| Common Name: | ICR18650-26J |
| Manufacturer: | SAMSUNG SDI KOREA |
| SDS Revision Date: | 1/1/2019 |
| SDS Format: | No Format Specified |
| Item Number(s): | 55MJ31, 55MJ34, 55MJ35, 55MJ36, 55MJ37, 55MJ43, 55MJ44, 55MJ46, 55MJ47, 55MJ48, 55MJ49, 55MJ50, 55MJ52, 55MJ59, 808ZM4 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAMSUNG
SAMSUNG SDI
SAMSUNG SDI CO., LTD.
DATE: JANUARY 1ST 2019
MODEL: ICR18650-26J
REVISION NO.: 01
SAFETY DATA SHEET
REGULATION:
IN ACCORDANCE WITH REGULATION (EU) 2015/830 (REACH), ANNEX II, AND OSHA
29 CFR 1910.1200
| SECTION I - IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
IMPORTANT NOTE:
AS A SOLID, MANUFACTURED ARTICLE, EXPOSURE TO HAZARDOUS INGREDIENTS IS NOT
EXPECTED WITH NORMAL USE. THIS BATTERY IS AN ARTICLE PURSUANT TO 29 CFR
1910.1200 AND, AS SUCH, IS NOT SUBJECT TO THE OSHA HAZARD COMMUNICATION
STANDARD REQUIREMENT. THE INFORMATION CONTAINED IN THIS SAFETY DATA SHEET
CONTAINS VALUABLE INFORMATION CRITICAL TO THE SAFE HANDLING AND PROPER USE
OF THE PRODUCT. THIS SDS SHOULD BE RETAINED AND AVAILABLE FOR EMPLOYEES AND
OTHER USERS OF THIS PRODUCT.
1.1 PRODUCT IDENTIFIER:
SUBSTANCE NAME: ICR18650-26J
SYNONYMS: LITHIUM-ION CELL
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
RELEVANT IDENTIFIED USES: LITHIUM-ION BATTERIES
USES ADVISED AGAINST: USE FOR RECOMMENDED USE ONLY
FURTHER INFORMATION: NOT AVAILABLE
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER: SAMSUNG SDI CO., LTD.
STREET ADDRESS/P.O. BOX:
150-20, GONGSE-RO, GIHEUNG-GU
YONGIN-SI, GYEONGGI-DO
KOREA
COUNTRY ID/POSTCODE/PLACE:
TELEPHONE NUMBER:
1-800-424-9300: US AND CANADA
1-703-527-3887: INTERNATIONAL
RESPONSIBLE DEPARTMENT: QUALITY TEAM
E-MAIL ADDRESS OF COMPETENT PERSON RESPONSIBLE FOR THE SDS: NOT AVAILABLE
NATIONAL CONTACT:
1-800-424-9300: US AND CANADA
1-703-527-3887: INTERNATIONAL
1.4 EMERGENCY TELEPHONE:
1-800-424-9300: US AND CANADA
1-703-527-3887: INTERNATIONAL
OPENING HOURS: NOT AVAILABLE
OTHER COMMENTS: NOT AVAILABLE
1.5 FURTHER INFORMATION:
BATTERY-SYSTEM: LITHIUM-ION (Li-ION)
NOMINAL VOLTAGE: 3.63 V
RATED CAPACITY: 2.600 AH
WH RATING: 9.438 WH
ANODE (NEGATIVE ELECTRODE): BASED ON INTERCALATION GRAPHITE
CATHODE (POSITIVE ELECTRODE): BASED ON LITHIATED METAL OXIDE (COBALT)
REMARK:
THE INFORMATION AND RECOMMENDATIONS SET FORTH ARE MADE IN GOOD FAITH AND
BELIEVED TO BE ACCURATE AS OF THE DATE OF PREPARATION.
SAMSUNG SDI CO. LTD. MAKES NO WARRANTY, EXPRESSED OR IMPLIED, WITH RESPECT
TO THIS INFORMATION AND DISCLAIMS ALL LIABILITIES FROM RELIANCE ON IT.
| SECTION II - HAZARDS IDENTIFICATION | |
THIS IS A PRODUCT THAT FULFILLS A CERTAIN FUNCTION IN SOLID STATE WITH
SPECIFIC SHAPE WITHOUT DISCHARGING ANY CHEMICAL SUBSTANCE IN ITS USE AND
HAS NO OBLIGATION TO WRITE (M)SDS. SINCE THIS DOCUMENT CONTAINS THE
PRECAUTIONS FOR SAFE HANDLING RELATED TO ITS MATERIALS OR CHEMICAL
SUBSTANCES CONSISTING OF THIS PRODUCT, PLEASE NOTE THAT THESE OVERALL
INFORMATION IS IRRELEVANT TO THIS PRODUCT.
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
2.1.1 CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP] AND
OSHA 29 CFR 1910.1200: NOT CLASSIFIED
2.1.2 ADDITIONAL INFORMATION:
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE.
PREPARATION HAZARDS AND CLASSIFICATION:
THE PRODUCT IS A LITHIUM ION CELL OR BATTERY AND IS THEREFORE CLASSIFIED AS
AN ARTICLE AND IS NOT HAZARDOUS WHEN USED ACCORDING TO THE RECOMMENDATIONS
OF THE MANUFACTURER. THE HAZARD IS ASSOCIATED WITH THE CONTENTS OF THE CELL
OR BATTERY. UNDER RECOMMENDED USE CONDITIONS, THE ELECTRODE MATERIALS AND
LIQUID ELECTROLYTE ARE NON-REACTIVE PROVIDED THAT THE CELL OR BATTERY
INTEGRITY REMAINS AND THE SEALS REMAIN INTACT. THE POTENTIAL FOR EXPOSURE
SHOULD NOT EXIST UNLESS THE CELL OR BATTERY LEAKS, IS EXPOSED TO HIGH
TEMPERATURES OR IS MECHANICALLY, ELECTRICALLY OR PHYSICALLY ABUSED/DAMAGED.
IF THE CELL OR BATTERY IS COMPROMISED AND STARTS TO LEAK, BASED UPON THE
BATTERY INGREDIENTS, THE CONTENTS ARE CLASSIFIED AS HAZARDOUS.
HAZARDOUS MATERIALS INFORMATION LABEL (HMIS):
HEALTH: NOT AVAILABLE
FLAMMABILITY: NOT AVAILABLE
PHYSICAL HAZARD: NOT AVAILABLE
NFPA HAZARD RATINGS:
HEALTH: NOT AVAILABLE
FLAMMABILITY: NOT AVAILABLE
REACTIVITY: NOT AVAILABLE
2.2 LABEL ELEMENTS:
HAZARD PICTOGRAMS: NOT APPLICABLE
SIGNAL WORD: NOT APPLICABLE
HAZARD STATEMENT: NOT APPLICABLE
PRECAUTIONARY STATEMENTS: NOT APPLICABLE
SUPPLEMENTAL HAZARD INFORMATION (EU): NOT APPLICABLE
2.3 OTHER HAZARDS:
APPEARANCE, COLOR AND ODOR: SOLID OBJECT WITH NO ODOR.
PRIMARY ROUTES(S) OF EXPOSURE:
THESE CHEMICALS ARE CONTAINED IN A SEALED ENCLOSURE. RISK OF EXPOSURE
OCCURS ONLY IF THE CELL OR PACK IS MECHANICALLY, THERMALLY, ELECTRICALLY
OR PHYSICALLY ABUSED TO THE POINT OF COMPROMISING THE ENCLOSURE.
IF THIS OCCURS, EXPOSURE TO THE ELECTROLYTE SOLUTION CONTAINED WITHIN CAN
OCCUR BY INHALATION, INGESTION, EYE CONTACT AND SKIN CONTACT.
POTENTIAL HEALTH EFFECT(S):
ACUTE (SHORT TERM): SEE SECTION 8 FOR EXPOSURE CONTROLS.
IN THE EVENT THAT THIS CELL OR PACK HAS BEEN RUPTURED, THE ELECTROLYTE
SOLUTION CONTAINED WITHIN THE CELL WOULD BE CORROSIVE AND CAN CAUSE BURNS
TO SKIN AND EYES.
INHALATION:
INHALATION OF MATERIALS FROM A SEALED CELL IS NOT AN EXPECTED ROUTE OF
EXPOSURE. VAPORS OR MISTS FROM A RUPTURED CELL MAY CAUSE RESPIRATORY
IRRITATION.
INGESTION:
SWALLOWING OF MATERIALS FROM A SEALED CELL IS NOT AN EXPECTED ROUTE OF
EXPOSURE. SWALLOWING THE CONTENTS OF AN OPEN CELL CAN CAUSE SERIOUS
CHEMICAL BURNS TO MOUTH, ESOPHAGUS, AND GASTROINTESTINAL TRACT.
SKIN:
CONTACT BETWEEN THE CELL AND SKIN WILL NOT CAUSE ANY HARM. SKIN CONTACT
WITH THE CONTENTS OF AN OPEN CELL CAN CAUSE SEVERE IRRITATION OR BURNS TO
THE SKIN.
EYE:
CONTACT BETWEEN THE CELL AND THE EYE WILL NOT CAUSE ANY HARM. EYE CONTACT
WITH THE CONTENTS OF AN OPEN CELL CAN CAUSE SEVERE IRRITATION OR BURNS TO
THE EYE.
CHRONIC (LONG TERM): SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL DATA.
INTERACTIONS WITH OTHER CHEMICALS:
IMMERSION IN HIGH CONDUCTIVITY LIQUIDS MAY CAUSE CORROSION AND BREACHING OF
THE CELL OR BATTERY ENCLOSURE. THE ELECTROLYTE SOLUTION INSIDE OF THE CELLS
MAY REACT WITH ALKALINE (BASIC) MATERIALS AND PRESENT A FLAMMABILITY
HAZARD.
POTENTIAL ENVIRONMENTAL EFFECTS: NOT AVAILABLE.
| SECTION III - COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1 MIXTURE:
CAS NO. EC NO. REACH %[WEIGHT] NAME
REGISTRATION NO.
7782-42-5 231-955-3 10-20 GRAPHITE
7439-89-6 231-096-4 10-20 IRON
13463-67-7 236-675-5 1-10 TITANIUM DIOXIDE
12016-80-7 234-614-7 1-10 COBALT HYDROXIDE
OXIDE
554-13-2 209-062-5 1-10 LITHIUM CARBONATE
1308-06-1 215-157-2 1-10 TRICOBALT
TETRAOXIDE
546-93-0 208-915-9 1-10 MAGNESIUM
CARBONATE
7440-50-8 231-159-6 1-10 COPPER
7429-90-5 231-072-3 1-5 ALUMINIUM
616-38-6 210-478-4 1-5 DIMETHYL CARBONATE
7440-44-0 231-153-3 1-5 CARBON
9002-88-4 NOT AVAILABLE 1-5 POLYETHYLENE
96-49-1 202-510-0 1-5 1,3-DIOXOLAN-2-ONE
21324-40-3 244-334-7 1-5 LITHIUM HEXAFLUOR-
OPHOSPHATE(1-)
141-78-6 205-500-4 0.1-1 ETHYL ACETATE
872-50-4 212-828-1 0.1-1 1-METHYL-2-
PYRROLIDINONE
7440-02-0 231-111-4 0.1-1 NICKEL
30174-67-5 NOT AVAILABLE 0.1-1 BUTADIENE-STYRENE-
ITACONIC ACID
COPOLYMER
110-61-2 203-783-9 0.1-1 BUTANEDINITRILE
7440-47-3 231-157-5 0.1-1 CHROMIUM
100-41-4 202-849-4 0.1-1 ETHYLBENZENE
NAME COMMON NAME CLASSIFICATION ACCORDING
(SYNONYMS) TO REGULATION(EC)
NO 1278/2008 (CLP)
GRAPHITE NOT AVAILABLE NOT CLASSIFIED
IRON NOT AVAILABLE NOT CLASSIFIED
TITANIUM DIOXIDE NOT AVAILABLE NOT CLASSIFIED
COBALT HYDROXIDE OXIDE NOT AVAILABLE NOT CLASSIFIED
LITHIUM CARBONATE NOT AVAILABLE NOT CLASSIFIED
TRICOBALT TETRAOXIDE NOT AVAILABLE NOT CLASSIFIED
MAGNESIUM CARBONATE NOT AVAILABLE NOT CLASSIFIED
COPPER NOT AVAILABLE NOT CLASSIFIED
ALUMINIUM NOT AVAILABLE PYR. SOL. 1, H250
WATER-REACT. 2, H261
DIMETHYL CARBONATE NOT AVAILABLE FLAM. LIQ. 2, H225
CARBON NOT AVAILABLE NOT CLASSIFIED
POLYETHYLENE NOT AVAILABLE NOT CLASSIFIED
1,3-DIOXOLAN-2-ONE NOT AVAILABLE NOT CLASSIFIED
LITHIUM NOT AVAILABLE NOT CLASSIFIED
HEXAFLUOROPHOSPHATE(1-)
ETHYL ACETATE NOT AVAILABLE FLAM. LIQ. 2, H225
EYE IRRIT. 2, H319
STOT SE 3, H336
1-METHYL-2-PYRROLIDINONE NOT AVAILABLE SKIN IRRIT. 2, H315
EYE IRRIT. 2, H319
STOT SE 3, H335
REPR. 1B, H360D
NICKEL NOT AVAILABLE SKIN SENS. 1, H317
CARC. 2, H351
STOT RE 1, H372
AQUATIC CHRONIC 3, H412
BUTADIENE-STYRENE- NOT AVAILABLE NOT CLASSIFIED
ITACONIC ACID COPOLYMER
BUTANEDINITRILE NOT AVAILABLE NOT CLASSIFIED
CHROMIUM NOT AVAILABLE NOT CLASSIFIED
ETHYLBENZENE NOT AVAILABLE FLAM. LIQ. 2, H225
ACUTE TOX. 4, H332
ASP. TOX. 1, H304
STOT RE 2, H373
(HEARING ORGANS)
FURTHER INFORMATION:
BECAUSE OF THE CELL STRUCTURE THE DANGEROUS INGREDIENTS WILL NOT BE
AVAILABLE IF USED PROPERLY.
DURING CHARGE PROCESS A LITHIUM GRAPHITE INTERCALATION PHASE IS FORMED.
| SECTION IV - FIRST-AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
FOLLOWING EYE CONTACT:
RINSE EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND SEEK MEDICAL
ATTENTION.
FOLLOWING SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
IMMEDIATELY RINSE CONTACT AREA WITH PLENTY OF CLEAN WATER.
PROVIDE FIRST AID TO CONTACTED AREA TO PREVENT INFECTION.
GET MEDICAL ATTENTION.
FOLLOWING INHALATION:
IN CASE OF INHALATION OF ORGANIC ELECTROLYTE MIST, REMOVE FROM EXPOSURE TO
FRESH AIR.
IF NECESSARY GIVE OXYGEN. GET MEDICAL ATTENTION.
FOLLOWING INGESTION:
IN CASE OF INGESTION OF ELECTROLYTE DON'T INDUCE VOMITING.
IF PATIENT IS CONSCIOUS AND ALERT GIVE 2-4 CUPFULS OF MILK OR WATER.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
GET MEDICAL ATTENTION IMMEDIATELY.
FURTHER INFORMATION:
THE FOLLOWING FIRST AID MEASURES ARE REQUIRED ONLY IN CASE OF EXPOSURE TO
INTERIOR BATTERY COMPONENTS AFTER DAMAGE OF THE EXTERNAL BATTERY CASING.
UNDAMAGED, CLOSED CELLS DO NOT REPRESENT A DANGER TO THE HEALTH.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ACUTE EFFECTS: NOT AVAILABLE
DELAYED EFFECTS: NOT AVAILABLE
4.3 INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES.
| SECTION V - FIRE-FIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
WHEN THE SCALE OF THE FIRE IS SMALL, USE A HFC (HYDROFLUOROCARBON) CLEAN-
AGENT FIRE EXTINGUISHER OR ALCOHOL RESISTANT FOAM FIRE EXTINGUISHERS.
(IN CASE OF BATTERY OVERHEATING, WEAR PROTECTIVE GEAR AND IMMERSE HEATED
BATTERY IN WATER)
IN CASE OF LARGE FIRE, USE LARGE AMOUNT OF WATER TO EXTINGUISH.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FLAMMABLE GAS LEAKS BEFORE IGNITION AND THEN THE PRODUCT IGNITES.
5.3 ADVICE FOR FIREFIGHTERS:
THE IGNITED BATTERY HAS A HIGH TEMPERATURE, SO THERE IS A RISK OF
ADDITIONAL IGNITION EVEN IF THE FIRE IS EXTINGUISHED AT EARLY STAGE.
SPRINKLE A LARGE AMOUNT OF WATER UNTIL THE BATTERY TEMPERATURE DROPS
TO NORMAL TEMPERATURE.
IF THE BATTERY IS IGNITED IN MULTI-STACKED CONDITION, MULTI-STACK SHOULD
BE DISASSEMBLED AND THEN EXTINGUISHED SO THAT HEAT IS NOT TRANSFERRED
BETWEEN BATTERIES
IN THE EVENT OF A BATTERY FIRE, COOL IT BY SPRAYING WATER DIRECTLY ON THE
BATTERY.
WHEN HANDLING A OVERHEATED BATTERY, WEAR HEAT-RESISTANT PROTECTIVE
EQUIPMENT.
| SECTION VI - ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: USE PERSONAL PROTECTIVE EQUIPMENT, SEE SECTION 8
EMERGENCY PROCEDURES:
IN CASE OF CELL DAMAGE, POSSIBLE RELEASE OF DANGEROUS SUBSTANCES AND A
FLAMMABLE GAS MIXTURE.
ELIMINATE ALL IGNITION SOURCES.
PLEASE NOTE THAT MATERIALS AND CONDITIONS TO AVOID.
BATTERY MAY EMIT ELECTROLYTE IF CHARGING OR DISCHARGING RATES EXCEED
MANUFACTURER'S RECOMMENDATIONS OR IF PACK HAS BEEN BREACHED.
MOVE BATTERY TO WELL VENTILATED AREA TO PREVENT GAS ACCUMULATION.
FOR EMERGENCY RESPONDERS:
ELIMINATE ALL IGNITION SOURCES.
PLEASE NOTE THAT MATERIALS AND CONDITIONS TO AVOID.
MOVE BATTERY TO WELL VENTILATED AREA TO PREVENT GAS ACCUMULATION.
6.2 ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT.
PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT: NOT AVAILABLE
FOR CLEANING UP:
COVER WITH DRY EARTH, DRY SAND OR OTHER NON-COMBUSTIBLE MATERIAL AND PUT
ON THE PLASTIC SHEET TO MINIMIZE SPREADING OR CONTACT WITH RAIN.
MOVE BATTERY TO WELL VENTILATED AREA TO PREVENT GAS ACCUMULATION.
DISPOSE IN ACCORDANCE WITH APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.
OTHER INFORMATION: NOT AVAILABLE
6.4 REFERENCE TO OTHER SECTIONS:
SEE ALSO SECTIONS 8 AND 13 OF THE SAFETY DATA SHEET.
| SECTION VII - HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
IN CASE OF CELL DAMAGE, POSSIBLE RELEASE OF DANGEROUS SUBSTANCES AND A
FLAMMABLE GAS MIXTURE.
THE BATTERY STORES ELECTRICAL ENERGY AND IS CAPABLE OF RAPID ENERGY
DISCHARGE.
BATTERY CELL CONTENTS ARE UNDER PRESSURE.
HANDLE BATTERY CAREFULLY TO AVOID PUNCTURING CASE OR ELECTRICALLY SHORTING
TERMINALS.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES AND STORAGE CONDITIONS: NOT AVAILABLE
PACKAGING MATERIALS: NOT AVAILABLE
REQUIREMENTS FOR STORAGE ROOMS AND VESSELS:
STORAGE AT ROOM TEMPERATURE (APPROX. 20 DEG. ) AT APPROX. 40% OF THE
NOMINAL CAPACITY
KEEP IN CLOSED ORIGINAL CONTAINER.
7.3 SPECIFIC END USE(S):
RECOMMENDATIONS: NOT AVAILABLE
INDUSTRIAL SECTOR SPECIFIC SOLUTIONS: NOT AVAILABLE
| SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
NAME ACGIH REGULATION BIOLOGICAL EXPOSURE INDEX
GRAPHITE TWA = 2 MG/M3 NOT AVAILABLE
IRON NOT APPLICABLE NOT AVAILABLE
TITANIUM DIOXIDE TWA = 10 MG/M3 NOT AVAILABLE
COBALT HYDROXIDE OXIDE NOT APPLICABLE NOT AVAILABLE
COBALT, Co TWA = 0.02 MG/M3 NOT AVAILABLE
LITHIUM CARBONATE NOT APPLICABLE NOT AVAILABLE
TRICOBALT TETRAOXIDE NOT APPLICABLE NOT AVAILABLE
MAGNESIUM CARBONATE NOT APPLICABLE NOT AVAILABLE
COPPER TWA = 0.2 MG/M3 NOT AVAILABLE
(FUME)
ALUMINIUM TWA = 1 MG/M3 NOT AVAILABLE
(RESPIRABLE
PARTICULATE MATTER)
DIMETHYL CARBONATE NOT APPLICABLE NOT AVAILABLE
CARBON TWA = 3 MG/M3 NOT AVAILABLE
(INHALABLE
PARTICULATE MATTER)
POLYETHYLENE NOT APPLICABLE NOT AVAILABLE
1,3-DIOXOLAN-2-ONE NOT APPLICABLE NOT AVAILABLE
LITHIUM NOT APPLICABLE NOT AVAILABLE
HEXAFLUOROPHOSPHATE(1-)
ETHYL ACETATE TWA = 400 PPM NOT AVAILABLE
1-METHYL-2-PYRROLIDINONE NOT APPLICABLE NOT AVAILABLE
NICKEL TWA = 1.5 MG/M3 NOT AVAILABLE
(INHALABLE
PARTICULATE MATTER)
BUTADIENE-STYRENE- NOT APPLICABLE NOT AVAILABLE
ITACONIC ACID COPOLYMER
BUTANEDINITRILE NOT APPLICABLE NOT AVAILABLE
CHROMIUM TWA = 0.5 MG/M3 NOT AVAILABLE
(INHALABLE
PARTICULATE MATTER);
TLV BASIS:
RESPIRATORY TRACT
IRRITATION,
TWA = 0.5 MG/M3
ETHYLBENZENE TWA = 20 PPM NOT AVAILABLE
NAME OSHA REGULATION NIOSH REGULATION EU REGULATION
GRAPHITE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
IRON NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
TITANIUM DIOXIDE TWA = 15 MG/M3 Ca (ULTRAFINE NOT APPLICABLE
PARTICLES)
2.4 MG/M3 (FINE)
0.3 MG/M3
(ULTRAFINE)
COBALT HYDROXIDE OXIDE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
COBALT, Co TWA = 0.1 MG/M3 TWA 0.05 MG/M3 NOT APPLICABLE
LITHIUM CARBONATE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
TRICOBALT TETRAOXIDE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
MAGNESIUM CARBONATE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
COPPER NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
ALUMINIUM TWA = 15 MG/M3 TWA = 1 MG/M3 NOT APPLICABLE
(ALUMINUM METAL (ALUMINUM METAL
(AS Al) TOTAL (AS Al),
DUST) RESPIRABLE
TWA = 5 MG/M3 FRACTION)
(ALUMINUM METAL
(AS Al)
RESPIRABLE
FRACTION)
DIMETHYL CARBONATE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
CARBON TWA = 3.5 MG/M3 TWA = 3.5 MG/M3 NOT APPLICABLE
Ca TWA = 0.1
MG PAHS/M3
[CARBON BLACK
IN PRESENCE OF
POLYCYCLIC
AROMATIC
HYDROCARBONS
(PAHS)]
POLYETHYLENE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
1,3-DIOXOLAN-2-ONE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
LITHIUM NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
HEXAFLUOROPHOSPHATE(1-)
ETHYL ACETATE TWA = 400 PPM TWA = 400 PPM TWA = 734
TWA = 1400 MG/M3,
MG/M3 TWA= 200 PPM,
STEL = 1468
MG/M3, STEL =
400 PPM
1-METHYL-2- NOT APPLICABLE NOT APPLICABLE TWA = 40 MG/M3,
PYRROLIDINONE TWA= 10 PPM,
STEL = 80
MG/M3, STEL =
20 PPM
NICKEL TWA = 1 MG/M3 Ca TWA = NOT APPLICABLE
(METAL AND 0.015 MG/M3
INSOLUBLE (METAL AND
COMPOUNDS INSOLUBLE
(AS Ni)) COMPOUNDS
TWA = 1 MG/M3 (AS Ni))
(SOLUBLE Ca TWA = 0.015
COMPOUNDS MG/M3 (SOLUBLE
(AS Ni)) COMPOUNDS
(AS Ni))
BUTADIENE-STYRENE- NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
ITACONIC ACID
COPOLYMER
BUTANEDINITRILE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE
CHROMIUM TWA = 0.5 MG/M3 TWA = 0.5 MG/M3 TWA = 2 MG/M3
(CHROMIUM (II) (CHROMIUM (II)
COMPOUNDS (AS COMPOUNDS (AS
CR), CHROMIUM Cr), CHROMIUM
(III) COMPOUNDS (III) COMPOUNDS
(AS Cr)) (AS Cr))
TWA = 1 MG/M3 TWA = 05 MG/M3
(CHROMIUM METAL (CHROMIUM METAL
AND INSOL. SALTS AND INSOL.
(AS Cr)) SALTS (AS Cr))
ETHYLBENZENE TWA = 100 PPM TWA = 100 PPM TWA = 442
TWA = 435 MG/M3 (ST) 125 PPM MG/M3, TWA=
100 PPM, STEL=
884 MG/M3,
STEL = 200 PPM
8.2 EXPOSURE CONTROLS:
8.2.1 APPROPRIATE ENGINEERING CONTROLS:
SUBSTANCE/MIXTURE RELATED MEASURES TO PREVENT EXPOSURE DURING IDENTIFIED
USES:
AVOID CHARGING BATTERIES IN AREAS WHERE HYDROGEN GAS ACCUMULATE.
USE LOCAL EXHAUST VENTILATION TO MAINTAIN CONCENTRATIONS OF HYDROGEN BELOW
THE LOWER EXPLOSIVE COLLECT AND TRANSPORT FLAMMABLE GASES IN VENTILATION
SYSTEMS.
INSURE PROPER VENTILATION IS PRESENT AND ELECTROLYTE MIST AND VAPOURS.
STRUCTURAL MEASURES TO PREVENT EXPOSURE:
AVOID CHARGING BATTERIES IN AREAS WHERE HYDROGEN GAS ACCUMULATE.
USE LOCAL EXHAUST VENTILATION TO MAINTAIN CONCENTRATIONS OF HYDROGEN BELOW
THE LOWER EXPLOSIVE COLLECT AND TRANSPORT FLAMMABLE GASES IN VENTILATION
SYSTEMS.
INSURE PROPER VENTILATION IS PRESENT AND ELECTROLYTE MIST AND VAPOURS.
ORGANISATIONAL MEASURES TO PREVENT EXPOSURE: NOT AVAILABLE
TECHNICAL MEASURES TO PREVENT EXPOSURE:
INSURE PROPER VENTILATION IS PRESENT AND ELECTROLYTE MIST AND VAPOURS.
8.2.2 INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE
EQUIPMENT:
EYE AND FACE PROTECTION:
WEAR ANSI APPROVED SAFETY GLASSES WITH SIDE SHIELD DURING NORMAL USE.
WEAR NIOSH APPROVED FACE SHIELD WITH SAFETY GLASSES AND H.V PROTECTION
DURING INTENTIONAL DISASSEMBLY.
SKIN PROTECTION:
HAND PROTECTION:
WEAR NITRILE BUTYL RUBBER, NEOPRENE, OR PVC GLOVE DURING BATTERY COMPONENT
DISASSEMBLY.
DISCARD CONTAMINATED WORK CLOTHING AFTER ONE WORK DAY.
OTHER SKIN PROTECTION:
WEAR PROTECTIVE CLOTHING DURING BATTERY COMPONENT DISASSEMBLY.
DISCARD CONTAMINATED WORK CLOTHING AFTER ONE WORK DAY.
RESPIRATORY PROTECTION:
NONE REQUIRED DURING NORMAL USE.
WEAR NIOSH OR EUROPEAN STANDARD EN 149 APPROVED FULL OR HALF FACE PIECE
(WITH GOGGLES) RESPIRATORY PROTECTIVE EQUIPMENT WHEN NECESSARY.
IN LACK OF OXYGEN (<19.5%), WEAR THE SUPPLIED-AIR RESPIRATOR OR SELF-
CONTAINED OXYGEN BREATHING APPARATUS.
IN CASE EXPOSED TO PARTICULATE MATERIAL, THE RESPIRATORY PROTECTIVE
EQUIPMENTS AS FOLLOW ARE RECOMMENDED; FACEPIECE FILTERING RESPIRATOR OR
AIR-PURIFYING RESPIRATOR, HIGH-EFFICIENCY PARTICULATE AIR(HEPA) FILTER
MEDIA OR RESPIRATOR EQUIPPED WITH POWERED FAN, FILTER MEDIA OF USE
(DUST, MIST, FUME)
8.2.3 ENVIRONMENTAL EXPOSURE CONTROLS:
SUBSTANCE/MIXTURE RELATED MEASURES TO PREVENT EXPOSURE: NOT AVAILABLE
INSTRUCTION MEASURES TO PREVENT EXPOSURE: NOT AVAILABLE
ORGANISATIONAL MEASURES TO PREVENT EXPOSURE: NOT AVAILABLE
TECHNICAL MEASURES TO PREVENT EXPOSURE: NOT AVAILABLE
| SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
DESCRIPTION: SOLID
COLOR: NOT AVAILABLE
ODOR: ODORLESS
ODOR THRESHOLD: NOT AVAILABLE
PH: NOT AVAILABLE
MELTING POINT/FREEZING POINT: NOT AVAILABLE
INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE
FLASH POINT: NOT AVAILABLE
EVAPORATION RATE: NOT AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: NOT AVAILABLE
VAPOR PRESSURE: NOT AVAILABLE
SOLUBILITY (IES): INSOLUBLE.
VAPOR DENSITY: NOT AVAILABLE
RELATIVE DENSITY: NOT AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE
AUTO IGNITION TEMPERATURE: NOT AVAILABLE
DECOMPOSITION TEMPERATURE: NOT AVAILABLE
VISCOSITY: NOT AVAILABLE
EXPLOSIVE PROPERTIES: NOT AVAILABLE
OXIDIZING PROPERTIES: NOT AVAILABLE
MOLECULAR WEIGHT: NOT AVAILABLE
9.2 OTHER INFORMATION: NOT AVAILABLE
| SECTION X - STABILITY AND REACTIVITY | |
10.1 REACTIVITY: STABLE AT AMBIENT TEMPERATURE.
10.2 CHEMICAL STABILITY:
THERE IS NO HAZARD WHEN THE MEASURES FOR HANDLING AND STORAGE ARE FOLLOWED.
STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
WILL NOT OCCUR UNDER NORMAL CONDITIONS.
IN CASE OF CELL DAMAGE, POSSIBLE RELEASE OF DANGEROUS SUBSTANCES AND A
FLAMMABLE GAS MIXTURE.
CONTAINERS MAY EXPLODE WHEN HEATED.
FIRE MAY PRODUCE IRRITATING AND/OR TOXIC GASES.
SOME LIQUIDS PRODUCE VAPORS THAT MAY CAUSE DIZZINESS OR SUFFOCATION.
INHALATION OF MATERIAL MAY BE HARMFUL.
10.4 CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING.
FRICTION, HEAT, SPARKS OR FLAMES
DUSTS OR SHAVINGS FROM BORINGS, TURNINGS, CUTTINGS, ETC.
DO NOT EXCEED MANUFACTURER'S RECOMMENDATION FOR CHARGING OR USE BATTERY FOR
AN APPLICATION FOR WHICH IT WAS NOT SPECIFICALLY DESIGNED.
DO NOT ELECTRICALLY SHORT.
10.5 INCOMPATIBLE MATERIALS:
AVOID CONTACT WITH ACIDS AND OXIDIZERS.
KEEP AWAY FROM ANY POSSIBLE CONTACT WITH WATER, BECAUSE OF VIOLENT REACTION
AND POSSIBLE FLASH FIRE.
HANDLE UNDER INERT GAS. PROTECT FROM MOISTURE.
COMBUSTIBLES, REDUCING AGENTS
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
NONE UNDER NORMAL CONDITIONS.
CORROSIVE AND/OR TOXIC FUME
MATERIAL MAY PRODUCE IRRITATING AND HIGHLY TOXIC GASES FROM DECOMPOSITION
BY HEAT AND COMBUSTION DURING BURNING.
IRRITATING AND/OR TOXIC GASES
| SECTION XI - TOXICOLOGICAL INFORMATION | |
THIS IS A PRODUCT THAT FULFILLS A CERTAIN FUNCTION IN SOLID STATE WITH
SPECIFIC SHAPE WITHOUT DISCHARGING ANY CHEMICAL SUBSTANCE IN ITS USE AND
HAS NO OBLIGATION TO WRITE (M)SDS. SINCE THIS DOCUMENT CONTAINS THE
PRECAUTIONS FOR SAFE HANDLING RELATED TO ITS MATERIALS OR CHEMICAL
SUBSTANCES CONSISTING OF THIS PRODUCT, PLEASE NOTE THAT THESE OVERALL
INFORMATION IS IRRELEVANT TO THIS PRODUCT.
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
ORAL:
ATEMIX: 535.2167 MG/KG BW
GRAPHITE:
RAT LD50: >2,000 MG/KG (FEMALE)(OECD GUIDELINE 401)
Fe:
RAT LD50: 98,600 MG/KG (REDUCED IRON, OECD TG 401)
TITANIUM DIOXIDE:
RAT LD50: >5,000 MG/KG (OECD TG 425)
COBALT HYDROXIDE OXIDE:
RAT LD50: >5,000 MG/KG (OECD GUIDELINE 425, GLP)
LITHIUM CARBONATE; LITHANE:
RAT LD50: 525 MG/KG
TRICOBALT TETRAOXIDE:
RAT LD50: >5,000 MG/KG (OECD TG 401, GLP)
MAGNESIUM CARBONATE:
RAT LD50:
>2,000 MG/KG (FEMALE) (OECD GUIDELINE 420, EU METHOD B.1 BIS, GLP)
COPPER:
RAT LD50: >2,500 MG/KG (CUPRIC OXIDE; READ ACROSS) (OECD TG 423, GLP)
ALUMINUM:
RAT LD50: >15,900 MG/KG (OECD TG 401) (FUMED ALUMINA; READ ACROSS)
DIMETHYL CARBONATE:
RAT LD50: >5,000 MG/KG (MALE/FEMALE) (OECD GUIDELINE 401)
CARBON:
RAT LD50: >10,000 MG/KG
POLYETHYLENE:
RAT LD50: >2,000 MG/KG
1,3-DIOXOLAN-2-ONE:
RAT LD50: 10,400 MG/KG (MALE) (OECD GUIDELINE 401)
LITHIUM HEXAFLUOROPHOSPHATE(1-):
RAT LD50: = 50 - 300 MG/KG (FEMALE)(OECD GUIDELINE 423, GLP)
ETHYL ACETATE:
RAT LD50: 4,934 MG/KG
1-METHYL-2-PYRROLIDINONE:
RAT LD50: 4,150 MG/KG (MALE/FEMALE) (OECD GUIDELINE 401)
NICKEL; RANEY NICKEL:
RAT LD50: >9,000 MG/KG (MALE/FEMALE) (OECD GUIDELINE 401, GLP)
BUTANEDINITRILE:
RAT LD50: 300 - 2,000 MG/KG (FEMALE) (OECD GUIDELINE 423, GLP)
CHROMIUM:
RAT LD50: 5,000 MG/KG (READ ACROSS; CHROMIUM(III) OXIDE)(OECD TG 420, GLP)
ETHYLBENZENE:
RAT LD50: 3,500 MG/KG (MALE OR FEMALE)
DERMAL:
ATEMIX: 15,432 MG/KG BW
COBALT HYDROXIDE OXIDE:
RAT LD50: 2,000 MG/KG (OECD GUIDELINE 402, GLP)
LITHIUM CARBONATE; LITHANE:
RABBIT LD50: >3,000 MG/KG (MALE/FEMALE) (OECD GUIDELINE 402)
TRICOBALT TETRAOXIDE:
RAT LD50: >2,000 MG/KG (OECD TG 402, GLP)
COPPER:
RAT LD50: >2,000 MG/KG (OECD TG 402, GLP)
DIMETHYL CARBONATE:
RABBIT LD50: >2,000 MG/KG (MALE/FEMALE)
1,3-DIOXOLAN-2-ONE:
RAT LD50: >2,000 MG/KG (MALE/FEMALE) (OECD GUIDELINE 402)
ETHYL ACETATE:
RABBIT LD50: >20,000 MG/KG (MALE)
1-METHYL-2-PYRROLIDINONE:
RAT LD50: >5,000 MG/KG (MALE/FEMALE) (OECD GUIDELINE 402)
BUTANEDINITRILE:
RAT LD50: >2,000 MG/KG (MALE/FEMALE) (OECD GUIDELINE 402, GLP)
ETHYLBENZENE:
RABBIT LD50: 15,432 MG/KG
INHALATION:
ATEMIX: 59.05 MG/L
GRAPHITE:
RAT LD50: >2 MG/L/4HR (MALE/FEMALE) (OECD GUIDELINE 403)
Fe:
RAT LC50: >100 MG/M3/6HR
TITANIUM DIOXIDE:
RAT LC50: 5.09 MG/L/4HR (OECD TG 403)
LITHIUM CARBONATE; LITHANE:
RAT LC50: >2 MG/L/4HR (MALE/FEMALE) (OECD GUIDELINE 403)
TRICOBALT TETRAOXIDE:
RAT LC50: >5.06 MG/L/4HR (OECD TG 436, GLP)
ALUMINUM:
RAT LC50: >0.888 MG/L/4HR (ANALYTICAL) (OECD TG 403)
DIMETHYL CARBONATE:
RAT LD50: >5.36 MG/L/4HR (MALE/FEMALE) (OECD GUIDELINE 403)
1,3-DIOXOLAN-2-ONE:
RAT LC0: 730 MG/M3 /8HR
ETHYL ACETATE:
RAT LC0: >6000 PPM (MALE/FEMALE)
1-METHYL-2-PYRROLIDINONE:
RAT LC50: >5.1 MG/L/4HR (MALE/FEMALE) (OECD GUIDELINE 403)
BUTANEDINITRILE:
RAT LC50: =/> 2.67 MG/L/4HR (MALE/FEMALE) (OECD GUIDELINE 403)
CHROMIUM:
RAT LD50:
>5.41 MG/L/4HR (READ ACROSS; CHROMIUM(III) OXIDE)(OECD TG 403, GLP)
ETHYLBENZENE:
RAT LC50: 17.8 MG/L/4HR
SKIN CORROSION/ IRRITATION:
GRAPHITE:
IN THE SKIN IRRITATION TEST USING RABBITS, THE TEST MATERIAL WAS NOT
IRRITATING. (OECD GUIDELINE 404, GLP)
Fe:
IN TEST ON SKIN IRRITATION WITH RABBITS, SKIN IRRITATIONS WERE NOT
OBSERVED. (READ ACROSS; FE3O4)(OECD TG 404, GLP)
TITANIUM DIOXIDE:
IN TEST ON SKIN IRRITATION WITH RABBITS, SKIN IRRITATIONS WERE NOT
OBSERVED. (OECD TG 404)
COBALT HYDROXIDE OXIDE:
IN THE IN VITRO SKIN IRRITATION TEST, THE TEST MATERIAL WAS NOT
IRRITATING. (OECD GUIDLINE 431, GLP)
LITHIUM CARBONATE; LITHANE:
IN THE SKIN IRRITATION TEST USING RABBITS, THE TEST MATERIAL WAS NOT
IRRITATING. (OECD GUIDELINE 404, GLP)
TRICOBALT TETRAOXIDE:
IN A TEST WITH RABBITS, THIS SUBSTANCE WAS NOT A SKIN IRRITATING.
(OECD TG 439, GLP)
MAGNESIUM CARBONATE:
IN SKIN CORROSION TEST WITH HUMAN EPIDERMIS MODEL, NO CORROSIVITY WAS SEEN
(OECD GUIDELINE 431, GLP).
COPPER:
IN TEST ON SKIN IRRITATION WITH RABBITS, SKIN IRRITATIONS WERE NOT
OBSERVED. (OECD TG 404, GLP)
ALUMINUM:
ALUMINIUM OXIDE CAUSED SLIGHT ERYTHEMA IN 2/12 RABBITS. THE OBSERVED
EFFECTS DO NOT LEAD TO A CLASSIFICATION. ALUMINIUM OXIDE IS, THEREFORE,
NOT CONSIDERED TO BE A PRIMARY SKIN IRRITANT. (OECD TG 404) (READ ACROSS;
ALUMINIUM OXIDE)
DIMETHYL CARBONATE:
IN THE SKIN IRRITATION TEST USING RABBITS, THE TEST MATERIAL WAS NOT
IRRITATING. (OECD GUIDELINE 404)
CARBON:
THESE SUBSTANCES CAUSE IRRITATION OF THE SKIN IF APPLIED IN LARGE
QUANTITIES.
POLYETHYLENE:
NO IRRITATION WAS OBSERVED AT THE OTHER TWO TREATED SITES AND NO CORROSIVE
EFFECTS WERE NOTED DURING THE STUDY USING RABBITS. THE PRIMARY IRRITATION
INDEX WAS CALCULATED AS 0.2 AND POLYETHYLENE WAS CLASSIFIED AS A MILD
IRRITANT.
1,3-DIOXOLAN-2-ONE:
IN THE SKIN IRRITATION TEST USING RABBITS, THE TEST MATERIAL WAS NOT
CLASSIFIED. (OECD GUIDELINE 404, GLP)
LITHIUM HEXAFLUOROPHOSPHATE(1-):
IN THE SKIN IRRITATION TEST USING HUMAN, THE TEST MATERIAL WAS CORROSIVE.
(EU METHOD B.40, GLP)
ETHYL ACETATE:
IN THE SKIN IRRITATION TEST USING RABBITS, THE TEST MATERIAL WAS SLIGHTLY
IRRITATING. (OECD GUIDELINE 404)
1-METHYL-2-PYRROLIDINONE:
IN THE SKIN IRRITATION TEST USING RABBITS, THE TEST MATERIAL WAS SLIGHTLY
IRRITATING. (OECD GUIDELINE 404, GLP)
NICKEL; RANEY NICKEL: INDUSTRIAL NICKEL DUST CAUSES NICKEL DERMATITIS.
BUTANEDINITRILE:
IN THE SKIN IRRITATION TEST USING RABBITS, THE TEST MATERIAL WAS NOT
IRRITATING. (OECD GUIDELINE 404)
CHROMIUM:
IN TEST ON SKIN IRRITATION WITH RABBITS, SKIN IRRITATIONS WERE NOT
OBSERVED.(READ ACROSS; CHROMIUM (III) OXIDE) (OECD TG 404, GLP)
ETHYLBENZENE:
IN TEST ON SKIN IRRITATION WITH RABBITS, MODERATE IRRITATIONS WERE OBSERVED
TO RABBIT SKIN.
SERIOUS EYE DAMAGE/ IRRITATION:
GRAPHITE:
IN THE EYE IRRITATION TEST USING RABBIT, THE TEST MATERIAL WAS NOT
IRRITATING. (OECD GUIDELINE 405, GLP)
Fe:
IN TEST ON EYES IRRITATION WITH RABBITS, EYES IRRITATIONS WERE NOT
OBSERVED. (READ ACROSS; Fe3O4)(OECD TG 405, GLP)
TITANIUM DIOXIDE:
IN TEST ON EYE IRRITATION WITH RABBITS, EYE IRRITATIONS WERE NOT
OBSERVED. (OECD TG 405)
COBALT HYDROXIDE OXIDE:
IN THE EYE IRRITATION TEST USING RABBIT, THE TEST MATERIAL WAS NOT
IRRITATING. (OECD GUIDELINE 405)
LITHIUM CARBONATE;LITHANE:
IN THE EYE IRRITATION TEST USING RABBIT, THE TEST MATERIAL WAS MODERATELY
IRRITATING. (OECD GUIDELINE 405, GLP)
TRICOBALT TETRAOXIDE:
THE TEST ITEM TRICOBALT TETRAOXIDE DID NOT CAUSE PERMEABILITY OF THE
CORNEAE COMPARED WITH THE RESULTS OF THE NEGATIVE CONTROL, BUT SLIGHT
OPACITY EFFECTS. THE CALCULATED MEAN IN VITRO SCORE WAS 10.39 AND
THEREFORE, THE TEST ITEM WAS CLASSIFIED AS MILD EYE IRRITANT.
(OECD TG 437, GLP)
MAGNESIUM CARBONATE:
IN EYE IRRITATION TEST WITH RABBITS, THERE WERE NO CORNEAL OR IRIDIAL
EFFECTS NOTED (OECD GUIDELINE 405, GLP).
COPPER:
IN TEST ON SKIN IRRITATION WITH RABBITS, SKIN IRRITATIONS WERE NOT
OBSERVED. (OECD TG 405, GLP)
ALUMINUM:
AN EYE IRRITATION STUDY OF THE ALUMINIUM OXIDE WAS PERFORMED IN RABBITS.
NO EYE IRRITATION/ CORROSION EFFECTS WERE OBSERVED. (READ ACROSS;
ALUMINIUM OXIDE)
DIMETHYL CARBONATE:
IN THE EYE IRRITATION TEST USING RABBIT, THE TEST MATERIAL WAS NOT
IRRITATING. (GLP)
CARBON:
THESE SUBSTANCES CAN CAUSE A IRRITATION, PARTICULARLY TO THE EYES AND
MUCOUS MEMBRANES.
POLYETHYLENE:
MILD IRRITANTS WERE OBSERVED IN EYE IRRITATION TEST WITH RABBITS.
(SCORE 11.7/110)
1,3-DIOXOLAN-2-ONE:
IN THE EYE IRRITATION TEST USING RABBIT, THE TEST MATERIAL WAS MODERATELY
IRRITATING. (OECD GUIDELINE 405, GLP)
LITHIUM HEXAFLUOROPHOSPHATE(1-):
IN THE EYE IRRITATION TEST USING FERTILISED BROWN LEGHORN CHICKEN EGGS, THE
TEST MATERIAL WAS SEVERELY IRRITATING. (GLP)
ETHYL ACETATE:
IN THE EYES IRRITATION TEST USING RABBITS, THE TEST MATERIAL WAS NOT
IRRITATING. (OECD GUIDELINE 405)
1-METHYL-2-PYRROLIDINONE:
IN THE EYE IRRITATION TEST USING RABBIT, THE TEST MATERIAL WAS MODERATELY
IRRITATING. (OECD GUIDELINE 405, GLP)
BUTANEDINITRILE:
IN THE EYE IRRITATION TEST USING RABBIT, THE TEST MATERIAL WAS NOT
IRRITATING. (OECD GUIDELINE 405)
CHROMIUM:
IN TEST ON EYES IRRITATION WITH RABBITS, EYES IRRITATIONS WERE NOT
OBSERVED. (READ ACROSS; CHROMIUM(III) OXIDE)(OECD TG 405, GLP)
ETHYLBENZENE:
IN TEST ON EYES IRRITATION WITH RABBITS, SLIGHT IRRITATIONS WERE OBSERVED
TO RABBIT.
RESPIRATORY SENSITIZATION:
ALUMINUM:
Al2O3 WAS THE LEAST INFLAMMATORY MATERIAL TESTED AND LED TO ONLY WEAK
EFFECTS ON THE MOUSE LUNG. (READ ACROSS; ALUMINIUM OXIDE)
SKIN SENSITIZATION:
GRAPHITE:
IN THE SKIN SENSITIZATION TEST USING MICE, THE TEST MATERIAL WAS NOT SKIN
SENSITIZATION. (OECD GUIDELINE 429, GLP)
Fe:
IN THE TEST USING GUINEA PIGS, THE TEST SUBSTANCE WAS NOT CONSIDERED TO BE
A DERMAL SENSITIZER IN GUINEA PIGS.(READ ACROSS; FeO, Fe2O3)
TITANIUM DIOXIDE:
IN TEST ON SKIN SENSITIZATION WITH GUINEA PIG, SKIN SENSITIZATIONS WERE NOT
OBSERVED. (OECD TG 406, GLP)
COBALT HYDROXIDE OXIDE:
IN THE SKIN SENSITIZATION TEST USING MOUSE, THIS MATERIAL WAS NOT SKIN
SENSITIZING. (OECD GUIDELINE 429, GLP)
LITHIUM CARBONATE; LITHANE:
IN THE SKIN SENSITIZATION TEST USING GUINEA PIG, THIS MATERIAL WAS NOT SKIN
SENSITIZING. (OECD GUIDELINE 406, GLP)
TRICOBALT TETRAOXIDE:
IN A LLNA WITH GUINEA-PIGS, THIS SUBSTANCE WAS NOT CLASSIFIED AS SKIN
SENSITISER. (OECD TG 429, GLP)
COPPER:
IN MAXIMIZATION TEST ON SKIN SENSITIZATION WITH GUINEA PIG, SKIN
SENSITIZATION WAS NOT OBSERVED. (OECD TG 406, GLP)
ALUMINUM:
IN TEST WITH GUINEA PIGS, IT CAN BE CONCLUDED THAT ALUMINIUM OXIDE HAS NO
SENSITISATION POTENTIAL UNDER THE EXPERIMENTAL CONDITIONS.
(READ ACROSS; ALUMINIUM OXIDE)
DIMETHYL CARBONATE:
IN THE SKIN SENSITIZATION TEST USING GUINEA PIG, THIS MATERIAL WAS NOT SKIN
SENSITIZING. (OECD GUIDELINE 406, GLP)
POLYETHYLENE:
NO REACTIONS WERE OBSERVED IN SKIN SENSITIZATION TEST WITH GUINEA PIGS.
1,3-DIOXOLAN-2-ONE:
IN THE SKIN SENSITIZATION TEST USING GUINEA PIG, THIS MATERIAL WAS NOT
CLASSIFIED. (OECD GUIDELINE 406, GLP)
LITHIUM HEXAFLUOROPHOSPHATE(1-):
IN THE SKIN SENSITIZATION TEST USING MICE, THE TEST MATERIAL WAS NOT SKIN
SENSITIZATION. (OECD GUIDELINE 429, GLP)
ETHYL ACETATE:
IN THE SKIN SENSITIZATION TEST USING GUINEA PIG, THIS MATERIAL WAS NOT SKIN
SENSITIZING. (OECD GUIDELINE 406)
1-METHYL-2-PYRROLIDINONE:
IN THE SKIN SENSITIZATION TEST USING MICE, THE TEST MATERIAL WAS NOT SKIN
SENSITIZATION. (OECD GUIDELINE 429, GLP)
NICKEL; RANEY NICKEL:
NICKEL HYPERSENSITIVITY DERMATITIS MAY BE INITIATED BY CONTACT WITH NICKEL
ON THE SKIN.
BUTANEDINITRILE:
IN THE SKIN SENSITIZATION TEST USING MICE, THE TEST MATERIAL WAS NOT
CLASSIFIED. (OECD GUIDELINE 429, GLP)
CHROMIUM:
IN VITRO SKIN SENSITISATION TEST, THE TEST SUBSTANCE WAS NOT CONSIDERED TO
BE A DERMAL SENSITIZER.
CARCINOGENICITY:
IARC:
TITANIUM DIOXIDE: GROUP 2B
COBALT AND COBALT COMPOUNDS: GROUP 2B
CARBON: GROUP 2B
POLYETHYLENE: GROUP 3
NICKEL: GROUP 2B
CHROMIUM: GROUP 3
ETHYLBENZENE: GROUP 2B
NTP:
IRON: PRESENT
CARBON: PRESENT
NICKEL: R
ETHYLBENZENE: PRESENT
OSHA:
TRICOBALT TETRAOXIDE: PRESENT
CARBON: PRESENT
NICKEL: PRESENT
ETHYLBENZENE: PRESENT
ACGIH:
TITANIUM DIOXIDE: A4
COBALT AND COBALT COMPOUNDS: A3
ALUMINUM: A4
CARBON: A3
NICKEL: A5
CHROMIUM: A4
ETHYLBENZENE: A3
KOREA-ISHL:
TITANIUM DIOXIDE: 2
COBALT AND INORGANIC COMPOUNDS: 2
CARBON: 2
NICKEL: 1A
CHROMIUM: 1A(CHROMIUM(VI)COMPOUNDS(WATER INSOLUBLE INORGANIC COMPOUNDS))
ETHYLBENZENE: 2
EU:
NICKEL: CARC. 2
TITANIUM DIOXIDE:
THERE WAS NO EVIDENCE CAUSED CANCER IN RATS AT DOSES OF 5 MG/M3 INHALATION
FOR 24 MONTHS. (OECD TG 453, GLP)
COBALT HYDROXIDE OXIDE:
CARCINOGENICITY STUDIES USING RATS (MALE / FEMALE) REVEALED CARCINOGENIC
EFFECTS.(OECD GUIDELINE 451, GLP)
TRICOBALT TETRAOXIDE:
UNDER THE CONDITIONS OF THESE 2-YEAR INHALATION STUDIES, THERE WAS SOME
EVIDENCE OF CARCINOGENIC ACTIVITY OF COBALT SULFATE HEPTAHYDRATE IN MALE
F344/N RATS BASED ON INCREASED INCIDENCES OF ALVEOLAR/BRONCHIOLAR
NEOPLASMS. (GLP)
MAGNESIUM CARBONATE:
IN CARCINOGENICITY TEST WITH MICE, NO ABNORMAL CLINICAL SIGNS WERE
OBSERVED. (READ-ACROSS; MGCL2.6H2O) (OECD GUIDELINE 451)
COPPER:
EPA IRIS: D IN CARCINOGENICITY STUDY WITH RAT, TUMOR WAS NOT OBSERVED.
POLYETHYLENE:
FIFTY RATS WERE IMPLANTED WITH POLYETHYLENE. IN THE POLYETHYLENE GROUP,
23 DEVELOPED TUMORS (TWO OF THESE WERE UNRELATED TO THE IMPLANTS).
ETHYLBENZENE:
THERE WAS CLEAR EVIDENCE OF CARCINOGENIC ACTIVITY OF ETHYLBENZENE IN RAT
(MALE/FEMALE)WITH BASED ON INCREASED INCIDENCES OF RENAL TUBULE NEOPLASMS;
INCREASED INCIDENCE OF TESTICULAR ADENOMA.
MUTAGENICITY:
GRAPHITE:
NEGATIVE REACTIONS WERE OBSERVED IN VITRO (BACTERIAL REVERSE MUTATION ASSAY
(OECD GUIDELINE 471, GLP)).
Fe:
IN MAMMALIAN CELL GENE MUTATION ASSAY ELECTROLYTIC IRON, POSITIVE CARBONYL
IRON EXHIBITED A CYTOTOXIC AND MUTAGENIC RESPONSE (OECD TG 476)
TITANIUM DIOXIDE:
NEGATIVE REACTIONS WERE OBSERVED IN IN VITRO (MAMMALIAN CELL GENE MUTATION
TEST(OECD TG 476, GLP), MAMMALIAN CHROMOSOME ABERRATION TEST(OECD TG 473,
GLP), BACTERIAL REVERSE MUTATION ASSAY(OECD TG 471)) AND IN IN VIVO
(MICRONUCLEUS ASSAY).
COBALT HYDROXIDE OXIDE:
NEGATIVE REACTIONS WERE OBSERVED IN VITRO BACTERIAL REVERSE MUTATION ASSAY
(OECD GUIDELINE 471, GLP). NEGATIVE REACTIONS WERE OBSERVED IN VIVO
MAMMALIAN BONE MARROW CHROMOSOME ABERRATION TEST(OECD GUIDELINE 475).
LITHIUM CARBONATE; LITHANE:
NEGATIVE REACTIONS WERE OBSERVED IN VITRO (BACTERIAL REVERSE MUTATION ASSAY
(OECD GUIDELINE 471, GLP)).
TRICOBALT TETRAOXIDE:
NEGATIVE REACTIONS WERE OBSERVED IN VITRO MAMMALIAN CELL GENE MUTATION TEST
(OECD TG 476), MAMMALIAN CELL MICRONUCLEUS TEST AND IN VIVO MAMMALIAN
CHROMOSOME ABERRATION ASSAY(OECD 475).
MAGNESIUM CARBONATE:
IN VITRO BACTERIAL REVERSE MUTATION ASSAY(READ-ACROSS; CAS NO. 7786-30-3)
(OECD GUIDELINE 471) MAMMALIAN CELL GENE MUTATION ASSAY (READ-ACROSS
MAGNESIUM CHLORIDE), MAMMALIAN CHROMOSOME ABERRATION TEST(OECD GUIDELINE
473, GLP) WERE NEGATIVE.
COPPER:
NEGATIVE REACTIONS WERE OBSERVED IN BOTH IN VITRO(AMES TEST) AND IN VIVO
(DNA DAMAGE AND/OR REPAIR; UNSCHEDULED DNA SYNTHESIS, MICRONUCLEUS ASSAY).
(GLP)
ALUMINUM:
NEGATIVE REACTIONS WERE OBSERVED IN VITRO (MAMMALIAN CELL GENE MUTATION
ASSAY WITH MOUSE LYMPHOMA L5178Y CELLS(OECD TG 476, GLP)) AND IN VIVO
(MICRONUCLEUS ASSAY WITH RATS (OECD TG 474, GLP)). (ALUMINIUM HYDROXIDE,
ALUMINIUM CHLORIDE, ALUMINUM OXIDE; READ ACROSS)
DIMETHYL CARBONATE:
NEGATIVE REACTIONS WERE OBSERVED IN BOTH IN VITRO (MAMMALIAN CHROMOSOME
ABERRATION TEST (OECD GUIDELINE 473, GLP)) AND IN VIVO (MAMMALIAN
SPERMATOGONIAL CHROMOSOME ABERRATION TEST (OECD GUIDELINE 483))
POLYETHYLENE:
NEGATIVE REACTIONS WERE OBSERVED IN AMES TEST USING SALMONELLA TYPHIMURIUM
AND ESCHERICHIA COLI.
1,3-DIOXOLAN-2-ONE:
NEGATIVE REACTIONS WERE OBSERVED IN VITRO (MAMMALIAN CELL GENE MUTATION
ASSAY (OECD GUIDELINE 476, GLP)).
LITHIUM HEXAFLUOROPHOSPHATE(1-):
NEGATIVE REACTIONS WERE OBSERVED IN BOTH IN VIVO (MAMMALIAN ERYTHROCYTE
MICRONUCLEUS TEST(OECD GUIDELINE 474)) AND IN VITRO (BACTERIAL REVERSE
MUTATION ASSAY(OECD GUIDELINE 471, GLP)).
ETHYL ACETATE:
NEGATIVE REACTIONS WERE OBSERVED IN BOTH IN VITRO(BACTERIAL REVERSE
MUTATION ASSAY(OECD GUIDELINE 471)) AND IN VIVO (MAMMALIAN ERYTHROCYTE
MICRONUCLEUS TEST(OECD GUIDELINE 474)).
1-METHYL-2-PYRROLIDINONE:
NEGATIVE REACTIONS WERE OBSERVED IN BOTH IN VITRO (CHROMOSOMAL ABERRATIONS
TEST (OECD GUIDELINE 476, GLP)) AND IN VIVO (MAMMALIAN ERYTHROCYTE
MICRONUCLEUS TEST (OECD GUIDELINE 474, GLP)).
BUTANEDINITRILE:
NEGATIVE REACTIONS WERE OBSERVED IN BOTH IN VIVO (MAMMALIAN ERYTHROCYTE
MICRONUCLEUS TEST(OECD GUIDELINE 474, GLP)) AND IN VITRO (BACTERIAL REVERSE
MUTATION ASSAY(OECD GUIDELINE 471, GLP)).
CHROMIUM:
IN VITRO MAMMALIAN CHROMOSOME ABERRATION TEST, THE RESULT OF THE ASSAY WAS
NEGATIVE. (READ ACROSS; STAINLESS STEEL)(OECD TG 473, GLP)
ETHYLBENZENE:
NEGATIVE REACTIONS WERE OBSERVED IN IN VITRO-MAMMALIAN CHROMOSOME
ABERRATION TEST(OECD TG 473), MAMMALIAN CELL GENE MUTATION TEST (OECD TG
476, GLP) AND IN VIVO-UNSCHEDULED DNA SYNTHESIS (UDS) TEST WITH MAMMALIAN
LIVER CELLS (OECD TG 486, GLP), MAMMALIAN ERYTHROCYTE MICRONUCLEUS TEST
(OECD TG 474, GLP).
REPRODUCTIVE TOXICITY:
TITANIUM DIOXIDE:
UNDER THE CONDITIONS OF THIS STUDY, THERE WAS NO EVIDENCE OF EITHER
MATERNAL OR DEVELOPMENTAL TOXICITY AT DOSES UP TO 1000 MG/KG/DAY.
THEREFORE, THE NO -OBSERVED-EFFECT LEVEL (NOAEL) FOR MATERNAL AND
DEVELOPMENTAL TOXICITY WAS CONSIDERED 1000 MG/KG/DAY.
COBALT HYDROXIDE OXIDE:
IN THE REPRODUCTION TOXICITY TEST USING RAT, NO EFFECTS WERE OBSERVED.
(OECD GUIDELINE 408, GLP)
TRICOBALT TETRAOXIDE:
NO EFFECT ON CULTURED EMBRYOS DERIVED FROM CHRONICALLY TREATED MALE RATS.
MAGNESIUM CARBONATE:
IN REPRODUCTIVE/DEVELOPMENTAL TOXICITY TEST WITH RATS, THERE WERE NO
SIGNIFICANT ADVERSE EFFECTS ON REPRODUCTIVE PARAMETERS AND NO EVIDENCE OF
MALFORMATIONS. (READ-ACROSS; CAS NO. 7791-18-6)(OECD GUIDELINE 422, GLP)
COPPER:
IN REPRODUCTIVE TOXICITY WITH RATS, THERE WERE NO EFFECTS CONSIDERED
(UP TO 1500 PPM). (OECD TG 416, GLP)
ALUMINUM:
NO REPRODUCTION, BREEDING AND EARLY POST-NATAL DEVELOPMENTAL TOXICITY WAS
OBSERVED IN RATS AT 1000 MG/KG BW FOR MALES AND FEMALES. (OECD TG 422, GLP)
(ALUMINIUM CHLORIDE; READ ACROSS)
LITHIUM HEXAFLUOROPHOSPHATE(1-):
IN THE TWO-GENERATION REPRODUCTIVE TOXICITY WITH RATS, NO EFFECTS OBSERVED
ON REPRODUCTIVE TOXICITY. (MALE/FEMALE)(OECD GUIDELINE 416, GLP)
(OECD GUIDELINE 414)(INFORMATION ON MAJOR HYDROLYSIS PRODUCT OF THE
REGISTERED SUBSTANCE (RELEASED RAPIDLY ON CONTACT WITH WATER/MOISTURE))
CHROMIUM:
IN THE 90 DAYS INHALATION TOXICITY STUDY USING RAT, THERE WERE NO EFFECTS
ON CLINICAL SIGNS, MORTALITY.(OECD TG 413)
ETHYLBENZENE:
THERE WERE NO ADVERSE EFFECTS ON REPRODUCTIVE OR DEVELOPMENTAL ENDPOINTS
AT DOSE LEVELS UP TO 500 PPM EB IN THIS GUIDELINE TWO-GENERATION RAT
INHALATION STUDY. OECD TG 416, GLP); RESULTS OF PRENATAL DEVELOPMENTAL
TOXICITY TESTS FOR RATS, LITTER SIZE WAS COMPARABLE BETWEEN THE TREATED
AND CONTROL DOSE GROUPS, WHILE A STATISTICALLY SIGNIFICANT DOSE-RELATED
REDUCTION IN FETAL WEIGHTS WERE NOTED IN THE 1000 AND 2000 PPM DOSE GROUPS.
VISCERAL MALFORMATIONS OCCURRED IN ONE OR FEW FETUSES FROM THE 100, 1000
AND 2000 PPM EXPOSURE GROUPS, WITHOUT A CLEAR DOSE RELATIONSHIP AND NO
STATISTICAL SIGNIFICANCE. NOAEC = 2000PPM (OECD GUIDELINE 414)
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
Fe:
IF INHALED, IRON IS A LOCAL IRRITANT TO THE LUNG AND GASTROINTESTINAL
TRACT.
TITANIUM DIOXIDE:
IN AN ACUTE ORAL TOXICITY TEST WITH RATS AT DOSE OF 1750 MG/KG, NO EFFECTS
ON TOXICITY. (OECD TG 425)
TRICOBALT TETRAOXIDE:
NO CLINICAL SIGNS WERE OBSERVED DURING THE STUDY WITH RATS.
(OECD TG 402, GLP)
MAGNESIUM CARBONATE:
IN ACUTE ORAL TOXICITY TEST WITH RATS, HUNCHED POSTURE WAS NOTED IN THE
INITIAL TREATED ANIMAL DURING THE DAY OF DOSING(FEMALE)(OECD GUIDELINE
420, GLP)
COPPER:
ALL ANIMALS SHOWED EXPECTED GAINS IN BODYWEIGHT OVER THE STUDY PERIOD AND
THERE WERE NO ABNORMALITIES NOTED AT NECROPSY. (OECD TG 423, GLP)
ALUMINUM:
IN TEST USING RATS, CLINICAL SIGNS OF DEPRESSION, LABOURED RESPIRATION,
PILOERECTION AND HUNCHED APPEARANCE WAS NOTED AT THE HIGHEST DOSE
15900 MG/KG. MACROSCOPIC EXAMINATION AT THE END OF THE OBSERVATION PERIOD
DID NOT REVEAL ANY ALUMINIUM-RELATED CHANGES OF THE INTERNAL ORGANS OF THE
ALUMINIUM TREATED ANIMALS COMPARED TO THE CONTROL GROUP. (OECD TG 401)
(FUMED ALUMINA; READ ACROSS)
POLYETHYLENE:
NO TEST SUBSTANCE-RELATED TOXIC EFFECTS WERE OBSERVED IN AN ACUTE ORAL
TOXICITY STUDY WITH RATS.
LITHIUM HEXAFLUOROPHOSPHATE(1-):
CLINICAL SIGNS OBSERVED DURING THE STUDY PERIOD WERE LETHARGY, HUNCHED
POSTURE, UNCOORDINATED MOVEMENTS, PILOERECTION AT 300 MG/KG, HUNCHED
POSTURE, PILOERECTION AT 50 MG/KG. THE SURVIVING ANIMALS HAD RECOVERED
FROM THE SYMPTOMS BY DAY 3.(OECD GUIDELINE 423, GLP)
NICKEL; RANEY NICKEL:
IN THE ACUTE ORAL TOXICITY USING RAT, THERE WERE NO EFFECTS ON CLINICAL
SIGNS, SYSTEMIC TOXICITY.(OECD GUIDELINE 401, GLP)
CHROMIUM:
IN THE ACUTE ORAL TOXICITY USING RAT, SALIVATION INCREASED AMONG ALL
ANIMALS 15 MINUTES AFTER ADMINISTRATION OF THE TEST SUBSTANCE, AND
LASTED ABOUT 8 HOURS. (OECD TG 420, GLP)
ETHYLBENZENE:
IN ACUTE ORAL, INHALATION, DERMAL TOXICITY STUDY WITH RATS, ADVERSE EFFECTS
WERE NOT OBSERVED RELATED TO ACUTE TOXICITY.
SPECIFIC TARGET ORGAN TOXICITY (REPEAT EXPOSURE):
Fe:
RATS WERE EXPOSED TO METALLIC IRON AS CARBONYL IRON VIA THEIR FEED (2.5%)
FOR 2, 4, 6, OR 9 WEEKS. THIS RESULTED IN A STRONG INCREASE OF NON-HEME
IRON IN THE LIVER AND CLEAR LIPID PEROXIDATION IN THE LIVER AND THE MUCOSA
OF THE DUODENUM. NO EVIDENCE FOR DNA BREAKAGE WERE FOUND. WHAT FOLLOWS IS
THE ORIGINAL ABSTRACT OF THE PUBLICATION. (CARBONYL IRON)
TITANIUM DIOXIDE:
IN AN ORAL REPEATED EXPOSURE TEST WITH RATS AT DOSE OF 24,000 MG/KG FOR
90 DAYS, THERE WERE NO SIGNIFICANT DOSE-RELATED EFFECTS. (OECD TG 407)
COBALT HYDROXIDE OXIDE:
UNDER THE CONDITIONS OF THE 2-YEAR INHALATION STUDY, THERE WAS SOME
EVIDENCE OF CARCINOGENIC ACTIVITY OF COBALT SULFATE HEPTAHYDRATE IN MALE
F344/N RATS. INCREASED ALVEOLAR / BRONCHIAL NEOPLASM AND PHEOCHROMOCYTOMA
OF THE ADRENAL GLAND, INFLAMMATORY, FIBROUS, AND PROLIFERATIVE LESIONS
APPEAR IN THE RESPIRATORY TRACT.
LITHIUM CARBONATE; LITHANE:
TRICOBALT TETRAOXIDE:
REPEAT EXPOSURE TO COBALT SULFATE HEPTAHYDRATE CAUSED A SPECTRUM OF
INFLAMMATORY, FIBROTIC, AND PROLIFERATIVE LESIONS IN THE RESPIRATORY
TRACT OF MALE AND FEMALE RATS. (GLP)
MAGNESIUM CARBONATE:
IN REPEATED ORAL TOXICITY TEST WITH RATS, NO SIGNIFICANT TREATMENT-RELATED
EFFECTS WERE NOTED (READ-ACROSS; CAS NO. 7791-18-6)(OECD GUIDELINE 422,
GLP)
COPPER:
IN TEST WITH RATS FOR 92 DAYS, THERE WERE NO MORTALITIES OR SIGNS OF
CLINICAL TOXICITY OBSERVED IN ANY OF THE TEST SPECIES DURING THE DURATION
OF THE STUDY. OPTHALMOSCOPIC EXAMINATIONS REVEALED NO ABNORMALITIES AT ANY
DOSE LEVEL TESTED. AT GROSS PATHOLOGY, SIGNIFICANT DECREASES IN HEART AND
KIDNEY WEIGHT WERE NOTED IN THE HIGH DOSE MALES IN THE THYMUS AND KIDNEYS
OF HIGH DOSE FEMALES. (GLP)
ALUMINUM:
ON OCCASION WORKERS CHRONICALLY EXPOSED TO ALUMINUM-CONTAINING DUSTS OR
FUMES HAVE DEVELOPED SEVERE PULMONARY REACTIONS INCLUDING FIBROSIS,
EMPHYSEMA AND PNEUMOTHORAX.
POLYETHYLENE:
NO SIGNIFICANT ADVERSE EFFECTS WERE OBSERVED IN SUBCHRONIC (90-DAY) ORAL
TOXICITY STUDY WITH RATS AND DOGS.
LITHIUM HEXAFLUOROPHOSPHATE(1-):
ACCORDING TO EXPERT REVIEW OF FLUORIDE INTAKE AND EFFECTS ON HUMAN HEALTH,
FLUORIDE INTAKE IN DRINKING WATER AT LEVELS CLOSE TO OR ABOVE 4 MG/L IS
ASSOCIATED WITH DENTAL FLUOROSIS AND PERHAPS ALSO BONE FLUOROSIS AND/OR
WEAKENING.; DAMAGE TO DENTAL ENAMEL RECORDED: ESPECIALLY NOTABLE IN YOUNG
ANIMALS, WHICH ALSO SHOWED ATROPHY OF RESPIRATORY ORGANS/TISSUES WITH LOCAL
OEDEMA OF BRONCHIAL MUCOSA. OLDER ANIMALS SHOWED PERIBRONCHIAL HYPERPLASIA.
ANIMALS AROUND 1 YEAR IN AGE SHOWED CAVITY FORMATION IN THEIR BONES.
(INFORMATION ON MAJOR HYDROLYSIS PRODUCT OF THE REGISTERED SUBSTANCE
(RELEASED RAPIDLY ON CONTACT WITH WATER/MOISTURE))(OECD GUIDELINE 412)
NICKEL; RANEY NICKEL:
IN NICKEL PLATING INDUSTRY, EXPOSURE TO NICKEL CONTAINING VAPORS HAS BEEN
REPORTED TO BE ASSOC WITH ASTHMA.
CHROMIUM:
IN THE REPEATED DOSE 90-DAY ORAL TOXICITY TEST USING RAT, THERE WERE NO
EFFECTS ON CLINICAL SIGNS, MORTALITY.
ETHYLBENZENE:
IN REPEATED ORAL TOXICITY STUDY WITH RATS FOR 28 DAYS, INCREASED LIVER
WEIGHT AND HEPATOCELLULAR HYPERTROPHY AT HIGHER DOSE LEVELS WERE OBSERVED.
(NOEAL = 75 MG/KG BW/DAY) (OECD TG 407, GLP); IN REPEATED INHALATION
TOXICITY STUDY WITH RATS FOR 13 WEEKS, INCREASES IN LIVER AND KIDNEY
WEIGHTS BUT NO OTHER TREATMENT RELATED EFFECTS WERE OBSERVED IN RATS THAT
INHALED >=250 PPM ETHYLBENZENE VAPOUR FOR 13 WEEKS, NOAEC = 1000PPM
(OECD GUIDELINE 413, GLP), CLASSIFIED AS CATEGORY 2 ACCORDING TO EU GHS
ASPIRATION HAZARD:
ETHYLBENZENE: CLASSIFIED AS CATEGORY 1 ACCORDING TO EU GHS
| SECTION XII - ECOLOGICAL INFORMATION | |
THIS IS A PRODUCT THAT FULFILLS A CERTAIN FUNCTION IN SOLID STATE WITH
SPECIFIC SHAPE WITHOUT DISCHARGING ANY CHEMICAL SUBSTANCE IN ITS USE AND
HAS NO OBLIGATION TO WRITE (M)SDS. SINCE THIS DOCUMENT CONTAINS THE
PRECAUTIONS FOR SAFE HANDLING RELATED TO ITS MATERIALS OR CHEMICAL
SUBSTANCES CONSISTING OF THIS PRODUCT, PLEASE NOTE THAT THESE OVERALL
INFORMATION IS IRRELEVANT TO THIS PRODUCT.
12.1 ECOLOGICAL TOXICITY:
ACUTE TOXICITY: ATEMIX = 0.05 MG/L
CHRONIC TOXICITY: NOT CLASSIFIED
FISH:
GRAPHITE:
96HR-LC50 (BRACHYDANIO RERIO): >100 MG/L
Fe:
96HR-LC50: >10000 MG/L (OECD TG 203, GLP)
TITANIUM DIOXIDE:
96HR-LC50: >100 MG/L
COBALT HYDROXIDE OXIDE:
96HR-LC50: 1.5 MG/L (ASTM GUIDELINE), NOEC=351.4 (MICRO)G/L
LITHIUM CARBONATE; LITHANE:
96HR-LC50:
30.3 MG/L (OECD GUIDELINE 203, GLP), 34D-NOEC (DANIO RERIO) = 15.28 MG/L
(READ ACROSS; LITHIUM HYDROXIDE MONOHYDRATE)(OECD GUIDELINE 210, GLP)
TRICOBALT TETRAOXIDE:
96HR-LC50:
>136 MG/L (OECD TG 203, GLP), 34D-NOEC (PIMEPHALES PROMELAS) = 0.21 MG/L
MAGNESIUM CARBONATE:
96HR-LC50: 2120 MG/L (READ-ACROSS; CAS NO. 7786-30-3)
ALUMINUM:
96HR-LC50:
>218.64 MG/L (GLP)(READ ACROSS; ALUMINIUM CHLORIDE HEXAHYDRATE), 28D-NOEC
(PIMEPHALES PROMELAS) = 4.7 MG/L (READ ACROSS; ALUMINIUM SULPHATE)
CARBON: 28D-NOEC(DANIO RERIO) = 0.000002 MG/KG BDWT (ESTIMATED)
1,3-DIOXOLAN-2-ONE:
96HR-LC50: >100 MG/L (OECD GUIDELINE 203, GLP)
LITHIUM HEXAFLUOROPHOSPHATE(1-):
96HR-LC50: 51 - 193 MG/L INFORMATION ON MAJOR HYDROLYSIS PRODUCT OF THE
REGISTERED SUBSTANCE (RELEASED RAPIDLY ON CONTACT WITH WATER/MOISTURE);
21D-NOEC = 4 MG F-/L
ETHYL ACETATE: 96HR-LC50 = 230 MG/L
1-METHYL-2-PYRROLIDINONE:
96HR-LC50: >500 MG/L (BBA-BULLETIN NO. 33, 2. EDITION)
ETHYLBENZENE:
96HR-LC50: 4.2 MG/L (OECD GUIDELINE 203)
CRUSTACEAN:
GRAPHITE:
48HR-EC50 (DAPHNIA MAGNA): >100 MG/L
Fe:
48HR-EC50: >100 MG/L (OECD TG 202, GLP)
TITANIUM DIOXIDE:
48HR-EC50: 29.7 MG/L (OECD TG 202, GLP), 25D-NOEC(DAPHNIA MAGNA) =/>70 MG/L
COBALT HYDROXIDE OXIDE:
48HR-LC50: >64.8 MG/L (OECD GUIDELINE 202, GLP)
LITHIUM CARBONATE; LITHANE:
48HR-EC50: 33.2 MG/L (OECD GUIDELINE 202, GLP), 21D-NOEC
(DAPHNIA MAGNA) = 9 MG/L (READ ACROSS; LITHIUM) (OECD GUIDELINE 211, GLP)
TRICOBALT TETRAOXIDE:
48HR-LC50: >136 MG/L (OECD TG 203, GLP)
MAGNESIUM CARBONATE:
48HR-LC50: 140 MG/L (WITHOUT FOOD)(READ-ACROSS ; CAS NO. 7791-18-6),
3WK-LC50 (DAPHNIA MAGNA) = 665 MG/L (READ-ACROSS ; CAS NO. 7791-18-6)
ALUMINUM:
48HR-LC50: 0.071 MG/L (READ ACROSS; CAS 13473-90-0), 8D-NOEC
(CERIODAPHNIA DUBIA) = 4.9 MG/L (READ ACROSS; CAS 7784-13-6)
1,3-DIOXOLAN-2-ONE:
48HR-EC50: >100 MG/L (OECD GUIDELINE 202, GLP)
LITHIUM HEXAFLUOROPHOSPHATE(1-):
48HR-LC50: >100 MG/L (OECD GUIDELINE 202, GLP); 21D-NOEC(DAPHNIA MAGNA)
= 10 MG/L (INFORMATION ON MAJOR HYDROLYSIS PRODUCT OF THE REGISTERED
SUBSTANCE (RELEASED RAPIDLY ON CONTACT WITH WATER/MOISTURE))
(OECD GUIDELINE 202, GLP)
ETHYL ACETATE:
24HR-EC50: 2500 MG/L
1-METHYL-2-PYRROLIDINONE:
24HR-EC50: >1000 MG/L GERMAN INDUSTRIAL STANDARD DIN 38 412 PART 11
ETHYLBENZENE:
48HR-EC50: 1.8 - 2.4 MG/L (EPA METHOD F), 7D-NOEC (CERIODAPHNIA DUBIA)
= 0.96 MG/L (U.S. EPA 600/4-91-003)
ALGAE:
GRAPHITE:
72HR-EC50 (SELENASTRUM CAPRICORNUTUM): >100 MG/L
TITANIUM DIOXIDE:
72HR-EC50: >100 MG/L (OECD TG 201), 72HR-NOEC (PSEUDOKIRCHNERELLA
SUBCAPITATA) >= 100 MG/L
COBALT HYDROXIDE OXIDE:
72HR-EC50: 0.043 MG/L (OECD GUIDELINE 201, GLP)
LITHIUM CARBONATE; LITHANE:
72HR-EC50: >400 MG/L
TRICOBALT TETRAOXIDE:
72HR-EC50:
88 MG/L (OECD TG 201, GLP), 72HR-NOEC(SELENASTRUM CAPRICORNUTUM) = 9.8 MG/L
MAGNESIUM CARBONATE:
72HR-EC50:
>18.5 MG/L (OECD GUIDELINE 201, GLP, READ-ACROSS; CAS NO. 7791-18-6),
72HR-NOEC (SCENEDESMUS SUBSPICATUS) = 100 MG/L (OECD GUIDELINE 201, GLP,
READ-ACROSS ; CAS NO. 7791-18-6)
ALUMINUM:
72HR-EC50: 0.0169 MG/L (OECD TG 201), (READ ACROSS; CAS 13473-90-0)
CARBON:
72H-NOEC(NAVICULA LONGA): 50 MG/L (ESTIMATED)
1,3-DIOXOLAN-2-ONE:
72HR-EC50:
>100 MG/L (OECD GUIDELINE 201, GLP), 72HR-NOEC(SELENASTRUM CAPRICORNUTUM)
= 100MG/L(OECD GUIDELINE 201, GLP)
LITHIUM HEXAFLUOROPHOSPHATE(1-):
96HR-EC50: >100 MG/L; 96H-NOEC = 22 MG/L (OECD GUIDELINE 201, GLP)
ETHYL ACETATE:
1-METHYL-2-PYRROLIDINONE:
72HR-EC50: 600.5 MG/L
ETHYLBENZENE:
96HR-EC50:
3.6 MG/L (U.S. EPA. 1985. TOXIC SUBSTANCE CONTROL ACT TEST GUIDELINES)
12.2 PERSISTENCE AND DEGRADABILITY:
PERSISTENCE:
GRAPHITE:
LOW PERSISTENCY (LOG KOW IS LESS THAN 4 ESTIMATED.) (LOG KOW = 0.78)
MAGNESIUM CARBONATE:
LOW PERSISTENCY (LOG KOW IS LESS THAN 4 ESTIMATED.) (LOG KOW = -2.12)
(ESTIMATED)
ALUMINUM:
LOW PERSISTENCY (LOG KOW IS LESS THAN 4 ESTIMATED.) (LOG KOW = 0.33)
(ESTIMATED)
1,3-DIOXOLAN-2-ONE:
LOW PERSISTENCY (LOG KOW IS LESS THAN 4 ESTIMATED.) (LOG KOW = 0.11)
(20 DEG. C, PH >5.33 - <5.79) (EU METHOD A.8, GLP)
LITHIUM HEXAFLUOROPHOSPHATE(1-):
LOW PERSISTENCY (LOG KOW IS LESS THAN 4 ESTIMATED.) (LOG KOW = 0.354)
(20 DEG. C, PH >6.5 - <7.5) ( OECD GUIDELINE 107, GLP)
ETHYL ACETATE:
LOW PERSISTENCY (LOG KOW IS LESS THAN 4 ESTIMATED.) (LOG KOW = 0.68)
1-METHYL-2-PYRROLIDINONE:
LOW PERSISTENCY (LOG KOW IS LESS THAN 4 ESTIMATED.) (LOG KOW = -0.46)
BUTANEDINITRILE:
LOW PERSISTENCY (LOG KOW IS LESS THAN 4 ESTIMATED.) (LOG KOW = -0.99)
ETHYLBENZENE:
LOW PERSISTENCY (LOG KOW IS LESS THAN 4 ESTIMATED.) (LOG KOW = 3.6)
(EU METHOD A.8)
DEGRADABILITY: NOT AVAILABLE
12.3 BIOACCUMULATIVE POTENTIAL:
BIOACCUMULATION:
GRAPHITE:
BIOACCUMULATION IS EXPECTED TO BE LOW ACCORDING TO THE BCF <500
(BCF = 2.433)
MAGNESIUM CARBONATE:
BIOACCUMULATION IS EXPECTED TO BE LOW ACCORDING TO THE BCF <500
(BCF = 3.162) (ESTIMATED)
COPPER:
BIOACCUMULATION IS EXPECTED TO BE LOW ACCORDING TO THE BCF <500
(BCF = 0.02 - 20)
ALUMINUM:
BIOACCUMULATION IS EXPECTED TO BE LOW ACCORDING TO THE BCF <500
(BCF = 3.162) (ESTIMATED)
DIMETHYL CARBONATE:
BIOACCUMULATION IS EXPECTED TO BE LOW ACCORDING TO THE BCF <500
(BCF = 3.2)
1,3-DIOXOLAN-2-ONE:
BIOACCUMULATION IS EXPECTED TO BE LOW ACCORDING TO THE BCF <500
(BCF = 3.162) (ESTIMATED)
LITHIUM HEXAFLUOROPHOSPHATE(1-):
BIOACCUMULATION IS EXPECTED TO BE LOW ACCORDING TO THE BCF <500
(BCF <31)
ETHYL ACETATE:
BIOACCUMULATION IS EXPECTED TO BE LOW ACCORDING TO THE BCF <500
(BCF = 30)
NICKEL; RANEY NICKEL:
BIOACCUMULATION IS EXPECTED TO BE LOW ACCORDING TO THE BCF <500
(BCF = 70)
BUTANEDINITRILE:
BIOACCUMULATION IS EXPECTED TO BE LOW ACCORDING TO THE BCF <500
(BCF = 3) (ESTIMATED)
ETHYLBENZENE:
BIOACCUMULATION IS EXPECTED TO BE LOW ACCORDING TO THE BCF <500
(BCF = 1)
BIODEGRADATION:
MAGNESIUM CARBONATE: NOT READILY BIODEGRADABLE (ESTIMATED)
DIMETHYL CARBONATE:
AS WELL-BIODEGRADED, IT IS EXPECTED TO HAVE LOW ACCUMULATION POTENTIAL IN
LIVING ORGANISMS (= 86% BIODEGRADATION WAS OBSERVED AFTER 28 DAYS)
(OECD GUIDELINE 301 C, GLP)
POLYETHYLENE:
AS NOT WELL-BIODEGRADED, IT IS EXPECTED TO HAVE HIGH ACCUMULATION POTENTIAL
IN LIVING ORGANISMS (= 0% BIODEGRADATION WAS OBSERVED AFTER 28 DAYS)
1,3-DIOXOLAN-2-ONE:
AS WELL-BIODEGRADED, IT IS EXPECTED TO HAVE LOW ACCUMULATION POTENTIAL IN
LIVING ORGANISMS (70% - 80% BIODEGRADATION WAS OBSERVED AFTER 10 DAYS)
(OECD GUIDELINE 301 A, GLP)
LITHIUM HEXAFLUOROPHOSPHATE(1-):
AS WELL-BIODEGRADED, IT IS EXPECTED TO HAVE LOW ACCUMULATION POTENTIAL IN
LIVING ORGANISMS (= 86% BIODEGRADATION WAS OBSERVED AFTER 28 DAYS)
(OECD GUIDELINE 301 C, GLP)
ETHYL ACETATE:
AS WELL-BIODEGRADED, IT IS EXPECTED TO HAVE LOW ACCUMULATION POTENTIAL IN
LIVING ORGANISMS (= 62% BIODEGRADATION WAS OBSERVED AFTER 10 DAYS)
1-METHYL-2-PYRROLIDINONE:
AS WELL-BIODEGRADED, IT IS EXPECTED TO HAVE LOW ACCUMULATION POTENTIAL IN
LIVING ORGANISMS (= 73% BIODEGRADATION WAS OBSERVED AFTER 28 DAYS)
BUTANEDINITRILE:
AS NOT WELL-BIODEGRADED, IT IS EXPECTED TO HAVE HIGH ACCUMULATION POTENTIAL
IN LIVING ORGANISMS (= 45.1% BIODEGRADATION WAS OBSERVED AFTER 4 DAYS)
ETHYLBENZENE:
AS WELL-BIODEGRADED, IT IS EXPECTED TO HAVE LOW ACCUMULATION POTENTIAL IN
LIVING ORGANISMS (70% - 80% BIODEGRADATION WAS OBSERVED AFTER 28 DAYS)
(ISO 14593-CO2-HEADSPACE TEST)
12.4 MOBILITY IN SOIL:
MAGNESIUM CARBONATE:
LOW POTENCY OF MOBILITY TO SOIL. (KOC = 0.3336) (ESTIMATED)
1,3-DIOXOLAN-2-ONE:
LOW POTENCY OF MOBILITY TO SOIL. (KOC = 3.219) (ESTIMATED)
ETHYL ACETATE: LOW POTENCY OF MOBILITY TO SOIL. (KOC = 6)
1-METHYL-2-PYRROLIDINONE:
LOW POTENCY OF MOBILITY TO SOIL. (KOC = 20.94) (ESTIMATED)
NICKEL; RANEY NICKEL: LOW POTENCY OF MOBILITY TO SOIL. (KOC = 2.86)
BUTANEDINITRILE: LOW POTENCY OF MOBILITY TO SOIL. (KOC = 28) (ESTIMATED)
ETHYLBENZENE: LOW POTENCY OF MOBILITY TO SOIL. (KOC = 257.04)
12.5 RESULTS OF PBT AND VPVB ASSESSMENT: NOT AVAILABLE
12.6 OTHER ADVERSE EFFECTS: NOT AVAILABLE
| SECTION XIII - DISPOSAL CONSIDERATION | |
13.1 WASTE TREATMENT METHODS:
PRODUCT/PACKAGING DISPOSAL:
CONSIDER THE REQUIRED ATTENTIONS IN ACCORDANCE WITH WASTE TREATMENT
MANAGEMENT REGULATION.
WASTE CODES / WASTE DESIGNATION ACCORDING TO LOW(2015): 16-06-05
WASTE TREATMENT-RELEVANT INFORMATION:
WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
ENVIRONMENTAL CONTROL REGULATIONS.
SEWAGE DISPOSAL-RELEVANT INFORMATION: NOT AVAILABLE
OTHER DISPOSAL RECOMMENDATIONS: NOT AVAILABLE
| SECTION XIV - TRANSPORTATION INFORMATION | |
IF THOSE LITHIUM-ION BATTERIES ARE PACKED WITH OR CONTAINED IN AN
EQUIPMENT, THEN IT IS THE RESPONSIBILITY OF THE SHIPPER TO ENSURE THAT
THE CONSIGNMENT ARE PACKED IN COMPLIANCE TO THE LATEST EDITION OF THE
IATA DANGEROUS GOODS REGULATIONS SECTION II OF EITHER PACKING INSTRUCTION
966 OR 967 IN ORDER FOR THAT CONSIGNMENT TO BE DECLARED AS NOT RESTRICTED
(NON-HAZARDOUS/NON-DANGEROUS). IF THOSE LITHIUM-ION BATTERIES ARE PACKED
WITH OR CONTAINED IN AN EQUIPMENT, UN NO. IS UN3481.
14.1 UN NUMBER: 3480
14.2 UN PROPER SHIPPING NAME: LITHIUM ION BATTERIES
14.3 TRANSPORT HAZARD CLASS: 9
14.4 PACKING GROUP: II
14.5 SPECIAL PROVISIONS: 188, 230, 384
14.6 PACKING INSTRUCTIONS: P903
14.7 ENVIRONMENTAL HAZARDS: NO
14.8 SPECIAL PRECAUTIONS FOR USER:
IN CASE OF FIRE: F-A
IN CASE OF LEAKAGE: S-I
14.9 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC
CODE: NOT AVAILABLE
14.10 IATA TRANSPORT: PI 965-SECTION IB
14.11 PACKAGE LABELS:
CLASS 9, MISCELLANEOUS PRODUCTS, SUBSTANCES, OR ORGANISMS
| SECTION XV - REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATION/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
EU REGULATIONS:
AUTHORISATIONS AND/OR RESTRICTIONS ON USE:
AUTHORISATIONS: NOT REGULATED
RESTRICTIONS ON USE:
1-METHYL-2-PYRROLIDINONE: REGULATED
NICKEL: REGULATED
OTHER EU REGULATIONS:
EU SVHC LIST:
1-METHYL-2-PYRROLIDINONE: REGULATED
FOREIGN REGULATORY INFORMATION:
EXTERNAL INFORMATION:
U.S.A MANAGEMENT INFORMATION (OSHA REGULATION): NOT REGULATED
U.S.A MANAGEMENT INFORMATION (CERCLA REGULATION):
COPPER: 5,000 LB
ETHYL ACETATE: 5,000 LB
NICKEL: 100 LB
CHROMIUM: 5,000 LB
ETHYLBENZENE: 1,000 LB
U.S.A MANAGEMENT INFORMATION (EPCRA 302 REGULATION): NOT REGULATED
U.S.A MANAGEMENT INFORMATION (EPCRA 304 REGULATION): NOT REGULATED
U.S.A MANAGEMENT INFORMATION (EPCRA 313 REGULATION):
COBALT, Co: REGULATED
LITHIUM CARBONATE
ALUMINIUM (METAL): REGULATED
COPPER: REGULATED
1-METHYL-2-PYRROLIDINONE: REGULATED
NICKEL: REGULATED
CHROMIUM: REGULATED
SUBSTANCE OF ROTERDAME PROTOCOL: NOT REGULATED
SUBSTANCE OF STOCKHOLME PROTOCOL: NOT REGULATED
SUBSTANCE OF MONTREAL PROTOCOL: NOT REGULATED
15.2 CHEMICAL SAFETY ASSESSMENT:
NO CHEMICAL SAFETY ASSESSMENT HAS BEEN CARRIED OUT FOR THIS PRODUCT BY THE
SUPPLIER.
| SECTION XVI - OTHER INFORMATION EU | |
PRODUCT SAFETY DATA SHEET FOR PA0001N0006A/PA0001N0007A/PA001N0008A
PREPARED IN ACCORDANCE WITH REGULATION (EU) 2015/830 (REACH), ANNEX II,
AND OSHA 29 CFR 1910.1200
16.1 INDICATION OF CHANGES:
DATE UPDATED: 28 JUNE. 2018
VERSION: REV. 01
16.2 ABBREVIATIONS AND ACRONYMS:
ACGIH: AMERICAN CONFERENCE OF GOVERNMENT INDUSTRIAL HYGIENISTS
CLP:
CLASSIFICATION LABELLING PACKAGING REGULATION; REGULATION (EC) NO 1272/2008
CAS NO.: CHEMICAL ABSTRACTS SERVICE NUMBER
DMEL: DERIVED MINIMAL EFFECT LEVELS
DNEL: DERIVED NO EFFECT LEVEL
EC NUMBER: EINECS AND ELINCS NUMBER (SEE ALSO EINECS AND ELINCS)
EU: EUROPEAN UNION
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
ISHL: INDUSTRIAL SAFETY & HEALTH LAW
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY & HEALTH
NTP: NATIONAL TOXICOLOGY PROGRAM
OSHA: EUROPEAN AGENCY FOR SAFETY AND HEALTH AT WORK
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC SUBSTANCE
PNEC(S): PREDICTED NO EFFECT CONCENTRATION(S)
REACH:
REGISTRATION, EVALUATION, AUTHORISATION AND RESTRICTION OF CHEMICALS
REGULATION (EC) NO 453/2010
STP: SEWAGE TREATMENT PLANT
SVHC: SUBSTANCES OF VERY HIGH CONCERN
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
UN: UNITED NATIONS
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS (IMO)
IBC: INTERMEDIATE BULK CONTAINER
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION & LIABILITY ACT (US)
EPCRA: EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT (US)
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
16.3 KEY LITERATURE REFERENCE AND SOURCES FOR DATA:
U.S. NATIONAL LIBRARY OF MEDICINE (NLM) HAZARDOUS SUBSTANCES DATA BANK
(HSDB)
LOOKCHEM; HTTP://WWW.LOOKCHEM.COM/
IUCLID: HTTP://ECB.JRC.EC.EUROPA.EU/IUCLID-DATASHEETS/7631905.PDF
CHRIP(CHEMICAL RISK INFORMATION PLATFORM)
EPISUITE V4.11; HTTP://WWW.EPA.GOV/OPT/EXPOSURE/PUBS/EPISUITEDL.HTML
THE CHEMICAL DATABASE:
THE DEPARTMENT OF CHEMISTRY AT THE UNIVERSITY OF AKRON;
HTTP://ULL.CHEMISTRY.UAKRON.EDU/ERD/
ECOTOX: HTTP://CFPUB.EPA.GOV/ECOTOX/
INTERNATIONAL CHEMICAL SAFETY CARDS (ICSC): HTTP://WWW.NIHS.GO.JP/ICSC/
NATIONAL CHEMICAL INFORMATION SYSTEM (HTTP://NCIS.NIER.GO.KR)
KOREA DANGEROUS MATERIAL INVENTORY MANAGEMENT SYSTEM
(HTTP://HAZMAT.NEMA.GO.KR)
REACH INFORMATION ON REGISTERED SUBSTANCES;
HTTPS://ECHA.EUROPA.EU/INFORMATION-ON-CHEMICALS/REGISTERED-SUBSTANCES
EU CLP; HTTPS://ECHA.EUROPA.EU/INFORMATION-ON-CHEMICALS/CL-INVENTORY-
DATABASE
NIOSH POCKET GUIDE; HTTP://WWW.CDC.GOV/NIOSH/NPG/NPGDCAS.HTML
IARC MONOGRAPHS ON THE EVALUATION OF CARCINOGENIC RISKS TO HUMANS;
HTTP://MONOGRAPHS.IARC.FR
NATIONAL TOXICOLOGY PROGRAM; HTTP://NTP.NIEHS.NIH.GOV/RESULTS/DBSEARCH/
TOMES-LOLI(R*); HTTP://WWW.RIGHTANSWERKNOWLEDGE.COM/LOGINRA.ASP
UN RECOMMENDATIONS ON THE TRANSPORT OF DANGEROUS GOODS 17TH
AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS TLVS AND BEIS.
16.4 CLASSIFICATION AND PROCEDURE USED TO DERIVE THE CLASSIFICATION FOR
MIXTURES ACCORDING TO REGULATION(EC) 1272/2008(CLP): NOT CLASSIFIED
16.5 RELEVANT H-STATEMENTS: NOT APPLICABLE
16.6 TRAINING ADVICE:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
16.7 FURTHER INFORMATION:
DATA OF SECTIONS 4 TO 8, AS WELL AS 10 TO 12, DO NOT NECESSARILY REFER TO
THE USE AND THE REGULAR HANDLING OF THE PRODUCT (IN THIS SENSE CONSULT
PACKAGE LEAFLET AND EXPERT INFORMATION), BUT TO RELEASE OF MAJOR AMOUNTS
IN CASE OF ACCIDENTS AND IRREGULARITIES. THE INFORMATION DESCRIBES
EXCLUSIVELY THE SAFETY REQUIREMENTS FOR THE PRODUCT (S) AND IS BASED ON
THE PRESENT LEVEL OF OUR KNOWLEDGE. THIS DATA DOES NOT CONSTITUTE A
UARANTEE FOR THE CHARACTERISTICS OF THE PRODUCT(S) AS DEFINED BY THE LEGAL
WARRANTY REGULATIONS. "(N.A. = NOT APPLICABLE; N.D. = NOT DETERMINED)"
THE DATA FOR THE HAZARDOUS INGREDIENTS WERE TAKEN RESPECTIVELY FROM THE
LAST VERSION OF THE SUB-CONTRACTOR'S SAFETY DATA SHEET.