| Common Name: | LITHIUM-ION BATTERY, INR10440 |
| Manufacturer: | CHENZHOU GRAND-PRO TECH CHINA |
| SDS Revision Date: | 2/10/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 453A18, 55MJ33 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFICATION: LITHIUM-ION BATTERY
COMMERCIAL PRODUCT NAME: INR10440
NOMINAL VOLTAGE: 3.7V
NOMINAL CAPACITY: 350MAH
WH RATING: 1.295WH[LSLP]
REVISION: 1.0
MANUFACTURERS: CHENZHOU GRAND-PRO TECH CO., LTD
ADDRESS:
THE INTERSECTION OF SHIHU AVE. AND LINJING 2ND RD
BAILUTANG TOWN, SUXAIN
DISTRICT, CHENZHOU, HUNAN
CHINA
THE PERIOD OF VALIDITY: AT THE END OF 2018
E-MAIL: GRAND-PRO@GRAND-PRO.CN
TEL: (86)735-2668188
FAX: (86)735-2668799
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS NOT CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200)THIS PRODUCT IS AN ARTICLE WHICH
IS A SEALED BATTERY AND AS SUCH DOES NOT REQUIRE AN MSDS PER THE OSHA
HAZARD COMMUNICATION STANDARD UNLESS RUPTURED. THE HAZARDS INDICATED ARE
FOR A RUPTURED BATTERY.
ACUTE TOXICITY-ORAL: CATEGORY 4
ACUTE TOXICITY-INHALATION(GASES): CATEGORY 4
ACUTE TOXICITY-INHALATION(DUSTS/MISTS): CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
REPRODUCTIVE TOXICITY: CATEGORY 1B
SPECIFIC TARGET ORGAN TOXICITY(REPEATED EXPOSURE): CATEGORY 2
EXCLAMATION MARK
HEALTH HAZARD
EMERGENCY OVERVIEW (INCLUDING SIGNS AND SYMPTOMS, ROUTE(S) OF ENTRY, ETC.)
INTACT BATTERIES PRESENT NO SPECIFIC HAZARDS.
ACUTE HEALTH HAZARDS (E.G., INHALATION, EYE CONTACT, SKIN CONTACT,
INGESTION, ETC.):
BURNING BATTERIES:
AVOID INHALATION OF TOXIC FUMES. BURNING BATTERIES EMIT TOXIC FUMES, WHICH
ARE IRRITATING TO THE LUNGS.
LEAKING BATTERIES:
AVOID EXPOSURE TO LEAKING ELECTROLYTE, IT CAN CAUSE SEVERE IRRITATION
AND/OR DAMAGE TO THE SKIN, MUCOUS MEMBRANE OR EYES.
CHRONIC HEALTH EFFECTS (E.G., CARCINOGENICITY, TERATOLOGY, REPRODUCTION,
MUTAGENICITY, ETC.):
COBALT: SUSPECTED HUMAN CARCINOGENIC AGENT.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: NONE.
HAZARDS NOT OTHERWISE CLASSIFIED(HNOC): NOT APPLICABLE
UNKNOWN TOXICITY:
1.7% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY.
OTHER INFORMATION: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
INTERACTIONS WITH OTHER CHEMICALS:
USE OF ALCOHOLIC BEVERAGES MAY ENHANCE TOXIC EFFECTS.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENTS APPROXIMATE W/W CAS NUMBER
LITHIUM COBALT OXIDE (LiCoO2) 30-33 12190-79-3
CARBON (GRAPHITE) 15-20 7440-11-0
LINEAR AND CYCLIC CARBONIC SOLVENTS 5-15 N/A
ELECTROLYTE (LiPF6/EC/DMC/EMC) 1-3 21324-40-3/
96-49-1/
616-38-6/
623-53-0
ALUMINUM 2-8 7429-90-5
COPPER 5-10 7440-50-8
HEXAFLUOROPROPYLENE-VINYLIDINE-FLUORIDE COP 1-3 9011-17-0
PP/PE/PET 0.1-4
STEEL, NICKEL AND INERT POLYMER 0.5-4 N/A
CARBON BLACK AND OTHERS 0-3 N/A
| 4. FIRST-AID MEASURES | |
INGESTION: IF SWALLOWED, OBTAIN MEDICAL ATTENTION IMMEDIATELY.
INHALATION:
IF BATTERY IS BURNING, LEAVE THE AREA IMMEDIATELY. IF EXPOSED TO FUMES,
SEEK MEDICAL ATTENTION PROMPTLY.
EYE CONTACT:
RINSE EYES WITH WATER FOR 15 MINUTES AND SEEK MEDICAL ATTENTION.
SKIN CONTACT:
IF BATTERY ELECTROLYTE LEAKS ON TO THE SKIN FLUSH THE AFFECTED AREA FOR AT
LEAST 15 MINUTES WITH CLEAN WATER. DO NOT ATTEMPT TO NEUTRALIZE. SEEK
MEDICAL ATTENTION PROMPTLY.
NGESTION:
DRINK MILK/WATER AND INDUCE VOMITING; SEEK MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
FLAMMABLE PROPERTIES: N/A
FLASHPOINT:
METHOD:
AUTOIGNITION TEMPERATURE:
FLAMMABLE LIMITS: N/A
LOWER FLAMMABLE LIMIT:
UPPER FLAMMABLE LIMIT:
HAZARDOUS COMBUSTION PRODUCTS:
BURNING BATTERIES MAY EMIT ACRID SMOKE IRRITATING FUMES, AND TOXIC FUMES
OF FLUORIDE.
EXTINGUISHING MEDIA:
CARBON DIOXIDE (CO2) OR DRY CHEMICAL FIRE EXTINGUISHER, 10-B: C.
FIRE FIGHTING INSTRUCTIONS:
PERSONNEL:
FIGHT THE FIRE IN A DEFENSIVE MODE, WHILE EXITING THE AREA. WHEN USING A
CO2 FIRE EXTINGUISHER, DO NOT RE-ENTER THE AREA UNTIL IT HAS BEEN
THOROUGHLY VENTILATED (I.E., PURGED) OF THE CO2 EXTINGUISHING AGENT.
FIREFIGHTERS: USE A SELF-CONTAINED BREATHING APPARATUS (SCBA).
| 6. ACCIDENTAL RELEASE MEASURES | |
SMALL SPILL:
IF BATTERIES SHOW SIGNS OF LEAKING, AVOID SKIN OR EYE CONTACT WITH THE
MATERIAL LEAKING FROM THE BATTERY. USE CHEMICAL RESISTANT RUBBER GLOVES
AND NON-FLAMMABLE ABSORBENT MATERIALS FOR CLEAN-UP.
ON LAND:
PLACE MATERIAL INTO SUITABLE CONTAINERS AND CALL LOCAL FIRE/POLICE
DEPARTMENT.
IN WATER:
IF POSSIBLE, REMOVE FROM WATER AND CALL LOCAL FIRE/POLICE DEPARTMENT.
| 7. HANDLING AND STORAGE | |
HANDLING:
RECHARGE BATTERIES IAW METHODS SPECIFIED IN APPLICABLE TECHNICAL MANUALS.
DO NOT:
( )OVERCHARGE THIS BATTERY.
( )ABUSE, MUTILATE OR SHORT CIRCUIT THE BATTERY.
STORAGE:
GAIN APPROVAL FOR STORAGE AREAS FROM THE INSTALLATION FIRE DEPARTMENT.
STORE BATTERIES IN A COOL (I.E., 130F), DRY AND WELL VENTILATED AREA.
DO NOT:
( )( )STORE BATTERIES IN DIRECT SUNLIGHT OR UNDER HOT CONDITIONS.
( )( )SMOKE AND KEEP BATTERIES AWAY FROM OPEN FLAME OR HEAT.
( )( )STORE BATTERIES IN THE SAME STACKS WITH HAZARDOUS MATERIALS.
( )( )STORE BATTERIES IN OFFICE AREAS, OR OTHER AREAS WHERE PERSONNEL
CONGREGATE.
WORK/HYGIENIC PRACTICES:
THOROUGHLY WASH HANDS AFTER CLEANING-UP A BATTERY SPILL (I.E., LEAKING OR
VENTING BATTERIES). NO EATING, DRINKING OR SMOKING IN BATTERY STORAGE
AREAS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
ENGINEERING CONTROLS:
KEEP AWAY FROM HEAT AND OPEN FLAME. STORE IN A COOL DRY PLACE.
PERSONAL PROTECTION:
RESPIRATOR:
NOT REQUIRED DURING NORMAL OPERATIONS. SCBA REQUIRED IN THE EVENT OF A
FIRE.
EYE/FACE PROTECTION: NOT REQUIRED BEYOND SAFETY PRACTICES OF EMPLOYER.
GLOVES: NOT REQUIRED FOR HANDLING OF CELLS.
FOOT PROTECTION: STEEL TOED SHOES RECOMMENDED FOR LARGE CONTAINER HANDLING.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
BOILING POINT @ 760 MMHg (DEG. C): NA
VAPOR PRESSURE (MMHg @ 25 DEG. C): NA
VAPOR DENSITY (AIR = 1): NA
DENSITY (GRAMS/CC): NA
PERCENT VOLATILE BY VOLUME (%): NA
EVAPORATION RATE (BUTYL ACETATE = 1): NA
PHYSICAL STATE: NA
SOLUBILITY IN WATER (% BY WEIGHT): NA
PH: NA
APPEARANCE AND ODOR: GEOMETRIC SOLID OBJECT
| 10. STABILITY AND REACTIVITY | |
STABLE OR UNSTABLE: STABLE
INCOMPATIBILITY (MATERIALS TO AVOID): NA
HAZARDOUS DECOMPOSITION PRODUCTS: NA
DECOMPOSITION TEMPERATURE (0 DEG. F): NA
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
CONDITION TO AVOID: AVOID ELECTRICAL SHORTING
| 11. TOXICOLOGICAL INFORMATION | |
THIS PRODUCT DOES NOT ELICIT TOXICOLOGICAL PROPERTIES DURING ROUTINE
HANDLING AND USE.
SENSITIZATION: NO
TERATOGENICITY: NO
REPRODUCTIVE TOXICITY: NO
ACUTE TOXICITY: NO
THIS PRODUCT DOES NOT CONTAIN ANY KINDS OF THE FOLLOWING SUBSTANCES AND
HALOGEN-TYPE FLAME RETARDANTS INCLUDING CHLORINE AND BROMIDE TYPE HARMFUL
FLAME RETARDANTS WHICH ARE LISTED IN APPENDIX OF TCO DOCUMENTS AND
RELEVANT INTERNATIONAL ECO REQUIREMENTS:
POLYBROMATED BIPHENYLS (PBB)
POLYBROMATED BIPHENYL ETHERS (PBBE)
POLYBROMATED BIPHENYL OXIDES (PBBO)
POLYBROMATED DIPHENYLETHERS (PBDE)
POLYCHLORINATED BIPHENYL (PCB)
POLYCHLORONATED DIPHENYLETHERS (PCDE)
TETRABROMPHISPHENOL A (TBBPA)
ASBESTOS, ANTIMONYTRIOXIDE, DIOXINE
NONE OF THE FOLLOWING SUBSTANCES WILL BE EXPOSED, LEAKED, OR EMITTED DURING
TRANSPORTATION, STORAGE OR ANY OPERATION AND ANY TEMPERATURE CONDITION:
CHLORINATED FLUOROHYDROCARBON (FCKW)
ACRYLONITRIDE STYROL PHENOL BENZOL
MERCURY OF GREATER THAN 0.0001 WT% FOR ALKALINE BATTERY
MERCURY OF GREATER THAN 0.0005 WT% FOR OTHER BATTERY
LITHIUM CONTENT OF GREATER THAN 0.5G/BATTERY CELL CADMIUM, LEAD, AND OTHER
HARMFUL HEAVY METAL
THIS PRODUCT DOES NOT CONTAIN MERCURY AND LITHIUM-METAL.
MERCURY CONTENT: <
LITHIUM-ION CONTENT: <
IF THE CELLS ARE OPENED THROUGH MISUSE OR DAMAGE, DISCARD IMMEDIATELY.
INTERNAL COMPONENTS OF CELL ARE IRRITANTS AND SENSITIZERS.
| 12. ECOLOGICAL INFORMATION | |
SOME MATERIALS WITHIN THE CELL ARE BIOACCUMULATIVE. UNDER NORMAL
CONDITIONS, THESE MATERIALS ARE CONTAINED AND POSE NO RISK TO PERSONS
OR THE SURROUNDING ENVIRONMENT.
| 13. DISPOSAL CONSIDERATIONS | |
GRAND-PRO POLYMER LITHIUM ION RECHARGEABLE CELLS AND BATTERIES CONTAIN NO
TOXIC METALS, ONLY NATURALLY OCCURRING TRACE ELEMENTS. LITHIUM CELLS AND
BATTERIES ARE EXEMPTED FROM HAZARDOUS WASTE STANDARDS UNDER THE UNIVERSAL
WASTE REGULATIONS, THEREFORE, IT IS ADVISABLE TO CONSULT WITH LOCAL STATE
OR FEDERAL AUTHORITIES AS DISPOSAL REGULATIONS MAY VARY DEPENDENT ON
LOCATION.
| 14. TRANSPORT INFORMATION | |
FOR THE INTERNATIONAL TRANSPORT OF LITHIUM BATTERIES, THEY MUST COMPLY
WITH THESE REGULATIONS: THE INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG)
CODE BY INTERNATIONAL MARITIME ORGANIZATION (IMO), DANGEROUS GOODS
REGULATIONS (DGR) BY INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA) AND
TECHNICAL INSTRUCTIONS FOR THE SAFE TRANSPORT OF DANGEROUS GOODS BY AIR
(TI) BY INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO). THESE REGULATIONS
ARE BASED ON THE UN RECOMMENDATIONS ON THE TRANSPORT OF DANGEROUS GOODS,
MANUAL OF TESTS AND CRITERIA. LITHIUM BATTERIES WHICH MEET THE REQUIREMENTS
OF UN38.3 (UN MANUAL OF TESTS AND CRITERIA, PART III, SUBSECTION 38.3)
COULD BE TRANSPORTED BY AIR AND BY SEA AS ORDINARY GOODS, OTHERWISE SHOULD
BE TRANSPORTED ACCORDING TO CLASS 9, PACKING GROUP II HAZARDOUS GOODS. AS
THE PUBLISHED OF THE UN RECOMMENDATIONS ON THE TRANSPORT OF DANGEROUS
GOODS, ALL THESE REGULATIONS HAVE ADDED SOME NEW CONTENTS TO REGULATE THE
TRANSPORT OF LITHIUM ION BATTERIES. WE REGARD TO AIR TRANSPORT, THE
FOLLOWING REGULATIONS ARE CITED AND CONSIDERED:
1. FOR LITHIUM ION BATTERIES, UN ID NUMBER IS 3480 / TRANS PORT HAZARD
CLASS(ES): 9.
2. THE INTERNATIONAL AIR TRANSPORT ASSOCIATION(IATA) DANGEROUS GOODS
REGULATIONS (59TH EDITION 2018: COMPLIES WITH CURRENT IATA PACKING
INSTRUCTION OF PI965-967).
3. FOR TRANSPORTED BY AIR, LITHIUM-ION CELLS/BATTERIES SHIPPED AS "NOT
RESTRICTED" CARGO: MUST COMPLY WITH SECTION II OF PI965- PI967; FOR CELLS,
THE WATT-HOUR RATING SHOULD NOT BE MORE THAN 20WH; FOR BATTERIES, THE
WATT-HOUR RATING SHOULD NOT BE MORE THAN 100WH. WATT- HOUR RATING MUST BE
MARKED ON THE OUTSIDE OF THE BATTERY CASE (MARKED BY MANUFACTURER).
(EXCEPT THOSE MANUFACTURED BEFORE 1 JANUARY 2009, WHICH MAY BE TRANSPORTED
WITHOUT THIS MARKING UNTIL 31 DECEMBER 2014).
4. EACH CONSIGNMENT MUST BE ACCOMPANIED WITH A DOCUMENT SUCH AS AN AIR
WAYBILL WITH AN INDICATION. FOR THOSE LITHIUM ION CELLS/BATTERIES CONTAINED
IN EQUIPMENT, THE EQUIPMENT MUST BE EQUIPPED WITH AN EFFECTIVE MEANS OF
PREVENTING ACCIDENTAL ACTIVATION.
THE TELEPHONE NUMBER FOR ADDITIONAL INFORMATION FOR GRAND-PRO CELLS IS
+86-735-2668188.
5. QUANTITY PER PACKAGE SHALL NOT EXCEED 10KG.
6. EACH PACKAGE MUST BE CAPABLE OF WITHSTANDING A 1.2M DROP TEST IN ANY
ORIENTATION WITHOUT DAMAGE OF CELLS OR BATTERIES CONTAINED THEREIN.
7. LITHIUM BATTERIES WHICH MEET THE REQUIREMENTS OF A154 COULD BE
TRANSPORTED BY AIR, (A154 LITHIUM BATTERIES IDENTIFIED BY THE MANUFACTURER
AS BEING DEFECTIVE FOR SAFETY REASONS, OR THAT HAVE BEEN DAMAGED, THAT HAVE
THE POTENTIAL OF PRODUCING A DANGEROUS EVOLUTION OF HEAT, FIRE OR SHORT
CIRCUIT ARE FORBIDDEN FOR TRANSPORT.)
8. CELLS AND BATTERIES MUST BE PROTECTED SO AS TO PREVENT SHORT CIRCUITS.
THIS INCLUDES PROTECTION AGAINST CONTACT WITH CONDUCTIVE MATERIALS WITHIN
THE SAME PACKAGING THAT COULD LEAD TO SHORT CIRCUIT.
9. COMPLY WITH SP188 OF IMDG.
MODE OF TRANSPORT: TO AIR, SEA, RAILWAY, HIGHWAY-BASED.
MANUAL OF TEST AND CRITERIA (38.3 LITHIUM BATTERY) TEST RESULTS REMARK
NO. TEST ITEM
T1 ALTITUDE SIMULATION PASS
T2 THERMAL TEST PASS
T3 VIBRATION PASS
T4 SHOCK PASS
T5 EXTERNAL SHORT CIRCUIT PASS
T6 IMPACT PASS
T7 OVERCHARGE PASS FOR PACK
ONLY
T8 FORCED DISCHARGE PASS FOR PACK
ONLY
| 15. REGULATORY INFORMATION | |
NON-HAZARDOUS
| 16. OTHER INFORMATION | |
REVISION DATE: 2018-2-10
REVISION NOTE: NO INFORMATION AVAILABLE
DISCLAIMER:
THE INFORMATION ABOVE IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST
INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, GRAND-PRO MAKES NO WARRANTY
OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, WITH RESPECT
TO SUCH INFORMATION, AND WE ASSUME NO LIABILITY RESULTING FROM ITS USE.
USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY
OF THE INFORMATION FOR THEIR PARTICULAR PURPOSES. ALTHOUGH REASONABLE
PRECAUTIONS HAVE BEEN TAKEN IN THE PREPARATION OF THE DATA CONTAINED
HEREIN, IT IS OFFERED SOLELY FOR YOUR INFORMATION, CONSIDERATION. THIS
MATERIAL SAFETY DATA SHEET PROVIDES GUIDELINES FOR THE SAFE HANDLING AND
USE OF THIS PRODUCT, IT DOES NOT AND CANNOT ADVISE ON ALL POSSIBLE
SITUATIONS, THEREFORE, YOUR SPECIFIC USE OF THIS PRODUCT SHOULD BE
EVALUATED TO DETERMINE IF ADDITIONAL PRECAUTIONS ARE REQUIRED.
THE DATA/INFORMATION CONTAINED HEREIN HAS BEEN REVIEWED AND APPROVED FOR
GENERAL RELEASE ON THE BASIS THAT THIS DOCUMENT CONTAINS NO EXPORT
CONTROLLED INFORMATION.