| Common Name: | TOUGH GUY ODOR COUNTERACTANT |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 9/11/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 55JF71 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
DATE ISSUED: 09/11/2019
SDS NO: GRAINGER 38TH14
TOUGH GUY ODOR COUNTERACTANT
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: TOUGH GUY ODOR COUNTERACTANT
GENERAL USE: ELIMINATE ODORS CAUSED BY SMOKE, ANIMALS, COOKING, ETC.
PRODUCT DESCRIPTION: AIR FRESHENER & DEODORIZER
PRODUCT CODE: 38TH14
CHEMICAL FAMILY: FRAGRANCE BLEND
MANUFACTURER:
W.W. GRAINGER INC.
100 GRAINGER WAY
LAKE FOREST, IL 60045
CUSTOMER SERVICE: 800-472-4643
24 HR. EMERGENCY TELEPHONE NUMBERS:
CHEM-TEL (MEDICAL AND TRANSPORTATION): 800-255-3924
POISON CONTROL CENTER (MEDICAL): 800-222-1222
| 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATIONS:
HEALTH:
EYE IRRITATION, CATEGORY 2A
SKIN IRRITATION, CATEGORY 3
ACUTE TOXICITY (ORAL), CATEGORY 5
GHS LABEL: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
H319: CAUSES SERIOUS EYE IRRITATION.
H316: CAUSES MILD SKIN IRRITATION.
H303: MAY BE HARMFUL IF SWALLOWED.
PRECAUTIONARY STATEMENT(S):
PREVENTION:
P273: AVOID RELEASE TO THE ENVIRONMENT.
P262: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P102: KEEP OUT OF REACH OF CHILDREN.
RESPONSE:
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER
P332+P313:
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
P301+P312:
IF SWALLOWED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P304+P312:
IF INHALED: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
STORAGE:
P404: STORE IN A CLOSED CONTAINER.
DISPOSAL:
P501:
DISPOSE OF CONTENTS/CONTAINER ACCORDING TO ALL LOCAL, STATE AND FEDERAL
REGULATIONS.
EMERGENCY OVERVIEW:
PHYSICAL APPEARANCE: CLEAR LIQUID
IMMEDIATE CONCERNS: EYE & SKIN IRRITANT
POTENTIAL HEALTH EFFECTS:
EYES: IRRITATING, AND MAY INJURE EYE TISSUE IF NOT REMOVED PROMPTLY.
SKIN: SKIN IRRITANT WITH PROLONGED OR REPEATED CONTACT.
SKIN ABSORPTION: NONE EXPECTED.
INGESTION:
ALTHOUGH OF MODERATE TO LOW TOXICITY, INGESTION OF LARGE AMOUNTS CAN CAUSE
GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, DIARRHEA.
INHALATION: MIST MAY BE IRRITATING TO NOSE, THROAT AND LUNGS.
REPRODUCTIVE TOXICITY:
REPRODUCTIVE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENIC EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MEDICAL CONDITIONS AGGRAVATED:
PREVIOUS SKIN CONDITIONS SUCH AS DERMATITIS MAY BE AGGREVATED.
ROUTES OF ENTRY: INGESTION, EYE
CANCER STATEMENT: NONE
SENSITIZATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
WARNING CAUTION LABELS: IRRITANT
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
CHEMICAL NAME WT.% CAS
ALCOHOL ETHOXYLATE 5 - 10 68131-39-5
DIPROPYLENE GLYCOL 5 - 10 25265-71-8
FRAGRANCE 5 - 10 TS
WATER 70 - 80 7732-18-5
COMMENTS:
IF CAS NUMBER IS "TS", THE SPECIFIC CHEMICAL IDENTITY HAS BEEN WITHHELD AS
A TRADE SECRET.
| 4. FIRST AID MEASURES | |
EYES:
IMMEDIATELY FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES, WHILE HOLDING
EYELIDS OPEN. REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST 5 MINUTES,
THEN CONTINUE RINSING EYE. SEEK MEDICAL ATTENTION IMMEDIATELY.
SKIN:
WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS OR
PERSISTS.
INGESTION:
GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING UNLESS INSTRUCTED
TO DO SO BY POISON CENTER OR PHYSICIAN.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND MONITOR. SEEK MEDICAL ADVISE IF IRRITATION
PERSISTS.
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
EYES: BURNING SENSATION WITH TEARING, REDNESS.
SKIN:
PROLONGED CONTACT WILL CAUSE IRRITATION MARKED BY REDNESS, BURNING
SENSATION.
SKIN ABSORPTION: NONE EXPECTED.
INGESTION: IRRITATION OF MOUTH, THROAT, ALONG WITH STOMACH UPSET, VOMITING.
INHALATION:
IRRITATION OF NOSE, THROAT AND LUNGS WITH COUGHING, SNEEZING, POSSIBLE
DIFFICULTY BREATHING.
ACUTE EFFECTS: NOT ESTABLISHED
| 5. FIRE FIGHTING MEASURES | |
FLAMMABLE CLASS:
NA = NOT APPLICABLE
GENERAL HAZARD:
NA = NOT APPLICABLE
EXTINGUISHING MEDIA: NOT REQUIRED. WATER BASED MATERIAL.
FIRE FIGHTING PROCEDURES:
KEEP FIRE EXPOSED CONTAINERS COOL WITH WATER STREAM OR MIST.
FIRE FIGHTING EQUIPMENT: NO SPECIAL REQUIREMENTS.
| 6. ACCIDENTAL RELEASE MEASURES | |
SMALL SPILL:
AVOID WALKING IN PRODUCT. WIPE UP OR OTHERWISE FLUSH SMALL SPILLS TO
SANITARY SEWER.
LARGE SPILL:
AVOID WALKING IN MATERIAL. PREVENT PRODUCT FROM ENTERING INTO STREAM, SOIL,
STORM SEWER OR OTHER BODIES OF WATER.
ENVIRONMENTAL PRECAUTIONS:
WATER SPILL: AVOID DISCHARGES INTO OPEN WATERWAYS.
LAND SPILL: AVOID DISCHARGE TO SOIL.
GENERAL PROCEDURES:
ISOLATE SPILL OR LEAK AREA IMMEDIATELY. KEEP UNAUTHORIZED PERSONNEL AWAY.
DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. PREVENT ENTRY INTO
WATERWAYS, SEWERS, OR CONFINED AREAS. ABSORB WITH DRY EARTH, SAND OR OTHER
NONCOMBUSTIBLE MATERIAL AND TRANSFER TO CONTAINERS.
SPECIAL PROTECTIVE EQUIPMENT:
EYE PROTECTION, RUBBER GLOVES, RUBBER BOOTS TO PROTECT FEET.
| 7. HANDLING AND STORAGE | |
GENERAL PROCEDURES: CLOSE CONTAINER AFTER USE.
HANDLING: WEAR EYE PROTECTION, RUBBER GLOVES WHEN HANDLING CONCENTRATE.
STORAGE: STORE IN AREA INACCESSIBLE TO CHILDREN.
STORAGE TEMPERATURE: STORE AT AMBIENT TEMPERATURES.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
ENGINEERING CONTROLS: NO SPECIAL REQUIREMENTS.
PERSONAL PROTECTIVE EQUIPMENT:
EYES AND FACE: SAFETY GLASSES WITH SIDE SHIELDS.
SKIN: RUBBER OR OTHER CHEMICAL RESISTANT GLOVES.
RESPIRATORY:
A RESPIRATOR IS NOT NEEDED UNDER NORMAL AND INTENDED CONDITIONS OF PRODUCT
USE.
PROTECTIVE CLOTHING: NO SPECIAL REQUIREMENTS.
WORK HYGIENIC PRACTICES:
WASH WITH SOAP AND WATER AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHILE
USING PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
ODOR: LAVENDER
ODOR THRESHOLD: NOT ESTABLISHED
COLOR: COLORLESS
PH: 7.0 TO 9.0
PERCENT VOLATILE: 85+
FLASH POINT AND METHOD: NONE
FLAMMABLE LIMITS: N/A
AUTOIGNITION TEMPERATURE:
NA = NOT APPLICABLE
VAPOR PRESSURE: APPROX 20 MMHg AT 20 DEG. C (68 DEG. F)
VAPOR DENSITY: APPROX. 1 AIR = 1
BOILING POINT:
212 DEG. F
100 DEG. C
FREEZING POINT:
32 DEG. F
0 DEG. C
MELTING POINT: NOT AVAILABLE
THERMAL DECOMPOSITION: NOT AVAILABLE
SOLUBILITY IN WATER: COMPLETE
EVAPORATION RATE (WATER = 1): 1.0
DENSITY: 8.37 AT 20 DEG. C (68 DEG. F)
SPECIFIC GRAVITY: 1.003 GRAMS/ML. AT 20 DEG. C (68 DEG. F)
VISCOSITY: WATER THIN.
(VOC): 5.8% BY WEIGHT
NOTES: FRAGRANCE ONLY
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: STABLE
HAZARDOUS POLYMERIZATION: NO
CONDITIONS TO AVOID: NOT ESTABLISHED
POSSIBILITY OF HAZARDOUS REACTIONS: NONE EXPECTED.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN.
INCOMPATIBLE MATERIALS: STRONG ACIDS, OXIDIZERS.
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50
(RAT) (RABBIT) (RAT)
DIPROPYLENE GLYCOL 14800 MG/KG >5000 MG/KG NO DATA AVAILABLE
(RAT) (RABBIT)
DERMAL LD50: NOT ESTABLISHED
ORAL LD50: NOT ESTABLISHED
INHALATION LC50: NOT ESTABLISHED
SERIOUS EYE DAMAGE/IRRITATION: IRRITANT
RESPIRATORY OR SKIN SENSITISATION:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
GERM CELL MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY IARC: NO LISTED SUBSTANCE
NOTES: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
REPRODUCTIVE TOXICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
STOT-SINGLE EXPOSURE: NOT ESTABLISHED
| 12. ECOLOGICAL INFORMATION | |
ENVIRONMENTAL DATA: NOT ESTABLISHED
ECOTOXICOLOGICAL INFORMATION: NOT ESTABLISHED
BIOACCUMULATION/ACCUMULATION: NONE EXPECTED.
AQUATIC TOXICITY (ACUTE): NOT ESTABLISHED
CHEMICAL FATE INFORMATION: THIS PRODUCT IS BIODEGRADABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHOD:
ANY METHOD IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL LAWS. BEST METHOD
IS TO RECYCLE OR REUSE FOR INTENDED PURPOSE. SMALL AMOUNTS (LESS THAN 1
GALLON) MAY BE DILUTED WITH COPIOUS AMOUNTS OF WATER AND DISPOSED OF INTO
SANITARY SEWER.
FOR LARGE SPILLS:
CONSULT WITH LOCAL AND STATE AUTHORITIES FOR LARGE VOLUME DISPOSAL.
PRODUCT DISPOSAL: SEE ABOVE.
EMPTY CONTAINER:
RINSE CONTAINER WITH CLEAR WATER. OFFER CONTAINER FOR RECYCLING, OR DISPOSE
OF IN TRASH.
RCRA/EPA WASTE INFORMATION:
NA = NOT APPLICABLE
| 14. TRANSPORT INFORMATION | |
DOT (DEPARTMENT OF TRANSPORTATION):
PROPER SHIPPING NAME: NOT REGULATED AS A DANGEROUS GOOD.
ROAD AND RAIL (ADR/RID):
PROPER SHIPPING NAME: CLEANING COMPOUND, NOT REGULATED.
AIR (ICAO/IATA):
SHIPPING NAME: NOT REGULATED AS A DANGEROUS GOOD.
VESSEL (IMO/IMDG):
SHIPPING NAME: NOT REGULATED AS A DANGEROUS GOOD.
CANADA TRANSPORT OF DANGEROUS GOODS:
SHIPPING NAME: NOT REGULATED AS A DANGEROUS GOOD.
| 15. REGULATORY INFORMATION | |
UNITED STATES:
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT):
311/312 HEALTH HAZARDS: HEALTH - ACUTE
311/312 PHYSICAL HAZARDS:
NA = NOT APPLICABLE
313 REPORTABLE INGREDIENTS: NO LISTED SUBSTANCE
302/304 EMERGENCY PLANNING:
EMERGENCY PLAN:
NA = NOT APPLICABLE
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT):
CERCLA REGULATORY:
NA = NOT APPLICABLE
TSCA (TOXIC SUBSTANCE CONTROL ACT):
TSCA REGULATORY:
ALL INGREDIENTS ARE LISTED ON THE TSCA CHEMICAL INVENTORY.
CLEAN AIR ACT:
40 CFR PART 68 - RISK MANAGEMENT FOR CHEMICAL ACCIDENT RELEASE PREVENTION:
NO LISTED SUBSTANCE
CLEAN AIR ACT (HAZARDOUS AIR POLLUTANTS): NO LISTED SUBSTANCE
STATES WITH SPECIAL REQUIREMENTS:
CHEMICAL NAME REQUIREMENTS
DIPROPYENE GLYCOL NEW JERSEY RIGHT TO KNOW SUBSTANCE
PENNSYLVANIA RIGHT TO KNOW SUBSTANCE
CALIFORNIA PROPOSITION 65: NO LISTED SUBSTANCE
CLEAN WATER ACT: NO LISTED SUBSTANCE
CARCINOGEN: NO LISTED SUBSTANCE
| 16. OTHER INFORMATION | |
DATE PREPARED: 09/11/2019
HMIS RATING:
HEALTH 2
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
NFPA CODES:
2
0
0
MANUFACTURER DISCLAIMER:
THIS COMPANY CANNOT ANTICIPATE ALL CONDITIONS OF HANDLING AND USE OF THIS
PRODUCT. THEREFORE, THIS COMPANY ACCEPTS NO RESPONSIBILITY FOR RESULTS
OBTAINED BY THE APPLICATION OF THIS INFORMATION, OR THE SAFETY AND
SUITABILITY OF THE PRODUCT EITHER ALONE OR IN COMBINATION WITH OTHER
PRODUCTS. IT IS THE RESPONSIBILITY OF THE EMPLOYER AND/OR USER TO PROVIDE
A SAFE WORKPLACE, USING HEALTH AND SAFETY INFORMATION CONTAINED HEREIN AS
A GUIDE. THIS COMPANY WILL ACCEPT NO LIABILITY FOR DAMAGES OR LOSSES
INCURRED FROM THE IMPROPER HANDLING AND USE OF THIS PRODUCT.