUCHING WITH
AS MUCH AS POSSIBLE.
ENVIRONMENTAL PRECAUTIONS: DO NOT THROW OUT INTO THE ENVIRONMENT.
METHOD OF CLEANING UP:
THE SPILLED SOLIDS ARE PUT INTO A CONTAINER. THE LEAKED PLACE IS WIPED OFF
WITH DRY CLOTH.
PREVENTION OF SECONDARY HAZARDS:
AVOID RE-SCATTERING. DO NOT BRING THE COLLECTED MATERIALS CLOSE TO FIRE.
| SECTION 7. HANDLING AND STORAGE | |
HANDLING SUGGESTIONS:
DO NOT CONNECT THE POSITIVE TERMINAL TO THE NEGATIVE TERMINAL WITH
ELECTRICAL WIRE OR CHAIN.
AVOID POLARITY REVERSE CONNECTION WHEN INSTALLING THE BATTERY TO AN
INSTRUMENT.
DO NOT WET THE BATTERY WITH WATER, SEAWATER, DRINK OR ACID; OR EXPOSE TO
STRONG OXIDIZER.
DO NOT DAMAGE OR REMOVE THE EXTERNAL TUBE.
KEEP THE BATTERY AWAY FROM HEAT AND FIRE.
DO NOT DISASSEMBLE OR RECONSTRUCT THE BATTERY; OR SOLDER THE BATTERY
DIRECTLY.
DO NOT GIVE A MECHANICAL SHOCK OR DEFORM.
DO NOT USE UNAUTHORIZED CHARGER OR OTHER CHARGING METHOD. TERMINATE
CHARGING WHEN THE CHARGING PROCESS DOESN'T END WITHIN SPECIFIED TIME.
STORAGE:
DO NOT STORE THE BATTERY WITH METALWARE, WATER, SEAWATER, STRONG ACID OR
STRONG OXIDIZER.
MAKE THE CHARGE AMOUNT LESS THAN OR EQUAL TO 50% THEN STORE AT -20-40
DEGREE C IN A DRY (HUMIDITY: 45-85%) PLACE.
SINCE DETERIORATION WILL BE FASTER IN THE HIGH TEMPERATURE RANGE THAN IN
THE LOW TEMPERATURE RANGE, SO DO NOT KEEP IT IN THE HIGH TEMPERATURE RANGE
BEYOND THE PERIOD THAT IS SPECIFIED BY THE SELLER OR OWNER.
USE ISOLATIVE AND ADEQUATELY STRONG PACKAGING MATERIAL TO PREVENT SHORT
CIRCUIT BETWEEN POSITIVE AND NEGATIVE TERMINAL WHEN THE PACKAGING BREAKS
DURING NORMAL HANDLING. DO NOT USE CONDUCTIVE OR EASY TO BREAK PACKAGING
MATERIAL.
| SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
CONTROL PARAMETERS:
ACGIH HAS NOT BEEN MENTIONED CONTROL PARAMETER OF ELECTROLYTE.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION: RESPIRATOR WITH AIR CYLINDER, DUST MASK
HAND PROTECTION: RESPIRATOR WITH AIR CYLINDER, DUST MASK
EYE PROTECTION:
GOGGLES OR PROTECTIVE GLASSES DESIGNED TO PROTECT AGAINST LIQUID SPLASHES
SKIN AND BODY PROTECTION:
WORKING CLOTHES WITH LONG SLEEVE AND LONG TROUSERS
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: SOLID
FORM: CYLINDRICAL OR PRISMATIC OR POUCH (LAMINATED)
COLOR: METALLIC COLOR OR BLACK (WITHOUT TUBE IF IT HAS TUBE)
ODOR: NO ODOR
| SECTION 10. STABILITY AND REACTIVITY | |
STABILITY:
NORMALLY STABLE UNLESS A STRONG SHOCK IS APPLIED OR HEATED STRONGLY
POSSIBILITY OF HAZARDOUS REACTIONS:
DAMAGE TO THE CONTAINER MAY CAUSE LEAKAGE OF CONTENTS. CONTENTS MAY LEAK
OR IGNITE DUE TO TEMPERATURE RISE.
CONDITIONS TO AVOID:
CRUSHING OR DEFORMATION, USE AND STORAGE AT 80 DEGREE C OR HIGHER OR AT
HIGH HUMIDITY. USAGE AT A VOLTAGE OR A CURRENT OUTSIDE THE RATING AND
EXTERNAL SHORT CIRCUIT.
INCOMPATIBLE MATERIALS:
CONDUCTIVE MATERIAL SUCH AS WATER OR METAL PIECES. OXIDIZING AGENT SUCH AS
BLEACH.
HAZARDOUS DECOMPOSITION PRODUCTS:
ACRID OR HARMFUL GAS IS EMITTED DURING LEAKAGE OR FIRE.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
ORGANIC ELECTROLYTE:
ACUTE TOXICITY:
LD50, ORAL - RAT: 2,000 MG/KG OR MORE
IRRITATING NATURE: IRRIGATIVE TO SKIN AND EYE
| SECTION 12. ECOLOGICAL INFORMATION | |
PERSISTENCE/DEGRADABILITY:
SINCE A BATTERY CELL AND THE INTERNAL MATERIALS REMAIN IN THE ENVIRONMENT,
DO NOT BURY OR THROW OUT INTO THE ENVIRONMENT.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
RECOMMENDED METHODS FOR SAFE AND ENVIRONMENTALLY PREFERRED DISPOSAL:
PRODUCT (WASTE FROM RESIDUES):
SPECIFIED COLLECTION OR DISPOSAL OF LITHIUM ION BATTERY IS REQUIRED BY THE
LAW LIKE AS "BATTERY CONTROL LAW" IN SEVERAL NATIONS. COLLECTION OR RECYCLE
OF THE BATTERY IS MAINLY IMPOSED ON BATTERY'S MANUFACTURER OR IMPORTER IN
THE NATIONS RECYCLE IS REQUIRED.
CONTAMINATED PACKAGING:
NEITHER A CONTAINER NOR PACKING IS CONTAMINATED DURING NORMAL USE. WHEN
INTERNAL MATERIALS LEAKED FROM A BATTERY CELL CONTAMINATES, DISPOSE AS
INDUSTRIAL WASTES SUBJECT TO SPECIAL CONTROL.
| SECTION 14. TRANSPORT INFORMATION | |
THE CELLS IN THESE BATTERIES HAVE BEEN TESTED AND MEET THE REQUIREMENTS FOR
THE UN MANUAL OF TESTS AND CRITERIA, PART III, SUBSECTION 38.3
WHEN A NUMBER OF BATTERIES ARE TRANSPORTED BY SHIP, VEHICLE AND RAILROAD
AVOID HIGH TEMPERATURE AND DEW CONDENSATION.
AVOID TRANSPORTATION WHICH MAY CAUSE DAMAGE OF PACKAGE.
LITHIUM-ION BATTERIES ARE NOT SUBJECT TO DANGEROUS GOODS REGULATION FOR THE
PURPOSE OF TRANSPORTATION BY THE INTERNATIONAL MARITIME DANGEROUS GOODS
REGULATIONS (IMDG). FOR LITHIUM-ION BATTERIES, THE WATT-HOUR RATING IS NO
MORE THAN 20WH/CELL AND 100WH/BATTERY PACK CAN BE TREATED AS "NON-DANGEROUS
GOODS" BY THE UNITED NATIONS RECOMMENDATIONS ON THE TRANSPORT OF DANGEROUS
GOODS/SPECIAL PROVISION 188, PROVIDED THAT THE PRODUCTS ARE PREVENTED FROM
BEING SHORT-CIRCUITED WITH EACH OTHER AND ARE PACKAGED IN AN APPROPRIATE
CONDITION WHICH SATISFIES PACKING GROUP II PERFORMANCE LEVEL.
IATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION): DANGEROUS GOODS REGULATION
PACKING INSTRUCTION 965 (LITHIUM ION OR LITHIUM POLYMER CELLS AND BATTERIES
WITHOUT ELECTRONIC EQUIPMENT) WENT INTO EFFECT APRIL 1, 2016: LITHIUM ION
CELLS AND BATTERIES MUST BE OFFERED FOR TRANSPORT AT A STATE OF CHARGE NOT
EXCEEDING 30 PER CENT OF THEIR RATED CAPACITY. UN 3480, PI 965, SECTION IA
AND IB AND II WILL BE RESTRICTED TO CARRIAGE ON CARGO AIRCRAFT. ALL
PACKAGES MUST BEAR THE CARGO AIRCRAFT ONLY LABEL IN ADDITION TO THE OTHER
MARKS AND LABELS REQUIRED BY THE REGULATIONS.
US HAZARDOUS MATERIALS REGULATIONS 49 CFR (CODE OF FEDERAL REGULATIONS)
SECTIONS 173-185 LITHIUM BATTERIES AND CELLS.
SECTION II REQUIREMENTS APPLY TO LITHIUM-ION CELLS WITH A WATT-HOUR RATING
NOT EXCEEDING 20 WH AND LITHIUM-ION BATTERIES WITH A WATT-HOUR RATING NOT
EXCEEDING 100 WH PACKED IN QUANTITIES THAT WITHIN THE ALLOWANCE PERMITTED
IN SECTION II, TABLE 965-11.
TABLE 965-II:
CONTENTS LITHIUM-ION CELLS LITHIUM-ION CELLS LITHIUM-ION
AND/OR BATTERIES WITH A WATT-HOUR BATTERIES WITH A
WITH A WATT-HOUR RATING OF MORE WATT-HOUR RATING
RATING OF 2.7 WH THAN 2.7WH BUT OF MORE THAN 2.7WH
OR LESS NOT MORE THAN BUT NOT MORE THAN
20WH 100WH
MAXIMUM NUMBER OF NO LIMIT 8 CELLS 2 BATTERIES
CELLS / BATTERIES
PER PACKAGE
MAXIMUM NET 2.5 KG N/A N/A
QUANTITY PER
PACKAGE
LITHIUM-ION CELLS AND BATTERIES MEETING THE REQUIREMENTS IN THIS SECTION
ARE NOT SUBJECT TO OTHER ADDITIONAL REQUIREMENTS OF THESE REGULATIONS
EXCEPT FOR:
EACH CELL AND BATTERY IS OF THE TYPE PROVEN TO MEET THE REQUIREMENTS OF
EACH TEST IN THE UN MANUAL OF TESTS AND CRITERIA, PART III, SUBSECTION
38.3
CELLS AND BATTERIES MUST BE MANUFACTURED UNDER A QUALITY MANAGEMENT
PROGRAM
FOR BATTERIES, THE WATT-HOUR RATING MUST BE MARKED ON THE OUTSIDE OF THE
BATTERY CASE
EACH PACKAGE MUST BE CAPABLE OF WITHSTANDING A 1.2M DROP TEST IN ANY
ORIENTATION WITHOUT
DAMAGE TO CELLS OR BATTERIES CONTAINED THEREIN
SHIFTING OF THE CONTENTS SO AS TO ALLOW BATTERY TO BATTERY (OR CELL TO
CELL) CONTACT
RELEASE OF CONTENTS.
EACH PACKAGE MUST BE MARKED WITH THE LITHIUM BATTERY MARK AND THE CARGO
AIRCRAFT ONLY LABEL.
A SHIPPER IS NOT PERMITTED TO OFFER FOR TRANSPORT MORE THAN ONE PACKAGE
PREPARED ACCORDING TO SECTION II IN ANY SINGLE CONSIGNMENT
SECTION IB REQUIREMENTS APPLY TO LITHIUM-ION CELLS WITH A WATT-HOUR RATING
NOT EXCEEDING 20 WH AND LITHIUM-ION BATTERIES WITH A WATT-HOUR RATING NOT
EXCEEDING 100 WH PACKED IN QUANTITIES THAT EXCEED THE ALLOWANCE PERMITTED
IN SECTION II, TABLE 965-II.
QUANTITIES OF LITHIUM-ION CELLS OR BATTERIES THAT EXCEED THE ALLOWANCE
PERMITTED IN SECTION II, TABLE 965-II MUST BE ASSIGNED TO CLASS 9 AND
ARE SUBJECT TO ALL OF THE APPLICABLE PROVISIONS OF REGULATION.
LITHIUM BATTERIES PACKED WITHOUT EQUIPMENT ARE CLASSIFIED UNDER (UN3480),
IATA DANGEROUS GOODS REGULATIONS PACKING INSTRUCTION 965 IS APPLIED.
LITHIUM BATTERIES PACKED WITH EQUIPMENT ARE CLASSIFIED UNDER (UN3481), IATA
DANGEROUS GOODS REGULATIONS PACKING INSTRUCTION 966 IS APPLIED.
LITHIUM BATTERIES INSTALLED IN EQUIPMENT ARE CLASSIFIED UNDER (UN3481),
IATA DANGEROUS GOODS REGULATIONS PACKING INSTRUCTION 967 IS APPLIED.
| SECTION 15. REGULATORY INFORMATION | |
REGULATIONS SPECIFICALLY APPLICABLE TO THE PRODUCT:
US DEPARTMENT OF TRANSPORTATION 49 CODE OF FEDERAL REGULATIONS [USA]
* ABOUT OVERLAPPING REGULATIONS, PLEASE REFER TO SECTION 14-TRANSPORT
INFORMATION.
| SECTION 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET IS OFFERED AN AGENCY WHO HANDLES THIS PRODUCT TO
HANDLE IT SAFELY.
THE AGENCY SHOULD UTILIZE THIS SAFETY DATA SHEET EFFECTIVELY (PUT IT UP,
EDUCATE PERSON IN CHARGE) AND TAKE PROPER MEASURES.
THE INFORMATION CONTAINED IN THIS SAFETY DATA SHEET IS BASED ON THE PRESENT
STATE OF KNOWLEDGE AND CURRENT LEGISLATION.
THIS SAFETY DATA SHEET PROVIDES GUIDANCE ON HEALTH, SAFETY AND
ENVIRONMENTAL ASPECTS OF THE PRODUCT AND SHOULD NOT BE CONSTRUED AS
ANY GUARANTEE OF TECHNICAL PERFORMANCE OR SUITABILITY FOR PARTICULAR
APPLICATIONS.
REFERENCE:
DANGEROUS GOODS REGULATIONS - 60TH EDITION EFFECTIVE 1 JANUARY 2019:
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA)
IMDG CODE - 2018 EDITION: INTERNATIONAL MARITIME ORGANIZATION (IMO)
THE EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD - 2019:
THE UNITED NATIONS ECONOMIC COMMISSION FOR EUROPE (UNECE)
SAFETY DATA SHEET
COMPLIES WITH THE OSHA HAZARD COMMUNICATION STANDARD: 29 CFR 1910 1200
| SECTION 1. CHEMICAL PRODUCT AND COMPANY NAME | |
LITHIUM-ION RECHARGEABLE BATTERY PACK BL1021B
MAKITA U.S.A., INC.
14930-C NORTHAM STREET
LA MIRADA, CA 90638
PREPARED BY: STAN RODRIGUES
DATE REVISED: 03/12/2019
EMERGENCY CONTACT INFORMATION:
TELEPHONE NUMBER FOR INFORMATION:
MAKITA: 1-510-657-9881
EMERGENCY RESPONSE:
FOR CHEMICAL EMERGENCY SPILLS, LEAK, FIRE, EXPOSURE, OR ACCIDENT CALL
CHEMTREC DAY OR NIGHT WITHIN USA AND CANADA: 1-800-424-9300
| SECTION 2. HAZARD IDENTIFICATION | |
THE PRODUCT IS A LITHIUM ION BATTERY AND IS THEREFORE CLASSIFIED AS AN
ARTICLE AND IS NOT HAZARDOUS WHEN USED ACCORDING TO THE RECOMMENDATIONS OF
THE MANUFACTURER. THE HAZARD IS ASSOCIATED WITH THE CONTENTS OF THE CELL OR
BATTERY. UNDER RECOMMENDED USE CONDITIONS, THE ELECTRODE MATERIALS AND
LIQUID ELECTROLYTE ARE NON-REACTIVE.
| SECTION 3. COMPOSITION, INFORMATION OR INGREDIENTS | |
BATTERY CELL:
HAZARDOUS INGREDIENTS % CAS NUMBER
ALUMINUM FOIL 2-10 7429-90-5
METAL OXIDE (PROPRIETARY) 20-50
POLYVINYLIDENE FLUORIDE (PVDF) <5 24937-79-9
COPPER FOIL 2-10 7440-50-8
CARBON (PROPRIETARY) 10-30 7440-44-0
ELECTROLYTE (PROPRIETARY) 10-20
STAINLESS STEEL, NICKEL AND REMAINDER N/A
INERT MATERIALS REMAINDER N/A
CIRCUIT MODULE:
HAZARDOUS INGREDIENTS % CAS NUMBER
LEAD 0.001 7439-92-1
MERCURY 0 7439-97-6
CHROMIUM 0 7440-47-3
CADMIUM 0 7440-43-9
PLASTIC CASE AND Si2O 0 N/A
PLASTIC PARTS AND PAINTS:
HAZARDOUS INGREDIENTS % CAS NUMBER
LEAD <0.1 7439-92-1
NICKLE <0.01 7440-02-0
CFCS 0 75-69-4
POLYCLORINATED BIPHENYLS 0 1336-36-3
DESCRIPTION:
WATT-HOUR RATING: UNDER 100 WH
| SECTION 4. FIRST AID MEASURE | |
INGESTION: IF SWALLOWED, OBTAIN MEDICAL ATTENTION IMMEDIATELY.
IF EXPOSURE TO INTERNAL MATERIALS WITHIN CELL (PACK) DUE TO DAMAGED OUTER
CASING, THE FOLLOWING ACTIONS ARE RECOMMENDED.
INHALATION: LEAVE AREA IMMEDIATELY AND SEEK MEDICAL ATTENTION.
EYE CONTACT:
RINSE EYES WITH WATER FOR 15 MINUTES AND SEEK MEDICAL ATTENTION.
SKIN CONTACT:
WASH AREA THOROUGHLY WITH SOAP AND WATER AND SEEK MEDICAL ATTENTION.
INGESTION: DRINK MILK/WATER AND INDUCE VOMITING; SEEK MEDICAL ATTENTION.
| SECTION 5. FIRE FIGHTING MEASURES | |
5.1 GENERAL HAZARD:
CELL IS NOT FLAMMABLE BUT INTERNAL ORGANIC MATERIAL WILL BURN IF THE CELL
IS INCINERATED. COMBUSTION PRODUCTS INCLUDE, BUT ARE NOT LIMITED TO
HYDROGEN FLUORIDE, CARBON MONOXIDE AND CARBON DIOXIDE.
5.2 EXTINGUISHING MEDIA:
USE EXTINGUISHING MEDIA SUITABLE FOR THE MATERIALS THAT ARE BURNING.
5.3 SPECIAL FIREFIGHTING INSTRUCTIONS:
IF POSSIBLE, REMOVE CELL(S) FROM FIREFIGHTING AREA. IF HEATED ABOVE 125
DEG. C, CELL(S) CAN EXPLODE/VENT.
5.4 FIREFIGHTING EQUIPMENT:
USE NIOSH/MSHA APPROVED FULL-FACE SELF-CONTAINED BREATHING APPARATUS (SCBA)
WITH FULL PROTECTIVE GEAR.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
6.1 ON LAND:
PLACE MATERIAL INTO SUITABLE CONTAINERS AND CALL LOCAL FIRE/POLICE
DEPARTMENT.
6.2 IN WATER:
IF POSSIBLE, REMOVE FROM WATER AND CALL LOCAL FIRE/POLICE DEPARTMENT.
| SECTION 7. HANDLING AND STORAGE | |
7.1 HANDLING:
NO SPECIAL PROTECTIVE CLOTHING REQUIRED FOR HANDLING INDIVIDUAL CELLS.
7.2 STORAGE: STORE IN A COOL, DRY PLACE.
| SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION | |
8.1 ENGINEERING CONTROLS:
KEEP AWAY FROM HEAT AND OPEN FAME. STORE IN A COOL DRY PLACE.
8.2 PERSONAL PROTECTION:
RESPIRATOR:
NOT REQUIRED DURING NORMAL OPERATIONS. SCBA REQUIRED IN THE EVENT OF A
FIRE.
EYE/FACE PROTECTION: NOT REQUIRED BEYOND SAFETY PRACTICES OF EMPLOYER.
GLOVES: NOT REQUIRED FOR HANDLING OF CELLS.
FOOT PROTECTION: STEEL TOED SHOES RECOMMENDED FOR LARGE CONTAINER HANDLING.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
STATE: SOLID
ODOR: N/A
PH: N/A
VAPOR PRESSURE: N/A
VAPOR DENSITY: N/A
BOILING POINT: N/A
SOLUBILITY IN WATER: INSOLUBLE
SPECIFIC GRAVITY: N/A
DENSITY: N/A
| SECTION 10. STABILITY AND REACTIVITY | |
10.1 REACTIVITY: NONE
10.2 INCOMPATIBILITIES:
NONE DURING NORMAL OPERATION. AVOID EXPOSURE TO HEAT, OPEN FLAME, AND
CORROSIVES.
10.3 HAZARDOUS DECOMPOSITION PRODUCTS:
NONE DURING NORMAL OPERATING CONDITIONS. IF CELLS ARE OPENED, HYDROGEN
FLUORIDE AND CARBON MONOXIDE MAY BE RELEASED.
10.4 CONDITIONS TO AVOID:
AVOID EXPOSURE TO HEAT AND OPEN FLAME. DO NOT PUNCTURE, CRUSH OR
INCINERATE.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
THIS PRODUCT DOES NOT ELICIT TOXICOLOGICAL PROPERTIES DURING ROUTINE
HANDLING AND USE.
SENSITIZATION: NO
TERATOGENICITY: NO
REPRODUCTIVE TOXICITY: NO
ACUTE TOXICITY: NO
THIS PRODUCT DOES NOT CONTAIN ANY KINDS OF THE FOLLOWING SUBSTANCES AND
HALOGEN-TYPE FLAME RETARDANTS INCLUDING CHLORINE AND BROMIDE TYPE HARMFUL
FLAME RETARDANTS WHICH ARE LISTED IN APPENDIX OF TCO DOCUMENTS AND RELEVANT
INTERNATIONAL ECO REQUIREMENTS:
POLYBROMATED BIPHENYLS (PBB)
POLYBROMATED DIPHENYLETHERS (PBDE)
POLYCHLORINATED BIPHENYLS (PCBS)
POLYCHLORINATED TERPHENYLS(PCTS)
POLYCHLORINATED PAPHTHALENE(PCN)
CHLORINATED PARAFFINS(C10-C13)
CHLOROFLUOROCARBONS(CFCS)
POLYVINYL CHLORIDE(PVC)
CARBON TETRACHLORIDE
NONE OF THE FOLLOWING SUBSTANCES WILL BE EXPOSED, LEAKED, OR EMITTED DURING
TRANSPORTATION, STORAGE OR ANY OPERATION AND ANY TEMPERATURE CONDITION:
CHLORINATED FLUOROHYDROCARBON (FCKW)
ACRYLONITRIDE
STYROL
PHENOL
BENZOL
MERCURY OF GREATER THAN 0.0001 WT% FOR ALKALINE BATTERY
MERCURY OF GREATER THAN 0.0005 WT% FOR OTHER BATTERY
LITHIUM CONTENT OF GREATER THAN 0.5G/BATTERY CELL
CADMIUM, LEAD, AND OTHER HARMFUL HEAVY METAL
AND WILL COMPLY WITH THE REGULATION OF 49 CFR (DOT REGULATION),
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA), AND DEUCHE
FORSCHUNGSGEMEINSCHAFT (DFG) REGARDING CONCENTRATIONS OF EMITTED
SUBSTANCES.
THIS PRODUCT DOES NOT CONTAIN MERCURY AND CADMIUM.
MERCURY CONTENT: N/A
CADMIUM CONTENT: N/A
IF THE CELLS ARE OPENED THROUGH MISUSE OR DAMAGE, DISCARD IMMEDIATELY.
INTERNAL COMPONENTS OF CELL ARE IRRITANTS AND SENSITIZERS.
| SECTION 12. ECOLOGICAL INFORMATION | |
SOME MATERIALS WITHIN THE CELL ARE BIO-ACCUMULATIVE. UNDER NORMAL
CONDITIONS, THESE MATERIALS ARE CONTAINED AND POSE NO RISK TO PERSONS
OR THE SURROUNDING ENVIRONMENT.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
CALIFORNIA REGULATED DEBRIS
RCRA WASTE CODE: NON-REGULATED
DISPOSE OF ACCORDING TO ALL FEDERAL, STATE, AND LOCAL REGULATIONS.
| SECTION 14. TRANSPORT INFORMATION | |
THE CELLS IN THESE BATTERIES HAVE BEEN TESTED AND MEET THE REQUIREMENTS
FOR THE UN MANUAL OF TESTS AND CRITERIA, PART III, SUBSECTION 38.3.
WHEN A NUMBER OF BATTERIES ARE TRANSPORTED BY SHIP, VEHICLE AND RAILROAD
AVOID HIGH TEMPERATURE AND DEW CONDENSATION.
AVOID TRANSPORTATION WHICH MAY CAUSE DAMAGE OF PACKAGE.
LITHIUM-ION BATTERIES ARE NOT SUBJECT TO DANGEROUS GOODS REGULATION FOR THE
PURPOSE OF TRANSPORTATION BY THE INTERNATIONAL MARITIME DANGEROUS GOODS
REGULATIONS (IMDG). FOR LITHIUM-ION BATTERIES, THE WATT-HOUR RATING IS NO
MORE THAN 20WH/CELL AND 100WH/BATTERY PACK CAN BE TREATED AS "NON-DANGEROUS
GOODS" BY THE UNITED NATIONS RECOMMENDATIONS ON THE TRANSPORT OF DANGEROUS
GOODS/SPECIAL PROVISION 188, PROVIDED THAT THE PRODUCTS ARE PREVENTED FROM
BEING SHORT-CIRCUITED WITH EACH OTHER AND ARE PACKAGED IN AN APPROPRIATE
CONDITION WHICH SATISFIES PACKING GROUP II PERFORMANCE LEVEL.
IATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION): DANGEROUS GOODS REGULATION
PACKING INSTRUCTION 965 (LITHIUM ION OR LITHIUM POLYMER CELLS AND BATTERIES
WITHOUT ELECTRONIC EQUIPMENT) WENT INTO EFFECT APRIL 1, 2016: LITHIUM ION
CELLS AND BATTERIES MUST BE OFFERED FOR TRANSPORT AT A STATE OF CHARGE NOT
EXCEEDING 30 PER CENT OF THEIR RATED CAPACITY. UN 3480, PI 965, SECTION IA
AND IB AND II WILL BE RESTRICTED TO CARRIAGE ON CARGO AIRCRAFT. ALL
PACKAGES MUST BEAR THE CARGO AIRCRAFT ONLY LABEL IN ADDITION TO THE OTHER
MARKS AND LABELS REQUIRED BY THE REGULATIONS.
SECTION II REQUIREMENTS APPLY TO LITHIUM-ION CELLS WITH A WATT-HOUR RATING
NOT EXCEEDING 20 WH AND LITHIUM-ION BATTERIES WITH A WATT-HOUR RATING NOT
EXCEEDING 100 WH PACKED IN QUANTITIES THAT WITHIN THE ALLOWANCE PERMITTED
IN SECTION II, TABLE 965-11.
TABLE 965-II:
CONTENTS LITHIUM-ION CELLS LITHIUM-ION CELLS LITHIUM-ION
AND/OR BATTERIES WITH A WATT-HOUR BATTERIES WITH A
WITH A WATT-HOUR RATING OF MORE WATT-HOUR RATING
RATING OF 2.7 WH THAN 2.7WH BUT OF MORE THAN
OR LESS NOT MORE THAN 2.7WH BUT NOT
20WH MORE THAN 100WH
MAXIMUM NUMBER OF NO LIMIT 8 CELLS 2 BATTERIES
CELLS / BATTERIES
PER PACKAGE
MAXIMUM NET 2.5 KG N/A N/A
QUANTITY PER
PACKAGE
LITHIUM-ION CELLS AND BATTERIES MEETING THE REQUIREMENTS IN THIS SECTION
ARE NOT SUBJECT TO OTHER ADDITIONAL REQUIREMENTS OF THESE REGULATIONS
EXCEPT FOR:
EACH CELL AND BATTERY IS OF THE TYPE PROVEN TO MEET THE REQUIREMENTS OF
EACH TEST IN THE UN MANUAL OF TESTS AND CRITERIA, PART III, SUBSECTION
38.3
CELLS AND BATTERIES MUST BE MANUFACTURED UNDER A QUALITY MANAGEMENT
PROGRAM
FOR BATTERIES, THE WATT-HOUR RATING MUST BE MARKED ON THE OUTSIDE OF THE
BATTERY CASE
EACH PACKAGE MUST BE CAPABLE OF WITHSTANDING A 1.2M DROP TEST IN ANY
ORIENTATION WITHOUT:
DAMAGE TO CELLS OR BATTERIES CONTAINED THEREIN
SHIFTING OF THE CONTENTS SO AS TO ALLOW BATTERY TO BATTERY (OR CELL TO
CELL) CONTACT
RELEASE OF CONTENTS.
EACH PACKAGE MUST BE MARKED WITH THE LITHIUM BATTERY MARK AND THE CARGO
AIRCRAFT ONLY LABEL.
A SHIPPER IS NOT PERMITTED TO OFFER FOR TRANSPORT MORE THAN ONE PACKAGE
PREPARED ACCORDING TO SECTION II IN ANY SINGLE CONSIGNMENT
SECTION IB REQUIREMENTS APPLY TO LITHIUM-ION CELLS WITH A WATT-HOUR RATING
NOT EXCEEDING 20 WH AND LITHIUM-ION BATTERIES WITH A WATT-HOUR RATING NOT
EXCEEDING 100 WH PACKED IN QUANTITIES THAT EXCEED THE ALLOWANCE PERMITTED
IN SECTION II, TABLE 965-II.
QUANTITIES OF LITHIUM-ION CELLS OR BATTERIES THAT EXCEED THE ALLOWANCE
PERMITTED IN SECTION II, TABLE 965-II MUST BE ASSIGNED TO CLASS 9 AND ARE
SUBJECT TO ALL OF THE APPLICABLE PROVISIONS OF REGULATION.
LITHIUM BATTERIES PACKED WITHOUT EQUIPMENT ARE CLASSIFIED UNDER (UN3480),
IATA DANGEROUS GOODS REGULATIONS PACKING INSTRUCTION 965 IS APPLIED.
LITHIUM BATTERIES PACKED WITH EQUIPMENT ARE CLASSIFIED UNDER (UN3481), IATA
DANGEROUS GOODS REGULATIONS PACKING INSTRUCTION 966 IS APPLIED.
LITHIUM BATTERIES INSTALLED IN EQUIPMENT ARE CLASSIFIED UNDER (UN3481),
IATA DANGEROUS GOODS REGULATIONS PACKING INSTRUCTION 967 IS APPLIED.
| SECTION 15. REGULATORY INFORMATION | |
OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200):
HAZARDOUS ( )
NON-HAZARDOUS (V)
| SECTION 16. OTHER INFORMATION | |
PACKAGE IF DAMAGED: DO NOT LOAD OR TRANSPORT.