| Common Name: | FLEX SEAL BLACK |
| Manufacturer: | SWIFT RESPONSE |
| SDS Revision Date: | 9/24/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 515Z14, 55KE45, 61TJ30 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT NUMBER: 1000012974
PRODUCT IDENTIFIER: FLEX SEAL BLACK
COMPANY INFORMATION:
SWIFT RESPONSE, LLC
2690 WESTON RD.
WESTON, FL 33331
UNITED STATES
COMPANY PHONE:
GENERAL ASSISTANCE: 1-800-307-6201
EMERGENCY TELEPHONE US: 1-800-424-9300
EMERGENCY TELEPHONE OUTSIDE:
US: 1-703-527-3887
VERSION #: 01
RECOMMENDED USE: NOT AVAILABLE.
RECOMMENDED RESTRICTIONS: NONE KNOWN.
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE AEROSOLS: CATEGORY 1
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
GERM CELL MUTAGENICITY: CATEGORY 1B
CARCINOGENICITY: CATEGORY 1B
REPRODUCTIVE TOXICITY (THE UNBORN CHILD): CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE: CATEGORY 2
ASPIRATION HAZARD: CATEGORY 1
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
GAS CYLINDER
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE AEROSOL. MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE
DROWSINESS OR DIZZINESS. MAY CAUSE GENETIC DEFECTS. MAY CAUSE CANCER.
SUSPECTED OF DAMAGING THE UNBORN CHILD. MAY CAUSE DAMAGE TO ORGANS THROUGH
PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENT:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN
FLAMES/HOT SURFACES. - NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR OTHER
IGNITION SOURCE.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT BREATHE MIST OR VAPOR. WASH
THOROUGHLY AFTER HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER/DOCTOR.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. CALL A POISON CENTER/DOCTOR IF YOU FEEL
UNWELL. SPECIFIC TREATMENT (SEE THIS LABEL). DO NOT INDUCE VOMITING.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE REUSE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC):
STATIC ACCUMULATING FLAMMABLE LIQUID CAN BECOME ELECTROSTATICALLY CHARGED
EVEN IN BONDED AND GROUNDED EQUIPMENT. SPARKS MAY IGNITE LIQUID AND VAPOR.
MAY CAUSE FLASH FIRE OR EXPLOSION.
SUPPLEMENTAL INFORMATION: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
DISTILLATES (PETROLEUM), 68410-97-9 20 - 40
LIGHT DISTILLATE
HYDROTREATING PROCESS,
LOW-BOILING
TOLUENE 108-88-3 20 - 40
BUTANE 106-97-8 10 - 20
ODORLESS MINERAL SPIRITS 64741-65-7 10 - 20
PROPANE 74-98-6 2.5 - 10
OTHER COMPONENTS BELOW 20 - 40
REPORTABLE LEVELS
*DESIGNATES THAT A SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF
COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OCCURS:
GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION:
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. RINSE MOUTH. DO NOT
INDUCE VOMITING. IF VOMITING OCCURS, KEEP HEAD LOW SO THAT STOMACH CONTENT
DOESN'T GET INTO THE LUNGS.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. IRRITATION
OF NOSE AND THROAT. ASPIRATION MAY CAUSE PULMONARY EDEMA AND PNEUMONITIS.
SEVERE EYE IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS,
SWELLING, AND BLURRED VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN.
PROLONGED EXPOSURE MAY CAUSE CHRONIC EFFECTS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW
THE LABEL WHERE POSSIBLE). ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE
MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW THIS
SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
ALCOHOL RESISTANT FOAM. WATER FOG. CARBON DIOXIDE (CO2). DRY CHEMICAL
POWDER, CARBON DIOXIDE, SAND OR EARTH MAY BE USED FOR SMALL FIRES ONLY.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY EXPLODE WHEN EXPOSED TO
HEAT OR FLAME. THIS PRODUCT IS A POOR CONDUCTOR OF ELECTRICITY AND CAN
BECOME ELECTROSTATICALLY CHARGED. IF SUFFICIENT CHARGE IS ACCUMULATED,
IGNITION OF FLAMMABLE MIXTURES CAN OCCUR. TO REDUCE POTENTIAL FOR STATIC
DISCHARGE, USE PROPER BONDING AND GROUNDING PROCEDURES. THIS LIQUID MAY
ACCUMULATE STATIC ELECTRICITY WHEN FILLING PROPERLY GROUNDED CONTAINERS.
STATIC ELECTRICITY ACCUMULATION MAY BE SIGNIFICANTLY INCREASED BY THE
PRESENCE OF SMALL QUANTITIES OF WATER OR OTHER CONTAMINANTS. MATERIAL WILL
FLOAT AND MAY IGNITE ON SURFACE OF WATER.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
FIREFIGHTERS MUST USE STANDARD PROTECTIVE EQUIPMENT INCLUDING FLAME
RETARDANT COAT, HELMET WITH FACE SHIELD, GLOVES, RUBBER BOOTS, AND IN
ENCLOSED SPACES, SCBA.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT RISK. CONTAINERS
SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE BUILD UP. FOR MASSIVE
FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER OR MONITOR NOZZLES, IF
POSSIBLE. IF NOT, WITHDRAW AND LET FIRE BURN OUT.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT
RISK. IN THE EVENT OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
GENERAL FIRE HAZARDS: EXTREMELY FLAMMABLE AEROSOL.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. REMOVE ALL POSSIBLE SOURCES OF IGNITION
IN THE SURROUNDING AREA. WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING
DURING CLEAN-UP. DO NOT BREATHE MIST OR VAPOR. DO NOT TOUCH DAMAGED
CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE
CLOTHING. VENTILATE CLOSED SPACES BEFORE ENTERING THEM. USE APPROPRIATE
CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION. TRANSFER BY MECHANICAL
MEANS SUCH AS VACUUM TRUCK TO A SALVAGE TANK OR OTHER SUITABLE CONTAINER
FOR RECOVERY OR SAFE DISPOSAL. LOCAL AUTHORITIES SHOULD BE ADVISED IF
SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE
SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
REFER TO ATTACHED SAFETY DATA SHEETS AND/OR INSTRUCTIONS FOR USE. ELIMINATE
ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN IMMEDIATE
AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED
MATERIAL. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. MOVE THE CYLINDER TO A
SAFE AND OPEN AREA IF THE LEAK IS IRREPARABLE. USE WATER SPRAY TO REDUCE
VAPORS OR DIVERT VAPOR CLOUD DRIFT. COVER WITH PLASTIC SHEET TO PREVENT
SPREADING. ABSORB IN VERMICULITE, DRY SAND OR EARTH AND PLACE INTO
CONTAINERS. PREVENT ENTRY INTO WATERWAYS, SEWER, BASEMENTS OR CONFINED
AREAS. FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH WATER.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. FOR WASTE DISPOSAL, SEE
SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND. USE
APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. MINIMIZE FIRE RISKS FROM
FLAMMABLE AND COMBUSTIBLE MATERIALS (INCLUDING COMBUSTIBLE DUST AND STATIC
ACCUMULATING LIQUIDS) OR DANGEROUS REACTIONS WITH INCOMPATIBLE MATERIALS.
HANDLING OPERATIONS THAT CAN PROMOTE ACCUMULATION OF STATIC CHARGES INCLUDE
BUT ARE NOT LIMITED TO: MIXING, FILTERING, PUMPING AT HIGH FLOW RATES,
SPLASH FILLING, CREATING MISTS OR SPRAYS, TANK AND CONTAINER FILLING, TANK
CLEANING, SAMPLING, GAUGING, SWITCH LOADING, VACUUM TRUCK OPERATIONS.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT USE IF SPRAY BUTTON IS
MISSING OR DEFECTIVE. DO NOT SPRAY ON A NAKED FLAME OR ANY OTHER
INCANDESCENT MATERIAL. DO NOT SMOKE WHILE USING OR UNTIL SPRAYED SURFACE IS
THOROUGHLY DRY. DO NOT CUT, WELD, SOLDER, DRILL, GRIND, OR EXPOSE
CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. ALL
EQUIPMENT USED WHEN HANDLING THE PRODUCT MUST BE GROUNDED. DO NOT RE-USE
EMPTY CONTAINERS. DO NOT BREATHE MIST OR VAPOR. AVOID CONTACT WITH EYES,
SKIN, AND CLOTHING. USE ONLY IN WELL-VENTILATED AREAS. SHOULD BE HANDLED IN
CLOSED SYSTEMS, IF POSSIBLE. PREGNANT OR BREASTFEEDING WOMEN MUST NOT
HANDLE THIS PRODUCT. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. WASH
HANDS THOROUGHLY AFTER HANDLING. OBSERVE GOOD INDUSTRIAL HYGIENE
PRACTICES.
FOR ADDITIONAL INFORMATION ON EQUIPMENT BONDING AND GROUNDING, REFER TO THE
CANADIAN ELECTRICAL CODE IN CANADA, (CSA C22.1), OR THE AMERICAN PETROLEUM
INSTITUTE (API) RECOMMENDED PRACTICE 2003, "PROTECTION AGAINST IGNITIONS
ARISING OUT OF STATIC, LIGHTNING, AND STRAY CURRENTS" OR NATIONAL FIRE
PROTECTION ASSOCIATION (NFPA) 77, "RECOMMENDED PRACTICE ON STATIC
ELECTRICITY" OR NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) 70, "NATIONAL
ELECTRICAL CODE".
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
LEVEL 3 AEROSOL.
STORE LOCKED UP. PRESSURIZED CONTAINER. PROTECT FROM SUNLIGHT AND DO NOT
EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. DO NOT PUNCTURE,
INCINERATE OR CRUSH. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR
OTHER SOURCES OF IGNITION. THIS MATERIAL CAN ACCUMULATE STATIC CHARGE WHICH
MAY CAUSE SPARK AND BECOME AN IGNITION SOURCE. AVOID SPARK PROMOTERS.
GROUND/BOND CONTAINER AND EQUIPMENT. THESE ALONE MAY BE INSUFFICIENT TO
REMOVE STATIC ELECTRICITY. REFRIGERATION RECOMMENDED. STORE AWAY FROM
INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
PROPANE (CAS 74-98-6) PEL 1800 MG/M3
1000 PPM
US. OSHA TABLE Z-2 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
TOLUENE (CAS 108-88-3) CEILING 300 PPM
TWA 200 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
BUTANE (CAS 106-97-8) STEL 1000 PPM
TOLUENE (CAS 108-88-3) TWA 20 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
BUTANE (CAS 106-97-8) TWA 1900 MG/M3
800 PPM
PROPANE (CAS 74-98-6) TWA 1800 MG/M3
1000 PPM
TOLUENE (CAS 108-88-3) STEL 560 MG/M3
150 PPM
TWA 375 MG/M3
100 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING
TIME
TOLUENE (CAS 108-88-3) 0.3 MG/G O-CRESOL, WITH CREATININE *
HYDROLYSIS IN URINE
0.03 MG/L TOLUENE URINE *
0.02 MG/L TOLUENE BLOOD *
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
EXPOSURE GUIDELINES:
US - CALIFORNIA OELS: SKIN DESIGNATION
TOLUENE (CAS 108-88-3): CAN BE ABSORBED THROUGH THE SKIN.
US - MINNESOTA HAZ SUBS: SKIN DESIGNATION APPLIES
TOLUENE (CAS 108-88-3): SKIN DESIGNATION APPLIES.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE, USE
PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL. EYE WASH FACILITIES AND EMERGENCY SHOWER MUST BE
AVAILABLE WHEN HANDLING THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
CHEMICAL RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE AND FULL FACEPIECE.
HAND PROTECTION: WEAR APPROPRIATE CHEMICAL RESISTANT GLOVES.
SKIN PROTECTION:
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON IS
RECOMMENDED.
SKIN PROTECTION:
RESPIRATORY PROTECTION:
CHEMICAL RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE AND FULL FACEPIECE.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING, DO NOT EAT, DRINK OR SMOKE. ALWAYS OBSERVE GOOD PERSONAL
HYGIENE MEASURES, SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE
EATING, DRINKING, AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND
PROTECTIVE EQUIPMENT TO REMOVE CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: AEROSOL.
COLOR: NOT AVAILABLE.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE.
FLASH POINT: -156.0 DEG. F (-104.4 DEG. C) PROPELLANT ESTIMATED
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 1% ESTIMATED
FLAMMABILITY LIMIT - UPPER (%): 7% ESTIMATED
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: 40 PSIG @70F ESTIMATED
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES):
SOLUBILITY (WATER): NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
OTHER INFORMATION:
SPECIFIC GRAVITY: 0.792 ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID:
AVOID TEMPERATURES EXCEEDING THE FLASH POINT. CONTACT WITH INCOMPATIBLE
MATERIALS.
INCOMPATIBLE MATERIALS:
ACIDS. STRONG OXIDIZING AGENTS. NITRATES. FLUORINE. CHLORINE.
HAZARDOUS DECOMPOSITION PRODUCTS:
NO HAZARDOUS DECOMPOSITION PRODUCTS ARE KNOWN.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION:
DROPLETS OF THE PRODUCT ASPIRATED INTO THE LUNGS THROUGH INGESTION OR
VOMITING MAY CAUSE A SERIOUS CHEMICAL PNEUMONIA.
INHALATION:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE BY
INHALATION. MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING.
SKIN CONTACT: CAUSES SKIN IRRITATION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. IRRITATION
OF NOSE AND THROAT. ASPIRATION MAY CAUSE PULMONARY EDEMA AND PNEUMONITIS.
SEVERE EYE IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS,
SWELLING, AND BLURRED VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. NARCOTIC EFFECTS.
COMPONENTS SPECIES TEST RESULTS
BUTANE (CAS 106-97-8):
ACUTE:
INHALATION:
LC50 MOUSE 1237 MG/L, 120 MINUTES
52%, 120 MINUTES
RAT 1355 MG/L
DISTILLATES (PETROLEUM), LIGHT DISTILLATE HYDROTREATING PROCESS,
LOW-BOILING (CAS 68410-97-9):
ACUTE:
DERMAL:
LD50 RABBIT >1900 MG/KG, 24 HOURS
INHALATION:
LC50 RAT >5020 MG/M3, 4 HOURS
>4980 MG/M3
>4980 MG/M3, 4 HOURS
>4.96 MG/L, 4 HOURS
ORAL:
LD50 RAT 4820 MG/KG
PROPANE (CAS 74-98-6):
ACUTE:
INHALATION:
LC50 MOUSE 1237 MG/L, 120 MINUTES
52%, 120 MINUTES
RAT 1355 MG/L
658 MG/L/4H
TOLUENE (CAS 108-88-3):
ACUTE:
DERMAL:
LD50 RABBIT >5000 MG/KG, 24 HOURS
INHALATION:
LC50 MOUSE 6405 - 7436 PPM, 6 HOURS
5320 PPM, 8 HOURS
RAT 5879 - 6281 PPM, 6 HOURS
12.5 - 28.8 MG/L, 4 HOURS
ORAL:
LD50 RAT 5000 MG/KG
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT AVAILABLE.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY: MAY CAUSE GENETIC DEFECTS.
CARCINOGENICITY: MAY CAUSE CANCER.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
TOLUENE (CAS 108-88-3):
3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING THE UNBORN CHILD.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS AND DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CHRONIC EFFECTS:
PROLONGED EXPOSURE MAY CAUSE CHRONIC EFFECTS. MAY CAUSE DAMAGE TO ORGANS
THROUGH PROLONGED OR REPEATED EXPOSURE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT CLASSIFIED AS ENVIRONMENTALLY HAZARDOUS. HOWEVER, THIS
DOES NOT EXCLUDE THE POSSIBILITY THAT LARGE OR FREQUENT SPILLS CAN HAVE A
HARMFUL OR DAMAGING EFFECT ON THE ENVIRONMENT.
COMPONENTS SPECIES TEST RESULTS
ODORLESS MINERAL SPIRITS (CAS 64741-65-7):
AQUATIC:
ALGAE IC50 ALGAE 30000 MG/L, 72 HOURS
TOLUENE (CAS 108-88-3):
AQUATIC:
ALGAE IC50 ALGAE 433.0001 MG/L, 72 HOURS
CRUSTACEA EC50 DAPHNIA 7.645 MG/L, 48 HOURS
WATER FLEA 5.46 - 9.83 MG/L, 48 HOURS
(DAPHNIA MAGNA)
FISH LC50 COHO SALMON, 8.11 MG/L, 96 HOURS
SILVER SALMON
(ONCORHYNCHUS
KISUTCH)
*ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT SHOWN.
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
BUTANE: 2.89
PROPANE: 2.36
TOLUENE: 2.73
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE OR
CRUSH. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
US RCRA HAZARDOUS WASTE U LIST: REFERENCE
TOLUENE (CAS 108-88-3): U220
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT
RESIDUE, FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED. DO NOT
RE-USE EMPTY CONTAINERS.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME:
AEROSOLS, FLAMMABLE, (EACH NOT EXCEEDING 1 L CAPACITY)
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): 2.1
PACKING GROUP: NOT APPLICABLE.
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: N82
PACKAGING EXCEPTIONS: 306
PACKAGING NON BULK: NONE
PACKAGING BULK: NONE
THIS PRODUCT MEETS THE EXCEPTION REQUIREMENTS OF SECTION 173.306 AS A
LIMITED QUANTITY AND MAY BE SHIPPED AS A LIMITED QUANTITY. UNTIL
12/31/2020, THE "CONSUMER COMMODITY - ORM-D" MARKING MAY STILL BE USED IN
PLACE OF THE NEW LIMITED QUANTITY DIAMOND MARK FOR PACKAGES OF UN 1950
AEROSOLS. LIMITED QUANTITIES REQUIRE THE LIMITED QUANTITY DIAMOND MARK ON
CARTONS AFTER 12/31/20 AND MAY BE USED NOW IN PLACE OF THE "CONSUMER
COMMODITY ORM-D" MARKING AND BOTH MAY BE DISPLAYED CONCURRENTLY.
IATA:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): 2.1
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS: YES
ERG CODE: 10L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED.
CARGO AIRCRAFT ONLY: ALLOWED.
PACKAGING EXCEPTIONS: LTD QTY
IMDG:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): NONE
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: YES
EMS: F-D, S-U
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
PACKAGING EXCEPTIONS: LTD QTY
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT APPLICABLE.
DOT: FLAMMABLE GAS, CLASS/DIVISION 2.1
IATA; IMDG: CLASS 2.1, FLAMMABLE GASES
MARINE POLLUTANT: ENVIRONMENT
GENERAL INFORMATION: IMDG REGULATED MARINE POLLUTANT.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
ALL COMPONENTS ARE ON THE U.S. EPA TSCA INVENTORY LIST.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
TOLUENE (CAS 108-88-3): LISTED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: YES
REACTIVITY HAZARD: NO
PRESSURE HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 311/312 HAZARDOUS CHEMICAL: NO
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
TOLUENE 108-88-3 20 - 40
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
TOLUENE (CAS 108-88-3)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION (40 CFR
68.130):
BUTANE (CAS 106-97-8)
PROPANE (CAS 74-98-6)
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 2, ESSENTIAL CHEMICALS (21 CFR
1310.02(B) AND 1310.04(F)(2) AND CHEMICAL CODE NUMBER:
TOLUENE (CAS 108-88-3): 6594
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 1 & 2 EXEMPT CHEMICAL MIXTURES
(21 CFR 1310.12(C)):
TOLUENE (CAS 108-88-3): 35%WV
DEA EXEMPT CHEMICAL MIXTURES CODE NUMBER:
TOLUENE (CAS 108-88-3): 594
US STATE REGULATIONS:
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
BUTANE (CAS 106-97-8)
PROPANE (CAS 74-98-6)
TOLUENE (CAS 108-88-3)
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
BUTANE (CAS 106-97-8)
PROPANE (CAS 74-98-6)
TOLUENE (CAS 108-88-3)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
BUTANE (CAS 106-97-8)
PROPANE (CAS 74-98-6)
TOLUENE (CAS 108-88-3)
US. RHODE ISLAND RTK:
BUTANE (CAS 106-97-8)
PROPANE (CAS 74-98-6)
TOLUENE (CAS 108-88-3)
US. CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/DEVELOPMENTAL TOXIN
TOLUENE (CAS 108-88-3):
LISTED: JANUARY 1, 1991
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/FEMALE REPRODUCTIVE TOXIN
TOLUENE (CAS 108-88-3):
LISTED: AUGUST 7, 2009
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR INVENTORY NAME ON INVENTORY
REGION (YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL NO
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) NO
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) YES
CHINA INVENTORY OF EXISTING CHEMICAL NO
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING NO
COMMERCIAL CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW NO
CHEMICAL SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) NO
NEW ZEALAND NEW ZEALAND INVENTORY NO
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS NO
AND CHEMICAL SUBSTANCES (PICCS)
UNITED STATES TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
& PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 09-24-2015
VERSION #: 01
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.
PRODUCT NAME: FLEX SEAL BLACK
PRODUCT #: 1000012974
SDS US