| Common Name: | TOUGH GUY CLEANER AND DISINFECTANT |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 9/11/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 55JF72 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATASHEET
DATE ISSUED: 09/11/2019
SDS NO: GRAINGER_38TH15
TOUGH GUY CLEANER AND DISINFECTANT
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: TOUGH GUY CLEANER AND DISINFECTANT
GENERAL USE: DISINFECTANT, VIRUCIDE, FUNGICIDE
PRODUCT DESCRIPTION: DISINFECTANT & CLEANER
PRODUCT CODE: 38TH15
CHEMICAL FAMILY: QUATERNARY AMMONIUM CHLORIDE/DETERGENG BLEND
MANUFACTURER:
W.W. GRAINGER INC.
100 GRAINGER WAY
LAKE FOREST, IL 60045
CUSTOMER SERVICE: 800-472-4643
EPA REG. NO.: 6836-78-10637
24 HR. EMERGENCY TELEPHONE NUMBERS:
CHEM-TEL (MEDICAL AND TRANSPORTATION): 800-255-3924
POISON CONTROL CENTER (MEDICAL): 800-222-1222
| 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATIONS:
HEALTH:
EYE CORROSION, CATEGORY 1
SKIN CORROSION, CATEGORY 1
ACUTE TOXICITY (ORAL), CATEGORY 5
ENVIRONMENTAL: ACUTE HAZARDS TO THE AQUATIC ENVIRONMENT, CATEGORY 1
GHS LABEL:
CORROSION
ENVIRONMENT
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H318: CAUSES SERIOUS EYE DAMAGE.
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H302: HARMFUL IF SWALLOWED.
H401: TOXIC TO AQUATIC LIFE.
PRECAUTIONARY STATEMENT(S):
PREVENTION:
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P102: KEEP OUT OF REACH OF CHILDREN.
P234: KEEP ONLY IN ORIGINAL PACKAGING.
RESPONSE:
P301+P330+P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER
[OR SHOWER].
P310: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
P391: COLLECT SPILLAGE.
STORAGE:
P405: STORE LOCKED UP.
DISPOSAL:
P501:
DISPOSE OF CONTENTS/CONTAINER ACCORDING TO ALL LOCAL, STATE AND FEDERAL
REGULATIONS.
EMERGENCY OVERVIEW:
PHYSICAL APPEARANCE: OPALESCENT GREEN
IMMEDIATE CONCERNS: CAUSES IRREVERSIBLE EYE DAMAGE AND SKIN BURNS.
POTENTIAL HEALTH EFFECTS:
EYES: CORROSIVE, CONTACT CAUSES SEVERE EYE BURNS.
SKIN: CONTACT CAUSES SEVERE SKIN IRRITATION AND POSSIBLE BURNS.
SKIN ABSORPTION: HARMFUL IF ABSORBED THROUGH SKIN.
INGESTION: HARMFUL IF SWALLOWED.
INHALATION: NONE EXPECTED.
REPRODUCTIVE TOXICITY:
REPRODUCTIVE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENIC EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
ROUTES OF ENTRY: EYE, SKIN, INGESTION.
CANCER STATEMENT: NONE
SENSITIZATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
WARNING CAUTION LABELS: CORROSIVE
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
CHEMICAL NAME WT.% CAS
OCTYL DECYL DIMETHYL AMMONIUM CHLORIDE 6.51 32426-11-2
DIDECYL DIMETHYL AMMONIUM CHLORIDE 3.906 7173-51-5
DIOCTYL DIMETHYL AMMONIUM CHLORIDE 2.604 5538-94-3
ALKYL DIMETHYLBENZYL AMMONIUM CHLORIDE(C12-C16) 8.68 68424-85-1
SODIUM SILICATE 1 - 5 6834-92-0
TETRASODIUM ETHYLENEDIAMINE TETRAACETATE 1 - 5 64-02-8
FRAGRANCE <1 TS
WATER 65 - 75 7732-18-5
COMMENTS:
IF CAS NUMBER IS "TS", THE SPECIFIC CHEMICAL IDENTITY HAS BEEN WITHHELD
AS A TRADE SECRET.
| 4. FIRST AID MEASURES | |
EYES:
IMMEDIATELY FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES, WHILE HOLDING
EYELIDS OPEN. REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST 5 MINUTES,
THEN CONTINUE RINSING EYE. SEEK MEDICAL ATTENTION IMMEDIATELY.
SKIN:
REMOVE CONTAMINATED CLOTHING. IMMEDIATELY FLUSH WITH WATER FOLLOWED BY
WASHING WITH MILD SOAP. SEEK MEDICAL ATTENTION.
INGESTION:
GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING UNLESS INSTRUCTED
TO DO SO BY POISON CENTER OR PHYSICIAN.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND MONITOR. SEEK MEDICAL ADVISE IF IRRITATION
PERSISTS.
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
EYES: SEVERE BURNING SENSATION, DAMAGE MARKED BY BURNS.
SKIN: BURNING SENSATION, REDNESS, SWELLING AND POSSIBLE BLISTERING.
SKIN ABSORPTION: NOT ESTABLISHED
INGESTION: IRRITATION OF MOUTH, THROAT, ALONG WITH STOMACH UPSET, VOMITING.
INHALATION:
IRRITATION OF NOSE, THROAT AND LUNGS WITH COUGHING, SNEEZING, POSSIBLE
DIFFICULTY BREATHING.
ACUTE EFFECTS:
CORROSIVE TO EYES. CAUSES MODERATE TO SEVERE SKIN IRRITATION. HARMFUL IF
SWALLOWED.
NOTES TO PHYSICIAN:
PROBABLE MUCOSAL DAMAGE MAY CONTRAINDICATE THE USE OF GASTRIC LAVAGE.
| 5. FIRE FIGHTING MEASURES | |
FLAMMABLE CLASS:
NA = NOT APPLICABLE
EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
EXPLOSION HAZARDS: NONE
FIRE FIGHTING PROCEDURES:
KEEP FIRE EXPOSED CONTAINERS COOL WITH WATER STREAM OR MIST.
FIRE FIGHTING EQUIPMENT:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT ANS
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
HAZARDOUS DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE: CARBON DIOXIDE, CARBON MONOXIDE,
NITROGEN OXIDES.
| 6. ACCIDENTAL RELEASE MEASURES | |
SMALL SPILL:
AVOID RUNOFF INTO STORM SEWERS AND DITCHES WHICH LEAD TO WATERWAYS.
LARGE SPILL:
AVOID WALKING IN MATERIAL. PREVENT PRODUCT FROM ENTERING INTO STREAM,
SOIL, STORM SEWER OR OTHER BODIES OF WATER.
ENVIRONMENTAL PRECAUTIONS:
WATER SPILL: AVOID DISCHARGES INTO OPEN WATERWAYS.
LAND SPILL: AVOID DISCHARGE TO SOIL.
AIR SPILL:
NA = NOT APPLICABLE
GENERAL PROCEDURES:
ISOLATE SPILL OR LEAK AREA IMMEDIATELY. KEEP UNAUTHORIZED PERSONNEL AWAY.
DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. PREVENT ENTRY INTO
WATERWAYS, SEWERS, OR CONFINED AREAS. ABSORB WITH DRY EARTH, SAND OR OTHER
NONCOMBUSTIBLE MATERIAL AND TRANSFER TO CONTAINERS.
RELEASE NOTES: PRODUCT IS TOXIC TO FISH AND AQUATIC INVERTEBRATES.
SPECIAL PROTECTIVE EQUIPMENT:
EYE PROTECTION, RUBBER GLOVES, RUBBER BOOTS TO PROTECT FEET.
| 7. HANDLING AND STORAGE | |
GENERAL PROCEDURES:
DO NOT CONTAMINATE WATER, FOOD, OR FEED BY STORAGE OR DISPOSAL.
HANDLING:
AVOID CONTACT WITH SKIN AND EYES. WASH HANDS BEFORE EATING, DRINKING,
SMOKING OR USING TOILET FACILITIES.
STORAGE:
STORE ONLY IN ORIGINAL CONTAINER. DO NOT REUSE EMPTY CONTAINER. IF A LEAKY
CONTAINER MUST BE CONTAINED WITHIN ANOTHER, MARK THE OUTER CONTAINER TO
IDENTIFY THE CONTENTS. STORE PESTICIDES AWAY FROM FOOD, PET FOOD, FEED, AND
WATER SOURCES. KEEP THIS PRODUCT UNDER LOCKED STORAGE SUFFICIENT TO MAKE IT
INACCESSIBLE TO CHILDREN OR PERSONS UNFAMILIAR WITH ITS PROPER USE.
STORAGE TEMPERATURE: STORE AT AMBIENT TEMPERATURES.
STORAGE PRESSURE: STORE AT AMBIENT ATMOSPHERIC PRESSURE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
ENGINEERING CONTROLS: USE IN WELL VENTILATED AREA.
PERSONAL PROTECTIVE EQUIPMENT:
EYES AND FACE: CHEMICAL SPLASH GOOGLES AND FULL FACE-SHIELD.
SKIN: RUBBER OR OTHER CHEMICAL RESISTANT GLOVES.
RESPIRATORY:
A RESPIRATOR IS NOT NEEDED UNDER NORMAL AND INTENDED CONDITIONS OF PRODUCT
USE.
PROTECTIVE CLOTHING: NO SPECIAL REQUIREMENTS.
WORK HYGIENIC PRACTICES:
WASH WITH SOAP AND WATER AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHILE
USING PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
ODOR: CHARACTERISTIC.
ODOR THRESHOLD: NOT ESTABLISHED
COLOR: OPALESCENT GREEN
PH: 12.0 TO 13.0
PERCENT VOLATILE: >75
FLASH POINT AND METHOD: NONE
FLAMMABLE LIMITS: N/A
AUTOIGNITION TEMPERATURE:
NA = NOT APPLICABLE
VAPOR PRESSURE: 20 MMHg AT 20 DEG. C (68 DEG. F)
VAPOR DENSITY: APPROX. 1 AIR = 1
BOILING POINT: 212 DEG. F; 100 DEG. C
FREEZING POINT: 32 DEG. F; 0 DEG. C
THERMAL DECOMPOSITION: NOT AVAILABLE
SOLUBILITY IN WATER: COMPLETE
EVAPORATION RATE (WATER = 1): 1.0
DENSITY: 8.34 AT 20 DEG. C (68 DEG. F)
SPECIFIC GRAVITY: 1.01 GRAMS/ML. AT 20 DEG. C (68 DEG. F)
VISCOSITY: WATER THIN.
(VOC): 2.79% BY WEIGHT
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
CONDITIONS TO AVOID: NOT ESTABLISHED
HAZARDOUS DECOMPOSITION PRODUCTS: NONE EXPECTED.
INCOMPATIBLE MATERIALS: STRONG OXIDIZERS
| 11. TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY:
CHEMICAL NAME ORAL LD5O (RAT) DERMAL LD5O (RABBIT)
OCTYL DECYL DIMETHYL 200 TO 2000 MG/KG NOT AVAILABLE
AMMONIUM CHLORIDE (RAT)
DIDECYL DIMETHYL 268 MG/KG (MOUSE) 2730 MG/KG (RABBIT)
AMMONIUM CHLORIDE
DIOCTYL DIMETHYL 50 MG/KG (MOUSE) NOT AVAILABLE
AMMONIUM CHLORIDE
ALKYL DIMETHYLBENZYL 450 MG/KG (RAT) 3342 MG/KG (RABBIT)
AMMONIUM CHLORIDE(C12-C16)
SODIUM SILICATE 1500 TO 3200 MG/KG
(RAT)
TETRASODIUM ETHYLENEDIAMINE 3030 MG/KG (RAT) >5000 MG/KG (RABBIT)
TETRAACETATE
DERMAL LD50: >2000 MG/KG MALE AND FEMALE RABBITS.
ORAL LD50: >1890 MG/KG MALE AND FEMALE RATS.
INHALATION LC50: NOT ESTABLISHED
SKIN CORROSION/IRRITATION: CORROSIVE
SERIOUS EYE DAMAGE/IRRITATION: CORROSIVE
RESPIRATORY OR SKIN SENSITISATION: NOT ESTABLISHED
GERM CELL MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY:
IARC: NO LISTED SUBSTANCE
NTP: NO LISTED SUBSTANCE
NOTES: NO LISTED SUBSTANCE
REPRODUCTIVE TOXICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
STOT-SINGLE EXPOSURE: NOT ESTABLISHED
| 12. ECOLOGICAL INFORMATION | |
ENVIRONMENTAL DATA: NOT ESTABLISHED
ECOTOXICOLOGICAL INFORMATION:
THIS PRODUCT IS TOXIC TO FISH AND AQUATIC INVERTEBRATES.
BIOACCUMULATION/ACCUMULATION: NOT ESTABLISHED
AQUATIC TOXICITY (ACUTE): NOT ESTABLISHED
CHEMICAL FATE INFORMATION: NOT ESTABLISHED
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHOD:
ATTEMPT TO USE PRODUCT COMPLETELY IN ACCORDANCE WITH INTENDED USE.
PESTICIDE WASTES ARE ACUTELY HAZARDOUS. IMPROPER DISPOSAL OF EXCESS
PESTICIDE, SPRAY MIXTURE OR RINSATE IS A VIOLATION OF FEDERAL LAW. IF
THESE WASTES CANNOT BE DISPOSED OF BY USE ACCORDING TO LABEL INSTRUCTIONS,
CONTACT YOUR STATE PESTICIDE OR ENVIRONMENTAL CONTROL AGENCY, OR THE
HAZARDOUS WASTE REPRESENTATIVE AT YOUR LOCAL OFFICE, OR THE NEAREST EPA
REGIONAL OFFICE FOR GUIDANCE.
FOR LARGE SPILLS:
CONSULT WITH LOCAL AND STATE AUTHORITIES FOR LARGE VOLUME DISPOSAL.
PRODUCT DISPOSAL:
ANY METHOD IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL LAWS. BEST METHOD
IS TO RECYCLE OR REUSE FOR INTENDED PURPOSE.
EMPTY CONTAINER:
TRIPLE RINSE CONTAINER PROMPTLY AFTER EMPTYING. FILL CONTAINER 1/4 FULL
WITH WATER AND RECAP. SHAKE FOR 10 SECONDS. DRAIN AND REPEAT. OFFER FOR
RECYCLING IF AVAILABLE OR PUNCTURE AND DISPOSE IN A SANITARY LANDFILL,
OR BY OTHER PROCEDURES APPROVED BY STATE AND LOCAL AUTHORITIES.
| 14. TRANSPORT INFORMATION | |
DOT (DEPARTMENT OF TRANSPORTATION):
PROPER SHIPPING NAME: DISINFECTANT, LIQUID, CORROSIVE N.O.S.
TECHNICAL NAME: QUATERNARY AMMONIUM COMPOUNDS
PRIMARY HAZARD CLASS/DIVISION: 8
UN/NA NUMBER: 1903
PACKING GROUP: III
PLACARDS: CORROSIVE
LABEL: CORROSIVE
OTHER SHIPPING INFORMATION:
CERTAIN SHIPPING MODES AND PACKAGING SIZES MAY HAVE EXCEPTIONS FROM THE
TRANSPORT REGULATIONS. THE CLASSIFICATIONS/INFORMATION PROVIDED ABOVE MAY
NOT REFLECT APPLICABLE EXCEPTIONS. CONTACT THE MANUFACTURER FOR MORE
SPECIFIC INFORMATION ON THE PROPER SHIPPING OF THIS MATERIAL.
SPECIAL SHIPPING NOTES:
QUANTITIES LESS THAN OR EQUAL TO ONE (1) GALLON = LIMITED QUANTITY NOT
REGULATED.
AIR (ICAO/IATA):
SHIPPING NAME: DISINFECTANT, LIQUID, CORROSIVE N.O.S.
TECHNICAL NAME: QUATERNARY AMMONIUM COMPOUNDS
UN/NA NUMBER: 1903
PRIMARY HAZARD CLASS/DIVISION: 8
PACKING GROUP: III
PLACARDS: CORROSIVE
LABEL: CORROSIVE
NOTE:
CERTAIN SHIPPING MODES AND PACKAGING SIZES MAY HAVE EXCEPTIONS FROM THE
TRANSPORT REGULATIONS. THE CLASSIFICATIONS/INFORMATION PROVIDED ABOVE MAY
NOT REFLECT APPLICABLE EXCEPTIONS. CONTACT THE MANUFACTURER FOR MORE
SPECIFIC INFORMATION ON THE PROPER SHIPPING OF THIS MATERIAL.
VESSEL (IMO/IMDG):
SHIPPING NAME: DISINFECTANT, LIQUID, CORROSIVE N.O.S.
TECHNICAL NAME: QUATERNARY AMMONIUM COMPOUNDS
UN/NA NUMBER: 1903
PRIMARY HAZARD CLASS/DIVISION: 8
PACKING GROUP: III
MARINE POLLUTANT #1: YES
PLACARDS: CORROSIVE
LABEL: CORROSIVE, MARINE POLLUTANT
CANADA TRANSPORT OF DANGEROUS GOODS:
SHIPPING NAME: DISINFECTANT, LIQUID, CORROSIVE N.O.S.
TECHNICAL NAME: QUATERNARY AMMONIUM COMPOUNDS
UN/NA NUMBER: 1903
PRIMARY HAZARD CLASS/DIVISION: 8
PACKING GROUP: III
LABEL: CORROSIVE
| 15. REGULATORY INFORMATION | |
UNITED STATES:
DOT LABEL SYMBOL AND HAZARD CLASSIFICATION:
LIMITED QUANTITY GROUND
CORROSIVE
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT):
311/312 HEALTH HAZARDS: HEALTH - ACUTE
311/312 PHYSICAL HAZARDS: NOT YET DETERMINED
313 REPORTABLE INGREDIENTS: NO LISTED SUBSTANCE
302/304 EMERGENCY PLANNING:
EMERGENCY PLAN: NO LISTED SUBSTANCE
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT):
CERCLA REGULATORY: NOT ESTABLISHED
TSCA (TOXIC SUBSTANCE CONTROL ACT):
TSCA REGULATORY: ALL INGREDIENTS ARE LISTED ON THE TSCA CHEMICAL INVENTORY.
CLEAN AIR ACT:
40 CFR PART 68-RISK MANAGEMENT FOR CHEMICAL ACCIDENT RELEASE PREVENTION:
NO LISTED SUBSTANCE
CLEAN AIR ACT (HAZARDOUS AIR POLLUTANTS): NO LISTED SUBSTANCE
STATES WITH SPECIAL REQUIREMENTS:
CHEMICAL NAME REQUIREMENTS
SODIUM SILICATE PENNSYLVANIA RIGHT TO KNOW SUBSTANCE
NEW JERSEY RIGHT TO KNOW SUBSTANCE
REGULATIONS:
STATE REGULATIONS:
STATE REGULATIONS REQUIRE THIS PRODUCT TO BE REGISTERED AS A PESTICIDE WHEN
SOLD WITHIN THE STATE. CONSULT INDIVIDUAL STATE REGULATIONS ON PESTICIDE
REGISTRATION FOR MORE DETAILS.
CALIFORNIA PROPOSITION 65: NO LISTED SUBSTANCE
RCRA STATUS: NOT ESTABLISHED
CLEAN WATER ACT: NO LISTED SUBSTANCE
CARCINOGEN: NO LISTED SUBSTANCE
FIFRA (FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT): REGULATED
| 16. OTHER INFORMATION | |
DATE PREPARED: 09/11/2019
HMIS RATING:
HEALTH 3
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION D
NFPA CODES:
3
0
0
MANUFACTURER DISCLAIMER:
THIS COMPANY CANNOT ANTICIPATE ALL CONDITIONS OF HANDLING AND USE OF THIS
PRODUCT. THEREFORE, THIS COMPANY ACCEPTS NO RESPONSIBILITY FOR RESULTS
OBTAINED BY THE APPLICATION OF THIS INFORMATION, OR THE SAFETY AND
SUITABILITY OF THE PRODUCT EITHER ALONE OR IN COMBINATION WITH OTHER
PRODUCTS. IT IS THE RESPONSIBILITY OF THE EMPLOYER AND/OR USER TO PROVIDE
A SAFE WORKPLACE, USING HEALTH AND SAFETY INFORMATION CONTAINED HEREIN AS
A GUIDE. THIS COMPANY WILL ACCEPT NO LIABILITY FOR DAMAGES OR LOSSES
INCURRED FROM THE IMPROPER HANDLING AND USE OF THIS PRODUCT.